INFORMATION GPO
SUBCHAPTER C—HAZARDOUS MATERIALS REGU LATIONS
PART 171—GENERAL INFORMA U.S.C. 2461 note); Pub. L. 104—134 section TION, REGULATIONS, AND DEFI 31001. NITIONS EDITORIAL NOTE: Nomenclature changes to part 171 appear at 70 FR 56090, Sept. 23, 2005. Sec. Subpart A—Applicability, General Subpart A—Applicability, General Require Requirements, and North ments, and North American Shipments American Shipments 171.1 Applicability of Hazardous Materials Regulations (HMR) to persons and func § 171.1 Applicability of Hazardous Ma tions. terials Regulations (HMR) to per 171.2 General requirements. sons and functions. 171.3 Hazardous waste. Federal hazardous materials trans 171.4 Marine pollutants. portation law (49 U.S.C. 5101 et di 171.6 Control numbers under the Paperwork seq.) Reduction Act. rects the Secretary of Transportation 171.7 Reference material. to establish regulations for the safe 171.8 Definitions and abbreviations. and secure transportation of hazardous 171.9 Rules of construction. materials in commerce, as the Sec 171.10 Units of measure. retary considers appropriate. The Sec 171.11 [Reserved] retary is authorized to apply these reg 171.12 North American Shipments. ulations to persons who transport haz 171.12a [Reserved] ardous materials in commerce. In addi 171.14 Transitional provisions for imple tion, the law menting certain requirements. authorizes the Secretary to apply these regulations to persons Subpart B—Incident Reporting, Notification, who cause hazardous materials to be BOE Approvals and Authorization transported in commerce. The law also authorizes the Secretary to apply these 171.15 Immediate notice of certain haz regulations to persons who manufac ardous materials incidents. ture or maintain a packaging or a com 171.16 Detailed hazardous materials inci ponent of a packaging that is rep dent reports. 171.17—171.18 [Reserved] resented, marked, certified, or sold as 171.19 Approvals or authorizations issued by qualified for use in the transportation the Bureau of Explosives. of a hazardous material in commerce. 171.20 Submission of Examination Reports. Federal hazardous material transpor 171.21 Assistance in investigations and spe tation law also applies to anyone who cial studies. indicates by marking or other means that a hazardous material being trans Subpart C—Authorization and Require ported in commerce is present in a ments for the Use of International package or transport conveyance when Transport Standards and Regulations it is not, and to anyone who tampers 171.22 Authorization and conditions for the with a package or transport convey use of international standards and regu ance used to transport hazardous mate lations. rials in commerce or a required mark 171.23 Requirements for specific materials ing, label, placard, or shipping descrip and packagings transported under the tion. Regulations prescribed in accord ICAO Technical Instructions, IMDG ance with Federal hazardous materials Code, Transport Canada TDG Regula tions, or the IAEA Regulations. transportation law shall govern safety 171.24 Additional requirements for the use aspects, including security, of the of the ICAO Technical Instructions. transportation of hazardous materials 171.25 Additional requirements for the use that the Secretary considers appro of the IMDG Code. priate. In 49 CFR 1.53, the Secretary 171.26 Additional requirements for the use delegated authority to issue regula of the IAEA Regulations. tions for the safe and secure transpor AUTHORITY: 49 U.S.C. 5101—5128, 44701; 49 tation of hazardous materials in com CFR 1.45 and 1.53; Pub. L. 101—410 section 4 (28 merce to the Pipeline and Hazardous
76 Pipeline and Hazardous Materials Safety Admin., DOT § 171.1 Materials Safety Administrator. The (5) Marking a package to indicate Administrator issues the Hazardous that it contains a hazardous material. Materials Regulations (HMR; 49 CFR (6) Labeling a package to indicate Parts 171 through 180) under that dele that it contains a hazardous material. gated authority. This section addresses (7) Preparing a shipping paper. the applicability of the HMR to pack (8) Providing and maintaining emer agings represented as qualified for use gency response information. in the transportation of hazardous ma (9) Reviewing a shipping paper to terials in commerce and to pre-trans verify compliance with the HMR or portation and transportation func international equivalents. tions. (10) For each person importing a haz (a) Packagings. Requirements in the ardous material into the United States, HMR apply to each person who manu providing with timely factures, fabricates, marks, maintains, the shipper and complete information to the HMR reconditions, repairs, or tests a pack as requirements aging or a component of a packaging that will apply to the that is represented, marked, certified, transportation of the material within or sold as qualified for use in the trans the United States. portation of a hazardous material in (11) Certifying that a hazardous ma commerce, including each person under terial is in proper condition for trans contract with any department, agency, portation in conformance with the re or instrumentality of the executive, quirements of the HMR. legislative, or judicial branch of the (12) Loading, blocking, and bracing a Federal government who manufac hazardous materials package in a tures, fabricates, marks, maintains, re freight container or transport vehicle. conditions, repairs, or tests a pack (13) Segregating a hazardous mate aging or a component of a packaging rials package in a freight container or that is represented, marked, certified, transport vehicle from incompatible or sold as qualified for use in the trans cargo. portation of a hazardous material in (14) Selecting, providing, or affixing commerce. placards for a freight container or (b) Pre-transportation functions. Re transport vehicle to indicate that it quirements in the HMR apply to each contains a hazardous material. person who offers a hazardous material (c) Transportation functions. Require for transportation in commerce, causes ments in the HMR apply to transpor a hazardous material to be transported tation of a hazardous material in com in commerce, or transports a hazardous merce and to each person who trans material in commerce and who per ports a hazardous material in com forms or is responsible for performing a merce, including each person under pre-transportation function, including contract with any department, agency, each person performing pre-transpor or instrumentality of the executive, tation functions under contract with legislative, or judicial branch of the any department, agency, or instrumen Federal government who transports a tality of the executive, legislative, or hazardous material in commerce. judicial branch of the Federal govern Transportation of a hazardous material ment. Pre-transportation functions in in commerce begins when a carrier clude, but are not limited to, the fol takes physical possession of the haz lowing: ardous material for the purpose of (1) Determining the hazard class of a transporting it and continues until the hazardous material. package containing the hazardous ma (2) Selecting a hazardous materials terial is delivered to the destination packaging. indicated on a shipping document, (3) Filling a hazardous materials package marking, or other medium, or, packaging, including a bulk packaging. in the case of a rail car, until the car (4) Securing a closure on a filled or is delivered to a private track or sid partially filled hazardous materials ing. For a private motor carrier, trans package or container or on a package portation of a hazardous material in or container containing a residue of a commerce begins when a motor vehicle hazardous material. driver takes possession of a hazardous
77 § 171.1 49 CFR Ch. I (10—1—10 Edition)
material for the purpose of trans Unloading incidental to movement in porting it and continues until the driv cludes transloading. er relinquishes possession of the pack (4) Storage incidental to movement of a age containing the hazardous material hazardous material. Storage of a trans at its destination and is no longer re port vehicle, freight container, or sponsible for performing functions sub package containing a hazardous mate ject to the HMR with respect to that rial by any person between the time particular package. Transportation of that a carrier takes physical possession a hazardous material in commerce in of the hazardous material for the pur cludes the following: pose of transporting it until the pack (1) Movement. Movement of a haz age containing the hazardous material ardous material by rail car, aircraft, has been delivered to the destination motor vehicle, or vessel (except as del indicated on a shipping document, egated by Department of Homeland Se package marking, or other curity Delegation No. 0170 at 2(103)). medium, or, in the (2) Loading incidental to movement of a case of a private motor carrier, hazardous material. Loading of pack between the time that a motor vehicle aged or containerized hazardous mate driver takes physical possession of the rial onto a transport vehicle, aircraft, hazardous material for the purpose of or vessel for the purpose of trans transporting it until the driver relin porting it, including blocking and brac quishes possession of the package at its ing a hazardous materials package in a destination and is no longer respon freight container or transport vehicle, sible for performing functions subject and segregating a hazardous materials to the HMR with respect to that par package in a freight container or trans ticular package. port vehicle from incompatible cargo, (1) Storage incidental to movement when performed by carrier personnel or includes— in the presence of carrier personnel. (A) Storage at the destination shown For a bulk packaging, loading inci on a shipping document, including dental to movement is filling the pack storage at a transloading facility, pro aging with a hazardous material for vided the original shipping documenta the purpose of transporting it when tion identifies the shipment as a performed by carrier personnel or in through-shipment and identifies the the presence of carrier personnel (ex final destination or destinations of the cept as delegated by Department of hazardous material; and Homeland Security Delegation No. 0170 (B) A rail car containing a hazardous at 2(103)), including transloading. material that is stored on track that (3) Unloading incidental to movement of does not meet the definition of “pri a hazardous material. Removing a pack vate track or siding” in §171.8, even if age or containerized hazardous mate the car has been delivered to the des rial from a transport vehicle, aircraft, tination shown on the shipping docu or vessel; or for a bulk packaging, ment. emptying a hazardous material from the bulk packaging after the hazardous (ii) Storage incidental to movement material has been delivered to the con does not include storage of a hazardous signee when performed by carrier per material at its final destination as sonnel or in the presence of carrier per shown on a shipping document. sonnel or, in the case of a private (d) Functions not subject to the require motor carrier, while the driver of the ments of the HMR. The following are ex motor vehicle from which the haz amples of activities to which the HMR ardous material is being unloaded im do not apply: mediately after movement is com (1) Storage of a freight container, pleted is present during the unloading transport vehicle, or package con operation. (Emptying a hazardous ma taining a hazardous material at an of terial from a bulk packaging while the feror facility prior to a carrier taking packaging is on board a vessel is sub possession of the hazardous material ject to separate regulations as dele for movement in transportation in gated by Department of Homeland Se commerce or, for a private motor car curity Delegation No. 0170 at 2(103).) rier, prior to a motor vehicle driver 78 Pipeline and Hazardous Materials Safety Admin., DOT § 171.1 taking physical possession of the haz authorized by another Federal statute ardous material for movement in or DOT issues a waiver of preemption, transportation in commerce. if— (2) Unloading of a hazardous material (i) Complying with both the non-Fed from a transport vehicle or a bulk eral requirement and Federal haz packaging performed by a person em ardous materials transportation law, ployed by or working under contract to the regulations issued under Federal the consignee following delivery of the hazardous material transportation law hazardous material by the carrier to or a hazardous material transportation its destination and departure from the security regulation or directive issued consignee’s premises of the carrier’s by the Secretary of Homeland Security personnel or, in the case of a private is not possible; carrier, departure of the driver from (ii) The non-Federal requirement, as the unloading area. applied or enforced, is an obstacle to (3) Storage of a freight container, accomplishing and carrying out Fed transport vehicle, or package con eral hazardous materials transpor taining a hazardous material after its tation law, the regulations issued delivery by a carrier to the destination under Federal hazardous material indicated on a shipping document, transportation law, or a hazardous ma package marking, or other medium, or, terial transportation security regula in the case of a rail car, storage of a tion or directive issued by the Sec rail car on private track. retary of Homeland Security; (4) Rail and motor vehicle move (iii) The non-Federal requirement is ments of a hazardous material exclu not substantively the same as a provi sively within a contiguous facility sion of Federal hazardous materials boundary where public access is re transportation law, the regulations stricted, except to the extent that the issued under Federal hazardous mate movement is on or crosses a public rial transportation law, or a hazardous road or is on track that is part of the material transportation security regu general railroad system of transpor lation or directive issued by the Sec tation, unless access to the public road retary of Homeland Security with re is restricted by signals, lights, gates, spect to— or similar controls. (A) The designation, description, and (5) Transportation of a hazardous ma classification of hazardous material; terial in a motor vehicle, aircraft, or (B) The packing, repacking, handling, vessel operated by a Federal, state, or labeling, marking, and placarding of local government employee solely for hazardous material; noncommercial Federal, state, or local (C) The preparation, execution, and government purposes. use of shipping documents related to (6) Transportation of a hazardous ma hazardous material and requirements terial by an individual for non-com related to the number, contents, and mercial purposes in a private motor ve placement of those documents: hicle, including a leased or rented (D) The written notification, record motor vehicle. ing, and reporting of the unintentional (7) Any matter subject to the postal release of hazardous material: or laws and regulations of the United (E) The design, manufacturing, fabri States. cating, marking, maintenance, recon (e) Requirements of other Federal agen ditioning, repairing, or testing of a cies. Each facility at which pre-trans package or container represented, portation or transportation functions marked, certified, or sold as qualified are performed in accordance with the for use in transporting hazardous ma HMR may be subject to applicable terial. standards and regulations of other Fed (iv) A non-Federal designation, limi eral agencies. tation or requirement on highway (f) Requirements of state and local gov routes over which hazardous material ernment agencies. (1) Under 49 U.S.C. may or may not be transported does 5125, a requirement of a state, political not comply with the regulations in subdivision of a state, or an Indian subparts C and D of part 397 of this tribe is preempted, unless otherwise title: or
79 § 171.2 49 CFR Ch. I (10—1—10 Edition)
(v) A fee related to the transpor involves the release of a hazardous ma tation of a hazardous material is not terial which results in death or bodily fair or is used for a purpose that is not injury to any person. related to transporting hazardous ma terial, including enforcement and plan [68 FR 61937, Oct. 30, 2003; 70 FR 20031, Apr. 15, 2005, as amended at 70 FR 73162, Dec. 9, ning, developing, and maintaining a ca 2005; 71 FR 8488, Feb. 17, 2006; 71 FR 44931, pability for emergency response. Aug. 8. 2006; 74 FR 68702, Dec. 29, 2009; 75 FR (2) Subject to the limitations in para 53596, Sept. 1, 2010] graph (f) (1) of this section, each facil ity at which functions regulated under § 171.2 General requirements. the HMR are performed may be subject (a) Each person who performs a func to applicable laws and regulations of tion covered by this subchapter must state and local governments and Indian perform that function in accordance tribes. with this subchapter. (3) The procedures for DOT to make administrative determinations of pre (b) Each person who offers a haz emption are set forth in subpart E of ardous material for transportation in part 397 of this title with respect to commerce must comply with all appli non-Federal requirements on highway cable requirements of this subchapter, routing (paragraph (f) (1) (iv) of this sec or an exemption or special permit, ap tion) and in subpart C of part 107 of proval, or registration issued under this chapter with respect to all other this subchapter or under subchapter A non-Federal requirements. of this chapter. There may be more (g) Penalties for noncompliance. Each than one offeror of a shipment of haz person who knowingly violates a re ardous materials. Each offeror is re quirement of the Federal hazardous sponsible for complying with the re material transportation law, an order quirements of this subchapter, or an issued under Federal hazardous mate exemption or special permit, approval, rial transportation law, subchapter A or registration issued under this sub of this chapter, or a special permit or chapter or subchapter A of this chap approval issued under subchapter A or ter, with respect to any pre-transpor C of this chapter is liable for a civil tation function that it performs or is penalty of not more than $55,000 and required to perform; however, each of not less than $250 for each violation, feror is responsible only for the specific except the maximum civil penalty is pre-transportation functions that it $110,000 if the violation results in performs or is required to perform, and death, serious illness or severe injury each offeror may rely on information to any person or substantial destruc provided by another offeror, unless tion of property, and a minimum $495 that offeror knows or, a reasonable per civil penalty applies to a violation re son, acting in the circumstances and lating to training. When a violation is exercising reasonable care, would have a continuing one and involves trans knowledge that the information pro porting of hazardous material or caus vided by the other offeror is incorrect. ing them to be transported, each day of (c) Each person who performs a func the violation is a separate offense. tion covered by or having an effect on Each person who knowingly violates a specification or activity prescribed in §171.20) or willfully or recklessly vio part 178, 179, or 180 of this subchapter, lates a provision of the Federal haz an approval issued under this sub ardous material transportation law, an chapter, or an exemption or special order issued under Federal hazardous permit issued under subchapter A of material transportation law, sub this chapter, must perform the func chapter A of this chapter, or a special tion in accordance with that specifica permit or approval issued under sub tion, approval, an exemption or special chapter A or C of this chapter, shall be permit, as appropriate. fined under title 18, United States (d) No person may offer or accept a Code, or imprisoned for not more than hazardous material for transportation 5 years, or both, except the maximum in commerce or transport a hazardous amount of imprisonment shall be 10 material in commerce unless that per years in any case in which a violation son is registered in conformance with 80 Pipeline and Hazardous Materials Safety Admin., DOT § 171.2 subpart C of part 107 of this chapter, if to be used for the transportation of a applicable. hazardous material. (e) No person may offer or accept a (h) The representations, markings, hazardous material for transportation and certifications subject to the prohi in commerce unless the hazardous ma bitions of paragraph (g) of this section terial is properly classed, described, include: packaged, marked, labeled, and in con (1) Specification identifications that dition for shipment as required or au include the letters “ICC”, “DOT”, thorized by applicable requirements of “CTC”, “MC”, or “UN”; this subchapter or an exemption or spe (2) Exemption, special permit, ap cial permit, approval, or registration proval, and registration numbers that issued under this subchapter or sub include the letters “DOT”, “EX”, “M”, chapter A of this chapter. or “R”; and (f) No person may transport a haz (3) Test dates associated with speci ardous material in commerce unless fication, registration, approval, retest, the hazardous material is transported exemption, or special permit markings indicating in accordance with applicable require compliance with a test or retest requirement ments of this subchapter, or an exemp of the HMR, or an exemption, special permit, approval, or tion or special permit, approval, or reg registration issued under the HMR istration issued under this subchapter or under subchapter A of this chapter. or subchapter A of this chapter. Each (i) No person may certify that a haz carrier who transports a hazardous ma ardous material is offered for transpor terial in commerce may rely on infor tation in commerce in accordance with mation provided by the offeror of the the requirements of this subchapter hazardous material or a prior carrier, unless the hazardous material is prop unless the carrier knows or, reason a erly classed, described, packaged, able person, acting in the cir marked, labeled, and in condition for cumstances and exercising reasonable shipment as required or authorized by care, would have knowledge that the applicable requirements of this sub information provided by the offeror or chapter or an exemption or special per carrier is prior incorrect. mit, approval, or registration issued (g) No person may represent, mark, under this subchapter or subchapter A certify, sell, or offer a packaging or of this chapter. Each person who offers container as meeting the requirements a package containing a hazardous ma of this subchapter governing its use in terial for transportation in commerce the transportation of a hazardous ma in accordance with the requirements of terial in commerce unless the pack this subchapter or an exemption or spe aging or container is manufactured, cial permit, approval, or registration fabricated, marked, maintained, recon issued under this subchapter or sub ditioned, repaired, and retested in ac chapter A of this chapter, must assure cordance with the applicable require that the package remains in condition ments of this subchapter. No person for shipment until it is in the posses may represent, mark, certify, sell, or sion of the carrier. offer a packaging or container as meet (j) No person may, by marking or ing the requirements of an exemption, otherwise, represent that a container a special permit, approval, or registra or package for transportation of a haz tion issued under this subchapter or ardous material is safe, certified, or in subchapter A of this chapter unless the compliance with the requirements of packaging or container is manufac this chapter unless it meets the re tured, fabricated, marked, maintained, quirements of all applicable regula reconditioned, repaired, and retested in tions issued under Federal hazardous accordance with the applicable require material transportation law. ments of the exemption, special per (k) No person may, by marking or mit, approval, or registration issued otherwise, represent that a hazardous under this subchapter or subchapter A material is present in a package, con of this chapter. The requirements of tainer, motor vehicle, rail car, aircraft, this paragraph apply whether or not or vessel if the hazardous material is the packaging or container is used or not present. 81 § 171.3 49 CFR Ch. 1(10—1—10 Edition)
(1) No person may alter, remove, de (3) Delivers, as designated on the face, destroy, or otherwise unlawfully manifest by the generator, the entire tamper with any marking, label, quantity of the waste received from the placard, or description on a document generator or a transporter to: required by Federal hazardous material (1) The designated facility or, if not transportation law or the regulations possible, to the designated alternate fa issued under Federal hazardous mate cility; rial transportation law. No person may (ii) The designated subsequent alter, deface, destroy, or otherwise un car rier; lawfully tamper with a package, con or tainer, motor vehicle, rail car, aircraft, (Hi) A designated place outside the or vessel used for the transportation of United States. hazardous materials. NOTE: Federal law specifies penalties up to Cm) No person may falsify or alter an $250,000 fine for an individual and $500,000 for exemption or special permit, approval, a company and 5 years imprisonment for the registration, or other grant of author willful discharge of hazardous waste at other ity issued under this subchapter or sub than designated facilities. 49 U.S.C. 5124. chapter A of this chapter. No person If may offer a hazardous material for (c) a discharge of hazardous waste transportation or transport a haz or other hazardous material occurs ardous material in commerce under an during transportation, and an official exemption or special permit, approval, of a State or local government or a registration or other grant of author Federal agency, acting within the ity issued under this subchapter or sub scope of his official responsibilities, de chapter A of this chapter if such grant termines that immediate removal of of authority has been altered without the waste is necessary to prevent fur the consent of the issuing authority. ther consequence, that official may au No person may represent, mark, cer thorize the removal of the waste with tify, or sell a packaging or container out the preparation of a manifest. under an exemption or special permit, [NOTE: In such cases, EPA does not re approval, registration or other grant of quire carriers to have EPA identifica authority issued under this subchapter tion numbers.] or subchapter A of this chapter if such NOTE I: EPA requires shippers grant of authority has been altered (generators) and carriers (transporters) of hazardous without the consent of the issuing au wastes to have identification numbers which thority. must be displayed on hazardous waste mani [68 FR 61937, Oct. 30, 2003, as amended at 70 fests. See 40 CFR parts 262 and 263. (Identi FR 43643. July 28, 2005; 70 FR 73162, Dec. 9, fication number application forms may be 2005] obtained from EPA regional offices.) NOTE 2: In 40 CFR part 263, the EPA sets § 171.3 Hazardous waste. forth requirements for the cleanup of re (a) No person may offer for transpor leases of hazardous wastes. tation or transport a hazardous waste jAmdt. 171—53, 45 FR 34586, May 22, 1980, as (as defined in § 171.8 of this subchapter) amended by Amdt. 171-53. 45 FR 74648, Nov. in interstate or intrastate commerce 10. 1980: Amdt. l7l-78, 49 FR 10510, Mar. 20, except in accordance with the require 1984; Amdt. 171—107, 54 FR 40068, Sept. 29, 1989; ments of this subchapter. Amdt. 171—111. 55 FR 52466, Dec. 21, 1990; 56 (b) No person may accept for trans FR 66157, Dec. 20, 1991; Amdt. 171—2, 59 FR 49132, Sept. 26, Amdt. 171—141, 61 FR portation, transport, or deliver a haz 1994; 21102. May 9, 1996: 73 FR 57004. Oct. 1, 20081 ardous waste for which a manifest is required unless that person: § 171.4 Marine pollutants. (1) Has marked each motor vehicle used to transport hazardous waste in (a) Except as provided in paragraph accordance with §390.21 of this title (c) of this section, no person may offer even though placards may not be re for transportation or transport a ma quired; rine pollutant, as defined in § 171.8, in (2) Complies with the requirements intrastate or interstate commerce ex for manifests set forth in § 172.205 of cept in accordance with the require this subchapter; and ments of this subchapter. 82 Pipeline and Hazardous Materials Safety Admin., DOT § 171.6 (b) The requirements of this sub perwork Reduction Act of 1995. This chapter for the transportation of ma section complies with the requirements rine pollutants are based on the provi of 5 CFR 1320.7(f), 1320.12, 1320.13 and sions of Annex III of the 1973 Inter 1320.14 (0MB regulations implementing national Convention for Prevention of the Paperwork Reduction Act of 1995) Pollution from Ships, as modified by for the display of control numbers as the Protocol of 1978 (MARPOL 73/78). signed by 0MB to collections of infor (c) Exceptions. Except when all or mation of the HMR. part of the transportation is by vessel, the requirements of this subchapter (b) 0MB control numbers. The table in paragraph specific to marine pollutants do not (b)(2) of this section sets apply to non-bulk packagings trans forth the control numbers assigned to ported by motor vehicle, rail car or air collection of information in the HMR craft. by the Office of Management and Budg et (0MB) under the Paperwork Reduc lAmdt. 171—116, 57 FR 52934, Nov. 5, 1993, as tion Act of 1995. amended by Amdt. 107—39, 61 FR 51337, Oct. 1, 1996; 73 FR 4712, Jan. 28, 2008] (1) Column 1 lists the 0MB control number assigned to the HMR collec § 171.6 Control numbers under the Pa tions of information, Column 2 con perwork Reduction Act. tains the Report Title of the approved (a) Purpose and scope. This section collection of information. Column 3 collects and displays the control num lists the part(s) or section(s) in 49 CFR bers assigned to the HMR collections of identified or described in the collection information by the Office of Manage of information. ment and Budget (0MB) under the Pa- (2) Table.
Current 0MB Title Title 49 CFR part or Section where identified control No. and described
2137—0014 Cargo Tank Specification Requirements §5107.503, 107.504, 178.320, 178.337, 178.338, 178.345, 180.407, 180.409, 180.413, 180.417. 2137—0018 Inspection and Testing of Portable Tanks and §5173.24, 173.32, 178.3, 178.255, 178.273, Intermediate Bulk Containers. 178.274, 178.703. 178801, 180.352, 180.605. 2137—0022 Testing. Inspection, and Marking Requirements §5173.5b, 173.302s, 173.303, 173.304, for Cylinders. 173.309. 178.2, 178.3, 178.35, 178.44, 178.45, 178.46, 178.57, 178.59, 178.60, 178.61, 178.68, 180.205, 180.207, 180.209, 180.211, 180.213, 180.215, 180.217, Appen dix C to Part 180. 2137—0034 Hazardous Materials Shipping Papers and §5172.200, 172.201, 172.202, 172.203, Emerqency Response Information. 172.204, 172.505, 172.600, 172.602, 172.604, 172.606, 173.6, 173.7, 173.22, 173.56. 174.24, 174.26, 174.114, 175.30, 175.31, 175.33, 176.24, 176.27, 176.30, 176.36, 176.89, 177.817. 2137—0039 Hazardous Materials Incidents Reports §5 171.15, 171.16, 171.21. 2137—0051 Rulemaking and Special Permit Petitions §5105.30, 105.40, 106.95. 106.110, 107.105. 107.107, 107.109, 107.113, 107.1 17, 107.121. 107.123, 107.125, 107.205, 107.211. 107.215, 107.217, 107.219, 107.221, 107.223. 2137—0510 RAM Transportation Requirements Part 173, Subpart I, §5173.22, 173.411, 173.415, 173.416, 173.417, 173.457, 173.471, 173.472, 173.473, 173.476. 2137—0542 Flammable Cryogenic Liquids §5173.318, 177.816, 177.840. 180.405.
83 § 171.7 49 CFR Ch. I (10—1—10 Edition)
Current 0MB Title Title 49 CFR part or section where identified control No. and described
2137—0557 Approvals for Hazardous Materials §i107.402, 107.403, 107.405, 107.502, 107.503. 107.705, 107.713, 107.715, 107.717, 107.803, 107.805, 107.807, 110.30, 172.101, 172.102, Special Provisions 19, 26, 53, 55, 60, 105, 118, 121, 125, 129, 131, 133, 136, 845, B55, B61, B69, B77, B81, Nb, N72, 173.2a, 173.4, 173.7, 173.21, 173.22, 173.24. 173.31, 173.38, 173.51. 173.56, 173.58. 173.59, 173.124, 173.128, 173.159, 173.166, 173.171, 173.214. 173.222, 173.224, 173.225, 173.245, 173.301, 173.305, 173.306, 173.314, 173.315, 173.316, 173.318. 173.334, 173.340, 173.411, 173.433, 173.457, 173.471, 173.472, 173.476, 174.50, 174.63, 175.8, 175.85. 175.701, 175.703, 176.168, 176.340, 176.704, 178.3, 178.35, 178.47, 178.53, 178.273, 178.274, 178.503, 178.509, 178.605, 178.606, 178.608, 178.801, 178.813, 180.213. 2137—0559 (Rail Carriers and Tank Car Tank Require § 172.102, Special provisions: B45, 846, 655, ments) Requirements for Rail Tank Car B61, B69, B77, B78, 881; 173.10, 173.31, Tanks—Transportation of Hazardous Mate 174.20, 174.50, 174.63, 174.104, 174.114, rials by Rail.. 174.204, 179.3, 179.4, 179.5, 179.6, 179.7, 179.11, 179.18, 179.22, 179.100—9, 179.100— 12, 179.100—13, 179.100—16, 179.100—17, 179.102-4, 179.102—17, 179.103—1, 179.103— 2, 179.103—3, 179.103—5, 179.200—10, 179.200—14, 179.200—15, 179.200—16, 179.200—17, 179.200—19, 179.201—3, 179.201—8, 179.201—9, 179.220—4, 179.220— 7, 179.220—8, 179.220—13. 179.220—15, 179.220—17, 179.220—18, 179.220—20, 179.220—22, 179.300—3, 179.300—7, 179.300— 9, 179.300—12, 179.300—13, 179.300—15, 179.300—20, 179.400—3, 179.400—4, 179.400— 11, 179.400-13, 179.400-16, 179.400—17, 179.400—19, 179.400—20, 179.500—5, 179.500—8, 179.500—12, 179.500—18, 180.505, 180.509, 180.515, 180.517. 2137—0572 Testing requirements for non-bulk packages §i173.168, 178.2. 178.601, Appendis C to Part 178, Appendix D to Part 178. 2137—0582 Container Certification Statement § 176.27, 176.172. 2137—0586 Hazardous Materials Public Sector Training and Part 110. Planning Grants. 2137—0591 Response Plans for Shipments of Oil Part 130. 2137—0595 Cargo Tank Motor Vehicles in Liquefied Com §173.315, 178.337—8, 178.337—9, 180.405, pressed Gas Service. 180.416. 2137—0612 Hazardous Materials Security Plans Part 172, Subpart I, §172.800, 172.802, 172.804. 2137—0613 Subsidiary Hazard Class and Number/Type of § 172.202, 172.203 Packagings. 2137—0620 Inspection and Testing of Meter Provers Part 173, Subpart A, §173.5a. 2137—0621 Requirements for United Nations (UN) Cylinders §173.301, 173.304, 173.304b, 178.69, 178.70, 178.74, 178.75. 180.207, 180.209, 180.212, 180.215, 180.217.
[Amdt. 171—111, 56 FR 661571 EDtTORtAL NOTE: For FEDERAL REGISTER citations affecting § 171.6, see the List of CFR Sec tions Affected which appears in the Finding Aids section of the printed volume and on GPO Access.
§ 171.7 Reference material. specifically set forth. This matter is (a) Matter incorporated by reference— hereby made a part of the regulations in parts 170—189 of this subchapter. (1) General. There is incorporated, by The matter subject change reference in parts 170—189 of this sub to is incor porated only it in chapter, matter referred to that is not as is effect on the
84 Pipeline and Hazardous Materials Safety Admin., DOT § 171.7 date of issuance of the regulation refer call 1—800—467—4922, or go to: http:// ring to that matter. The material list www.phmsa. dot.gov and ed in paragraph (a)(3) has been ap (ii) The National Archives and proved for incorporation by reference Records Administration (NARA). For by the Director of the Federal Register information on the availability of this in accordance with 5 U.s.c 552(a) and 1 material at NARA, call 202—741—6030, or CFR part 51. Material is incorporated go to: http:Uwww.archives.gov/ as it exists on the date of the approval federal register/ and a notice of any change in the mate codeof federal_regulations! rial will be published in the FEDERAL ibrlocations.html. REGISTER. Matters referenced by foot (3) Table of material incorporated by note are included as part of the regula reference. The following table sets forth tions of this subchapter. material incorporated by reference. (2) Accessibility of materials. All incor The first column lists the name and ad porated matter is available for inspec dress of the organization from which tion at: the material is available and the name (i) The Office of Hazardous Materials of the material. The second column Safety, Office of Hazardous Materials lists the section(s) of this subchapter, Standards, East Building, PHH-lO, 1200 other than §171.7, in which the matter New Jersey Avenue, SE., Washington, is referenced. The second column is DC 20590-0001. For information on the presented for information only and availability of this material at PHH-lO, may not be all inclusive.
Source and name of material 49 CFR reference
Air Transport Association of America. 1301 Pennsylvania Avenue, NW., Washington, DC 20004—1707: ATA Specification No. 300 Packaging of Airline Supplies, Revision 19, July 31, 1996 172.102. The Aluminum Association. 420 Lexington Avenue, New York, NY 10017. telephone 301—645—0756, http://www.aluminum.org: Aluminum Standards and Data, Seventh Edition, June 1982 172.102; 178.65. Welding Aluminum: Theory and Practice, 2002 Fourth Edition 178.68 American National Standards Institute, Inc., 25 West 43rd Street, New York, NY 10036: ANSI/ASHRAE 15—94, Safety Code for Mechanical Refrigeration 173.306; 173.307. ANSI B16.5—77, Steel Pipe Flanges, Flanged Fittings 178.360-4. ANSI N14.1 Uranium Hexafluoride—Packaging for Transport, 1971, 1982. 1987, 1990, 1995 and 173.417; 173.420. 2001 Editions. American Petroleum Institute, 1220 L Street, NW. Washington, D.C. 20005—4070: API Recommended Practice Closures of Underground Petroleum Storage Tanks, 3rd Edition, 172.102. March 1996. American Pyrotechnics Association (APA), P.O. Box 30438, Bethesda, MD 20824, (301) 907—8181, www.americanpyro.com: APA Standard 87—1, Standard for Construction and Approval for Transportation of Fireworks, 173.56. Novelties, and Theatrical Pyrotechnics, December I, 2001 version. American Society of Mechanical Engineers, ASME International, 22 Law Drive, P.O. Box 2900, Fairfield, NJ 07017—2900, telephone 1—800—843—2763 or 1—973—882—1170, http://www.asme.org:
85 § 171.7 49 CFR Ch. 1(10—1—10 Edition)
Source and name of material 49 CFR reference
ASME Code’; ASME Code, Sections II (Parts A and B), V, VIII (Division I), and IX of 1998 Edi- 172.102; 173.5b; lion of American Society of Mechanical Engineers Boiler arid Pressure Vessel Code I 73.24b; 173.32; 173.306; 173.315; 173.318; 173.420; 178.245—1; 178.245-3; 178.245—4; 178.245-6; 178.245-7; 178.255-1; 178.265—2; 178.255—14; 178.255-15; 178.270—2; 178.270—3; 178.270—7; 178.270—9; 178.270—11; 178.270—12; 178.271—1; 178.272—1; 178.273; 178.274; 178.276; 178.277; 178.320; 178.337— 1; 178.337—2; 178.337—3; 178.337-4; 178.337—6; 178.337—16; 178.337—18; 178.338—1; 178.338—2; 178.338—3; 178.338-4; 178.338—5; 178.338—6; 178.338-13; 178.338—16; 178.338-18; 178.338—19; 178.345-1; 178.345-2; 178.345-3; 178.345—4; 178.345-7; 178.345—14; 178.345-15; 178.348-1; 178.347—1; 178.348-1; 179.400—3; 180.407. Pipeline Transportation Systems for Liquid Hydrocarbons and other Liquids, Chapters II, Ill, IV, 173.5a. V and VI, ASME B31.4—1998 Edition. American Society for Testing and Materials, 100 Barr Harbor Drive, West Conshohocken, PA 1942, tele phone (610) 832—9585, http://www.astm.org: Noncurrent ASTM Standards are available from: Engineering Societies Library, 364 East 47th Street, New York, NY 10017 ASTM A 20/A 20M—93a Standard Specification for General Requirements for Steel Plates for 178.337—2; Pressure Vessels 179.102-4; 179.102—1; 179.102—17. ASTM A 47—68 Malleable Iron Castings 179.200—15. ASTM A 53, ASTM A 53/A 53M—06a Standard Specification for Pipe, Steel, Black and Hot- 173.5b. Dipped, Zinc-Coated, Welded and Seamless. ASTM A 106, ASTM A 106/A 106M—06a Standard Specification for Seamless Carbon Steel Pipe 173.5b. for High-Temperature Service.
86 Pipeline and Hazardous Materials Safety Admin., DOT §171 J
Source and name of material 49 CFR reference
ASTM A 240/A 240M—99b Standard Specification for Heal-Resisting Chromium and Chromium- 178.57; 178,358—5; Nickel Stainless Steel Plate, Sheet and Strip for Pressure Vessels 179.100—7; 179.100—10; 179.102—1; 179.102—4; 179.102—17; 179.200—7; 179.201—5; 179.220—7; 179.300—7; 179.400—5. ASTM A 242—81 Standard Specification for High-Strength Low-Alloy Structural Steel 178.338—2. ASTM A 262—93a Standard Practices for Detecting Susceptibility to lntergrsnular Attack in Aus- 179.100—7; tenitic Stainless Steels 179.200—7; 179.201—4. ASTM A 285—78 Pressure Vessel Plates, Carbon Steel, Low- and Intermediate-Tensile Strength 179.300—7. ASTM A 300—58 Steel Plates for Pressure Vessels for Service at Low Temperstures 178.337—2. ASTM A 302/A 302M—93 Standard Specification for Pressure Vessel Plates, Alloy Steel, Man- 179.100—7; ganese-Molybdenum and Manganese-Molybdenum Nickel 179.200-7; 179.220—7. ASTM A 333—67 Seamless and Welded Steel Pipe for Low-Temperature Service 178.45. ASTM A 370—94 Standard Test 179.102—1; 179.102—4; Methods and Definitions for Mechanical 179.102—17. Testing of Steel Products. ASTM A 441—81 Standard Specification for High-Strength Low-Alloy Structural Manganese Va- 178.338—2. nadium Steel. ASTM A 514—81 Standard Specification for High-Yield Strength Quenched and Tempered Alloy 178.338—2. Steel Plate, Suitable for Welding. ASTM A 515/A 515M—03 Standard Specification for Pressure Vessel Plates, Carbon Steel, for 179.300—7. Intermediate- and Higher-Temperature Service. ASTM A 516/A 516M—90 Standard Specification for Pressure Vessel Plates, Carbon Steel, for 178.337—2; Moderate and Lower-Temperature Service 179.100—7; 179.102—1; 179.102—2; 179.102-4; 179.102—17; 179.200—7; 179.220—7; 179.300—7. ASTM A 537/A 537M—91 Standard Specification for Pressure Vessel Plates, Heat-Treated, Car- 179.100—7; ban-Manganese-Silicon Steel 179.102—4; 179.102—17. ASTM A 572—82 Standard Specification for High-Strength Low-Alloy Columbian-Vanadium 178.338—2. Steels of Structural Quality. ASTM A 588—81 Standard Specification for High-Strength Low-Alloy Structural Steel with 50 Ksi 178.338—2. Minimum Yield Point to 4 in. Thick. ASTM A 606—75 Standard Specification for Steel Sheet and Strip Hot- Rolled and Cold-Rolled, 178.338—2. High-Strength, Low-Alloy, with Improved Atmospheric Corrosion Resistance, 1975 (Re- approved 1981). ASTM A 607—98 Standard Specification for Steel, Sheet and Strip, High-Strength, Low-Alloy, 178.338—2. Columbium or Vanadium, or Both, Hot-Rolled and Cold-Rolled. ASTM A 612—72a High Strength Steel Plates for Pressure Vessels for Moderate and Lower 178.337—2. Temperature Service. ASTM A 633—79a Standard Specification for Normalized High-Strength Low-Alloy Structural 178.338—2. Steel, 1979 Edition. ASTM A 715—81 Standard Specification for Steel Sheet and Strip, Hot-Rolled, High-Strength, 178.338—2. Low-Alloy with Improved Formability, 1981. ASTM A 1008/A 1008M—03 Standard Specification for Steel, Sheet, Cold-Rolled, Carbon, 178.338—2; Structural, High-Strength Low-Alloy and High Strength Low-Alloy with Improved Formability 178.345-2 ASTM A 1011/A 1OI1M—03a Standard Specification for Steel, Sheet and Strip, Hot-Rolled, Car- 178.338—2; ban, Structural, High-Strength Low Alloy and High Strength Low-Alloy with Improved 178.345—2 Formability. ASTM B 162—93a Standard Specification for Nickel Plate, Sheet, and Strip 173.249; 179.200—7. ASTM B 209—93 Standard Specification for Aluminum and Aluminum-Alloy Sheet and Plate 179.100—7; 179.200-7; 179.220—7. ASTM B 221—76 Aluminum Alloy Extruded Bars, Rods, Shapes, and Tubes 178.46. ASTM B 557—84 Tension Testing Wrought and Cast Aluminum and Magnesium-Alloy Products 178.46. ASTM B 580—79 Standard Specification for Anodic Oxide Coatings on Aluminum, (Re-approved 173.316; 173.318; 2000) 178.338—17. ASTM D 1238—9Db Standard Test Method for Flow Rates of Thermoplastics for Extrusion Plas- 173.225. tometer. ASTM D 1709—01 Standard Text Methods for Impact Resistance of Plastic Film by the Free-Fall- 173.197. ing Dart Method. ASTM D 1835—97 Standard Specification for Liquefied Petroleum (LP) Gases 180.209.
87 § 171.7 49 CFR Ch. I (10—1—10 Edition)
Source and name of material 49 CFR reference
ASTM D 1838—64 Copper Strip Corrosion by Liquefied Petroleum (LP) Gases 173.315. ASTM D 1922—00a Standard Test Method for Propogation Tear Resistance of Plastic Film and 173.197. Thin Sheeting by Pendulum Method. ASTM D 4206—96 Standard Test Method for Sustained Burning of Liquid Mixtures Using the 173.120. Small Scale Open-Cup Apparatus. ASTM D 4359—90 Standard Test Method for Determining Whether a Material is a Liquid or a 171.8. Solid. ASTM E 8—99 Standard Test Methods for Tension Testing of Metallic Materials 178.36; 178.37; 178.38; 178.39; 178.44; 178.45; 178.50; 178.51; 178.53; 178.55; 178.56; 178.57; 178.58; 178.59; 178.60; 178.61; 178.68. ASTM E 23—98 Standard Test Methods for Notched Bar Impact Testing of Metallic Materials 178.57. ASTM E 112—88 Standard Test Methods for Determining Average Grain Size 178.44. ASTM E 112—96 Standard Test Methods for Determining Average Grain Size, 1996 Edition 178.274; Part 178, appendix A. ASTM E 114—95 Standard Practice for Ultrasonic Pulse-Echo Straight-Beam Examination by the 178.45. Contact Method. ASTM E 213—98 Standard Practice for Ultrasonic Examination of Metal Pipe and Tubing 178.45. American Water Works Association, 1010 Vermont Avenue, N.W., Suite 810, Washington, DC 20005: AWWA Standard C207—55, Steel Pipe Flanges, 1955 178.360—4. American Welding Society, 550 N.W. Le Jeune Road, Miami, Florida 33126: AWS Code B 3.0; Standard Qualification Procedure; 1972 (FRB 3.0—41, rev. May 1973) 178.356—2, 178.358—2. AWS Code D 1.0; Code for Welding in Building Construction (FR D 1.0-66, 1966) 178.356—2; 178.358—2. Association of American Railroads, American Railroads Building, 50 F Street, NW., Washington, DC 20001; telephone (877) 999—8824, http://www.aar.org/publications.com;
88 Pipeline and Hazardous Materials Safety Admin., DOT § 171.7
Source and name of material 49 CFR reference
5AR Manual of Standards and Recommended Practices, Section C—Part Ill, Specifications for 17331: 17463; Tank Cars, Specification M—1002, (AAR Specifications for Tank Cars>, December 2000 179.6: 179.7: 179.15; 179.16; 179.20; 179.22; 179.100—9; 179.100—10: 179.100—12; 179.100—13; 179.100—14; 179.100—18; 179.101—1; 179.102—I; 179.102—4; 179.102—17: 179.103—5: 179.200—7; 179.200—9; 179.200-10; 179.200—11; 179.200-13: 179.200-17: 179.200—22; 179.201—6; 179.220—6; 179.220-7; 179.220—10; 179.220—11; 179.220—14; 179.220—18; 179.220—26; 179.300-9: 179.300-10; 179.300-15: 179.300—17: 179.400—5; 179.400—6; 179.400-8; 179.400—11; 179.400-12: 179.400-15; 179.400—18; 179.400—20; 179.400—25; 180.509: 180.513; 180.515; 180.517. AAR Manual of Standards and Recommended Practices, Section I, Specially Equipped Freight 174.55; 174.63. Car and lntermodal Equipment, 1988. AAR Specifications for Design, Fabrication and Construction of Freight Cars, Volume 1, 1988 179.16. Chlorine Insfifufe, Inc., 1300 Wilson Boulevard, Arlington, VA 22209 AAR Standard 286; AAR Manual of Standards and Recommended Practices, Section C, Car 179.13 Construction Fundamentals and Details, Standard S—286, FreelUnrestricted Interchange for 286,000 lb Gross Rail Load Cars (Adopted 2002; Revised: 2003, 2005, 2006). Chlorine Institute Emergency Kit “A” for 100-lb. & 150 lb. Chlorine Cylinders (with the esception 173.3 of repair method using Device 8 for side leaks), Edition 10, June 2003. Chlorine Institute Emergency Kit “B” for Chlorine Ton Containers (with the exception of repair 173.3 method using Device 9 for side leaks), Edition 9, June 2003. Type 1½ JQ 225, Dwg., H51970, Revision F, November 1996; or Type 1½ JQ 225, Dwg 173.315. 1-150155, Revision 1-I, November 1996. Section 3, Pamphlet 57, Emergency Shut-Off Systems for Bulk Transfer of Chlorine, Edition 4, 177.840. October 2003. Section 3, Pamphlet 166, Angle Valve Guidelines for Chlorine Bulk Transportation, 1st Edition, 178.337—9. October 2002. Standard Chlorine Angle Valve Assembly, Dwg. 104—8, July 1993 178.337—9. Excess Flow Valve with Removable Seat, 0mg. 101—7, July 1993 178.337—8. Excess Flow Valve with Removable Basket, Dwg. 106—6, July 1993 178.337—8. Standards for Housing and Manway Covers for Steel Cargo Tanks, Dwgs. 137—1 and 137—2, 178.337—10. September 1, 1982. Typical Manway Arrangement Chlorine Cargo Tank, Dwg 137—5. November 1996 178.337—10. Canadian General Standards Board, Place du Portage Ill, 6B1 11 171.12 Laurier Street, Gatineau, Quebec, Canada K1A 1G6 National Standard of Canada (CAN/CGSB 43.147—2005) Construction, Modification, Qualifica tion, Maintenance, and Selection and Use of Means of Containment for the Handling, Offering for Transport, or Transportation of Dangerous Goods by Rail.
89 § 171.7 49 CFR Ch. 1(10—1—10 Edition)
Source and name of material 49 CFR reference
CGA Pamphlet C—3, Standards for Welding on Thin-Walled Steel Cylinders, 1994 178.47; 178.50; 178.51; 178.83; 178,55; 178.56; 178.57; 178.58; 178.59; 178.60; 178.61; 178.65; 178.68; 180.211. CGA C—5, Cylinder Service Life—Seamless Steel High Pressure Cylinders, 1991 (reaffirmed 173.302a. 1995). CGA Pamphlet C—6, Standards for Visual Inspection of Steel Compressed Gas Cylinders, 1993 173.3, 173.198, 180.205, 180.209, 180.211, 180.411, 180.519. CGA Pamphlet C—El, Standards for Visual Inspection of High Pressure Aluminum Compressed 180.205; 180.209 Gas Cylinders, 2002, Fourth Edition. CGA Pamphlet C—6.2, Guidelines for Visual Inspection and Requalification of Fiber Reinforced 180.205. High Pressure Cylinders, 1996, Third Edition. CGA Pamphlet C—6.3, Guidelines for Visual Inspection and Requalitication of Lom Pressure Alu- 180,205; 180.209. minum Compressed Gas Cylinders, 1991. CGA C—7, Guide to Preparation of Precautionary Labeling and Marking of Compressed Gas 172.400a. Containers, Appendix A, issued 2004 (8th Edition). CGA Pamphlet C—8, Standard for Requalification of DOT-3HT Cylinder Design, 1985 180.205; 180.209. CGA Pamphlet C—il, Recommended Practices for Inspection of Compressed Gas Cylinders at 178.35. Time of Manufacture, 2001, Third Edition. CGA Pamphlet C—12, Qualification Procedure for Acetylene Cylinder Design, 1994 173.301; 173.303; 178.59; 178.60. CGA Pamphlet C—13, Guidelines for Periodic Visual Inspection and Requalification of Acetylene 173.303; 180.205; Cylinders, 2000, Fourth Edition. 180.209. CGA Pamphlet C—14, Procedures for Fire Testing of DOT Cylinder Pressure Relief Device Sys- 173.301; 173.323. tems, 1979. CGA Pamphlet G—2.2, Guideline Method for Determining Minimum of 0.2% Water in Anhydrous 173.315. Ammonia, 1985, Second Edition, Reaffirmed 1997. CGA Pamphlet G—4.1, Cleaning Equipment for Oxygen Service, 1985 178.338—15. CGA Pamphlet P—20, Standard for the Classification of Toxic Gas Mixtures, 2003, Third Edition 173.115. CGA Pamphlet P—20, Standard for the Classification of Toxic Gas Mixtures, 1995 173.115. CGA S—il, Pressure Relief Device Standards—Part i—Cylinders for Compressed Gases, 2005 173.301, 173.304a (mith the exception of paragraph 9.1.1.1), Twelfth Edition 178.75. CGA Pamphlet S—i.2, Safety Relief Device Standards Part 2—Cargo and Portable Tanks for 173.315; 173.318; Compressed Gases, 1980 178.276; 178.277. CGA S—7, Method for Selecting Pressure Relief Devices for Compressed Gas Mixtures in Cyl- 173.301. inders, 2005. CGA Technical Bulletin TB—2, Guidelines for Inspection and Repair of MC—330 and MC—331 180.407; 180.413. Cargo Tanks, 1980. CGA Technical Bulletin TB—25, Design Considerations for Tube Trailers, 2008 Edition 173.301. Department of Defense (DOD), 2461 Eisenhower Avenue, Alexandria, VA 22331: DOD TB 700—2; NAVSEAINST 8020.88; AFTO 1IA—i—47; DLAR 8220.1: Explosives Hazard 173.56. Classification Procedures, January 1998. Packaging of Hazardous Material, DLAD 4145.41/ AR 700—143/AFJI 24—210/NAVSUPINST 173.7 4030.55B/MCO 4030.40B, January 14, 2000. Department of Energy (USDDE), 100 Independence Avenue SW., Washington, DC 20545: USDOE publications available from: Superintendent of Documents, Government Printing Office (GPO) or The National Technical Information Service (NTIS). USDOE, CAPE—1662, Revision 1, and Supplement 1, Civilian Application Program Engineering 178.356—1; Drawings, April 6, 1988 178.356-2; 178.358—i; 178.358—2; 178.358—3; 178.358—4. USDOE, Material and Equipment Specification No. SP—9, Rev. 1, and Supplement—Fire Resist- 178.356—2; ant Phenolic Foam, March 28, 1968 178.358—2. USDOE, KSS—471, November 30, 1986—Proposal for Modifications to U.S. Department of 178.356-i; Transportation Specification 21PF—1, Fire and Shock Resistant Phenolic Foam—Insulated 178.358—3. Metal Overpack. General Services Administration, Specification Office, Room 6662, 7th and D Street, SW., Washington, DC 20407: Federal Specification RR-C—901D, Cylinders, Compressed Gas: Seamless Shatterproof, High 173.302; 173.336; Pressure DOT 3AA Steel, and 3AL Aluminum, February 21, 2003 (Superseding RR-C—901C, 173.337. 1981). Institute of Makers of Explosives, 1120 19th Street NW., Suite 310, Washington, DC 20036—3605: IME Safety Library Publication No. 22 (IME Standard 22), Recommendation for the Safe Trans- 173.63; 177.835. portation of Detonators in a Vehicle with Certain Other Explosive Materials, May 1993. International Atomic Energy Agency (IAEA), P.O. Box 100, Wagramer Strasse 5, A—1400 Vienna, Austria:
90 Pipeline and Hazardous Materials Safety Admin., DOT § 171.7
Source and name of material 49 CFR reference
Also available from: Bernan Associates, 4611—F Assembly Drive, Lanham, MD 20706—4391, USA; or Renouf Publishing Company, Ltd., 812 Proctor Avenue, Ogdensburg, New York 13669, USA. IAEA, Regulations for the Safe Transport of Radioactive Material, (IAEA Regulations), 1996 Edi- 171.22: 171.23: tion (Revised), No. TS-R-1 (ST-I, Revised) 171.26, 173.415, 173.416, 173.417, 173.473 International Civil Aviation Organization (“ICAO”), 999 University Street, Montréal, Quebec H3C 5H7, Canada, 1—514—954—8219, htfp:I/www.icao.int: ICAO Technical Instructions available from: INTEREG, International Regulations, Publishing and Distribution Organization. P.O. Bos 60105, Chicago, IL 60660. Technical Instructions for the Safe Transport of Dangerous Goods by Air )“ICAO Technical Instructions”), 171.8; 171.22; 2009—2010 Edition 171.23; 171.24; 172.202; 172.401: 172.512: 172.602: 173.56; 173.320: 175.33; 178.3. International Electrotechnical Commission (IEC) 3, rue de Varembé, P.O. Bos 131, CH—1211, GENEVA 20, Switzerland: Fuel cell technologies—Part 6—1: Micro fuel cell power systems—Safety, IEC/PAS 62282—6— § 175.10. 1:2006(E), First Edition 2006—02, with Corrigendum 1, First Edition 2007—04. International Maritime Organization (“lMO’), 4 Albert Embankment, London, 561 7SR, United Kingdom or New York Nautical Instrument & Service Corporation, 140 West Broadway, New York, NY 10013, +44 (0) 20 7735 7611, http://www.imo.org: International Convention for the Safety of Life at Sea, (“SOLAS”) 176.63, 176.84. Amendments 2002, Chapter ll—2lRegulation 19, Consolidated Edition 2004.. International Maritime Dangerous Goods Code (“IMDG Code”), 2008 Edition, Incorporating Amendment 171.22; 17123; 34—08 (English Edition), Volumes 1 and 2 171.25; 172.101 Appendix B: 172.202: 172.401: 172.502; 172.602: 173.21: 173.56: 176.2; 176.5: 176.11: 176.27: 176.30: 176.84; 178.3: 178.274. International Organization for Standardization, Case Postale 56, CH—121 I, Geneve 20, Switzerland, http://www.iso.org: Also available from: ANSI 25, West 43rd Street, New York, NY 10036, 1—212—642—4900, htfp.1/ www.ansi.org. ISO 535—1991(E) Paper and board—Determination of water absorptiveness—Cobb method 178.516; 178.707: 178.708. ISO 1496—1: 1990 )E)—Series 1 freight containers—Specification and testing, Part 1: General 173.411 cargo containers. Fifth Edition, (August 15, 1990). ISO 1496—3—Series 1 freight containers—Specification and testing—Part 3: Tank containers for 178.74; 178.75; liquids, gases and pressurized dry bulk, Fourth edition, March 1995, )E) 178.274. ISO 2431—1984(E) Standard Cup Method 173.121. ISO 2592—1973(E) Petroleum products—Determination of 6 ash and fire points—Cleveland open 173.120. cup method. ISO 2919—1980(E) Sealed radioactive sources—Classification 173.469. ISO 3036—1975(E) Board—Determination of puncture resistance 178.708. ISO 3574—1986(E) Cold-reduced carbon steel sheet of commercial and drawing qualities 178.503; Part 178, appendix C. ISO 3807—2, Cylinders for acetylene—Basic requirements—Part 2: Cylinders with fusible plugs, 173.303: 178.71. First edition, March 2000, )E). ISO 4126—1 Safety valves—Part 1: General Requirements. December 15, 1991, First Edition 178.274. ISO 6406, Gas cylinders—Seamless steel gas cylinders—Periodic inspection and testing, Sec- 180.207. ond edition, February 2005, )E). ISO 6892 Metallic materials—Tensile testing, July 15, 1984, First Edition 178.274. ISO 7225, Gas cylinders—Precautionary labels, Second Edition, July 2005, )E) 178.71. ISO 7866, Gas cylinders—Refillable seamless aluminum alloy gas cylinders—Design, construc- 178.71. tion and testing. First edition, June 1999, (E). ISO 8115 Cotton bales—Dimensions and density, 1986 Edition 172.102. ISO 9809—1: Gas cylinders—Refillable seamless steel gas cylinders—Design, construction and 178.37; 178.71; testing—Part 1: Quenched and tempered steel cylinders with tensile strength less than 1 100 178.75. MPa., First edition, June 1999, (B). ISO 9809—2: Gas cylinders—Refillable seamless steel gas cylinders—Design, construction and 178.71; 178.75. testing—Part 2: Quenched and tempered steel cylinders with tensile strength greater than or equal to 1100 MPa., First edition, June 2000, (6). ISO 9809—3: Gas cylinders—Refillable seamless steel gas cylinders—Design, construction and 178.71; 178.75. testing—Part 3: Normalized steel cylinders, First edition, December 2000, (E). ISO 9978:1992(E)—Radiation protection—Sealed radioactive sources—Leakage test methods. 173.469. First Edition, (February 15, 1992).
91 § 171.7 49 CFR Ch. I (10—1—10 Edition)
Source and name of material 49 CFR reterence
ISO 10156:1996, Gases and Gas Mixtures—Determination of fire potential and oxidizing ability for the se- 173.115. lection of cylinder valve outlets, Second edition, February 1996 (8). ISO 10156—2:2005, Gas cylinders—Gases and gas mixtures—Part 2: Determination of oxidizing ability of 173.115. toxic and corrosive gases and gas mixtures, First edition, August 2005, (E). ISO 10297, Gas cylinders—Refillable gas cylinder valves—Specification and type testing, First 173.301b, 178.71. edition, May 1999, (E). ISO 10461, Gas cylinders—Seamless aluminum—alloy gas cylinders—Periodic inspection and 180.207. testing, Second edition, February 2005, (E). ISO 10462, Gas cylinders—Transportable cylinders for dissolved acetylene—Periodic inspection 180.207. and maintenance, Second edition, February 2005, (E). ISO 111 14—i, Transportable gas cylinders—Compatibility of cylinder and valve materials with 173.301b; 178.71. gas contents—Part 1: Metallic materials, First edition, October 1997, (E). ISO 11114—2, Transportable gas cylinders—Compatibility of cylinder and valve materials with 173.301b; 178.71. gas contents—Part 2: Non-metallic materials, First edition, December 2000, (E). ISO 11117, Gas cylinders—Valve protection caps and valve guards for industrial and medical 173.301b. gas cylinders—Design, construction and tests, First edition, August 1998, (6). ISO 11118, Gas cylinders—Non-refillable metallic gas cylinders—Specification and test methods, 178.71. First edition, October 1999, (E). ISO 11119—1, Gas cylinders—Gas cylinders of composite construction—Specification and test 178.71. methods—Part 1: Hoop-wrapped composite gas cylinders, First edition, May 2002, (E). ISO 11119—2, Gas cylinders—Gas cylinders of composite construction—Specification and test 178.71. methods—Part 2: Fully wrapped fibre reinforced composite gas cylinders with load-sharing metal liners, First edition, May 2002, (F). ISO 11119—3, Gas cylinders of composite construction—Specification and test methods—Part 3: 178.71. Fully wrapped fibre reinforced composite gas cylinders with non-load-sharing metallic or non metallic liners, First edition, September 2002, (E), ISO 11120, Gas cylinders—Refillable seamless steel tubes of water capacity between 150 L and 178.71; 178.75. 3000 L—Design, construction and testing, First edition, March 1999, (E).
ISO 11621, Gas cylinders—Procedures for change of gas service, First edition, April 1997, (E) .. 173.302, 173.336, 173.337. ISO 11623, Transportable gas cylinders—Periodic inspection and testing of composite gas cyl- 180.207. inders, First edition, March 2002, (E). National Board of Boiler and Pressure Vessel Inspectors, 1055 Crupper Avenue, Columbus, Ohio 43229: National Board Inspection Code, A Manual for Boiler and Pressure Vessel Inspectors, NB—23, 180.413. 1992 Edition. National Fire Protection Association, Batterymarch Park, Quincy, MA 02269: NFPA 58-Liquetied Petroleum Gas Code, 2001 Edition 173.315. National Institute of Standards and Technology, Department of Commerce, 5285 Port Royal Road, Springfield, VA 22151: USDC, NBS Handbook H—28 (1957), 1957 Handbook of Screw-Thread Standards for Federal 179.2; 178.45; Services, December 1966 Edition. 178.46. Organization for Economic Cooperation and Development (OECD), OECD Publications and Information Center, 2001 L Street, N.W., Suite 700, Washington, DC 20036: OECD Guideline for Testing of Chemicals, No. 404 “Acute Dermal Irritation/Corrosion,” 1992 173.137. Transport Canada, TDG Canadian Government Publishing Center, Supply and Services, Canada, Ot tawa, Ontario, Canada K1A 059, 416—973—1868, htIp://www.tc.gc.ca: Transportation of Dangerous Goods Regulations (Transport Canada TDG Regulations), August 171.12; 171.22; 2001 including Clear Language Amendments SOR 2001—286, Amendment 1 (SORI2002—306) 171.23; 172.401; August 8, 2002; Amendment 2 (SOR/2003—273) July 24, 2003; Amendment 3 (SORI2003— 172.502; 172.519; 400) December 3, 2003; Amendment 4 (SORI2005—216) July 13, 2005; AmendmentS (SORI 172.602; 173.31; 2005-279) September 21, 2005; and subsection 4.18(5) of Amendment 6 (SOR/2008—34) 173.32; 173.33. February 7, 2008. Truck Trailer Manufacturers Association, 1020 Princess Street, Alexandria, Virginia 22314: TTMA RP No. 61—98, Performance of manhole and/or Fill Opening Assemblies on MC 306, 180.405. DOT 406, Non-ASME MC 312 and Non-ASME DOT 412 Cargo Tanks, June 1, 1998. TTMA RP No. 81—97, Performance of Spring Loaded Pressure Relief Valves on MC 306, MC 178.3.45—10; 307, MC 312, DOT 406, DOT 407, and DOT 412 Tanks, July 1, 1997 Edition. 178.346—3. TTMA TB No. 107, Procedure for Testing In-Service Unmarked and/or Uncertified MC 306 and 180.405. Non-ASME MC 312 Type Cargo Tank Manhole Covers, June 1, 1998 Edition. United Nations, Publications, 2 United Nations Plaza, Room DC2—853, New York, NY 10017, 1—212— 963—8302, http://unp.un.org. UN Recommendations on the Transport of Dangerous Goods, Fifteenth revised edition (2007). Volumes I 171.8; 171.12; and II. 171.22; 171.23; 172.202; 172.401; 172.502; 173.22; 173.24; 173.24b; 173.40; 173.56; 173.192; 173.197; 173.302b; 173.304b; 175.75; 178.274; 178.801. 92 Pipeline and Hazardous Materials Safety Admin., DOT § 171.7
Source and name of material 49 CFR reference
UN Recommendations on the Transport of Dangerous Goods, Manual of Teats and Criteria, Fourth re- 172102; 173.21; vised edition, (2003), and Addendum 2, (2004). 173.56; 173.57; 173.58; 173.115; 173.124; 173.125; 173.127; 173.128; 173.137; 173.185; Part 173, appen dix H; 178.274. United States Enrichment Corporation, Inc. (USEC): USEC Inc., 6903 Rockledge Drive, Bethesda, MD 20817. USEC—651—Good Handling Practices for Uranium Haxafluoride, Revision 8, January 1999 173.417
(b) List of informational materials not by reference and are included for infor requiring incoiporation by reference. The mational purposes. These materials materials listed in this paragraph do may be used as noted in those sections not require approval for incorporation in which the material is referenced.
Source and name of material 49 CFR reference
American Biological Safety Association 1202 Allanson Road, Mundelein, IL 60060 Risk Group Classification for Infectious Agents, 1998 173.134 American Institute of Chemical Engineers (AIChE), 3 Park Avenue New York, NY 10016—5991 Process Safety Progress Journal, Vol. 21, No.2. Example of a Test Method for Venting Sizing: OPPSD/SPI Methodology Note to § 173. 225(h)(3)(vi). American Society for Testing and Materials, 100 Barr Harbor Drive, West Conshohocken, PA 19428: Noncurrent ASTM Standards are available from: Engineering Societies Library. 354 East 47th Street, New York, NY 10017 ASTM B 380—89 Standards for Metric Practice 171.10 Association of American Railroads, American Railroads Building, 50 F Street, NW., Washington, DC 20001 fAR Catalog Nos. SE6OCHT; SE6OCC; SE6OCHTE; SE6OCE; SE600C; SE6ODE 179.14 AAR Catalog Nos. SE67CC; SE67CE; SE67BHT; SE67BC; SE67BHTE; SE67BE 179.14 AAR Catalog Nos. SE68BHT; SE68BC; SE68BHTE; SE68BE 179.14 AAR Catalog Nos. SE69AHTE; SE69AE 179.14 AR Catalog Nos. SF7OCHT; SF7OCC; SF7OCHTE; SF7OCE 179.14 AAR Catalog Nos. SF73AC; SF73AE; SF73AHT; SF73AHTE 179.14 AAR Catalog Nos. SF79CHT; SF79CC; SF79CHTE; SF79CE 179.14 Bureau of Explosives, Hazardous Materials Systems (BDE), Association of American Railroads, American Railroads Build ing, 50 F Street, NW., Washington, DC 20001 Fetterley’s Formula (The Determination of the Relief Dimensions for Safety Valves on Containers in 173.315 which Liquefied gas is charged and when the exterior surface of the container is exposed to a tem perature of 1,200 CF.). Pamphlet 6, Illustrating Methods for Loading and Bracing Carload and Less-Than-Carload Shipments of 174.55; 174.101; Explosives and Other Dangerous Articles, 1962 174.112; 174.115; 174.290 Pamphlet 6A (includes appendix No. 1, October 1944 and appendix 2, December 1945), Illustrating Meth- 174.101; 174.290 ods for Loading and Bracing Carload and Less-Than-Carload Shipments of Loaded Projectiles, Loaded Bombs, etc., 1943. Pamphlet 6C, Illustrating Methods for Loading and Bracing Trailers and Less-Than-Trailer Shipments of 174.55; 174.63; Explosives and Other Dangerous Articles Via Trailer-on-Flatcar (TOFC) or Container-on-Flatcar 174.101; 174.112; (COFC), 1985 174.115 Emergency Handling of Hazardous Materials in Surface Transportation, 1989 171.7 Centers for Disease Control and Prevention 1600 Clifton Road, Atlanta, GA 30333 Biosafety in Microbiological and Biomedical Laboratories, Fourth Edition, April 1999 173.134 Compressed Gas Association, Inc., 4221 Walney Road, 5th Floor, Chantilly, Virginia 20151 CGA C—li, Personnel Training and Certification Guidelines for Cylinder Requalification By the Volu- 180.209 metric Expansion Method, 2004, First Edition. National Institutes of Health Bethesda, MD 20892 NIH Guidelines for Research Involving Recombinant DNA Molecules (NIH Guidelines), January 2001, Ap- 173.134 pendis B. Pantone Incorporated 590 Commerce Boulevard, Carlstadt, New Jersey 07072—3098 Pantonev Formula guide coated/uncoated, Second Edition 2004 172.407, 172.519
93 § 171.8 49 CFR Ch. 1(10—1—10 Edition)
Source and name of material 49 CFR reference
Society of Plastics Industries, Inc., Organic Peroxide Producers Safety Division, 1275 K Street, NW., Suite 400, Washington, DC 20005 Self Accelerating Decomposition Temperature Test, 1972 173.21 Truck Trailer Manufacturers Association, 1020 Princess Street, Alexandria, Virginia 22314, telephone (703) 549—3010, http://www.ttmanet.org: TTMA RP No. 96—01, TTMA EP No. 96—01, Structural Integrity of DOT 406, DOT 407, and DOT 412 Cy- 178.345—3 lindrical Cargo Tanks, January 2001 Edition.
[Amdt. 171—111, 55 FR 52466, Dec. 21, 1990; 71 FR 78611, Dec. 29, 2006; 75 FR 69, Jan. 4, 2010] EDtTORIAL NOTE: For FEDERAL REGISTER citations affecting §171.7, see the List of CFR Sec tions Affected which appears in the Finding Aids section of the printed volume and on GPO Access. EDITORIAL NOTE: At 68 FR 19273, Apr. 18, 2003, §171.7(a)(3) was amended by removing the entry for “TTMA TB No. 81” under “Truck Trailer Manufacturers Association”. The amend ment could not be incorporated because that entry does not exist.
§ 171.8 Definitions and abbreviations. Asphyxiant gas means a gas which di In this subchapter, lutes or replaces oxygen normally in the atmosphere. Administrator means the Adminis trator, Pipeline and Hazardous Mate Associate Administrator means the As rials Safety Administration. sociate Administrator for Hazardous Aerosol means any non-refillable re Materials Safety, Pipeline and Haz ceptacle containing a gas compressed, ardous Materials Safety Administra liquefied or dissolved under pressure, tion. the sole purpose of which is to expel a Atmospheric gases means air, nitro nonpoisonous (other than a Division 6.1 gen, oxygen, argon, krypton, neon and Packing Group III material) liquid, xenon. paste, or powder and fitted with a self- Authorized Inspection Agency means: closing release device allowing the con (1) A jurisdiction which has adopted tents to be ejected by the gas. and administers one or more sections Aggregate lithium content means the of the ASME Boiler and Pressure Ves sum of the grams of lithium content or sel Code as a legal requirement and has equivalent lithium content contained a representative serving as a member by the cells comprising a battery. of the ASME Conference Committee; or Agricultural product means a haz (2) an insurance company which has ardous material, other than a haz been licensed or registered by the ap ardous waste, whose end use directly propriate authority of a State of the supports the production of an agricul United States or a Province of’ Canada tural commodity including, but not to underwrite boiler and pressure ves limited to a fertilizer, pesticide, soil sel insurance in such State or Prov amendment or fuel. An agricultural ince. product is limited to a material in Authorized Inspector means an Inspec Class 3, 8 or 9, Division 2.1, 2.2, 5.1, or tor who is currently commissioned by 6.1, or an ORM-D material. the National Board of Boiler and Pres Approval means a written authoriza sure Vessel Inspectors and employed as tion, including a competent authority an Inspector by an Authorized Inspec approval. from the Associate Adminis tion Agency. trator or other designated Department Bag means a flexible packaging made official, to perform a function for of paper, plastic film, textiles, woven which prior authorization by the Asso material or other similar materials. ciate Administrator is required under Bar means 1 BAR = 100 kPa (14.5 psi). subchapter C of this chapter (49 CFR Barge means a non-selfpropelled ves parts 171 through 180.) sel. Approved means approval issued or Biological product. See § 173.134 of this recognized by the Department unless subchapter. otherwise specifically indicated in this Biological substances, Category B. See subchapter. §173.134 of this subchapter. 94 Pipeline and Hazardous Materials Safety Admin., DOT § 171.8
Bottle means an inner packaging hav for the transport of gases in Division ing a neck of relatively smaller cross 2.3 is limited to a water capacity of section than the body and an opening 1,000 L. capable of holding a closure for reten Bureau of Explosives means the Bu tion of the contents. reau of Explosives (B of F) of the Asso Bottom shell means that portion of a ciation of American Railroads. tank car tank surface, excluding the C means Celsius or Centigrade. head ends of the tank car tank, that Captain of the Port (COTP) means the lies within two feet, measured circum officer of the Coast Guard, under the ferentially, of the bottom longitudinal command of a District Commander, so center line of the tank car tank. designated by the Commandant for the Box means a packaging with com purpose of giving immediate direction plete rectangular or polygonal faces, to Coast Guard law enforcement activi made of metal, wood, plywood, recon ties within an assigned area. As used in stituted wood, fiberboard, plastic, or this subchapter, the term Captain of the other suitable material. Holes appro Port includes an authorized representa priate to the size and use of the pack tive of the Captain of the Port. aging, for purposes such as ease of han Carfloat means a vessel that operates dling or opening, or to meet classifica on a short run on an irregular basis and tion requirements, are permitted as serves one or more points in a port long as they do not compromise the in area as an extension of a rail line or tegrity of the packaging during trans highway over water, and does not oper portation, and are not otherwise pro ate in ocean, coastwise, or ferry hibited in this serv subchapter. ice. Break-bulk means packages of haz Cargo aircraft only ardous materials that are handled indi means an aircraft that is used to transport cargo vidually, palletized, or unitized for pur and is not engaged in carrying passengers. poses of transportation as opposed to For purposes bulk and containerized freight. of this subchapter, the terms cargo aircraft Btu means British thermal unit. only, cargo-only air craft and cargo aircraft have Bulk packaging means a packaging, the same meaning. other than a vessel or a barge, includ ing a transport vehicle or freight con Cargo tank means a bulk packaging tainer, in which hazardous materials that: are loaded with no intermediate form (1) Is a tank intended primarily for of containment. A Large Packaging in the carriage of liquids or gases and in which hazardous materials are loaded cludes appurtenances, reinforcements, with an intermediate form of contain fittings, and closures (for the definition ment, such as one or more articles or of a tank, see 49 CFR 178.320, 178.337—1, inner packagings, is also a bulk pack or 178.338—1, as applicable); aging. Additionally, a bulk packaging (2) Is permanently attached to or has: ** * forms a part of a motor vehicle, or is (1) A maximum capacity greater than not permanently attached to a motor 450 L (119 gallons) as a receptacle for a vehicle but which, by reason of its size, liquid; construction or attachment to a motor (2) A maximum net mass greater vehicle is loaded or unloaded without than 400 kg (882 pounds) and a max being removed from the motor vehicle; imum capacity greater than 450 L (119 and gallons) as a receptacle for a solid; or (3) Is not fabricated under a speci (3) A water capacity greater than 454 fication for cylinders, intermediate kg (1000 pounds) as a receptacle for a bulk containers, multi-unit tank car gas as defined in §173.115 of this sub tanks, portable tanks, or tank cars. chapter. Cargo tank motor vehicle means a Bundle of cylinders means assemblies motor vehicle with one or more cargo of UN cylinders fastened together and tanks permanently attached to or interconnected by a manifold and forming an integral part of the motor transported as a unit. The total water vehicle. capacity for the bundle may not exceed Cargo vessel means: (1) Any vessel 3,000 L, except that a bundle intended other than a passenger vessel; and 95 § 171.8 49 CFR Ch. I (10—1--la Edition)
(2) Any ferry being operated under law for the control or regulation of a authority of a change of character cer particular aspect of the transportation tificate issued by a Coast Guard Offi of hazardous materials (dangerous cer-in-Charge, Marine Inspection. goods). The term Appropriate Authority, Carrier means a person who trans as used in the ICAO Technical Instruc ports passengers or property in com tions (IBR, see §171.7), has the same merce by rail car, aircraft, motor vehi meaning as Competent Authority. For cle, or vessel. purposes of this subchapter, the Asso CC means closed-cup. ciate Administrator is the Competent Character of vessel means the type of Authority for the United States. service in which the vessel is engaged Composite packaging means a pack at the time of carriage of a hazardous aging consisting of an outer packaging material. and an inner receptacle, so constructed Class means hazard class. See hazard that the inner receptacle and the outer class. packaging form an integral packaging. Class 1. See § 173.50 of this subchapter. Once assembled it remains thereafter Class 2. See §173.115 of this sub an integrated single unit; it is filled, chapter. stored, shipped and emptied as such. Class 3. See §173.120 of this sub- Compressed gas. See §173.115 of this chapter. subchapter. Class 4. See §173.124 of this sub- Consignee means the person or place chapter. shown on a shipping document, pack Class 5. See §173.128 of this sub- age marking, or other media as the lo chapter. cation to which a carrier is directed to Class 6. See § 173.132 of this sub- transport a hazardous material. chapter. Consumer commodity means a material Class 7. See § 173.403 of this sub- that is packaged and distributed in a chapter. form intended or suitable for sale Class 8. See §173.136 of this sub- through retail sales agencies or instru chapter. mentalities for consumption by indi Class 9. See §173.140 of this sub- viduals for purposes of personal care or chapter. household use. This term also includes Closure means a device which closes drugs and medicines. an opening in a receptacle. Containership means a cargo vessel COFC means container-on-flat-car. designed and constructed to transport, Combination packaging means a com within specifically designed cells, port bination of packaging, for transport able tanks and freight containers purposes, consisting of one or more which are lifted on and off with their inner packagings secured in a non-bulk contents intact. outer packaging. It does not include a composite packaging. Corrosive material. See §173.136 of this subchapter. Combustible liquid. See § 173.120 of this subchapter. Crate means an outer packaging with Commerce means trade or transpor incomplete surfaces. tation in the jurisdiction of the United Crewmember means a person assigned States within a single state; between a to perform duty in an aircraft during place in a state and a place outside of flight time. the state; that affects trade or trans Cryogenic liquid. See §173.115(g) of portation between a place in a state this subchapter. and place outside of the state; or on a Cultures and stocks. See § 173.134 of United States-registered aircraft. this subchapter. Compatibility group letter means a des Cylinder means a pressure vessel de ignated alphabetical letter used to cat signed for pressures higher than 40 psia egorize different types of explosive sub and having a circular cross section. It stances and articles for purposes of does not include a portable tank, stowage and segregation. See § 173.52 of multi-unit tank car tank, cargo tank, this subchapter. or tank car. Competent Authority means a national Dangerous when wet material. See agency responsible under its national § 173.124 of this subchapter. 96 Pipeline and Hazardous Materials Safety Admin., DOT § 171.8
Design Certifying Engineer means a (2) Is in a liquid phase with a flash person registered with the Department point at or above 38 °C (100 °F) that is in accordance with subpart F of part intentionally heated and offered for 107 of this chapter who has the knowl transportation or transported at or edge and ability to perform stress anal above its flash point; or ysis of pressure vessels and otherwise (3) Is in a solid phase and at a tem determine whether a cargo tank design perature at or above 240 °C (464 °F). and construction meets the applicable Engine means a locomotive propelled DOT specification. A Design Certifying by any form of energy and used by a Engineer meets the knowledge and abil railroad. ity requirements of this section by EPA means U.S. Environmental Pro meeting any one of the following re tection Agency. quirements: Equivalent lithium content means, for (1) Has an engineering degree and one a lithium-ion cell, the product of the year of work experience in cargo tank rated capacity, in ampere-hours, of a structural or mechanical design; lithium-ion cell times 0.3, with the re (2) Is currently registered as a profes suit expressed in grams. The equivalent sional engineer by appropriate author lithium content of a battery equals the ity of a state of the United States or a sum of the grams of equivalent lithium province of Canada; or content contained in the component (3) Has at least three years’ experi cells of the battery. ence performing in the duties of a De Etiologic agent. See §173.134 of this sign Certifying Engineer prior to Sep subchapter. tember 1, 1991. EX number means a number preceded Designated facility means a hazardous by the prefix “EX”, assigned by the As waste treatment, storage, or disposal sociate Administrator, to an item that facility that has been designated on has been evaluated under the provi the manifest the generator. by sions of 173.56 of this subchapter. District Commander means the Dis § Explosive. See of this trict Commander of the §173.50 sub Coast Guard, chapter. or his authorized representative, who F means degree Fahrenheit. has jurisdiction in the particular geo graphical area. Farmer means a person engaged in production Division means a subdivision of a haz the or raising of crops, ard class. poultry, or livestock. DOD means the U.S. Department of Federal hazardous material transpor Defense. tation law means 49 U.S.C. 5101 et seq. Domestic transportation means trans Ferry vessel means a vessel which is portation between places within the limited in its use to the carriage of United States other than through a for deck passengers or vehicles or both, op eign country. erates on a short run on a frequent DOT or Department means U.S. De schedule between two points over the partment of Transportation. most direct water route, other than in Drum means a flat-ended or convex- ocean or coastwise service, and is of ended cylindrical packaging made of fered as a public service of a type nor metal, fiberboard, plastic, plywood, or mally attributed to a bridge or tunnel. other suitable materials. This defini Filling density has the following tion also includes packagings of other meanings: shapes made of metal or plastic (e.g., (1) For compressed gases in cylinders, round taper-necked packagings or pail- see § 173.304a(a)(2) table note 1. shaped packagings) but does not in (2) For compressed gases in tank clude cylinders, jerricans, wooden bar cars, see § 173.314(c) table note 1. rels or bulk packagings. (3) For compressed gases in cargo Elevated temperature material means a tanks and portable tanks, see material which, when offered for trans §173.315(a) table note 1. portation or transported in a bulk (4) For cryogenic liquids in cylinders, packaging: except hydrogen, see § 173.316(c) (1). (1) Is in a liquid phase and at a tem (5) For hydrogen, cryogenic liquid in perature at or above 100 °C (212 °F); cylinders, see §173.316(c) (3) table note 1. 97 § 171.8 49 CFR Ch. I (10—1—10 Edition)
(6) For cryogenic liquids in cargo Gross weight or Gross mass means the tanks, see §173.318(f) (1). weight of a packaging plus the weight (7) For cryogenic liquids in tank cars, of its contents. see §173.319(d) (1). Hazard class means the category of Flammable gas. See § 173.115 of this hazard assigned to a hazardous mate subchapter. rial under the definitional criteria of Flammable liquid. See §173.120 of this part 173 of this subchapter and the pro subchapter. visions of the §172.101 table. A material Flammable solid. See 173.124 of this may meet the defining criteria for § more subchapter. than one hazard class but is as signed to only one hazard class. Flash point. See of this sub §173.120 Hazard zone means one of four levels chapter. of hazard (Hazard Zones A through D) Freight container means a reusable assigned to gases, as specified in container having a volume of 64 cubic §173.116(a) of this subchapter, and one feet or more, designed and constructed of two levels of hazards (Hazard Zones to permit being lifted with its contents A and B) assigned to liquids that are intact and intended primarily for con poisonous by inhalation, as specified in tainment of packages (in unit form) § 173.133(a) of this subchapter. A hazard during transportation. zone is based on the LC5O value for Fuel cell means an electrochemical acute inhalation toxicity of gases and device that converts the energy of the vapors, as specified in § 173.133(a). chemical reaction between a fuel, such Hazardous material means a substance as hydrogen or hydrogen rich gases. al or material that the Secretary of cohols, or hydrocarbons, and an oxi Transportation has determined is capa dant, such as air or oxygen, to direct ble of posing an unreasonable risk to current (d.c.) power, heat, and other re health, safety, and property when action products. transported in commerce, and has des Fuel cell cartridge or fuel cartridge ignated as hazardous under section 5103 means an article that stores fuel for of Federal hazardous materials trans discharge into the fuel cell through a portation law (49 U.S.C. 5103). The term valve(s) that controls the discharge of includes hazardous substances, haz fuel into the fuel cell. ardous wastes, marine pollutants, ele Fuel cell system means a fuel cell with vated temperature materials, mate an installed fuel cell cartridge together rials designated as hazardous in the with wiring, valves, and other attach Hazardous Materials Table (see 49 CFR ments that connect the fuel cell or car 172.101), and materials that meet the tridge to the device it powers. The fuel defining criteria for hazard classes and cell or cartridge may be so constructed divisions in part 173 of subchapter C of this chapter. that it forms an integral part of the de Hazardous substance for the purposes vice or may be removed and connected of this subchapter, means a material, manually to the device. including its mixtures and solutions, Fuel tank means a tank other than a that— transport cargo tank, used to flam (1) Is listed in the appendix A to mable or combustible liquid, or com §172.101 of this subchapter; pressed gas for the purpose of sup (2) Is in a quantity, in one package, plying fuel for propulsion of the trans which equals or exceeds the reportable port vehicle to which it is attached, or quantity (RQ) listed in the appendix A for the operation of other equipment to § 172.101 of this subchapter; and on the transport vehicle. (3) When in a mixture or solution— Fumigated lading. See § 172.302(g) and (i) For radionuclides, conforms to 173.9. paragraph 7 of the appendix A to Gas means a material which has a § 172.101. vapor pressure greater than 300 kPa (ii) For other than radionuclides, is (43.5 psia) at 50 °C (122 °F) or is com in a concentration by weight which pletely gaseous at 20 °C (68 F) at a equals or exceeds the concentration standard pressure of 101.3 kPa (14.7 corresponding to the RQ of the mate psia). rial, as shown in the following table: 98 Pipeline and Hazardous Materials Safety Admin., DOT § 171.8
Concentration by (iii) Prepares hazardous materials for RQ pounds (kilograms) weight transportation; Percent PPM (iv) Is responsible for safety of trans porting hazardous materials; 5000 (2270) 10 100,000
1000 (454) ...... 2 20000 (v) Operates a vehicle used to trans 100 (45.4) 0.2 2,000 port hazardous materials. 10 (4.54) 0.02 200 1 (0.454) 0.002 20 Hazmat employer means: (1) A person who employs or uses at The term does not include petroleum, least one hazmat employee on a full- including crude oil or any fraction time, part time, or temporary basis; thereof which is not otherwise specifi and who: cally listed or designated as a haz (i) Transports hazardous materials in ardous substance in appendix A to commerce; §172.101 of this subchapter, and the (ii) Causes hazardous materials to be term does not include natural gas, nat transported in commerce; or ural gas liquids, liquefied natural gas, (iii) Designs, manufactures, or synthetic gas usable for fuel (or mix fab ricates, tures of natural gas and such synthetic inspects, marks, maintains, re gas). conditions, repairs or tests a package, Hazardous waste, for the purposes of container, or packaging component this chapter, means any material that that is represented, marked, certified, is subject to the Hazardous Waste or sold by that person as qualified for Manifest Requirements of the U.S. En use in transporting hazardous mate vironmental Protection Agency speci rials in commerce; fied in 40 CFR part 262. (2) A person who is self-employed (in Hazmat means a hazardous material. cluding an owner-operator of a motor Hazmat employee means: (1) A person vehicle, vessel, or aircraft) trans who is: porting materials in commerce; and (i) Employed on a full-time, part who: time, or temporary basis by a hazmat (i) Transports hazardous materials in employer and who in the course of such commerce; full time, part time or temporary em (ii) Causes hazardous materials to be ployment directly affects hazardous transported in commerce; or materials transportation safety; (iii) Designs, manufactures, fab (ii) Self-employed (including an ricates, inspects, marks, maintains, re owner-operator motor of a vehicle, ves conditions, repairs or tests a package, sel, or aircraft) transporting hazardous container, or packaging component materials in commerce who in the that is represented, marked, certified, course of such self-employment di or sold by that person as qualified for rectly affects hazardous materials use in transporting hazardous mate transportation safety; rials in commerce; or (iii) A railroad signalman; or (iv) A railroad maintenance-of-way (3) A department, agency, or instru employee. mentality of the United States Govern (2) This term includes an individual, ment, or an authority of a State, polit employed on a full time, part time, or ical subdivision of a State, or an Indian temporary basis by a hazmat employer, tribe; and who: or who is self-employed, who during (i) Transports hazardous materials in the course of employment: commerce; (i) Loads, unloads, or handles haz (ii) Causes hazardous materials to be ardous materials; transported in commerce; or (ii) Designs, manufactures, fab (iii) Designs, manufactures, fab ricates, inspects, marks, maintains, re ricates, inspects, marks, maintains, re conditions, repairs, or tests a package, conditions, repairs or tests a package, container or packaging component container, or packaging component that is represented, marked, certified, that is represented, marked, certified, or sold as qualified for use in trans or sold by that person as qualified for porting hazardous material in com use in transporting hazardous mate merce. rials in commerce. 99 § 171.8 49 CFR Ch. 1(10—1—10 Edition)
Hermetically sealed means closed by aging or article and is itself enclosed in fusion, gasketing, crimping, or equiva an outer packaging. lent means so that no gas or vapor can Intermodal container means a freight enter or escape. container designed and constructed to Household waste means any solid permit it to be used interchangeably in waste (including garbage, trash, and two or more modes of transport. sanitary waste from septic tanks) de Intermodal portable tank or IMportable rived from households (including single tank means a specific class of portable and multiple residences, hotels and tanks designed primarily for inter motels, bunkhouses, ranger stations, national intermodal use. crew quarters, campgrounds, picnic International transportation means grounds, and day-use recreation areas). transportation— This term is not applicable to consoli (1) Between any place in the United dated shipments of household haz States and any place in a foreign coun ardous materials transported from col try; lection centers. A collection center is a (2) Between places in the United central location where household waste States through a foreign country: or is collected. (3) Between places in one or more for HMR means the Hazardous Materials eign countries through the United Regulations, Parts 171 through 180 of States. this chapter. Irritating material. See §173.132(a) (2) of IAEA means International Atomic this subchapter. Energy Agency. Jerrican means a metal or plastic IATA means International Air Trans packaging of rectangular or polygonal port Association. cross-section. ICAO means International Civil Avia Large packaging means a packaging tion Organization. that— 1MG means International Maritime (1) Consists of an outer packaging Organization. that contains articles or inner pack Incorporated by reference or IBR agings: means a publication or a portion of a (2) Is designated for mechanical han publication that is made a part of the dling; regulations of this subchapter. See (3) Exceeds 400 kg net mass or 450 li § 171.7. ters (118.9 gallons) capacity: Infectious substance (etiologic agent). (4) Has a volume of not more than 3 See § 173.134 of this subchapter. cubic meters (m3) (see § 178.801(1) of this Inner packaging means a packaging subchapter); and for which an outer packaging is re (5) Conforms to the requirements for quired for transport. It does not in the construction, testing and marking clude the inner receptacle of a com of Large Packagings as specified in posite packaging. subparts P and Q of part 178 of this sub Inner receptacle means a receptacle chapter. which requires an outer packaging in Limited quantity, when specified as order to perform its containment func such in a section applicable to a par tion. The inner receptacle may be an ticular material, means the maximum inner packaging of a combination amount of a hazardous material for packaging or the inner receptacle of a which there is a specific labeling or composite packaging. packaging exception. Intermediate bulk container or IBC Lighter means a mechanically oper means a rigid or flexible portable pack ated flame-producing device employing aging, other than a cylinder or port an ignition device and containing a able tank, which is designed for me Class 3 or a Division 2.1 material. For chanical handling. Standards for IBCs design, capacity, and filling density re manufactured in the United States are quirements for lighters containing a set forth in subparts N and 0 of part Division 2.1 material, see § 173.308. 178 of this subchapter. Lighter refill means a pressurized con Intermediate packaging means a pack tainer that does not contain an igni aging which encloses an inner pack- tion device but does contain a release
100 Pipeline and Hazardous Materials Safety Admin., DOT § 171.8 device and is intended for use as a re when in a solution or mixture of one or placement cartridge in a lighter or to more marine pollutants, is packaged in refill a lighter with a Division 2.1 flam a concentration which equals or ex mable gas fuel. For capacity limits, see ceeds: § 173306(h) of this subchapter. (I) Ten percent by weight of the solu Liquid means a material, other than tion or mixture for materials listed in an elevated temperature material, with the appendix: or a melting point or initial melting point (2) One percent by weight of the solu of 20 °C (68 °F) or lower at a standard tion or mixture for materials that are pressure of 101.3 kPa (14.7 psia). A vis identified as severe marine pollutants cous material for which a specific in the appendix. melting point cannot be determined Marking means a descriptive name, must be subjected to the procedures identification number, instructions, specified in ASTM D 4359 Standard cautions, weight, specification, or UN Test Method for Determining Whether marks, or combinations thereof, re a Material is Liquid or Solid” (IBR, see quired by this subchapter on outer § 171.7). packagings of hazardous materials. Liquid phase means a material that Material of trade means a hazardous meets the definition of liquid when material, other than a hazardous evaluated at the higher of the tempera waste, that is carried on a motor vehi ture at which it is offered for transpor c le— tation or at which it is transported, (1) For the purpose of protecting the not at the 38 °C (100 °F) temperature health and safety of the motor vehicle specified in ASTM D 4359 (IBR, see operator or passengers; § 171.7). (2) For the purpose of supporting the Lithium content means the mass of operation or maintenance of a motor lithium in the anode of a lithium metal vehicle (including its auxiliary equip or lithium alloy cell. The lithium con ment); or tent of a battery equals the sum of the (3) By a private motor carrier (in grams of lithium content contained in cluding vehicles operated by a rail car the component cells of the battery. For rier) in direct support of a principal a lithium-ion cell see the definition for business that is other than transpor “equivalent lithium content”. tation by motor vehicle. Loading incidental to movement means Material poisonous by inhalation or loading by carrier personnel or in the Material toxic by inhalation means: presence of carrier personnel of pack (1) A gas meeting the defining cri aged or containerized hazardous mate teria in §173.115(c) of this subchapter rial onto a transport vehicle, aircraft, and assigned to Hazard Zone A, B, C, or or vessel for the purpose of trans D in accordance with § 173.116(a) of this porting it, including the loading, subchapter; blocking and bracing a hazardous ma (2) A liquid (other than as a mist) terials package in a freight container meeting the defining criteria in or transport vehicle, and segregating a §173.132(a)(1)(iii) of this subchapter and hazardous materials package in a assigned to Hazard Zone A or B in ac freight container or transport vehicle cordance with §173.133(a) of this sub from incompatible cargo. For a bulk chapter; or packaging, loading incidental to move (3) Any material identified as an in ment means filling the packaging with halation hazard by a special provision a hazardous material for the purpose of in column 7 of the § 172.101 table. transporting it. Loading incidental to Maximum allowable working pressure movement includes transloading. or MA WP: For DOT specification cargo Magazine vessel means a vessel used tanks used to transport liquid haz for the receiving, storing, or dispensing ardous materials, see § 178.320(a) of this of explosives. subchapter. Magnetic material. See §173.21(d) of Maximum capacity means the max this subchapter. imum inner volume of receptacles or Marine pollutant, means a material packagings. which is listed in appendix B to §172.101 Maximum net mass means the allow of this subchapter (also see §171.4) and, able maximum net mass of contents in
101 § 171.8 49 CFR Ch. I (10—1—10 Edition) a single packaging, or as used in sub United States, including the territorial part M of part 178 of this subchapter, seas. the maximum combined mass of inner Non-bulk packaging means a pack packaging, and the contents thereof. aging which has: Mechanical displacement meter prover (1) A maximum capacity of 450 L (119 means a mechanical device used in the gallons) or less as a receptacle for a oilfield service industry consisting of a liquid; pipe assembly that is used to calibrate (2) A maximum net mass of 400 kg the accuracy and performance of me (882 pounds) or less and a maximum ca ters that measure the quantities of a pacity of 450 L (119 gallons) or less as a product being pumped or transferred at receptacle for a solid; or facilities such as drilling locations, re (3) A water capacity of 454 kg (1000 fineries, tank farms, and loading racks. pounds) or less as a receptacle for a gas Metered delivery service means a cargo as defined in § 173.115 of this sub tank unloading operation conducted at chapter. a metered flow rate of 378.5 L (100 gal Nonflammable gas. See § 173.115 of this lons) per minute or less through an at subchapter. tached delivery hose with a nominal in N.O.S. means not otherwise specified. side diameter of 3.175 cm (11/4 inches) or N.O.S. description means a shipping less. description from the §172.101 table Miscellaneous hazardous material. See which includes the abbreviation no.5. § 173.140 of this subchapter. NPT means an American Standard Mixture means a material composed taper pipe thread conforming to the re of more than one chemical compound quirements of NBS Handbook H—28 or element. (IBR, see §171.7). NRC (non-reusable container) means a Mode means any of the following packaging (container) whose reuse is transportation methods; rail, highway, restricted in accordance with the pro air, or water. visions of § 173.28 of this subchapter. Motor vehicle includes a vehicle, ma Occupied caboose means a rail car chine, tractor, trailer, or semitrailer, being used to transport non-passenger or any combination thereof, propelled personnel. or drawn by mechanical power and Officer in Charge, Marine Inspection used upon the highways in the trans means a person from the civilian or portation of passengers or property. It military branch of the Coast Guard does not include a vehicle, locomotive, designated as such by the Commandant or car operated exclusively on a rail or and who under the supervision and di rails, or a trolley bus operated by elec rection of the Coast Guard District tric power derived from a fixed over Commander is in charge of a des head wire, furnishing local passenger ignated inspection zone for the per transportation similar to street-rail formance of duties with respect to the way service. enforcement and administration of Movement means the physical trans title 52, Revised Statutes, acts amend fer of a hazardous material from one atory thereof or supplemental thereto, geographic location to another by rail rules and regulations thereunder, and car, aircraft, motor vehicle, or vessel. the inspection required thereby. Multiple-element gas container or Offshore supply vessel means a cargo MEGC means assemblies of UN cyl vessel of less than 500 gross tons that inders, tubes, or bundles of cylinders regularly transports goods, supplies or interconnected by a manifold and as equipment in support of exploration or sembled within a framework. The term production of offshore mineral or en includes all service equipment and ergy resources. structural equipment necessary for the Operator means a person who controls transport of gases. the use of an aircraft, vessel, or vehi Name of contents means the proper cle. shipping name as specified in § 172.101 Organic peroxide. See §173.128 of this of this subchapter. subchapter. Navigable waters means, for the pur ORM means other regulated mate poses of this subchapter, waters of the rial. See § 173.144 of this subchapter. 102 Pipeline and Hazardous Materials Safety Admin., DOT § 171.8
Outage or ullage means the amount a person being carried on a vessel other by which a packaging falls short of than: being liquid full, usually expressed in (1) The owner or his representative; percent by volume. (2) The operator; Outer packaging means the outermost (3) A bona fide member of the crew enclosure of a composite or combina engaged in the business of the vessel tion packaging together with any ab who has contributed no consideration sorbent materials, cushioning and any for his carriage and who is paid for his other components necessary to contain services; or and protect inner receptacles or inner (4) A guest who has not contributed packagings. any consideration directly or indi Overpack, except as provided in sub rectly for his carriage. part K of part 178 of this subchapter, Passenger-carrying aircraft means an means an enclosure that is used by a aircraft that carries any person other single consignor to provide protection than a crewmember, company em or convenience in handling of a pack ployee, an authorized representative of age or to consolidate two or more the United States, or a person accom packages. Overpack does not include a panying the shipment. transport vehicle, freight container, or Passenger vessel means— aircraft unit load device. Examples of (1) A vessel subject to any of the re overpacks are one or more packages: quirements of the International Con (I) Placed or stacked onto a load vention for the Safety of Life at Sea, board such as a pallet and secured by 1974, which carries more than 12 pas strapping, shrink wrapping, stretch sengers; wrapping, or other suitable means; or (2) A cargo vessel documented under (2) Placed in a protective outer pack the laws of the United States and not aging such as a box or crate. subject to that Convention, which car ries more Oxidizer. See §173.127 of this sub than 16 passengers; chapter. (3) A cargo vessel of any foreign na tion that extends reciprocal privileges Oxidizing gas means a gas which may, and is not subject to that Convention generally by providing oxygen, cause and which carries more than 16 pas or contribute to the combustion of sengers; and other material more than air does. (4) A vessel engaged in a ferry oper Oxygen generator (chemical) means a ation and which carries passengers. device containing chemicals that upon Person means an individual, corpora activation release oxygen as a product tion, company, association, firm, part of chemical reaction. nership, society, joint stock company; Package or Outside Package means a or a government, Indian tribe, or au packaging plus its contents. For radio thority of a government or tribe offer active materials, see § 173.403 of this ing a hazardous material for transpor subchapter. tation in commerce or transporting a Packaging means a receptacle and hazardous material to support a com any other components or materials mercial enterprise. This term does not necessary for the receptacle to perform include the United States Postal Serv its containment function in conform ice or, for purposes of 49 U.S.C. 5123 and ance with the minimum packing re 5124, a Department, agency, or instru quirements of this subchapter. For ra mentality of the government. dioactive materials packaging, see Person who offers or offeror means: § 173.403 of this subchapter. (1) Any person who does either or Packing group means a grouping ac both of the following: cording to the degree of danger pre (i) Performs, or is responsible for per sented by hazardous materials. Pack forming, any pre-transportation func ing Group I indicates great danger; tion required under this subchapter for Packing Group II, medium danger; transportation of the hazardous mate Packing Group III, minor danger. See rial in commerce. §172.101(f) of this subchapter. (ii) Tenders or makes the hazardous Passenger (With respect to vessels and material available to a carrier for for the purposes of part 176 only) means transportation in commerce. 103 § 171.8 49 CFR Ch. 1(10—1—10 Edition)
(2) A carrier is not an offeror when it (4) Securing a closure on a filled or performs a function required by this partially filled hazardous materials subchapter as a condition of accept package or container or on a package ance of a hazardous material for trans or container containing a residue of a portation in commerce (e.g., reviewing hazardous material. shipping papers, examining packages (5) Marking a package to indicate to ensure that they are in conformance that it contains a hazardous material. with this subchapter, or preparing (6) Labeling a package to indicate shipping documentation for its own that it contains a hazardous material. use) or when it transfers a hazardous (7) Preparing a shipping paper. material to another carrier for contin (8) Providing and maintaining emer ued transportation in commerce with gency response information. out performing a pre-transportation (9) Reviewing a shipping paper to function. verify compliance with the HMR or PHMSA means the Pipeline and Haz international equivalents. ardous Materials Safety Administra (10) For each person importing a haz tion, U.S. Department of Transpor ardous material into the United States, tation, Washington, DC 20590. providing the shipper with timely and Placarcied car means a rail car which complete information as to the HMR is placarded in accordance with the re requirements that will apply to the quirements of part 172 of this sub transportation of the material within chapter. the United States. Poisonous gas. See §173.115 of this sub (11) Certifying that a hazardous ma chapter. terial is in proper condition for trans portation in conformance with Poisonous materials. See §173.132 of the re this subchapter. quirements of the HMR. (12) Loading, blocking, and bracing Portable tank means a bulk packaging a hazardous materials package in a (except a cylinder having a water ca freight container or transport vehicle. pacity of 1000 pounds or less) designed (13) Segregating a hazardous mate primarily to be loaded onto, or on, or rials package in a freight container or temporarily attached to a transport ve transport vehicle from incompatible hicle or ship and equipped with skids, cargo. mountings, or accessories to facilitate (14) Selecting, providing, or affixing handling of the tank by mechanical placards for a freight container or means. It does not include a cargo transport vehicle to indicate that it tank, tank car, multi-unit tank car contains a hazardous tank, or trailer carrying material. 3AX, 3AAX, or Primary 3T cylinders. hazard means the hazard class of a material as assigned in the Preferred route or Preferred highway is §172.101 table. highway a for shipment of highway Private track or Private siding means: route controlled quantities of radioactive (1) Track located outside of a carrier’s materials so designated by a State right-of-way, yard, or terminals where routing agency, and any Interstate the carrier does not own the rails, ties, System highway for which an alter roadbed, or right-of-way, or native highway has not been des (ii) Track leased by a railroad to a ignated by such State agency as pro lessee, where the lease provides for, vided by § 397.103 of this title. and actual practice entails, exclusive Pre-transportation function means a use of that trackage by the lessee and! function specified in the HMR that is or a general system railroad for pur required to assure the safe transpor pose of moving only cars shipped to or tation of a hazardous material in com by the lessee, and where the lessor oth merce, including— erwise exercises no control over or re (1) Determining the hazard class of a sponsibility for the trackage or the hazardous material. cars on the trackage. (2) Selecting a hazardous materials Proper shipping name means the name packaging. of the hazardous material shown in (3) Filling a hazardous materials Roman print (not italics) in §172.101 of packaging, including a bulk packaging. this subchapter. 104 Pipeline and Hazardous Materials Safety Admin., DOT § 171.8 Psi means pounds per square inch. Reportable quantity (RQ) for the pur Psia means pounds per square inch poses of this subchapter means the absolute. quantity specified in column 2 of the Psig means pounds per square inch appendix to § 172.101 for any material gauge. identified in column 1 of the appendix. Public vessel means a vessel owned by Research means investigation or ex and being used in the public service of perimentation aimed at the discovery the United States. It does not include a of new theories or laws and the dis vessel owned by the United States and covery and interpretation of facts or engaged in a trade or commercial serv revision of accepted theories or laws in ice or a vessel under contract or char the light of new facts. Research does ter to the United States. not include the application of existing Pyrophoric liquid. See § 173.124(b) of technology to industrial endeavors. this subchapter. Residue means the hazardous mate Radioactive materials. See § 173.403 of rial remaining in a packaging, includ this subchapter for definitions relating ing a tank car, after its contents have to radioactive materials. been unloaded to the maximum extent Rail car means a car designed to practicable and before the packaging is carry freight or non-passenger per either refilled or cleaned of hazardous sonnel by rail, and includes a box car, material and purged to remove any flat car, gondola car, hopper car, tank hazardous vapors. car, and occupied caboose. Reused packaging. See §173.28 of this Railroad means a person engaged in subchapter. transportation by rail. SADT means self-accelerated decom Receptacle means a containment ves position temperature. See §173.21(f) of sel for receiving and holding materials, this subchapter. including any means of closing. Salvage packaging means a special Reconditioned packaging. See § 173.28 packaging conforming to §173.3 of this of this subchapter. subchapter into which damaged, defec Registered Inspector means a person tive, leaking, or non-conforming haz registered with the Department in ac ardous materials packages, or haz cordance with subpart F of part 107 of ardous materials that have spilled or this chapter who has the knowledge leaked, are placed for purposes of and ability to determine whether a transport for recovery or disposal. cargo tank conforms to the applicable SCF (standard cubic foot) means one DOT specification. A Registered Inspec cubic foot of gas measured at 60 °F. and tor meets the knowledge and ability re 14.7 psia. quirements of this section by meeting Secretary means the Secretary of any one of the following requirements: Transportation. (1) Has an engineering degree and one Self-defense spray means an aerosol or year of work experience relating to the non-pressurized device that: testing and inspection of cargo tanks; (1) Is intended to have an irritating (2) Has an associate degree in engi or incapacitating effect on a person or neering and two years of work experi animal; and ence relating to the testing and inspec (2) Meets no hazard criteria other tion of cargo tanks; than for Class 9 (for example, a pepper (3) Has a high school diploma (or spray; see §173.140(a) of this sub General Equivalency Diploma) and chapter) and, for an aerosol, Division three years of work experience relating 2.1 or 2.2 (see §173.115 of this sub to the testing and inspection of cargo chapter), except that it may contain tanks; or not more than two percent by mass of (4) Has at least three years’ experi a tear gas substance (e.g., ence performing the duties of a Reg chioroacetophenone (CN) or 0- istered Inspector prior to September 1, chlorobenzylmalonitrile (CS); see 1991. § 173.132(a) (2) of this subchapter.) Regulated medical waste. See § 173.134 Settled pressure means the pressure of this subchapter. exerted by the contents of a UN pres Remanufactured packagings. See sure receptacle in thermal and diffu § 173.28 of this subchapter. sive equilibrium. 105 § 171.8 49 CFR Ch. I (10—1—10 Edition)
Sharps. See §173.134 of this sub iana Islands, the Virgin Islands, Amer chapter. ican Samoa, Guam, or any other terri Shipping paper means a shipping tory or possession of the United States order, bill of lading, manifest or other designated by the Secretary. shipping document serving a similar State-designated route means a pre purpose and prepared in accordance ferred route selected in accordance with subpart C of part 172 of this chap with U.S. DOT “Guidelines for Select ter. ing Preferred Highway Routes for Siftproof packaging means a pack Highway Route Controlled Quantities aging impermeable to dry contents, in of Radioactive Materials” or an equiv cluding fine solid material produced alent routing analysis which ade during transportation. quately considers overall risk to the Single packaging means a non-bulk public. packaging other than a combination Storage incidental to movement means packaging. storage of a transport vehicle, freight Solid means a material which is not a container, or package containing a haz gas or a liquid. ardous material by any person between Solution means any homogeneous liq the time that a carrier takes physical uid mixture of two or more chemical possession of the hazardous material compounds or elements that will not for the purpose of transporting it in undergo any segregation under condi commerce until the package con tions normal to transportation. taining the hazardous material is phys Special permit means a document ically delivered to the destination indi issued by the Associate Administrator, cated on a shipping document, package or other designated Department offi marking, or other medium, or, in the cial, under the authority of 49 U.S.C. case of a private motor carrier, be 5117 permitting a person to perform a tween the time that a motor vehicle function that is not otherwise per driver takes physical possession of the mitted under subchapters A or C of this hazardous material for the purpose of chapter, or other regulations issued transporting it in commerce until the under 49 U.S.C. 5101 et seq. (e.g., Federal driver relinquishes possession Motor Carrier Safety routing require of the package its ments). The terms “special permit” at destination and is no longer responsible for and “exemption” have the same mean performing func tions subject the ing for purposes of subchapters A or C to HMR with respect of this chapter or other regulations to that particular package. issued under 49 U.S.C. 5101 through (1) Storage incidental to movement in 5128. cludes— Specification packaging means a pack (i) Storage at the destination shown aging conforming to one of the speci on a shipping document, including fications or standards for packagings storage at a transloading facility, pro in part 178 or part 179 of this sub vided the shipping documentation iden chapter. tifies the shipment as a through-ship Spontaneously combustible material. ment and identifies the final destina See § 173.124(b) of this subchapter. tion or destinations of the hazardous Stabilized means that the hazardous material; and material is in a condition that pre (ii) Rail cars containing hazardous cludes uncontrolled reaction. This may materials that are stored on track that be achieved by methods such as adding does not meet the definition of “pri an inhibiting chemical, degassing the vate track or siding” in §171.8, even if hazardous material to remove dis those cars have been delivered to the solved oxygen and inerting the air destination shown on the shipping doc space in the package, or maintaining ument. the hazardous material under tempera (2) Storage incidental to movement ture control. does not include storage of a hazardous State means a State of the United material at its final destination as States, the District of Columbia, the shown on a shipping document. Commonwealth of Puerto Rico, the Stowage means the act of placing haz Commonwealth of the Northern Mar- ardous materials on board a vessel. 106 Pipeline and Hazardous Materials Safety Admin., DOT § 171.8
Strong outer packaging means the out during switching operations or where ermost enclosure that provides protec the operation is that of classifying and tion against the unintentional release assembling rail cars within a railroad of its contents. It is a packaging that yard for the purpose of making or is sturdy, durable, and constructed so breaking up trains. that it will retain its contents under Trainship means a vessel other than a normal conditions of transportation. In rail car ferry or carfloat, specifically addition, a strong outer packaging equipped to transport railroad vehicles, must meet the general packaging re and fitted with installed securing de quirements of subpart B of part 173 of vices to tie down each vehicle. this subchapter but need not comply Transloading means the transfer of a with the specification packaging re hazardous material by any person from quirements in part 178 of the sub one bulk packaging to another bulk chapter. For transport by aircraft, a packaging, from a bulk packaging to a strong outer packaging is subject to non-bulk packaging, or from a non- § 173.27 of this subchapter. The terms bulk packaging to a bulk packaging for “strong outside container” and “strong the purpose of continuing the move outside packaging” are synonymous ment of the hazardous material in com with “strong outer packaging.” merce. Subsidiary hazard means a hazard of a Transport vehicle means a cargo-car material other than the primary haz rying vehicle such as an automobile, ard. (See primary hazard). van, tractor, truck, semitrailer, tank Table in §172.101 or §172.101 table car or rail car used for the transpor means the Hazardous Materials Table tation of cargo by any mode. Each in § 172.101 of this subchapter. cargo-carrying body (trailer, rail car, Technical name means a recognized etc.) is a separate transport vehicle. chemical name or microbiological Transportation or transport means the name currently used in scientific and movement of property and loading, un technical handbooks, journals, and loading, or storage incidental to that texts. Generic descriptions are author movement. ized for use as technical names pro UFC means Uniform Freight Classi vided they readily identify the general fication. chemical group, or microbiological UN means United Nations. group. Examples of acceptable generic UN cylinder means a transportable chemical descriptions are organic phos pressure receptacle with a water capac phate compounds, petroleum aliphatic ity not exceeding 150 L that has been hydrocarbons and tertiary amines. For marked and certified as conforming to proficiency testing only, generic the applicable requirements in part 178 microbiological descriptions such as of this subchapter. bacteria, mycobacteria, fungus, and UN portable tank means an inter- viral samples may be used. Except for modal tank having a capacity of more names which appear in subpart B of than 450 liters (118.9 gallons). It in part 172 of this subchapter, trade cludes a shell fitted with service equip names may not be used as technical ment and structural equipment, includ names. ing stabilizing members external to the TOFC means trailer-on-flat-car. shell and skids, mountings or acces Top shell means the tank car tank sories to facilitate mechanical han surface, excluding the head ends and dling. A UN portable tank must be ca bottom shell of the tank car tank. pable of being filled and discharged Toxin. See § 173.134 of this subchapter. without the removal of its structural Trailership means a vessel, other than equipment and must be capable of a carfloat, specifically equipped to being lifted when full. Cargo tanks, rail carry motor transport vehicles and tank car tanks, non-metallic tanks, fitted with installed securing devices non-specification tanks, bulk bins, and to tie down each vehicle. The term IBCs and packagings made to cylinder trailership includes Roll-on/Roll-off (RO/ specifications are not UN portable RU) vessels. tanks. Train means one or more engines cou UN pressure receptacle means a UN pled with one or more rail cars, except cylinder or tube. 107 § 171.8 49 CFR Ch. I (10—1—10 Edition)
UN Recommendations means the UN transport vehicle, aircraft, or vessel, or Recommendations on the Transport of for a bulk packaging, emptying a haz Dangerous Goods (IBR, see §171.7). ardous material from the bulk pack UN standard packaging means a pack aging after the hazardous material has aging conforming to standards in the been delivered to the consignee when UN Recommendations (IBR, see § 171.7). performed by carrier personnel or in UN tube means a seamless transport the presence of carrier personnel or, in able pressure receptacle with a water the case of a private motor carrier, capacity exceeding 150 L but not more while the driver of the motor vehicle than 3,000 L that has been marked and from which the hazardous material is certified as conforming to the require being unloaded immediately after ments in part 178 of this subchapter. movement is completed is present dur Undeclared hazardous material means ing the unloading operation. a hazardous material that is: (I) Sub (Emptying a hazardous material from a ject to any of the hazard communica bulk packaging while the packaging is tion requirements in subparts C (Ship on board a vessel is subject to separate ping Papers), D (Marking), E (Label regulations as delegated by Depart ing), and F (Placarding) of Part 172 of ment of Homeland Security Delegation this subchapter, or an alternative No. 0170.1 at 2(103).) Unloading inci marking requirement in Part 173 of dental to movement includes this subchapter (such as § 173.4(a) (10) transloading. and 173.6(c)); and (2) offered for trans Vessel includes every description of portation in commerce without any watercraft, used or capable of being visible indication to the person accept used as a means of transportation on ing the hazardous material for trans the water. portation that a hazardous material is Viscous liquid means a liquid material present, on either an accompanying which has a measured viscosity in ex shipping document, or the outside of a cess of 2500 centistokes at 25 °C. (77 CF.) transport vehicle, freight container, or when determined in accordance with package. the procedures specified in ASTM Unintentional release means the es Method D 445-72 “Kinematic Viscosity cape of a hazardous material from a of Transparent and Opaque Liquids package on an occasion not anticipated (and the Calculation Dynamic Vis or planned. This includes releases re of cosity)” or ASTM Method D 1200-70 sulting from collision, package fail “Viscosity ures, human error, criminal activity, of Paints, Varnishes, and Lacquers Ford negligence, improper packing, or un by Viscosity Cup.” usual conditions such as the operation Volatility refers to the relative rate of of pressure relief devices as a result of evaporation of materials to assume the over-pressurization, overfill or fire ex vapor state. posure. It does not include releases, Water reactive material. See § 173.124(c) such as venting of packages, where al of this subchapter. lowed, and the operational discharge of Water resistant means having a degree contents from packages. of resistance to permeability by and Unit load device means any type of damage caused by water in liquid form. freight container, aircraft container, Wooden barrel means a packaging aircraft pallet with a net, or aircraft made of natural wood, of round cross- pallet with a net over an igloo. section, having convex walls, con United States means a State of the sisting of staves and heads and fitted United States, the District of Colum with hoops. bia, the Commonwealth of Puerto Rico, Working pressure for purposes of UN the Commonwealth of the Northern pressure receptacles, means the settled Mariana Islands, the \Jirgin Islands, pressure of a compressed gas at a ref American Samoa, Guam, or any other erence temperature of 15 CC (59 °F). territory or possession of the United W. T. means watertight. States designated by the Secretary. Unloading incidental to movement lAmdt. 171—32, 41 FR 15994, Apr. 15, 19761 means removing a packaged or con EDIToRIAL NOTE: For FEDERAL REGISTER ci tainerized hazardous material from a tations affecting §171.8, see the List of CFR
108 Pipeline and Hazardous Materials Safety Admin., DOT § 171.10
Sections Affected which appears in the Find § 171.10 Units of measure. ing Aids section of the printed volume and on GPO Access. (a) General. To ensure compatibility with international transportation § 171.9 Rules of construction. standards, most units of measure in (a) In this subchapter, unless the con this subchapter are expressed using the text requires otherwise: International System of Units (“SI” or (1) Words imparting the singular in metric). Where SI units appear, they clude the plural; are the regulatory standard. U.S. (2) Words imparting the plural in standard or customary units, which ap clude the singular; and pear in parentheses following the SI Words imparting (3) the masculine units, are for information only and are gender include the feminine; not intended to be the regulatory (b) In this subchapter, the word: (1) standard. ‘Shall” is used in an imperative sense; (2) “Must” is used in an imperative (b) Abbreviations for SI units of sense; measure generally used throughout (3) “Should” is used in a rec this subchapter are as shown in para ommendatory sense; graph (c) of this section. Customary (4) “May” is used in a permissive units shown throughout this sub sense to state authority or permission chapter are generally not abbreviated. to do the act described, and the words (c) Conversion values. (1) Conversion “no person may * * “ or “a person values are provided in the following may not ** “ means that no person is table and are based on values provided required, authorized, or permitted to in ASTM F 380, “Standard for Metric do the act described; and Practice”. (5) “Includes” is used as a word of in (2) If an exact conversion is needed, clusion not limitation. the following conversion table should (Amdt. 171—32, 41 FR 15996, Apr. 15, 1976, as be used. amended by Amdt. 171—32A, 41 FR 40630, Sept. 20, 1976; Amdt. 171—121, 58 FR 51528, Oct. 1, 1993; 75 FR 60338, Sept. 30, 2010]
TABLE OF CONVERSION FACTORS FOR SI UNITS
Measurement SI to U.S. standard U.S. standard to SI
Activity 1 TBq=27 Ci 1 Ci=0.037 TBq Length 1 cm=O.3937008 in 1 in=2.540000 cm 1 m=3.280840 ft 1 ft=0.3048000 m Thickness 1 mm=0.03937008 in 1 in=25.40000 mm Mass (weight) 1 kg=2.204622 lb 1 lb=0.4535924 kg 1 g0.03527397 oz I oz28.34952 g Pressure 1 kPa=O.1450377 psi 1 psi=6.894757 kPa I Bar=100 kPa=14.504 psi 1 psi=O.06895 Bar I kPa=7.5 mm Hg Radiation level 1 Sv/hrlOO rem/hr 1 rem/hrO.O1 Sv/hr Volume (liquid) 1 L=0.2641720 gal 1 gal3.785412 L 1 rnL0.03381402 oz 1 oz’29.57353 mL 1 m3=35.31466 ft3 1 ft=0.02831685 m3 Density I kg/m3=0.06242797 lb/ft3 1 lb/ft3=16.01846 kg/m3 Force 1 Newton 0.2248 Pound-force 1 Pound-force4.483 N Abbreviation for units of measure are as follows: Unit of measure and abbreviation: (SI): millimeter, mm; centimeter, cm; meter, m; gram, g; kilogram, kg; kiloPascal, kPa; liter, L; milliliter, mL; cubic meter, m3; Terabecquerel, TBq; Gigabecquerel, GBq; millisievert, mSv; Newton, N; (U.S.): Inch, in; foot, ft; ounce, oz; pound. lb; psig, psi; gallon, gal; cubic feet, ft3; Curie, Ci; millicurie, mCi; millirem, mrem. lAmdt. 171—111, 56 FR 66159, Dec. 20. 1991, as amended by Amdt. 171—136, 60 FR 49108, Sept. 21, 1995; Amdt. 171—135, 60 FR 50302. Sept. 28, 1995; 66 FR 33335, June 21, 2001: 66 FR 45378, Aug. 28, 2001; 68 FR 75740, Dec. 31, 2003]
109 § 171.11 49 CFR Ch. 1(10—1—10 Edition)
§171.11 [Reserved] specified in the §172.101 table for the material to be transported; § 171.12 North American Shipments. (iii) The portable tank, cargo tank (a) Requirements for the use of the motor vehicle or rail tank car con Transport Canada TDG Regulations. (1) forms to the requirements of all as A hazardous material transported from signed bulk packaging special provi Canada to the United States, from the sions (B codes, and T and TP codes) in United States to Canada, or transiting § 172.102 of this subchapter; and the United States to Canada or a for (iv) The bulk packaging conforms to eign destination may be offered for all applicable requirements of §l73.31, transportation or transported by motor 173.32, 173.33 and 173.35 of this sub carrier and rail in accordance with the chapter, and parts 177 and 180 of this Transport Canada TDG Regulations subchapter. The periodic retests and (IBR, see §171.7) as authorized in inspections required by § 173.31, 173.32 § 171.22, provided the requirements in and 173.33 of this subchapter may be §l71.22 and 171.23, as applicable, and performed in accordance with part 180 this section are met. In addition, a of this subchapter or in accordance cargo tank motor vehicle, portable with the requirements of the TDG Reg tank or rail tank car authorized by the ulations provided that the intervals Transport Canada TDG Regulations prescribed in part 180 of this sub may be used for transportation to, chapter are met. from, or within the United States pro (v) Rail tank cars must conform to vided the cargo tank motor vehicle, the requirements of Canadian General portable tank or rail tank car conforms Standards Board standard 43.147 (IBR, to the applicable requirements of this see §171.7). section. Except as otherwise provided (4) Cylinders. When the provisions of in this subpart and subpart C of this this subchapter require that a DOT part, the requirements in parts 172, 173, specification or UN pressure recep and 178 of this subchapter do not apply a tacle must used for hazardous ma for a material transported in accord be a ance with the Transport Canada TDG terial, a packaging authorized by the Regulations. Transport Canada TDG Regulations (2) General packaging requirements. may be used only if it corresponds to When the provisions of this subchapter the DOT specification or UN standard require a DOT specification or UN authorized by this subchapter. Unless standard packaging to be used for otherwise excepted in this subchapter, transporting a hazardous material, a a cylinder (including a UN pressure re packaging authorized by the Transport ceptacle) may not be transported un Canada TDG Regulations may be used, less— subject to the limitations of this part, (i) The packaging is a UN pressure re and only if it is equivalent to the cor ceptacle marked with the letters responding DOT specification or UN ‘CAN” for Canada as a country of packaging (see § l73.24(d)(2) of this sub manufacture or a country of approval chapter) authorized by this subchapter. or is a cylinder that was manufactured, (3) Bulk packagings. A portable tank, inspected and tested in accordance cargo tank motor vehicle or rail tank with a DOT specification or a UN car equivalent to a corresponding DOT standard prescribed in part 178 of this specification and conforming to and subchapter, except that cylinders not authorized by the Transport Canada conforming to these requirements must TDG Regulations may be used pro meet the requirements in §171.23. Each vided— cylinder must conform to the applica (i) An equivalent type of packaging is ble requirements in part 173 of this sub authorized for the hazardous material chapter for the hazardous material in according to the §172.101 table of this volved. subchapter; (ii) The packaging is a Canadian (ii) The portable tank, cargo tank Transport Commission (CTC) specifica motor vehicle or rail tank car con tion cylinder manufactured, originally forms to the requirements of the appli marked and approved in accordance cable part 173 bulk packaging section with the CTC regulations and in full 110 Pipeline and Hazardous Materials Safety Admin., DOT § 17114 conformance with the Transport Can that is a material poisonous by inhala ada TDG Regulations. tion (see § 171.8) is transported by high (A) The CTC specification cor way or rail from Mexico to the United responds with a DOT specification and States, or from the United States to the cylinder markings are the same as Mexico, the following requirements those specified in this subchapter ex apply: cept that they were originally marked (1) The shipping description must in with the letters ‘CTC” in place of clude the words “Toxic Inhalation Haz ‘DOT”; ard” or “Poison-Inhalation Hazard” or (B) The cylinder has been requalified “Inhalation Hazard”, as required in under a program authorized by the § 172.203(m) of this subchapter. Transport Canada TDG Regulations or (2) The material must be packaged in requalified in accordance with the re accordance with requirements of this quirements in § 180.205 within the pre subchapter. scribed requalification period provided (3) The package must be marked in for the corresponding DOT specifica accordance with §172.313 of this sub tion; chapter. (C) When the regulations authorize a (4) Except as provided in paragraph cylinder for a specific hazardous mate (e) (5) of this section, the package must rial with a specification marking prefix be labeled or placarded POISON GAS or of “DOT”, a cylinder marked “CTC” POISON INHALATION HAZARD, as which otherwise bears the same mark appropriate, in accordance with sub ings that would be required of the spec parts E and F of this subchapter. ified “DOT” cylinder may be used; and (5) A label or placard that conforms (D) Transport of the cylinder and the to the UN Recommendations (IBR, see material it contains is in all other re 171.7) specifications for a “Division spects in conformance with the re § 2.3” or “Division 6.1” label or placard quirements of this subchapter (e.g. may be substituted for the POISON valve protection, filling requirements, GAS or POISON INHALATION HAZ operational requirements, etc.). ARD label or placard required by (5) Class 1 (explosive) materials. When 172.400(a) and 172.504(e) of this sub transporting Class 1 (explosive) mate § chapter on a package transported in a rial, rail and motor carriers must com closed transport vehicle or freight con ply with 49 CFR 1572.9 and 1572.11 the to tainer. The transport vehicle or freight extent the requirements apply. container must be marked with identi (6) Primary lithium batteries and cells. fication numbers for the material, re Packages containing primary lithium gardless of the total quantity con batteries and cells that meet the excep tained in the transport vehicle or tion in §172.102, Special Provision 188 freight container, in the manner speci or 189 of this subchapter must be fied in 172.313(c) of this subchapter marked “PRIMARY LITHIUM BAT § and placarded as required by subpart F TERIES—FORBIDDEN FOR TRANS of this subchapter. PORT ABOARD PASSENGER AIR CRAFT” or “LITHIUM METAL BAT [Amdt. 171—111, 55 FR 52472, Dec. 21, 1990] TERIES—FORBIDDEN FOR TRANS EDITORIAL NOTE: For FEDERAL REGIsTER ci PORT ABOARD PASSENGER AIR tations affecting § 171.12, see the List of CFR CRAFT.” The provisions of this para Sections Affected which appears in the Find graph do not apply to packages that ing Aids section of the printed volume and contain 5 kg (11 pounds) net weight or on GPO Access. less of primary lithium batteries cells that are contained in or packed with § 171.12a [Reserved] equipment. (b) Shipments to or from Mexico. Unless § 171.14 Transitional provisions for im otherwise excepted, hazardous mate plementing certain requirements. rials shipments from Mexico to the General. The purpose of the provi United States or from the United sions of this section is to provide an or States to Mexico must conform to all derly transition to certain new require applicable requirements of this sub ments so as to minimize any burdens chapter. When a hazardous material associated with them. 111 § 171.14 49 CFR Ch. I (10—1—10 Edition)
(a) Previously filled packages—(1) (d) A final rule published in the FED Packages filled prior to October 1, 1991. ERAL REGISTER on December 29, 2006, Notwithstanding the marking and la effective January 1, 2007, resulted in re beling provisions of subparts D and E, visions to this subchapter. During the respectively, of part 172, and the pack transition period, until January 1, 2008, aging provisions of part 173 and subpart as provided in paragraph (d) (1) of this B of part 172 of this subchapter, a pack section, a person may elect to comply age may be offered for transportation with either the applicable require and transported prior to October 1, ments of this subchapter in effect on 2001, if it— December 31, 2006, or the requirements (i) Conforms to the old requirements published in the December 29, 2006 final of this subchapter in effect on Sep rule. tember 30, 1991; (1) Transition dates. The effective date (ii) Was filled with a hazardous mate of the final rule published on December rial prior to October 1, 1991; 29, 2006 is January 1, 2007. A delayed (iii) Is marked “Inhalation Hazard” if compliance date of January 1, 2008, is appropriate, in accordance with authorized. Unless otherwise specified, § 172.313 of this subchapter or Special on and after January 1, 2008, all appli Provision 13, as assigned in the § 172.101 cable regulatory requirements adopted table; and in the final rule in effect on January 1, (iv) Is not emptied and refilled on or 2007, must be met. after October 1, 1991. (2) Intermixing old and new require (2) Non-bulk packages filled prior to Oc ments. Marking, labeling, placarding, tober 1, 1996. Notwithstanding the pack and shipping paper descriptions must aging provisions of subpart B of part conform to either the old requirements 172 and the packaging provisions of of this subchapter in effect on Decem part 173 of this subchapter with respect ber 31, 2006, or the new requirements of to UN standard packagings, a non-bulk this subchapter in the final rule with package other than a cylinder may be out intermixing communication ele offered for transportation and trans ments, except that intermixing is per ported domestically prior to October 1, mitted during the applicable transition 1999, if it— period for packaging, hazard commu (i) Conforms to the requirements of nication and handling provisions, as this subchapter in effect on September follows: 30, 1996; (i) If either shipping names or identi (ii) Was filled with a hazardous mate fication numbers are identical, a ship rial prior to October 1, 1996; and ping paper may display the old ship (iii) Is not emptied and refilled on or ping description even if the package is after October 1, 1996. marked and labeled under the new (b) [Reserved] shipping description; (c) Non-specification fiber drums. A (ii) If either shipping names or iden non-specification fiber drum with a re tification numbers are identical, a movable head is authorized for a liquid shipping paper may display the new hazardous material in Packing Group shipping description; and III that is not poisonous by inhalation (iii) Either old or new placards may for which the packaging was author be used regardless of whether old or ized under the requirements of part 172 new shipping descriptions, labels, and or part 173 of this subchapter in effect package markings are used. on September 30, 1991. This authoriza (3) [Reserved] tion expires on the date on which funds (4) Until January 1, 2010, a hazardous are authorized to be appropriated to material may be transported in an IM, carry out chapter 51 of title 49, United IMO, or DOT Specification 51 portable States Code (related to transportation tank in accordance with the T Codes of hazardous materials), for fiscal years (Special Provisions) assigned to a haz beginning after September 30, 1997. In ardous material in Column (7) of the formation concerning this funding au §172.101 Table in effect on September thorization date may be obtained by 30, 2001. contacting the Office of the Associate (5) Proper shipping names that in Administrator. cluded the word “inhibited” prior to
112 Pipeline and Hazardous Materials Safety Admin., DOT § 171.15 the June 21, 2001 final rule in effect on Subpart B—Incident Reporting, October 1, 2001 are authorized on pack Notification, BOE Approvals agings and shipping papers in place of and Authorization the word ‘stabilized’ until October 1, 2007. Proper shipping names that in § 171.15 Immediate notice of certain cluded the word “compressed” prior to hazardous materials incidents. the final rule published on July 31, 2003 (a) General. As soon as practical but and effective on October 1, 2003 may no later than 12 hours after the occur continue to be shown on packagings rence of any incident described in para and shipping papers until October 1, graph (b) of this section, each person in 2007. physical possession of the hazardous (6) Section 172.202(a)(7) requires the material must provide notice to the number and types of packages to be in National Response Center (NRC) by dicated on shipping papers. Until Octo telephone at 800—424—8802 (toll free) or ber 1, 2007, a person may elect to com 202—267—2675 (toll call) or online at ply with the requirements for the num http://www.nrc.uscg.mil. Notice involv ber and type of packages in effect on ing an infectious substance (etiologic September 30, 2003. agent) may be given to the Director, (e) The shipping description se Centers for Disease Control and Pre quences in effect on December 31, 2006, vention (CDC), U.S. Public Health may be used until January 1, 2013. Service, Atlanta, GA, 800—232—0124 (toll free), in place of notice to the (f) Except for transportation by high NRC. Each notice must include the following way, a Division 5.2 label and a Division information; 5.2 placard conforming to the specifica (1) Name of reporter; tions in 172.427 and 172.552, respec § (2) Name and address of person rep tively, of this subchapter in effect on resented by reporter; December 31, 2006, may be used until (3) Phone number where reporter can January 1, 2011. For transportation by be contacted; highway, a Division 5.2 placard con (4) Date, time, and location of inci forming to the specifications in § 172.552 dent; of this subchapter in effect on Decem (5) The extent of injury, if any; ber 31, 2006 may be used until January (6) Class or division, proper shipping 1, 2014. name, and quantity of hazardous mate (g) The Class 3 and Division 6.1 classi rials involved, if such information is fication criteria and packing group as available; and signments in effect on December 31, (7) Type of incident and nature of 2006, may be used until January 1, 2012. hazardous material involvement and (h) The proper shipping name “Gas whether a continuing danger to life ex ohol gasoline mixed with ethyl alcohol, ists at the scene. with not more than 20 percent alcohol’ in (b) Reportable incident. A telephone effect on January 28, 2008, may con report is required whenever any of the tinue to be used until October 1, 2010. following occurs during the course of Effective October 1, 2010, the new prop transportation in commerce (including er shipping name “Ethanol and gaso loading, unloading, and temporary line mixture or ethanol and motor spir storage); it mixture or ethanol and petrol mix (1) As a direct result of a hazardous ture,” and the revised proper shipping material— name “Gasohol gasoline mixed with (1) A person is killed; ethyl alcohol, with not more than 10% al (ii) A person receives an injury re quiring cohol” must be used, as appropriate. admittance to a hospital; (iii) The general public is evacuated lAmdt. 171—131, 59 FR 67406, Dec. 29, 19941 for one hour or more; EDITORIAL NOTE; For FEDERAL REGISTER ci (iv) A major transportation artery or tations affecting §171.14, see the List of CFR facility is closed or shut down for one Sections Affected which appears in the Find hour or more; or ing Aids section of the printed volume and (v) The operational flight pattern or on GPO Access. routine of an aircraft is altered;
113 § 171.16 49 CFR Ch. 1(10—1—10 Edition)
(2) Fire, breakage, spillage, or sus (I) Any of the circumstances set pected radioactive contamination oc forth in §171.15(b); curs involving a radioactive material (2) An unintentional release of a haz (see also § 176.48 of this subchapter); ardous material or the discharge of any (3) Fire, breakage, spillage, or sus quantity of hazardous waste; pected contamination occurs involving (3) A specification cargo tank with a an infectious substance other than a capacity of 1,000 gallons or greater con regulated medical waste; taining any hazardous material suffers (4) A release of a marine pollutant structural damage to the lading reten occurs in a quantity exceeding 450 L tion system or damage that requires (119 gallons) for a liquid or 400 kg (882 repair to a system intended to protect pounds) for a solid; the lading retention system, even if (5) A situation exists of such a nature there is no release of hazardous mate (e.g., a continuing danger to life exists rial; at the scene of the incident) that, in (4) An undeclared hazardous material the judgment of the person in posses is discovered; or sion of the hazardous material, it (5) A fire, violent rupture, explosion should be reported to the NRC even or dangerous evolution of heat (i.e., an though it does not meet the criteria of amount of heat sufficient to be dan paragraphs (b)(l), (2), (3) or (4) of this gerous to packaging or personal safety section; or to include charring of packaging, melt (6) During transportation by aircraft, ing of packaging, scorching of pack violent rupture, a fire, explosion or aging, or other evidence) occurs as a di dangerous evolution of heat (i.e., an rect result of a battery or battery-pow amount of heat sufficient to be dan ered device. gerous to packaging or personal safety (b) Providing and retaining copies of to include charring of packaging, melt the report. Each person reporting under ing of packaging, scorching of pack this section must— aging, or other evidence) occurs as a di rect result of a battery or battery-pow (1) Submit a written Hazardous Mate ered device. rials Incident Report to the Informa (c) Written report. Each person mak tion Systems Manager, PHH-63, Pipe ing a report under this section must line and Hazardous Materials Safety also make the report required by Administration, Department of Trans §171.16 of this subpart. portation, Washington, DC 20590-0001, or an electronic Hazardous Material In NOTE TO §171.15: Under 40 CFR 302.6, EPA cident Report to the Information Sys requires persons in charge of facilities (in tem Manager, DHM-63, Research and cluding transport vehicles, vessels, and air Special Programs Administration, De craft) to report any release of a hazardous substance in a quantity equal to or greater partment of Transportation, Wash than its reportable quantity, as soon as that ington, DC 20590—0001 at http:// person has knowledge of the release, to hazmat.dot.gov; DOT’s National Response Center at (toll (2) For an incident involving trans free) 800—424-8802 or (toll) 202—267—2675. portation by aircraft, submit a written [68 FR 67759, Dec. 3, 2003, as amended at 72 or electronic copy of the Hazardous FR 55684, Oct. 1, 2007; 74 FR 2233, Jan. 14, 2009; Materials Incident Report to the FAA 74 FR 53186, Oct. 16, 2009] Security Field Office nearest the loca tion of the incident; and § 171.16 Detailed hazardous materials (3) Retain a written or electronic incident reports. copy of the Hazardous Materials Inci (a) General. Each person in physical dent Report for a period of two years at possession of a hazardous material at the reporting person’s principal place the time that any of the following inci of business. If the written or electronic dents occurs during transportation (in Hazardous Materials Incident Report is cluding loading, unloading, and tem maintained at other than the reporting porary storage) must submit a Haz person’s principal place of business, the ardous Materials Incident Report on report must be made available at the DOT Form F 5800.1 (01/2004) within 30 reporting person’s principal place of days of discovery of the incident: business within 24 hours of a request
114 Pipeline and Hazardous Materials Safety Admin., DOT § 171.21 for the report by an authorized rep (3) An undeclared hazardous material resentative or special agent of the De discovered in an air passenger’s partment of Transportation. checked or carry-on baggage during the (c) Updating the incident report. A airport screening process. (For discrep Hazardous Materials Incident Report ancy reporting by carriers, see §175.31 must be updated within one year of the of this subchapter.) date of occurrence of the incident whenever: [68 FR 67759, Dec. 3, 2003; 69 FR 30119, May 26, 2004, as amended at 70 FR 56091, Sept. 23. (1) A death results from injury 2005; 74 FR 2233, Jan. 14, 2009] caused by a hazardous material; (2) There was a misidentification of § 171.17—171.18 [Reservedl the hazardous material or package in formation on a prior incident report; § 171.19 Approvals or authorizations (3) Damage, loss or related cost that issued by the Bureau of Explosives. was not known when the initial inci Effective December 31, 1998, approv dent report was filed becomes known; als or authorizations issued by the Bu or reau of Explosives (BOE), other than (4) Damage, loss, or related cost those issued under part 179 of this sub changes by $25,000 or more, or 10% of chapter, are no longer valid. the prior total estimate, whichever is [63 FR greater. 37459. July 10, 1998] (d) Exceptions. Unless a telephone re § 171.20 Submission of Examination port is required under the provisions of Reports. § 171.15 of this part, the requirements of (a) When it is required in this sub paragraphs (a), (b), and (c) of this sec chapter that the issuance of an tion do not apply to the following inci ap proval dents: by the Associate Administrator be based on an examination by the Bu (1) A release of a minimal amount of reau of Explosives (or any other material from— test facility recognized by PHMSA), it is (1) A vent, for materials for which the responsibility of the applicant to venting is authorized; submit the results of the examination (ii) The routine operation of a seal, to the Associate Administrator. pump, compressor, or valve; or (b) Applications for approval sub (iii) Connection or disconnection of mitted under paragraph (a) of this sec loading or unloading lines, provided tion, must be submitted to the Asso that the release does not result in ciate Administrator for Hazardous Ma property damage. terials Safety, Pipeline and Hazardous (2) An unintentional release of haz Materials Safety Administration, ardous material when: Washington, DC 20590-0001. (1) The material is properly classed (c) Any applicant for an approval ag as— grieved by an action taken by the As (A) ORM-D; or sociate Administrator, under this sub (B) a Packing Group III material in part may file an appeal with the Ad Class or Division 3, 4, 5, 6.1, 8, or 9; ministrator, PHMSA within 30 days of (ii) Each package has a capacity of service of notification of a denial. less than 20 liters (5.2 gallons) for liq uids or less than 30 kg (66 pounds) for [Amdt. 171—54, 45 FR 32692, May 19, 1980, as solids; amended by Amdt. 171-66, 47 FR 43064, Sept. 30, 1982; Amdt. 171—109, 55 FR 39978, Oct. 1, (iii) The total aggregate release is 1990; Amdt. 171—111, 56 FR 66162, Dec. 20, 1991; less than 20 liters (5.2 gallons) for liq 66 FR 45378, Aug. 28, 2001] uids or less than 30 kg (66 pounds) for solids; and § 171.21 Assistance in investigations (iv) The material is not— and special studies. (A) Offered for transportation or (a) A shipper, carrier, package owner, transported by aircraft, package manufacturer or certifier, re (B) A hazardous waste, or pair facility, or person reporting an in (C) An undeclared hazardous mate cident under the provisions of § 171.16 rial. must: 115 § 171.22 49 CFR Ch. 1(10—1—10 Edition)
(1) Make all records and information cordance with the international stand pertaining to the incident available to ards and regulations authorized in an authorized representative or special paragraph (a) of this section— agent of the Department of Transpor (1) Is subject to the requirements of tation upon request; and the applicable international standard (2) Give an authorized representative or regulation and must be offered for or special agent of the Department of transportation or transported in con Transportation reasonable assistance formance with the applicable standard in the investigation of the incident. or regulation; and (b) If an authorized representative or (2) Must conform to all applicable re special agent of the Department of quirements of this subpart. Transportation makes an inquiry of a person required to complete an inci (c) Materials excepted from regulation dent report in connection with a study under international standards and regu of incidents, the person shall: lations. A material designated as a haz (1) Respond to the inquiry within 30 ardous material under this subchapter, days after its receipt or within such but excepted from or not subject to the other time as the inquiry may specify; international transport standards and and regulations authorized in paragraph (a) (2) Provide true and complete an of this section (e.g., paragraph 1.16 of swers to any questions included in the the Transport Canada TDG Regula inquiry. tions excepts from regulation quan tities of hazardous materials less than [68 FR 67760, Dec. 3, 2003] or equal to 500 kg gross transported by rail) must be transported in accordance Subpart C—Authorization and Re with all applicable requirements of this quirements for the Use of subchapter. International Transport Stand (d) Materials not regulated under this ards and Regulations subchapter. Materials not designated as hazardous materials under this sub SOURCE: 72 FR 25172, May 3, 2007. unless chapter but regulated by an inter otherwise noted. national transport standard or regula tion authorized in paragraph (a) of this § 171.22 Authorization and conditions section may be offered for transpor for the use of international stand tation and transported in the United ards and regulations. States in full compliance (i.e., pack (a) Authorized international standards aged, marked, labeled, classed, de and regulations. This subpart author scribed, stowed, segregated, secured) izes, with certain conditions and limi with the applicable international tations, the offering for transportation transport standard or regulation. and the transportation in commerce of (e) Forbidden materials. No person hazardous materials in accordance may offer for transportation or trans with the International Civil Aviation port a hazardous material that is a for Organization’s Technical Instructions bidden material or package as des for the Safe Transport of Dangerous ignated in— Goods by Air (ICAO Technical Instruc (1) Section 173.21 of this subchapter; tions), the International Maritime §172.101 Dangerous Goods Code (IMDG Code), (2) Column (3) of the Table of Transport Canada’s Transportation of this subchapter; Dangerous Goods Regulations (Trans (3) Column (9A) of the § 172.101 Table port Canada TDG Regulations), and the of this subchapter when offered for International Atomic Energy Agency transportation or transported on pas Regulations for the Safe Transport of senger aircraft or passenger railcar; or Radioactive Material (IAEA Regula (4) Column (9B) of the §172.101 Table tions) (IBR, see § 171.7), of this subchapter when offered for (b) Limitations on the use of inter transportation or transported by cargo national standards and regulations. A aircraft. hazardous material that is offered for (I) Complete information and certifi transportation or transported in ac cation. (1) Except for shipments into
116 Pipeline and Hazardous Materials Safety Admin., DOT § 171.23 the United States from Canada con (3) The security requirements in sub forming to § 171.12, each person import part I of part 172 of this subchapter; ing a hazardous material into the (4) The incident reporting require United States must provide the for ments in §l7l.l5 and 171.16 of this part warding agent at the place of entry for incidents occurring within the ju into the United States timely and com risdiction of the United States includ plete written information as to the re ing on board vessels in the navigable quirements of this subchapter applica waters of the United States and aboard ble to the particular shipment. aircraft of United States registry any (2) After May 4, 2009, the shipper, di where in air commerce; rectly or through the forwarding agent (5) For export shipments, the general at the place of entry, must provide the packaging requirements in § 173.24 and initial U.S. carrier with the shipper’s 173.24a of this subchapter; certification required by § 172.204 of (6) For export shipments, the require this subchapter, unless the shipment is ments for the reuse, reconditioning, otherwise excepted from the certifi and remanufacture of packagings in cation requirement. Except for ship § 173.28 of this subchapter; and ments for which the certification re (7) The registration requirements in quirement does not apply, a carrier subpart C of part 107 of this chapter. may not accept a hazardous material [72 FR 25172, May 3, 2007, as amended at 72 for transportation unless provided a FR 55091 Sept. 28, 2007; 74 FR 53186, Oct. 16, shipper’s certification. 2009] (3) All shipping paper information and package markings required in ac § 171.23 Requirements for specific ma cordance with this subchapter must be terials and packagings transported under the ICAO in English. The use of shipping Technical Instruc papers tions, IMDG Code, Transport Can. and a package marked with both ada TDG Regulations, or the IAEA English and a language other than Regulations. English, in order to dually comply with All shipments offered for transpor this subchapter and the regulations of tation or transported in the United a foreign entity, is permitted under States under this subchapter. the ICAO Technical In structions, IMDG Code, Transport Can (4) Each person who provides for ada TDG Regulations, or the IAEA transportation or receives for transpor Regulations (IBR, see § 171.7) must con tation (see § 174.24, 175.30, 176.24 and form to the requirements of this sec 177.817 of this subchapter) a shipping tion, as applicable. paper must retain a copy of the ship (a) Conditions and requirements for cyl ping paper or an electronic image inders—(l) Except as provided in this thereof that is accessible at or through paragraph, a filled cylinder (pressure its principal place of business in ac receptacle) manufactured to other than cordance with § 172.201(e) of this part. a DOT specification or a UN standard (g) Additional requirements for the use in accordance with part 178 of this sub of international standards and regula chapter, or a DOT exemption or special tions. All shipments offered for trans permit cylinder or a cylinder used as a portation or transported in the United fire extinguisher in conformance with States in accordance with this subpart § 173.309(a) of this subchapter, may not must conform to the following require be transported to, from, or within the ments of this subchapter, as applicable: United States. (1) The emergency response informa (2) Cylinders (including UN pressure tion requirements in subpart G of part receptacles) transported to, from, or 172 of this subchapter; within the United States must conform (2) The training requirements in sub to the applicable requirements of this part H of part 172 of this subchapter, subchapter. Unless otherwise excepted including function-specific training in in this subchapter, a cylinder must not the use of the international transport be transported unless— standards and regulations authorized (i) The cylinder is manufactured, in in paragraph (a) of this section, as ap spected and tested in accordance with a plicable; DOT specification or a UN standard
117 § 171.23 49 CFR Ch. I (10—1—10 Edition) prescribed in part 178 of this sub of this subchapter, or a cylinder manu chapter, except that cylinders not con factured to other than a UN standard, forming to these requirements must DOT specification, exemption or spe meet the requirements in paragraphs cial permit, may be filled with a gas in (a) (3), (a) (4) or (a) (5) of this section; the United States and offered for trans (ii) The cylinder is equipped with a portation and transported for export or pressure relief device in accordance alternatively, for use on board a vessel, with §173.301(f) of this subchapter and if the following conditions are met: conforms to the applicable require (i) The cylinder has been requalified ments in part 173 of this subchapter for and marked with the month and year the hazardous material involved; of requalification in accordance with (iii) The openings on an aluminum subpart C of part 180 of this subchapter, cylinder in oxygen service conform to or has been requalified as authorized the requirements of this paragraph, ex by the Associate Administrator; cept when the cylinder is used for air (ii) In addition to other requirements craft parts or used aboard an aircraft of this subchapter, the maximum fill in accordance with the applicable air ing ensity, service pressure, and pres worthiness requirements and operating sure relief device for each cylinder con regulations. An aluminum DOT speci form to the requirements of this part fication cylinder must have an opening for the gas involved; and configured with straight (parallel) (iii) The bill of lading or other ship threads. A UN pressure receptacle may ping paper identifies the cylinder and have straight (parallel) or tapered includes the following certification: threads provided the UN pressure re “This cylinder has (These cylinders ceptacle is marked with the thread have) been qualified, as required, and type, e.g. “17E, 25E, 18P, or 25P” and filled in accordance with the DOT re fitted with the properly marked valve; quirements for and export.” (iv) A UN pressure receptacle is (5) Cylinders not equipped with pres marked with “USA” as a country of sure relief devices: A DOT specification approval in conformance with §5178.69 or a UN cylinder manufactured, in and 178.70 of this subchapter. spected, tested and marked in accord (3) Importation of cylinders for dis ance with part 178 of this subchapter charge within a single port area: A cyl and otherwise conforms to the require inder manufactured to other than a ments of part 173 for the gas involved, DOT specification or UN standard in except that the cylinder is not accordance with part 178 of this sub equipped with a pressure relief device chapter and certified as being in con may be filled with a gas and offered for formance with the transportation regu transportation and transported for ex lations of another country may be au port if the following conditions are thorized, upon written request to and met: approval by the Associate Adminis (i) Each DOT specification cylinder trator, for transportation within a sin or UN pressure receptacle must be gle port area, provided— plainly and durably marked “For Ex (i) The cylinder is transported in a port Only”; closed freight container; (ii) The shipping paper must carry (ii) The cylinder is certified by the the following certification: “This cyl importer to provide a level of safety at inder has (These cylinders have) been least equivalent to that required by the retested and refilled in accordance regulations in this subchapter for a with the DOT requirements for ex comparable DOT specification or UN port.”; and cylinder; and (iii) The emergency response infor (iii) The cylinder is not refilled for mation provided with the shipment and export unless in compliance with para available from the emergency response graph (a) (4) of this section. telephone contact person must indicate (4) Filling of cylinders for export or that the pressure receptacles are not for use on board a vessel: A cylinder fitted with pressure relief devices and not manufactured, inspected, tested provide appropriate guidance for expo and marked in accordance with part 178 sure to fire.
118 Pipeline and Hazardous Materials Safety Admin., DOT § 171.23 (b) Conditions and requirements specific conform to the shipping paper require to certain materials—(1) Aerosols. Except ments in § 172.203(c) of this subchapter for a limited quantity of a compressed and the marking requirements in gas in a container of not more than 4 § 172.324 of this subchapter: fluid ounces capacity meeting the re (i) The proper shipping name must quirements in §l73.306(a)(l) of this sub identify the hazardous substance by chapter, the proper shipping name name, or the name of the substance “Aerosol,” UN1950, may be used only must be entered in parentheses in asso for a non-refillable receptacle con ciation with the basic description and taining a gas compressed, liquefied, or marked on the package in association dissolved under pressure the sole pur with the proper shipping name. If the pose of which is to expel a nonpoi hazardous substance meets the defini sonous (other than Division 6.1, Pack tion for a hazardous waste, the waste ing Group III material) liquid, paste, or code (for example, DOOl), may be used powder and fitted with a self-closing to identify the hazardous substance; release device (see §171.8). In addition, (ii) The shipping paper and the pack an aerosol must be in a metal pack age markings must identify at least aging when the packaging exceeds 7.22 two hazardous substances with the low cubic inches. est reportable quantities (RQs) when (2) Air bag inflator, air bag module and the material contains two or more haz seat-belt pretensioner. For each approved ardous substances; and air bag inflator, air bag module and (iii) The letters “RQ” must be en seat-belt pretensioner, the shipping tered on the shipping paper either be paper description must conform to the fore or after the basic description, and requirements in §173.166(c) of this sub marked on the package in association chapter. with the proper shipping name for each (1) The EX number or product code hazardous substance listed. must be included in association with (6) Hazardous wastes. A material the basic shipping description. When a meeting the definition of a hazardous product code is used, it must be trace waste (see § 171.8) must conform to the able to the specific EX number as following: signed to the inflator, module or seat- (i) The shipping paper and the pack belt pretensioner by the Associate Ad age markings must include the word ministrator. The EX number or prod “Waste” immediately preceding the uct code is not required to be marked proper shipping name; on the outside package. (ii) The shipping paper must be re (ii) The proper shipping name “Arti tained by the shipper and by each car cles, pyrotechnic for technical purposes, rier for three years after the material UN0431” must be used for all air bag in is accepted by the initial carrier (see flators, air bag modules, and seat-belt § 172.205(e) (5)); and pretensioners meeting the criteria for a (iii) A hazardous waste manifest Division l.4G material. must be completed in accordance with (3) Chemical oxygen generators. Chem § 172.205 of this subchapter. ical oxygen generators must be ap (7) Marine pollutants. Except for ma proved, classed, described, packaged, rine pollutants (see §171.8) transported and transported in accordance with the in accordance with the IMDG Code, requirements of this subchapter. marine pollutants transported in bulk (4) Class 1 (explosive) materials. Prior packages must meet the shipping paper to being transported, Class 1 (explo requirements in § 172.203(1) of this sub sive) materials must be approved by chapter and the package marking re the Associate Administrator in accord quirements in § 172.322 of this sub ance with § 173.56 of this subchapter. chapter. Each package containing a Class 1 (ex (8) Organic peroxides. Organic perox plosive) material must conform to the ides not identified by technical name marking requirements in § 172.320 of in the Organic Peroxide Table in this subchapter. § 173.225(b) of this subchapter must be (5) Hazardous substances. A material approved by the Associate Adminis meeting the definition of a hazardous trator in accordance with §173.128(d) of substance as defined in § 171.8, must this subchapter.
119 § 171.23 49 CFR Ch. I (10—1—10 Edition)
(9) Poisonous materials, Division 6.1. vehicle or freight container, a label or Division 6.1 hazardous materials trans placard conforming to the TDG Regula ported as limited quantities are not ex tions specifications for a “Class 2.3” or cepted from labeling (see §173.153(b)). “Class 6.1” label or placard may be sub (10) Poisonous by inhalation materials. stituted for the POISON GAS or POI A material poisonous by inhalation SON INHALATION HAZARD label or (see §171.8) must conform to the fol placard, as appropriate. The transport lowing requirements: vehicle or freight container must be (i) The words “Poison-Inhalation marked with the identification num Hazard” or “Toxic-Inhalation Hazard” bers for the hazardous material, re and the words “Zone A,” “Zone B,” gardless of the total quantity con “Zone C,” or “Zone D” for gases, or tained in the transport vehicle or “Zone A” or “Zone B” for liquids, as freight container, in the manner speci appropriate, must be entered on the fied in § 172.313(c) of this subchapter shipping paper immediately following and placarded as required by subpart F the basic shipping description. The of part 172 of this subchapter. While in word “Poison” or “Toxic” or the transportation in the United States, phrase “Poison-Inhalation Hazard” or the transport vehicle or freight con “Toxic-Inhalation Hazard” need not be tainer may also be placarded in accord repeated if it otherwise appears in the ance with the appropriate Transport shipping description; Canada TDG Regulations in addition to (ii) The material must be packaged being placarded with the POISON GAS in accordance with the requirements of or POISON INHALATION HAZARD this subchapter; placards. (iii) The package must be marked in (11) Class 7 (radioactive) materials. (i) accordance with § 172.313 of this sub Highway route controlled quantities chapter; and (see § 173.403 of this subchapter) must (iv) Except as provided in subpara be shipped in accordance with graph (B) of this paragraph (b)(10)(iv) §172.203(d)(4) and (d)(lO); 172.507, and and for a package containing anhy 173.22(c) of this subchapter; drous ammonia prepared in accordance (ii) For fissile materials and Type B, with the Transport Canada TDG Regu Type B(U), and Type B(M) packagings, lations, the package must be labeled or the competent authority certification placarded with POISON INHALATION and any necessary revalidation must be HAZARD or POISON GAS, as appro obtained from the appropriate com priate, in accordance with Subparts F petent authorities as specified in and F of part 172 of this subchapter. § 173.471, 173.472, and 173.473 of this sub (A) For a package transported in ac chapter, and all requirements of the cordance with the IMDG Code in a certificates and revalidations must be closed transport vehicle or freight con met; tainer, a label or placard conforming to (iii) Type A package contents are the IMDG Code specifications for a limited in accordance with § 173.431 of “Class 2.3” or “Class 6.1” label or this subchapter; placard may be substituted for the (iv) The country of origin for the POISON GAS or POISON INHALATION shipment must have adopted the edi HAZARD label or placard, as appro tion of TS-R-I of the IAEA Regula priate. The transport vehicle or freight tions referenced in § 171.7; container must be marked with the (v) The shipment must conform to identification numbers for the haz the requirements of § 173.448, when ap ardous material, regardless of the total plicable; quantity contained in the transport ve (vi) The definition for “radioactive hicle or freight container, in the man material” in § 173.403 of this subchapter ner specified in § 172.313(c) of this sub must be applied to radioactive mate chapter and placarded as required by rials transported under the provisions subpart F of part 172 of this sub of this subpart; chapter. (vii) Except for limited quantities, (B) For a package transported in ac the shipment must conform to the re cordance with the Transport Canada quirements of § 172.204(c) (4) of this sub TDG Regulations in a closed transport chapter; and
120 Pipeline and Hazardous Materials Safety Admin., DOT § 171.24
(viii) Excepted packages of radio rials offered for transportation or active material, instruments or arti transported in accordance with the cles, or articles containing natural ura ICAO Technical Instructions must con nium or thorium must conform to the form to the following specific condi requirements of § 173.421, 173.424, or tions and requirements, as applicable; 173.426 of this subchapter, as appro (1) Batteries—(i) Nonspillable wet elec priate. tric storage batteries. Nonspillable wet (12) Self-reactive materials. Self-reac electric storage batteries are not sub tive materials not identified by tech ject to the requirements of this sub nical name in the Self-reactive Mate chapter provided— rials Table in § 173.224(b) of this sub (A) The battery meets the conditions chapter must be approved by the Asso specified in Special Provision 67 of the ciate Administrator in accordance with ICAO Technical Instructions; § 173.124(a) (2) (iii) of this subchapter. (B) The battery, its outer packaging, [72 FR 25172, May 3, 2007, as amended at 72 and any overpack are plainly and dura FR 55684, Oct. 1, 2007; 73 FR 57004, Oct. 1, 2008] bly marked “NONSPILLABLE” or “NONSPILLABLE BATTERY”; and § 171.24 Additional requirements for the use of the ICAO Technical In (C) The batteries or battery assem structions. blies are offered for transportation or transported in a manner that prevents (a) A hazardous material that is of short circuiting or forced discharge, in fered for transportation or transported cluding, but not limited to, protection within the United States by aircraft, of exposed terminals. and by motor vehicle or rail either be Primary fore or after being transported by air (ii) lithium batteries and cells. craft in accordance with the ICAO Primary lithium batteries and cells are forbidden Technical Instructions (IBR, see for transportation aboard §171.7), as authorized in paragraph (a) passenger-carrying aircraft. Equipment ofl7l.22, must conform to the require containing or packed with primary ments in §171.22, as applicable, and this lithium batteries or cells are forbidden section. for transport aboard passenger-car (b) Any person who offers for trans rying aircraft except as provided in portation or transports a hazardous §172.102, Special Provision AlOl of this material in accordance with the ICAO subchapter. When transported aboard Technical Instructions must comply cargo-only aircraft, packages con with the following additional condi taining primary lithium batteries and tions and requirements; cells transported in accordance with (1) All applicable requirements in Special Provision A45 of the ICAO parts 171 and 175 of this subchapter Technical Instructions must be marked (also see 14 CFR 121.135, 121.401, “PRIMARY LITHIUM BATTERIES— l21.433a, 135.323, 135.327 and 135.333); FORBIDDEN FOR TRANSPORT (2) The quantity limits prescribed in ABOARD PASSENGER AIRCRAFT” or the ICAO Technical Instructions for “LITHIUM METAL BATTERIES— transportation by passenger-carrying FORBIDDEN FOR TRANSPORT or cargo aircraft, as applicable; ABOARD PASSENGER AIRCRAFT.” (3) The conditions or requirements of This marking is not required on pack a United States variation, when speci ages that contain 5 kg (11 pounds) net fled in the ICAO Technical Instruc weight or less of primary lithium bat tions. teries or cells that are contained in or (c) Highway transportation. For trans packed with equipment. portation by highway prior to or after (iii) Prototype lithium batteries and transportation by aircraft, a shipment cells. Prototype lithium batteries and must conform to the applicable re cells are forbidden for transport aboard quirements of part 177 of this sub passenger aircraft and must be ap chapter, and the motor vehicle must be proved by the Associate Administrator placarded in accordance with subpart F prior to transportation aboard cargo of part 172. aircraft, in accordance with the re (d) Conditions and requirements specific quirements of Special Provision A55 in to certain materials. Hazardous mate- § 172.102 of this subchapter. 121 § 171.25 49 CFR Ch. 1(10—1—10 Edition)
(2) A package containing Oxygen, marked “PRIMARY LITHIUM BAT compressed, or any of the following TERIES—FORBIDDEN FOR TRANS oxidizing gases must be packaged as re PORT ABOARD PASSENGER AIR quired by Parts 173 and 178 of this sub CRAFT” or “LITHIUM METAL BAT chapter: carbon dioxide and oxygen TERIES—FORBIDDEN FOR TRANS mixtures, compressed; compressed gas, PORT ABOARD PASSENGER AIR oxidizing, n.o.s.; liquefied gas, oxi CRAFT.” This marking is not required dizing, n.o.s.; nitrogen trifluoride; and on packages that contain 5 kg (11 nitrous oxide. pounds) net weight or less of primary [72 FR 25172, May 3, 2007, as amended at 72 lithium batteries and cells that are FR 44847, Aug. 9, 2007; 72 FR 55097, Sept. 28, contained in or packed with equip 2007] ment. (c) Conditions and requirements for § 171.25 Additional requirements for bulk packagings. Except for IBCs and the use of the IMDG Code. UN portable tanks used for the trans (a) A hazardous material may be of portation of liquids or solids, bulk fered for transportation or transported packagings must conform to the re to, from or within the United States by quirements of this subchapter. Addi vessel, and by motor carrier and rail in tionally, the following requirements accordance with the IMDG Code (IBR, apply: see §171.7), as authorized in §171.22, (1) UN portable tanks must conform provided all or part of the movement is to the requirements in Special Provi by vessel. Such shipments must con sions TP37, TP38, TP44 and TP45 when form to the requirements in §171.22, as applicable, and any applicable bulk applicable, and this section. special provisions assigned to the haz (b) Any person who offers for trans ardous material in the Hazardous Ma portation or transports a hazardous terials Table in §172.101 of this sub material in accordance with the IMDG chapter; Code must conform to the following ad (2) IMO Type 5 portable tanks must ditional conditions and requirements: conform to DOT Specification 51 or UN (1) Unless otherwise excepted, a ship portable tank requirements, unless spe ment must conform to the require cifically authorized in this subchapter ments in part 176 of this subchapter. or approved by the Associate Adminis For transportation by rail or highway trator; prior to or subsequent to transpor (3) Except as specified in this sub tation by vessel, a shipment must con part, for a material poisonous (toxic) form to the applicable requirements of by inhalation, the T Codes specified in parts 174 and 177 respectively, of this Column 13 of the Dangerous Goods List subchapter, and the motor vehicle or in the IMDG Code may be applied to rail car must be placarded in accord the transportation of those materials ance with subpart F of part 172 of this in IM, IMO and DOT Specification 51 subchapter. When a hazardous material portable tanks, when these portable regulated by this subchapter for trans tanks are authorized in accordance portation by highway is transported by with the requirements of this sub motor vehicle on a public highway or chapter; and by rail under the provisions of subpart (4) No person may offer an TM or UN C of part 171, the segregation require portable tank containing liquid haz ments of Part 7, Chapter 7.2 of the ardous materials of Class 3, PG I or II, IMDG Code are authorized. or PG III with a flash point less than (2) For transportation by vessel, the 100 °F (38 °C); Division 5.1, PG I or II; or stowage and segregation requirements Division 6.1, PG I or II, for unloading in Part 7 of the IMDG Code may be sub while it remains on a transport vehicle stituted for the stowage and segrega with the motive power unit attached, tion requirements in part 176 of this unless it conforms to the requirements subchapter. in § 177.834(o) of this subchapter. (3) Packages containing primary lith (5) Effective February 13, 2009, port ium batteries and cells that are trans able tanks, cargo tanks, and tank cars ported in accordance with Special Pro containing cryogenic liquids must be vision 188 of the IMDG Code must be stowed “on deck” regardless of the 122 Pipeline and Hazardous Materials Safety Admin., DOT Pt. 172
stowage authorized in the IMDG Code. genic liquids may be stowed one deck Cargo tanks or tank cars containing below the weather deck when trans cryogenic liquids may be stowed one ported on a trailership or trainship deck below the weather deck when that is unable to provide “on deck” transported on a trailership or stowage because of the vessel’s design. trainship that is unable to provide ‘on Tank cars must be Class DOT-1l3 or deck” stowage because of the vessel’s AAR-204W tank cars. Portable tanks, design. Tank cars must be Class DOT- cargo tanks, and tank cars containing 113 or AAR—204W tank cars. Portable cryogenic liquids that are in transpor tanks, cargo tanks, and tank cars con tation and stowed below deck on or be taining cryogenic liquids that are in fore February 13, 2009, may continue to transportation and stowed below deck be transported to their final destina on or before February 13, 2009 may con tion. tinue to be transported to their final [72 FR 25172, May destination. 3, 2007, as amended at 72 FR 44847, Aug. 9, 2007; 73 FR 57004, Oct. 1, (d) Use of IMDG Code in port areas. (1) 2008; 74 FR 2233, Jan. 14, 20091 Except for Division 1.1, 1.2, and Class 7 materials, a hazardous material being § 171.26 Additional requirements for imported into or exported from the the use of the IAEA Regulations. United States or passing through the A Class 7 (radioactive) material being United States in the course of being imported into or exported from the shipped between locations outside the United States or passing through the United States may be offered and ac United States in the course of being cepted for transportation and trans shipped between places outside the ported by motor vehicle within a single United States may be offered for trans port area, including contiguous har portation or transported in accordance bors, when packaged, marked, classed, with the IAEA Regulations (IBR, see labeled, stowed and segregated in ac §171.7) as authorized in paragraph (a) of cordance with the IMDG Code, offered §171.22, provided the requirements in and accepted in accordance with the re §171.22, as applicable, are met. quirements of subparts C and F of part 172 of this subchapter pertaining to PART 172—HAZARDOUS MATERIALS shipping papers and placarding, and TABLE, otherwise conforms to the applicable SPECIAL PROVISIONS, requirements of part 176 of this sub HAZARDOUS MATERIALS COM chapter. MUNICATIONS, EMERGENCY RE (2) The requirement in §172.201(d) of SPONSE INFORMATION, TRAIN this subchapter for an emergency tele ING REQUIREMENTS, AND SECU phone number does not apply to ship RITY PLANS ments made in accordance with the IMDG Code if the hazardous material is Subpart A—General not offloaded from the vessel, or is off’loaded between ocean vessels at a Sec. 172.1 Purpose and scope. U.S. port facility without being trans 172.3 Applicability. ported by public highway. (3) Notwithstanding § 171.25(d)(l), ex Subpart B—Table of Hazardous Materials cept for portable tanks, cargo tanks, and Special Provisions and tank cars transporting cryogenic liquids before February 13, 2009. Effec 172.101 Purpose and use of hazardous mate tive February 13, 2009, portable tanks, rials table. 172.102 Special provisions. cargo tanks, and tank cars containing cryogenic liquids, which are trans Subpart C—Shipping Papers ported by a vessel passing through the United States in the course of being 172.200 Applicability. shipped between locations outside of 172.201 Preparation and retention of ship ping papers. the United States must be stowed “on 172.202 Description of hazardous material on deck” regardless of the stowage au shipping papers. thorized in the IMDG Code. Cargo 172.203 Additional description requirements. tanks or tank cars containing cryo 172.204 Shipper’s certification.
123 INFORMATiON GPO
L iIGfNAL
Pipeline and Hazardous Materials Safety Admin., DOT Pt. 172
stowage authorized in the IMDG Code. genic liquids may be stowed one deck Cargo tanks or tank cars containing below the weather deck when trans cryogenic liquids may be stowed one ported on a trailership or trainship deck below the weather deck when that is unable to provide “on deck” transported on a trailership or stowage because of the vessel’s design. trainship that is unable to provide “on Tank cars must be Class DOT-l13 or deck” stowage because of the vessel’s AAR-204W tank cars. Portable tanks, design. Tank cars must be Class DOT- cargo tanks, and tank cars containing 113 or AAR-204W tank cars. Portable cryogenic liquids that are in transpor tanks, cargo tanks, and tank cars con tation and stowed below deck on or be taining cryogenic liquids that are in fore February 13, 2009, may continue to transportation and stowed below deck be transported to their final destina on or before February 13, 2009 may con tion. tinue to be transported their final to [72 FR 25172, May 3. 2007, as amended at 72 destination. FR 44847, Aug. 9, 2007; 73 FR 57004, Oct. 1, (d) Use of IMDG Code in port areas. (1) 2008; 74 FR 2233, Jan. 14, 20091 Except for Division 1.1, 1.2, and Class 7 materials, a hazardous material being § 171.26 Additional requirements for imported into or exported from the the use of the IAEA Regulations. United States or passing through the A Class 7 (radioactive) material being United States in the course of being imported into or exported from the shipped between locations outside the United States or passing through the United States may be offered and ac United States in the course of being cepted for transportation and trans shipped between places outside the ported by motor vehicle within a single United States may be offered for trans port area, including contiguous har portation or transported in accordance bors, when packaged, marked, classed, with the IAEA Regulations (IBR, see labeled, stowed and segregated in ac § 171.7) as authorized in paragraph (a) of cordance with the IMDG Code, offered § 171.22, provided the requirements in and accepted in accordance with the re § 171.22, as applicable, are met. quirements of subparts C and F of part 172 of this subchapter pertaining to PART 1 72—HAZARDOUS MATERIALS shipping papers and placarding, and TABLE, SPECIAL otherwise conforms to the applicable PROVISIONS, requirements of part 176 of this sub HAZARDOUS MATERIALS COM chapter. MUNICATIONS, EMERGENCY RE (2) The requirement in § 172.201(d) of SPONSE INFORMATION, TRAIN this subchapter for an emergency tele ING REQUIREMENTS, AND SECU phone number does not apply to ship RITY PLANS ments made in accordance with the IMDG Code if the hazardous material is Subpart A—General not offloaded from the vessel, or is offloaded between ocean vessels at a Sec. 172.1 Purpose and scope. U.S. port facility without being trans 172.3 Applicability. ported by public highway. (3) Notwithstanding § 171.25(d)(1), ex Subpart B—Table of Hazardous Materials cept for portable tanks, cargo tanks, and Special Provisions and tank cars transporting cryogenic liquids before February 13, 2009. Effec 172.101 Purpose and use of hazardous mate February 2009, rials table. tive 13, portable tanks, 172.102 Special provisions. cargo tanks, and tank cars containing cryogenic liquids, which are trans Subpart C—Shipping Papers ported by a vessel passing through the United States in the course of being 172.200 Applicability. shipped between locations outside of 172.201 Preparation and retention of ship ping papers. the United States must be stowed “on 172.202 Description of hazardous material on deck” regardless of the stowage au shipping papers. thorized in the IMDG Code. Cargo 172.203 Additional description requirements. tanks or tank cars containing cryo 172.204 Shipper’s certification. 123 Pt. 172 49 CFR Ch. I (10—1—10 Edition)
172.205 Hazardous waste manifest. 172.426 OXIDIZER label. 172.427 ORGANIC PEROXIDE label. Subpart D—Marking 172.429 POISON INHALATION HAZARD label. 172.300 Applicability. 172.430 POISON label. 172.301 General marking requirements for 172.431 [Reserved] non-bulk packagings. 172.432 INFECTIOUS SUBSTANCE label. 172.302 General marking requirements for 172.436 RADIOACTIVE WHITE-I label. bulk packagings. 172.438 RADIOACTIVE YELLOW-Il label. 172.303 Prohibited marking. 172.440 RADIOACTIVE YELLOW-Ill label. 172.304 Marking requirements. 172.441 FISSILE label. 172.306 [Reserved] 172.442 CORROSIVE label. 172.308 Authorized abbreviations. 172.444 [Reserved] 172.310 Class 7 (radioactive) materials. 172.446 CLASS 9 label. 172.312 Liquid hazardous materials in non- 172.448 CARGO AIRCRAFT ONLY label. bulk packagings. 172.450 EMPTY label. 172.313 Poisonous hazardous materials. 172.315 Packages containing limited quan Subpart F—Piacarding tities. 172.316 Packagings containing materials 172.500 Applicability of placarding require classed as ORM-D. ments. 172.317 KEEP AWAY FROM HEAT handling 172.502 Prohibited and permissive mark. placarding. 172.320 Explosive hazardous materials. 172.503 Identification number display on 172.322 Marine pollutants. placards. 172.323 Infectious substances. 172.504 General placarding requirements. 172.324 Hazardous substances in non-bulk 172.505 Placarding for subsidiary hazards. packagings. 172.506 Providing and affixing placards: 172.325 Elevated temperature materials. Highway. 172.326 Portable tanks. 172.507 Special placarding provisions: High 172.328 Cargo tanks. way. 172.330 Tank cal-s and multi-unit tank car 172.508 Placarding and affixing placarding; tanks. Rail. 172.331 Bulk packagings other than portable 172.5 10 Special placarding provisions: Rail. tanks, cargo tanks, tank cars and multi- 172.512 Freight containers and aircraft unit unit tank car tanks. load devices. 172.332 Identification number markings. 172.514 Bulk packagings. 172.334 Identification numbers; prohibited 172.516 Visibility and display of placards. display. 172.5 19 General specifications for placards. 172.336 Identification numbers; special pro 172.521 DANGEROUS placard. visions. 172.522 EXPLOSIVES 1.1, EXPLOSIVES 1.2 172.338 Replacement of identification num and EXPLOSIVES 1.3 placards. bers. 172.523 EXPLOSIVES 1.4 placard. 172.524 EXPLOSIVES 1.5 placard. Subpart E—Labeling 172.525 EXPLOSIVES 1.6 placard. 172.526 [Reserved] 172.400 General labeling requirements. 172.527 Background requirements for cer 172.400a Exceptions from labeling. tain placards. 172.401 Prohibited labeling. 172.528 NON-FLAMMABLE GAS placard. 172.402 Additional labeling requirements. 172.530 OXYGEN placard. 172.403 Class 7 (radioactive) material. 172.532 FLAMMABLE GAS placard. 172.404 Labels for mixed and consolidated 172.536 [Reserved] packaging. 172.540 POISON GAS placard. 172.405 Authorized label modifications. 172.542 FLAMMABLE placard. 172.406 Placement of labels. 172.544 COMBUSTIBLE placard. 172.407 Label specifications. 172.546 FLAMMABLE SOLID placard. 172.411 EXPLOSIVE 1.1, 1.2, 1.3, 1.4, 1.5 and 172.547 SPONTANEOUSLY COMBUSTIBLE 1.6 labels, and EXPLOSIVE Subsidiary placard. label. 172.548 DANGEROUS WHEN WET placard. 172.415 NON-FLAMMABLE GAS label. 172.550 OXIDIZER placard. 172.416 POISON GAS label. 172.552 ORGANIC PEROXIDE placard. 172417 FLAMMABLE GAS label. 172.553 [Reserved] 172.419 FLAMMABLE LIQUID label. 172.554 POISON placard. 172.420 FLAMMABLE SOLID label. 172.555 POISON INHALATION HAZARD 172.422 SPONTANEOUSLY COMBUSTIBLE placard. label. 172.556 RADIOACTIVE placard. 172.423 DANGEROUS WHEN WET label. 172.558 CORROSIVE placard.
124 Pipeline and Hazardous Materials Safety Admin., DOT § 172.101
172.560 CLASS 9 placard. (2) Each carrier by air, highway, rail, or water who transports a hazardous Subpart G—Emergency Response material. Information (b) When a person, other than one of 172.600 Applicability and general require those provided for in paragraph (a) of ments. this section, performs a packaging la 172.602 Emergency response information. beling or marking function required by 172.604 Emergency response telephone num this part, that person shall perform the ber. function in accordance with this part. 172.606 Carrier information contact. [Amdt. 172—29, 41 FR 15996, Apr. 15, 1976, as Subpart H—Training amended by Amdt. 172-32, 41 FR 38179, Sept. 9, 1976] 172.700 Purpose and scope. 172.701 Federal-State relationship. 172.702 Applicability and responsibility for Subpart B—Table of Hazardous training and testing. Materials and Special Provisions 172.704 Training requirements. § 172.101 Purpose and use of haz Subpart I—Safety and Security Plans ardous materials table. 172.800 Purpose and applicability. (a) The Hazardous Materials Table 172.802 Components of a security plan. (Table) in this section designates the 172.804 Relationship to other Federal re materials listed therein as hazardous quirements. materials for the purpose of transpor 172.820 Additional planning requirements tation of those materials. For each for transportation by rail. listed material, the Table identifies the 172.822 Limitation on actions by states, hazard class or specifies that the mate local governments, and Indian tribes. rial is forbidden in transportation, and APPENDIX A TO PART 172—OFFICE OF HAZ gives the proper shipping name or di ARDOUS MATERIALS TRANSPORTATION rects the COLOR TOLERANCE CHARTS AND TABLES user to the preferred proper APPENDIX B TO PART 172—TREFOIL SYMBOL shipping name. In addition, the Table APPENDIX C TO PART 172—DIMENSIONAL SPEC specifies or references requirements in IFICATIONS FOR RECOMMENDED PLACARD this subchapter pertaining to labeling, HOLDER packaging, quantity limits aboard air APPENDIX D TO PART 172—RAIL RISK ANAL craft and stowage of hazardous mate YSIS FACTORS rials aboard vessels. AUTHORITY: 49 U.S.C. 5101—5128, 44701; 49 (b) Column 1: Symbols. Column 1 of the CFR 1.53. Table contains six symbols (“+“, “A”, SOURCE: Amdt. 172—29, 41 FR 15996, Apr. 15, ‘D”, “G”, “I” and ‘W”) as follows: 1976, unless otherwise noted. (1) The plus (±) sign fixes the proper shipping name, hazard class and pack Subpart A—General ing group for that entry without regard to whether the material meets the defi § 172.1 Purpose and scope. nition of that class, packing group or any other hazard class definition. When This part lists and classifies those the plus sign is assigned to a proper materials which the Department has shipping name in Column (1) of the designated as hazardous materials for §172.101 Table, it means that the mate purposes of transportation and pre rial is known to pose a risk to humans. scribes the requirements for shipping When a plus sign is assigned to mix papers, package marking, labeling, and tures or solutions containing a mate transport vehicle placarding applicable rial where the hazard to humans is sig to the shipment and transportation of nificantly different from that of the those hazardous materials. pure material or where no hazard to [Amdt. 172—29, 41 FR 15997, Apr. 15, 1976, as humans is posed, the material may be amended by 66 FR 45379, Aug. 28, 2001] described using an alternative shipping name that represents the hazards posed § 172.3 Applicability. by the material. An appropriate alter (a) This part applies to— nate proper shipping name and hazard (1) Each person who offers a haz class may be authorized by the Asso ardous material for transportation, and ciate Administrator.
125 § 172.101 49 CFR Ch. I (10—1—10 Edition)
(2) The letter ‘A’ denotes a material Words may be alternatively spelled in that is subject to the requirements of the same manner as they appear in the this subchapter only when offered or ICAO Technical Instructions or the intended for transportation by aircraft, IMDG Code. For example “aluminum” unless the material is a hazardous sub may be spelled “aluminium” and “sul stance or a hazardous waste. A ship fur” may be spelled “sulphur”. How ping description entry preceded by an ever, the word “inflammable” may not “A” may be used to describe a material be used in place of the word “flam for other modes of transportation pro mable”. vided all applicable requirements for (2) Punctuation marks and words in the entry are met. italics are not part of the proper ship (3) The letter ‘D” identifies proper ping name, but may be used in addition shipping names which are appropriate to the proper shipping name. The word for describing materials for domestic “or” in italics indicates that terms in transportation but may be inappro the sequence may be used as the proper priate for international transportation shipping name, as appropriate. under the provisions of international (3) The word “poison” or “poisonous” regulations (e.g., IMO, ICAO). An alter may be used interchangeably with the nate proper shipping name may be se word “toxic” when only domestic lected when either domestic or inter transportation is involved. The abbre national transportation is involved. viation “n.o.i.” or “n.o.i.b.n.” may be (4) The letter “C” identifies proper used interchangeably with “no.5.”. shipping names for which one or more (4) Except for hazardous wastes, when technical names of the hazardous ma qualifying words are used as part of the terial must be entered in parentheses, proper shipping name, their sequence in association with the basic descrip in the package markings and shipping tion. (See §172.203(k).) paper description is optional. However, (5) The letter “I” identifies proper the entry in the Table reflects the pre shipping names which are appropriate ferred sequence. for describing materials in inter (5) When one entry references an national transportation. An alternate other entry by use of the word “see”, if proper shipping name may be selected both names are in Roman type, either when only domestic transportation is name may be used as the proper ship involved. ping name (e.g., Ethyl alcohol, see Eth (6) The letter “W” denotes a material anol). that is subject to the requirements of (6) When a proper shipping name in this subchapter only when offered or cludes a concentration range as part of intended for transportation by vessel, the shipping description, the actual unless the material is a hazardous sub concentration, if it is within the range stance or a hazardous waste. A ship stated, may be used in place of the con ping description entry preceded by a centration range. For example, an “W” may be used to describe a mate aqueous solution of hydrogen peroxide rial for other modes of transportation containing 30 percent peroxide may be provided all applicable requirements described as “Hydrogen peroxide, aque for the entry are met. ous solution with not less than 20 percent (c) Column 2: Hazardous materials de but not more than 40 percent hydrogen scriptions and proper shipping names. peroxide” or “Hydrogen peroxide, aque Column 2 lists the hazardous materials ous solution with 30 percent hydrogen descriptions and proper shipping names peroxide”. of materials designated as hazardous (7) Use of the prefix “mono” is op materials. Modification of a proper tional in any shipping name, when ap shipping name may otherwise be re propriate. Thus, Iodine monochloride quired or authorized by this section. may be used interchangeably with Io Proper shipping names are limited to dine chloride. In “Glycerol alpha those shown in Roman type (not monochlorohydrin” the term “mono” italics). is considered a prefix to the term (1) Proper shipping names may be “chiorohydrin” and may be deleted. used in the singular or plural and in ei (8) Use of the word “liquid” or ther capital or lower case letters. “solid”. The word “liquid” or “solid”
126 Pipeline and Hazardous Materials Safety Admin., DOT § 172.101 may be added to a proper shipping (ii) If one or more of the conditions name when a hazardous material spe specified in paragraph (c) (10) (i) of this cifically listed by name may, due to section is satisfied, then a proper ship differing physical states, be a liquid or ping name shall be selected as pre solid. When the packaging specified in scribed in paragraph (c)(12)(H) of this Column 8 is inappropriate for the phys section. ical state of the material, the table (iii) A mixture or solution not identi provided in paragraph (i) (4) of this sec fied in the Table specifically by name, tion should be used to determine the comprised of two or more hazardous appropriate packaging section. materials in the same hazard class, (9) Hazardous wastes. If the word shall be described using an appropriate “waste” is not included in the haz shipping description (e.g., “Flammable ardous material description in Column liquid, n.o.s.”). The name that most ap 2 of the Table, the proper shipping propriately describes the material name for a hazardous waste (as defined shall be used; e.g., an alcohol not listed in §171.8 of this subchapter), shall in by its technical name in the Table clude the word “Waste” preceding the shall be described as “Alcohol, n.o.s.” proper shipping name of the material. rather than “Flammable liquid, n.o.s.”. For example: Waste acetone. Some mixtures may be more appro (10) Mixtures and solutions. (i) A mix priately described according to their ture or solution not identified specifi application, such as “Coating solution” cally by name, comprised of a haz or “Extracts, flavoring liquid” rather ardous material identified in the Table than by an n.o.s. entry. Under the pro by technical name and non-hazardous visions of subparts C and D of this part, material, shall be described using the the technical names of at least two proper shipping name of the hazardous components most predominately con material and the qualifying word tributing to the hazards of the mixture “mixture” or “solution”, as appro or solution may be required in associa priate, unless— tion with the proper shipping name. (A) Except as provided in (11) Except for a material subject to § 172.101(1) (4) the packaging specified in or prohibited by §173.21, 173.54, Column 8 is inappropriate to the phys 173.56(d), 173.56(e), 173.224(c) or 173.225(b) ical state of the material; of this subchapter, a material that is (B) The shipping description indi considered to be a hazardous waste or a cates that the proper shipping name sample of a material for which the haz applies only to the pure or technically ard class is uncertain and must be de pure hazardous material; termined by testing may be assigned a (C) The hazard class, packing group, tentative proper shipping name, hazard or subsidiary hazard of the mixture or class, identification number and pack solution is different from that specified ing group, if applicable, based on the for the entry; shipper’s tentative determination ac (D) There is a significant change in cording to: the measures to be taken in emer (1) Defining criteria in this sub gencies; chapter; (E) The material is identified by spe (ii) The hazard precedence prescribed cial provision in Column 7 of the in § 173.2a of this subchapter; §172.101 Table as a material poisonous (Hi) The shipper’s knowledge of the by inhalation; however, it no longer material; meets the definition of poisonous by in (iv) In addition to paragraphs halation or it falls within a different (c)(11)(i) through (Hi) of this section, hazard zone than that specified in the for a sample of a material other than a special provision; or waste, the following must be met: (F) The material can be appro (A) Except when the word “Sample” priately described by a shipping name already appears in the proper shipping that describes its intended application, name, the word “Sample” must appear such as “Coating solution”, “Extracts, as part of the proper shipping name or flavoring” or “Compound, cleaning liq in association with the basic descrip uid”. tion on the shipping paper. 127 § 172.101 49 CFR Ch. 1(10—1—10 Edition)
(B) When the proper shipping descrip shipping name may not provide suffi tion for a sample is assigned a “G” in cient information for shipping papers Column (1) of the §172.101 Table, and and package markings. Under the pro the primary constituent(s) for which visions of subparts C and D of this part, the tentative classification is based are the technical name of one or more con not known, the provisions requiring a stituents which makes the product a technical name for the constituent(s) hazardous material may be required in do not apply; and association with the proper shipping (C) A sample must be transported in name. a combination packaging that con (iii) Multiple hazard materials. If a ma forms to the requirements of this sub terial meets the definition of more chapter that are applicable to the ten than one hazard class, and is not iden tative packing group assigned, and tified in the Table specifically by name may not exceed a net mass of 2.5 kg (5.5 (e.g., acetyl chloride), the hazard class pounds) per package. of the material shall be determined by NOTE TO PARAGRAPH (c)(1l): For the trans using the precedence specified in portation of samples of self-reactive mate §173.2a of this subchapter, and an ap rials, organic peroxides, explosives or light propriate shipping description (e.g., ers, see §1173.224(c)(3), 173.225(c)(2), 173.56(d) “Flammable liquid, corrosive no.5.”) or l73308(b)(2) of this subchapter, respec shall be selected as described in para tively. graph (c)(l2)(ii) of this section. (12) Except when the proper shipping (iv) If it is specifically determined name in the Table is preceded by a plus that a material is not a forbidden ma
(±) — terial and does not meet the definition (i) If it is specifically determined of any hazard class, the material is not that a material meets the definition of a hazardous material. a hazard class, packing group or hazard (13) Self-reactive materials and organic zone, other than the class, packing peroxides. A generic proper shipping group or hazard zone shown in associa name for a self-reactive material or an tion with the proper shipping name, or organic peroxide, as listed in Column 2 does not meet the defining criteria for of the Table, must be selected based on a subsidiary hazard shown in Column 6 the material’s technical name and con of the Table, the material shall be de centration, in accordance with the pro scribed by an appropriate proper ship visions of § 173.224 or 173.225 of this ping name listed in association with subchapter, respectively. the correct hazard class, packing (14) A proper shipping name that de group, hazard zone, or subsidiary haz scribes all isomers of a material may ard for the material. be used to identify any isomer of that (ii) Generic or no.5. descriptions. If an material if the isomer meets criteria appropriate technical name is not for the same hazard class or division, shown in the Table, selection of a prop subsidiary risk(s) and packing group, er shipping name shall be made from unless the isomer is specifically identi the generic or no.5. descriptions cor fied in the Table. responding to the specific hazard class, (15) Unless a hydrate is specifically packing group, hazard zone, or sub listed in the Table, a proper shipping sidiary hazard, if any, for the material. name for the equivalent anhydrous The name that most appropriately de substance may be used, if the hydrate scribes the material shall be used: e.g., meets the same hazard class or divi an alcohol not listed by its technical sion, subsidiary risk(s) and packing name in the Table shall be described as group. “Alcohol, n.o.s.” rather than “Flam (16) Unless it is already included in mable liquid, n.o.s.”. Some mixtures the proper shipping name in the may be more appropriately described §172.101 Table, the qualifying words according to their application, such as “liquid” or “solid” may be added in as “Coating solution” or “Extracts, fla sociation with the proper shipping voring, liquid”, rather than by an no.5. name when a hazardous material spe entry, such as “Flammable liquid, cifically listed by name in the §172.101 no.5.” It should be noted, however, Table may, due to the differing phys that an no.5. description as a proper ical states of the various isomers of the
128 Pipeline and Hazardous Materials Safety Admin., DOT § 172.101 material, be either a liquid or a solid Identification numbers in the “NA9000” (for example “Dinitrotoluenes, liquid” series are associated with proper ship and “Dinitrotoluenes, solid”). Use of ping names not appropriately covered the words “liquid” or ‘solid” is subject by international hazardous materials to the limitations specified for the use (dangerous goods) transportation of the words “mixture” or “solution” standards, or not appropriately ad in paragraph (c) (10) of this section. The dressed by international transpor qualifying word “molten” may be tation standards for emergency re added in association with the proper sponse information purposes, except for shipping name when a hazardous mate transportation between the United rial, which is a solid in accordance States and Canada. with the definition in §171.8 of this sub (I) Column .5: Packing group. Column 5 chapter, is offered for transportation in specifies one or more packing groups the molten state (for example, assigned to a material corresponding to “Alkylphenols, solid, n.o.s., molten”). the proper shipping name and hazard (d) Column 3: Hazard class or Division. class for that material. Class 2, Class 7, Column 3 contains a designation of the Division 6.2 (other than regulated med hazard class or division corresponding ical wastes), and ORM-D materials, do to each proper shipping name, or the not have packing groups. Packing word “Forbidden”. Groups I, II and III indicate the degree (1) A material for which the entry in of danger presented by the material is this column is “Forbidden” may not be either great, medium or minor, respec offered for transportation or trans tively. If more than one packing group ported. This prohibition does not apply is indicated for an entry, the packing if the material is diluted, stabilized or group for the hazardous material is de incorporated in a device and it is termined using the criteria for assign classed in accordance with the defini ment of packing groups specified in tions of hazardous materials contained subpart D of part 173. When a reevalua in part 173 of this subchapter. tion of test data or new data indicates (2) When a reevaluation of test data a need to modify the specified packing or new data indicates a need to modify group(s), the data should be submitted the “Forbidden” designation or the to the Associate Administrator. Each hazard class or packing group specified reference in this column to a material for a material specifically identified in which is a hazardous waste or a haz the Table, this data should be sub ardous substance, and whose proper mitted to the Associate Administrator. shipping name is preceded in Column 1 (3) A basic description of each hazard of the Table by the letter “A” or “W”, class and the section reference for class is modified to read “III” on those occa definitions appear in § 173.2 of this sub sions when the material is offered for chapter. transportation or transported by a (4) Each reference to a Class 3 mate mode in which its transportation is not rial is modified to read “Combustible otherwise subject to requirements of liquid” when that material is reclassi this subchapter. fied in accordance with § 173.150(e) or (f) (g) Column 6: Labels. Column 6 speci of this subchapter or has a flash point fies codes which represent the hazard above 60 °C (140 °F) but below 93 °C (200 warning labels required for a package °F). filled with a material conforming to (e) Column 4: Identification number. the associated hazard class and proper Column 4 lists the identification num shipping name, unless the package is ber assigned to each proper shipping otherwise excepted from labeling by a name. Those preceded by the letters provision in subpart E of this part, or “UN” are associated with proper ship part 173 of this subchapter. The first ping names considered appropriate for code is indicative of the primary haz international transportation as well as ard of the material. Additional label domestic transportation. Those pre codes are indicative of subsidiary haz ceded by the letters “NA” are associ ards. Provisions in § 172.402 may require ated with proper shipping names not that a label other than that specified recognized for international transpor in Column 6 be affixed to the package tation, except to and from Canada. in addition to that specified in Column
129 § 172.101 49 CFR Ch. 1(10—1—10 Edition) 6. No label is required for a material all packagings prescribed in § 173.24 of classed as a combustible liquid or for a this subchapter and any other applica Class 3 material that is reclassed as a ble requirements in subparts A and B combustible liquid. For Empty” label of part 173 of this subchapter. requirements, see § 173.428 of this sub (1) Exceptions. Column 8A contains chapter. The codes contained in Col exceptions from some of the require umn 6 are defined according to the fol ments of this subchapter. The ref lowing table: erenced exceptions are in addition to LABEL SUBSTITUTION TABLE those specified in subpart A of part 173 and elsewhere in this subchapter. A Label code Label name “None” in this column means no pack 1 Explosive aging exceptions are authorized, except 1.11 Explosive 1.11 as may be provided by special provi 1.21 Explosive 1.21 sions in Column 7. 1.31 Explosive 1.31 1.4’ Explosive 1.41 (2) Non-bulk packaging. Column 8B 1.51 Explosive I 51 references the section in part 173 of 1.61 Explosive 1.6’ this subchapter which prescribes pack 2.1 Flammable Gas 2.2 Non-Flammable Gas aging requirements for non-bulk pack 2.3 Poison Gas agings. A “None” in this column means 3 Flammable Liquid non-bulk packagings are not author 4.1 Flammable Solid 4.2 Spontaneously Combustible ized, except as may be provided by spe 4.3 Dangerous When Wet cial provisions in Column 7. Each ref 5.1 Oxidizer erence in this column to a material 5.2 Organic Peroxide 6.1 (inhalation hazard, Zone A Poison Inhalation Hazard which is a hazardous waste or a haz or B>. ardous substance, and whose proper 6.1 (other than inhalation haz- Poison shipping name is preceded in Column I ard, Zone A or B)2. 6.2 Infectious substance of the Table by the letter “A” or “W”,
7 Radioactive is modified to include “ 173.203” or 8 Corrosive “ 173.213’’, as appropriate for liquids 9 ClassS and solids, respectively, on those occa I Refers to the appropriate compatibility group letter. 2The packing group for a material is indicated in column 5 sions when the material is offered for of the table. transportation or transported by a (h) Column 7: Special provisions. Col mode in which its transportation is not umn 7 specifies codes for special provi otherwise subject to the requirements sions applicable to hazardous mate of this subchapter. rials. When Column 7 refers to a special (3) Bulk packaging. Column (8C) speci provision for a hazardous material, the fies the section in part 173 of this sub meaning and requirements of that spe chapter that prescribes packaging re cial provision are as set forth in quirements for bulk packagings, sub § 172.102 of this subpart. ject to the limitations, requirements, (i) Column 8: Packaging authorizations. and additional authorizations of Col Columns 8A, 8B and 8C specify the ap umns (7) and (8B). A “None” in Column plicable sections for exceptions, non- (8C) means bulk packagings are not au bulk packaging requirements and bulk thorized, except as may be provided by packaging requirements, respectively, special provisions in Column (7) and in in part 173 of this subchapter. Columns packaging authorizations Column (8B). 8A, 8B and 8C are completed in a man Additional authorizations and limita ner which indicates that “ 173.” pre tions for use of UN portable tanks are cedes the designated numerical entry. set forth in Column 7. For each ref For example, the entry “202” in Col erence in this column to a material umn 8B associated with the proper that is a hazardous waste or a haz shipping name “Gasoline” indicates ardous substance, and whose proper that for this material conformance to shipping name is preceded in Column 1 non-bulk packaging requirements pre of the Table by the letter “A” or “W” scribed in § 173.202 of this subchapter is and that is offered for transportation required. When packaging require or transported by a mode in which its ments are specified, they are in addi transportation is not otherwise subject tion to the standard requirements for to the requirements of this subchapter: 130 Pipeline and Hazardous Materials Safety Admin., DOT § 172.101 (4) For a hazardous material which is (5) The total net quantity of haz specifically named in the Table and ardous material for an outer non-bulk whose packaging sections specify pack packaging that contains more than one agings not applicable to the form of the hazardous material may not exceed the material (e.g. packaging specified is lowest permitted maximum net quan for solid material and the material is tity per package as shown in Column being offered for transportation in a 9A or 9B, as appropriate. If one mate liquid form) the following table should rial is a liquid and one is a solid, the be used to determine the appropriate maximum net quantity must be cal packaging section: culated in kilograms. See § l73.24a(c) (1) (iv). Packaging sechon reference for aging sectio&Hquid (k) Column 10: Vessel stowage require ments. Column lOA [Vessel stowage] specifies the authorized stowage loca §173.187 §173.181 tions on board cargo and passenger ves §173.211 §173.201
§173.212 §173.202 sels. Column lOB [Other provisions]
§173.213 ...... , §173.203 specifies codes for stowage require §173.240 §173.241 ments for specific hazardous materials. §173.242 §173.243 The meaning of each code in Column lOB is set forth in § 176.84 of this sub (5) Cylinders. For cylinders, both non- chapter. Section 176.63 of this sub bulk and bulk packaging authoriza chapter sets forth the physical require tions are set forth in Column (8B). Not ments for each of the authorized loca withstanding a designation of “None” tions listed in Column bA. (For bulk in Column (8C), a bulk cylinder may be transportation by vessel, see 46 CFR used when specified through the sec parts 30 to 40, 70, 98, 148, 151, 153 and tion reference in Column (8B). 154.) The authorized stowage locations (j) Column 9: Quantity limitations. Col specified in Column 1OA are defined as umns 9A and 9B specify the maximum follows: quantities that may be offered for (1) Stowage category “A” means the transportation in one package by pas material may be stowed “on deck” or senger-carrying aircraft or passenger- “under deck” on a cargo vessel and on carrying rail car (Column 9A) or by a passenger vessel. cargo aircraft only (Column 9B), sub (2) Stowage category “B” means— ject to the following: (1) The material may be stowed “on (I) “Forbidden” means the material deck” or “under deck” on a cargo ves may not be offered for transportation sel and on a passenger vessel carrying or transported in the applicable mode a number of passengers limited to not of transport. more than the larger of 25 passengers, (2) The quantity limitation is “net” or one passenger per each 3 m of over except where otherwise specified, such all vessel length; and as for “Consumer commodity” which (ii) “On deck only” on passenger ves specifies “30 kg gross.” sels in which the number of passengers (3) When articles or devices are spe specified in paragraph (k) (2) (i) of this cifically listed by name, the net quan section is exceeded. tity limitation applies to the entire ar (3) Stowage category “C” means the ticle or device (less packaging and material must be stowed “on deck packaging materials) rather than only only” on a cargo vessel and on a pas to its hazardous components. senger vessel. (4) A package offered or intended for (4) Stowage category “D” means the transportation by aircraft and which is material must be stowed “on deck filled with a material forbidden on pas only” on a cargo vessel and on a pas senger-carrying aircraft but permitted senger vessel carrying a number of pas on cargo aircraft only, or which ex sengers limited to not more than the ceeds the maximum net quantity au larger of 25 passengers or one passenger thorized on passenger-carrying air per each 3 m of overall vessel length, craft, shall be labelled with the CARGO but the material is prohibited on pas AIRCRAFT ONLY label specified in senger vessels in which the limiting § 172.448 of this part. number of passengers is exceeded. 131 § 172.101 49 CFR Ch. I (10—1—10 Edition)
(5) Stowage category “E” means the (14) Stowage category “09” means the material may be stowed on deck” or material may be stowed “on deck “under deck” on a cargo vessel and on only” in closed cargo transport units a passenger vessel carrying a number or “under deck” in closed cargo trans of passengers limited to not more than port units on a cargo vessel (up to 12 the larger of 25 passengers, or one pas passengers) and on a passenger vessel. senger per each 3 m of overall vessel (15) Stowage category “10” means the length, but is prohibited from carriage material may be stowed “on deck” in on passenger vessels in which the lim closed cargo transport units or “under iting number of passengers is exceeded. deck” in closed cargo transport units (6) Stowage category “01” means the on a cargo vessel (up to 12 passengers) material may be stowed ‘on deck” or and “on deck” only in closed cargo “under deck” on a cargo vessel (up to transport units on a passenger vessel. 12 passengers) and on a passenger ves (16) Stowage category “11” means the sel. material may be stowed “on deck” in (7) Stowage category “02” means the closed cargo transport units or “under material may be stowed “on deck” or deck” in magazine stowage type “c” on “under deck” on a cargo vessel (up to a cargo vessel (up to 12 passengers) and 12 passengers) and “on deck” in closed “on deck” only in closed cargo trans cargo transport units or “under deck” port units on a passenger vessel. in closed cargo transport units on a (17) Stowage category “12” means the passenger vessel. material may be stowed “on deck” in (8) Stowage category “03” means the closed cargo transport units or “under material may be stowed “on deck” or deck” in magazine stowage type ‘c” on “under deck” on a cargo vessel (up to a cargo vessel (up to 12 passengers) but 12 passengers) and “on deck” in closed the material is prohibited on a pas cargo transport units on a passenger senger vessel. vessel. (18) Stowage category “13” means the (9) Stowage category “04” means the material may be stowed “on deck” in material may be stowed “on deck” or closed cargo transport units or “under “under deck” on a cargo vessel (up to deck” in magazine stowage type “A” 12 passengers) but the material is pro on a cargo vessel (up to 12 passengers) hibited on a passenger vessel. and “on deck” only in closed cargo (10) Stowage category “05” means the transport units on a passenger vessel. material may be stowed “on deck” in (19) Stowage category “14” means the closed cargo transport units or “under material may be stowed “on deck” in deck” on a cargo vessel (up to 12 pas closed cargo transport units on a cargo sengers) and on a passenger vessel. vessel (up to 12 passengers) but the ma (11) Stowage category “06” means the terial is prohibited on a passenger ves material may be stowed “on deck” in sel. closed cargo transport units or “under (20) Stowage category “15” means the deck” on a cargo vessel (up to 12 pas material may be stowed “on deck” in sengers) and “on deck” in closed cargo closed cargo transport units or “under transport units or “under deck” in deck” in closed cargo transport units closed cargo transport units on a pas on a cargo vessel (up to 12 passengers) senger vessel. but the material is prohibited on a pas (12) Stowage category “07” means the senger vessel. material may be stowed “on deck” in (1) Changes to the Table. (I) Unless closed cargo transport units or “under specifically stated otherwise in a rule deck” on a cargo vessel (up to 12 pas document published in the FEDERAL sengers) and “on deck” only in closed REGISTER amending the Table— cargo transport units on a passenger (i) Such a change does not apply to vessel. the shipment of any package filled (13) Stowage category “08” means the prior to the effective date of the material may be stowed “on deck” in amendment; and closed cargo transport units or “under (ii) Stocks of preprinted shipping pa deck” on a cargo vessel (up to 12 pas pers and package markings may be sengers) but the material is prohibited continued in use, in the manner pre on a passenger vessel. viously authorized, until depleted or 132 Pipeline and Hazardous Materials Safety Admin., DOT § 172.101 for a one-year period, subsequent to (3) The proper shipping name of a the effective date of the amendment, hazardous material changed in the May whichever is less. 6, 1997 final rule, in effect on October 1, (2) Except as otherwise provided in 1997, only by the addition or omission this section, any alteration of a ship of the word ‘compressed,” “inhibited,” ping description or associated entry ‘liquefied” or “solution” may continue which is listed in the §172.101 Table to be used to comply with package must receive prior written approval marking requirements, until January from the Associate Administrator. 1, 2003.
133 §172.101 HAzARDous MATERIALS TABLE C0)
(8) (9) (10) Vessel Hazard Identi- Packaging Quantity limitations stowage 0 Sym- Hazardous materials descriptions Label Special provisions ( 173.***( (see 173.27 and bols and proper shipping names class or fication PG § Division Numbers Codes ( 172.102) — — — 175.75) Escep- Non- Other tions bulk Bulk Passenger Cargo air- r aircraft/rail craft only (1) (2) (3) (4) (5) (6) (7) (8A) (8B) (SC) (9A) (96) (1OA) (lOB)
Accellerene, see Nitrosodimethylaniline. Accumulators, electric, see Batteries, wet etc. Accumulators, pressurized, pneu matic or hydraulic (containing non ttamable gas), see Articles pres surized, pneumatic or hydraulic (containing non-flamable gas). Acetal 3 UN1088 II 3 62, T4, TP1 150 202 242 5L 60L E 3 Acetaldehyde UN1OS9 3 A3, 616, Til, TP2, TP7 None 201 243 Forbidden 30L E A Acetaldehyde ammonia 9 UN1841 Ill 9 lBS. 1P3, lP7, Ti, TP33 155 204 240 200 kg 200kg A 34 Ill 3 Acetaldehyde oxime 3 UN2332 61, 1B3,T4, TP1 150 203 242 60 L 220L A Acetic acid, glacial or Acetic acid so 8 UN2789 II 8, 3 A3, A6,A7, AlO, 62, 154 202 243 1L 30L A lution, with more than 80 percent 162, T7, TP2 acid, by mass.
Acetic acid solution, not less than 50 8 UN2790 II 8 A3, AS, A7, AlO, B2, 154 202.... 242.... 1L 30L A percent but not more than 80 per 182, T7, TP2 cent acid, by mass. Acetic acid solution, with more than 8 UN2790 III 8 1B3,T4, TP1 154 203 .... 242 5L 60L A 10 percent and less than 50 per cent acid, by mass. C) -F’ Acetic anhydride S UN1715 Il 8,3.... A3, AS, A7, AlO, 62, 154 202 243 1L 30L A 40 1B2,T7, TP2 C, Acetone 3 UN1O9O II 3 82, T4, TP1 150 202 242 5L 60L B Acetone cyanohydrin, stabilized 6.1 UNI 541 I 6.1 2, B9, 614, B32, B76, None 227 244 Forbidden Forbidden D 25, 40, 877, N34, T20, TP2, 52, 53 TPI3, TP38, TP45 Acetone oils 3 UN1O9I II 3 1B2,T4, TP1, TP8 150 202 .... 242 .... 5 L 60 L B 3 Acetonitrile UN1648 II 3 l82, T7, TP2 150 202 .... 242 .... 5 L 60 L B 40 Acetyl acetone peroxide with more Forbidden than 9 percent by mass active oxy 0 gen. m Acetyl benzoyl peroxide, solid, or Forbidden 0 with more than 40 percent in solu lion. 0 Acetyl bromide 8 UN1716 II 8 92, 182, T8, TP2 154 202 .... 242 1L 30L C 40 2.12.12.22.2,0.CU,
Acetyl chloride 3 UN1717 II 3,8.... A3, A6, A7,IB1, N34, 150 ...... 202 .... 243 .... IL 5 L 8 40 T8, TP2 V Acetyl cyclohexanesulfonyl peroxide, Forbidden (D with more then 82 percent wetted
with tess then 12 percent weter. CD Acetyl iodide 8 UN1898 II 8 B2, 182, T7, TP2, TP13 154 202 242 1L 30 L C 40 Acetyl methyl carbinol 3 UN2621 III 3 Bi, 83, T2, TP1 150 203 242 60 L 220 L A Acetyl peroxide, solid, or with more Forbidden then 25 percent in solution. x Acetylene, dissolved 2.1 UN1001 2.1 N86, N88 None 303 None Forbidden iS kg D 25, 40, 0 57 Acetylene (liquefied) Forbidden Acetylene silver nitrate Forbidden 0. Acetylene, solvent free Forbidden 0 Acetylene tetra bromide, see Tetrabromoethane. Acid butyl phosphate, see Butyl acid phosphate. 0 Acid, sludge, see Sludge acid CD Acridine 6.1 UN2713 III 61 lB8, 1P3, Ti, TP33 153 213 240 100 kg 200 kg A 0 Acrolein dimer, stabilized 3 UN2607 III 3 Bi, lB3, T2, TPI 150 203 242 60 L 220 L A 40
Acrolein, stabilized 6.1 UN1092 I 6.1,3 1, B9, B14, B30, B42, None 226 244 Forbidden Forbidden D 40 B77, T22, TP2, TP7, 0 TP13, TP38, TP44 CD cz Acrylamide, solid 6.1 UN2074 III 61 188, P3, Ti, TP33 153 213 240 100 kg 200 kg A 12 C.), Acrylamide solution 6.1 UN3426 III 6.1 lB3, T4, TP1 153 203 241 60 L 220 L A Acrylic acid, stabilized 8 UN2218 II 8,3.... B2, 1B2,T7, TP2 154 202 243 1L 30 L C 25, 40 >
Acrylonitrile, stabilized 3 UN1093 I 3,61 89, T14, TP2, TP13 None 201 243 Forbidden 30 L 6 40 Actuating cartridge, explosive, see Cartridges, power device. 201 Adhesives, containing a flammable 3 UN1133 I 3 Tli, TP1, TP8, TP27 150 243 1L 30 L B liquid. B II 3 149, 852, 182, T4, TP1, 150 173 242.... 5L 60 L 0 TP8 -I Ill 3 81, 852, lB3, T2, TP1 150 173 242 .... 60 L 220 L A Adiponitrila 6.1 UN2205 Ill 6.1 183, T3, TP1 153 203 241 60 L 220 L A Aerosols, corrosive, Packing Group II 2.2 UN1950 2.2,8 A34 306 None None 75 kg 150 kg A 48, 87, or Ill, (each not exceeding 1 L ca 126 pacity). Aerosols, flammable, (each not ex 2.1 UN1950 N82 306 None None 75 kg 150kg A 48, 87, ceeding I L capacity). 126 Aerosols, flammable, no.s. (engine 2.1 UN1950 N82 306 304 .... None Forbidden 150kg A 48, 87. starting fluid) (each not exceeding 126 I L capacity). Aerosols, non-flammable,(each not 2.2 UN1950 306 None None 75 kg 150kg A 48, 87, (0) exceeding I L capacity). 126. — Aerosols, poison, (each not exceed 2.2 UN19SO 306 None None Forbidden Forbidden A 48,87 ing I L capacity). 6.1. Air bag inflators, or Air bag modules, 1.4G UN0503 II 1.4G 161 None 62 None Forbidden 75kg 02 or Seat-belt pretensioners.. 0
C-) ,, C) 0 m 0 0 0. 51 51 40 40 40 40 Other (lOB) (10) Vessel stowage (bA) A D D E A F B A F B B E E B A A. B A A L L L L L L L L L L L L L L kg kg 5L air- 42 30 60 60 30 60 30 30 60 60 only 220 220 220 220 and 100 150 (9B) Forbidden Forbidden craft Cargo limitations (9) L L L L kg kg 175.75) §173.27 bL 1L 5L 1L 1L 5L 1L 5L 60 60 60 60 75 25 (9A) Quantity (see Forbidden Forbidden Forbidden Forbidden Forbidden aircraWrail Passenger 319. 319. Bulk (8C) 166 ‘- 302 318, 318, None 243 242 243 242 242 243 242 243 243 242 242 242 243 243 (8) bulk (86) Non- 166 302 172 316 316 202 202 203 201 201 202 203 203 201 202 203 201 202 202 (173.***) Packaging 307. (8A) bone Excep- 166 306, None 150 150 320 320 150 150 150 150 None 150 150 150 None None None 150 — 78 1B2 T4, T2, 160 TP1 TP1 TP8, TP1, TP22 TP22 TP27 TP27 TP27 TP28 TP28 TP27 TP28 TP29 TP29 TP27 TP27 182, TABLE—Cont)rtued Nil, T4, TPI, TP1, TP8, TP5, TPS, TP2, TP1, TPI, TPI, TP8, TP2, BI, TP13, TP13, provisions l83, (7) T7, T4, T7, 172.102) Til, T75, T75, Til, Tn, Til, TP1, 149, Bi, 81, 83, TP2, TP2, ( 1B2, lB3, lB3, 172, T7, lB2. lB2, 24, Special 24. 172, T14, T14, MATERIALS Bi, B1, 172, 1B2, 8 6.1 6.1 (6) 6,1 5.1. 8. 5.1. Label Codes 9 2.2 2.2, 3,6.1, 2.2, 3, 3 3 3, 3, 3 3 3 3 3, 6.1 3, 6.1 3, 3 3 II II II II II Ill Ill Ill Ill Ill HAZARDOuS (5) PG 172.101 Identi- fication Numbers UN3268 UNIQO2 UN1003 UNIOO3 UN3165 UN3274 UN1987 UN3065 UN1986
§ UN1989 UN1988 9 3 3 3 3 3 3 3 or 2.2 2.2 2.2 (3) (4) Hazard Division class liq liq Life tank alco hydra saving in n.o.s. fuel see modules, turbines), anhydrous no.s Life names unit of bag combustion. descriptions (cryogenic (cryogenic toxic, s.o.s., see toxic slides, etc. Air monomethyt or power (2) (including shipping liquid, kits, liquid, mixture internal pretensioners.. a materials fuel). etc. and solution, no.s flammable, proper n.o.s beverages flammable, appliances evacuation inflators, engines survival hydraulic (M86 non-pressurized. Engines, and Seat-belt refrigerated refrigerated compressed bag Hazardous or uid) (containing uid). see hydrazine saving hol. sine) appliances Air Air, Air, Air, Aircraft Aircraft Aircraft Alcoholates Alcohols, Aircraft Alcoholic Alcohols, Aldehydes, Aldehydes, G G G (1) bols Sym- Ill I 3, 6.1 81, 1B3,T7, TP1, TP28 150 203 242 60 L 220 L A Aldol 6.1 UN2839 II 6.1 1B2,T7, TP2 153 202 243 5L 60 L A 12 II •0 G Alkali metal alcoholates, self-heating, 4.2 UN3206 4.2, 8 64, A7, 1B5, P2, T3, None 212 242 15 kg 50 kg B corrosive, no.5.. TP33
Ill 4.2, 8 64, A7, 1B8, lP3, Ti, None 2i3 242 25 kg 100 kg B CD TP33 a Alkali metal alloys, liquid, no.s 4.3 UN1421 4.3 A2, A3,A7, B48, N34 None 201 244 Forbidden 1L D 52 Alkali metal amalgam, liquid 4.3 UNi389 4.3 A2, A3,A7, N34 None 201 244 Forbidden 1L C 40, 52 a. Alkali metal amalgam, solid 4.3 UN3401 4.3 lB4, IP1, N40, T9, TP7, None 211 242 Forbidden 15 kg C 52 TP33 a Alkali metal amides 4.3 UN1390 II 4.3 A6, A7, A8,A19, A20, 151 212 24i 15 kg 50 kg B 40, 52 N 1B7,lP2, T3, TP33 a D Alkali metal dispersions, or Alkaline 4.3 UN1391 4.3 A2, A3, A7 None 201 244 Forbidden 1L 52 0. earth metal dispersions. 0 C G Alkaline corrosive liquids, n.o.s., see 0) Caustic alkali liquids, no.s.. Alkaline earth metal alcoholstes, 4.2 UN3205 4.2 65, A7, lB6, 1P2, T3, None 212 241 15 kg 50 kg B no.5.. TP33 a 4.2 65, A7, 1B8, 1P3, Ti, None 2i3 241 25 kg 100 kg B CD TP33 a Alkaline earth metal alloys, no.s 4.3 UN1393 II 4.3 A19, 1B7, lP2, T3, TP33 151 212 241 15 kg 50 kg E 52 Alkaline earth liquid UN1392 metal amalgams, 4.3 4.3 A19, N34, N40 None 201 244 Forbidden iL B 40, 52 C.’, G Alkaline earth metal amalgams, solid 4.3 UN3402 4.3 Ai9, N34, N40, T9, TP7, None 211 242 Forbidden 15 kg 0 52 a TP33 II CD -a UN3140 201 cz Alkaloids, liquid, n.o.s., or Alkaloid 6.1 6.1 A4, T14, TP2, TP27 None 243 1L 30 L A G salts, liquid, n.o.s.. 6.1 A IB2, Til, TP2, TP27 153 202 243 5L 60 L > 6,1 A Ill lB3, T7, TP1, TP28 153 203 241 60 L L 0. 6.1 220 Alkaloids, solid, n,o,s. or Alkaloid 6.1 UN1544 1B7, P1, T6, TP33 None 211 242 5 kg 50 kg A 3 salts, solid, no.s. poisonous. 6.1 Ill 6.1 1B8, 1P2, 1P4,T3, TP33 153 212 242 25 kg 100 kg A A 1B8,lP3, Ti, TP33 153 213 240 100 kg 200 kg UN2584 Alkylsulfonic acids, liquid or Aryl sul 8 II 8 B2, 1B2,T8, TP2, TP13 154 202 242 1L 30 L B 0 tonic acids, liquid with more than 5 -I percent free sulfuric acid. 8 UN2586 Alkylsulfonic acids, liquid or Aryl sul III 8 183, T4, TP1 154 203 .... 241 5L 60L B tonic acids, liquid with not more than 5 percent free sulfuric acid. 8 UN2583 Alkyl sulfonic acids, solid or Aryl sul II 8 lB8, lP2, lP4, T3, TP33 154 212 .... 240 15 kg 50kg A tonic acids, solid, with more than 5 percent free sulfuric acid. 8 UN2585 Alkyl sulfonic acids, solid or Aryl sul III 8 188, lP3, Ti, TP33 154 213 .... 240 25 kg 100kg A tonic acids, solid with not more than 5 percent free sulfuric acid. UN3145 Alkylphenols, liquid, no.s. (including 8 8 A6, T14, TP2 None 201 243 0.5 L 2.5 L B ‘0, C2-C12 homologues). 8 B lB2, Til, TP2, TP27 154 202 242 1L 30 L 8 Ill lB3, T7, TPI, TP28 154 203 241 5L 60 L A UN2430 8 Alkylphenols, solid, no.s, (including 8 lB7, IP1, T6, TP33 None 211 242 1 kg 25 kg B C2-Cl2 homologues). 0 0
(.)
Ca, ,, C) cj m 0 a. 0
14
40 40 40 40 40 40 40 40 52 40 40 40
40 40
(lOB) Other
(10)
Vessel
stowage
tiofl
(1OA)
B A C 6 0 S 8 0 E B E 0 A D D C
A A A A A
L
L L L L L L L L L L L
kg kg
kg kg kg
5
air-
30 60 30 30
60 30 60 30
60 60
only
50
50 50 50 220
and
100
(9B)
Forbidden
craft Forbidden
Forbidden Forbidden
Cargo
limitations
(9)
173.27
L L
L L L
L L
kg kg
175.75)
kg kg kg
1
1
§ I 1
5 5
60
15
25
15 15 15
(9A)
Quantity
(see
Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden
aircraWrail Passenger ......
(8C) Bulk
240 242 240 243 243 244 243 243 244 243 242 243 243 243 244 244 242 240 241 240 241 ......
(8)
bulk (SB)
Non-
173.***)
212 213 202 202 227 181 201 201 227 203
‘-- 202 202 201 202 227 206 212 203 203 212 212
(
Packaging ......
(BA)
Sons
Excep-
154 154 154 150
None 150 None None 150 None 150
None None 154 154 None None 181 None 154 154
T7,
T3,
TPI TP2
TP1 TP1 B77,
N41, T20, Tb,
TP13 TP33 TP28 TP33 TP45 TP13 TP13 TP13 TP13 TP4S TP4S TP13 TP13 TP33 TP33 TP33 TP33
TPI3, TP38,
TP38,
T7, T2, T4,
T4, TABLE—Continued
N34,
N41,
T3, TI,
T3, T3,
B32,
632,
B32, N34,
TP1, TP2, TP2, TP1, TP2,
TP2, TP7, TP7,
TP2,
TP38,
83,
TPI3, TP13, 1B3, 1B2, lB3,
provisions
181,
lP2,
(7)
lP4, lP3,
B6, 1P4,
1P4,
T7,
T7,
B14, T8, 614, B14, 172.102)
T14,
T14,
T14, T21,
TP2,
81,
A7,
A6,
87,
(
TP2, TP2, B2,
1P2, 186,
1P2, TP13, 1P2.
162, 69, 89,
B9, 162,
182,
A3,
Special
611,
A3,
2,
2,
2,
A7,
188, MATERIALS T20, T20,
lB8, lB8, A20,
62.
TP2,
1 1
3
6.1 6.1 6.1 6 6 (6) 8 3
8.
4,3,
Label
Codes
B 8 6 3, 6.1,3 3, 3, 6.1,3, 3, 3, 3 3, 6,1,3 61, 4.2, 8, 8 8 4.3 8 8 i
II II
II II II II
Ill
Ill Ill
Ill
HAzARDOuS
(5)
PG
(4)
172.101
Identi-
tication
Numbers
UN2571 UN2333 UN1099 UN1098 UN1100 UN1722 UN2335 UN2336 UN2219 UN1723 UN2B7O UN1724 UN1545 UN2334 § UN1725 UN1726 UN2580 UN1394 UN2581
8 3
3 3 3 3 3 3 B 8 8 B 8
or
6.1 6.1
6.1 6.1 4.2
4.3
(3)
Hazard
Division
class
Forbidden
Allyl
toxic
Aluminum
see
names
liquid,
or hot
descriptions
or
stabilized
anhydrous solution
anhydrous solution
stabilized
(2)
wet
devices.
shipping
in
Pesticides,
materials
acids
borohydride
bromide, bromide, carbide dross, chloride, chloride,
ether
proper
see
chlorocarbonate,
and
bromide
acetate alcohol chloride chloroformate iodide ethyl formate isothiocyanate, glycidyl
Hazardous no.5..
chloroformate.
borohydride
lyl
Alkylsulfuric Allethrin, Allyl Allyl Allyl Allyl Allyl Al Allyl Allyl Allyl Aluminum Allyl Allyltrichlorosilane, Allyl Allylamine Aluminum Aluminum Aluminum Aluminum Aluminum Aluminum
(1)
bols
Sym-
Go Aluminum ferrosilicon powder 4.3 UN1395 4,3, A19, 1B5, P2, T3, TP33 151 212 .... 242 .,.. 15 kg 50 kg A 39, 40, -U 6.1. 52, 53, 85, 103 (D Ill 4,3, Aig, A20, lB4 151 213 .... 241 .... 25 kg 100 kg A 39, 40, z 6.1. 52, 53, (D 85, 103 0 Aluminum hydride 4.3 UN2463 Ill 4.3 A19, N40 None 211 .... 242 Ill .... Forbidden 15 kg E D Aluminum, molten 9 NA9260 9 183, Ti, TP3 None None 247 .... Forbidden Forbidden D 0. Aluminum nitrate 5.1 UN1438 5.1 Al, A29, 68, lP3, Ti, 152 213 .... 240 .... 25 kg 100 kg A = TP33 0 Aluminum phosphate solution, see N Corrosive liquids, etc. 0 Aluminum phosphide 4.3 UN1397 4.3, A8, A19, N40 None ... 211 .... 242 .... Forbidden 15 kg E 40, 52, 0. 6.1. 0 85 C Aluminum phosphide pesticides 6.1 UN3048 6.1 A8, lB7,IPi, T6, TP33 None ... 211 .... 242 .... Forbidden 15 kg E 40, 85 U, Aluminum powder, coated 4.1 UN1309 II 4.1 88, 1P2, 1P4,T3, TP33 151 212 .... 240 .... 15 kg 50 kg A 13, 39, 52, 53, 0 74, 101 4.1 Ill lB8, 1P3,Ti, TP33 151 213 .... 240 .... 25 kg 100 kg A 13, 39, 0 52, 53, 74, 101 0(I, Aluminum powder, uncoated 4.3 UN1396 4.3 A19, A20, 1B7,lP2, T3, 151 212 .... 242 .... 15 kg 50 kg A 39, 52, cn TP33 53 0 Ill 4.3 1B8, A19, A20, lP4, Ti, 151 213 .... 241 .... 25 kg 100 kg A 39, 52, 0 C) Ill TP33 53 Aluminum resinate 4.1 UN2715 Ill 4.1 1B6,Ti,TP33 151 213 .... 240 .... 25kg 100 kg A Aluminum silicon powder, uncoated 4.3 UN1398 4.3 Al, A19, lB8, 1P4, Ti, 151 213 .... 241 .... 25 kg 100 kg A 39, 40, > TP33 52, 53, 0. 85, 103 3 Aluminum smelting by-products or 4.3 UN3170 4.3 128, BuS, 1B7, 1P2, T3, None ... 212 .... 242 .... 15 kg 50 kg B 85, 103 Aluminum remelting by-products. TP33 Ill 4.3 128, BuS, 188, P4, Ti, None ... 213 .... 241 .... 25 kg 100 kg B 85, 103 TP33 0 Amatols, see Esplosives, blasting, -4 type B. 13 Amine, flammable, corrosive, no.s. 3 UN2733 3, 8 T14, TP1, TP27 None ... 201 .... 243 .... 0.5 L 2.5 L D 40, 52 or Polyamines, flammable, corro sive, no.5. Ill
13 3, 8 182, Tii, TP1, TP27 150 202 .... 243 .... 1 L 5 L B 40, 52 3, 8 Bi, lB3, T7, TP1, TP28 150 203 .... 242 .... 5 L 60 L A 40, 52 Amine, liquid, corrosive, flammable, 8 UN2734 8, 3 A3, AS, N34, T14, TP2, None 201 .... 243 .... 0.5 L 2.5 L A 52 13 no.s, or Polyamines, liquid, corro TP27 sive, flammable, no.s.
8, 3 1B2,Ti 1, TP2, TP27 None 202 .... 243 .... 1 L 30 L A 52 Amines, liquid, corrosive, no.s., or 8 UN2735 8 A3, A6, 810, N34, Ti4, None 201 .... 243 .... 0.5 L 2.5 L A 52 (0) Polyamines, liquid, corrosive, no.5.. Ill TP2, TP27 8 B2, 182, TIl, TP1, TP27 154 202 .... 242 .... 1 L 30 L A 52 8 lB3, T7, TP1, 8 TP28 154 203 .... 241 .... 5 L 60 L A 52 G Amines, solid, corrosive, no.s., or 8 UN3259 lB7, lPl, T6, TP33 None ... 211 242 .... 1 kg 25 kg A 52 Polyamines, solid, corrosive no.5.. §172.101 HAZARDousMATERIALsTABLE—Continued cm -J (8) (9) (10) 1” Vessel Packaging Quantity limitations stowage Sym- Hazardous materials Hazard Identi- 73,***) C descriptions Label Speciat provisions 1 (see 173.27 and bots and proper shipping names class or tication PG ( § Division Numbers Codas ( 172.102) — — 175.75) Excep- Non- Other tions bulk Butk Passenger Cargo air- hon aircraWrait craft only
(1) (2) (3) (4) (5) (6) (7) (8A( (88) (8C( (9A) (9B) (1OA( (lOB)
II 8 188, P2, 1P4, T3, TP33 154 212 240 15 kg 50kg A 52 Ill 8 168, P3, Ti, TP33 154 213 240 25 kg 100kg A 52 2-Amino-4-chtorophenot 6.1 UN2673 It 6.1 88, P2, P4, T3, TP33 153 212 242 25 kg 100kg A 6.1 6.1 2-Amino-5-diethylaminopentane UN2946 Ill 1B3,T4, TP1 153 203 241 60 L 220L A 2-Amino-4,6-Dinitrophenol, wetted 4.1 UN3317 4.1 23, A8, Aig, A20, 1941 None 211 None I kg 15kg 8 28, 36 with not less than 20 percent wafer by mass, 2-(2-Aminoethosy) ethanol 8 UN3055 III 8 83, T4, TP1 154 203 241 5L 60L A 8 N-Aminoethylpiperazine UN2815 III 8 tB3, T4, TP1 154 203 241 60L A 12 + 5L Aminophenols (. m-; p-) 6.1 UN2512 III 6,1 lB8, 1P3, TI, TP33 153 213 240 100 kg 200kg A Aminopropyldiethanolamine, see Amines, etc. n-Aminopropylmorpholine, see Amines, etc. Aminopyridines (o-; m-; p-) 6.1 UN2671 II 6.1 88, P2, 1P4, T3, TP33 153 212 242 25 kg 100kg B 12, 40, 52. Ammonia, anhydrous 2.3 UN1005 2.3,8 4, N87, T50 None 304 314, Forbidden Forbidden D 40, 52, 315. 57 D Ammonia, anhydrous 2.2 UN1005 2.2 13, T50 None 304 314, Forbidden Forbidden D 40, 52, 315. 57 Ammonia solution, relative density 2.3 UN3318 2.3,8 4, N87, T50 None 304 314, Forbidden Forbidden D 40, 52, less than 0.880 at 15 degrees C in 315. 57 C) water, with more than 50 percent -n ammonia. 0 Ammonia solution, relative density 2.2 UN3318 2.2 13, T50 None ... 304 .... 314, Forbidden Forbidden D 40, 52, C-) less than 0.880 at 15 degrees C in 315. 57 water, with more than 50 percent ammonia. Ammonia solutions, relative density 2.2 UN2073 2.2 N87 306 304 .... 314, Forbidden 150kg F 40, 52, less than 0.880 at 15 degrees C in 315. 57 water, with more than 35 percent but not more than 50 percent am monia. C Ammonia solution, relative density 8 UN2672 III 8 183, 1P8, T7, TP1 1S4 203 .... 241 5L 60L A 40, 52, m between 0.880 and 0.957 at 15 de 85 0 grees C in wate, with more than 10 percent but not more than 35 0 percent ammonia. 5.1
Ammonium arsenate 6.1 UN1546 II 6.1 1B8, P2, 1P4, T3, TP33 153 .... 212.... 242.... 25 kg 100 kg A 53 -U Ammonium aside Forbidden V Ammonium bitluoride, solid, see Am CD monium hydrogen ditluoride, solid. CD Ammonium bifluoride solution, see Ammonium hydrogen difluoride, II a solution. II II a- Ammonium bromate Forbidden = Ammonium chlorate Forbidden a Amrnonium dichromate 5.1 UN1439 5.1 1B8, 1P2, 1P4, T3, TP33 152 212 242 5 kg 25 kg A 52 N Arnrnonium dinitro-o-cresolate, solid 6.1 UN1843 6.1 lB8, 1P2, 1P4, T3, TP33 153 212 242 25 kg 100 kg B 36, 65, a 66, 77 a B Ammonium dinitro-o-cresolste solu 6.1 UN3424 6.1 162, T7, 153 202 0 TP2 243 5L 60 L 36, 66, C tion. 78, 91 (I, 6.1 153 Ill 182, T7, TP2 203 241 60 L 220 L A 36, 66, 6.1 78, gi 6.1 A a Ammonium fluoride 6.1 UN2505 Ill 188, 1P3, Ti, TP33 153 213 240 100 kg 200 kg 52 6.1 A CD Ammoniurn fluorosilicate UN2854 168, 1P3, TI, TP33 153 213 240 100 kg 200 kg 52 Ammonium fulminate Forbidden a A (n Ammonium hydrogen sulfate 8 UN2506 II 8 1B8, 1P2, lP4, T3, TP33 154 212 240 15 kg 50 kg A 40 II Cd) Ammonium hydrogendiftuoride, solid 8 UN1727 8 188, lP2, lP4, N34, T3, 154 212 240 15 kg 50 kg 25, 40, II a TP33 52 8 CD Ammonium hydrogendifluoride, solu UN2817 8, 6.1 162, N34, T8, TP2, TP13 154 202 243 1L 30 L B 40 tion. 8, 6.1 154 B Ill lB3, N3,T4, TP1 , TPI3 203 241 5L 60 L 40, 95 Ammonium hydrosulflde, solution, a- see Ammonium sulfide solution. 3 D Ammonium hydroxide, see Ammonia solutions, etc. 6.1 Ammonium metavanadate 6.1 UN2859 lB8, lP2, 1P4, T3, TP33 153 212.... 242.... 25 kg 100 kg A 44, 89, 0 100, - 141 Ammonium nitrate based fertilizer 5.1 UN2067 III 5.1 52, 150, 1B8, 1P3, Ti, 152 213.... 240.... 25 kg 100kg B 48, 59, TP33 60, 66, 117 AW An,monium nitrate based fertilizer 9 UN2O71 III 9 132, lB8, lP3 155 213.... 240.... 200 kg 200kg A Ammonium nitrate emulsion or Am 5.1 UN3375 II 5.1 147, 163 None ... 214 .... 214 Forbidden Forbidden D 48, 59, monium nitrate suspension or Am 60, 66, monium nitrate gel, intermediate 124 for blasting explosives. D Amrnonium nitrate-fuel oil mixture i.5D NA0331 II 1.5D None ... 62 None Forbidden Forbidden 10 196 containing Only prilled ammonium (0) nitrate and fuel oil. Ammonium nitrate, liquid (hot con 5.1 UN2426 B5,T7INone ...INone 243 Forbidden Forbidden D 59, 60 centrated solution). C § 172.101 HAzARDousMATERIALSTABLE—Continued Go,
(8) (9) (10) Vessel Hazard Identi- Packaging Quantity limitations stowage C Sym- Hazardous materials descriptions class Label Special provisions 173.) (see 173.27 and bols and proper shipping names or fication PG Codes ( § Division Numbers ( 172.102) — — 175.75) Excep- Non- Bulk Lt1oc Other tions bulk Passenger Cargo air- aircraft/rail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (88) (8C) (9A) (9B( (1OA) (lOB)
Ammonium nitrate, with more than 1.10 UN0222 II 1.10 None 62 None Forbidden Forbidden 10 19E 0.2 percent combustible sub stances, including any organic sub stance calculated as carbon, to the exclusion of any other added sub stance. Ammonium nitrate, with not more 5.1 UN1942 III 5.1 Al, A29, lB8, IP3, Tl, 152 213.... 240.... 25 kg 100kg A 48, 59, than 0.2% total combustible mate TP33 60, 116 ria including any organic sub stance, calculated as carbon to the exclusion of any other added sub stance, Ammonium nitrite Forbidden Ammonium perchlorate 1.10 UN0402 1.10 107 None 62 None Forbidden Forbidden 10 198 Ammonium perchlorate 5.1 UN1442 5.1 107, A9, lB6,1P2, T3, 152 212 242 5 kg 25kg E 58, 69 TP33 Ammonium permanganate Forbidden Ammonium persulfate 5.1 UN1444 III 5.1 Al, A29, 88, P3, Ti, 152 213 240 25 kg 100kg A TP33 Ammonium picrate, dry or wetted 1.10 UN0004 1.10 None 62 None Forbidden Forbidden 10 5E, with than 10 less percent water, by 19E ‘0 mass. C) Ammonium picrate, wetted with not 4.1 UN131O 4.1 23, A2, N4l None ... 211 .... None 0.5 kg 0.5kg 0 28, 36 -I, less than 10 percent water, by mass. 0 Ammonium polysulfide, solution 8 UN2818 8, 6.1 lB2, T7, TP2, TP13 154 202 243 lL 30L B 12, 40, p. 52 Ill 8, 6.1 lB3,T4,TPI,TP13 154 203 241 5L 60L B 12, 40, 52 Ammonium polyvanadate 6.1 UN2861 6.1 188, lP2, P4, T3, TP33 153 212 242 25 kg 100kg A 44, 89, 100, 141 Ammonium silicofluoride, see Ammo C nium tluorosilicate. m Ammonium sulfide solution 8 UN2683 8,6.1, IB1, T7, TP2, TPI3 154 202 243.... 1L 30L B 12, 22, 0. 3. 52, 100 Ammunition, blank, see Cartridges 0 for weapons, blank. Ammunition illuminating with or with- 1.2G UNO171 II 1.2G 62 62 ,.., Forbidden Forbidden 03 out burster, expelling charge or propelling charge. CD Ammunition, illuminating with or with- 1.3G UN0254 II 1.3G 62 62 Forbidden Forbidden 03 out burste, expelling charge or CD propelling charge. 0 Ammunition, illuminating with or with- 1.4G UN0297 II 1.4G 62 62 Forbidden 75 kg 02 out burster, expelling charge or propelling charge. X Ammunition, incendiary liquid or gel, 1.3J UN0247 II l.3J 62 None Forbidden Forbidden 04 236 with burste, expelling charge or Q propelling charge. a Ammunition, incendiary (water-a cti- 0 vated contrivances) with burster, expelling charge or propelling charge, see Contrivances, water- activated, etc.. 0 Ammunition, incendiary, white phos- 1.2H UN0243 II 1.2H 62 62 Forbidden Forbidden 08 86, CD phorus, with burster, expelling 14E, charge or propelling charge. 15E, 17E Ammunition, incendiary, white phos- 1.3H UN0244 II 1.3H 62 62 Forbidden Forbidden 08 8E, phorus, with burste, expelling 146, charge or propelling charge. 156, — 17E Ammunition, incendiary with or with- I.2G UN0009 1.2G 62 62 Forbidden Forbidden 03 out burster, expelling charge, or propelllng charge. — Ammunition, incendiary with or with- 1.3G UNOO1O II 1.3G 62 62 Forbidden Forbidden 03 out burste, expelling charge, or propelling charge. Ammunition, incendiary with or with- 1.4G UNO300 II 1.4G 62 62 Forbidden 75kg 02 out burster, expelllng charge or propelling charge. Ammunition, practice 1.4G UN0362 II 1.4G 62 62 Forbidden 75kg 02 Ammunition, practice 1.3G UN0488 II 1.3G 62 62 Forbidden Forbidden 03 Ammunition, proot 1.4G UN0363 II 1.4G 62 62 Forbidden 75kg 02 Ammunition, rocket, see Warheads rocket etc. Ammunition, SA (small arms), see Cartridges tor meapons, etc. Ammunition, smoke (water-activated contrivances), white phosphorus, with burster, expelling charge or propelllng charge, see Contri vances, water-activated, etc. (UN 0248). §172.101 HAzARDousMATERIALSTABLE—Continued
(8) (9) (10) Vessel Hazard Iclenti- Packaging Quantity limitations stowage C Sym- Hazardous materials descriptions Label Special provisions 173.) (see 173.27 and bole and proper shipping names class or fication PG ( § Division Numbers Codes ( 172.102) — 175.75) Excep- Non- Lttocna Other fions bulk Bulk Passenger Cargo air- aircraWrail craftonly
(1) (2) (3) (4) (5) (6) (7) (8A) (86) (8C) (9A) (9B) (1OA) (106)
Ammunition, smoke (water-activated contrivances), without white phos phorus or phosphides, with burster, expelting charge or propelling charge, see Contrivances, water- activated, etc. (UN 0249). Ammunition smoke, white phos- 1.2H UN0245 II 1.2H 62 62 Forbidden Forbidden 08 8E, phorus with bursterexpelling 14E, charge, or propelling charge. I SE, 17E Ammunition, smoke, white phos- 1.3H UN0246 II 1.3H 62 62 Forbidden Forbidden 08 86, phorus with burster, expelling 146,
charge, or propelling charge. 1SE, 17E Ammunition, smoke with or without 1.20 UNOOI5 II 1.2G 62 62 Forbidden Forbidden 8E, burster, expelling charge or propel- i 7E, ling charge. 20E Ammunition, smoke with or without 1.3G UNOO16 II 1.3G 62 62 Forbidden Forbidden 86, burster, expelling charge or propel- i 7E, ling charge. 206 Ammunition, smoke with or without 1.4G UN0303 II 1.4G 62 62 Forbidden 75kg 7E, 8E, burste, expelling charge or propel- 14E, ling charge. 1SE, 17E C) Ammunition, sporting, see Cartridges for weapons, etc. (UN 0012; UN — 0328; UN 0339). Ammunition, tear-producing, non-ex- 6.1 UN2017 II 6.1,8 None 212 None Forbidden 50kg E 13,40 0 plosive, without burster or expelling charge, non-fuzed. Ammunition, tear-producing with 1.2G UNOO18 II 1.2G 62 62 Forbidden Forbidden 8E, burste, expelling charge or propel- 8, 176, m ling charge. 6.1. 20E Ammunition, tear-producing with 1.3G UNOO19 II 1.3G, 62 62 Forbidden Forbidden 86, burster, expelling charge or propel- 8, 17E, 0 llng charge. 6.1. 20E Ammunition, tear-producing with 1.4G UNO3O1 II 1.4G. 62...... 62 Forbidden 75 kg 7E, 8E, -U burster, expelling charge or propel 8, 146, ling charge. II 6.1. I SE, (D
17E (D Ammunition, toxic, non-explosive, 6.1 UN2016 6.1 None ... 212 .... None Forbidden 100 kg E 13,40 without burster or expelling charge, non-fuzed. 0 II D Ammunition, toxic (water-activated 0. contrivances), with burste expel II x llng charge or propelling charge, 0 see Contrivances, water-activated, N etc. 0 G Ammunition, toxic with burste expel 1.2K UNOQ2O 1.2K, 62 None Forbidden Forbidden 08 SE, 0. ling charge, or propelling charge. 6.1. 0 14E, C 166, G 17E Ammunition, toxic with burster, expel 1.3K UNOO21 1.3K, 62 None Forbidden Forbidden 08 8E, 0 ling charge, or propelling charge. 6.1. 146, 15E, (It 17E 0 Amyl acetates 3 UN1104 Ill 3 Bi, 1B3,T2, TP1 150 203 242 60 L 220 L A (n Ill Amyl acid phosphate 8 UN2819 8 1B3,T4, TP1 154 203 241 SL 60 L A U, 3 3 A Arnyl butyrates UN2620 Ill Bi, 1B3,T2, TP1 150 203 242 60 L 220 L 0 3 150 Amyl chlorides UN1107 3 1B2,T4, TP1 202 242 5L 60 L B (D 3 150 Amyl formates 3 UN1109 Ill 3 Bi, lB3, T2, TP1 203 242 60 L 220 L A c-fl Amyl mercaptans UNI1I1 3 A3, A6, 1B2,T4, TP1 None 202 242 5L 60 L B 95, 102 Ill 3 n-Amyl methyl ketone 3 UN111O Bi, 1B3,T2, TP1 150 203 242 60 L 220 L A 3 0. Amyl nitrate 3 UN1112 Ill Bi, 183, T2, TPI 150 203 242 60 L 220 L A 40 Arnyl nitrites 3 UN1113 II 3 182, T4, TP1 150 202 242 5L; 60 L E 40 3 3 II 150 Arnylsmines UN11O6 3, 8 182, T7, TP1 202 243 1 L 5L B Ill 3, 8 B1, T4, TP1 150 8 83, 203 242 5L 60 L A Amyltrichlorosilane UN1728 II 8 A7, B2, 86, N34, Tb, None 206 242 Forbidden 30 L C 40 TP2, TP7, TP13 0 Anhydrous ammonia, see Ammonia, -I
anhydrous. II Anhydrous hydrofluoric acid, see Hy drogen fluoride, anhydrous. + Aniline 6.1 UN1547 6.1 182, T7, TP2 153 202 243 SL 60 L A 40, 62 Aniline hydrochloride 6.1 UN1548 Ill 6.1 168, lP3, Ti, TP33 153 213 240 100 kg 200 kg A Anlline oil, see Aniline 6.1 Ill A Anisidines UN2431 Ill 6.1 1B3,T4, TP1 153 203 241 60 L 220 L A Anisole 3 UN2222 3 81, 183, T2, TP1 150 203 242 60 L 220 L A Anisoyl chloride 8 UN1729 II 8 82, 84, 188, P2, lP4, 154 212 240 15 kg 50 kg T3, TP33 Anti-freeze, llquid, see Flammable C0) liquids, no.s.. Antimonous chloride, see Antimony -J trichloride. A Antimony compounds, inorganic, liq 6.1 UN3141 Ill 6.1 35, 1B3,T7, TP1, TP28 153 203 .... 241 .... 60 L 220 L C uid, no.s.. __
§172.101 HAzARDous MATERIALsTABLE—Continued c0)
(8) (9) (10) Vessel Hazard ldenti- Packaging Quantity limitations stowage C Sym- Hazardous materials descriptions Label Special provisions 173.) (see 173,27 and bols and proper shipping names class or fication PG Codes (172.102) ( § Division Numbers — — 175.75) Excep- Non- Bulk Other tions bulk Passenger Cargo air- tiofl aircraft/rail craftonly
(1) (2) (3) (4) (5) (6) (7) (8A) (86) (8C( (9A) (96) (1OA) (lOB)
Antimony compounds, inorganic, 6.1 UN1549 Ill 6.1 35, 1B8, 1P3, TI, TP33 153 213 240 100 kg 200 kg A solid, no.s.. 6.1 Antimony lactate UN1550 Ill 8.1 1B8,1P3, Ti, TP33 153 213 240 100 kg 200 kg A Antimony pentachloride, liquid 8 UN1730 II 8 B2, 1B2,T7, TP2 None 202 242 1L 30 L C 40 II 8 Antimony pentachloride, solutions 8 UN1731 B2, 1B2,T7, TP2 154 202 242 1L 30 L C 40 8 Ill 63, T4, TPI 154 203 241 5L 60 L C 40 Antimony pentafluoride 8 UN1732 II 8, 6.1 A3, AS, A7, Ale, 1B2, None 202 243 Forbidden 30 L D 44, 89, N3, N36, T7, TP2 100, 141 Antimony potassium tartrate 6.1 UN1551 Ill 6.1 1B8, 1P3, Ti, TP33 153 213 240 100 kg 200 kg A Antimony powder 6.1 UN2871 III 6.1 1B8, lP3, Ti, TP33 153 213 240 100 kg 200 kg A Antimony sulfide and a chlorate, mix Forbidden tures of. Antimony sulfide, solid, see Antimony compounds, inorganic, no.5.. 154 Antimony trichloride, liquid 8 UN1733 II 8 62, 1B2 202 242 1L 30 L C 40 II 154 Antimony trichloride, solid 8 UN1733 8 1B8, lP2, 1P4, T3, TP33 212 240 15 kg 50 kg A 40. Aqua ammonia, see Ammonia solu tion, etc. Argon, compressed 2.2 UN1006 2.2 306, 302 314, 75 kg 150 kg A ‘0 307. 316. C) Argon, refrigerated liquid (ciyogenic 2,2 UN1951 2.2 T75, TP5 320 316 318 50 kg 500 kg B -n liquid). Arsenic 6.1 UN1558 6.1 lB8, 1P2, 1P4, T3, TP33 153 212 242 25 kg 100 kg A C) Arsenic acid, liquid 6.1 UN1553 6.1 T20, TP2, TP7, TP13 None 201 243 1L 30 L B 46 6.1 Arsenic acid, solid UN1554 6.1 168, lP2, 1P4, T3, TP33 163 212 242 25 kg 100 kg A 6.1 6.1 Arsenic bromide UN1555 1B8, lP2, P4, T3, TP33 163 212 242 25 kg 100 kg A 12,40 Arsenic chloride, see Arsenic tn- chloride. 6.1 Arsenic compounds, liquid, no.s, in UN1556 6.1 T14, TP2, TP13, TP27 None 201 243 IL 30 L B 40, 137 organic, including arsenates, -r no.s.,’ arsenifes, no.5.; arsenic C sulfides, no.5.; and organic com m pounds of arsenic, no.s.. 0 II 6.1 162, Til, TP2, TP13, 153 202.... 243.... 5L 60 L B 40, 137 TP27 B III 6.1 163, T7, TP2, TP28 153 203.... 241 60 L 220 L 40, 137 .2. None...
Arsenic compounds, solid, n.o.s. in 6.1 I UN1557 6.1 1B7,IP1,T6,TP33INone .1211 .1242 5 kg 50 kg A 137 organic. including arsenates, V n.o.s.; arsenifes, n.o.s.; arsenic CD sulfides, no.5.; and organic com pounds of arsenic, n.o.s.. 6.1 (D II 6.1 188, lP2, 1P4,T3, TP33 153 212 242 25 kg 100 kg A 137 0 Ill 6.1 lB8, 1P3, TI, TP33 153 213 240 100 kg 200 kg A 137 A Arsenic pentoxide 6.1 UN1559 II lB8, 1P2, 1P4,T3, TP33 153 212 242 25 kg 100 kg 0. Arsenic sulfide and a chlorate, mix Forbidden = tures of. 6.1 0 N Arsenic trichloride 6.1 UN1560 II 2, B9, 814, 832, T20, None 227 6.1 244 Forbidden Forbidden B 40 0 TP2, TP13, TP3B, TP45 II 0. Arsenic trioside 6.1 UN1561 188, 1P2, 1P4,T3, TP33 153 212 242 25 kg 100 kg A 0 Arsenic, white, solid, see Arsenic tn 6.1 C II (I, oxide. 3, 6.1 A Arsenical dust 6,1 UN1562 188, 1P2, 1P4,T3, TP33 153 212 242 25 kg 100 kg Arsenical pesticides, liquid, flam 3 UN2760 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L B 40 0 3, 6.1 mable, toxic, flash point less than CD 23 degrees C. 6.1 B 0 6.1 lB2, T11, TP2, TPI3, 150 202 243..... IL 60 L 40 TP27 B B Arsenical pesticides, liquid, tosic 6.1 UN2994 6.1 T14, TP2, TPI3, TP27 None 201 243 1L 30 L 40 II 1B2,T11, TP2, TP13, 153 L 202 243 5L 60 40 0CD TP27 Ill 1B3,T7, TP2, TP28 153 203 241 60 L 220 L A 40 Arsenical pesticides, liquid, toxic, 6.1 UN2993 6.1, 3 T14, TP2, TP13, TP27 None 201 243 1L 30 L B 40 > flammable, flash point not less 0. than 23 degrees C. 3 II 6.1, 3 182, Til, TP2, TP13, 153 202 243 5L 60 L B .40 TP27 Ill 6.1,3 B1, lB3, T7, TP2, TP28 153 203 242 60 L 220 L A 40 Arsenical pesticides, solid, toxic 6.1 UN2759 6.1 187, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40 0 A -I II 6.1 188, 1P2, P4, T3, TP33 153 212 242 25 kg 100 kg 40 A Ill 6.1 188, lP3, TI, TP33 153 213 240 100 kg 200 kg 40 Arsenious acid, solid, see Arsenic tn- oxide. Arsenious and mercuric iodide solu tion, see Arsenic compounds, liq uid, no.s.. Arsine 2.3 UN2188 2.3, None 192 245 Forbidden Forbidden D 40 2.1. Articles, explosive, extremely insensi 1.6N UN0486 II 1.6N 62 None Forbidden Forbidden 07
tive or Articles, EEl. II II cm G Articles, explosive, n.o.s 1.4S UN0349 II 1.4S None 62 None 25 kg 100 kg 05 G UN0350 II 62 Articles, explosive, no.s 1.4B II 1.48 None None Forbidden Forbidden 06 G Articles, explosive, n.o.s 1.4C UN0351 1,4C None 62 None Forbidden 75 kg 06 G Articles, explosive, s.o.s 1.4D UN0352 1.4D None 62 None Forbidden 75 kg 06 G C Articles, explosive, s.o.s 1.4G UN0353 1.4G.. None 62 None Forbidden 75 kg 06. None
§172.101 HAzARDous MATERIALSTABLE—Continued c0)
(8) (9) (10) Vessel Hazard Identi- Packaging Quantity limitations stowage 0 Sym- Hazardous materials descriptions Label Special provisions 173.•) (see 173.27 and bols and proper Shipping names class or fication PG ( § — Division Numbers Codes (172.102) — — 175.75) Excep- Non- Other tions bulk Bulk Passenger Cargo air- tion aircraft/rail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (86) (8C) (9A) (96) (bA) (108)
G Articles, explosive, n.o.s ilL UN0354 II IlL None 62 None Forbidden Forbidden 08 86, 14E, 158, 17E. G Articles, explosive, n.o.s 1.2L UN0355 II 1.2L None 62 None Forbidden Forbidden 08 88, 14E, 158, 17E. G Articles, explosive, no.s 1,3L UN0356 II 1.3L 62 None Forbidden Forbidden 08 88, 14E, 15E, 17E. G Articles, explosive, no.s 1.1C UN0462 II 1.1C None 62 None Forbidden Forbidden 07 G Articles, explosive, no.s 1.10 UN0463 II liD None 62 None Forbidden Forbidden 07 0 Articles, explosive, no.s 1.18 UN0464 II 1.18 None 62 None Forbidden Forbidden 07 G Articles, explosive, no.x 1.1F UN0465 II 1.1F None 62 None Forbidden Forbidden 08 G Articles, explosive, no.s l.2C UN0466 II 1.2C None 62 None Forbidden Forbidden 07 0 Articles, explosive, no.s 1.2D UN0467 II 1.20 None 62 None Forbidden Forbidden 07. G Articles, explosive, no.5 1.2E UN0468 II 1.2E... None 62 None Forbidden Forbidden 07 G Articles, explosive, no.s 1.2F UN0469 II 1.2F None 62 None 08 G Forbidden Forbidden Articles, explosive, n.o.s 1.3C UN0470 II 1.3C G None 62 None Forbidden Forbidden 07 Articles, explosive, no.s 1.4E UN0471 II 1.4E... G None 62 None Forbidden 75 kg 06 C, Articles, explosive, no.s 1.4F UN0472 II 1.4F None 62 None Forbidden Forbidden 08 -TI Articles, pressurized pneumatic or 2.2 UN3164 2.2 306 302, None No limit No limit A hydraulic containing non-flammable 304. C) gas. Articles, pyrophoric I .2L UN0380 II 1.2L None 62 None Forbidden Forbidden 08 88, 148, 158, 178 Articles, pyrotechnic for technical 1.10 UN0428 Il 1.1G.. None 62 None Forbidden Forbidden 07 purposes. Articles, pyrotechnic for technical 1.2G UN0429 II 1.2G None 62 None Forbidden Forbidden 07 C purposes. m Articles, pyrotechnic for technical 1.3G UN0430 II 1.30 None 62 None Forbidden Forbidden 07 0. purposes. Articles, pyrotechnic for technical I .4G UN0431 II 1.4G None 62 None Forbidden 75 kg 06 0 purposes. Articles, pyrotechnic for technical 1.4S UN0432 II 1.4S None 62 None 25 kg 100 kg 05 -U purposes. -o D Asbestos 9 NA2212 Ill 9 156, 168, 1P2,1P4 155 216 240 200 kg 200 kg A 34, 40 (D Ascaridole (organic peroxide) Forbidden D 3 D Asphalt, at or above its flash point 3 NA1999 Ill 163, Ti, TP3 150 203 247 Forbidden Forbidden D m Asphalt, cut back, see Tars, liquid, etc. 0 Automobile, motorcycle, tractor, other 0. self-propelled vehicle, engine, or = other mechanical apparatus, see 0 Vehicles or Battery etc. 9 N 9 155 AG Aviation regulated liquid, n.o.s 9 UN3334 A35 204 No limit No limit A 0 155 AG Aviation regulated solid, n.o.s 9 UN3335 A35 204 No limit No limit A 0. Azaurolic acid (salt o (dry) Forbidden 0 Azido guanidine picrate (dry) Forbidden C0 5-Azido-l-hydroxy tetrazole Forbidden Azido hydroxy tetrazole (mercury and Forbidden silver salts). 0 3-Azido-l,2-Propylene glycol dinitrate Forbidden (D Azidodithiocarbonic acid Forbidden Azidoethyl nitrate Forbidden 0 1-Aziridinylphosphine oxide-(tris), see Tria-(1-aziridinyl) phoaphine oside, U, solution. 0 (D Azodicarbonamide 4.1 UN3242 II 4.1 38, 168, T3, TP33 151 223 240 Forbidden Forbidden 0 2, 52, cc 53, 74 Azotetrazole (dry) Forbidden 151 Barium 4.3 UN1400 II 4.3 A19, 167, P2, T3, TP33 212 241 15 kg 50 kg B 52 0. D Barium alloys, pyrophoric 4.2 UN1854 I 4,2 T21, TP7, TP33 None 181 None Forbidden Forbidden 3 Barium azide, dry or wetted with less hA UN0224 II hA, 111, 117 None 62 None Forbidden Forbidden 12 than 50 percent water, by mass. 6.1.
Barium azide, wetted with not less 4.1 UN1571 I 4.1, 162, A2 None 182 None Forbidden 0.5 kg D 28 than 50 percent water, by mass. 6.1. 0 Barium bromate 5.1 UN2719 II 5.1, 168, 1P2, 1P4, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 -I 6.1. Barium chlorate, solid 5.1 UN1445 II 5.1, A9, lB6, lP2, N34, T3, 152 212 242 5 kg 25 kg A 56, 58 6.1. TP33 Barium chlorate, solution 5.1 UN3405 II 5.1, A9, 62, N34, T4, TP1 152 202 243 1L 5L A 56, 58, 6.1. 133 152 A 5.1, A9, lB2, N34, T4, TP1 203 242 2.5 L 30 L 56, 58, 6.1. 133 6.1 153 Barium compounds, no.5 UN1564 6.1 1B8, P2, 1P4, T3, TP33 212 242 25 kg 100 kg A 153 6.1 lii 6.1 68, P3, Ti, TP33 213 240 100 kg 200 kg A 6.1 A Barium cyanide UN1565 I 1B7, IP1, N74, N75, T6, None 211 242 5 kg 50 kg 40, 52 5.1 TP33 5 kg c0) Barium hypochiorite with more than UN2741 II 5.1, A7, A9, 168, 1P2, 1P4, 152 212 None 25 kg B 4, 52, 22 percent available chlorine. 6.1. N34, T3, TP33 56, 58, 106 Barium nitrate 5.1 UN1446 Si, 1B8, lP2, 1P4, T3, TP33 152 212 .... 242 5 kg 25 kg A 6.1. C §172.101 HAzARDOus MATERIALS TABLE C0)
(8) (9) (10) Vessel Hazard Identi- Packaging Quantity limitations stowage C Sym- Hazardous materials descriptions Label Special provisions 173.) (see 173.27 and bols and proper shipping names class or fication PG ( § Division Numbers Codes ) 172.102) — 175.75) Excep- - Non- Other Bulk tions bulk Passenger Cargo air- tiofl aircraft/rail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) )8B) (8C) (BA) (9B) (1OA) (lOB)
Barium oxide 6.1 UN1884 Ill 6.1 188, lP3, Ti, TP33 I53 213 240 100 kg 200 kg A Barium perchlorate, solid 5.1 UN1447 II 5.1, 186, 1P2, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 6.1. A Barium perchlorate, solution 5.1 UN3406 5.1, 1B2,T4, TP1 152 202 243 IL 5L 56, 58, 6.1. 133 Ill 5.1, 182, T4, TP1 152 203 242 2.5 L 30 L A 56, 58, 6.1. 133 Barium permanganate 5.1 UN1448 II 5.1, lB6, 1P2, T3, TP33 152 212 242 5 kg 25 kg D 56, 58, II 6.1. 138 Barium peroxide 5.1 UN1449 5.1, Ag, 86, 1P2, T3, TP33 152 212 242 5 kg 25 kg A 13, 52, 6.1. 56, 75 Barium se/enate, see Selenates or Selenites. Barium selenite, see Selenates or Selenites. Batteries, containing sodium 4.3 UN3292 4.3 189 189 189 Forbidden No limit A Batteries, dry, containing potassium 8 UN3028 Ill 8 237 None 213 None 25 kg 230 kg A 52 hydroxide solid, electric, storage. gross gross Batteries, dry, sealed, no.s 130 Batteries, wet, filled with acid, electric 8 UN2794 Ill 8 159 159 159 30 kg No limit A 146 storage. gross 8 Batteries, wet, filled with alkali, elec UN2795 Ill 8 159 159 159 30 kg No A limit 52, 146 C) tric storage. gross 8 Ill 8 Batteries, wet, non-spillable, electric UN2800 159a 159 159 No limit No limit A storage. 8 8 C) UN2796 Battery fluid, acid A3, A7,82, 815, 182, 154 202 242 IL 30 L B 8 8 N6, N34, TB, TP2 UN2797 Battery fluid, alkali B2, 1B2, N6, T7, TP2, 154 202 242 1L 30 L A 29 TP28 Battery lithium type, see Lithium bat 9 teries etc. Battery-powered vehicle or Battery- UN3171 9 134 220 220 None No limit No limit powered equipment. C Battery, wet, filled with acid or alkali m with vehicle or mechanical equip 0. ment containing an internal com bustion engine, see Vehicle, etc. or 0 Engines, internal combustion, etc. ca
+ Benzaldehyde UN1990 III 9 183, T2, TP1 155 203 241 100 L 220L A Benzerie 3 UN1114 II 3 82, T4, TPI 150 202 242 5L 60L B 40 0 Benzene diazonium chloride (thy) Forbidden CD Benzene diazonium nitrate (dry) Forbidden
Benzene phosphorus dichloride, see CD Phenyl phosphorus dichloride. Benzene phosphorus thiodichioride, 0 see Phenyl phosphorus 0. thiodichioride. x Benzene III sulfonyl chloride 8 UN2225 8 63, T4, TP1 154 203 241 5L 60 L A 40 0 Benzene triozonide Forbidden N Benzenefhiol, see Phenyl mercaptan 0 Benzidirre 6.1 UN1885 II 6.1 88, 1P2, P4, T3, TP33 153 212 242 25 kg 100 kg A 0. BenzoL see Benzene 0 C Benzonitrile 6.1 UN2224 II 6.1 182, T7. TP2 153 202 243 5L 60 L A 40, 52 v) Benzoquinone 6.1 UN2587 II 6.1 88, 1P2, 1P4, T3, TP33 153 212 242 25 kg 100 kg A Benzotrichloride 8 UN2226 II 8 B2, 182, T7, TP2 154 202 242 1L 30 L A 40 3 0 Benzotrifluoride UN2338 II 3 182, T4, TP1 150 202 242 5L 60 L B 40 Benzoxidiazoles (dry) Forbidden CD Benzoyl azide Forbidden 0 Benzoyl chloride 8 UN1736 II 8 62. 1B2, T8, TP2, TP13 154 202 242 1L 30 L C 40 (I, Benzyl bromide II 6.1 UN1737 6.1,8 A3, A7, 1B2, N33, N34, None 202 243 1L 30 L D 13, 40. U, T8, TP2, TPI3 0 Benzyl chloride 6.1 UN1738 II 6.1,8 A3, A7, 670, 62, N33. 202 None 243 1L 30 L D 13, 40. CD N42, T8, TP2, TP13 C)-’ 6.1 D Benzyl chloride unstabilized UN1738 II 6.1,8 A3, A7, 88, 811, 182, 153 202 243 1L 30 L 13,40 N33, N34, N43, T8, > TP2, TP13 0. D Benzyl chloroforrnate 8 UN1739 I 8 A3, A6, 84, N41, Tb, None 201 243 Forbidden 2.5 L 40 3 TP2, TP13 B Benzyl iodide 6.1 UN2653 II 6.1 1B2,T7, TP2 153 202 243 5L 60 L 12, 40 Benzyldimethylamine 8 UN2619 II 8,3.... 62, 1B2, T7, TP2 154 202 243 IL 30 L A 40, 48 V Benzylidene chloride 6.1 UN1886 II 6.1 82, T7, TP2 153 202 243 5L 60 L D 40 0 Beryllium compounds, n.o.s 6.1 UN1566 II 6.1 1B8, P2, 1P4, T3, TP33 153 212 242 25 kg 100 kg A -I Ill 6.1 1B8, 1P3, Ti, TP33 153 213 240 100 kg 200 kg A 5.1 Beryllium nitrate UN2464 II 5.1, 1B8, 1P2, 1P4, T3, TP33 152 212 242 5 kg 25 kg A 6.1. 6.1 A Beryllium, powder UN1567 II 6.1, 88, P2, P4, T3, TP33 153 212 242 15 kg 50 kg 4.1. Bicyclo [2,2,1) hepta-2,5-diene, sta 3 UN2251 II 3 82, T7, TP2 150 202 242 5L 60 L D bilized or 2,5-Norbornadiene, sta bilized. Biological substance, Category B 6.2 UN3373 A82 134 199 .... None 4 L or 4kg 4 L or 4kg A 40 Biphenyl triozonide Forbidden
Bipyridilium pesticides, liquid, flam 3 UN2782 I 3,6.1 T14, TP2, TP13, TP27 None .. 201 .... 243 .... Forbidden 30 L E mable, tosic, flash point less than 23 degrees C. II 3, 6.1 182,T11,TP2,TP13, 150 202 .... 243 1L 60L B 40 TP27 C Bipyridilium pesticides, liquid, tosic 6.1 UN3016 I 6.1 T14, TP2, TP13, TP27 None ... 201 .... 243 1L 30L B 40 — § 172.101 HAzARDOus MATERIALS TABLE—Continued co
(8) (9) (10) Vessel Hazard Identi- Packaging Quantity limitations stowage C Sym- Hazardous materials descriptions Label Special provisions 173.) (see 17327 and bols and proper shipping names class or fication PG ( § Division Numbers Codes (172.102) — — 175.75) Excep- Non- - Bulk Passenger Cargo air- tion Other tions bulk aircraWrail craft only
(1) (2) (3) (4) (5) (6) (7) (8A( (88) (8C) (9A( (96) (bA) (108)
II 6.1 lB2, Til, TP2, TP13, 153 202.... 243.... 5L 60 L B 40 TP27 III 6.1 1B3,T7, TP2, TP28 153 203 .... 241 60 L 220 L A 40
Bipyridilium pesticides, liquid, I toxic, 6.1 UN3015 6.1,3 T14, TP2, TP13, TP27 None 201 .... 243 IL 30 L B 21,40 flammable, flash point not less than 23 degrees C. II 6.1, 3 lB2, T11, TP2, TP13, 153 202.... 243.... 5L 60 L B TP27 21,40 III 6.1,3 81, 183, T7, TP2, TP28 153 203.... 242.... 60 L 220 L A 21,40 Bipyridiliumpesticides, eolid, toxic 6.1 UN2781 I 6.1 167, IP1, TB, TP33 None 211 .... 242 5 kg 50 kg A 40 II 6.1 lB8, 1P2, lP4, T3, TP33 153 212..,. 242.... 25 kg 100 kg A 40 III 6.1 lB8, 1P3, Ti, TP33 153 213.... 240.... 100 kg 200 kg A 40 Bis (Aminopropyl) pipera sine, see Corrosive liquid, no.s.. Bisulfate, aqueous solution 8 UN2837 II 8 A7, B2, lB2, N34, T7, 154 202.... 242.... iL 30 L A TP2 A III 8 A7, 183, N34, T4, TP1 154 203 241 5L 60 L Bisulfites, aqueous solutions, n.o.s. 8 UN2693 III 8 163, T7, TP1, TP28 154 203 241 5L 60 L A 40, 52 Black powder, compressed or Gun liD UN0028 II liD None 62 None Forbidden Forbidden 10 powder, compreseed or Black pow der, in pellets or Gunpowder, in pellets. (.) Black powder or Gunpowder, granu UN0027 II lID None ... 62 None Forbidden Forbidden 10 -n lar or as a meal. liD Black powder for small arms 4.1 NA0027 I 4.1 70 None ... 170 .... None Forbidden Forbidden E C) Blasting agent, no.s., see Explo sives, blasting etc. Blasting cap assemblies, see Deto nator assemblies, non-electric, for blasting. Blasting caps, electric, see Deto nators, electric for blasting. Blasting caps, non-electric, see Deto C nators, non-electric, for blasting. m Bleaching powder, see Calcium hy 0. pochlorite mixtures, etc. Blue asbestos (Crocidolite) or Brown 9 UN2212 II 9 156, 1B8, 1P2, 1P4,T3, 155 ...... 216.... 240.... Forbidden Forbidden A 34, 40 0 asbestos (amosite, mysorite). TP33 0. (D - 0 N 0. (I, 0 0 3 0 D C
C0) “U
12
40 90 40 40
74, 40, 49,
100 133
133
238 238
89, 25,40 56,58
12,40, 12,
21,28, 56,58, 56,58,
40, 66,
11 8
03 08 03 07 0 B 0 03 03 03 04 04 07 07 0 B 08 08 0 0 B A A A A A A
IC
L L
kg
kg kg
1L 5L
30L 30L 30
2.5
50kg 50 50 50kg 25kg
100
Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden
L L
kg kg kg kg
1L iL 1L
5
0.5 2.5
15kg 15 15
25
Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden
315
None None None None 62 None None None 62 None None None 62 244 243 243 62 62 240 314. 242 240 314 240 242.... 242 249.... 240.... 241.... 242......
160 62 62 62 62 62 62 62 62 62 62 62 213 304 302 62 227 212.... 201 201 202.... 212.... 202.... 226.... 202.... 212.... 203.... 212......
None None 154 154 152
None None None 154 152 None None Nons 154 154 None None None None
1152
P4, T3,
Bl4 614
TP2 TP7 TP2 TP1 TP1 TP2 TP2
N34, N43,
TP33 TP45 TP33 TP33 TP33 TPI3
TP3fl,
1P4,
89, B9, Tfl, TB, T4, T4, T7,
1P2,
Ti, Tb, T3, T3,
TP2,
832,
N34,
3, 2,
P2,
TPIO.
182, 1B2, 1B2, TPI3, 182, 1B2,
188,
1P3,
1P4,
A19,
Tb,
B14,
BBS,
B2, 86,
1B8,
86,
TP2,
TP2,
188,
1P2, A3,
B9,
B9,
A19,
B2,
B2,
B2,
2, 1,
T22, Al,
T20, IBS,
8,
6.1
3.
1.2F 1.18 1.20 liE 1.20 1.10 1.10 l.3G 1.10 1.1J 1.2J 1.2B 1.20 1.1F... 8,6.1 2.3,8 8 8,3.... B 8 5.1 8 2.3,8 5.1 5.1 8 4.3, 8 8, 4.1
I I I
II II II II II II II II II II II II II II II II II II II II II II
III Ill
1450 1744
UN0225 UN1741 UN0039 UN2028 UN0033 UN0035 UN0042 UN2692 UN0038 UN0299 UN0034 UN0399 UNO400 UN0268 UN0283 UN1312 UN100fl UN1742 UN0037 UN0291 UN3419 UN2604 UN1743 UN3213 UN UN2965 UN3420 UN UN2851
8 8. 8 B 8 8 8 8
2.3
2.3 5.1 5.1 4.1 4.3
1.1J 1.2J
1.IF 1.1F 1.2F
1.1B 1.2B 1.10 1.20 1.10 1.20 1.10 1.2G I.3G
see
with with with
solu
corn com etc
initiating
complex, complex,
acid
acid
liquid, liquid,
etherate
etherate
acid acid
mixtures,
mixtures.
aqueous
charge charge charge charge
no.5
without
Nitrocellulose
detonator detonator
non-explosive,
propionic propionic
acetic acetic
dihydrate diethyl dimethyl
borate
detonator detonator flammable flammable see
chlorate
bursting bursting bursting bursting liquid,
inorganic,
and
charge. charge. inorganic,
without without
with with
smoke,
with with with with with gum, photo-flash with photo-Sash photo-flash photo-Sash and
solid.
liquid.
no.5..
trifluoride trifluoride
trifluoride tritluoride trichloride tribromide trifluoride trifluoride trifluoride trifluoride
toe
corrosive Chlorate device. plex, plex, bursting bursting liquid. solid. tion,
Bombs, Bombs, Bombs, Boosters Boosters, Boron Boron Bombs, Bombs, Bombs, Bombs Boosters Borate Borneol Boron Box Bombs, Bombs, Bombs, Bombs Boosters, Boron Boron Boron Boron Boron Boron Bromates, Bromine Boron Broniates,
+ +
= 0 62 Cd) § 172101 HazARDous MATERIALSTABLE—Continued C0) —I (8) (91 (10) Vessel Hazard Identi- Packaging Quantity limitations stowage 0 Sym- Hazardous materials descriptions Label Special provisions 173.) (see 173.27 and bols and proper shipping names class or fication PG ( § Division Numbers Codes ( 172.102) — 175.75) Excep- Non- Other tions bulk Bulk Passenger Cargo air- o aircraft/rail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (88) (BC) (9A( (9B) (1OA( (lOB)
Bromine azide Forbidden Bromine chloride 2.3 UN2901 2.3, 8, 2, B9, B14, N86 None ... 304 .... 314, Forbidden Forbidden 0 40, 89, 5.1. 315, 90 + Bromine pentafluoride 5.1 UN1745 5.1, 1, 99, B14, B30, T22, None ... 228 .... 244 Forbidden Forbidden D 25, 40, 6.1, TP2, TP13, TP38, TP44 66, 90 8. + Bromine solutions 8 UN1744 8, 6.1 1, B9, B85, N34, N43, None ... 226 .... 249 Forbidden Forbidden 0 12, 40, T22, TP2, TPIO, TP13 66, 74, 8 89, 90 + Bromine solutions UN1744 8, 6.1 2, B9, B85, N34, N43, None ... 227 .... 249 Forbidden Forbidden 0 12, 40, T22, TP2, TP1O, TP13 66, 74, 89, 90 Bromine trifluoride 5.1 UN1746 5.1, 2, B9, B14, 832, T22, None 228.... 244.... Forbidden 25, 40, + Forbidden 0 6.1, TP2, TP13, TP38, TP45 66, 90 8. 4-Bromo-1,2-dinitrobenzene Forbidden 4-Bromo-1,2-dinifrobenzene (unsta Forbidden ble at 59 degrees C). 1-Bromo-3-chloropropane 6.1 UN2688 Ill 6.1 1B3,T4, TP1 153 203 241 60 L 220 L A Ill 1-Bromo-3-methylbutane 3 UN2341 3 Bi, 193, T2, TP1 ISO 203 242 60 L 220 L A l-Bromo-3-nitrobenzene (unstable at Forbidden 56 degrees C). C) 2-Bromo-2-nitropropane-l ,3-diol 4.1 UN3241 Ill 4.1 46, 198, 1P3 151 213 None 25 kg 50 kg C 12, 25, ‘.1 40 Bromoacetic acid, solid 8 UN3425 II 8 A7, 1B8,1P2, 1P4,N34, 154 212 240 15 kg 50 kg A C, II T3, TP33 8 8 Bromoacetic acid solution UN1938 A7, 92, 1B2,T7, TP2 154 202 242 1L 30 L A 40 8 Ill 92, 193, T7, TP2 154 203 241 5L 60 L A 40 Bromoacetone 6.1 UN1569 II 6.1,3 2, T20, TP2, TP13 None 193 245 Forbidden Forbidden 0 40 + II Bromoacetyl bromide 8 UN2513 8 B2, 1B2,T8, TP2 154 202 242 1L 30 L C 40, 53 Bromobenzene 3 UN2514 Ill 3 B1, lB3, T2, TP1 150 203 242 60 L 220 L A Bromobenzyl cyanides, liquid 6.1 UN1694 6.1 T14, TP2, TP13 None 201 243 Forbidden 30 L 0 12, 40, 52 0 Bromobenzyl cyanides, solid 6.1 UN3449 6.1 T6, TP33 None 211 242 5 kg 50 kg 0 12, 40, m 52 0. l-Bromobutane UN1126 II 3 1B2,T4, TP1 ISO 202 242 5L 60 L B 40 II 2-Bromobutane 3 UN2339 3 81, 192, T4, TPI 150 202 242 5L 60 L B 40 0 Bromochloromethane 6.1 UN1887 Ill 6.1 1B3,T4, TP1 153 203 241 60 L 220 L A 2.1
2-Bromoethyl ethyl ether 3 UN2340 II 3 182, T4, TP1 150 202 242 5L 60 L B 40 Bromoform 6.1 UN2515 Ill 6.1 183, T4, TP1 153 203 241 60 L 220 L A 12,40 V Brornomethylpropanes 3 UN2342 II 3 1B2,T4, TP1 150 202 242 5L 60 L B CD 3 II 3 150 B 2-Bromopentane UN2343 II 1B2,T4, TP1 202 242 5L 60 L 3 150 B Bromopropanes UN2344 3 162, T4, TP1 202 242 60 L 40 CD 3 150 5L Ill 1B3,T2, TP1 203 242 60 L 220 L A 3 150 0 3-Bromopropyne UN2345 II 3 1B2,T4, TP1 202 242 5L 60 L D 40 Bromosilane Forbidden 0. Bromotoluene-aipha, see Benzyl bro x mide. B 0 Bromotrifluoroethylene 2.1 UN2419 2.1 None 304 314, Forbidden 150 kg 40 N II 315, 0 Bromotrifluoromethane or Refrigerant 2.2 UN1009 2.2 T50 306 304 314, 75 kg 150 kg A 0 gas, R 13B1.. 0 315. C Brucine 6.1 UN1570 6.1 1B7, P1, T6, TP33 None 211 242 5 kg 50 kg A C’, Bursters, explosive liD UN0043 liD None... 62 None Forbidden Forbidden 07 Butadienes, stabilized or Butadienes 2.1 UN1O1O 2.1 T50 306 304 314, Forbidden 150 kg B 40 and Hydrocarbon mixture, sta 315. 0 bilized containing more than 40% CD butadienes. 0 Butane see also Petroleum gases, 2.1 I UN1O11 19, T50 306 304 314, Forbidden 150kg E 40 Cd, liquefied. 315. C’, Butane, butane mixtures and mix 0 in tures having similar properties CD 500 C)I cartridges each not exceeding C.,, grams, see Receptacles, etc. Butanedione 3 UN2346 II 3 1B2,T4, TPI 150 202 242 5L 60L B 0. 1,2,4-Butanet riol trinitrate Forbidden II Butanols 3 UNII2O 3 162, T4, TP1, TP29 150 202 242 5L 60L B 3 Ill 3 81, 183, T2, TP1 150 203 242 60 L 220L A tert-Butoxycarbonyl azide Forbidden 3 Butyl 3 UN1123 II lB2, T4, TPI 150 202 acetates 3 242 5L 60L B Ill 8 81, 183, T2, TP1 150 203 242 60 L 220L A 0 Butyl acid 8 UN1718 Ill lB3, T4, 203 -4 phosphate Ill 3 TPI 154 241 5L 60L A Butyl acrylates, stabilized 3 UN2348 BI, 1B3,T2, TP1 150 203 242 60 L 220L A Butyl alcohols, see Butanols Ill 3 3 Butyl benzenes UN2709 81, 1B3,T2, TP1 150 203 242 60 L 220L A n-Butyl bromide, see 1-Bromobutane n-Butyl chloride, see Chlorobutanes D sec-Butyl chlorotormate 6.1 NA2742 6.1,3, 2, 89, 814, 832, 874, None 227 244 Forbidden Forbidden A 12, 13, 8. T20, TP4, TP13, TP38, 22, 25, TP45 40, 48, 100 n-Butyl chlorotormate 6.1 UN2743 6.1, 8, 2, 89, 814, 832, T20, None 227 .... 244 Forbidden Forbidden A 12, 13, 3. TP2, TP13, TP38, TP45 21, 25, C0 40, 100 Butyl ethers, see Dibutyl ethers Butyl ethyl ether, see Ethyl butyl ether. C n-Butyl tormate 3 UN1128 3 82, T4, TP1 150 202.... 242.... 5L 60 L B § 172.101 HAzARDousMATERIALSTABLE—Continued La,
(8) (9) (10) Vessel Hazard Ideriti- Packaging Quantity limitations stowage C Sym- Hazardous materials descriptions Label Special provisions (l73.**) (see §173.27 and bols and proper shipping names class or fication PG Division Numbers Codes (172.102) — 175.75) Excep- Non- Bulk Lna• Other tions bulk Passenger Cargo air- aircraft/rail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C( (9A) )9B( (1OA) (lOB)
tert-Butyl hydroperoxide, with more Forbidden than 90 percent with water. tert-Butyl hypochiorite 4.2 UN3255 4.2, 8 None 211 243 Forbidden Forbidden D N-n-Butyl imidazole 6.1 UN2690 II 6.1 82, T7, TP2 153 202 243 5L 60 L A tert-Butyl isocyanate 6.1 UN2484 6.1, 3 1, B9, B14, 830, 872, None 226 244 Forbidden Forbidden D 40 T22, TP2, TP13, TP38, TP44 ri-Butyl isocyanate 6.1 UN2485 6.1,3 2, 89, 814. 832, 877, None ... 227 ,... 244 Forbidden Forbidden 8 40 T20, TP2, TP13, TP38, TP45 Butyl mercaptans 3 UN2347 3 A3, A6, lB2, T4, TP1 150 202 242 5L 60 L B 52, 95 3 n-Butyl wethacrylate, stabilized UN2227 Ill 3 Bi, 183, T2, TP1 150 203 242 60 L 220 L A 3 3 cri Butyl methyl ether UN2350 II 162, T4, TP1 150 202 242 5L 60 L B 3 Butyl nitrites 3 UN2351 Til, TP1, TP8, TP27 150 201 243 1L 30 L E 40 3 II 162, T4, TP1 150 3 202 242 5L 60 L B 40 Ill Bi, 183, T2, TPI 150 203 242 60 L 220 L A 40 tert-Butyl peroxyacetate, with more Forbidden than 76 percent in solution. n-Bulyl peroxydicarbonate, with more Forbidden than 52 percent in solution. tert-Butyl peroxyisobutyrate, with Forbidden ‘0 more than 77 percent in solution. C) Butyl phosphoric acid, see Butyl acid ,, phosphate. 70 Butyl propionates 3 UN1914 Ill 3 Bi, 183, T2, TPI 150 203 242 60 L 220 L A C-) 5-tert-Butyl-2,4,6-trinitro-m-xylene or 4.1 UN2956 Ill 4.1 159 None 223 None Forbidden Forbidden D 12, 25, p. Musk xylene. 48, 127 Butyl vinyl ether, stabilized 3 UN2352 It 3 182, T4, TPI 150 202 242 5L 60 L B 40 n-Butylamine 3 UN1125 II 3, 8 162, T7, TP1 150 202 242 1L 5L 8 40 N-Butylaniline 6.1 UN2738 II 6.1 182, T7, TP2 153 202 243 5L 60 L A 74 tert-Butylcyclohexylchloroforniate 6.1 UN2747 Ill 6.1 183, T4, TP1 153 203 241 60 L 220 L A 12, 13, 25 Butylene see also Petroleum gases, 2.1 UN1012 2.1 19, T50 306 304 314, Forbidden 150 kg E 40 C liquefied. 315. m I ,2-Butylene oxide, stabilized 3 UN3022 II 3 82, T4, TP1 150 202 242 5L 60 L B 27. 49 0. Butyltoluenes 6.1 UN2667 Ill 6.1 183, T4, TP1 153 203 241 60 L 220 L A Butyltrichlorositane 8 UN1747 II 8, 3 A7, 82, 86, N34, Tb, None 206 243 Forbidden 30 L C 40 0 TP2, TP7, TP13 1,4-Butynediol 6.1 UN2716 Ill 6.1 1B8, Al, P3, Ti, TP33 None •. 213 .... 240 100 kg 200 kg C 52, 53, 70 Butyraldehyde 3 UN1129 3 lB2, T4, TP1 150 202 242 5L 60 L B (D 3 Butyraldoxime UN2840 Ill 3 81, 1B3,T2, TP1 150 203 242 60 L 220 L A Butyric acid 8 UN2820 Ill 8 1B3, T4, TP1 154 203 241 5L 60 L A 12 (p Ill A Butyric anhyctride 8 UN2739 8 1B3,T4, TP1 154 203 241 5L 60 L a 3 Butyronitrile UN241 1 3. 6.1 lB2, T7, TP1, TP13 150 202 243 1L 60 L F 40 3 a. Butyryl chloride UN2353 3, 8 lB2, T8, TP2, TP13 150 202 243 lL 5L C 40 = Cacodylic acid 6.1 UN1572 6.1 lB8. lP2, 1P4,T3, TP33 153 212 242 25 kg 100 kg F 52 0 Cadmium compounds 6.1 UN2570 Ill 6.1 lB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A N 6.1 188, lP2, 1P4, T3, TP33 153 212 242 25 kg 100 kg A 0 6.1 tB8, 1P3, Ti, TP33 153 213 240 100 kg 200 kg A 0. A Caesium hydroxide 8 UN2682 8 88, tP2, 1P4, T3, TP33 154 212 15 kg 0 240 50 kg A 29, 52. C 8 8 ‘ft Caesium hydroxide solution UN2681 B2, 1B2,T7, TP2 154 202 242 1L 30 L A 29,52 8 III lB3, T4, TP1 154 203 241 5L 60 L 29, 52 Calcium 4.3 UN1401 4.3 1B7, 1P2. T3, TP33 151 212 241 15 kg 50kg F 52 a Calcium arsenate 6.1 UN1573 6.1 1B8, 1P2, P4, T3, TP33 153 212 242 25 kg 100 kg A (P Calcium arsenate and calcium 6.1 UN1574 6.1 188, 1P2, lP4, T3, TP33 153 212 242 25 kg 100 kg A arsenite, mixtures, solid. a en Calcium bisulfite solution, see ci, Bisulfites, aqueous solutions, n.o.s.. a Calcium carbide UN 4.3 1402 4.3 Al, A8, 855, 859, 84, None 211 242 Forbidden 15 kg 8 52 (P IP1, N34, T9, TP7, TP33 4.3 Al, A8, 855, 859. 187, 151 212 241 15 kg 50 kg B 52 1P2, N34, > T3, TP33 0. Calcium chlorate 5.1 UN1452 5.1 A9, 188, lP2, lP4, N34, 152 212 242 5 kg 25 kg A 56. 58 T3, TP33 3 Calcium chlorate aqueous solution 5.1 UN2429 5.1 A2. 82, N41, T4, TP1 152 202 242 1L 5L B 56, 58. 133 5.1 Ill A2, 182, N41, T4, TPI 152 203 241 2.5 L 30 L B 56, 68, 133 0-I Calcium chlorite 5.1 UN1453 5.1 A9, lB8, 1P2, P4, N34, 152 212 242 5 kg 25 kg A 56, 58 Ill T3, TP33 Calcium cyanamide with more than 4.3 UN1403 4.3 Al, A19, 188, 1P4, Ti, 151 213 241 25 kg 100 kg A 52 0.1 percent of calcium carbide. TP33 A Calcium cyanide 6.1 UN1575 6.1 87, IP1, N79, N80, T6, None 211 242 5 kg 50 kg 40, 52 TP33 Calcium dithionite or Calcium hydro 4.2 UN1923 4.2 A19, A20, 186, lP2, T3, None 212 241 15 kg 50 kg F 13 sulfite. TP33 Calcium hydride 4.3 UN1404 4.3 A19, N40 None 211 242 Forbidden 15 kg F 52 Calcium hydrosulfite, see Calcium dithionite. Ce, Calcium hypochlorite, dry or Calcium 5.1 UN1748 5.1 165, 166, A7, A9, lB8, 152 212 ...j None 5 kg 25kg D 4, 25, hypochlorite mixtures dry with 1P2, lP4, lPl3, N34, W9 48, 52, more than 39 percent available 56, 58, chlorine (8.8 percent available oxy 69, 142 C gen). 0 -n
C) C) 0 m 0 a. 75 58 85 52, 52, 58, 25, 25, 58, 69, 25, 52, 58, 85, 52, 52, 85, 142 142 103 138 103 103 142. 4, 4, 4, (lOB) 56, 56, Other 56, 58, 56, 48, 56. 48. 13, 56, 52, 48, 40, 52, 85. 52, 69, 69, (10) Vessel stowage OA) L- (1 0 D 0 D E A A D A A B A A B A A A A L kg kg kg kg kg kg kg kg kg kg kg kg air- 60L only 25kg 15 25 25 25 50 220 and 100kg 100 100kg 100 100 100 100 100 100 (9B) craft Forbidden Cargo
I limitations
j (9) L 175.75) kg kg kg kg kg kg kg kg kg kg kg kg §173.27 5L 5 5 5 5 kg 60 25 25 25 25 15 kg 25 25 25 25 25 (9A) Quantity (see Forbidden Forbidden aircraft/rail Passenger (8C) Bulk 240.... 240... 241 240.... 240 240 242 242 242 242 None 240 240 241 241 242 240 241 (8) bulk )8B) Non- 213.... 212.... 213.... 187 213 213 213 212 212 212 211 213 213 213 212 213 203 203.... (173.***) Packaging ... (8A) lions Excep- 152 154 152 151 152 152 152 152 152 None 151 None None 151 None 154 150 None Tl, W9 W9 w9 Ti, 188, 1P3, N40 TP1 TP1 1P13, TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 1P4, A9, 1P4, T4 T2,
TABLE—Continued N34, lB8, N34, Ti, T3, T3, Ti, Tl, TI, T3, A19, T3, Ti, 1P4, A7, 188. 188, lB3 1B3. provisions A8, (7) 1P3, 1P2, 1P2, 1P3, 1B6, A29, lP2, 184, 1P2, 1P3, 1P2, lPl3, lPl3, 172.102) 17l, BI, ( A19, 88, Al, A19, 188, 186, lB6, 1B6, P4, 187, 188, 188, Al9, Al9, Special 165, Al, Al, 34, 165, Al,
MATERIALS Al, Al, 165, A19, (6) 6.1. Label Codes 5.1 5.1 5.1 5.1 8 5.1 4.3 5.1 5.1 4.3, 4.1 4.1 4.2 3 4.3 4.1 4.3 8 II II II II Ill III Ill Ill Ill Ill Ill Ill Ill Ill Ill
HAzARDoUS (5) PG (4)
172.101 Identi- fication Numbers UN2880 UN2844 UN2208 UN1454 UN191O UN1455 UN1360 UN1456 UN1855 UN1457 UN1313
§ UNI314 UNI405 UN113O UN2717 UN2829 8 3 8 or 5.1 5.1 5.1 5.1 5.1 4.3 5.1 4.3 4.2 4.1 4.1 4.3 4.1 (3) Hazard Division class or or al 5.5 not dry, per tubular 16 but hydrated available than names Calcium than hydrated Selenates descriptions mixtures, less percent or Primers, silicon percent see more 10 not fused (2) see shipping 39 not materials hypochlorite, than with but synthetic hypochlorite, pyrophoric proper hypochlorite oil than selenate, manganese perchlorate nitrate oxide phosphide permanganate peroxide resinate resinate, silicide primers, acid pyrophoric. water. more and Hazardous mixtures, cent Calcium with chlorine. more percent loys, Selenites. Calcium Calcium Calcium Calcium Calcium Calcium Calcium Calcium Calcium Calcium Calcium, Cannon Calcium Celcium Calcium Csmphor Camphor, Caproic A (1) bols Sym- 0.
Caps, blasting, see Detonators, etc -Q liquid, 3 UN2758 Carbamate pesticides, flam 3, 6.1 T14, TP2, TPI3, TP27 I None ... 201 .... I 243 Forbidden 30L B 40 mable, tosic, flash point less than 23 degrees C. 3, 6.1 lB2, Til, TP2, TP13, 150 202 243 iL 60L B 40 CD 6.1 TP27 0 Carbamate pesticides, liquid, toxic 6.1 UN2992 6.1 T14, TP2, TP13, TP27 None 201 243 30L B 40 Z lB2, Til, TP2, TP13, 153 202 243 5LiL 60L B 40 TP27 = Ill 6.1 lB3, T7, TP2, TP28 153 203 241 60 L 220L A 40 Carbamate pesticides, liquid, toxic, 6.1 UN2991 6.1,3 T14, TP2, TP13, TP27 None 201 243 IL 30L B 40 flammable, flash point not less 0 than 23 degrees C. 0. 6.1,3 lB2, Til, TP2, TP13, 153 202 243 5L 60L B 40 TP27 Ill 61, 163, T7, TP2, TP28 153 203 242 60 L 220L A 40 Carbamate pesticides, solid, toxic 6.1 UN2757 6.16.1,3 lB7, IP1, T6, TP33 None 21I 242 5 kg 50kg A 40 0 Ill 6.1 lB8, lP2, P4, T3, TP33 153 212 242 25 kg 100kg A 40 6.1 lB8, 1P3, TI, TP33 153 213 240 100 kg 200kg A 40 Carbolic acid, see Phenol, solid or 0 Phenol, molten. C’, Carbolic acid solutions, see Phenol U, solutions. 0 -A Carbon, activated 4.2 UN1362 Ill 4.2 lB8, lP3, Ti, TP33 None 213 241 0.5 kg 0.5kg A 12 cJ1 Carbon, animal or vegetable origin 4.2 UNI361 4.2 166, T3, TP33 None 212 242 Forbidden A Ill Forbidden 12 4.2 lB8, lP3, Ti, TP33 None 213 241 Forbidden Forbidden A 12 Carbon bisulfide, see Carbon diaul tide. Carbon dioxide 2.2 UNiOi3 2.2 306 302, 302, 75 kg 150kg A 304. 314, Ill 315. Carbon dioxide, refrigerated liquid 2.2 UN2187 2.2 T75, TP5 306 304 314, 50 kg 500kg 8 0 315. -I AW Carbon dioxide, solid or Dry ice 9 UN1845 None 217 217 240 200 kg 200kg C 40 Carbon disultide 3 UN1131 3, 6.1 816, Ti4, TP2, TP7, None 201 243 Forbidden Forbidden D 18, 40, Ill TP13 115 Carbon monoside, compressed 2.3 UNiOi6 2.3, 4 None 302 314, Forbidden 25kg D 40 2.1. 315. D Carbon monoside, refrigerated liquid 2.3 NA9202 2.3, 4, T75, TP5 None 316 318 Forbidden Forbidden D (cryogenic liquid). 2.1. Carbon tetrabromide 6.1 UN2516 6.1 188, 1P3, Ti, TP33 153 213 240 100 kg 200kg A 25 Carbon tetrachloride 6.1 UN1846 6.1 lB2, N36, T7, TP2 153 202 243 5L 60L A 40 Carbonyl chloride, see Phosgene Carbonyl fluoride 2.3 UN2417 2.3, 8 2 None 302 None Forbidden Forbidden D 40 co Carbonyl sulfide 2.3 UN2204 2.3, 3, Bi4 None 304 314, Forbidden Forbidden D 40 — 2.1. 315. Cartridge cases, empty primed, see Cases, cartridge, empty, with prim 0 er. § 172.101 HAzARDOus MATERIALs TABLE—Continued ‘0,
(8) (9) (10) Vessel Packaging Quantity limitations stowage Sym- Hazardous materials descriptions Hazard Identi- 73.***) C Label Special provisions 1 (see 173.27 and bols and proper shipping names class or fication PG ( § Division Numbers Codes ( 172.102) — —.— 175.75) Escep- Non- Bulk Other tions bulk Passenger Cargo air- aircraWrail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (88) (8C) (9A) (9B) (IOA) (108)
Cartridges, actuating, for aircraft ejector seat catapult, fire extin guisher, canopy removal or appa ratus, see Cartridges, power de vice. Cartridges, explosive, see Charges, demolition. Cartridges, sporting, see Cartridges for weapons, inert projectile, or Cartridges, small arms. Cartridges, flash 1.1G UN0049 II 1.10 .. None 62 None Forbidden Forbidden 07 Cartridges, flash 1.3G UNOO5O II 1.3G .. None 62 None Forbidden 75kg 07 Cartridges for weapons, blank 1.1C UN0326 II 1.10 .. None 62 None Forbidden Forbidden 07 Cartridges for weapons, blank 1.2C UN0413 II 1.2C .. None 62 None Forbidden Forbidden 07 Cartridges for weapons, blank or 1.4S UNOOI4 II None 63 62 None 2Skg 100 kg 05 Cartridges, small arms, blank. Cartridges for weapons, blank or 1.30 UN0327 II 1.3C .. None 62 None Forbidden Forbidden 07 Cartridges, small arms, blank. Cartridges for weapons, blank or 1.4C UN0338 II 1.4C .. None ... 62 None Forbidden 7kg 06 Cartridges, small arms, blank. Cartridges for weapons, inert projec- 1.2C UN0328 II 1.2C .. None ... 62 62 Forbidden Forbidden 03 ‘0 tile. 0 Cartridges for weapons, inert projec- 1.4S UNOO12 II None 63 62 None 2kg 100 kg 05 ‘.1 tile or Cartridges, small arms. Cartridges for weapons, inert projec- 1.4C UN0339 II 1.4C .. None ... 62 None Forbidden 7Skg 06 tile or Cartridges, small arms. 0 Cartridges for weapons, inert projec- 1.3C UN0417 II 1.3C .. None ... 62 None Forbidden Forbidden 06 tile or Cartridges, small arms. Cartridges for weapons, with bursting 1.1F UN0005 II 1.IF ... None ... 62 None Forbidden Forbidden 08 charge. Cartridges for weapons, with bursting lIE UN0006 Il 1.15 ... None ... 62 62 Forbidden Forbidden 03 charge. Cartridges for weapons, with bursting 1.2F UN0007 II 1.2F ... None ... 62 None Forbidden Forbidden 08 0 charge. m Cartridges for weapons, with bursting 1.25 UN0321 II 1.25 ... None ... 62 62 Forbidden Forbidden 03 0. charge. Cartridges for weapons, with bursting 1.4F UN0348 II 1.4F ... None ... 62 None Forbidden Forbidden 08 0 charge. z III
Cartridges for weapons, with bursting 1.45 UN0412 II 1.4E None 62 62 Forbidden 75kg 02 charge. Cartridges, oil well 1.3C UN0277 II 1.3C None 62 62 Forbidden Forbidden 07 Cartridges, oil well 1.4C UN0278 II 1.4C None 62 62 Forbidden 75kg 06 Cartridges, power device 1.3C UN0275 II 1.3C None .., 62 62 Forbidden 75 kg 07 0 Cartridges, power device 1.4C UN0276 II 1.4C 110 None 62 62 Forbidden 75kg 06 Cartridges, power device 1.4S UN0323 II 1.4S 110 63 62 62 25kg 100 kg 05 Cartridges, power device 1.2C UN0381 II 1.2C None 62 62 Forbidden Forbidden 07 0. Cartridges, safety, blank, see Car- tridges for weapons, blank (UN = 00I4) N Cartridges, safety, see Cartriges for — weapons, inert projectile, or Car- 0. tridges, small arms or Cartridges,
power device (UN 0323) Cl, Cartridges, signal 1.3G UN0054 II 1.3G None 62 None Forbidden 75kg 07 Cartridges, signal 1.4G UN0312 II 1.4G None 62 None Forbidden 75kg 06 Cartridges, signal 1.4S UNO4OS II 1.4S None 62 None 25 kg 100 kg 05 — 0 Cartridges, small arms ORM-D None 63 None None 30 kg 30 kg A gross gross D Cartridges power device (used to ORM—D None 63 None None 30 kg 30 kg A project fastening devices), gross gross Cartridges, starter, jet engine, see 0 Cartridges, power device. Cases, cartridge, empty with primer 1.4S UN0055 II 1.4S 50 None 62 None 25kg 100 kg 05 Cases, cartridges, empty with primer 1.4C UN0379 II 1.4C 50 None 62 None Forbidden 75kg 06 Cases, combustible, empty, without 1.4C UN0446 II 1.4C None 62 None Forbidden 75kg 06 primer. Cases, combustible, empty, without 1.3C UN0447 II 1.3C None 62 None Forbidden Forbidden 07 —. primer. Casinghead gasoline see Gasoline
A W Castor beans or Castor meal or Cas- 9 UN2969 , II None 168. 1P2, P4, T3, TP33 155 204 240 No limit No limit E 34,40 I tor pomace or Castor fake ) Q 0 Caustic alkali liquids, no.s 8 UN1719 II 8 B2, 1B2,Til, TP2, TP27 154 202 242 1 L 30 L A 29,52 8 1B3,T7, TP1, TP28 154 203 241 5 L SQL A 29, 52 Caustic potash, see Potassium hy- droxide etc. Caustic soda, (etc.) see Sodium by- droxide etc. Cells, containing sodium 4.3 UN3292 II 4.3 189 189 189 25 kg No limit A gross Celluloid, in block, rods, rolls, sheets, 4.1 UN2000 III 4.1 None 213 240 2Skg 100 kg A tubes, etc., except scrap. Celluloid, scrap 4.2 UN2002 III 4.2 lB8, 1P3 None 213 241 Forbidden Forbidden D Cement, see Adhesives containing co flammable liquid. — Cerium, slabs, ingots, or rods 4.1 UN1333 II 4.1 1B8,lP2, P4, N34 None 212 .... 240 .... 15 kg 50 kg A 74, 91 Cerium, turnings or gritty powder 4.3 UN3078 II 4.3 Al, 187, lP2, T3, TP33 151 212 .... 242 .... 15kg SOkg 6 52
Cesium orCaesiun, 4.3 UN1407 I 4.3 A7, A19, 1B4, IPI, N34, None 211 .... 242 .... Forbidden 15kg 0 52 N40 — 1’-’ 0
C-) C-) ,, p. m 0 0 0
12
40 40
Other (108)
(10)
Vessel
stowage
(IOA)
10 10 A 07 03 10 A 07 06 05 03 06 10 13 07 07 05 07 07 B 06 07 07 07 06 07 06 05
A
kg kg
kg
air-
30L 60L
only
75kg 10kg 75kg 75kg 75kg 75kg
and
100kg 100kg
100 100
100
(9B)
Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden craft Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden
Cargo
limitations
(9)
173.27
kg kg 175.75) kg kg
kg kg
§ 1L 5L
25 25
25 10 25 25
(9A)
Quantity (see
Forbidden
Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden
aircraftlrail Psssenger
Bulk
(8C)
None None 240 240 None None None 62 None None None None
— None None None None None 62 None None None None None None None None None None 243....
(8) 73***)
bulk (88)
Non-
1 —
213 62 62 213 62 62 62 62 62 62 62 62 161 62 62 62 62 161 62 62 62 62 62 62 62 62 62 62 202....
(
Packaging
(BA)
tions
Escep-
151 152 None None None None None None None None None None None 161 None None None None 153 None None None None None 154 None None None None
I I
15
Ti,
TP2
TP33 TP33
P3,
T7,
TABLE—Continued
Ti,
lB8,
lB2,
provisions
(7)
lB8.
172.102)
(
A29,
Special
Al,
MATERIALS ...... ,, ......
(6)
Label
Codes
1.2D liD 1.10 l.2D 1.4D 1.4S 1.10 1.10 1.4D 1.1C 1.4C liD 5.1 1.4S 1.3C 1.3C 1.4D 1.10 1.20 1.4D 1.2C l.IC l.2C 1.10 1.4S 4.2 6.1 8 9
II II II II II II II II II II II II II II II II II Il II II II II II II II
Ill Ill
HAzARDOUS
(5)
4
(4)
172.101
Identi-
fication
Numbers
UN1451 NA1361 UN0458 UN0443 UN0459 UN0056 UN0442 UN0457 UN0460 UN0048 UN0491 UN0445 UN0272 UN0242 UN0237 UN0444 UN0415 UN0279 UN0288 UN0059 UN0271 UNO41 UN0439 UN0060 UN2075 UN0440 NA1760 UN3316 UN0441 §
8 9
or 5.1 4.2
6.1
1.4S 1.2D 1.4D lID i.4S 1.10 1.10 1.2D 1iC 1.3C 1.4C 1.3C liD 1.40 1.2C 1.4S 1.2D 1.10 1.1C 1.4D 1.10 1.40 1.2C 1.10
(3)
Hazard
class Division
fire
with with with with
shell,
for
nitrate
bonded bonded bonded bonded
linear linear Cartridges,
detonator detonator detonator detonator
names
explosive -
cannon cannon cannon
descriptions
etc.
for for for commercial commercial commercial commercial
explosive,
stabilized
see
plastics plastics plastics plastics
without without without without flexible,
flexible,
Caesium
(2)
shipping
briquettes,
or
wood,
materials
kit bursting, bursting, bursting, bursting, expelling, kits depth explosive, propelling explosive, explosive, propelling demolition explosive, propelling proper propelling propelling, propelling, propelling, shaped, shaped, shaped, supplementary shaped, shaped, shaped,
device.
nitrate anhydrous,
detonator. detonator. detonator. detonator.
and
Hazardous
extinguishers, power screenings, out out out out
Charcoal Cesium Charges, Charges, Charges, Charges, Charges, Charges, Charges, Charges, Charges, Charges, Charges, Charges, Charges, Charges, Charges, Charges, Charges, Charges, Charges, Charges, Charges, Charges, Charges, Chloral, Charges, Charges, Chemical Chemical
13
(1)
bols
Syni- Chlorate and borate mixtures 5.1 UN1458 II 5.1 Ag, 88, lP2, 1P4, N34, 152.1212.1240.... 5 kg 25 kg A 56, 58 T3, TP33 V . 5.1 A9, 168, 1P3, N34, 152 A (D Ti, 213 240 25 kg 100 kg 56, 58 TP33 5.1 A Chlorate and magnesium chloride 5.1 UN1459 II A9, 1B8, lP2, 1P4, N34, 152 212 240 5 kg 25 kg 56, 58 mixture solid, 5.1 T3, TP33 A 0 A9, 168, P3, N34, Ti, 152 213 240 25 kg 100 kg 56, 58 A 5.1 TP33 0 152 Chlorate and magnesium chloride 5.1 UN3407 II Ag, 1B2,N34, T4, TP1 202 242 1L 5L A 56, 58, = mixture solution. 5.1 133 0 152 N Ag, 1B2,N34, T4, TP1 203 241 2.5 L 30 L 56, 58, 0 133 0 Chlorate of potash, see Potassium 0 chlorate. C U, Chlorate of soda, see Sodium chlo rate. Chlorates, inorganic, aqueous solu 5.1 UN3210 II 5.1 182, T4, TPI 152 202 242 1L 5L B 56, 58, 0 tion, no.5.. 133 5.1 1B2,T4, TP1 152 203 241 2.5 L 30 L B 56, 58, 0 133 (I, 5.1 Chloratss, inorganic, no.5 5.1 UN1461 II Ag, 1B6, 1P2, N34, T3, 152 212 242 5 kg 25 kg A 56, 58 C’, TP33 5.1 0 Chloric acid aqueous solution, with 5.1 UN2626 II 162, T4, TP1 None 229 None Forbidden Forbidden D 56, 58 not more than 10 percent chloric acid. Chloride of phosphorus, see Phos > phorus trichloride. 0 Chloride of sulfur, see Sulfur chloride 3 Chlorinated lime, see Calcium hypo D chlorite mixtures, etc. Chlorine 2.3 UN1O17 2.3, 2, 6g, 814, N86, T50, None 304 314, Forbidden Forbidden 40, 51, 5.1, TP19 315. 55, 62, -I0 8. 68, 89, go Chlorine aside Forbidden D Chlorine dioxide, hydrate, frozen 5.1 NA9191 II 5.1, None ... 229 .... None Forbidden Forbidden 6 6.1. Chlorine dioxide (not hydrate) Forbidden Chlorine pentafluoride 2.3 UN2548 2.3, 1, B7, 89, 614, N86 None ... 304 .... 314 Forbidden Forbidden D 40, 89, 5.1, 90 8. Chlorine trifluoride 2.3 UN1749 2.3, 2, 87, 89, 814, N86 None ... 304 .... 314 Forbidden Forbidden D 40, 89, 5.1, 90 Ce) 8. Chlorite solution 8 UN1908 II 8 A3, A6, A7,82, 1B2, 154 202 .... 242 1L 30L B 26, 44, N34, T7, TP2, TP24 89, 100, C 141 §172.101 HAzARDous MATERIALS TABLE—Continued L0
(8) (9) (10) Vessel Hazard Ictenti- Packaging Quantity limitations stowage 0 Sym- Hazardous materials descriptions Label Special provisions 173.’) (see 173.27 and bols and proper shipping names class or fication PG ( § Division Numbers Codes ( 172.102) — — 175.75) Excep- Non- Bulk Ltciocna Other tions bulk Passenger Cargo air- aircraft/rail craft only
(1) (2) (3) (4) (5) (6) (7) (BA) (8B) (8C) (9A) (9B( (1OA) (lOB)
III 8 A3, A6, A7,B2, lB3, 154 203.... 241 5L 60L B 26, 44, N34, T4, TP2, TP24 89, 100, 141 Chlorites, inorganic, no.5 5.1 UN1462 II 5.1 A7, 1B6, 1P2, N34, T3, 152 212 242 5 kg 25kg A 56, 58 TP33 2.1 2.1 1-Chloro-l,l-difluoroethane or Refrig UN2517 T50 306 304 314, Forbidden 150kg B 40 erant gas R 142b. 6.1 315. 3-Chloro-4-methylphenyl isocyanate, UN2236 II 6.1 182 153 202 243 5L 60L B 40 liquid. 6.1 3-Chloro-4-methylphenyl isocyanate, UN3428 II 6,1 lB8, 1P2, lP4, T3, TP33 153 212 242 25 kg 100kg 8 40 solid. 1-Chloro-1 ,2,2,2-tetrafuoroethsneor 2.2 UN1021 2.2 T50 306 304 314, 75 kg 150kg A Refrigerant gas R 124. 315. 4-Chloro-o-toluidine hydrochloride, 6.1 UN1579 III 6.1 lB8, P3, Ti, TP33 153 213 240 100 kg 200kg A solid. 4-Chloro-o-toluidine hydrochloride, 6.1 UN3410 III 6.1 lB3, T4, TP1 153 203 241 60 L 220L A solution. 1-Chloro-2,2,2-trifluoroethane or Re 2.2 UN1983 2.2 T50 306 304 314, 75 kg 150kg A frigerant gas R 133a. 315. Chloroacetic acid, molten 6.1 UN3250 II 6.1,8 lBi, T7, TP3, TP28 None 202 243 Forbidden Forbidden C 40 Chloroacetic acid, solid 6.1 UN1751 II 6.1,8 A3, A7, 1B8,1P2, P4, 153 212 242 15 kg 50kg C 40 C-) N34, T3, TP33 ,, 6.1 Chloroacetic acid, solution UN1750 II 6.1,8 A7, lB2, N34, T7, TP2 153 202 243 1L 30L C 40 6.1 Chloroacetone, stabilized UN1695 I 6.1,3, 2, B9, 614, B32, N12, None 227 244 Forbidden Forbidden D 21, 40, C) 8. N32, N34, T20, TP2, 100 TP13, TP38, TP45 Chloroacetone (unsfabilized) Forbidden + Chloroacetonitrile 6.1 UN2668 II 6.1, 3 2, B9, B14, 832, 1B9, None 227 244 Forbidden Forbidden A 12, 40, T20, TP2, TP38, TP45 52 6.1 Chloroscetophenone, liquid, (CN) UN3416 II 6.1 A3, lB2, N12, N32, N33, None 202 243 Forbidden 60L D 12, 40 T7, TP2, TP13 Chloroacetophenone, solid, (ON) 6.1 UN1697 II 6.1 A3, 1B8, lP2, lP4, N12, None 212 None Forbidden 100kg D 12, 40 0 N32, N33, N34, T3, m TP2, TPI3, TP33 0. Chloroacetyl chloride 6.1 UN1752 6.1, 8 2, B3, B8, B9,B14, 832, None ... 227 .... 244 Forbidden Forbidden D 40 877, N34, N43, T20, 0 TP2, TP13, TP38, TP45 Chioroanilines, liquid 6.1 UN2019 6.1 1B2,T7, TP2 153 202 243 5L 60L A 52 - Chioroanilines, solid 6.1 UN2018 II 6.1 188, P2, 1P4, T3, TP33 153 212 242 25 kg 100kg A 6.1 Chioroanisidines 6.1 UN2233 Ill 1B8, 1P3, Ti, TP33 153 213 240 100 kg 200kg A CD Ill 150 Chlorobenzene 3 UN1134 3 Bi, 1B3,T2, TP1 203 242 60 L 220L A CD Chlorobenzol, see Chlorobenzene Ill Ill 3 Chlorobenzotrifluorides 3 UN2234 Bi, 1B3,T2, TP1 150 203 242 60 L 220L A 40 Ill a Chlorobenzyl chlorides, liquid 6.1 UN2235 6.1 lB3, T4, TP1 153 203 241 60 L 220L A Chlorobenzyl chlorides, solid 6.1 UN3427 6.1 188, P3, Ti, TP33 153 213 240 100 kg 200kg A a. Chlorobutanes 3 UN1127 II 3 lB2, T4, TP1 150 202 242 5L 60L 8 II = Chlorocresols solution 6.1 UN2669 6.1 1B2,T7, TP2 153 202 243 5L 60L A 12 a Ill 6.1 1B3,T7, TP2 153 203 241 60 L 220L A 12 N 6.1 6.1 Chlorocresols, solid UN3437 II 168, 1P2, 1P4,T3, TP33 153 212 242 25 kg 100kg A 12 0 Chloroditluorobromomethane or Re 2.2 UN1974 2.2 T50 306 304 314, 75 kg 150kg A 0. frigerant gas R 12B1. 315. 0 Chloroditluoromethane and 2.2 UN1973 2.2 T50 304 C I 306 314, 75 kg 150kg A U) chioropentafluoroethane rnisture or 315. Refrigerant gas R 502 with fixed boiling point, with approximately 49 0 percent chlorodifluoromethane. CD Chlorodifluoromethane or Refrigerant 2.2 UN1018 2.2 T50 306 304 314, 75 kg 150kg A 0 gas R 22. 315. U) + Chlorodinitrobenzenes, liquid 6.1 UN1577 6.1 62, T7, TP2 153 202 243 5L 60L B 91 Cn + Chlorodinitrobenzenes, solid 6.1 UN3441 6.1 1B8, 1P2, lP4, T3, TP33 153 212 242 25 kg 100kg A 91 0 6.1 6.1 2, 2-Chloroethanal UN2232 B9, B14, B32, T20, None 227 244 Forbidden Forbidden D 40 CD TP2, TP13, TP38, TP45 6.1 6.1 Chloroform 6.1 UN1888 Ill 1B3,N36, T7, TP2 153 203 241 60 L 220L A 40 G Chloroformates, toxic, corrosive, UN2742 6,1,8, 5, 181, T7, TP2 153 202 243 1L 30L A 12, 13, > flammable, s.o.s.. 3. 21, 25, 0. 40, 100 3 G Chloroformates, toxic, corrosive, 6.1 UN3277 6.1,8 82, T8, TP2, TPI3, 153 202 .... 243 1L 30L A 12, 13, n.o.s.. TP28 25, 40 Chlorornethyl chloroformate 6.1 UN2745 6.1,8 182, T7, TP2, TP13 153 202 .... 243 1L 30L A 12, 13, 21, 25, 0 40, 100 -4 Chloromethyl ethyl ether 3 UN2354 3, 5.1 1B2,T7, TP1, TPI3 150 202 243 1L 60L F 40 Chiororutroaniliries 6.1 UN2237 Ill 6.1 168, lP3, Ti, TP33 153 213 240 100 kg 200kg A + Chloronitrobenzenes, liquid 6.1 UN3409 6.1 182, T7, TP2 153 202 243 5L 60L A + Chloronitrobenzenes, solid 6.1 UN1578 6.1 68, 1P2, 1P4,T3, TP33 153 212 242 25 kg 100kg A 6.1 6.1 Chloronitrotoluenes, liquid UN2433 Ill 183, T4, TP1 153 203 241 60 L 220L A 44, 89, 100, 141 6.1 6.1 153 Chloronitrotoluenes, solid UN3457 Ill 188, 1P3,T1, TP33 213 240 25 kg 200kg A Chloropentafluoroethane or Refrig 2.2 UN1020 2.2 T50 306 304 314, 75 kg 150kg A erant gas R 115. Ill 315. Chlorophenolates, liquid or 8 UN2904 8 183 154 203 241 5L 60L A 0, Phenolates, liquid. 8 8 Chlorophenolates, solid or UN2905 Ill 68, lP3, Ti, TP33 154 213 240 25 kg 100kg A Phenolates, solid. Ill 203 Chlorophenols, liquid 6.1 UN2021 6.1 183, T4, TP1 153 241 60 L 220L A 0 Chlorophenols, solid 6.1 UN2020 Ill 6.1 lB8, P3, Ti, TP1, TP33 153 213 240 100 kg 200kg A § 172.101 HAzARDous MATERIALS TABLE—Continued (0,
(8) (9) (10) Vessel Hszard Identi- Packaging Quantity limitations stowage C Sym- Hazardous materials descriptions Label Special provisions (173.***) (see §173.27 and bols and proper shipping names class or fication Codes Division Numbers ( 172.102) — — 175.75) Excep- Non- Bulk Other tions bulk Passenger Cargo air- tlofl aircraft/rail craft only
(I) (2) (3) (4) (5) (6) (7) (8A) (88) (8C) )9A) (9B) (bA) (lOB)
Chlorophenyltrichlorosilane 8 UN1753 Il 8 A7, 82, B6, N34, Tb, None ... 206 .... 242 .... Forbidden 30L C 40 TP2, TP7
Chloropicrin 6.1 UN1580 I 6.1 2, 87, 89, B14, B32, None ... 227 .... 244 .... Forbidden Forbidden D 40 B46, T20, TP2, TP13, TP38, TP45 Chloropicrin and methyl bromide mix 2.3 UN1581 2.3 2, B9, 814, N86, T50 None ... 193 .... 314, Forbidden Forbidden 0 25, 40 tures. 315. Chloropicrin and methyl chloride mix 2.3 UN1582 2.3 2, N86, T50 None ... 193 .... 245 Forbidden Forbidden 0 25, 40 tures. Chloropicrin mixture, flammable (pressure not exceeding 14.7 psia at 115 degrees F flash point below 100 degrees F) see Toxic liquids, flammable, etc.
Chloropicrin mixtures, no.s 6.1 UN1583 I 61 5 None 201 243 Forbidden Forbidden C 40 II 6.1 82 153 202 243 Forbidden Forbidden C 40 III 6.1 183 153 203 241 Forbidden Forbidden C 40 Chloropivaloyl chloride 6.1 NA9263 I 6.1,8 2, 89, 814, B32, T20, None 227 244 Forbidden Forbidden B 40 TP4, TP13, TP38, TP45 Chloroplatinic acid, solid 8 UN2507 III 8 1B8, P3, TI, TP33 154 213 240 25 kg 100 kg A
Chloroprene, stabilized 3 UN1991 I 3,6.1 B57, T14, TP2, TP13 None 201 243 Forbidden 30 L 0 40 Chloroprene, uninhibited Forbidden C, 1-Chloropropane 3 UN1278 II 3 lB2, 1P8, N34, T7, TP2 None 202 242 Forbidden 60 L E -n 3 2-Chloropropane UN2356 I 3 N36, Til, TP2, TP13 150 201 243 1L 30 L 8 3-Chloropropanol-1 6.1 UN2849 Ill 6.1 lB3, T4, TP1 153 203 241 60 L 220 L A C) 2-Chloropropene 3 UN2456 I 3 A3, N36, Tib, TP2 150 201 243 1L 30 L E 2-Chloropropionic acid 8 UN2511 III 8 lB3, T4, TP2 154 203 241 5L 60 L A 8 2-Chloropyridine 6.1 UN2822 II 6.1 lB2, T7, TP2 153 202 243 5L 60 L A 40 Chlorosilanes, corrosive, flammable, 8 UN2986 II 8,3.... T14, TP2, TP7, TP13, None 206 243 IL 30 L C 40 n.o.s. TP27 8 Chlorosilanes, corrosive, no.5 UN2987 II 8 82, T14, TP2, TP7, None 206 242 1L 30 L C 40 TP13, TP27 3 Chlorosilanes, flammable, corrosive, UN2985 II 3,8.... T14, TP2, TP7, TP13, None 206 243 1L 5L B 40 0 no.5. TP27 m Chlorosilanes, toxic, corrosive, flam 6.1 UN3362 II 6.1,3, T14, TP2, TP7, TPI3, None 206 243 lL 30 L C 40, 125 0 mable, no.s. 8. TP27 6.1 Chlorosilanes, toxic, corrosive, no.5 UN3361 Il 6.1,8 T14, TP2, TP7, TP13, None 206 243 1L 30 L C 40 0 TP27 z I Chlorosilanes, water-reactive, flam 4.3 UN2988 4.3, 3, A2, T14, TP2, TP7, None ... I 201 244 Forbidden 1L D 21, 28, mable, corrosive, n.o.s. 8. TP1 3 40, 49, •0 100 CD + Chiorosulfonic acid (with or without 8 UN1754 8, 6.1 2. B9, BlO, 814, 832, None 227 244 Forbidden Forbidden C 40 sulfur trioxide). T20, TP2, TP38, TP45 CD Chiorotoluenes 3 III UN2238 3 Bi, 163, T2, TP1 150 203 242 60 L 220 L ‘ A III 0 Chlorotoluidines, liquid 6.1 UN3429 6.1 1B3,T4, TP1 153 203 241 60 L 220L A Chlorotoluidines, solid 6.1 UN2239 III 6.1 88, lP3, Ti, TP33 153 213 240 100 kg 200kg A 0. Chiorotritluorornethane and 2.2 UN2599 2.2 306 304 314, 75 kg 150kg A = trifluoromethane azeotropic mixture 315. 0 N or Refrigerant gas R 503 with ap 0 proximately 60 percent 0. chlorotrifluoromethane. 0 Chiorotrifluoromethane or Refrigerant 2.2 UN1022 2.2 306 304 .... 314, 75 kg 150kg A C gas R 13. 315. C’, Chromic acid solution 8 UN1755 II 8 B2, 1B2, T8, TP2 154 202.... 242.... 1L 30L C 40, 44, 89, 0 100, CD 141 Ill 8 lB3, T4, TP1 1154 203 .... 241 5L 60L C 40, 44, 0 89, (n 100, Cl, 141 0 Chromic anhydride, see Chromium CD trioxide, anhydrous. Chromic fluoride, solid 8 UN1756 8 1B8, lP2, lP4, T3, TP33 154 212 240 15 kg 50kg A 52 > Chromic fluoride, solution 8 UN1757 8 62, 162, T7, TP2 154 202 242 1L 30L A 0. Ill 8 1B3, T4, TP1 154 203 241 5L 60L A 3 Chromium nitrate 5.1 UN2720 Ill 5.1 Al, A29, 188, 1P3, Ti, 152 213 240 25 kg 100kg A TP33 Chromium oxychloride 8 UN1758 8 A3, A6, A7, BiO, N34, None 201 243 0.5 L 2.5L C 40, 66, Tb, TP2 74, 89. 0 90 -f Chromium trioxide, anhydrous 5.1 UN1463 5.1, 68, P2, P4, T3, TP33 None 212 242 5 kg 25kg A 66, 90 6.1, 8. Chromosulfuric acid 8 UN2240 8 A3, A6, A7, 64, 66, None ..j201 .1243,.., 0.5L 2.5L B 40, 66, N34, Tb, TP2, TP13 74, 89, 90 Chromyl chloride, see Chromium osychioride. Cigar and cigarette lighters, charged with fuel, see Lighters or Lighter refills containing flammable gas.. 0, Coal briquettes, hot Forbidden Coal gas, compressed 2.3 UN1023 2.3, 3 None 302 314, Forbidden Forbidden D 40 2.1. 315. Coal tar distillates, flammable 3 UN1136 3 182, T4, TP1 150 202 242 5L 60L 8 0 Ill 3 Bi, 1B3,T4, TPI, TP29 150 203 242 60 L 220L A § 172.101 HAzARDOuS MATERIALSTABLE—Continued co,
(8) (9) (10) Vessel Packaging Quantity limitations stowage Sym- Hazardous materials descriptions Hazard Identi- 173.**( C class or Label Special provisions ( (see 173.27 and bols and proper shipping names lication PG Codes § Division Numbers (172.102) — — 175.75) Escep- Non- Bulk Other lions bulk Passenger Cargo sir- aircraft/rail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (8B( (8C) (9A( (98) (bA) (108)
Coal tar dye, corrosive, liquid, n.o.s, see Dyes, liquid or solid, s.o.s. or Dye intermediates, liquid or solid, corrosive, no.s.. Coating solution (includes surface 3 UN1139 3 Til, TP1, TP8, TP27 150 201 .... 243 1L 30L E treatments or coatings used for in dustrial or other purposes such as vehicle undercoating, drum or bar rel lining). 3 149, 82, T4, TP1, TP8 150 202 242 5L 60L B Ill 3 Bi, 1B3, T2, TP1 150 203 242 60 L 220L A Cobalt naphthenates, powder 4.1 UN2001 Ill 4.1 A19, 188, P3, Ti, TP33 151 213 240 25 kg 100kg A Ill Cobalt resinate, precipitated 4.1 UN1318 4.1 Al, A19, 186, Ti, TP33 151 213 240 25 kg 100kg A 00 Coke, hot Forbidden Collodion, see Nitrocellulose etc Ill DG Combustible liquid. no.s Comb liq NA1993 None 1B3,Ti, T4. TP1 150 203 241 60 L 220L A 0 Components, esplosive train, n.o.s 1.28 UN0382 1.28 None 62 None Forbidden Forbidden 11 G Components, esplosive train, no.s 1.4B UN0383 1.48 None 62 None Forbidden 75kg 06 G Components, esplosive train, no.5 i,4S UN0384 1.4S None 62 None 25 kg 100 kg 05 G Components, esplosive train, no.5 i.1B UN0461 i.1B None 62 None Forbidden Forbidden ii Composition B, see Hexolite, etc DO Compounds. cleaning liquid 8 NA1760 8 A7, 810, T14, TP2, None 201 243 0.5 L 2.5L 8 40 TP27 0-TI 8 82, 1B2, N37, Ti 1, TP2, 154 202 242 1L 30L B 40 TP27 C) Ill 8 183, N37, T7, TP1, TP28 154 203 241 5L 60L A 40 DG Compounds, cleaning liquid 3 NA1993 3 Til, TP1 150 201 243 1L 30L E 3 182, T7, TP1, TP8, TP28 150 202 242 5L 60L B Ill 3 Bi, 852, 183, T4, TPI, 150 203 242 60 L 220L A TP29 DG Compounds. tree killing, liquid or 8 NA1760 8 A7, 810, T14, TP2, None 201 243 0.5 L 2.5L B 40 Compounds, weed killing, liquid. TP27 8.... 82, 1B2, N37, Til, TP2, 184 202 242 iL 30L B 40 0 TP27 m Ill 8 183, N37, T7, TP1, TP28 154 203 241 5L 60L A 40 DG Compounds. tree killing, liquid or 3 NA1993 3 Tii, TP1 150 201 243 1L 30L B Compounds, weed killing, liquid. 0 3 1B2, T7, TP1, TP8, TP28 150 202 242 5L 60L B III 3 B1, B52, 1B3,T4, TP1, 150 203 242 60 L 220L A -U TP29 DG Compounds, tree killing, liquid or 6,1 NA2810 6.1 T14, TP2, TP13, TP27 None 201 243 IL 30L B 40 CD Compounds, weed killing, liquid. CD 6.1 1B2,Til, TP2, TP27 153 202 243 5L 60L B 40 6.1 Ill lB3, T7, TP1, TP28 153 203 241 60 L 220L A 40 0 2.1 UN1954 2.1 G Compressed gas, flammable, no.5. 306 302, 314, Forbidden 150kg D 40 305. 315. 0 G UN1956 Compressed gas, no.5 2.2 2.2 77 306, 302, 314, 75 kg 150 kg A. = 307. 305. 315. 0 G UN3156 N Compressed gas, oxidizing, no.5 2.2 2.2, Al 4 306 302 314, 75 kg 150kg ID 0 5.1. 315. UN3304 0. GI Compressed gas, toxic, corrosive, 2.3 2.3, 8 None 192 245 Forbidden Forbidden D 40 0 no.5. Inhalation Hazard Zone A. C UN3304 GI Compressed gas, toxic, corrosive, 2.3 2.3, 8 2, B9, 814 None 302, 314, Forbidden Forbidden ID 40 no.s. Inhalation Hazard Zone B. 305. 315. UN3304 0 GI Compressed gas, toxic, corrosive, 2.3 2.3, 8 3, B14 None 302, 314, Forbidden Forbidden ID 40 no.s, Inhalation Hazard Zone C. 305. 315. CD UN3304 GI Compressed gas, toxic, corrosive, 2.3 2.3, 8 4 None 302, 314, Forbidden Forbidden D 40 0 no.s. Inhalation Hazard Zone 0. 305. 315. UN3305 U, Compressed gas, toxic, flammable, 2.3 2.3, None 192 245 Forbidden Forbidden D 17,40 LI, GI corrosive, no.5. Inhalation Hazard 2.1, 0 Zone A. 8. CD 2.3 UN3305 ØD Compressed gas, toxic, flammable, 2.3, 2, 89, 814 None 302, 314, Forbidden Forbidden ID 17,40 cc’ GI corrosive, no.5. Inhalation Hazard 2.1, 305. 315. Zone B. 8. 0. Compressed gas, toxic, flammable, 2.3 UN3305 2.3, 3, 614 None 302, 314, Forbidden Forbidden ID 17,40 corrosive, no.s. Inhalation Hazard 2.1, 305. 315. GI Zone C. 8. Compressed gas, toxic, flammable, 2.3 UN3305 2.3, 4 None 302, 314, Forbidden Forbidden ID 17, 40 corrosive, no.s. Inhalation Hazard 2.1, 305. 315. GI Zone D. 8. 0-4 G Compressed gas, toxic, flammable, 2.3 UN1953 2.3, None 192 245 Forbidden Forbidden ID 40 no.s. Inhalation hazard Zone A. 2.1. G Compressed gas, toxic, flammable, 2.3 UN1953 2.3, 2, 89, 814 None 302, 314, Forbidden Forbidden ID 40 no.s, Inhalation hazard Zone B. 2.1. 305. 315.
G Compressed gas, toxic, flammable, 2.3 UN1953 2.3, 3, B14 None 302, 314, Forbidden Forbidden ID 40 no.5. Inhalation Hazard Zone C. 2.1. 305. 315.
G Compressed gas, toxic, flammable, 2.3 UN1953 2.3, 4 None 302, 314, Forbidden Forbidden ID 40 no.s. Inhalation Hazard Zone 0. 2.1. 305. 315. G Compressed gas, toxic, no.5. Inhala 2.3 UN1955 2.3 None 192 245 Forbidden Forbidden ID 40 tion Hazard Zone A. G Compressed gas, toxic, s.o.s. Inhala 2.3 UN1955 2.3 2, 89, 814 None 302, 314, Forbidden Forbidden ID 40 (0) tion Hazard Zone B. 305. 315. G Compressed gas, toxic, n.o.s. Inhala 2.3 UN1955 2.3 3, B14 None 302, 314, Forbidden Forbidden ID 40 tion Hazard Zone C. 305. 315. G Compressed gas, toxic, n.o.s. Inhala 2.3 UN1955 2.3 4 None 302, 314, Forbidden Forbidden ID 40 C tion Hazard Zone 0. 305. 315. None
§172.101 HAzARDOus MATERIALS TABLE—Continued C0
(8) (9) (10) Vessel Hazard Identi- Packaging Quantity limitations stowage C Sym- Hazardous materials descnptions Label Special provisions (173.***) (see §173.27 and bols and proper shipping names class or Itcation PG Division Numbers Codes ( 172.102) — — 175.75) - Escep- Non- -c01 Other - Bulk Passenger Cargo air- tions bulk sircraWrail craft only (1) (2) (3) (4) (5) (6) (7) (8A) (88) (BC) (9A) (9B) (1OA) (lOB)
Compressed gas, tosic, osdizing, 2.3 UN3306 2.3, 1 None 192.... 244.... Forbidden Forbidden D 40, 89, corrosive, n.o.s. Inhalation Hazard 5.1, go Zone A. 8. 01 Compressed gas, toxic, oxidizing, 2.3 UN3306 2.3, 2, B9, 814 None 302, 314, Forbidden Forbidden D 40, 89, corrosive, n.o.s. Inhalation Hazard 5.1, 305. 315. 90 Zone B. 8. GI Compressed gas, tosic, oxidizing, 2.3 UN3306 2.3, 3, B14 None 302, 314, Forbidden Forbidden D 40, 89, corrosive, no.5. Inhalation Hazard 5.1, 305. 315. 90 Zone C. 8. 01 Compressed gas, toxic, oxidizing, 2.3 UN3306 2.3, 4 None 302, 314, Forbidden Forbidden 0 40, 89, corrosive, no.5. Inhalation Hazard 5.1, 305. 315. go Zone 0. 8. G Compressed gas, toxic, oxidizing, 2.3 UN3303 2.3, None 192 245 Forbidden Forbidden 0 40 no.5. Inhalation Hazard Zone A. 5.1. G Compressed gas, toxic, oxidizing, 2.3 UN3303 2.3, 2, 89, 814 None 302, 314, Forbidden Forbidden 0 40 G n.o.s. Inhalation Hazard Zone B. 5.1. 305. 315. Compressed gas, toxic, oxidizing, 2.3 UN3303 2.3, 3, B14 None 302, 314, Forbidden Forbidden D 40 G no.s. Inhalation Hazard Zone C. 5.1. 305. 315. 2.3 Compressed gas, toxic, oxidizing, UN3303 2.3, 4 None 302, 314, Forbidden Forbidden 0 40 no.s. lnhalat ion Hazard Zone D. 5.1. 305. 315. D Consumer commodity ORM-D None 156, 156, None 30 kg 30 kg A 306. 306. gross gross C-) G Contrivances, water-activated, with l.2L UN0248 II 1.2L None 62 None Forbidden Forbidden 08 8E, 70 burster, expelling charge or propel 14E, ling charge. C) I SE, p. 17E 0 Contrivances, water-activated, with 1.3L UN0249 II 1.3L 62 None Forbidden Forbidden 08 88, burxte, expelling charge or propel 14E, cj ling charge. II 15E, 17E Copper acetoarxenite 6.1 UN1585 6.1 188, P2, P4, T3, TP33 153 212 242 25 kg 100kg A Copper acetylide Forbidden II 0 Copper amine azide Forbidden m Copper arxenite 6.1 UN1586 6.1 1B8, P2, lP4, T3, TP33 153 212 242 25 kg 100kg A 0. Copper based pesticides, liquid, 3 UN2776 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30L B 40 flammable, toxic, flash point less 0 than 23 degrees C. x CD 0. N 0. — 0 0 0 0 4j 0 3 -4 —
(0)
40 58 52 40 40 62 40 40 40 40 40 40 40 40 40 40 40 40 40
19,
56,
40,52 40,
13,
48,119
B B B B B B A 8 B B A A 06 B A B A A A 06 06 A A A 07 07 A 07
L L
kg kg kg kg kg kg kg kg kg
30L 60L 60L 30L 30L 30L 30L 60L 60 60L
2.5L 2,SL 2.5L
50 75 75 25 220L 220 75
100 100 100 200
Forbidden Forbidden Forbidden Forbidden
L L L L
kg kg kg kg kg kg
1L IL 1L iL 1L 1L 5L 5L 5L SL
5 5
60L 60
0.5 0.5 0.5
25 25 25
100
Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden
None None None None 242 242 242 None None 243 241 242 243 243 243 241 242 242 241 243 241 242 243 243 240 240 242 243
201 211 202 202 203 213 201 202 212 213 62 62 201 203 201 212 204 213 62 62 201 202 203 203 62 62 202 202 ......
153 153 153 154 153 152 154 154 None 153 153 None 154 150 None 163 154 154 None None None None None None None None 63(a) None
1P7 T3,
102
TP2, TP2,
TP28 TP27 TP33 TP33 TP27 TP27 TP27 TP28 TP33 TP33 TP33 TP27 TP27 TP28 TP27 TP27 TP27 TP33 TP28 TP27
TP13, TP13, TP13,
P3,
1P4,
T3, T3, T6, Ti, Ti,
T14, T14,
TP2, TP2, TP2, TPI, TP2, TP2. TP2, TPi.
TP2, TP2, TP2,
p2,
88, TP13.
1P4, 1P4, 1P3, 1P3, IP1,
T7, T7, T7, T7,
BlO, BlO,
TIl, Tii, T14, T11,
Til, Til, Til, 88,
TP2.
P2, 88, 88, 87,
1P2,
83,
AS, 1B3, AS, 183, 1B3,
AS,
182, 1B2, 182,
1B2, 182, 182,
Al,
T14,TP2,TP13,TP27 T14, 88, 88,
81,
82, 82, 82,
6.1
1.10 1.40 1.4G.. 1.40 1.20 liD 6.1 8 6.1 6.1 6.1 5.1 6.1 8 8 8 3, 6.1 6.1,3 6.1,3 6.1,3 6.1 8 8 8 8 4.2
I I IS
II II II II II II II II II II II II
Ill Ill Ill Ill III Ill III
UN3O1O UN2775 UNOOS6 UN3264 UN3265 UN3009 UN2721 UN2802 UN3266 UN1587 UN1363 UN0065 UN0289 UNOIO4 UN0102 UN0290
8 8 8 8
6.1 6.1 5.1 6.1 6.1
4.2
.4D
liD 1.4D 1 liD 1.20 1.4G
Forbidden
or or
not
toxic
toxic Cord, Fuse,
liquid,
clad.
organic,
or
inorganic, point inorganic,
detonating detonating
see
detonating,
liquid, solid,
metal
Selenates C.
Selenates
effect
smokeless
flash
Fuse
Fuse, acidic,
fuse,
basic,
Cord,
acidic,
see
effect see
pesticides,
nitrate mild flexible flexible
or or
degrees
pesticides, pesticides,
etc;
mild
Powder,
liquid, 23
liquid,
liquid,
detonant
based
flammable,
selenite,
selenate,
clad. see clad.
based fetramine based
chlorate cyanide chloride
than
detonating detonating, igniter detonating, detonating
detonating
Selenites. n.o.s.. toxic, metal metal flexible. no.5. no.5.. less Selenites. detonating, detonating,
Copper Copper Copper Cordeau Copper Cord Cordite, Corrosive Copper Copper Copper Copra Cord, Cord, Cord, Copper Copper Cord, Cord, Corrosive Corrosive
G G G
AW
Cl, CD 0 C 0, ‘0 C) C) C m 0 0. -S 52 52 52 52 40 40 40 89 89 40 40 40 40 52 52 52 52 52 52 40, 40, 25, (lOB) 40, 40, 25, 40 Other 12,25 (10) Vessel stowage tjo (1OA) B B A D 0 C C B B A B B C C B B B B A E B B B B B A B A B A A L L L L L L L L L L L L L L L L kg kg kg kg kg kg kg kg kg kg kg kg kg iL 5L air- 60 30 60 30 30 30 60 30 30 60 only 2.5 2.5 2.5 2.5 2.5 2.5 25 50 25 50 25 50 50 25 25 and 100 100 100 100 (9B) craft Cargo limitations 73.27 (9) 1 L L L L L 175.75) kg kg kg kg kg kg kg kg kg kg kg kg 1L 1L 5L IL 1L § 5L 1L IL 5L iL 5L 1 1 1 1 1 0.5 0.5 0.5 0.5 0.5 15 kg 15 15 15 25 25 25 25 (9A) Quantity (see Forbidden Forbidden Passenger aircraft/rail Bulk (8C( — 241 243 242 241 243 242 243 243 243 242 241 243 243 243 243 241 243 243 242 240 240 242 240 240 242 240 240 240 242 240 242 (8) 73.) bulk (86) Non- I 203 201 202 201 203 201 202 202 202 203 201 201 202 202 201 211 203 201 212 202 211 213 211 212 213 212 212 213 211 213 211 ( Packaging (8A) tions Excep- 154 None 154 154 154 None 154 154 None None 154 None — 154 None None None None None 154 154 154 None 154 154 154 None 154 None 154 None None A7 A7 IB1 182 BlO TP2 TP2, TP2, TP2, TP2, TP28 TP27 TP27 TP28 TP27 TP27 TP27 TP27 TP28 TP27 TP28 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 A6, A6, A6, A7 62, A7, A6, T7, TABLE—Continued T6, T3, Ti, T6, T3, T6, T3, Ti, TI, T3, Ti, T6, T14, T6, T14, T14, T14, TP1, TP2, TP1, TP2, TP2, TP1, TP1, A6, TPI3, lB2, provisions P1, P3, P3, P1, P3, (7) 1P4, IP1, lP4, lP4, 1P4, 186, 1P3, IPI, T7, T7, T7, T7, BlO, 810, BlO. BlO, 172.102) Til, T11, Til, B3, ( 87, P2, 87, 88, 1P2, 1B8, 187, 1B7, 1B8, 1P2, lP2, 188, 1B3, A6, 183, A6, A7, lB3, 183, A7, lB2, 182, 1B2, Special MATERIALS A6, 188, A6, 188, 188, lB8, 82, B2, B2, 3 3 4.2 5.1 5.1 (6) 4.3 4.3 Label Codes 8 8 8 8. 8 8, 8 8, 8,4.2 8 8, 8 8, 6.1 8. 6.1 8, 8, 6.1 8, 8 8 8 8. 8 8 8 8 8 8 8 8,4.1 8 8 II Ill Ill Ill Ill Ill Ill Ill Ill HAzARDous (5) PG (4) 172.101 Identi- fication Numbers UN3267 UN3301 UN2920 UN1760 UN3093 UN2922 UN3094
§ UN3260 UN3261 UN3262 UN3263 UN2921 8 8 8 8 8 8 8 8 8 8 8 8 or (3) Hazard Division class .. .. n.o.s. n.o.s. n.o.s. no.s. no.5. n.o.s n.o.s inorganic, inorganic, names no.5 descriptions organic, organic, water-reactive, organic, basic, acidic, no.s flammable, oxidizing, toxic, (2) basic, shipping self-heating, flammable, acidic, basic, materials liquids, solid, solid, liquid, liquids, liquid, liquids, liquids, liquids, solid, solids, solid, proper and Hazardous n.o.s.. no.5.. no.5.. Corrosive Corrosive Corrosive Corrosive Corrosive Corrosive Corrosive Corrosive Corrosive Corrosive Corrosive Corrosive G G G G G G G G S 0 S G (1) bols Sym- 00.
II 8, 4.1 68, P2, 1P4, T3, TP33 None 212 242 15 kg 50 kg B 12, 25 B C Corrosive solids, no.s 8 UN1759 II 8 lB7, IP1, T6, TP33 None 211 242 1 kg 25 kg 8 128, 188, lP2, 1P4, T3, 154 212 240 15 kg 50 kg A (D TP33 Ill 8 128, 1B8, 1P3, Ti, TP33 154 213 240 25 kg 100 kg A Corrosive oxidizing, S.O.S C solids. 8 UN3084 8, 5.1 T6, TP33 None 211 242 1 kg 25 kg C 0 II 8, 5.1 lBS, 1P2, T3, TP33 None 212 242 15 kg 50 kg C
G Corrosive solids, self-heating, no.s 8 UN3095 II 8, 4.2 T6, TP33 None 211 243 1 kg 25 kg C
II 8, 4.2 1B6, 1P2, T3, TP33 None 212 242 15 kg 50 kg C toeic, ]: C Corrosive solids, no.5 8 UN2923 8, 6.1 1B7,T6, TP33 None 211 242 1 kg 25 kg B 40 0 8, 6.1 1B8, 1P2, 1P4, T3, TP33 154 212 240 15 kg 50 kg B 40 N B III 8, 6.1 1B8, P3, Ti, TP33 154 213 240 25 kg 100 kg 40,95 — C Corrosive solids, water-reactive, 8 UN3096 8, 4.3 1B4, IP1, T6, TP33 None 211 243 1 kg 25 kg 0 0. no.5.. . 0 C II 8, 4.3 1B6, 1P2, T3, TP33 None 212 242 15 kg 50 kg 0 DW Cotton 9 NA1365 9 137, 168, 1P2, P4, W41 None None None No limit No limit A AW Cotton waste, oily 4.2 UN1364 Ill 4.2 188, P3, 1P7 None 213 None Forbidden Forbidden A Al Cotton, wet 4.2 UN1365 Ill 4.2 188, 1P3, 1P7 None 204 241 Forbidden Forbidden A w Cournarin derivative pesticides, liq- 3 UN3024 3, 6.1 T14. TP2, TPI3, TP27 None 201 243 Forbidden L B I . I 30 uid, flammable, toxic, flash point less than 23 degrees C. B II 3, 6.1 1B2,T11,TP2,TP13, 150 202 243 1L 60 L TP27 B Coumarin derivative pesticides, liq- 6.1 UN3026 6.1 T14,TP2,TP13,TP27 Nose 201 243 1L 30 L uid, tonic. 6.1 II 162, Til, TP2, TP27 153 202 243 5L 60 L B 6.1 Ill 183, T7, TP1, TP28 153 203 241 60 L 220 L A Coumarin derivative pesticides, liq- 6.1 UN3025 6.1,3 T14,TP2,TP13,TP27 None 201 243 1L 30 L B uid, toxic, flammable, flash point 23 degrees C. not less than B II 6.1. 3 lB2, T11, TP2, TP13, 153 202 243 5L 60 L TP27 Ill 6.1, 3 81, 63, T7, TP1, TP28 153 203 242 60 L 220 L A Coumarin derivative pesticides, solid, 6.1 UN3027 6.1 167, IP1, T6, TP33 None 211 242 5 kg 50 kg A toxic. II 6.1 168, lP2, lP4, T3, TP33 153 212 242 25 kg 100 kg A Ill fl.1 lB8, lP3, Ti, TP33 153 213 240 100 kg 200 kg A Cresols. liquid 6.1 UN2076 II 6.1,8 162, 1P2, 1P4,T7, TP2 153 202 243 1L 30 L B 6.1 II Cresols, solid UN3455 II 6.1,8 lB8, lP2, lP4, T3, TP33 153 212 242 15 kg 50 kg B Cresylic acid 6.1 UN2022 62, T7, TP2, TP13 153 202 243 1L 30 L B 6.1 6.1,8 Crotonaldehyde or Crotonaldehyde, UN1143 6.1, 3 2, 175, 89, 614, 632, None 227 244 Forbidden Forbidden B stabilized. 677, T20, TP2, TP13, TP38, TP45 Crotonic acid, liquid 8 UN3472 Ill 8 1B8,Ti 154 203 241 5L 60 L A Crotonic acid, solid 8 UN2823 Ill 8 188, lP3, Ti, TP33 154 213 240 25 kg 100 kg A Crotonylene 3 UN1144 Tii, TP2 150 201 243 1L 30 L 6 8 Cupriethylenediamine solution UN176I II 8, 6.1 lB2, T7, TP2 154 202 243 1L 30 L A Ill 8, 6.1 1B3,T7, TPI, TP28 154 203 242 5L 60 L A Cutters, cable, explosive 1.4S UNOO7O II 1.4S None 62 62 25 kg 100 kg 05 § 172.101 HAzARDous MATERIALS TABLE—Continued L0
(8) (9) (10) Vessel Hazard Identi- Packaging Quantity limitations stowage C Sym- Hazardous materials descriptions Label Special provisions (173.***) (see §173.27 and bols and proper shipping names class or fication PG Division Numbers Codes ( 172.102) — 175.75) Excep- Non- Bulk Passenger Cargo air- Other Sons bulk I aircraftlrail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (96) (1OA( (108) [ Cyanide or cyanide mixtures, dry, see Cyanides, inorganic, solid, n.o.s..
Cyanide solutions, no.s 6.1 UN1935 6.1 B37, T14, TP2, TP13, None 201 243 1L 30 L B 40, 52 TP27 6.1 162, Til, TP2, TPI3, 153 202 243 5L 60 L A 40, 52 TP27 6.1 Ill 83,17, TP2, TP13, 153 203 241 60 L 220 L A 40, 52 TP28 Cyanides, inorganic, solid, s.o.s 6.1 UN1588 6.1 187, lPl, N74, N75, T6, None 211 242 5 kg 50 kg A 52 -I TP33 6.1 198, 1P2, 1P4, N74, N75, 153 212 242 25 kg 100 kg A 52 T3, TP33 6.1 Ill 188, 1P3, N74, N75, Ti, 153 213 240 100 kg 200 kg A 52 TP33 Cyanogen 2.3 UN1026 2.3, None 304 245 Forbidden Forbidden D 40 2.1. D Cyanogen bromide 6.1 UN1889 6.1, 8 A6, AS, T6, TP33 None 211 242 I kg 15kg 40 D Cyanogen chloride, stabilized 2.3 UN1589 2.3, 8 None 192 245 Forbidden Forbidden 40 Cyanuric chloride 8 UN2670 8 188, 1P2, 1P4,T3, TP33 None 212 240 15 kg 50 kg A 12, 40 Cyanuric triazide Forbidden 0 Cyclobutane 2.1 UN2601 2.1 306 304 314, Forbidden 150 kg B 40 315. Cyclobutyl chloroformate 6.1 UN2744 6.1,8, IB1, T7, TP2. TP13 153 202 243 IL 30 L A 12, 13, C) 3. 21, 25, 40, 100 6.1 1,5,9-Cyclododecatriene UN2518 Ill 6.1 lB3, T4, TP1 153 203 241 60 L 220 L A 40 Cycloheptane 3 UN2241 3 lB2. T4, TP1 150 202 242 5L 60 L 8 40 Cycloheptatriene 3 UN2603 3, 6.1 1B2,T7, TP1, TP13 150 202 243 1L 60 L 8 40 Cycloheptene 3 UN2242 3 Bi, 182. T4, TP1 150 202 242 5L 60 L B Cyclohexane 3 UN1145 3 182, T4, TP1 150 202 242 5L 60 L E 3 C Cyclohexanone UN1915 Ill 3 81, 1B3,T2, TP1 150 203 242 60 L 220 L A Cyclohexene 3 UN2256 3 182, T4, TP1 150 202 242 5L 60 L E 0. Cyclohexenyltrichlorosilane 8 UN1762 8 A7, 82, N34, Tb, TP2, None 206 242 Forbidden 30 L C 40 TP7, TP13 0 Cyclohexyl acetate 3 UN2243 Ill 3 Bi, 183, T2, TP1 150 203 242 60 L 220 L A Cyclohexyl isocyanate 6.1 UN2488 I 6.1, 3 2, B9, 814, 832, B77, None 227 244 Forbidden Forbidden D 40 T20, TP2, TP13, TP38, TP45 Cyclohexyl mercaptan 3 UN3054 III 3 Bi, 1B3,T2, TP1 150 203 .... 242 .... 60 L 220 L A 40, 95 Cyclohexylamine 8 UN2357 II 8, 3 82, T7, TP2 None ... 202 .... 243 ,... 1 L 30 L A 40 Cyclohexyltrichlorosilane 8 UN1763 II 8 A7, B2, N34, Tb, TP2, None ... 206 .... 242 .... Forbidden 30 L C 40 0 TP7,TP13 Cyclonite and 0. cyclotetramethylenetetranitramine = mixtures, wetted or desensitized N see RDX and HMX mixtures, 0 wetted or desensitized etc a Cyclonite and HMX mixtures, wetted 0 or desensitized see RDX and HMX mixtures, wetted or desensitized etc. Cyclonite and octogen mixtures, a wetted or desensitized see ROX and HMX mixtures, wetted or de sensitized etc. Cyclonite, see Cyclotrimethylenetrinitramine, etc. 0 Cyclooctsdiene phosphines, see 9- Phosphabicyclononanes. C..n Cyclooctsdienes 3 UN2520 III 3 81, 1B3,T2, TP1 150 203 .... 242 .... 60 L 220 L A Cyclooctatetraene 3 UN2358 II 3 1B2,T4. TP1 150 202 .... 242 .... 5 L 60 L B Cyclopentane 3 UN1146 II 3 182, T7, TP1 150 202 .... 242 .... 5 L 60 L E Cyclopentane, methyl, see Methylcyclopentane.
Cyclopentanol 3 UN2244 III 3 81, 1B3,T2, TPI 150 203 .... 242 .... 60 L 220 L A Cyclopentsnone 3 UN2245 III 3 B1, B3,T2, TPI 150 203 .... 242 .... 60 L 220 L A 0 Cyclopentene 3 UN2246 II 3 1B2, P8, T7, TP2 150 202 .... 242 .... 5 L 60 L B Cyclopropane 2.1 UN1027 2.1 T50 306 304 .... 314, Forbidden 150 kg 8 40 315. Cyclotetramethytene tetranitramine Forbidden (dry or unphlegmatized) (HMX). Cyclotetramethylenetetranitramine, liD UN0484 II lID .. None ... 62 None Forbidden Forbidden 10 desensitized or Octogen, desen sitized or HMX,desensitized. Cyclotetramethylenetetrsnitramine, liD UN0226 II liD .. None ... 62 None Forbidden Forbidden 10 wetted or HMX, wetted or Octogen, wetted with not less than 15 percent water, by mass. 0) Cyclotrimethylenenitramine and octogen, mixtures, wetted or dx- r) sensitized see RDX and HMX mix- — tures, wetted or desensitized, etc. 0 § 172.101 HAzARDous MATERIALS TABLE—Continued 0
(8) (9) (10) Vessel Hazard Identi- Packaging Quantity limitations stowage C Sym- Hazardous materials descriptions Label Special provisions I73.•) (see 173.27 and bols and proper shipping names class or fication PG ( § Division Numbers Codes ( 172.102) — — 175.75) Excep- Non- Other tions bulk Bulk Passenger Cargo air- fl aircraWrail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (88) (BC) (9A) (9B) (1OA) (lOB) Cyclotrimethylenetririitramine and cyclotetramethylenetetranitramine mixtures, wetted or desensitized see RDX and HMX mixtures. wetted or desensitized etc. Cyclotrimethylenetrinitramine and HMX mixtures, wetted or desen sitized see RDX and HMX mix tures. wetted or desensitized etc. Cyclotrimethylenetrinitramine, desen 1.10 UN0483 liD None ... 62 None Forbidden Forbidden 10 sitized or Cyclonite, desensitized or Hexogen, desensitized or RDX, desensitized. Cyclotrimethylenetrinitramine, wetted 1.1D UN0072 liD None ... 62 None Forbidden Forbidden 10 or Cyclonite, wetted or Hexogen, wetted or RDX, wetted with not less than 15 percent water by mass. Cymenes 3 UN2046 III 3 81, 1B3,T2, TP1 150 203 242 60 L 220L A 9 Dangerous Goods in Machinery or UN3363 136, A105 None 222 None See A105 See A105 A. Dangerous Goods in Apparatus. ‘0 Decaborane 4.1 UN1868 II 4.1, A19, A20, 1B6, P2, T3, None 212 None C-) Forbidden 50kg A 74 11 6.1. TP33 Decahydronaphthalene 3 UN1147 Ill 3 81,183, T2, TP1 150 203 242 60 L 220L A Ill 3 C-) n-Decane 3 UN2247 81, 183, T2, TP1 150 203 242 60 L 220L A Deflagrating metal salts of aromatic 1.3C UN0132 II 1.3C None 62 None Forbidden Forbidden 10 SE nitroderivatives, no.s.. Delay electric ignitei see Igniters D Denatured alcohol 3 NA1987 II 3 172, TB 150 202 242 5L 60L 8 Ill 3 172, Bi, T7 150 203 242 60 L 220L A Depth charges, see Charges, depth 3 B Desensitized explosive, liquid, no.s. 3 UN3379 164 None 201 None Forbidden Forbidden D 36 C B Desensitized explosive, solid, no.s. 4.1 UN3380 4.1 164 None 211 None Forbidden Forbidden D 28, 36 m Detonating relays, see Detonators, 0 etc. Detonator assemblies, non-electric 1.18 UN0360 1,18 None 62 None Forbidden Forbidden 11 0 for blasting. 0Cl,
Detonator assemblies, non-electric, 1.4B UN0361 II 1.48 103 63(f), 62...... None Forbidden 75kg 06 for blasting. II 63(g). •0 CD Detonator, assemblies, non-electric 1.4S UN0500 II 1.4S 63(f), 62 None 25 kg 100 kg 05
for blasting. II 63(g). CD
Detonators, electric, for blasting 1.1B UNOO3Q II 1.18 63(t), 62 None Forbidden Forbidden 11 63(g). II Q 103 Detonators, electric, for blasting 1.4B UN0255 II 1.48 63(f), 62 None Forbidden 75kg 06 II II 63(g). 0. Detonators, electric for blasting 1.4S UN0456 1.4S 63(f), 62 None 25 kg 100 kg 05 = 0 63(g). N Detonators for ammunition 1.16 UN0073 1.1B None 62 None Forbidden Forbidden 11 Detonators for ammunition 1.28 UN0364 1.28 None 62 None Forbidden Forbidden 11 0. Detonators for ammunition 1.4B UN0365 1.48 103 None 62 None Forbidden 75kg 06 Detonators for ammunition 1.4S UN0366 1.4S None 62 None 25 kg I00 kg 05 C Detonators, non-electric, for blasting 1.IB UN0029 II 1.18 None 62 None Forbidden Forbidden 11 II Detonators, non-electric, for blasting 1.4B UN0267 1.48 103 63(f), 62 None Forbidden 75kg 06 63(g). 0 Detonators, non-electric, for blasting 1.4S UN0455 1.4S 63(f), 62 None 25 kg 100 kg 05 CD 63(g), 0 Deuterium, compressed 2.1 UN1957 2.1 N89 306 302 None Forbidden 150kg E 40 2.1 Devices, small, hydrocarbon gas UN3150 2,1 306 304 None 1 kg 15kg B 40 Cd) powered or Hydrocarbon gas refills 0 for small devices with release de CD vice. Di-n-amylamine 3 UN2841 Ill 3, 6.1 81,183, T4, TP1 150 203 242 60 L 220L A Di-n-butyl peroxydicarbonate, with Forbidden 0. more than 52 percent in solution. 3 Di-n-butylamine 8 UN2248 8, 3 182, T7, TP2 None 202 243 1L 30L A 2,2-Di-(tert-butylperoxy) butane, with Forbidden more than 55 percent in solution. Di-(tert-butylperoxy) phtha late, with Forbidden V more than 55 percent in solution. -4 2,2-Di-(4,4-di-tert- Forbidden butylperoxycyclohexyl) propane, with more than 42 percent with inert solid, Di-2,4-dichlorobenzoyl peroxide, with Forbidden more than 75 percent with water. 242 1,2-Di-(dimethylamino)ethane UN2372 II 3 1B2,T4, TP1 150 202 5L 60L B Di-2-ethylhexyl phosphoric acid, see Disooctyl acid phosphate. Di-(l-hydroxytetrazole) (dry) Forbidden
Di-(l-naphthoyl) peroxide Forbidden II Ce, a,a’-Di-(nitroxy) methylether Forbidden Di-(beta-nitroxyethyl) ammonium ni Forbidden trate. 3 242 Diacetone alcohol 3 UN1148 3 1B2,T4, TP1 150 202 5L SQL B 242 C Ill 81, 83, T2, TP1 150 203 60 L 220L A § 172.101 HAZARDous MATERIALSTABLE—Continued C0
(8) (9) (10) Vessel Hazard Identi . Packaging Quantity limitations stowage C Sym- Hazardous materials descriptions Label Special provisions 173.) (see 173.27 and bols and proper shipping names class or fication ( § Division Numbers Codes ( 172.102) — — 175.75) Excep- Non- Lacna Other tions bulk Bulk Passenger Cargo air- aircraft/rail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C( (9A) (9B) (leA) (lOB)
Diacetone alcohol peroxides, with Forbidden more than 57 percent in solution with more than 9 percent hydrogen peroxide, less than 26 percent diacetone alcohol and less than 9 percent water; total active oxygen content more than 9 percent by mass. Diacetyl, see Butanedione Diacetyl peroxide, solid or with more Forbidden than 25 percent in solution. Diallylamine 3 UN2359 II 3,6,1, lB2, T7, TP1 150 202 243 1L 5L B 21, 40, 8. 100 0O Diallylether UN2360 II 3, 6.1 lB2, N12, T7, TP1, TP13 150 202 243 1L 60 L E 40 4,4’-Diaminodiphenyl methane 6,1 UN2651 III 6,1 88, P3, Ti, TP33 153 213 240 100 kg 200 kg A p-Diazidobenzene Forbidden l,2-Diazidoethane Forbidden 1,1’-Diazoaminonaphthalene Forbidden Diazoaminotetrazole (dry) Forbidden Diazodinitrophenol (dry) Forbidden Diazodinitrophenol, wetted with not hA UN0074 II 1.1A 111, 117 None 62 None Forbidden Forbidden 12 less than 40 percent water or mix C) ture of alcohol and water, by mass. -n Diazodiphenylmethane Forbidden Diazonium nitrates (dry) Forbidden C-) Diazonium perchlorates (dry) Forbidden 1,3-Diazopropane Forbidden Dibenzyl peroxydicarbonate, with Forbidden more than 87 percent with water. Dibenzyldichlorosilane 8 UN2434 II 8 B2, Tie, TP2, TP7, 154 206 242 IL 30 L C 40 TP13 Diborane 2.3 UN1911 2.3, 1, N89 None 302 None Forbidden Forbidden D 40, 57 2.1. C D Diborane mistures 2.1 NA19I1 2.1 5 None 302 245 Forbidden Forbidden D 40, 57 m Dibromoacetylene Forbidden 0. 1,2-Dibromobutan-3-one 6.1 UN2648 II 6.1 lB2 153 202 243 5L 60 L B 40 Dibromochloropropane 6.1 UN2872 II 6.1 62, T7, TP2 153 202 243 5L 60 L A 0 III 6.1 lB3, T4, TP1 153 203 241 60 L 220 L A 00.00(D
Dibromodifluorornethane, R1282 g UN1941 Ill None Til, TP2 I 155 ...... I 203 .... I 241 100 L 220 L A 25 l,2-Dibromoethane, see Ethylene dibroniide. (D A Dibromomethane 6.1 UN2664 Ill 6.1 1B3,T4, TP1 153 203 241 60 L 220 L A Dibutyl ethers 3 UN1149 Ill 3 Bi, 83, T2, TP1 150 203 242 60 L 220 L (D A Dibutylaminoethanol 6.1 UN2873 Ill 6.1 1B3,T4, TP1 153 203 241 60 L 220 L N,N’-Dichlorazodicarbonamidine Forbidden (salts of) (dry). A 6.1 1,1-Dichloro-1-nitroethane 6.1 UN2650 182, T7, TP2 153 202 243 5L 60 L 12, 40, A 6.1 2 D 3,5-Dichloro-2,4,6-trifluoropyridine 6.1 NA9264 2, 89, 614, B32, T20, None 227 244 Forbidden Forbidden 40 0 TP4, TP13, TP38, TP45 0. Dichloroacetic acid 8 UN1764 8 A3, A6, A7, 62, 1B2. 154 202 242 1L 30 L A N34, T8, TPZ C,, 1,3-Dichloroacetone 6.1 UN2649 6.1 1B8, P2. 1P4, T3, TP33 153 212 242 25 kg 100 kg B 12,40 Dichioroacetyl chloride 8 UN1765 8 A3, A6, A7,B2, B6. 62. 154 202 242 1L 30 L D 40 N34, T7, TP2 Dichloroacetylene Forbidden (D + Dichioroanilines, liquid 6.1 UN1590 6.1 1B2, T7, TP2 153 202 243 5L 60 L A 40 Dichioroanilines, solid 6.1 UN3442 6.1 1B8, 1P2, 1P4, T3, TP33 153 212 242 25 kg 100 kg A 40 +1 o-Dichlorobenzene 6.1 UN1591 Ill 6.1 1B3, T4, TP1 153 203 241 60 L 220 L A C,, 2,2-Dichlorodiethyl ether 6.1 UN1916 6.1, 3 162, N33, N34, T7, TP2 153 202 243 5L 60 L A Dichlorodifluoromethane and 2.2 UN2602 2.2 T50 306 304 314, 75 kg 150 kg A diftuoroethane azeotropic mixture 315. or Refrigerant gas R 500 with ap proximately 74 percent dichioro 0. difluoromethane. A Dichlorodifluoromethane or Refrig 2.2 UN1028 2.2 T50 306 304 314, 75 kg 150 kg 3 erant gas R 12. 315. Dichlorodimethyl ether, symmetrical 6.1 UN2249 6.1, 3 None 201 243 Forbidden Forbidden 40 1,1-Dichloroethane 3 UN2362 3 182, T4, TP1 150 202 242 5L 60 L 8 40 l,2-Dichloroethane, see Ethylene di- -4 chloride. Dichloroethyl sulfide Forbidden
1,2-Dichloroethylene 3 UN1150 3 1B2,T7, TP2 150 202 242 5L 60 L B Dichlorofluoromethane or Refrigerant 2.2 UN1029 2.2 T50 306 304 314, 75 kg 150 kg A gas R21. 315. Dichloroisocyanuric acid, dry or 5.1 UN2465 5.1 28, 1B8, 1P2, 1P4, T3, 152 212 240 5 kg 25 kg A 13 Dichloroisocyanuric acid salts. TP33 6.1 6.1 Dichioroisopropyl ether UN2490 162, T7, TP2 153 202 243 5L 60 L B 6.1 6.1 Dichioromethane UN1593 Ill 1B3, 1P8, N36, T7, TP2 153 203 241 60 L 220 L A Ill Dichioropentanes 3 UN1152 3 B1, 1B3, T2, TP1 150 203 242 60 L 220 L A Dichiorophenyl isocyanates 6.1 UN2250 6.1 88, P2, 1P4, T3, TP33 153 212 242 25 kg 100 kg B 25, 40, 48 — Dichlorophenyltrichlorosilane 8 UN1766 8 A7, 82, B6, N34, Tb, None 206 242 Forbidden 30 L C 40 TP2, TP7, TP13 3 1,2-Dichloropropane 3 UN1279 162, N36, T4, TP1 150 202 242 5L 60 L B 0 1,3-Dichloropropanol-2 6.1 UN2750 6.1 182, T7, TP2 153 202 243 5L 60 L A 12,40 — §172.101 HAZARDOus MATERIALSTABLE—Continued C0)
(8) (9) (10) Vessel Packaging Quantity limitations stowage Hazard Identi- (173.***) C Sym- Hazardous materials descriptions class Label Special provisions (see §173.27 and bols and proper shipping names or fication PG Codes Division Numbers ( 172.102) — 175.75) Excep- Non- Bulk Other boos bulk Passenger Cargo air- fi aircraft/rail craft only
(I) (2) (3) (4) (5) (6) (7) (8A) (8B) (BC) (9A) (9B) (bA) (lOB) Dichioropropene and propylene di chloride mixture, see 1,2- Dichloroproparre. Dichloropropenes 3 UN2047 3 lB2, T4, TP1 150 202 242 5L 60L B 3 81, 1B3,T2, TP1 150 203 242 60 L 220L A Dichlorosilane 2.3 UN2189 2.3, 2, B9, B14 None ... 304 314, Forbidden Forbidden D 17, 40 2.1, 315. 8. I ,2-Dichloro-1.1,2,2- 2.2 UN1958 2.2 T50 306 304 314, 75 kg 150kg A tetrafluoroethane or Refrigerant 315. gas R 114. Dichiorovinylchioroarsine Forbidden 00 Dicyclohepfad/ens, see Bicyclo [2,2,1] hepta-2,5-diene, stabilized. Dicyclohexylsmine 8 UN2565 Ill 8 1B3,T4, TPI 154 203 241 5L 60 L A Dicyclohesylammonium nitrite 4.1 UN2687 Ill 4.1 1B8, lP3, Ti, TP33 151 213 240 25 kg 100 kg A 48 A Dicyclopentadiene 3 UN2048 Ill 3 81, 1B3,T2, TP1 150 203 242 60 L 220 L A Didymium nitrate 5.1 UN1465 Ill 5.1 Al, lB8, P3, TP33 152 213 Ill TI, 240 25 kg 100 kg Diesel fuel 3 NA1993 None 144, 81, 183, T4, TP1, 150 203 242 60 L 220 L A Ill TP29 Diesel fuel 3 UN1202 3 144, 81, 183, T2, TPI 150 203 242 60 L 220 L A Diethanol nitrosamine dinitrafe (dry) Forbidden Ill 3 150 C) Diethoxywethane 3 UN2373 182, T4, TP1 202 242 5L 60 L E ,, 3 150 3,3-Diethoxypropene 3 UN2374 1B2,T4, TP1 202 242 60 L B 3 150 5L Diethyl carbonate 3 UN2366 81, 183, T2, TP1 203 242 60 L 220 L A C) Diethyl cellosolve, see Ethylene gly col diethyl ether. 3 Diethyl ether or Ethyl ether 3 UN1155 3 Til, TP2 ISO 201 243 IL 30 L E 40 Diethyl ketone UN1156 3 82, T4, TPI ISO 202 242 5L 60 L B 0/ethyl peroxydicarbonate, with more Forbidden than 27 percent in solution. Diethyl sulfate 8.1 UN1594 6.1 82, T7, TP2 153 202 243 5L 60 L C UN2375 Diethyl sulfide 3 3 182, T7, TP1, TP13 None 202 243 5L 60 L E C UN1154 Ill Diethylamine 3 Ill 3, 8 A3, 182, N34, T7, TPI 150 202 243 1L 5L E 40 rn UN2686 2-Diethylaminoetharrol 8 Ill 8, 3 82, 182, T7, TP2 None 202 243 1L 30 L A 0. 3 3-Diethyamino-propylamine UN2684 3, 8 81, lB3, T4, TP1 150 203 242 5L 60 L A UN2432 N, N-Diethylaniline 6.1 8.1 183, T4, TP1 153 203 241 60 L 220 L A 0 UN2049 A Diethylbenzene 3 3 81, 183, T2, TPI 150 203 242 60 L 220 L Diethyldichlorosilane 8 UN1767 8, 3 A7, B6, N34, Tb, TP2, None 206 243 Forbidden 30 L C 40 31 TP7, TP13 Diethylene glycol din,trate Forbidden CD Diethyleneglycol dinitrate, desen liD UN0075 liD None 62 None Forbidden 13 218 sitized with not less than 25 per CD cent non-volatile waler-insoluble 0 phlegmatizer by mass. Diethylenetriamine 8 UN2079 8 B2, IB2, T7, TP2 154 202 242 IL 30 L A 40, 52 0. N,N-Diethylethylenediamine 8 UN2685 8. 3 IB2, T7, TP2 None 202 243 1L 30 L A x Diethylgold bromide Forbidden 0 N Diethylthiophosphoryl chloride 8 UN2751 8 B2, tB2, T7, TP2 None 212 240 15 kg 50 kg 12, 40 0 Difluorochloroethanes, 1-Chloro see 0. 1,1-difluoroethanes. 0 1,1-Difiuoroelhane or Refrigerant gas 2.1 UN1O3O 2.1 T50 306 304 314, Forbidden 150 kg B 40 R 152a. 315. U, 1,1-Ditluoroethylene or Refrigerant 2.1 UN1959 2.1 306 304 None Forbidden 150 kg E 40 gas R 1132a. D 0 Diftuoromethane or Refrigerant gas R 2.1 UN3252 2.1 T50 306 302.... 314, Forbidden 150 kg 40 32. 315. Ditluorophosphoric acid, anhydrous 8 UN1768 8 A6, A7, B2, 62. N5, None 202 242 1L 30 L A 40 N34, T8, TP2 Cl, 3 3 2,3-Dihydropyran UN2376 IB2, T4, TPI 150 202 242 5L 60 L B Co 1,8-Dihydroxy-2,4,5, 7- Forbidden 0 letranitroanthraquinone CD Go (chrysamminic acid). Diiodoacetylene Forbidden Disobutyl ketone 3 UN1157 III 3 81, 1B3,T2, TP1 150 203 242 60 L 220 L A 0. Disobulylamine 3 UN2361 III 3, 8 Bi, 1B3,T4, TP1 150 203 242 5L 60 L A 3 3 150 Disobutylene, isomeric compounds UN2050 III 3 IB2, T4, TP1 202 242 5L 60 L B Disooctyl acid phosphate 8 UN1902 8 IB3, T4, TP1 154 203 241 5L 60 L A Disopropyl ether 3 UN1159 3 I82, T4, TP1 150 202 242 60 L E 40 5L Disopropylanrine 3 UN1158 3, 8 IB2, T7, TP1 150 202 243 1L 5L B 0 Diisopropylbenzene hydroperoxide, Forbidden - with more than 72 percent in solu tion. Diketene, stabilized 6.1 UN2521 6.1,3 2, B9, B14, B32, T20, None 227 244 Forbidden Forbidden D 26, 27, TP2, TP13, TP38, TP45 40
1,2-Dimethoxyethane 3 UN2252 3 1B2,T4, TP1 150 202 242 5L 60 L B 3 3 1,1-Dimethoxyethane UN2377 1B2, T7, TP1 150 202 242 5L 60 L B 3 Dimethyl carbonate 3 UN1161 1B2, T4, TP1 150 202 242 5L 60 L B Dimethyl chiorothiophosphate, see Dimethyl thiophosphoryl chloride. 2.5-Dimethyl-2, 5-dihydroperoxy Forbidden hexane, with more than 82 percent cm with water. Dimethyt disulfide 3 UN2381 II 3 82, T4, TP1 150 202 242 60 L 40 Dimethyt ether 2.1 UN1033 2.1 T50 306 304 314, Forbidden5L 150 kg 8 40 315. C Dimethyl-N-propylamine 31UN2266 I II13,8....I 1B2,T7,TP2,TP131150 1202.... 243 1L SL B 40 — § 172.101 HAZARDous MATERIALs TABLE—Continued cot
(8) (9) (10) Vessel Hazard Identi- Packaging Quantity limitations stowage 0 Sym- Hazardous materials descriptions Label Special provisions (l73.***) (see §173.27 and bols and proper shipping names class or ficabon PG Division Numbers Codes ( 172.102) 175.75) Excep- Non- Other tiona bulk Bulk Passenger Cargo air- don aircraWrail craft only (1) (2) (3) (4) (5) (6) (7) (8A( (88) (8C( (9A) (9B) (1OA) (108)
Diwethyl sulfate 6.1 UN1595 6.1,8 2, 89, 814, 832, 877, None ... 227 244 Forbidden Forbidden D 40 T20, TP2, TPI3, TP38, TP45 Dimethyl sulfide 3 UN1164 3 182, 1P8,T7, TP2 150 202 242 5L 60 L B 40 Dimethyl thiophosphoryl chloride 6.1 UN2267 6.1.8 1B2,T7, TP2 153 202 243 1L 30 L B 25 Dimethylamine, 2.1 anhydroua UN1032 2.1 N87, T50 None 304 314, Forbidden 150 kg D 40 315. Dimethylamine solution 3 UN1160 3, 8 62, T7, TP1 150 202 243 1L 5L B 52. 2-Dimethylaminoacetonitrile 3 UN2378 3, 6.1 82, T7, TP1 150 202 243 1L 60 L A 40, 52 2-Dimethylaminoethanol 8 UN2051 8, 3 62, 182, T7, TP2 154 202 243 1L 30 L A 2-Dimethylaminoethyl acrylate 6.1 UN3302 6.1 182, T7, TP2 153 202 243 5L 60 L D 25 2-Dimethylaminoethyl 6.1 6.1 methacrylate UN2522 182, T7, TP2 153 202 243 5L 60 L B 40 I- 6.1 00 N,N-Dimethylaniline 6.1 UN2253 IB1, T7, TP2 153 202 243 60 L A 150 5L 2,3-Dimethylbutane 3 UN2457 3 162, T7, TP1 202 242 60 L E 3 150 5L I, 3-Dimethylbutylamine UN2379 3, 8 82, T7, TP1 202 243 IL 5L B 52. 154 Dimethylcarbamoyl chloride 8 UN2262 8 B2, lB2, T7, TP2 202 242 1L 30 L A 40 3 3 150 Dimethylcyclohexanes UN2263 182, T4, TP1 202 242 5L 60 L B 154 N,N-Dimethylcyclohesylamirie 8 UN2264 8, 3 82, 182, T7, TP2 202 243 3 1L 30 L A 40 Dimethyldichlorosilane UN1162 3, 8 B77, Tb, TP2, TP7, None 206 243 Forbidden Forbidden B 40 3 TP13 Dimethyldiethoxysilane 3 UN2380 II 3 1B2,T4, TP1 150 202 242 5L 60 L B II Dirnethyldiosanes UN2707 B 3 182, T4, TP1 150 202 242 5L 60 L 3 0 3 Ill 81, 1B3,T2, TPI 150 203 242 60 L 220 L A •11 UN2265 Ill 3 N,N-Dimethylformamide 81, 1B3,T2, TP2 150 203 242 60 L 220 L A Dimethylhexane dihydroperoxide Forbidden (dry). 0 UN2382 Dimethylhydrazine, symmetrical 6.1 6.1, 3 2, 89, B14, B32, B77, None 227 244 Forbidden Forbidden B 40, 52, T20, TP2, TP13, TP38, 74. TP45 Dimethylhydrazine, unsymmetrical 6.1 UN1163 6.1,3, 2, B7, B9, B14, 832, None ... 227 .... 244 Forbidden Forbidden B 21, 38, 8. T20, TP2, TP13, TP38, 40, 52, TP45 100. 2,2-Dimethylproparie 2.1 UN2044 2.1 306 304 314, Forbidden 150kg E 40 0 315. m 6.1 6.1 Dinitro-o-cresol UN1598 II 1B8, lP2, 1P4, T3, TP33 153 212 242 25 kg 100kg A 0 1,3-Dinifro-5,5-dimefhyl hydantoin Forbidden Dinitro-7,8-dimethylglycoluril (dry) Forbidden 0 1,3-Dinitro-4,5-dinitrosobenzene Forbidden l,4-Dinitro-l, 1,4,4- Forbidden tatramethylolbutanetetranit rate -D (thy). CD 2,4-Dinitro-1 3,5-frimethylbenzene Forbidden Dinitroanilines 6.1 UN1596 6.1 1B8, 1P2, 1P4, T3, TP33 153 212 242 25 kg 100 kg A 91 CD 6.1 6.1 Dinitrobenzenes, liquid UN1597 II 11, 1B2,T7, TP2 153 202 243 5L 60 L A 91 6.1 C Ill 11, 1B3,T7, TP2 153 203 241 60 L 220 L A gi Dinitrobenzenes, 6.1 6.1 A eolid UN3443 II 1B8, P2, P4, T3, TP33 153 212 242 25 kg 100 kg gi 0. Dinitrochlorobenzene, see = Chlorodinitrobenzene. a I, 2-Dinitroethane Forbidden N 1,1-Dinitroethane (dry) Forbidden a UN1067 Dinitrogen tetroxide 2.3 2.3, I, 87, B14, B45, B46, None ... 336 .... 314 ..., Forbidden Forbidden D 40, 89, a. 5.1, 861, 866, B67, 877, go 0 8. T50, TP21 C Dinitroglycolurilor Dingu liD UN0489 lID None 62 None Forbidden Forbidden 10 Dinitromethane Forbidden Dinitrophenol, dry or wetted with less liD UN0076 liD, None 62 None Forbidden Forbidden 10 SE a than 15 percent water, by mass. 6.1. CD UN1599 Dinhtrophenol solutions 6.1 6.1 182, T7, TP2 153 202 243 5L 60L A 36 6.1 a Ill 1B3,T4, TPI 153 203 241 60 L 220L A 36 U, Dinitrophenol, wetted with not less 4.1 UN1320 4.1, 23, A8, A20, Aig, N41 None 211 None 1 kg 15kg 8 28, 36 cn than 15 percent water, by mass. 6.1. a Dinitrophenolates alkali metals, dry i.3C UN0077 l.3C, None 62 None Forbidden Forbidden 10 5E CD 00 or wetted with less than 15 percent 6.1. water, by mass.
Dinitrophenolates, wetted with not 4.1 I UN1321 4.1, 23, A8, A19, A20, N41 None ... 211 .... None 1 kg 15kg 8 28, 36 less than 15 percent water, by 6.1. a. mass. 3 Dinifropropylene glycol Forbidden Dinitroresorcinol, dry or wetted with lID UN0078 liD None ... 62 None Forbidden Forbidden 10 5E less than 15 percent watei by mass. 0 2,4-Dinitroresorcinol (heavy metal Forbidden -I salts 01) (dry). 4,6-Dinitroresorcinol (heavy metal Forbidden salts of) (dry). Dinitroresorcinol, wetted with not less 4.1 UN1322 4.1 23, AS, A19, A20, N41 None ... 211 .... None 1 kg 15 kg E 28, 36 than 15 percent water, by mass. 3,5-Dinitrosalicylic acid (lead salt) Forbidden (dry). Dinitrosobenzene 1.3C UN0406 1.3C None ... 62 None Forbidden Forbidden 10 Dinitrosobenzylamidine and salts of Forbidden (dry). 2,2-Dinitrostilbene Forbidden Dinitrotoluenes, liquid 6.1 UN2038 II 6.1 1B2,T7, TP2 153 202 243 5L 60 L A II Dinitrotoluenes, molten 6.1 UN1600 II 6.1 T7,TP3 None 202 243 Forbidden Forbidden C 6.1 Dinitrotoluenes, solid UN3454 6.1 1B8, P2, P4, T3, TP33 153 212 242 25 kg 100 kg A 1,9-Dinifroxy pent amethylene-2,4, Forbidden 6,8-fetramine (dry). 0 §172.101 HAzARDouS MATERIALSTA8LE—Continued c0)
(8) (9) 1 (10) Vessel Hazard Identi- Packaging Quantity limitations stowage 0 Sym- Hazardous materials descriptions Label Special provisions i73.) (see 17327 and bole and proper shipping names class or fication PG ( § Division Numbers Codes ( 172.102) — — 175.75) Excep- Non- Loca Other tions bulk Bulk Passenger Cargo air- tion aircraft/rail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (BB) (8C) (9A) (98) )1OA) (lOB)
Dioxane 3 UN1165 3 l82, T4, TP1 150 202 242 5L 60 L B Dioeolane 3 UN1166 3 l82, T4, TP1 150 202 242 5L 60 L B 40 3 Dipentene 3 UN2052 Ill 81, 83, T2, TP1 150 203 242 60 L 220 L A Diphenylamine chioroersine 6.1 UN1698 6.1 T6, TP33 None 201 None Forbidden Forbidden 0 40 Diphenylchloroarsine, liquid 6.1 UN1699 6.1 A8, 814, B32, N33, N34, None 201 243 Forbidden 30 L 0 40 T14, TP2, TP13, TP27 Diphenylchioroarsine, solid 6.1 UN3450 6.1 lB7, lPl, TO, TP33 None 211 242 5 kg 50 kg D 40 Diphenyldichlorosilane 8 UN1769 8 A7, B2, N34, Tb, TP2, None 206 242 Forbidden 30 L C 40 TP7, TP13 Diphenylmethyl bromide 8 UN1770 8 l88, lP2, 1P4, T3, TP33 154 212 240 15 kg 50 kg 0 40 Dipicryl sulfide, dry or wafted with 1.10 UN0401 liD None 62 None Forbidden Forbidden 10 less than 10 percent water, by Go mass. Dipicryl sulfide, wetted with not less 4.1 UN2852 4.1 162,A2,N41,N84 None ... 211 .... None Forbidden 0.5 kg 0 28 than 10 percent water; by mass. Dipicrylamine, see Hexanitrodiphenylamine. Dipropionyl peroxide, with more than Forbidden 28 percent in solution. Di-n-propyl ether 3 UN2384 3 lB2, T4, TP1 150 202 242 5L 60 L B Dipropyl ketone 3 UN2710 Ill 3 81, 83, T2, TP1 150 203 242 60 L 220 L A ‘0 Dipropylamine 3 UN2383 3, 8 182, T7, TP1 150 202 243 1L 5L B C) G Disinfectant, liquid, corrosive, no.5. 8 UN1903 8 A6, A7, BlO, T14, TP2, None 201 243 0.5 L 2.5 L B -n TP27 G Disinfectants, liquid, corrosive no.s 8 UN1903 8 82, 1B2, T7, TP2 154 202 242 1L 30 L B 0 Ill 8 183, T4, TP1 154 203 241 5L 60 L A G Disinfectants, liquid, toxic, no.5 6.1 UN3142 6.1 A4, T14, TP2, TP27 None 201 243 1L 30 L A 40 II 6.1 182, TIl. TP2, TP27 153 202 243 5L 60 L A 40 Ill 6.1 1B3,T7, TP1, TP28 153 203 241 60 L 220 L A 40 G Disinfectants, solid, toxic, n.o.s 6.1 UN1601 6.1 187, P1, T6, TP33 None 211 242 5 kg 50 kg A 40 6.1 88, 1P2, lP4, T3, TP33 153 212 242 25 kg 100 kg A 40 Ill 6.1 lB8, 1P3, Ti, TP33 153 213 240 100 kg 200 kg A 40 Ill Disodium trioxosilicate 8 UN3253 8 IB8, 1P3, Ti, TP33 154 213 240 25 kg 100 kg A 52. 0 G Dispersant gases, no.5. see Refrig- m erant gases, no.5.. 0. Divinyl ether, stabilized 3 UN1167 3 A7, T11, TP2 None 201 243 1L 30L E 40 Dodecyltrichlorosilane 8 UN1771 8 A7, 82, 86, N34, Tb, None 206 242 Forbidden 30L C 40 0 TP2, TP7, TP13 Dry ice, see Carbon dioxide, solid - G Dyes, liquid, corrosive, n.o.s. or Dye 8 UN2801 8 11, A6, 810, T14, TP2, None ... 201 .... 243 .... 0.5 L 2.5 L A -D intermediates, liquid, corrosive, TP27 CD no.5. II 8. 11, B2, 182, Til, TP2, 154 202 .... 242 1L 30 L A CD TP27 0 G Ill 8. 11, 183, T7, TP1, TP28 154 203 .... 241 5L 60 L A Dyes, liquid, toxic, n.o.s. or Dye 6.1 UNI602 6.1 None ... 201 .... 243 1L 30L A 0. intermediates, liquid, toxic, n.o.s.. x 6.1 162 153 202.... 243 5L 60L A 0 6.1 N Ill 1B3 153 203 .... 241 60 L 220 L A 0 C Dyes, solid, Dye 8 UN3147 1B7, corrosive, no.s. or 8. P1, T6, TP33 None ... 211 .... 242 1 kg 25kg A intermediates, solid, corrosive, 0. n.o.s.. 0 Ill C lB8, lP2, P4, T3, TP33 154 212 .... 240 15 kg 50kg A lB8, lP3, Ti, TP33 154 213 .... 240 25 kg 100 kg A G Dyes, solid, toxic, s.o.s. or Dye inter- 6.1 UN3143 Ill 6.1 A5, 187, lPl, T6, TP33 None ... 211 .... 242 5 kg 50kg A 0 mediates, solid, toxic, no.5.. CD 6.1 188, lP2, 1P4, T3, TP33 153 212 .... 242 25 kg 100 kg A 6.1 68, lP3, Ti, TP33 153 213 .... 240 100 kg 200 kg A 0 Dynamite, see Explosive, blasting, U, type A. C,, Electrolyte (acid or alkali) for bat 0 teries, see Battery fluid, acid or 8. CD 00 Battery fluid, alkali. c-ri Elevated temperature liquid, 8am- 3 UN3256 III 3 lBi, T3, TP3, TP29 None ... None 247 Forbidden Forbidden A mable, n.o.s., with flash point 0. above 37.8 C, at or above its flash 8. 3 point. Elevated temperature liquid, no.s., at 9 UN3257 Ill 9 IB1, T3, TP3, TP29 None ... None 247 Forbidden Forbidden A 85 or above 100 C and below its flash point (including molten metals, 0 molten salts, etc.). -I Elevated temperature solid, s.o.s., at 9 UN3258 Ill 9 247(h) None 247 Forbidden Forbidden A 85 or above 240 C, see (4). § 173.247(h) (4). Engines, internal combustion, flam- 9 UN3166 9 135 220 220 220 Forbidden No limit A G mable gas powered. UN3166 9 A G Engines, internal combustion, 8am- 9 135 220 220 220 No limit No limit mable liquid powered. UN3082 A Environmentally hazardous sub- 9 Ill 9 8, 146, 335, lB3, T4, 155 203 241 No limit No limit stance, liquid, s.o.s. TP1, TP29 UN3077 9 Environmentally hazardous sub- 9 Ill 8, 146, 335, 854, 188, 155 213 240 No limit No limit A stance, solid, s.o.s. lP3, N20, Ti, TP33 UN2558 Lo, Epibromohydrin 6.1 6.1, 3 Ti4, TP2, TP13 None 201 243 Forbidden Forbidden D 40 — UN2023 + Epichlorohydrin 6.1 6.1, 3 182, T7, TP2, TP13 153 202 243 5L 60 L A 40 UN2752 1,2-Epoxy-3-sthoxypropane 3 Ill 3 Bi, 183, T2, TP1 150 203 242 60 L 220 L A UN3272 Eaters, s.o.s 3 3 1B2,T7, TP1, TP8, TP28 150 202 242 5L 60 L B 0 Ill 3 81, 183, T4, TP1, TP29 150 203 242 60 L 220 L A C)m
§172101 HAzARDOUSMATERIALSTABLE—Continued LO
(6) (9) (10) Vessel Packaging Quantity limitations stowage Sym- Hazardous Hazard Identi- 0 materials descriptions class Label Special provisions ( I73.**) (see 17327 and bols and proper shipping names or fication PG Codes § Division Numbers (172.102) — — 175.75) Excep- Non- Other tions bulk Bulk Passenger Cargo air- tion aircraft/rail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (SC) (9A) (9B) (1OA) (108)
Etching acid, liquid, n.o.s., see Hydrotluoric acid, etc. Ethane 2.1 UN1035 2.1 306 304 302 Forbidden 150kg E 40 D Ethane-Propane mixture, refrigerated 2.1 NA1961 2.1 T75, TP5 None 316 314, Forbidden Forbidden 0 40 liquid. 315. 2.1 Ethane, refrigerated liquid 2.1 UN1961 T75, TP5 None None 315 Forbidden Forbidden U 40 Ethanol amine dinitrate Forbidden Ethanol and gasoline mixture or Eth 3 UN3475 II 3 144, 177, lB2, T4, TP1 150 202 242 5L 60L B anol and motor spirit mixture or Ethanol and petrol mixture, with more than 10% ethanol. Ethanol or Ethyl alcohol or Ethanol 3 UN1I7O II 3 24, 82, T4, TP1 150 202 242 5L 60L A 00 solutions or Ethyl alcohol solutions. Ill 3 24, Bi, 83, T2, TP1 150 203 242 60 L 220L A Ethanolarnine or Ethanolamine sotu 8 UN2491 Ill 8 83, T4, TP1 154 203 241 5L 60L A 52. tions. Ethe, see Diethyl ether Ethers, no.s 3 UN3271 3 182, T7, TP1, TP8, TP28 150 202 242 5L 60L B 3 Bi, 1B3,T4, TP1, TP29 150 203 242 60 L 220L A Ethyl acetate 3 UN1173 II 3 182, T4, TP1 150 202 242 5L 60L B II Ethyl acrylate, stabilized 3 UN1917 3 182, T4, TP1, TP13 150 202 242 5L 60L B 40 Ethyl alcohol, see Ethanol C, Ethyl aldehyde, see Acetaldehyde ,, Ethyl amyl ketone 3 UN2271 Ill 3 Bi, 83, T2, TP1 150 203 242 60 L 220L A N-Ethylbenzyltoluidines, solid 6.1 UN3460 Ill 6.1 1B8,1P3, Ti, TP33 153 213 240 100 kg 200kg A Ill N-Ethyl-N-benzylaniline 6.1 UN2274 6.1 183, T4, TPI 153 203 241 60 L 220L A 150 Ethyl borate 3 UN1176 II 3 182, T4, TP1 202 242 5L 60L B II 153 Ethyl bromide 6.1 UN1S9I 6.1 lB2, lP8, T7, TP2, TP13 202 243 5L 60L B 40, 85 —‘ II Ethyl bromoacetate 6.1 UN1603 II 6.1,3 182, T7, TP2 None 202 243 Forbidden Forbidden 0 40 Ethyl butyl ether 3 UN1179 3 81, 182, T4, TP1 150 202 242 5L 60L B Ethyl butyrate 3 UN118O Ill 3 81, 83, T2, TP1 150 203 242 60 L 220L A Ethyl chloride 2.1 UN1037 2.1 B77, N86, T50 None 322 314, Forbidden 150kg B 40 315. 0 Ethyl chloroacetate 6.1 UN1181 II 6.1, 3 182, T7, TP2 153 202 243 5L 60L A Ethyl chloroformate 6.1 UN1182 6.1, 3, 2. 89, 814, 832, N34, None 227 244 Forbidden Forbidden D 21,40, 8. T20. TP2, TP13, TP38, 100 TP45 Ethyl 2-chtoropropionate 3 UN2935 Ill 3 81, lB3, T2, TP1 150 203.... 242.... 60 L 220L A 0.=0U,(0)
+ Ethyl chiorothioformate 8 UN2626 8,6.1, 2, 89, B14, 832, T20, None 227 244 Forbidden Forbidden A 40 3. TP2, TP38, TP45 •0 Ethyl crotonate 3 UN1862 3 1E2,T4, TP2 150 202 242 5L 60L 8 CD Ethyl ether, see Diethyl ether
Ethyl fluoride or Refrigerant gee 2,1 UN2453 2.1 306 304 314, Forbidden 150kg 8 40 CD R161. 315. 0 Ethyl formate 3 UN119O 3 lB2, T4, TP1 150 202 242 5L 60L E Ethyl hydroperoxide Forbidden 3 Ethyl isobutyrate 3 UN2385 82, T4, TP1 150 202 242 5L 60L B Ethyl isocyanate 3 UN2481 3, 6.1 1, 89, 814, B30, T22, None 226 244 Forbidden Forbidden 0 40,52 0 + TP2, TP13, TP38, TP44 N 3 Ethyl lactate UN1192 Ill 3 lB3, 0 3 81, T2, TP1 150 203 242 60 L 220L A Ethyl mercaptan 3 UN2363 3 A6, Til, TP2, TP13 None 201 243 Forbidden 30L E 95. 1:: Ethyl methacrylate, stabilized UN2277 3 lB2, T4, TP1 150 202 242 5L 60L 8 Ethyl methyl ether 2.1 UN1039 2.1 None 201 314, Forbidden 150kg B 315. Ethyl methyl ketone or Methyl ethyl 3 UN1193 3 1B2,T4, TP1 150 202 242 5L 60L B ketone. Ethyl nitrite solutions 3 UN1194 3, 6.1 None 201 None Forbidden Forbidden E 40, 105 3 Ethyl orthoformate UN2524 Ill 3 B1, lB3, T2, TP1 150 203 242 60 L 220L A Ill Ethyl oxalate 6.1 UN2525 6.1 183, T4, TP1 153 203 241 60 L 220L A Ethyl perchlorate Forbidden C’, D Ethyl phosphonothioic dichloride, an- 6.1 NA2927 6.1,8 2, 89, B14, 832, 874, None 227 244 Forbidden Forbidden D 40 0 hydrous. T20, TP4, TP13, TP38, -a CD 00 TP45 0 Ethyl phosphonous dichloride, anhy 6.1 NA2845 6.1, 2, 89, B14, 832, 874, None ... 227 .... 244 Forbidden Forbidden 0 8 drous pyrophoric liquid. 4.2. T20, TP4, TP13, TP3S, TP45 0. D Ethyl phosphorodichloridate 6.1 NA2927 6.1,8 2, 89, B14, 832, 874, None ... 227 .... 244 Forbidden Forbidden 0 40 T20, TP4, TP13, TP38, TP45 Ethyl propionate 3 UN1195 3 182, T4, TP1 150 202 242 5L 60 L 8 Ethyl propyl ether 3 UN2615 3 182, T4, TP1 150 202 242 5L 60 L E Ethyl silicate, see Tetraethyl silicate -l B Ethylacetylene, stabilized 2.1 UN2452 2.1 N88 None 304 314 Forbidden 150 kg 40 315. D Ethylamine 2.1 UN1036 2.1 877, N87, T50 None 321 314, Forbidden 150 kg 40 315. 3, Ethylamine, aqueous solution with 3 UN2270 8 182, T7, TP1 150 202 243 1L 5L B 40, 52. not less than 50 percent but not more than 70 percent ethylamine. Ill N-Ethylaniline 6.1 UN2272 6.1 1B3,T4, TP1 153 203 241 L L Ill 60 220 A 52, 74 2-Ethylaniline 6.1 UN2273 6.1 183, T4, TP1 153 203 241 60 L 220 L A 52, 74 Ill Ethylbenzene 3 UN1175 3 1B2,T4, TP1 150 202 242 5L 60 L B UN2753 Ill N-Ethylbenzyltoluidines liquid 6.1 Ill 6.1 lB3, T7, TPI 153 203 241 60 L 220 L A 2-Ethylbutanol 3 UN2275 3 B1, 1B3,T2, TP1 150 203 242 60 L 220 L A 2-Ethylbutyl acetate 3 UN1177 3 Bi, 83, T2, TP1 150 203 242 60 L 220 L A 3 2-Ethylbutyraldehyde 3 UN1178 81,182, T4, TP1 150 202 242 5L 60 L B Ethyldichloroarsine 6.1 UN1892 6.1 2, 89, 814, B32, T20, None 227 244 Forbidden Forbidden D 40 TP2, TP13, TP38, TP45 §172.101 HAZARDOus MATERIALsTABLE—Continued cm
(8) (9) (10) Vessel Hazard Identi- Packaging Quantity limitations stowage 0 Sym- Hazardous matenals descriptions Label Special provisions 173.) (see 173.27 and bols and proper shipping names class or fication PG ( § Division Numbers Codes (172.102) — 175.75) Excep- Non- Other tions bulk Bulk Passenger Cargo air- tjon aircraWrail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (IOA) (lOB)
Ethyldichlorosilane 4.3 UN1183 4.3, 8, A2, A3,A7, N34, T14, None 201.... 244.... Forbidden 1L D 21, 28, 3. TP2, TP7, TP13 40, 49, 100 Ethylene, acetylene and propylene in 2.1 UN3138 2.1 T75, TP5 None ... 304 314, Forbidden Forbidden D 40, 57 mixture, refrigerated liquid with at 315. least 71.5 percent ethylene with not more than 22.5 percent acety lene and not more than 6 percent propylene. Ethylene chiorohydrin 6.1 UN1135 6.1,3 2, B9, B14, 632, T20, None 227 244 Forbidden Forbidden D 40 TP2, TP13, TP38, TP45 Ethylene 2.1 UN1962 2.1 306 304 302 Forbidden 150kg E 40 00 Ethylene diamine diperchlorate Forbidden Ethylene dibromide 6.1 UN1605 6.1 2, B9, B14, 832, B77, None 227 244 Forbidden Forbidden D 40 T20, TP2, TP13, TP38, TP45 Ethylene dibromide and methyl bro mide liquid mistures, see Methyl bromide and ethylene dibromide, liquid mistures. Ethylene dichioride 3 UN1184 II 3, 6.1 182, N36, T7, TP1 150 202 243 1L 60L B 40 II Ethylene glycol diethyl C-) ether 3 UN1153 3 162, T4, TP1 150 202 242 5L 60L A -n Ill 3 BI, 83, T2, TP1 150 203 242 60 L 220L A Ethylene glycol dinitrate Forbidden Ill 3 C.) Ethylene glycol monoethyl ether 3 UN1171 Ill 81, 1B3,T2, TP1 150 3 203 242 60 L 220L A 3 150 Ethylene glycol monoethyl ether ace UN1172 B1, 1B3,T2, TP1 203 242 60 L 220L A tate. 3 3 150 Ethylene glycol monornethyl ether UN1188 Ill 3 B1, 183, T2, TP1 203 242 60 L 220L A 3 150 Ethylene glycol monomethyl ether UN1189 Ill Bi, 63, T2, TP1 203 242 60 L 220L A acetate. Ethylene oxide and carbon dioxide 2.3 UN3300 2.3, 4 None 304 314, Forbidden Forbidden D 40 mixture with more than 87 percent 2.1. 315, 0 ethylene oxide. m Ethylene oxide and carbon dioxide 2.1 UN1O4I 2.1 T50 306 304 314, Forbidden 25kg B 40 0 mixtures with more than 9 percent 315. but not more than 87 percent 0 ethylene oxide. Ethylene oxide and carbon dioxide 2.2 UN1952 2.2 306 304 314. 75 kg 150 kg A mixtures with not more than 9 per 315. cent ethylene oxide, m Ethylene oxide and 22 UN3297 2.2 T50 306 304 314, 75 kg 150 kg A m chiorotetrafluoroethane mixture 315. with not mom than 8.8 percent ethylene oxide. D Ethylene oxide and dichlorodiftuoro 2.2 UN3070 2.2 T50 306 304 314, 75 kg 150 kg A 0. methane mixture, with not more 315. than 12.5 percent ethylene oxide. 0I Ethylene oxide and 2.2 UN3298 2.2 TSQ 306 304 314, 75 kg 150 kg A N penlafluoroethane mixture with not 315. 0 more than 7.9 percent ethylene 0. 0 oxide. C Ethylene oxide and propylene oxide 3 UN2983 3, 6.1 5, All, N4, N34, T14, None 201 243 Forbidden 30 L 40 mixtures, with not more than 30 TP2, TP7, TP13 percent ethylene oxide. 0 Ethylene oxide and tetrafluoroethane 2.2 UN3299 2.2 T50 306 304 314, 75 kg 150 kg A mixture with not more than 5.6 per 315. CD cent ethylene oxide. 0 Ethylene oxide or Ethylene oxide 2.3 UN1040 2.3, 4, A59, T50, TP2O None 323 323 Forbidden Forbidden 0 40 with nitrogen up to a total pressure 2.1. LI, of IMPa (10 bar) at 50 degrees C. 0 Ethylene, refrigerated liquid (cryo 2.1 2.1 T75, TPS 316 318, Forbidden UN1038 None Forbidden 0 40 CD 00 genic liquid). 319. Ethylenediarnine 8 UN1604 8, 3 lB2, T7, TP2 154 202 243 1L 30 L A 40, 52. Ethyleneimine, stabilized 6.1 UN1185 6.1, 3 1, 59, 814, 830, B77, None 226 244 Forbidden Forbidden D 40 N25, N32, T22, TP2, TP13, TP38, TP44 3 Ethylhexaldehyde, see Oclyl aldehydes etc. 2-Ethyihexyl chloroformate 6.1 UN2748 6.1,8 lB2, T7, TP2, TPI3 153 202 243 1L 30 L A 12, 13, 21,25, 0 40, 100 2-Ethylhexylamine 3 UN2276 Ill 3. 8 Bi, lB3, T4, TP1 150 203 242 5L 60 L A 40 Ethylphenyldichlorosilane 8 UN2435 8 A7, 62, N34, Tb, TP2, None 206 242 Forbidden 30 L C TP7, TP13 1-Ethylpiperidine 3 UN2386 3, 8 lB2. T7, TP1 150 202 243 1L 5L B 52. N-Ethyltoluidines 6.1 UN2754 6.1 162, T7, TP2 153 202 243 5L 60 L A Ethyltrichlorosilane 3 UN1196 3. 8 A7, N34, Tb, TP2, TP7, None 206 243 1L 5L B 40 TPI3 Etiologic agent, see Infectious sub stances, etc. Explosive articles, see Articles, es
plosive , no.s. etc. CU, Explosive, blasting, type A liD UNOO81 1.10 None 62 None Forbidden Forbidden 10 19E, — 21E Explosive, blasting, type B 1.10 UN0082 II 1.10 None ... 62 None Forbidden Forbidden 10 19E Explosive, blasting, type B or Agent 1.50 UN0331 II 1.50 .. 105,106 None ... 62 None Forbidden Forbidden 10 19E blasting, Type B. 0 f1
C-) () p. (0)
0 ‘Ii 0. 0
40 40
53,
40,
19E 198 103 226
Oer (106)
13,
52,
85,
(10)
Vessel
stowage
Lt (1OA)
10 10 10 10 —
B B A A A A A A A B A A 8 A A A
L L L L L L
kg kg kg kg kg kg kg kg kg
air-
60 60 60 30
only
220 50 220 50
and
100 100 100 100 100 100 100 150kg
(9B)
Forbidden Forbidden Forbidden Forbidden
craft
Cargo
limitations
(9)
L L
175.75) kg kg kg kg kg kg kg kg kg
§173.27 5L 5L IL 5L
60 60
15 15 25 25 25 25 25 25 25
(9A)
Quantity
(see
Forbidden Forbidden Forbidden Forbidden
Forbidden
aircraft/rail
nger
315.
Bulk (8C)
None None None None
—.—————-j 242 242 242 240 241 242 242 240 242 240 240 242 240 242 241 314,
(8)
bulk
(86)
Non-
i73.)
62 62 62 62 202 203 202 203 212 213 213 212 212 203 212 213 212 202 213 304
)
Packaging
(8A)
lions
Excep-
None None 150 None None 150 150 150 154 153 154 151 153 152 154 151 153 154 None
306 -
Ti, 123 106 lP7
lP4,
lP4, TP8 TP1 TP8 TPI TP1
N87
TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP27
P3,
T2, T2,
T4, 1P3,
TABLE—Continued 105,
lP2, 188,
Ti, T3, T3, T3, T3, Ti, T3, TPI, TP1,
TP2,
83,
1B3, 188, 183,
86, 168,
provisions
P7. lB8,
T4, T4,
(7)
lP3, 1P4, 1P4, lP4, 1P4,
172.102)
Til,
81, 81,
(
B15, 182, A29, lB2, A19,
A19,
1P2, lP2, 1B8, lP2, lP2, A19,
lB2,
Special
Al,
Al,
Al,
59,
149, 149,
MATERIALS 188, 1B8, lB8, 188,
83,
(6)
6.1.
Label
Codes
liD 1.5D 1.10 1.10
3 3 3 3 5.1 8 8 6.1 6.1 4.1 8 8 6.1 4.3, 4.2 2.2
II II II It II It II II II II II
Ill Ill Ill Ill Ill Ill Ill
HAzARDOUS
(5)
PG
169
(4)
172.101
Identi-
fication
Numbers UN0241 UN0083 UN0332 UN0084 UNI UN1773 UN1197 UN1606 UN2582 UN1466 UN1607 UN1323 UN1408 UN1608 NA1759 NA1760 UN2793 UN1043 §
3 3 8 8
8 8
or
6.1 5.1 6.1 4.1 6.1
4.3 4.2 2.2
liD 1.50 1.10 1.10
(3)
Hazard
Division
class
Forbidden
oil
with
Sub-
more
metal
Agent
Explo-
Ferrous
cuttings
or
or
etc.
173.54
Explosive
silicon.
see
E
see
names
or
E C
etc. solution
vegetable
descriptions
metal
Ferrous
n.o.s.
axe
6. See
percent
type
or
self-heating.
type typeD type
gels,
liquid
or liquid
percent
to
(2)
solid solution 30
E.
shipping
borings
type
E.
fabrics,
90
anhydrous solution
Ferrous
materials
or sluny,
water
animal
with
substances,
liable
blasting, explosive,
type Type
blasting, or blasting, blasting, forbidden.
than
ammoniating proper
metal aromatic, flavoring,
shavings
chloride, chloride, arsenate
blasting, with
Fibers ammon/a.
form chloride, arsenate chloride, nitrate arserrite
less
and
a
Hazardous blasting, blasting, stances,
see sive, but
metal in turnings free
Explosive, Explosive, Explosive, Explosive, Explosives, Explosive, Explosive Explosives, Extracts, Ferric Extracts, Fabric Ferric Ferric Ferric Ferrocerium Ferric Ferrosilicon Ferrous Ferrous Ferrous Ferrous
Fertilizer
0 0
(1)
bols
Sym-
CD Al Fibers, animal or Fibers, vegetable 4.2 UN1372 III 4.2 151 213.... 240 Forbidden Forbidden A -v w burnt, wet or damp. -o 1W Fibers, vegetable, dry 4.1 UN3360 Ill 4.1 137 151 213 240 No Limit No Limit A (D AW Fibers or Fabrics, animal or vege 4.2 UN1373 Ill 4.2 137, 88, P3, Ti, TP33 None 213 241 Forbidden Forbidden A table or Synthetic, n.o.s, with ani CD mal or vegetable oil. 0 Fibers or Fabrics impregnated with 4.1 UN1353 Ill 4.1 Al, lB8, lP3 None . 213 .... 240 25 kg 100kg D weakly nitrated nitrocellulose, 0. n.o.s.. = Films, nitrocellulose base, from which 0 gelatins has been removed; film N scrap, see Celluloid scrap. 0 Films, nitrocellulose base, gelatine 4.1 UN1324 III 4.1 None ... 183 .... None 25 kg 100kg D 28 0. coated (except scrap). 0 Fire estinguinher charges, corrosive 8 UN1774 II 8 N41 154 202 .... None 1L 30L A Cl, liquid. Fire extinguisher charges, expelling, explosive, see Cartridges, power 0 device. CD Fire estinguishers containing com 2.2 UN1044 2.2 18, 110 309 309 None 75 kg 150kg A 0 pressed or liquefied gas. Firelighters, solid with flammable Ill liq 4.1 UN2623 4.1 Al, A19 None 213 None 25 kg 100kg A 52 Cd., uid. 0 Fireworks l.1G UN0333 1.1G.. 108 62 None None Forbidden Forbidden 07 CD Fireworks 1.2G UN0334 1.2G.. 108 None 62 None Forbidden Forbidden 07 Fireworks 1.3G UN0335 1.3G.. 108 None 62 None Forbidden Forbidden 07 Fireworks 1.4G UN0336 1.4G.. 108 None 62 None Forbidden 75kg 06 > Fireworks 1.4S UN0337 1.4S 108 None 62 None 25 kg 100 kg 05 0. First aid kits 9 UN3316 9 15 161 161 None 10 kg 10kg A 3 W Fish meal, stabilized or Fish scrap, 9 UN2216 Ill None 155, 1B8, P3, Ti, TP33 155 218 218 No limit No limit B 88, stabilized. 122, 128 Fish meal, unstablized or Fish scrap, 4.2 UN1374 4.2 155, Al. Al9, 1B8, P2, None .1212 241 15 kg 50kg B 18, 128 0 unstabilized. 1P4, T3, TP33 - Flammable compressed gas, see Compressed or Liquefied gas, flammable, etc. Flammable compressed gas (small receptacles not fitted with a disper sion device, not refillable), see Re ceptacles, etc. Flammable gas in lighters, see Light ers or lighter refills, cigarettes, con taining flammable gas. G Flammable liquid, tosic, corrosive, 3 UN3286 3,6.1, T14, TP2, TP13, TP27 None 201 243 Forbidden 2.5L B 21, 40, cm n.o.s.. 8. 100 3,6.1, 1B2,Til, TP2, TP13, 150 202 243 1L 5L B 21, 40, 8. TP27 100 G Flammable liquids, corrosive, n.o.s. 3 UN2924 3, 8 T14, TP2 None 201 243 0.5 L 2.5L F 40 C 3, 8 1B2,Tii, TP2, TP27 150 202 243 1L 5L B 40 §172.101 HAzARDous MATERIALSTASLE—Continued .1 (8) 9) (10) Vessel Hazard Identi- 1 Packaging anklyIimiIalions stowage 0 Sym- Hazardous materials descriptions Label Special provisions l73.) (see 173.27 and bole and proper shipping names class or fication PG ( § Division Numbers Codes ( 172.102) 175.75) Excep- Non- Passenger Cargo air- 01L Other tions bulk c aircraftirail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (bA) (lOB)
Ill 3, 8 B1, 1B3, T7, TP1, TP28 150 203 242 5L 60 L A 40 G Flammable liquids, n.o.s 3 UN1993 3 Til, TP1, TP27 150 201 243 1L 30 L E II 3 182, T7, TP1, TP8, TP28 150 202 242 5L 60 L B Ill 3 81, B52, 1B3,T4, TP1, 150 203 242 60 L 220 L A TP29 G Flammable liquids, toxic, no.5 3 UN1992 3, 6.i T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L E 40 3, 6.i 182, T7, TP2, TPI3 150 202 243 1L 60 L B 40 Ill 3, 6.1 Bi, 183, T7, TPI, TP28 ISO 203 242 60 L 220 L A G Flammable solid, corrosive, inor 4.1 UN3180 4.1,8 Al, lB6, 1P2, T3, TP33 151 212 242 15 kg 50 kg D 40 ganic, no.s.. Ill 4.1,8 Al, 1B6,Ti. TP33 151 213 242 25 kg 100 kg D 40 G Flammable solid, inorganic, n.o.s 4.1 UN3178 II 4.1 Al, 88, lP2, 1P4, T3, 151 212 240 i5 kg 50 kg B cc’ TP33 Ill 4.1 Al, 188, 1P3, Ti, TP33 151 213 240 25 kg 100 kg B G Flammable solid, organic, molten, 4.1 UN3176 4.1 181, T3, TP3, TP26 151 212 240 Forbidden Forbidden C 5.0.5.. Ill 4.1 181, Ti, TP3, TP26 151 213 240 Forbidden Forbidden C G Flammable solid, oxidizing, s.o.s 4.1 UN3097 II 4.1, 131 None 214 214 Forbidden Forbidden E 40 5.1. Ill 4.1, 131, Ti, TP33 None 214 214 Forbidden Forbidden D 40 5.1. G Flammable solid, toxic, inorganic, 4.1 UN3179 4.1, Al, 186, 1P2, T3, TP33 151 242 15 kg 212 50 kg B 40 C-) no.5.. 6.1. -I, Ill 4.1, Al, 186, Tb, TP33 151 213 242 25 kg 100 kg B 40 6.1. C) D G Flammable solids, corrosive, organic, 4.1 UN2925 4.1,8 Al, 186, lP2, T3, TP33 None 212 242 15 kg 50 kg 40 no.5.. D Ill Al, 1B6, Ti, TP33 151 213 242 25 kg 100 kg G 4.1,8 40 Flammable solids, organic, n.o.s 4.1 UN1325 4.1 Al, 188, 1P2, lP4, T3, 151 212 240 15kg 50 kg B TP33 Ill 4.1 Al, 188, 1P3, Ti, TP33 151 213 240 25 kg 100 kg B G Flammable solids, toxic, organic, 4.1 UN2926 4.1, Al, 186, 1P2, T3, TP33 151 212 242 15 kg 50 kg B 40 s.o.s. - 6.1. 0 Ill 4.1, Al. 186, Tl, TP33 151 213 242 25 kg 100 kg B 40 m 6.1. 0. Flares, aerial 1.3G UN0093 II 1.3G.. None 62 None Forbidden 75 kg 07 Flares, aerial 1.4G UN0403 II 1.4G.. None 62 None Forbidden 75 kg 06 0 Flares, aerial 1.4S UN0404 l.4S None 62 None 25 kg 100 kg 05 GO)
Flares, aerial 1.1G UN0420 1.1G.. None 62 None Forbidden Forbidden 07 -U Flares, aerial 1.2G UN0421 1.2G None 62 None Forbidden Forbidden 07 Flares, airplane, see Flares, aerial (D Flares, signal, see Cartridges, signal (D Flares, surface 1.3G UN0092 1.3G None 62 None Forbidden 75 kg 07 Flares, surface 1.1G UN0418 1.1G.. None 62 None Forbidden Forbidden 07 a Flares, surface I.2G UN0419 1.2G.. None 62 None Forbidden Forbidden 07 Flares, wafer-activated, see Contri a vances, water-activated, etc. x Flash powder 1.1G UN0094 1.1G.. None 62 None Forbidden Forbidden 15 a Flash powder 1.3G UN0305 1.3G.. None 62 None Forbidden Forbidden 15 N Flue dusts, poisonous, see Arsenical a dust. a Fluoric acid, see Hydrofluoric acid, 0 etc. C Fluorine, compressed 2.3 UN1045 2.3, 1, N86 None ... 302 .... None Forbidden Forbidden C 40, 89, 5.1, 90 8. a (D Fluoroacetic acid 6.1 UN2642 6.1 lB7, P1, T6, TP33 None 211 242 1 kg 15 kg E 6.1 Fluoroanilines 6.1 UN2941 Ill 183, T4, TP1 153 203 241 60 L 220 L A a Fluorobenzene 3 UN2387 3 182, T4, TP1 150 202 242 5L 60 L B Fluoroboric acid 8 UN1775 II 8 AS, A7, B2, 615, 1B2, 154 202 242 IL 30 L A U, N3, N34, T7, TP2 a 8 A Fluorophosphoric acid anhydrous UN1776 8 A6, A7,B2, lB2, N3, None 202 242 1L 30 L (I, N34, T8, TP2 A Fluorosilicates, no.5 6.1 UN2856 Ill 6.1 188, 1P3, Ti, TP33 153 213 240 100 kg 200 kg 52 Fluorosilicic acid 8 UN1778 II 8 A6, A7, 82, 815, 162, None 202 242 1L 30 L A N3, N34, T8, TP2 a. 8 Fluorosulfonic acid UN1777 II 8 A3, A6, A7, AlO, B6, None 201 243 0.5 L 2.5 L D 40 3 810, N3, N36, Tb, TP2 3 3 Fluorotoluenes UN2388 182, T4, TP1 150 202 242 5L 60 L B 40 Forbidden materials. See 173.21 Forbidden Formaldehyde, solutions, flammable 3 UN1198 Ill 3, 8 81, 183, T4, TP1 150 203 242 5L 60 L A 40 0 8 UN2209 Ill 154 A -I Formaldehyde, solutions, with not 8 1B3,T4, TP1 203 241 5L 60 L less than 25 percent formaldehyde. Formalin, see Formaldehyde, solu tions. 8 A Formic acid with not less than 10% 8 UN3412 II 1B2,T7, TP2 154 202 .... 242 .... IL 30 L 40. buf not more than 85% acid by A mass. 8 8 Formic acid with not less than 5% UN3412 Ill lB3, T4, TPI 154 203 241 5L 60 L A 40 but less than 10% acid by mass. 8 Formic acid with more than 85% acid UN1779 II 8, 3 82, 828, 1B2,T7, TP2 154 202 242 1L 30 L 40. by mass. II Fracturing devices, explosive, without liD UN0099 lID None 62 62 Forbidden Forbidden 07 detonators for oil wells. Fuel, aviation, turbine engine 3 UN1863 3 144, Til, TPI, TP8, 150 201 243 1L 30 L B II TP28 3 B 144, lB2, T4, TP1, TP8 150 202 242 5L 60 L C Ill 3 144, Bi, 1B3,T2, TP1 150 203 242 60 L 220 L A § 172101 HAzARDOUS MATERIALS TABLE—Continued (0)
(8) (9) (10) Vessel Hazard Identi- Packaging Quantity limitations stowage 0 Sym- Hazardous materials descriptions Label Special provisions 173.) (see 173.27 and bols and proper shipping names class or fication PG ( § Division Numbers Codes ( 172.102) 175.75) Excep- Non- Other tions bulk Bulk Passenger Cargo air- tion aircraWrail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) )1OA) (lOB)
Fuel cell cartridges or Fuel cell car 8 UN3477 8 230 230 230 5 kg 50 kg A tridges contained in equipment or Fuel call cartridges packed with equipment, containing corrosive substances. Fuel cell cartridges or Fuel cell car 3 UN3473 3 230 230 230 5 kg 50 kg A tridges contained in equipment or Fuel cell cartridges packed with equipment, containing flammable liquids.
Fuel cell cartridges or Fuel cell car 2.1 UN3479 2.1 230 230 230 1 kg 15 kg B tridges contained in equipment or Fuel cell cartridges packed with equipment, conta Thinghydrogen in metal hydride.
Fuel cell cartridges or Fuel cell car 2.1 UN3478 2.1 230 230 230 1 kg 15 kg B tridges contained in equipment or Fuel cell cartridges packed with equipment, containing liquefied flammable gas. ‘0 Fuel cell cartridges or Fuel cell car 4.3 UN3476 4.3 230 230 230 5 kg 50 kg A tridges contained in equipment or C) Fuel cell cartridges packed with equipment, containing water-reac C) tive substances. A D Fuel oil (NO. 1, 2, 4, 5, or 6) 3 NA1993 Ill 3 144, B1, 1B3,T4, TP1, 150 203 242 60 L 220 L TP29 Fuel system components (including fuel control units (FCU), carbu cp retors, fuel lines, fuel pumps) see Dangerous Goods in Apparatus or Dangerous Goods in Machinery. C Fulminate of mercury (dry) Forbidden m Fulminate of mercury, wet, see Mer 0. cury fulminate, etc. Fulminating gold Forbidden 0 Fulminating mercury Forbidden Fulminating platinum Forbidden Fulminating silver Forbidden 13 Fulminic acid Forbidden CD Fumaryl chloride 8 UN1780 8 B2, 1B2,T7, TP2 154 202 242 1L 30 L C 8,40 Fumigated lading, see . § 172.302(g), CD 173.9 and 176.76(h). 0 Fumigated transport vehicle or freight container see § 173.9. 0. 153 Furaldehydes 6.1 UN1199 6.1,3 lB2, T7, TP2 202 243 5L 60 L A = Furan 3 UN2389 3 T12, TP2, TPI3 None 201 243 1L 30 L 0 40 N Furfuryl alcohol 6.1 UN2874 Ill 6,1 1B3,T4, TP1 153 203 241 60 L 220 L A 52, 74 0 Furfurylamine 3 UN2526 Ill 3, 8 Bi, 183, T4, TP1 150 203 242 5L 60 L A 40 0. Fuse, detonating, metal clad, see 0 Cord, detonating, metal clad. C Fuse, detonating, mild effect, metal clad, see Cord, detonating, mild ef fect, metal clad. 0 Fuse, igniter tubular metal clad i.4G UNO1O3 1,4G None 62 None Forbidden 75 kg 06 CD Fuse, non-detonating instantaneous 1.3G UNO1O1 i.3G None 62 None Forbidden Forbidden 07 or quickmatch, 0 to Fuse, safety 1.4S UNO1O5 1.4S None 62 None 25 kg 100 kg 05 U) Fuses (railway or highway) 4.1 NA1325 4.1 None 184 None 15 kg 50 kg B 0 Fusel oil 3 UN12OI 3 1B2,T4, TP1 150 202 242 5L 60 L B CD Ill 3 61, 1B3,T2, TP1 150 203 242 60 L 220 L A Fuses, tracer, see Tracers for ammu cJ1 nition. Fuzes, combination, percussion and 0. time, see Fuzes, detonating (UN0257, UN0367); Fuzes, igniting (UN0317, UN0368). Fuzes, detonating 1.1B UNO1O6 i.1B None 62 None Forbidden Forbidden ii Fuzes, detonating 1.2B UNO1O7 1.28 None 62 None Forbidden Forbidden II 0 Fuzes, detonating l.4B UN0257 1.4B 116 None 62 None Forbidden 75 kg 06 -I Fuzes, detonating 1.4S UN0367 1.4S 116 None 62 None 25 kg 100 kg 05 Fuzes, detonating, with protective liD UN0408 liD None 62 None Forbidden Forbidden 07 features. 62 Fuzes, detonating, with protective 1.2D UN0409 1.2D None None Forbidden Forbidden 07 features. Ill 62 Fuzes, detonating, with protective 1.4D UNO41O l.4D 116 None None Forbidden 75 kg 06 features. 62 Fuzes, igniting 1,3G UN0316 Ill 1.3G.. None 62 None Forbidden Forbidden 07 Fuzes, igniting 1.4G UN0317 1.4G.. None 62 None Forbidden 75 kg 06 Fuzes, igniting 1.4S UN0368 1.4S None None 25 kg 100 kg 05 Galactsan trinitrafe Forbidden to, Gallium 8 UN2803 8 Ti, TP33 None 162 240 20 kg 20 kg B 48 B Gas cartridges, (flammable) without a 2.1 UN2037 2.1 306 304 None 1 kg 15 kg 40 ‘.3 release device, non-refillable. Gas identif cation set 2.3 NA9035 2.3 6 None 194 None Forbidden Forbidden D C Gas oil 3 UN1202 3 144, 81, 1B3,T2, TP1 150 203 242 60 L 220 L A § 172.101 HAzARDOus MATERIALSTABLE—Continued C0)
(8) (9) (10) Vessel Hazard Identi- Packaging Quantity limitations stowage C Sym- Hazardous materials descriptions Label Special provisions 173.) (see 17327 and bols and proper shipping names class or fication PG ( § Division Numbers Codes (172 102) 175 75) Escep- Non- Bulk Other lions bulk Passenger Cargo air- tjofl aircraft/rail craft only
(I) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C( (9A) (9B) (bA) (lOB)
G Gas, refrigerated liquid, flammable, 2.1 UN33l2 2.1 T75, TP5 None 316 318 Forbidden Forbidden D 40 no.5. (cryogenic liquid). G Gas, refrigerated liquid, n.o.s. (cryo 2.2 UN3158 2.2 T75, TP5 320 316 318 50 kg 500kg D genic liquid). G Gas, refrigerated liquid, osidizing, 2.2 UN3311 2.2, T75, TP5, TP22 320 316 318 Forbidden Forbidden D no.s. (cryogenic liquid). 5,1. Gas sample, non-pressurized, flam 2.1 UN3167 2.1 306 302, None 1L 5L D mable, no.s., not refrigerated liq 304. uid. Gas sample, non-pressurized, toxic, 2.3 UN3168 2.3, 6 306 302 None Forbidden 1L D flammable, n.o.s., not refrigerated 2.1. liquid. cc Gas sample, non-pressurized, toxic, 2.3 UN3l69 2.3 6 306 302, None Forbidden IL D D n.o.s., not refrigerated liquid. 304. Gasohol gasoline mixed with ethyl al 3 NA1203 3 144, 177 150 202 .... 242 5L 60L E cohol, with not more than 10% al cohol. Gasoline includes gasoline mixed 3 UN1203 3 144, 177, 81, B33, 182, 150 202.... 242.... 5L 60L E with ethyl alcohol, with not more T4, TP1 than 10% alcohol. Gasoline, casinghead, see Gasoline Gelatine, blasting, see Explosive, C) blasting, type A. -n Gelafine dynamites, see Explosive, blasting, type A. 0 Germane 2.3 UN2192 2.3, 2 None 302 245 Forbidden Forbidden 0 40 p. 2.1. Glycerol-1,3-dinitrate Forbidden Glycerol gluconate trinitrate Forbidden Glycerol lactate frinitrate Forbidden Glycerol alpha-monochlorohydrin 6.1 UN2689 Ill 6.1 1B3,T4, TPI 153 203 241 60 L 220L A Glyceryl trinitrate, see Nitroglycerin, etc. C Glycidaldehyde 3 UN2622 II 3, 6.1 1B2, 1P8, T7, TP1 150 202 243 1L 60L A 40 II m Grenades, hand or rifle, with bursting liD UN0284 1.10 62 None Forbidden Forbidden 07 0 charge. II Grenades, hand or rifle, with bursting l.2D UN0285 1.2D 62 None Forbidden Forbidden 07 0 charge. z Grenades, hand or rifle, with bursting 1.1F UN0292 1.1F 62 None Forbidden Forbidden 08 -o charge. Grenades, hand or rifle, with bursting l.2F UN0293 1.2F 62 None Forbidden Forbidden 08 (D charge.
Grenades, illuminating, see Ammuni CD tion, illuminating. etc. 0 Grenades, practice, hand or rifle 1.4S UNO11O 1.4S 62 None 25 kg 100 kg 05 Grenades, practice, hand or rifle 1.3G UN0318 1.3G.. 62 None Forbidden Forbidden 07 0. Grenades, practice, hand or rifle i.2G UN0372 1.2G.. 62 None Forbidden Forbidden 07 = Grenades practice Hand or rifle i.4G UN0452 1.4G.. 62 None Forbidden 75kg 06 0 Grenades, smoke, see Ammunition, 0N smoke, etc. 0. Guanidine nitrate 5.1 UN1467 Ill 5.1 Al. 1B8, 1P3. Ti, TP33 152 213 240 25 kg 100kg A 0 Guanyl nitrosaminoguanylidene hy Forbidden C drazine (dry). U, Guanyl nitrosaminoguanylidene fly 1.1A UNO113 1.1A iii, 117 None 62 None Forbidden Forbidden 12 drazine, wetted with not less than 0 water; 30 percent by mass. CD Guanyl nitrosaminoguanylt etrazene Forbidden (dry). 0 U) Guanyl nitrosaminoguanylletrazene, 1.1A UNO114 1.1A 111, 117 None ... 62 None Forbidden Forbidden 12 wetted or Tetrazene, wetted with CO not less than 30 percent water or 0 mixture of alcohol and water, by CD mass. Gunpowder, compressed or Gun > powder in pellets, see Black pow 0. der (UN 0028). 3 Gunpowder, granular or as a meal, see Black powder (UN 0027). Hafnium powder, dry 4.2 UN2545 4.2 None 211 242 Forbidden Forbidden 0 4.2 A19, A20, 166. lP2. N34. None 212 241 15 kg 50kg D 0 T3, TP33 Ill 4.2 1B8, 1P3, Ti, TP33 None 213 241 25 kg 100kg D Hafnium powder, wetted with not less 4.1 UN1326 4.1 A6, A19, A20, lBS. P2, None 212 241 15 kg 50kg E ¼ than 25 percent water (a visible N34, T3, TP33 excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns. Hand signal device, see Signal de vices, hand. Hazardous substances, liquid or sotid no.5., see Environmentally hazardous substances, etc. DG Hazardous waste, liquid, no.s 9 NA3082 Ill 9 63, T2, TP1 1S5 203 .... 241 No limit No limit A DG Hazardous waste, solid, no.s 9 NA3077 Ill 9 B54, 68, P2, Ti, TP33 155 213 .... 240 No limit No limit A Ill 0 Heating oil, light 3 UN1202 3 61, 163, T2, TP1 150 203 .... 242 60 L 220L A C -n 0 C) C m 0 0. 85 12 40 40 40 40 40 40 40 40 12,40 (106) 13,40 Other (10) Vessel stowage tion )IOA) 8 B B 0 A B A D D E A A C E A B B B A A A C A A A L L L L L L L L L L L L L kg kg kg kg kg kg kg kg kg air- 60 60 30 60 60 60 30 60 only 220 220 220 220 220 and 150 150 500 100 150 100 150 100 200 (9B) Forbidden Forbidden craft Forbidden Cargo limitations (9) L L L L L kg kg 175.75) kg kg kg kg kg kg kg 5L 5L §173.27 iL 5L 5L 5L 5L 60 60 60 60 60 50 75 75 25 75 25 75 25 100 (9A) Quantity (see Forbidden Forbidden Forbidden Forbidden Passenger aircrsWrail 314. 315. 315. 315. 315. Bulk (8C) 318 314, 302, 242 242 242 241 241 241 244 None 242 242 314, 242 243 314, 240 243 240 242 314, 242 242 243 — (8) bulk (88) Non- 302 316 304 203 202 202 203 203 206 203 227 334 213 304 212 304 202 212 202 202 304 202 213 203 202 (j73,***) Packaging (8A) lions Excep- 150 150 150 153 153 153 153 — 306 153 None None 320 306 153 153 None 153 154 None None 150 153 306 None 306 N3, T50 TP5 B14 T50 TPI N76 TP1 TP1 TP1 TP2 TP2 TP2 TP1 TiO, 877, TP33 TP33 TP13 TP45 TP33 TP33 TP13 TP38, T4, T2, T4, T4, TP1 T4, TP1 T4, 89, T7, T7, T2, 182, T8, TABLE—Continued 1P4, T75, Ti, Ti, T3, Ti, N34, 832, 2, TP7, TP2, 82, 183, 162, 182, 183, 163, TPI3, 1B2, 182, 183, P3, provisions P3, 1P2, N76, N34, (7) 86, 1P4, 1P3, T7, 814, TP2, A7, 61, 81, (172.i02) B2, 1B8, TP2, 182, 168, 188, lBS. 89, 182, A6, Special 2, A7, B3, MATERIALS T20, 188, 1P2, 8 (6) Label Codes 2.2 3 2.2 3 3 8 2.2 6.1 6.1 6.1 2.3 3 6.1 6.1 6.1 6.1 2.3, 6.1 2.2 6.1 2.2 3 6.1 8 8 II II Ill Ill Ill Ill Ill Ill HAzARDoUS (5) PG 1 206 (4) 1858 1207 172.101 Identi- tication Numbers UN1963 UN1046 UN2278 UN2661 UN2729 UN2279 UN2646 UN3296 UN3056 UN2875 UNI UN1781 UN161 UN2420 UN2552 UN3436 UN2458 UN1612 UN1611 UN2280 UN UN2193 UN UN2281
§ UN1782 3 3 3 8 3 3 8 8 or 2.2 2.2 2.2 6.1 6,1 6.1 6.1 2.3 6.1 6.1 2.3 6.1 6.1 6.1 2.2 2,2 6.1 (3) Hazard class Division Forbidden or gas com diamine liquid solid (cryogenic and solid liquid Refrigerant names solid descriptions acid or Refrigerant compressed liquid 1216. hydrate, hydrate, or R (2) triperoxide shipping disocyanate mixtures. materials gas tetraphosphale gas tetraphosphate, tetraphosphate, proper 227. refrigerated compressed R and 116. Hazardous liquid). gas (dry). Refrigerant pressed R Helium, n-Heplene Hexachloroacetone Hesachlorobenzene Heplattuoropropane Helium, n-Heptaldehyde Heptanes Hexadecytlrichlorosilane Hesachtorobutadiene Hexadienes Hesaethyl Hesachtorocyclopentadiene Hexaethyl Hesaethyl Hesachloropherie Hexafluoroacetone Hesafluoroacetone Hesafluoropropylene Hexsfluoroacetone Hesafluoroethane, Hexaldehyde Hexamethylene Hesafluorophosphoric Hexamethylenediamine, Hexamefhylene (1) bols Sym- Hexamethylenediamine solution 8 UN1783 II 8 1B2,T7,TP2I None ... 1202 .... 1242 1L 30 L A -U III 8 183, T4, TP1 154 203 241 5L 60 L A 3 Hexamethyleneimine UN2493 II 3,8.... 82, T7, TP1 150 202 243 1L 5L B 40 CD Hexarnethylenetetramine 4.1 UN1328 III 4.1 Al, 1B8, 1P3, Tl, TP33 151 213 240 25 kg 100 kg A CD Hexamethylol benzene hexanitrate Forbidden UN1208 Hexanes 3 II 3 82, T4, TP1 150 202 242 5L 60 L E 0 2,2,4,4’, 6,6’- Hexanitro-3,3’- Forbidden dihydroxyazobenzene (thy). a. Hexanitroazoxy benzene Forbidden x N,N’-(hexanitrodiphenyl) ethylene Forbidden Na dinitramine (dry). a Hexanitrodiphenyl urea Forbidden 2,2’,3’,4,4’,6-Hexanitrodiphenylamine Forbidden a. UN0079 0 Hexanitrodiphenylamine or lID II liD None ... 62 None Forbidden Forbidden 10 C Dipicrylamine or Hexyl. 2,3’,4,4’,6,6’-Hexanitrodiphenylether Forbidden Hexanitroethane Forbidden a Hexanitrooxanilide Forbidden UN0392 10 CD Hexanitrostilbene lID II liD None 62 None Forbidden Forbidden Hexanoic acid, see Corrosive liquids, a (I, n.o.s.. UN2282 74 U, Hexanols 3 III 3 81,183, T2, TPI 150 203 242 60 L 220 L A UN2370 a 1-Hexene 3 II 3 182, T4, TPI 150 202 242 5L 60 L E Hexogen and CT, cc cc cyclotetramethylenetetranitramine mixtures, wetted or desensitized > see RDX and HMX mixtures, a. wetted or desensitized etc. 3 Hexogen and HMX mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc. 0 Hexogen and octogen mixtures, -I wetted or desensitized see RDX and HMX mixtures, wetted or de sensitized etc. Hesogen, see Cyclotrimethylenetrinitramine, etc. Hesolite, or Hexotol dry or wetted liD UNO1I8 II lID None ... 62 None Forbidden Forbidden 10 with less than 15 percent water, by mass. Hexotonal UN0393 II liD None ... 62 None Forbidden Forbidden 10 Hexyl, see Hexanitrodiphenylamine liD Hexyltrichiorosilane 8 UN1784 II 8 A7, B2, B6, N34, Tb, None ... 206 .... 242 .... Forbidden 30 L C 40 W) TP2, TP7, TP13 High explosives, see individual explo -J sives’ entries. HMX, see Cyclotetramethylenete C tranitramine, etc. §172.101 HAzARDous MATERIALSTABLE—Continued GOn
(8) (9) (10)
I Vessel Packaging Quantity limitations stowage Hazard Identi- I C Sym- Hazardous materials descriptions Label Special provisions l73.) (see 173.27 and bols and proper shipping names class or fication PG ( § — Division Numbers Codes ( 172.102) 175.75) Excep- Non- - Other tions bulk Bulk Passenger Cargo air- tion aircraft/rail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (BC) (9A) (9B) (1OA) (lOB)
Hydrazine, anhydrous 8 UN2029 I 8,3, A3, A6, A7,AlO, B7, None 201 .... 243 Forbidden 2.5L D 40, 52, 6.1. B16, 853 125. Hydrazine, aqueous solution, with not 6.1 UN3293 III 6.1 lB3, T4, TPI 153 203..., 241 60 L 220L A 52. more than 37 percent hydrazine, by mass. Hydrazine aqueous solution, with 8 UN2030 8, 6.1 816, B53, Tb, TP2, None ... 201 .... 243 Forbidden 2.5L 0 40, 52 more than 37% hydrazine, by TP13 mass. II 8, 6.1 B16, B53, 1B2,T7, TP2, None 202 243 Forbidden 30L D 40, 52 TP13 8, Ill 6.1 B16, B53, 183, T4, TPI 154 203 241 5L 60L D 40, 52 Hydrazine azide Forbidden Hydrazine chlorate Forbidden Hydrazine dicarbonic acid diazide Forbidden II 8, 6.1 816, 853, 1B2,T7, TP2, None 202 243 Forbidden 30L 0 40 TP1 3 Ill 8, 6.1 816, B53, lBS. T4, TPI 154 203 241 5L 60L D 40 Hydrazine perchiorate Forbidden Hydrazine selenate Forbidden Hydriodic acirL anhydrous, see Hy drogen iodide, anhydrous. Hydriodic acid II 8 UN1787 8 AS, A6, B2, lB2, N41, 154 202 242 1L 30L C C) T7, TP2 ,, III 8 1B3,T4, TP1 154 203 241 5L 60L C 8 Hydrobromic acid, anhydrous, see C-) Hydrogen bromide, anhydrous. 8 Hydrobromic acid, with more than 49 8 UN1788 II B2, B15, 182, N41, T7, 154 202 242 Forbidden Forbidden C percent hydrobromic acid. 8 TP2 154 Ill 8 183, T4, TP1 203 241 Forbidden Forbidden C 8 154 cp Hydrobromic acid, with not more than 8 UN1788 II A3, A6, 82, 815, 182, 202 242 1L 30L C 49 percent hydrobromic acid. 8 N41, T7, TP2 Ill A3, 1B3,T4, TP1 154 203 241 5L 60L C 8 Hydrocarbon gas mixture, com 2.1 UN1964 2.1 306 302 314, Forbidden 150kg E 40 C pressed, no.s.. 315. m 2.1 Hydrocarbon gas mixture, liquefied, 2.1 UN1965 T50 306 304 314, Forbidden 150kg E 40 0. no.5.. 315. Hydrocarbons, liquid, no.s 3 UN3295 3 144, Til, TP1, TP8, 150 201 243 IL 30L F 0 TP28 m0
3 144, 1B2,T7, TP1, TPS, 150 202 242 5L SQL B 0 TP28 0 3 144, B1, lB3, T4, TP1, 150 203 242 60 L 220L A m TP29 D Hydrochloric acid, anhydrous, see Hydrogen chloride, anhydrous. 8 a Hydrochloric acid 8 UN1789 A3, A6,B3, B15, 1B2, 154 202 242 IL 30L C 8 N41, T8, TP2 0. A3, lB3, T4, TPI 154 203 241 5L 60L C 8 Hydrocyanic acid, anhydrous, see Hydrogen cyanide etc. Hydrocyanic acid, aqueous solutions 6.1 UN1613 6.1 2, B61, B65, 677, 882, None 195 244 Forbidden Forbidden D or Hydrogen cyanide, aqueous so T20, TP2, TP13 lutions with not more than 20 per cent hydrogen cyanide. 6.1 D Hydrocyanic acid, aqueous solutions 6.1 NA1613 lBl, T14, TP2, TP13, None ... 1195 243 Forbidden 5L 0 with less than 5 percent hydrogen TP27 cyanide. Hydrocyanic acid, liquefied, see Hy drogen cyanide, etc. Hydrocyanic acid (prussic), Forbidden unstabilized. 8, 6.1 Hydrofluoric acid and Sulfuric acid 8 UN1786 A6, A7,B15, B23, N5, None 201 243 Forbidden 2.5L D E mixtures. N34, Tb, TP2, TP13 I Hydrofluoric acici anhydrous, see Hydrogen fluoride, anhydrous. 8, 6.1 8 201 Hydrofluoric acid, with more than 60 UN1790 AS, A7, B4, 815, 823, None 243 0.5 L 2.5L D 12,40 percent strength. N5, N34, Tb, TP2, 8, 6.1 8 TPI 3 Hydrofluoric acid, with not more than UN1790 A6, A7,B15, 62, N5, 154 202 243 1L 30L 0 12,40 60 percent strength. N34, T8, TP2 Hydrofluoroboric acid, see Fluoroboric acid. 0 Hydrofluorosilicic acid, see -I Fluorosilicic acid. Hydrogen and Methane mixtures, 2.1 UN2034 2,1 N89 306 302 302, Forbidden 150kg F 40, 57 compressed. 314, 315. Hydrogen bromide, anhydrous 2.3 UN1048 2.3, 8 3, 814, N86, N89 None 304 314, Forbidden Forbidden D 40 315. Hydrogen chloride, anhydrous 2.3 UN1050 2.3, 8 3, N86, N89 None 304 None Forbidden Forbidden D 40 Hydrogen chloride, refrigerated liquid 2.3 UN2186 2.3, 8 3, B6 None None 314, Forbidden Forbidden B 40 315. Hydrogen, compressed 2.1 UN1049 2.1 N89 306 302 302, Forbidden 150kg E 40, 57 314. C0) Hydrogen cyanide, solution in alcohol 6.1 UN3294 6,1, 3 2, 89, B14, B32, T20, None 227 244 Forbidden Forbidden 0 40 — with not more than 45 percent hy TP2, TPI3, TP38, TP45 drogen cyanide. 6.1, 3 1, B35, B61, B65, None 244 D Hydrogen cyanide, stabilized with 6.1 I UN1O51 877, ... 1195 Forbidden Forbidden 40 less than 3 percent water. B82 §172.101 HAzARDous MATERIALS TABLE—Continued øn
(8) (9) (10) Vessel Hazard Identi- Packaging Quantity limitations stowage C Sym- Hazardous materials descriptions Label Special provisions (173.***) (see §173.27 and bols and proper shipping names class or fication PG Division Numbers Codes ( 172.102) 175.75) Excep- Non- 0Lc- Other Bulk kons bulk Passenger Cargo air- aircraft/rail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) )9A) (9B) (mA) (lOB)
Hydrogen cyanide, stabilized, with 6.1 UN1614 6.1 5 None ... 195 .... None Forbidden Forbidden D 25, 40 less than 3 percent water and ab sorbed in a porous inert material. Hydrogen fluoride, anhydrous 8 UN1O52 8.6.1 3, 67, 646, B77, N86, None ... 163 .... 244 Forbidden Forbidden D 40 Tin, TP2 D Hydrogen in a metal hydride storage 2.1 UN3468 2.1 167 None ... 214 .... None Forbidden 100 kg system or Hydrogen in a metal hy gross dride storage system contained in equipment or Hydrogen in a metal hydride storage system packed with equipment. Hydrogen iodide, anhydrous 2.3 UN2197 2.3, 3, B14, None 304 314, Forbid Forbidden D 40 8 N86, 315. den. N89. Hydrogen iodide solution, see Hydri- odic acid. III 8 168, 1P3, N3, N34, Ti, 154 213 240 25 kg 100 kg A 25, 40, TP33 52. A Hydrogendifluoride, solid, no.s 8 UN1740 8 lB8, 1P2, P4, N3, N34, None 212 240 15 kg 50 kg 25, 40, T3, TP33 A 52 8 Ill 88, lP3, N3, N34, Ti, 154 213 240 25 kg 100 kg 25, 40, C) -‘1 TP33 52 Hydrogendifluoride solution, n.o.s 8 UN3471 8, 6.1 162, T7, TP2 154 202 242 1L 30 L A 25, 40, Ill 52. C) A 8, 6.1 163, T4, TPI 154 203 241 5L 60 L 25, 40, 52. Hydrogen peroside and peroxyacetic 5.1 UN3149 5.1,8 145, A2, A3, A6,B53, None 202 243 1L 5L D 25, 66, acid mixtures, stabilized with acids, 1B2, P5, T7, TP2, TP6, 76. wate, and not more than 5 per TP24 cent peroxyacetic acid. Hydrogen, peroside, aqueous sole- 6.1 UN2014 5.1, 8 12, A60, B53, 680, 881, None ... 202 .... 243 Forbidden Forbidden D 25, 66, C tions with more than 40 percent B85, lB2, lP5, T7, TP2, 75 m but not more than 60 percent hy TP6, TP24, TP37 0 drogen peroxide (stabilized as nec essaiy). 0 (I)
Hydrogen peroxide, aqueous solu 5.1 UN2014 5.1,8 A2, A3, A6, 853, 1B2, None ... 202 .... 243 1L 5L D 25, 66, 37 tions with not less than 20 percent 1P5, T7, TP2, TP6, 75. but not more than 40 percent hy TP24, TP37 drogen peroxide (stabilized as nec z essary). CD Hydrogen, peroxide, aqueous solu 5.1 UN2984 Ill 5.1 Al, 82, 1P5, T4, TPI, 152 203.... 241 2.5L 30L B 25, 66, tions with not less than 8 percent TP6, TP24, TP37 75 but less than 20 percent hydrogen 0. peroxide (stabilized as necessary). = Hydrogen peroxide, stabilized or Hy 5.1 UN2015 5.1,8 12, 853, 880, B81, B85, None ... 201 .... 243 Forbidden Forbidden 0 25, 66, 0 drogen peroxide aqueous solu T9, TP2, TP6, TP24, 75. tions, stabilized with more than 60 TP37 percent hydrogen peroxide. a. Hydrogen, refrigerated liquid (cryo 2.1 UN1966 2.1 T75, TP5 None ... 316 .... 318, Forbidden Forbidden 0 40 genic liquid). 319. Hydrogen selenide, anhydrous 2.3 UN2202 2.3, None ... 192 .... 245 Forbidden Forbidden D 40 2.1. Hydrogen sulfate, see Sulfuric acid 0 Hydrogen sulfide 2.3 UN1053 2.3, 2,89,814, N89 None ... 304.... 314, Forbidden Forbidden D 40 2,1. 315. 0 Hydrosilicofluoric acid, see Fluorosilicic acid. U, I -Hydroxybenzotriazole, anhydrous, l.3C UN0508 1.3C None... 62 None Forbidden Forbidden 10 0 dry or with than wetted less 20 CD percent water, by mass. 1-Hydrosybenzotriazole, anhydrous, 4.1 UN3474 4.1 162, N90 None 211 .... None 0.6 kg 0.5kg 0 28, 36 wetted with not less than 20 per cent water, by mass. 0. Hydroxyl amine iodide Forbidden 3 Hydroxylamine sulfate 8 UN2865 III 8 88, P3, Ti, TP33 154 213 240 25 kg 100 kg A Hypochlorite solutions 8 UN1791 8 A7, 82, 815, 182, lP5, 164 202 242 1L 30 L 8 26 III N34, T7, TP2, TP24 8 1B3,N34, T4, TP2, TP24 154 203 241 5L 60 L 8 26 0 Hypoct,lorites, inorganic, no.5 5.1 UN3212 5.1 A9, 188, 1P2, 1P4,T3, 152 212 240 5 kg 25 kg 0 4, 48, TP33 52, 56, 58, 69, 106, 116 118 Hyponitrous acid Forbidden Igniter fuse, metal clad, see Fuse, ig niter, tubular, metal clad. Igniters i.1G UNO121 1,1G None 62 None Forbidden Forbidden 07 Igniters 1.2G UN0314 l.2G None 62 None Forbidden Forbidden 07 lgnitars 1.3G UN0315 1.3G None 62 None Forbidden Forbidden 07 Igniters 1.4G UN0325 1.4G None 62 None Forbidden 75 kg 06 Igniters 1.4S UN0454 1.4S None 62 None 25 kg 100 kg 05 3,3’-lminodipropylamine 8 UN2269 Ill 8 1B3,T4, TP2 154 203 241 5L 60 L A G Infectious substances, affecting ani 6.2 UN2900 6.2 A82 134 196 None 50 mL or 4 L or 4 kg 8 40 mals only. 50 g §172.101 HAZARDous MATERIALsTABLE—Continued cm
(8) (9) (10) Vessel Hazard Identi- Packaging Quantity limitations stowage 0 Sym- Hazardous materials descriptions Label Special provisions 173.) (see §173.27 and bols and proper shipping names class or fication PG ( Division Numbers Codes ( 172.102) — — — 175.75) Excep- Non- Other tions bulk Bulk Passenger Cargo air- tiori aircraWrail craft only (1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (1OA) (lOB)
G Infectious substances, affecting hu 6.2 UN 2814 6.2 A82 134 196 .... None SOmLor 4Lor4kg B 40 mans. 50 g Inflammable, see Flammable Initiating explosives (dry) Forbidden Inositol hexanitrate (dry) Forbidden G Insecticide gases, no.s 2.2 UN1968 2.2 306 304 .... 314, 75kg 150 kg A 315. Insecticide G gases, flammable, no.s. 2.1 UN3354 2.1 T50 306 304 .... 314, Forbidden 150 kg D 40 315. G Insecticide gases, toxic, flammable, 2.3 UN3355 2.3, None 192 .... 245 ..,, Forbidden Forbidden D 40 no.s. Inhalation hazard Zone A. 2.1. r’,z G Insecticide gases, toxic, flammable, 2.3 UN3355 2.3, 2, 89, B14 None 302, 314, Forbidden Forbidden 0 40 no.s. Inhalation hazard Zone B. 2.1. 305. 315. G Insecticide gases, toxic, flammable, 2.3 UN3355 2.3, 3, B14 None 302, 314, Forbidden Forbidden D no.5. Inhalation hazard Zone C. 2.1, 305. 315. G Insecticide gases, toxic, flammable, 2.3 UN3355 2.3, 4 None 302, 314, Forbidden Forbidden D no.5. Inhalation D. G hazard Zone 2.1. 305. 315. 3 Insecticide gases, toxic, no.5 2.3 UN1967 2.3 None 193, 245 .... Forbidden Forbidden D 40 334. Inulin trinitrate (dry) Forbidden Iodine azide (dry) Forbidden
Iodine monochioride UN1792 II C) 8 8 B6, IB8, 1F2, P4, N41, None 212 .... 240 .... Forbidden 50 kg D 40, 66, ,, T7, TP2 74, 89, 90 () Iodine pentafluoride I 5.1 UN2495 5.1, None ... 205 .... 243 Forbidden Forbidden D 25, 40, p. 6.1, 52, 66, 8. go 2-lodobutane 3 UN2390 II 3 IB2, T4, TP1 150 202 242 5L 60L B 3 cj lodomethyipropanes UN2391 II 3 1B2,T4, TP1 150 202 242 5L SQL B lodopropanes 3 UN2392 III 3 Bi, IB3, T2, TP1 150 203 242 60 L 220L A lodoxy compounds (dry) Forbidden Iridium nitratopenlamine iridium ni Forbidden 0 trate. m Iron chloride, see Ferric chloride a. Iron oxide, spent, or Iron sponge, 4.2 UN1376 III 4.2 B18, lBS 1P3, Ti, TP33 None ... 213 240 Forbidden Forbidden B spent obtained from coal gas puri 0 fication. Iron pentacarbonyl 6.1 UN1994 1, B9, B14, I 6.1,3 B30, B77, None.,.1226...j244.... Forbidden I Forbidden I 0 40 T22, TP2, TP13, TP38, TP44 (D Iron sesquichtoride, see Ferric chlo ride. (D Irritating material, see. Tear gas sub 0 stances, etc. Isobutane see also Petroleum gases, 2.1 UN1969 2.1 19, T50 306 304 314, Forbidden 150kg E 40 0. liquefied. 315. x Isobutanol or Isobutyl alcohol 3 UN1212 III 3 81, 1B3,T2, TP1 150 203 242 60 L 220L A 0 3 3 Isobutyl acetate UN1213 III 1B2,T4, TP1 150 202 242 5L 60L B N 3 Isobutyl acrylate, stabilized 3 UN2527 81, 1B3,T2, TP1 150 203 242 60 L 220L A 0 Isobutyl alcohol, see Isobutanol 0. Isobutyl aldehyde, see 0 C Isobutyraldehyde. C’, 0 Isobutyl chioroformate 6.1 NA2742 6.1,3, 2, 89, 814, B32, B74, None 227 244 Forbidden Forbidden A 12, 13, III 8. T20, TP4, TP13, TP38, 22, 25, TP45 40, 48, 0 III 100 III Isobutyl formate 3 UN2393 3 1B2,T4, TP1 150 202 242 5L 60L B 0 Isobutyl isobutyrate 3 UN2528 3 81, 1B3,T2, TP1 150 203 242 60 L 220L A Cd, + Isobutyl isocyanate 3 UN2486 3, 6.1 1, 89, 814, 830, T22, None 226 244 Forbidden Forbidden D 40 C,, III TP2, TP13, TP27 0 Isobutyl methacrylate, stabilized 3 UN2283 3 81, 183, T2, TP1 150 203 242 60 L 220L A 3 Isobutyl propionate UN2304 3 81, 1B3,T2, TP1 150 203 242 60 L 220L B 3 C.,-’ Isobutylamine UN1214 3, 8 1B2,T7, TP1 150 202 243 IL 5L B 40 Isobutylene see also Petroleum 2.1 UN1055 2.1 19, T50 306 304 314, Forbidden 150kg 8 40 > gases, liquefied. 315. 0. Isobutyraldehyde or Isobutyl 3 UN2045 3 1B2,T4, TP1 150 202 242 5L 60L B 40 3 aldehyde. 3 Isobutyric acid UN2529 3, 8 81, 1B3,T4, TP1 150 203 242 5L 60L A Isobutyronitrile 3 UN2284 3, 6.1 182, T7, TP2, TP13 150 202 243 1L 60L E 40 Isobutyryl chloride 3 UN2395 3, 8 IBI, T7, TP2 150 202 243 1L 5L C 40 3 0 G Isocyanates, flammable, toxic, no.5. UN2478 3, 6.1 5, A3, A7, 82, Til, 150 202 243 1L 60L D 40 -I or Isocyanate solutions, flammable, TP2, TP13, TP27 toxic, s.o.s. flash point less than 23 degrees C. III 3, 6.1 5, A3, A7, 183,T7, TP1, 150 203.... 242.... 60 L 220L A TP13, TP28 Isocyanates, toxic, flammable, no.s. 6.1 UN3080 II 6.1,3 82, T11, TP2, TP13, 153 202.... 243.... 5L 60L B 25, 40, or laocyanate solutions, toxic, flam TP27 48 mable, no.s., flash point not less than 23 degrees C but not more than 61 degrees C and boiling pointless than 300 degrees C. cm
Isocyanates, toxic, or I 6.1 UN2206 II 6.1 1B2, TP2, TP13, 153 202 .... 243 E 25, 40, : no.s. I TIl, 60L Isocyanate solutions, toxic, no.5., TP27 5L 48 .1 flash point more than 61 degrees C and boiling point less than 300 0 degrees C. § 172.101 HAZARDousMATERIALsTABLE—Continued (0)
(8) (9) (10) Vessel Hazard Identi- Packaging Quantity limitations stowage C Syrn- Hazardous materials descriptions Label Special provisions 173’ (see 17327 and bols and proper shipping names class or fication PG ( ) § Division Numbers Codes ( 172.102) — 175.75) Excep- Non- Other bone bulk Bulk Passenger Cargo air- aircraft/rail craft only (1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (98) (1QA) (lOB)
III 6.1 lB3, T7, TP1, TP13, 153 203 241 60 L 220L E 25, 40, TP28 48 lsocyanatobenzotrifluorides 6.1 UN2285 II 6.1,3 5, 182, T7, TP2 153 202 243 5L 60L 0 25, 40, 48 Isoheptenes 3 UN2287 Il 3 lB2, T4, TP1 150 202 242 5L 60L B Isohesenes 3 II 150 UN2288 3 1B2, 1P8, TIl, TPI 202 242 5L 60L E lsooctane, see Octanes 150 Isooctenes 3 UN1216 II 3 82, T4, TPI 202 242 60L B Isopentane, see Pentane 5L Isopentanoic acid, see Corrosive liq uids. n.o.s.,
Isopentenes I 150 C’.) 3 UN2371 3 T11, TP2 201 243 IL 30L E 153 Isophororie diisocyanate 6.1 UN2290 III 6.1 183, T4, TP2 203 241 60 L 220L B 40 154 lsophoronediamine S UN2289 III 8 183, T4, TP1 203 241 SL 60L A 150 lsoprene, stabilized 3 UN1218 I 3 Ti 1, TP2 201 243 1L E 150 30L Isopropanol or Isopropyl alcohol 3 UN1219 II 3 1B2,T4, TP1 202 242 5L 60L B 150 Isopropenyl acetate 3 UN2403 II 3 182, T4, TP1 202 242 150 5L 60L B lsopropenylbenzene 3 UN2303 III 3 B1, 1B3,T2, TPI 203 150 242 60 L 220L A Isopropyl acetate 3 UN1220 II 3 1B2,T4, TP1 154 202 242 5L 60L B Isopropyl acid phosphate 8 UN1793 Ill 8 1B2,T4, TP1 213 240 25 kg 100kg A Isopropyl alcohol, see Isopropanol 150 ‘0 lsopropyl butyrate III 3 UN2405 3 61,183, T2, TP1 150 203 242 60 L 220L A 0 Isopropyl chloroacetate 3 UN2947 III 3 81, 183, T2, TP1 203 242 60 L 220L A -n Isopropyl chioroformate 6.1 UN2407 I 6.1,3, 2, 69, 814, 832, 977, None 227 244 Forbidden Forbidden B 40 8. T20, TP2, TP13, TP38, 0 TP44 Isopropyl 2-chloropropionate 3 UN2934 III 3 81, 183, T2, TP1 150 203.... 242.... 60 L 220L A Isopropyl sobutyrate 3 UN2406 II 3 82, T4, TP1 150 202.... 242.... 5L 60L B + Isopropyl isocyanate 3 UN2483 I 3,6.1 1, 89, 814, B30, T22, None 226 .... 244 Forbidden Forbidden D 40 TP2, TP13, TP38, TP44 Isopropyl mercaptan, see Propanethiols. Isopropyl nitrate 3 UN1222 II 3 1B9 150 202 None 5L 60L D C isopropyl phosphoric acid, see Iso m propyl acid phosphate. 0. Isopropyl propionate 3 UN2409 II 3 1B2,T4, TP1 150 202 242 5L 60L B Isopropylamine 3 UN1221 I 3,8.... T11, TP2 None 201 243 0.5 L 2.5L E 0 lsopropylbenzene 3 UN1918 III 3 61, 183, T2, TP1 150 203 242 60 L 220L A Isopropylcumyl hydroperoxide, with Forbidden -D more than 72 percent in solution. lsosorbide dinitrate mixture with not 4.1 UN2907 II 4.1 1B6, P2, N85 None ... 212 .... None 15kg 50kg E 28, 36 less than 60 percent lactose, mannose, starch or calcium hydro (I, gen phosphate. 4.1 0 Isosorbide-5-mononitrate UN3251 Ill 4.1 66, 159 68 151 223 240 Forbidden Forbidden 0 12 Isothiocyanic acid Forbidden 0. Jet fuel, see Fuel aviation, turbine = engine. 0 0 Jet perforating guns, charged oil well, 1.10 NA0124 II 1.10 55, 56 None 62 None Forbidden Forbidden 07 N with detonator. 0 0 Jet perforating guns, charged oil well, 1.4D NA0494 II 1.40 55, 56 None 62 None Forbidden Forbidden 06 0. with detonator. 0 62 C Jet perforating guns, charged oil well, liD UNOI24 II 1.10 55 None None Forbidden Forbidden 07 (I) without detonator. 62 Jet perforating guns, charged, of 1.40 UN0494 II 1.40 55, 114 None None Forbidden 300 kg 06 well, without detonator, 0 Jet perforators, see Charges, 0 shaped, etc. Jet tappers, without detonator, see 0 Charges, shaped, etc. C’, Jet thrust igniters, for rocket motors 0 or Jato, see Igniters. Jet thrust unit (Jab), see Rocket mo 0 tors. Kerosene 3 UN1223 Ill 3 144, 61, 1B3,T2, TP2 150 203 242 60 L 220L A 0. G Ketones, liquid, no.s 3 UN1224 I 3 Ti 1, TP1, TP8, TP27 None 201 243 1L 30L E II 3 182, T7, TP1, TP8, TP28 150 202 242 5L 60L B 3 Ill 3 Bi, 1B3,T4, TP1, TP29 150 203 242 60 L 220L A Krypton, compressed 2.2 UN1056 2.2 306, 302 None 75 kg 150 kg A 307. Krypton, refrigerated liquid (cryogenic 2.2 UN1970 2.2 T75, TP5 320 None None 50 kg 500kg B 0 liquid). Lacquer base or lacquer chips, nitro cellulose, dry, see Nitrocellulose, etc. (UN 2557). Lacquer base or lacquer chips, plas tic, wet with alcohol or solvent, see Nitrocellulose (UN2059, UN2555, UN2556, UN2557) or Paint etc.(UN1263). Lead acetate 6.1 UN1616 Ill 6.1 168, lP3, Ti, TP33 153 213 240 100 kg 200kg A Lead arsenetes 6.1 UN1617 II 6.1 168, lP2, P4, T3, TP33 153 212 242 25 kg 100kg A 6.1 Lead arsenites UN1618 II 6.1 68, P2, 1P4, T3, TP33 153 212 242 25 kg 100kg A c0) Lead aside (dry) Forbidden Lead azide, wetted with not less than 1.1A UN0129 II 1.IA iii, 117 None 62 None Forbidden Forbidden 12 20 percent water or mixture of al cohol and water, by mass. C
Lead compounds, soluble, no.s 6.1 I UN2291 Ill 6.1 138, 1B8,lP3, Ti, TP33 1153 I 213 .... I 240 100 kg 200kg A None2.1None...
§172.101 HAZARDOusMATERIALSTABLE—Continued W)
(8) (9) (10) Vessel Hazard Identi- Packaging Quantity limitatrons stowage C Sym- Hazardous materials descriptions Label 73,** Special provisions 1 ) (see 173.27 and bols and proper shipping names class or fication PG ( § Division Numbers Codes (172.102) — — — 175.75) Excep- Non- Other tions bulk Bulk Passenger Cargo air- Son aircrsttirail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (88) (8C) (9A) (9B) (1OA) (lOB) Lead cyanide 6.1 UN1620 II 6.1 1B8, lP2, lP4, T3, TP33 153 212 242 25 kg 100kg A 52 5.1 Lead dioxide UN1872 III 5.1 Al, 88, 1P3, Ti, TP33 152 213 240 25 kg 100kg A Lead dross, see Lead sulfate, with more than 3 percent free acid, Lead nitrate 5.1 UN1469 II 5.1, 1B8, P2, lP4, T3, TP33 152 212 242 5 kg 25kg A 6.1. Lead nitroresorcinate (dr,’) Forbidden Lead perchlorate, solid 5.1 UN1470 II 5.1, 1B6, P2, T3, TP33 152 212 242 5 kg 25kg A 56, 58 6.1. Lead perchlorate, solution 5.1 UN3408 II 5.1, 1B2,T4, TP1 152 202 243 1L 5L A 56, 58 6.1. III 152 00 5.1, 82, T4, TP1 203 242 2.5 L 30L A 56, 58 6.1. Lead peroxide, see Lead dioxide Lead phosphite, dibasic 4.1 UN2989 II 4.1 88, 1P2, 1P4,T3, TP33 None 212 240 15 kg 50kg B 34. III 4.1 1B8,1P3, T1,TP33 151 213 240 25 kg 100kg B 34. Lead picrate (dry) Forbidden Lead styphnate (dry) Forbidden Lead styphnate, wetted or Lead 1.IA UN0130 II 1.1A 111, 117 None 62 None Forbidden Forbidden 12 ‘0 trinitroresorcinate, wetted with not C) less than 20 percent water or mix ‘.1 ture of alcohol and water, by mass, Lead sulfate with more than 3 per 8 UN1794 II 8 188, lP2, 1P4, T3, TP33 154 212 .... 240 15 kg 50kg A C) cent free acid. Lead trinitroresorcinate, see Lead styphnate, etc. Life-saving appliances, not self inflat 9 UN3072 None 219 .... None No limit No limit A cp ing containing dangerous goods as equipment. 9 Life-saving appliances, self inflating UN2990 None ... 219 .... None No limit No limit A C Lighters containing flammable gas 2.1 UN1057 168 21,308 21,308 None 1 kg 15kg B 40 m Lighters, new or empty, purged of all 168 0 residual fuel and vapors. Lighters, non-pressurizer.( containing 3 NA1057 Il 3 168 21 None None Forbidden Forbidden B 40 0 flammable liquid,. Lighter refills containing flammable 2.1 UN1057 2.1 169 306 ...... 306 .... None 1 kg 15 kg B 40 gas not exceeding 4 fluid ounces (7.22 cubic inches) and 65 grams CD of flammable gas.
Lighter replacement cartridges con- CD taming liquefied petroleum gases see Lighter refills containing fiam mable gas. Etc 0.. Lighters, fuse 1.4S UNO131 II 1.4S ... None ... 62 None 25kg 100 kg 05 Lime, unslaked, see Calcium oxide 0 G Liquefied gas, flammable, no.5 2.1 UN3161 2.1 T50 306 304 .... 314, Forbidden 150 kg C 40 N 315 — G Liquefied gas, no.5 2.2 UN3163 2.2 T50 306 304 .... 314, 75 kg 150 kg A 315, g G Liquefied gas, oxidizing, n.o.s 2.2 UN3157 2.2, A14 306 304 .... 314, 75 kg 150 kg D 5.1. 315.
C I Liquefied gas, toxic, corrosive, no.5 2.3 UN3308 2.3, 8 1 None ... 192 .... 245 Forbidden Forbidden C 40 Inhalation Hazard Zone A —
C I Liquefied gas, toxic, corrosive, no.5 2.3 UN3308 2.3, 8 2, 89, B14 None ... 304 .... 314, Forbidden Forbidden D 40 Inhalation Hazard Zone B. 315.
G I Liquefied gas, toxic, corrosive, no.s 2.3 UN3308 2.3, 8 3, 814 None ... 304 .... 314, Forbidden Forbidden D 40 Inhalation Hazard Zone C. 315 Cl’) C I Liquefied gas, toxic, corrosive, no.5 2.3 UN3308 2.3, 8 4 None ... 304 .... 314, Forbidden Forbidden D 40 0 Inhalation Hazard Zone D. 315.
C I Liquefied gas, toxic, flammable, cor- 2.3 UN3309 2.3, 1 None ... 192 .... 245 Forbidden Forbidden D 17,40 rosive, no.s. Inhalation Hazard 2.1, ZoneA 8.
G I Liquefied gas toxic, flammable, corro- 2.3 UN3309 2.3, 2, B9, B14 None ... 304 .... 314, Forbidden Forbidden C 17, 40 sive, no.s, Inhalation Hazard Zone 2.1, 315. B 8.
C I Liquefied gas, toxic, flammable, cor- 2.3 UN3309 2.3, 3, B14 None ... 304 .... 314, Forbidden Forbidden C 17, 40 roxive, no.5. Inhalation Hazard 2.1, 315. Zone C 8 0 C I Liquefied gas, toxic, flammable, cor- 2.3 UN3309 2.3, 4 None ... 304 .... 314, Forbidden Forbidden 0 17, 40 rosive, no.s. Inhalation Hazard 2.1, 315. Zone 0 8. C Liquefied gas, toxic, flammable, 2.3 UN3160 2.3, 1 None ... 192 .... 245 Forbidden Forbidden D 40 no.s. Inhalation Hazard Zone A 2.1. G Liquefied gas, toxic, flammable, 2.3 UN3160 2.3, 2, 69, 814 None ... 304 .... 314, Forbidden Forbidden D 40 n.o.s. Inhalation Hazard Zone B 2.1. 315. C Liquefied gas, toxic, flammable, 2.3 UN3160 2.3, 3, 814 None ... 304 .... 314, Forbidden Forbidden D 40 no.s. Inhalation Hazard Zone C 2.1. 315. G Liquefied gas, toxic, flammable, 2.3 UN3160 2.3, 4 None ... 304 .... 314, Forbidden Forbidden 0 40 no.s. Inhalation Hazard Zone D 2.1. 315. C Liquefied gas, toxic, no.s. Inhalation 2.3 UN3162 2.3 I None ... 192 .... 245 Forbidden Forbidden D 40 Hazard Zone A — G Liquefied gas, toxic, n.o.s. Inhalation 2.3 UN3162 2.3 2, B9, B14 None ... 304 .... 314, Forbidden Forbidden 0 40 Hazard Zone B. 315. C Liquefied gas, toxic, no.s. Inhalation 2.3 UN3162 2.3 3, B14 None ... 304 .... 314, Forbidden Forbidden C 40 o Hazard Zone C. 315. cm §172.101 HAZARDoUS MATERIALS TABLE—Continued
(8) (9) (10) Vessel Hazard Identi- Packaging Quantity limitations stowage C Sym- Hazardous materials descriptions Label Special provisions 173.) (see 173.27 and bols and proper shipping names class or fication PG ( § Division Numbers Codes ( 172.102) — —.. 175.75) Excep- Non- Other tions bulk Bulk Passenger Cargo air- tion aircraft/rail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (88) (8C) (9A) (98) (1OA) (108)
S Liquefied gas, toxic, n.o.s. Inhalation 2.3 UN3162 2.3 4 None ... 304 .... 314, Forbidden Forbidden D 40 Hazard Zone D. 315. GI Liquefied gas, toxic, oxidizing, corro 2.3 UN3310 2.3, 1 None... 192.... 245.... Forbidden Forbidden D 40, 89, sive, no.5. Inhalation Hazard Zone 5.1, 90 A. 8. SI Liquefied gas, toxic, oxidizing, corro 2.3 UN3310 2.3, 2, 89, 814 None ... 304 314, Forbidden Forbidden D 40, 89, sive, n.o.s. Inhalation Hazard Zone 5.1, 315. 90 B. 8. Liquefied gas, toxic, oxidizing, corro 2.3 UN3310 2.3, 3, 814 None ... 304 314, Forbidden Forbidden D 40, 89, sive, no.5. Inhalation Hazard Zone 5.1, 315. 90 C. SI Liquefied gas, toxic, oxidizing, corro 2.3 UN3310 2.3, 4 None ... 304 314, Forbidden Forbidden U 40, 89, sive, n.o.s. Inhalation Hazard Zone 5.1, 315. 90 0. 8, S Liquefied gas, toxic, oxidizing, no.5. 2.3 UN3307 2.3, None 192 245 Forbidden Forbidden D 40 Inhalation Hazard Zone A. 5.1. G Liquefied gas, toxic, oxidizing, no.5. 2.3 UN3307 2.3, 2, B9, 814 None 304 314, Forbidden Forbidden U 40 Inhalation Hazard Zone B. 5.1. 315. G U Liquefied gas, toxic, oxidizing, no.5. 2.3 UN3307 2.3, 3, 814 None 304 314, Forbidden Forbidden 40 Inhalation Hazard Zone C. 5.1. 315. U G Liquefied gas, toxic, oxidizing, no.5. 2.3 UN3307 2.3, 4 None 304 314, Forbidden Forbidden 40 ‘0 Inhalation Hazard Zone D. 5.1. 315. C-) Liquefied gases, non-flammable 2.2 UN1058 2.2 306 304 None 75 kg 150 kg A T1 charged with nitrogen, carbon diox ide or air. C-) Liquefied hydrocarbon gas, see Hy drocarbon gas mixture, liquefied, n.o.s.. Liquefied natural gas, see Methane, etc. (UN 1972). Liquefied petroleum gas see Petro leum gases, liquefied. UN1415 Lithium 4.3 I 4.3 A7, A19, 184, P1, N45 None ... 211 .... 244 .... Forbidden 15kg 52 C Lithium acetylide ethylenediamine m complex, see Water reactive solid etc.
Lithium aluminum hydride 4.3 UN141O I 4.3 A19 None ... 211 .... 242 .... Forbidden 15kg E 52 0
Lithium aluminum hydride, ethereal 4.3 UN1411 I 4.3,3 A2, A3,All, N34 None ... 201 .... 244 .... Forbidden 1L D 40 Lithium batteries, contained in equip 9 UN3091 II 9 29, 188, 189, 190, A54, 185 185 None See AlOl, 35 kg A 0 ment. II ASS, AiQi, A104 A104. 9 9 Lithium batteries packed with equip UN3091 29, 188, 189, 190, A54, 185 185 None See AlOl, 35 kg A (D ment. A55, A101, A103 9 9 A103. gross A (D Lithium battery UN3090 29, 188, 189, 190, A54, 185 185 None See Al00 35 kg ASS, Aloe. gross a Lithium borohydride 4.3 UN1413 4.3 A19, N40 None 211 242 Forbidden 15 kg E 52 Lithium ferrosilicon 4.3 UN2830 II 4.3 A19, lB7, 1P2, T3, TP33 151 212 241 15 kg 50 kg E 40, 85, 0. 103 = Lithium hydride UN1414 4.3 0 4.3 A19, N40 None 211 242 Forbidden iS kg B 52 N Lithium hydride, fused solid 4.3 UN2805 4.3 A8, A19, A20, lB4, T3, 151 212 241 15 kg 50 kg E 52 0 TP33 a. Lithium hydroxide 8 UN2680 8 1B8,1P2, 1P4,T3, TP33 154 212 240 15 kg 50 kg A 52. 0 8 8 Lithium hydroxide, solution UN2679 B2, 162, T7, TP2 154 202 242 lL 30 L A 29, 52. £ Ill 8 183, T4, TP2 154 203 241 SL 60 L A 29, 52, 96. 152 Lithium hypochlorite, dry with more 5.1 I UN1471 II 5.1 A9, 188, 1P2, 1P4,N34 212 240 5 kg 25 kg A 4, 48, 0 than 39% available chlorine (8.8% 52, 56, (D available oxygen) or Lithium hypo 58, 69, with 0 chlorite mixtures, dry more 106, (I, than 39% available chlorine (8.8% 116 C,, available oxygen). a Lithium in cartridges, see Lithium 5.1 A Lithium nitrate S.1 UN2722 Ill Al, 188, 1P3, Tl, TP33 152 213 240 25 kg 100 kg Lithium nitride 4.3 UN2806 4.3 A19, lB4, IPI, N40 None 211 242 Forbidden 15 kg B Lithium peroxide 5.1 UN1472 II 5.1 A9, lB6, P2, N34, T3, 152 212 None 5 kg 25 kg A 13, 52, a. II TP33 66, 75 Lithium silicon 4.3 UN1417 4.3 A19, A20, 187, P2, T3, 151 212 241 15 kg 50 kg A 85, 103 B II TP33 z LNG, see Methane etc. (UN 1972) A London purple 6.1 UN1621 6.1 1B8,1P2, 1P4,T3, TP33 153 212 242 25 kg 100 kg V LPG, see Petroleum gases, liquefied -I0 Lye, see Sodium hydroxide, solutions II Magnesium aluminum phosphide 4.3 UN1419 4.3, A19, N34, N40 None 211 242 Forbidden 15 kg B 40, 52,
II 6.1. 8S + UN 1P4, Magnesium arsenate 6.1 1622 II 6.1 88, lP2, T3, TP33 153 212 242 25 kg 100 kg A Magnesium bisulfite solution, see II Bisultites, aqueous solutions, no.s.. 5.1 A Magnesium bromate UN1473 5.1 Al, 1B8, P2, lP4, T3, 152 212 242 S kg 25 kg 56, 58 5.1 TP33 A Magnesium chlorate UN2723 5.1 188, 1P2, P4, T3, TP33 152 212 242 5 kg 25 kg 56, 58 Magnesium diamide 4.2 UN2004 4.2 A8, A19, A20, lB6, T3, None 212 241 iS kg 50 kg C TP33 Ca, Magnesium dross, wet or hot Forbidden Magnesium fluorosilicate 6.1 UN2853 Ill 6.1 188, lP3, Ti, TP33 153 213 240::.: 100 kg 200 kg A 52 Magnesium granules, coated, particle 4.3 UN29SO Ill 4.3 Al, A19, 188, 1P4, TI, 151 213 240 25 kg 100 kg A 52 size not less than 149 microns. TP33 C Magnesium hydride 4.3 UN2OIO 4.3 A19, N40 None 211 242 Forbidden iS kg E 52 C -n c0) ‘0 C) C) C m 0. 0 75 85 12 52 52 34 74, 52, 52, 101 103 66, 56. 58 Other 39, 52 (108) 39, 52 39, 34. 53, 13, 39, 52, 40, 85, (10) Vessel stowage na (bA) E A A A A A B A A A A B A A A A kg kg kg kg kg kg kg kg kg kg kg kg kg air- Only 15 15 25 25 50 50 and 100 100 100 100 100 100kg 100kg 100 100 (98) craft Forbidden Cargo limitations (9) 173.27 175.75) kg kg kg kg kg kg kg kg kg kg kg kg §5 5 5 25 15 25 15 kg 25 25 25 25 25 25 25 (9A) Quantity (see Forbidden Forbidden Forbidden Passenger aircrattirail Bulk (SC) 240 None 240 242 242 244 241 241 240 242 241 242.... 240 242.... 240 240 .... (8) bulk (88) Non- 173.) 213 213 211 211 212 212 212 212 213 213 213 212 213.... 213.... 213 213 (5 Packaging ...... (8A) lions Escep- — 152 151 152 152 None None 154 151 153 None None None 151 151 152 None Ti, T3, T3, Ti, TI, P4, B56 N40 TP3 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 P3, 1P2, lP2, lP4, lB6, T4, TABLE—Continued 1B8, Ti, T3, T3, A19, A19, Ti, T3, Ti, TI, Ti, 1B8, 1B5, lB7, 188, provisions P2, P3, A19, (7) lP3, lP2, lP4, 1P3, 1B6, A19, 172.102) Al, Al, (5 856, B56, 88, Al, Al, 188, 1B6, lB6, lP2, 1B8, Special 57, 332, 54, Al, Al, MATERIALS A19, A19, A19, A20, lB8, (6) 6.1. 4.2. 4.2. 4.2. 4.3. Label Codes 5.1 4.1 5.1 5.1 4.3, 4.3, 8 4.3, 4.3, 6.1 8 4.3 5.1 4.2, 4.3 4.1 II II II II Ill III Ill Ill Ill Ill III Ill Ill HAzARDous (5) PG 1476 (4) 1330 172.101 Identi- lication Nsmbers UN1869 UN1474 UN1475 UN UN2011 UN1418 UN2215 UN2215 UN2624 UN2647 § UN2968 UN2210 UN2724 UN 8 8 or 5.1 5.1 4.1 4.3 5.1 4.3 6.1 4.3 4.3 4.2 5.1 4.1 (3) Hazard class Division Forbidden Forbidden with com alloys magne ribbons. prepara self-heat maneb. or names Magnesium 5173.21 Magnesium, (manganese descriptions or percent Maneb. see Maneb (dry) see preparations against percent 50 molten Magnesium turnings or (2) see shipping 60 materials or powder than scrap, nilrate phosphide peroxide perchlorate silicicle material, nitrate resinate zinc) Maneb 1869). than pellets, proper letranilrale powder. hexanitrate stabilized or in stabilized more anhydride anhydride, with (UN less and Hazardous with sium alloys, etc. ethylenebisdithiocarbamate aol tions, ing. plex Magnesium Magnesium Magnesium Magnesium, Magnesium Magnesium Magnesium Maleic Magnesium Maleic Malononitrile Magnetized Maneb Maneb Mancozeb Manganese Manganese Mannilan Mannitol (1) hots Sym- IIIII
Mannitol hexanitrate, wetted or 1.10 UN0133 II 1.10 121 None ... 62 ...... None Forbidden Forbidden 10 Nitromannite, wetted with not less V than 40 percent wale,; or mixture of alcohol and water; by mass.
Marine pollutants, liquid or solid, CD no.s., see Environmentally haz ardous substances, liquid or solid, n.o.s 0. Matches, block, see Matches, ‘strike = anywhere’ 0 Matches, tusee 4.1 UN2254 III 4.1 186 186 None Forbidden Forbidden A Matches, safety (book, card or strike 4.1 UN1944 UI 4.1 186 186 None 25 kg 100 kg A — on box) o Matches, strike anywhere 4.1 UN1331 III 4.1 186 186 None Forbidden Forbidden B C C” Matches, wax, Vests 4.1 UN1945 III 4.1 186 186 None 25 kg 100 kg B Matting acid, see Sulfuric acid Medicine, liquid, flammable, toxic, 3 UN3248 II 3, 6.1 lB2 150 202 None 1 L 5 L B 40 0 no.5.. 3,6.1 lB3 150 203 None 5 L 5 L A Medicine, liquid, toxic, no.5 6.1 UN1851 II 6.1 153 202 243 5 L 5 L C 40 2. U’ 6.1 153 203 241 5 L 5 L C 40 Medicine, solid, toxic, no.5 6.1 UN3249 II 6.1 T3, TP33 153 212 None 5 kg 5 kgC 40 6.1 Ti, TP33 153 213 None kg kg C 40 Memtetrahydrophthalic anhydride — see Corrosive liquids, no.s..
Mercaptans, liquid, flammable, no.s 3 UN3336 3 Tii, TP2 150 201 243 1 L 30 L E 95 or Mercaptan mixture, liquid, 8am- 0. mable, no.s 3 3 1B2,T7, TP1, TP8, TP28 ISO 202 242 5 L 60 L B 95 3 Bi, B52, lB3, T4, TP1, 150 203 241 60 L 220 L B 95 TP29 Mercaptans, liquid, flammable, toxic, 3 UN1228 II 3,6.1 182, T11, TP2, TP27 None 202 243 Forbidden SQL B 40,95 0 no.s. or Mercaptan mixtures, liq- —I uld, flammable, toxic, no.5.. 3,6.1 AS, Bi, 1B3,T7, TP1, 150 203 242 5 L 220 L A 40, 95 TP28 Mercaptans, liquid, toxic, flammable, 6.1 UN3071 II 6.1,3 A6, 1B2,Til, TP2, 153 202 243 5 L 60 L C 40, 121 no.s. or Mercaptan mixtures, Iiq- TPI3, TP27 uid, toxic, flammable, no.s., Sash point not less than 23 degrees C. 5-Mercaptotetrazol-1-acetic acid 1.4C UN0448 II 1.4C None 62 None Forbidden 75kg 09 Mercuric arsenate 6.1 UN1623 II 6.1 lB8, lP2, 1P4, T3, TP33 153 212 242 25 kg 100 kg A Mercuric chloride 6.1 UN1624 II 6.1 IB8, lP2, 1P4, T3, TP33 153 212 242 25 kg 100 kg A Mercuric compounds, see Mercury compounds, etc — Mercuric nitrate 6.1 UN1625 II 6.1 IBS, lP2, P4, N73, T3, 153 212 242 25 kg 100 kg A TP33
+ Mercuric potassium cyanide 6.1 UN1626 I 6.1 l87, IP1, N74, N75, T6, None 211 242 Skg 50kg A 52 TP33 — 0
Go, 0 ,, p. (-) m 0 0 a.
97 40
40 40 40 40 40 40 40 40 40 40 40 40 40
Other (108) 40,
(10)
Vessel
stowage
(10A)
B A A B B B 6 A B B A A B A A B A A B A A A A
I
L L L L L L
kg kg kg kg
kg
air-
30
60 60 30 30 60L
30L SOL
only
35
220 50kg 220L 50kg
220L
and
100 100 100
100kg 100kg 100kg 100kg 200kg 200
(98)
craft
Cargo
limitations
(9)
L L
L
175.75) kg
kg kg kg
kg kg kg kg kg kg kg kg
§i73.27
1L 1L 1L 5L iL 5L
5L
5 60 60 5 60
25 35 25 25
25 25 25 25
100 100
(9A(
Quantity (see
Forbidden
aircraft/rail Passenger
Bulk (SC) —
242 242 240 242 243 243 243 243 243 243 241 242 242 242 240 242 242 240 243 241 242 243 242
(8)
bulk (88)
Non-
164
212 212 201 212 202 201 202 203 201 202 203 211 212 203 212 213 212 201 202 211 213 212
(173.**)
Packaging
(8A(
tions
Excep-
153 164 153
153 153 153 None 150 153 None 153 None 153 153 153 153 153 None 153 153 None 153 None
lB2 lB3
TP33
TP33 TP33 TP27 TP27 TP27
TP27 TP27 TP28 TP27 TP33 TP33 TP28 TP33 TP33 TP33 TP33 TP33 TP33
TP13, TP13, TP13,
TABLE—Continued
T3, T3, T3,
T3, T6, T3, T6, Ti, T3, Ti, T3,
TP2, TP2,
TP2, TP2, TP2,
TP13, TP13,
TPI3,
provisions
P4,
P4,
P4, P3, P4,
(7) P4.
lP4.
IPI, 1P4, 1P3, IP1,
T7, T7,
Til, Til, Til,
TP2, TP2,
TP2, (172.i02(
lP2, lP2, lP2,
lP2, 1B8, 1B7, lP2, 187, 1P2, 1P2, 186,
1B3, 1B3,
82,
Special 182, lB2,
88, T14, T14. T14,
MATERIALS lB8,
1B8.
1B8,
188, 188, lBS.
6.1 6.1
(6)
Label
Codes
6.1 8 6.1 3, 6.1 3, 6.1 6.1 6.1 6.1,3 6.1,3 6.1 6.1,3 6,1 6.1 6,1 6.1 6.1 6.1 6.1 6.1 6.1 6.1
II II
II
Ill
Ill
Ill Ill
Ill Ill
HAzARDOus
(5) PG
(4)
172.101
Identi-
fication
Numbers
UN1627 UN1630 UN2809 UN1629 UN2778 UN3012
§ UN3011 UN1634 UN2777 UN1631 UN2025 UN2024
8 3
or
6.1 6,1 6.1 6.1
6.1 6.1
6.1 6.1 6.1 6,1
(3)
Hazard
class Division
Forbidden Forbidden
not
less
toxic
liquid,
liquid, liquid,
Mercury
Mercury
no.5
point
no.s
point
solid,
names
see
see
C.
descriptions
nucleate
flash
solid, liquid,
flash
chloride
C.
pesticides, pesticides, pesticides,
(2)
shipping
pesticides,
etc.
degrees
Mercury toxic,
materials
23
compounds,
aside
nitrate
degrees
based based
see based
sulfocyanate,
proper
acetate acetylide flammable,
ammonium
bromides based benzoste compounds, compounds,
23
than
and
Hazardous
thiocyanale. compounds, than flammable,
tonic. less
toxic,
Mercuric Mercurol, Mercurous Mercurous Mercurous Mercury Mercury Mercury Mercury Mercury Mercury Mercury Mercury Mercury Mercury Mercury Mercury
(1)
AW
bols
Sym- A Mercury contained in manufactured 8 UN2809 Ill 8 None 164 None No limit No limit B 40, 97 - articles, Mercury cyanide 6.1 UN1636 6.1 1B8, 1P2, 1P4,N74, N75, 153 212 242 25 kg 100 kg A 52 CD T3, TP33 Mercury fulminate, wetted with not i.iA UN0135 1.iA 111, 117 None 62 None Forbidden Forbidden 12 CD less than 20 percent water, or mix ture of alcohol and water, by mass. 0 Mercury gluconate 6.1 UN1637 6.1 lB8, 1P2, 1P4, T3, TP33 153 212 .... 242 .... 25 kg 100 kg A 0. Mercury iodide 6.1 UN1638 6.1 162. P2 1P4, T3, TP33 153 212 .... 242 .... 25 kg 100 kg A Mercury iodide aquabasic Forbidden 0 ammonobasic (Iodide of Millon’s N base). 0 0. Mercury nitride Forbidden A 0 Mercury nucleate 6.1 UN1639 6.1 68, 1P2, P4, T3, TP33 153 212 242 25 kg 100 kg Mercury oleate 6.1 UN1640 6.1 1B8, P2, P4, T3, TP33 153 212 242 25 kg 100 kg A C,, Mercury oxide 6.1 UN1641 6.1 1B8, P2, lP4, T3, TP33 153 212 242 25 kg 100 kg A Mercury oxycyanide Forbidden 6.1 0 Mercury oxycyanide, desensitized 6.1 UN1642 188, P2, 1P4, T3, TP33 153 212 25 kg 100 kg A 52, 91 6.1 242 CD Mercury potassium iodide 6.1 UN1643 68, lP2, 1P4, T3, TP33 153 A 6.1 212 242 25 kg 100 kg Mercury salicylate 6.1 UN1644 168, P2, 1P4, T3, TP33 153 212 242 25 kg 100 kg A 0 6.1 A + Mercury sulfates 6.1 UN1645 1B8, lP2, lP4, T3, TP33 153 212 242 C,, 6.1 25 kg 100 kg A thiocyanate 6.1 C’, Mercury UN1646 1B8, 1P2, P4, T3, TP33 153 212 242 25 kg 100 kg A a Mesityl oxide 3 UN1229 Ill 3 Bi, 1B3,T2, TP1 150 203 242 60 L 220 L CD r’.z G Metal carbonyls, liquid, n.o.s 6.1 UN3281 6.1 5, T14, TP2, TP13, None 201 243 lL 30 L B 40 TP27 6.1 B 162, Til, TP2, TP27 153 202 243 5L 60 L 40 6.1 Ill 183, T7, TPI, TP28 153 203 241 60 L 220 L A 40 0. G Metal carbonyls, solid, no.s 6.1 UN3466 6.1 167, IP1, T6, TP33 None 211 I 242 5 kg 50 kg D 40 3 6.1 lB8, P2. 1P4, T3, TP33 153 212 242 25 kg 100 kg B 40 Ill 6.1 1B8. 1P3, Ti, TP33 153 213 240 100 kg 200 kg B 40 Metal catalyst, dry 4.2 UN2881 4.2 N34, T2i, TP7. TP33 None 187 None Forbidden Forbidden C 4.2 166, P2, N34, T3, TP33 None 187 242 Forbidden 50 kg C 0 4.2 168, 1P3, N34, Ti, TP33 None 187 241 25 kg 100 kg C - Metal catalyst, wetted with a visible 4.2 UN1378 4.2 A2, A8, IBi, N34, T3, None 212 None Forbidden 50 kg C excess of liquid. TP33 Metal hydrides, flammable, no.s 4.1 UN3182 4.1 Al, 1B4, T3, TP33 151 212 240 15 kg 50 kg B Ill 4.1 Al, 1B4, Ti, TP33 151 213 240 25 kg 100 kg 8 Metal hydrides, water reactive, no.5. 4.3 UN1409 4.3 A19, N34, N40 None 211 242 Forbidden 15 kg D 52 4.3 Ai9, 164, N34, N40, T3, 151 212 242 15 kg 50 kg D 52 TP33 Metal powder, self-heating, no.s 4.2 UN3189 4.2 166, lP2, T3, TP33 None 212 241 15 kg 50 kg C Ill 4.2 1B8, 1P3, Ti, TP33 None 213 241 25 kg 100 kg C Metal powders, flammable, no.s 4.1 UN3089 4.1 1B8, 1P2, lP4, T3, TP33 151 212 240 15 kg B Ill 50 kg 4.1 lB6, Ti, TP33 151 213 240 25 kg 100 kg B cm Metal salts of methyl nitramine (dry) Forbidden G Metal salts of organic compounds, 4.1 UN3181 4.1 Al, 1B8, 1P2, 1P4, T3, 151 212 240 15 kg 50 kg B 40 flammable, no.s.. TP33 B Ill 4.1 Al, 68, 1P3, Ti, TP33 151 213 240 25 kg 100 kg 40 4.1 C Metaldehyde 4.1 UN1332 Ill Al, 188, 1P3, Ti, TP33 151 213 240 25 kg 100 kg A F1 0 c0)
‘0 C) — C, m 0 0. 40 40 40 40 40 40 40 40 48 40 40 40 40 40 40, (lOB) Other 12, (10) Vessel stowage tiOfl (1QA) E E E E E E D B C D D E A B B B D B A A air- 30L 60L 60L 60L 60L only 15kg 15kg 50kg 50kg 220L 220L 220L and 100kg 100kg 150kg 150kg (96) craft Forbidden Forbidden Forbidden Forbidden Cargo limitations (9) 173.27 L L L kg 175.75> kg kg 1L IL § IL 1L 5L 60 60 60 15 kg 15 25 25 (BA) Quantity (see Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden aircraWrail Passenger 315. Bulk (SC) 242 242 242 241 242 242 242 244 243 242 302 244 318 242 242 242 242 — 242 314, 244 (8) 73,***) bulk (86) Non- I 212 211 212 213 213 211 202 202 227 None 203 302 227 202 202 203 203 304 226 202 ( Packaging ... (8A) tions Excep- 151 151 None 154 None None None 150 150 — None None 150 None 150 150 306 150 150 None 306 64 A7 T50 TP1 TP5 TP2 TPI TP1 TP2 TP1 T20, T20, T22, TP33 TP33 TP33 TP3O TP33 TP13 TP45 TP45 TP44 TP18, A7, T2, T7, T7,
TABLE—Continued T2, T2, T4, T3, T3, Ti, Ti, T75, N88, B32, 832, 830, TP1, TPI, TP38, 63, TP38, 83, TP38. 162, 162, 183, 1B2, provisions P4, (7) 1P2. 1P2, 1P4, T7, 614, 614, 172.102) 614, T7, 61, 61, 61, ( 185, 1B7, 1B8, 168, TP13, TP13, TP13, 69, 69, 182, 89, 162, Special 2, 1. 2, A7, A7, A7, A7,
MATERIALs 45, 41, TP2, TP2, TP2, 6.1 6.1 (6) 6.1 6.1 4.2. 4.2. 4.2. Label Codes 4.3 4.3 4.3 8 4.3, 4.3, 3, 4.3, 3, 3 2.1 2.1 6.1,8 3 3, 3 3 3, 3 2.1 II Ill Ill Ill Ill Ill
HAzARDous (5) PG (4) 1231 Identi- tication Numbers UN3209 UN3208 UN2396 UN2531 UN3079 UN1971 UN2614 UN3246
§172.101 UN1972 UN3092 UN2605 UN1230 UN1230 UN2293 UN1O6O UN 3 8 3 3 3 3 3 3 3 3 or 4.3 4.3 6.1 2.1 2.1 2.1 (3) Hazard Division class Forbidden with mix (cryo meth refrig Natural mixtures, high gas, propadiene liquid), names or liquid descriptions water-reactive, water-reactive, methane, (with and stabilized Natural and (2) stabilized stabilized shipping chloride content). hydrogen, isocyanate or n.o.s.. (cryogenic materials acid, stabilized, compressed refrigerated and acid substance, substance, proper alcohol liquid etc. liquid) acetylene compressed methane acetate Hydrogen content). and Hazardous no.5.. self-heating, see high ane tures, genic erated gas, mistures, -Methoxy-2-propanol Metallic Metallic Methacrylonitrile, Methacrylaldehyde, Methacrylic Methallyl Methane Methane, Methane, Metharresulfonyl 1 Methanol Methanol Methyl Methoxymethyl Methazoic Methyl 4-Methosy-4-methylpentan-2-one + G G D +1 (1) bole Sym- Methyl acrylate, stabilized 3 UN1919 II 3 1B2,T4, TP1, TPI3 150 202 242 5L SQL B -D Methyl alcohol, see Methanol II 3 3 0 Methyl allyl chloride UN2554 lB2, T4, TP1, TP13 150 202 242 5L 60L E CD Methyl amyt ketone, see Amyl methyl CD ketone. Methyl bromide 2.3 UN1062 2.3 3, 614, N86, T50 None 193 314, Forbidden Forbidden D 40 0 315. Methyl bromide and chloropicrin mix tures with more than 2 percent = chloropicrin, see Chloropicrin and II 0 methyl bromide mixtures. II N Methyl bromide and chloropicrin mix 0 tures with not more than 2 percent 0. chloropicrin, see Methyl bromide. 0 Methyl C bromide and ethylene I I 6.1 UN1647 6.1 2, B9, B14, B32, N65, None ... I 227 .... 244 .... Forbidden Forbidden C 40 (n dibromide mixtures, liquid. II T20, TP2, TP13, TP3S, TP44 6.1 0 Methyl bromoacetate 6.1 UN2643 1B2,T7, TP2 153 202 243 5L 60L D 40 2-Methylbutanal 3 UN3371 3 182, T4, TP1 iso 202 242 5L 60L B CD 2-Methyl-i-butane 3, UN2459 3 Til, TP2 None 201 243 1L 30L E 3 0 2-Methyl-2-butene 3 UN2460 lB2, lP8, T7, TP1 None 202 242 5L SQL E U, 3 3 3-Methyl-i-butane UN2561 Til, TP2 None 201 243 1L 30L E Cd, 3 3 Methyl tert-butyl ether UN2398 162, T7, TP1 150 202 242 5L SQL E 3 3 0 Methyl butyrate UN1237 1B2, 150 T4, TP1 202 242 5L 60L B CD Methyl chloride or Refrigerant gas R 2.1 UN1063 2.1 N86, T50 306 304 314, 5 kg 100kg D 40 40. 315. Methyl chloride and chloropicrin mix > tures, see Chloropicrin and methyl 0. chloride mixtures. 3 Methyl chloride and methylene chlo 2.1 UN1912 2.1 N86, T50 306 304 314, Forbidden 150kg D 40 ride mixtures. 315. 6.1 Methyl chloroacetate UN2295 6.1,3 T14, TP2, TP13 None 201 243 1L 30L D Methyl chlorocarbonate, see Methyl 0 chlorotormate. -I Methyl chloroform, see 1,1,1-Tn chloroethane. Methyl chloroformate 6.1, UN1238 6.1,3, 1, B9, 814, 830, N34, None 226 244 Forbidden Forbidden D 21, 40, 8. T22, TP2, TP13, TP38, 100 TP44 Methyl chloromethyl ether 6.1 UN1239 6.1,3 1, 89, B14, B30, T22, None 226 244 Forbidden Forbidden D 40 TP2, TP13, TP38, TP44 UN2933 Methyl 2-chloropropionate 3 Ill 3 Bi, lB3, T2, TP1 150 203 242 60 L 220L A UN2299 Ill Methyl dichloroacetate 6.1 6.1 1B3,T4, TP1 153 203 241 60 L 220L A Methyl ethyl ether, see Ethyl methyl ether. Methyl ethyl ketone, see Ethyl methyl ketone. Methyl ethyl ketone peroxide, in solu Forbidden tion with more than 9 percent by 0 mass active oxygen. C
C) T1 Ca, C) m C 0
40 40 52
40 40
40
102
12,
(lOB)
Other 40,
40,
(10)
Vessel
stowage tjQfl
(1OA)
E E D D A B D A B 8 A D B A C
C
L L L L L L
kg
1L
air-
30 60
60 60 60L
only
220
220
and
150
)9B)
Forbidden Forbidden Forbidden Forbidden craft Forbidden Forbidden Forbidden
Cargo
limitations 73.27
(9)
1
L
L
175.75)
1L
§ 5L 5L 5L 5L
60
60
(9A)
Quantity (see
Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden
Forbidden
aircraft/rail Passenger
315,
315.
Bulk (8C)
241 314, 244 243 244 242 242 244
242 314, 242 244 243 242
244 244
(8)
73,***) bulk
Non-
1 —.-—
203 227 304 227 201 203 202 226 202 304 202 227 201 202.... 227 227
(
Packaging
(8A) (SB)
tions
Excep-
153 150 150 150 None 150 None 150 306 None 150 None None None None None
T50
TP1 TP2
TP1 TP1 TP1 TP1 TP1
T20, T20, T22,
T20,
N89, T20,
N34,
TP45
TP44 TP45 TP45
TP45 TP45
TP13,
T4, T2, T4. T4, T4, T4,
TABLE—Continued
T11,
832, 632, B30, 832,
832,
814,
832,
TP4,
TP38, TP38,
82, TP36, TP38,
TP36, TP38,
lB3,
182, 1B3, 1B2, lB2,
provisions
(7)
89,
B14, 814, 814, 814,
B14,
172.102)
B14,
81,
T20,
(
87,
TP13, TPI3, TP13,
TP13.
TP13,
B9, 89, B9, B9, 89,
89,
3,
Special
1,
2, 2,
2, 2,
N43,
2,
MATERIALS
TP2,
TP2,
TP2, TP2,
TP2,
3
3
(6)
2,1.
Label
Codes
6.1 3 2.1 6.1,3 6.1 3 3 6.1, 3 3 6.1,3 2.3, 3 4.3, 6.1,3 6.1,6
II II II
Ill
Ill
HAzARDOUS
(5)
PG
(4)
1064
172.101
Identi-
fication
Numbers UN2644 UN2300 UN1243 UN3023 UN2454 UN2480
UN2053 UN1246 UN1245 UN2400 UN UN1928 UN2477 UN1247 UN2606 § NA9206
3 3 3
3 3 3
or 2.1 6.1 6.1 6.1 6.1
6.1 2.3
4.3 6.1 6.1
(3)
Hazard
Division class
Forbidden
Forbidden Forbidden Forbidden
R
in
sta
ethyl
anhy
gas
no.s..
percent in
9
stabilized
names
peroxide,
descriptions
liquids,
than
monomer,
bromide,
Refrigerant ketone,
dicarboxylic
dichloride
oxygen.
(2)
(dry)
ketone
shipping
or
more
carbinol ketone
materials
Corrosive
active
with
mercaptopropionaldehyde,
proper
see
isobutyl
methacrylate
fluoride, magnesium
iodide formate isobutyl isobutyt isocyanate isopropenyl isovalerate isothiocyanate mercaptan
nitrate nitrite norbornene phosphonic nitramine orthosilicate
4-Thiapentanal.
mass
and
Hazardous
by 41. solution ether. bilized. see
dride,
Methyl Methyl Methyl 2-Methyl-5-ethylpyridine Methyl Methyl Methyl Methyl 2-Methyl-2-heptanethiol Methyl Methyl Methyl Methyl Methyl Methyl Methyl Methyl Methyl Methyl Methyl Methyl Methyl
0
(1)
bols
Sym- Methyl phosphonothioic dichioride, -U anhydrous, see Corrosive liquid, n.o.s,. (D
Methyl phosphonous dichloride, 6.1 I NA2845 6.1, 2, 89, 814, 816, B32, None...1227...,1244.... Forbidden Forbidden D 18 pyrophoric liquid. 4.2. B74, T20, TP4, TPI3, (D TP38, TP45 Methyl picric acid (heavy metal salts Forbidden a of). 0. Methylpropionate 3 UN1248 3 1B2,T4, TPI 150 202 242 5L 60 L B = Methylpropylether 3 UN2612 3 182, lP8, T7, TP2 150 202 242 5L 60 L F 40 3 3 0 Methylpropyl ketone UN1249 1B2,T4, TP1 150 202 242 5L 60 L B N Methyl sulfate, see Dimethyl sulfate 0 Methyl sulfide, see Dirnethyl sulfide 0. UN2533 153 0 Methyl trichloroacetate 6.1 Ill 6.1 183, T4, TP1 203 241 60 L 220 L A C Methyl trimethylol methane trinitrate Forbidden Methyl vinyl ketone, stabilized 6.1 UN1251 6.1,3, 1, B9, B14, 830, T22, None 226 244 Forbidden Forbidden B 40 8. TP2, TP13, TP38, TP44 0 Methylal 3 UN1234 3 1B2, 1P8,T7, TP2 None 202 242 5L 60 L F Methylamine, anhydrous 2.1 UN1O61 2.1 N87, T50 306 304 314, Forbidden 150 kg B 40 315. Methylamine, aqueous solution UN1235 3, 8 81, 182, T7, TP1 150 202 243 1L 5L E 52, 0(n 135. Cl, Methylamine dinitramine and dry Forbidden Ill 0 thereof. Ill salts Ill Methylamine nitroform Forbidden Ill 0 Methylamine perchlorate (dry) Forbidden Methylsmyl acetate 3 UN1233 3 81, 183, T2, TP1 150 203 242 60 L 220 L A 153 N-Methylaniline 6.1 UN2294 6.1 1B3,T4, TP1 203 241 60 L 220 L A 0. 153 A alpha-Methylbenzyl alcohol, liquid 6.1 UN2937 6.1 1B3,T4, TP1 203 241 60 L 220 L 3 153 A alpha-Methylbenzyl alcohol, solid 6.1 UN3438 Ill 6.1 88, 1P3, Ti, TP33 213 240 100 kg 200 kg Ill 150 3-Methylbutsn-2one 3 UN2397 3 1B2,T4, TP1 202 242 5L 60 L B N-Methylbutylamine 3 UN2945 3, 8 lB2, T7, TP1 150 202 243 IL 5L B 40 Methylchlorosilane 2.3 UN2534 2.3, 2, 89, 814, N34 None 226 314, Forbidden Forbidden D 17, 40 0 2.1, 315. -4 8. Methylcyclohesane 3 UN2296 3 81, 1B2,T4, TP1 150 202 242 5L 60 L B Methylcyclohexanols, flammable 3 UN2617 3 81, 183, T2, TP1 150 203 242 60 L 220 L A 3 3 Methylcyclohexanone UN2297 81, 183, T2, TP1 150 203 242 60 L 220 L A UN2298 3 Methylcyclopentane 1B2,T4, TP1 150 202 242 5L 60 L B D Methyldichloroarsine 6.1 NA1556 6.1 2, T20, TP4, TP13, None 192 None Forbidden Forbidden 0 40 TP38, TP45 Methyldichlorosilane 4.3 UN1242 4.3, 8, A2, A3, A7,B6, B77, None 201 243 Forbidden 1L D 21, 28, 3. N34, T14, TP2, TP7, 40, 49, TP13 100 Methylene chloride, see (0, Dichloromethane. Methylene glycol dinitrate Forbidden 2-Methylfuran UN2301 3 1B2,T4, TP1 150 202 242 5L 60 L F a-Methylglucoside tetranitrate Forbidden C a-Methylglycerol trinitrate Forbidden §172.101 HAzARDOus MATERIALS TABLE—Continued cm
(8) (9) (10) Vessel Packaging Quantity limitations stowage Sym- Hazardous materials Hazard Identi- 73,***) C descriptions Label Special provisions 1 (see 173.27 and bols and proper shipping names class or fication PG ( § Division Numbers Codes ( 172,102) — — 175.75) Excep- Non- Other tions bulk Bulk Passenger Cargo air- tjon aircrattirail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (88) (8C) (9A) (9B) (bA) (108)
5-Methylhexan-2-one 3 UN2302 Ill 3 81,183, T2, TP1 150 203.... 242.... 60 L 220L A Methylbydrazine 6.1 UN1244 6.1,3, 1, 87, 89, B14, B30, None ... 226 .... 244 Forbidden Forbidden 0 21, 40, 8. 877, N34, T22, TP2, 49, 52 TP13, TP38, TP44 and 100 4-Methylrnorpholine or n 3 UN2535 3, 8 B6, 182, T7, TPI 150 202 243 1L 5L B 40 methylmorpholine. Methylpentadienes 3 UN2461 II 3 1B2,T4, TP1 150 202 242 5L 60 L B 2-Methylpentan-2-ol 3 UN2560 Ill 3 81, 183, T2, TP1 150 203 242 60 L 220 L A Methylpentanes, see Hexanes 8 Methylphenyldichlorosilane 8 UN2437 II Tb, TP2, TP7, TP13 None 206 242 1L 30 L C II 40 1-Methylpiperidine 3 UN2399 II 3, 8 182, T7, TP1 150 202 243 1L 5L B 52. N.) Methyltetrahydrofuran 3 UN2536 3 82, T4, TP1 150 202 242 5L 60 L B Methyltrichloroailane 3 UN1250 3, 8 A7, B6, B77, N34, Tb, None 206 243 1L 5L B 40 II TP2, TP7, TPI3 alpha-Methylvaleraldehyde 3 UN2367 3 81, 182, T4, TP1 150 202 242 5L 60 L B
Mine rescue equipment containing II carbon dioxide, see Carbon diox II ide. Mines with bursting charge liP UN0136 II 1.1F 62 None Forbidden Forbidden 08 Mines with bursting charge biD UN0137 1.10 62 62 Forbidden Forbidden 03 •0 Mines with bursting charge 1.2D UN0138 1.20 62 62 03 Forbidden Forbidden C-) Mines with bursting charge 1.2F UN0294 II 1.2F 62 None Forbidden Forbidden 08 -n Mixed acid, see Nitrating acid, mix II tures etc. 0 Mobility aids, see Battery powered p. equipment or Battery powered ve hicle’. 0 Model rocket motor i.4C NA0276 1.4C 51 None 62 None Forbidden 75 kg 06 0 Model rocket motor 1.4S NA0323 1.4S 51 None 62 None 25 kg 100 kg 05 Molybdenum pentachloride 8 UN2508 Ill 8 188, P3, Ti, TP33 154 213 240 25 kg 100 kg C 40 Monochloroacetone (unstabitized) Forbidden Monochioroethylene, see Vinyl chlo C ride, stabilized. m Monoethanolamine, see Ethanol- 0. amine, solutions. Monoethylamine, see Ethylamine 0 Morpholine 8 UN2054 8, 3 A6, Tb, TP2 None 201.... 243.... 0.5L 2.5L A Morpholine, aqueous, mixture, see -U Corrosive liquids, no.s.. Motor fuel anti-knock compounds see CD
Motor fuel anti-knock mixtures. CD + Motor fuel anti-knock mixtures 6.1 UN1649 6.1 14, 151, B9, B90, T14, None 201 .... 244 .... Forbidden 30 L D 25, 40. TP2, TP13 0 Motor spirit, see Gasoline Muriatic acid, see Hydrochloric acid 0. Musk xylene, see 5-tert-Butyl-2,4,6- = trinitro-m-xylene. 0 Naphtha see Petroleum distilletes 0N n.o.s.. 4.1 Naphthalene, crude or Naphthalene, 4,1 UN1334 Ill Al, lB8, lP3, Ti, TP33 151 213.... 240.... 25 kg 100 kg A 0. refined. 0 Nephthalene diozonide Forbidden C A beta-Naphthylamine, solid 6.1 UN1650 II 6.1 lB8, 1P2, lP4, T3, TP33 153 212 242 25 kg 100 kg II beta-Naphthylamine solution 6.1 UN3411 6.1 182, T7, TP2 153 202 243 5L 60 L A 0 Ill 6.1 1B2,T7, TP2 153 203 241 60 L 220 L A 6.1 elpha-Naphthylamine 6.1 UN2077 Ill 1B8, P3, Ti, TP33 153 213 kg kg A CD Ill 240 100 200 Nephthalene, molten 4.1 UN2304 4.1 IB1, Ti, TP3 151 213 241 Forbidden Forbidden C 0 Naphthylamineperchlorate Forbidden Naphthylthiourea 6.1 UNl651 II 6.1 188, 1P2, 1P4, T3, TP33 153 212 242 25 kg 100 kg A II C,, Naphthylurea 6.1 UN1652 6.1 1B8, lP2, 1P4, T3, TP33 153 212 242 25 kg 100 kg A 0 Natural gases (with high methane CD rz content), see Methane, etc. (UN 1971, UN 1972). Neohexane, see Hexanes Neon, compressed 2.2 UN1065 2.2 306, 302 None 75kg 150 kg A 0. 307. 3 Neon, refrigerated liquid (cryogenic 2.2 UN1913 2.2 T75, TP5 320 316 .... None 50 kg 500 kg B liquid). New explosive or explosive device, see 173.51 and 173.56. 0 Nickel carbonyl 6.1 UN1259 6.1,3 None 198 None Forbidden Forbidden D 18,40 -l Nickel cyanide 6.1 UN1653 II 6.1 188, 1P2, lP4, N74, N75, 153 212 242 25 kg 100 kg A 52 T3, TP33 5,1 A Nickel nitrate UN2725 Ill 5.1 Al, 1B8,lP3, Ti, TP33 152 213 240 25 kg 100 kg 5.1 A Nickel nitrite 5.1 UN2726 Ill Al, lB8, lP3, Ti, TP33 152 213 240 25 kg 100 kg 56, 58 Nickel picrate Forbidden 6.1 153 Nicotine 6.1 UN1654 II 6.1 182 202 243 5L 60 L A Nicotine compounds, liquid, no.s, or 6.1 UN3144 A4 None 201 243 1L 30 L B 40 Nicotine preparations, liquid, no.5.. II 6,1 B 6.1 182, Tii, TP2, TP27 153 202 243 5L 60 L 40 6.1 B Ill 183, T7, TP1, TP28 153 203 241 60 L 220 L B 40 6.1 Nicotine compounds, solid, or UN1655 1B7,IPI, T6, TP33 None 211 242 5 kg 50 kg CU, no.s, 6.1 Nicotine preparations, solid, no.5.. 6.1 II 6.1 1B8, 1P2, 1P4, T3, TP33 153 212 242 25 kg 100 kg A Ill 1B8,lP3, Ti, TP33 153 213 240 100 kg 200 kg A Nicotine hydrochloride liquid or solu 6.1 UN1656 II 182 153 202 243 5L 60 L A I 0 tion. § 172.101 HAzARDOUSMATERIALSTABLE—Continued
(8) (9) (10) Vessel Hazard Identi- Packaging Quantity limitations stowage C Sym- Hazardous materials descriptions Label Special provisions i73.*) (see 173.27 and bols and proper shipping names class or fication PG ( § Division Numbers Codes ( 172.102) — — 175.75) Excep- Non- Bulk Other boris bulk Passenger Cargo air- tim, aircraft/rail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) )9B) (bA) (lOB)
6.1 1B3 153 203 241 60 L 220 L A Nicotine hydrochloride, solid 6.1 UN3444 II 6.1 lB8. 1P2, lP4, T3, TP33 153 212 242 25 kg 100 kg A 6.1 Nicotine salicytate UN1657 II 6.1 1B8, P2, lP4. T3, TP33 153 212 242 25 kg 100 kg A Nicotine sulfate solution 6.1 UN1658 II 6.1 182, T7, TP2 153 202 243 5L 60 L A 6.1 Ill 183, T7, TP2 153 203 241 60 L 220 L A Nicotine sulphate, solid 6.1 UN3445 II 6.1 1B8, 1P2, lP4, T3, TP33 153 212 242 25 kg 100 kg A 6.1 Nicotine tartrate 6.1 UN1659 II 1B8, 1P2, lP4. T3, TP33 153 212 242 25 kg 100 kg A Nitrated paper (unstable) Forbidden Nitrates, 5.1 inorganic, aqueous solution. 5.1 UN3218 58, 1B2, T4, TP1 152 202 242 1L 5L B 56. 58, n.o.s.. 133 5.1 58, 1B2,T4, TP1 152 203 241 2.5 L 30 L B 56, 58. E’,) 133 1’.J 5.1 Nitrates, inorganic, no.5 5.1 UN1477 II lB8, 1P2, 1P4, T3, TP33 152 212 240 5 kg 25 kg A 56. 58 5.1 Ill 188, lP3, Ti, TP33 152 213 240 25 kg 100 kg A 56, 58 Nitrateu of diazonium compounds Forbidden Nitrating mixtures, acid spent with 8 UN1826 8. 5 1 A7, Tb, TP2, TP13 None 158 243 Forbidden 2.5 L 0 40. 66 more than 50 percent nitric acid. Nitrating acid mixtures spent with not 8 UN1826 II 8 A7, B2, 182, T8, TP2 None 158 242 Forbidden 30 L 0 40 more than 50 percent nitric acid. ‘0 Nitrating acid mixtures with more 8 UN1796 8. 5 1 A7, Tb, TP2, TP13 None 158 243 Forbidden 2.5 L 0 40. 66 than 50 percent nitric acid. 0 Nitrating acid mixtures with not more 8 UN1796 II 8 A7, 82. 182, T8, TP2, None 158 242 Forbidden 30 L D 40 than 50 percent nitric acid. II TP13 C-) Nitric acid ofher than red fuming, with 8 UN2031 8, 5.1 A6, 82, 847, 853, 182. None 158 242 Forbidden 30 L 0 66, 74, at least 65 percent, but not more 1P15, T8, TP2 89, 90 than 70 percent nitric acid, II Nitric acid, other than red fuming, 8 UN2031 8 A6, 82, B47, 853, 1B2, None ... 158 .... 242 Forbidden 30L 0 44, 66, with less than 65 percent nitric lPb5, T8, TP2 74, 89, acid. 90 Nitric acid other than red fuming, with 8 UN2031 8. 5.1 A3, 847. 853, Tb, TP2. None ... 158 .... 243 Forbidden 2.5L D 44, 66. more than 70 percent nitric acid. TP12, TP13 89, 90, C 110, m 111 0. Nitric acid other than red fuming with 8 UN2031 It 8 A6. 82, 847, B53, 182. None ... 158 .... 242 1L 30L 0 not more than 20 percent nitric T8, TP2 0 acid. + Nitric acid, red fuming 8 UN2032 8, 5.1, 2, B9, 832, T20, TP2, None ... 227 .... 244 Forbidden Forbidden D 40, 66, 6.1. TP13, TP38, TP45 74, 89, 13 9° CD Nitric oxide, compressed 2,3 UN1660 2.3, 1, 877 None ... 337 .,.. None Forbidden Forbidden D 40, 89, CD 5.1, 90 8. 0 Nitric oxide and dinitrogen tetroxide 2.3 UN1975 2.3, 1, 877 None 337 .... None Forbidden Forbidden D 40, 89, mixturesor Nitric oxide and nitro 5.1, 90 0. gen dioxide mixtures. 8. = G Nitriles, flammable, toxic, no.5 3 UN3273 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L 8 40, 52 0 II 3, 6.1 182, Til, TP2, TP13, 150 202 243 1L 60 L B 40, 52 N TP27 0 G Nitriles, toxic, flammable, no.5 6.1 UN3275 5, T14, B 0. II 6.1,3 TP2, TPI3, None 201 243 1L 30 L 40, 52 0 TP27 B C 82, TP2, TP13, 153 L II 6.1,3 Til, 202 243 5L 60 40, 52 (n G TP27 Nitriles, toxic, liquid, no.5 6.1 UN3276 6.1 5, T14, TP2, TP13, None 201 243 1L 30 L B 52 TP27 0 B 6.1 CD 1B2,Til, TP2, TP27 153 202 243 5L 60 L 52 6.1 G Ill 83, T7, TP1, TP28 153 203 241 60 L 220 L A 52 6.1 0 Nitriles, toxic, solid, no.s 6.1 UN3439 6.1 lB7, IP1, T6, TP33 None 211 242 5 kg 50 kg D 52 (I, B II 6.1 lB8, 1P2, lP4, T3, TP33 153 212 242 25 kg 100 kg 52 Lfl Ill 5.1 88, 1P3, Ti, TP33 153 213 240 100 kg 200 kg A 52 0 II 152 Nitrites, inorganic, aqueous solution, 5.1 UN3219 181, T4, TPI 202 242 IL 5L B 46, 56, CD n.o.s.. 5.1 58, 133 B c.z Ill 82, T4, TP1 152 203 241 2.5 L 30 L 46, 56, 5.1 58, 133 152 0. Nitrites, inorganic, n.o.s 5.1 UN2627 6.1 33, lB8, 1P2, 1P4,T3, 212 None 5 kg 25 kg A 46, 56, TP33 58, 133 3 153 3-Nitro-4-chlorobenzotrifluoride 6.1 UN2307 II 182, T7, TP2 202 243 5L 60 L A 40 6-Nitro-4-diazotoluene-3-xulfonic acid Forbidden (dry). Nitro isobutane triol trinitrate Forbidden II -I0 N-Nitro-N-mefhylglycolamide nitrate Forbidden II 2-Nitro-2-methylpropanol nitrate Forbidden Nitro urea liD UN0147 lID None 62 None Forbidden Forbidden 10 N-Nitroaniline Forbidden + Nitroanilines (0-; m-; p-;) 6.1 UN1661 6.1 88, P2, 1P4, T3, TP33 153 212 242 25 kg 100 kg A Nitroanisole, liquid 6.1 UN2730 Ill 6.1 183, T4, TPI 153 203 241 60 L 220 L A Nitroanisoles, solid 6.1 UN3458 Ill 6.1 1B8, 1P3, Ti, TP33 153 213 240 100 kg 200 kg A 6.1 6.1 + Nitrobenzene UN1662 II lB2, T7, TP2 153 202 243 5L 60 L A 40 m-Nitrobenzene diazonium per- Forbidden chlorate. II 154 A Nitrobenzenesulfonic acid 8 UN2305 8 B2, 84, 1B8, 1P2, 1P4, 202 242 1L 30 L II II T3, TP33 ‘0, Nitrobenzol, see Nitrobenzene 5-Nitrobenzotriazol liD UN0385 liD None 62 None Forbidden Forbidden 10 Nitrobenzotrifluorides, liquid 6.1 UN2306 6.1 1B2,T7, TP2 153 202 243 5L 60 L A 40 Nitrobenzotrifluorides, solid 6.1 UN3431 6.1 188, 1P2, P4, T3, TP33 153 212 242 25 kg 100 kg A 40 A 0 Nitrobromobenzenes, liquid 6.1 UN2732 Ill 6.1 183, T4, TP1 153 203 241 60 L 220 L §172.101 HAzARDous MATERIALSTABLE—Continued Go)
(8) (9) (10) Vessel Hazard Identi- Packaging Quantity limitations stowage 0 Sym- Hazardous materials descriptions Label Special provisions (173.***) (see §173.27 and bols and proper shipping names class or tication PG Division Numbers Codes (172.102) — 175.75) Excep- Non- Other tions bulk Bulk Passenger Cargo air- tion aircraft/rail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (88) (8C) (9A) (96) (1QA) (lOB)
Nitrobromobenzenes, solid 6.1 UN3459 III 6.1 lBS. 1P3, Ti, TP33 153 213 .... 240 .... 100 kg 200kg A Nitrocellulose, dry or wetted with less liD UN0340 II liD None 62 None Forbidden Forbidden 13 27E than 25 percent water (or alcohol), by mass. Nitrocellulose, with not more than 4.1 UN2557 4.1 44 151 212 .... None 1 kg 15kg 0 28, 36 12.6 percent, by dry mass misture with or without plasticizer, with or without pigment. Nitrocellulose membrane filters, with 4.1 UN3270 II 4.1 43,A1 151 212 .... 240 .... 1kg 15kg 0 not more than 12.6% nitrogen, by dry mass. Nitrocellulose, plasticized with not 1.3C UN0343 II 1.3C None ... 62 None Forbidden Forbidden 10 less than 18 percent plasticizing substance, by mass. Nitrocellulose, solution, flammable 3 UN2059 3 198, Til, TP1, TP8, None... 201 .... 243.... 1L 30L B with not more than 12.6 percent ni TP27 trogen, by mass, and not more than 55 percent nitrocellulose. II 3 198, 162, T4, TP1, TP8 150 202 242.... 5L 60L B III 3 198, B1, lB3, T2, TP1 150 203 242.... 60L 220L A Nitrocellulose, unmodified or plasti 1.10 UN0341 II liD None 62 None Forbidden Forbidden 13 27E cized with less than 18 percent C) plasticizing substance, by mass. -I, Nitrocellulose, wetted with not less l.3C UN0342 II 1.3C None 62 None Forbidden Forbidden 10 than 25 percent alcohol, by mass. C) Nitrocellulose with alcohol with not 4.1 UN2556 II 4.1 151 212 None I kg 15 kg D 28, less than 25 percent alcohol by 36 mass, and with not more than 12.6 percent nitrogen, by dry mass. Nitrocellulose with water with not less 4.1 UN2555 II 4.1 151 212 None 15 kg 50 kg E 28, than 25 percent water by mass. 36 Nitrochlorobenzene, see Chloronitrobenzenes etc. 0 Nitrocresols, liquid 6.1 UN3434 III 6.1 1B3,T4, TP1 153 203 241 60 L 220L A m Nitrocresols, solid 6.1 UN2446 III 6.1 1B8,lP3, Ti, TP33 153 213 240 100 kg 200kg A 0. Nitroethane 3 UN2842 Ill 3 61, 163, T2, TP1 150 203 242 60 L 220L A Nitroethyl nitrate Forbidden 0 Nitroethylene polymer Forbidden Nitrogen, compressed 2.2 UN1066 2.2 . 306, 302 .... 314, 75 kg 150 kg A 307. 315. Nitrogen dioxide, see Dinitrogen te- troxide. 5 Nitrogen fertilizer solution, see Fer- tilizer ammoniating solution etc. Nitrogen peroxide, see Dinitrogen te- troxide. Nitrogen, refrigerated liquid cryogenic 2.2 UN1977 2.2 T75, TP5 320 316 .... 318 .... 50 kg 500 kg D liquid. Nitrogen tetroxide and nitric oxide mixtures, see Nitric oxide and ni- trogen tetroxide mixtures. ao Nitrogen tetroxide, see Dinitrogen te- C troxide. Nitrogen trichloride Forbidden Nitrogen triftuoride 2.2 UN2451 2.2, None ... 302 .... None 75 kg 150 kg D 40 0 5.1. m Nitrogen triiodide Forbidden Nitrogen triiodide monoamine Forbidden — Nitrogen trioxide 2.3 UN2421 2.3, 1 None ... 336 .... 245 .... Forbidden Forbidden D 40, 89, 51, 90
Nitroglycerin, desensitized with not liD UN0143 II liD, 125 None 62 None Forbidden Forbidden 13 216 less than 40 percent non-volatile 6.1. water insoluble phlegmatizer, by mass. Nitroglycerin, liquid not desensitized Forbidden 3 Nitroglycerin mixture, desensitized, 3 UN3343 3 129 None 214 None Forbidden Forbidden D liquid, flammable, no.x. with not more than 30 percent nitroglycerin, by mass Q Nitroglycerin mixture, desensitized, 3 UN3357 3 142 None 202 243 5 L 60 L E —4 liquid, no.s. with not more than 30% nitroglycerin, by mass. Nitroglycerin mixture, desensitized, 4.1 UN3319 II 4.1 118 None None None Forbidden 0.5 kg E solid, no.s. with more than 2 per cent but not more than 10 percent nitroglycerin, by mass. Nitroglycerin, solution in alcohol, with 3 UN3064 II 3 N8 None 202 None Forbidden 5 L B more than 1 percent but not more than 5 percent nitroglycerin. Nitroglycerin, solution in alcohol, with liD UN0144 II liD None 62 None Forbidden Forbidden 10 21E more than 1 percent but not more cm than 10 percent nitrogylcerin. Nitroglycerin solution in alcohol with 3 UN1204 II 3 1B2,N34 150 202 None 5 L 60 L B not more than 1 percent nitroglyc erin. Nitroguanidine nitrate Forbidden — §172.101 HazARDous MATERIALsTABLE—Continued c0)
(8) (9) (10) Vessel Hazard Identi- Packaging Quantity limitations stowage C Sym- Hazardous materials descriptions Label Special provisions 173.) (see 173.27 and bols and proper shipping names class or tication PG ( § Division Numbers Codes ( 172.102) — 175.75) Excep- Non- 01a-Li Other Bulk Passenger c tions bulk Cargo air- aircraWrail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (98) (bA) (lOB)
Nitroguanidine or Picrite, dry or liD UN0282 II liD None 62 None Forbidden Forbidden 10 wetted with less than 20 percent water; by mass.
Nitroguanidine, wetted or Picrite, 4.1 UN1336 I 4.1 23, A8, A19, A20, N41 None ... 211 None 1kg 15kg 6 28, 36 wetted with not less than 20 per cent wafer, by mass. l-Nitrohydantoin Forbidden
Nitrohydrochloric acid 8 UN1798 I 8 A3, Blo, N41, Tb, TP2, None ... 201 243 Forbidden 2.5 L D 40, 66, TP13 74, 89, 90 Nitromannite (dry) Forbidden Nitromannite, wetted, see Mannitol hesanitrate, etc. Nitromethane 3 UN1261 3 150 202 None Forbidden 60 L A Nitromuriatic acid, see Nitrohydrochloric acid. Nitronaphthalene 4.1 UN2538 Ill 4.1 Al, 1B8, 1P3, Ti, TP33 151 213 240 25kg 100kg A + Ill Nitrophenola (o-; m-; p-;) 6.1 UN1663 6.1 188, 1P3, Ti, TP33 153 213 240 100 kg 200 kg A m-Nitrophenyldinitro methane Forbidden 4-Nitrophenylhydrazine, with not less 4.1 UN3376 4.1 162, A8, Ai9, A20, N4i None 211 None Forbidden 15 kg E 28, 36 than 30 percent water; by mass. Ill Nitropropanes 3 UN2608 3 81, lB3, T2, TP1 150 203 242 60L A 220L C-) p-Nitrosodimethylaniline 4.2 UN1369 II 4.2 Ai9, A20, 1B6, 1P2, N34, None 212 241 15kg 50kg D 34 I1 T3, TP33 Nitrostarch, dry or wetted with UN0146 II less liD lID None 62 None Forbidden Forbidden 10 C-) than 20 percent water, by mass. Nitrostarch, wetted with not less than 4.1 UN1337 4.1 23, A8, A19, A20, N4l None 211 None 1kg 15kg D 28, 36 20 percent water; by mass. Nitrosugars (dry) Forbidden Nitrosyl chloride 2.3 UN1069 2.3, 8 3, Bi4 None 304 .... 314, Forbidden Forbidden D 40 315. Nitrosylsulfuric acid, liquid 8 UN2308 8 A3, A6,A7, B2, 1B2, 154 202.... 242.... 1L 30L D 40, 66, N34, T8, TP2 74, 89, C 90 m Nitroaylsulphuric acid, solid 8 UN3456 8 lB8, 1P2, 1P4, T3, TP33 154 212.... 240.... 15 kg 50kg D 40, 66, 0. 74, 89, 90 0 Nitrotoluenea, liquid 6.1 UN1664 II 6.1 lB2, T7, TP2 153 202.... 243.... 5L 60L A Nitrotoluenee, solid 6,1 UN3446 6.1 88, 1P2, 1P4,T3, TP33 153 212 242 25 kg 100 kg A - Nitrotoluidinee (mono> 6.1 UN2660 III 6.1 88, 1P3, Ti, TP33 153 213 240 100 kg 200 kg A -o Nitrotriazolone or NTO liD UNO490 liD None 62 None Forbidden Forbidden 10 CD Nitrous oxide 2.2 UN1O7O 2.2, Al 4 306 304 314, 75 kg 150 kg A 40 5.1. 315. CD Nitrous oxide, refrigerated liquid 2.2 UN2201 2.2, B6, T75, TPS, TP22 None 304 314, Forbidden Forbidden B 40 5.1. 315. 0 Nitroxylenes, liquid 6.1 UN1665 6.1 1B2,T7, TP2 153 202 243 5L 60 L A 0. Nitroxylenes, solid 6,1 UN3447 6.1 88, 1P2, 1P4, T3, TP33 153 212 242 25 kg 100 kg A Nitroxylol, see Nitroxylenes 0 Nonanes 3 UN1920 Ill 3 Bi, B3, T2, TPI 150 203 242 60 L 220 L A N Non-flammable gas, no.s., see Com 0 pressed gas, etc. or Liquefied gas, 0. etc. 0 Nonlique fled gases, see Compressed C gases, etc. Nonlique fled hydrocarbon gas, see Hydrocarbon gas mixture, com 0 pressed, no.s., 8 CD UN1799 Nonyltrichiorosilane S A7, 82, 86, N34, Tb, None ... 206 .... 242 .... Forbidden 30 L C 40 0 TP2, TP7, TP13 Nordhausen acid, see Sulfuric acid, Cl, fuming etc. 0 2,5-Norbornadiene, stabilized, see CD Bicyclo [2,2,1] hepta-2,5-diene, stabilized. UN1800 Octadecyltrichlorosilane 8 II 8 A7, 82, 86, N34, Tb, None 206 242 Forbidden 30 L C 40 II TP2, TP7, TPI3 0. 3 UN2309 3 Octadiene 81, 182, T4, TPI 150 202 242 5L 60 L B 3 1,7-Octadine-3,5-diyne-l,8- Forbidden dimethoxy-9-octadecynoic acid. UN2422 Octafluorobut-2-ene or Refrigerant 2.2 2.2 None 304 314, 75 kg 150 kg A gas R 1318. 315. UN1976 0 Octafluorocyclobutane, or Refrigerant 2.2 2.2 T50 None 304 314, 75 kg 150 kg A -I gas RC 318. 315. UN2424 Octaftuoropropaneor Refrigerant gas 2.2 2.2 T50 None 304 314, 75 kg 150 kg A R 218. 315. UN1262 Octanes 3 3 82, T4, TP1 150 202 242 5L 60 L B Octogen, etc. see Cyclotetramethylene tetranitramine, etc.. II
Octolite or Octol, dry or wetted with liD I UN0266 liD None...162 INone Forbidden Forbidden 110 less than 15 percent wate, by mass. Octonal liD UN0496 None 62 None Forbidden Forbidden 10 C0 Octyl aldehydes 3 UN1191 Ill 3liD 81, lB3, T2, TP1 150 203 242 60 L 220 L A Octyltrichlorosilsne 6 UN18O1 II 8 A7, 82, 86, N34, Tb, None 206 242 Forbidden 30 L C 40 TP2, TP7, TP13 Oil gas, compressed 2.3 UN1071 2.3, 6 None 304 314, Forbidden 25 kg C 40 C 2.1. 315. §172.101 HAzRDous MATERIALSTABLE—Continued cm
(8) (9) (10) Vessel Hazard Identi- Packaging Quantity limitations stowage C Sym- Hazardous materials descriptions Label Special provisions (I73.***) (see §173.27 and bols and proper shipping names class or fication PG Division Numbers Codes ( 172.102) — 175.75) Excep- Non- Other tions bulk Bulk Passenger Cargo air- fj aircraWrail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (1OA) (lOB)
Oleum, see Sulfuric acid, fuming Organic peroxide type A, liquid or Forbidden solid. G Organic peroxide type B, liquid 5.2 UN31O1 II 5.2, 1 53 152 225 None Forbidden Forbidden D 12, 40, 52, 53 0 Organic peroxide type B, liquid, tem 5.2 UN3II1 II 5.2, 1 53 None 225 None Forbidden Forbidden B 2, 40, perature controlled. II 52, 53 0 Organic peroxide type B, solid 5.2 UN3102 5.2, 1 53 152 225 None Forbidden Forbidden B 12, 40, 52, 53 0 Organic peroxide type B, solid, tem 5.2 UN3112 5.2, 1 53 None 225 None Forbidden Forbidden D 2, 40, perature controlled. 52, 53 0 Organic peroxide type C, liquid 5.2 UN3103 5.2 152 225 None 5L 1OL B 12, 40, 00 II 52, 53 Organic peroxide type C, liquid, tem 5.2 UN3113 5.2 0 II None 225 None Forbidden Forbidden D 2, 40, perature controlled. II 52, 53 5.2 G Organic peroxide type C, solid UN3104 II 5.2 152 225 None 5 kg 10kg B 12, 40, 52, 53 G II Organic peroxide type C, solid, tem 5.2 UN3114 5.2 None 225 None Forbidden Forbidden B 2, 40, perature controlled. 52, 53 G Organic peroxide type D, liquid 5.2 UN3105 5.2 152 225 None 5L 1OL B 12, 40, 52, 53 C-, G Organic peroxide type D, liquid, tem 5.2 UN3115 5.2 None 225 None Forbidden Forbidden B 2, 40, -n perature controlled. 52, 53 0 Organic peroxide type D, solid 5.2 UN3106 5.2 152 225 None 5 kg 10kg B 12, 40, C) 52, 53 G Organic peroxide type D, solid, tem 5.2 UN3116 5.2 None 225 None Forbidden Forbidden D 2, 40, perature controlled. 52, 53 0 Organic peroxide type B, liquid 5.2 UN3107 5.2 152 225 None 10 L 25L B 12, 40, 52, 53 G Organic peroxide type E, liquid, tem 5.2 UN3117 5.2 None 225 None Forbidden Forbidden D 2, 40, perature controlled. 52, 53 0 Organic peroxide type E, solid 5.2 UN3108 5.2 152 225 None 10 kg 25kg B 12, 40, C 52, 53 m 0 Organic peroxide type E, solid, tem 5.2 UN3118 5.2 None 225 None Forbidden Forbidden D 2,40, 0. perature controlled. 52, 53 Organic peroxide F, 5.2 0 0 type liquid 5.2 UN3109 1P5 152 225 .... 225 10 L 25L D 12, 40, 52, 53 LI)CO)
‘3 Organic peroxide type F, liquid, tem 5.2 I UN3119 5.2 P5 None 225.1225.... Forbidden I Forbidden D 2, 40, perature controlled. ‘3 52, 53 Organic peroxide type F, solid 5.2 UN311O 5.2 TP33 152 225 225 10 kg 25 kg V 12, 40,
‘3 52, 53 Organic peroxide type F, solid, tem 5.2 UN3120 5.2 TP33 None 225 225 Forbidden Forbidden V 2,52, CD perature controlled. 53 D 0 D Organic phosphate, mixed with com 2.3 NA1955 2.3 None 334 None Forbidden Forbidden 40 pressed gas or Organic phosphate 0. compound, mixed with compressed = gas or Organic phosphorus com 0 pound, mixed with compressed N gas. 0 Organic pigments, self-heating 4.2 UN3313 4.2 1B8, 1P2, 1P4, 0. T3, TP33 None 212 241 15 kg 50 kg C 0 Ill 4.2 88, 1P3, Ti, TP33 None 213 241 25 kg 100 kg C C G Organoarsenic compound. liquid, 6.1 UN3280 6.1 5, T14, TP2, TP13, None 201 242 iL 30 L B C., n.o.s.. TP27 B 6.1 182, Ti 1, TP2, TP27 153 202 242 5L 60 L 0 Ill 6.1 183, T7, TP1, TP28 153 203 241 60 L 220 L A 6.1 CD ‘3 Organoarsenic compound, solid, 6.1 UN3465 1B7, IP1, T6, TP33 None 211 242 5 kg 50 kg B no.5.. 0 6.1 88, 1P2, 1P4,T3, TP33 153 212 242 25 kg 100 kg B Ill 6.1 88, P3, Ti, TP33 153 213 240 100 kg 200 kg A 3, Organochlorine pesticides liquid, 3 UN2762 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L B 40 0 flammable, toxic, flash point less CD than 23 degrees C. B cc 3. 6.1 1B2,Tii, TP2, TP13, 150 202 243 1L 60 L 40 TP27 B Organochlorine pesticides, liquid, 6.1 UN2996 6.1 T14, TP2, TP13, TP27 None 201 30 L 243 1L B toxic. Ill 6.1 1B2, Til, TP2, TP13, 153 202 243 5L 60 L I. TP27 6.1 83, T7, TP2, TP28 153 203 241 60 L 220 L A 40 V Organochlorine pesticides, liquid, 6.1 UN2995 6.1.3 T14, TP2, TP13, TP27 None 201 243 1L 30 L B 40 0 toxic, flammable, flash point not -I less than 23 degrees C. II 6.1,3 lB2, Til, TP2, TP13, 153 202 243 5L 60 L B 40 TP27 18 6.1,3 81, 83, T7, TP2, TP28 153 203 242 60 L 220 L A 40 Organochlorine pesticides, solid, 6.1 UN2761 6.1 1B7, P1, T6, TP33 None 211 242 5 kg 50 kg A 40 toxic. 6.1 II 1B8, 1P2, P4, T3, TP33 153 212 242 25 kg 100 kg A 40 6.1 Ill 188, P3, Ti, TP33 153 213 240 100 kg 200 kg A 6.1 40 ‘3 Organometallic compound, toxic, liq 6.1 UN3282 T14, TP2, TP13, TP27 None 201 242 IL 30 L B uid, n.o.s.. 6.1 II 6.1 182, T11, TP2, TP27 153 202 242 5L 60 L B ‘3 Ill 6.1 1B3,T7, TP1, TP28 153 203 241 60 L 220 L A Organometallic compound, toxic, 6.1 UN3467 1B7, P1, T6, TP33 None 211 242 5 kg 50 kg 6 solid, no.s.. II 6.1 188, 1P2, P4, T3, TP33 153 212 .... 242 25 kg 100kg B C III 6.1 1B8, P3, Ti, TP33 153 213 .... 240 100 kg 200kg A 0 -F’ C) C0) C.) 0 0 m 0. 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 40 52. 143 40, 40, 40, Other 40, (lOB) 40, 40. 40, 40, 40, 40, 40, 40, 40, 40. 40, (10) Vessel stowage tion (1OA) D D E E D 6 D 6 D D C E E E C 6 8 6 E E E B iL 1L 5L 5L air- 60L 60L 30L only 50kg 50kg 50kg 50kg and 100kg 100kg 100kg 100kg (9B( Forbidden Forbidden Forbidden Forbidden craft Forbidden Forbidden Forbidden Cargo limitations (9) 173.27 175.75) kg kg kg kg kg kg kg kg IL § 1L 5L SL IL 15 15 15 15 25 25 25 25 (9A) Quantity (see Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden aircraftlrail Passenger Bulk (8C) 244 244 244 242 243 242 244 244 — 243 242 244 242 242 242 241 242 242 242 241 243 242 241 .... (8) bulk (86) Non- 173,***) — 181 181 187 187 202 203 201 201 203 202 212 203 211 211 212 213 212 211 213 212 213 201 ( Packaging ... (8A) lions Escep- — None None None None None None None None None None None 151 151 None None None 151 None 151 None None None TP7 TP7 TP7 TP7 TP7 TP7 TP7 TP7 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP27 TP33 TP33 TP13, TABLE—Corttinued Ti, TP2, T3, TP2, T3, TP2, T3, TP2, TP2, TI, TP2, T3, TP2, TP2, Ti, Ti, TP7, TP7, TP7, TP7, TP7, TP2, provisions T7, T7, 84, (7) 186, 188, lB4, 1B4, 186, 1B6, 186, T21, T21, T13, T13, T9, T9, T21, T21, 714, (172.102) IB1,T7, 1P4, 1B2, 12,17, 5, 811, Bil, N40, N40, T9, N40, Special 811, 182, 181, MATERIALs 3 3 3 3 (6) 4.3. 4.3. 4.1. 4.1, 41. 4.2. 4.2. 4.2. Label Codes 4.2 4,2, 4.3 4.3, 4.3 4.3, 4.3 4.3, 4.2 4.2 4.3 4.2, 4.3 4.2 4.3, 4.3, 4.3 4.3, 4.3, 6.1, 4.3, 4.3, It II II II Ill Ill Ill Ill Ill Ill HAzARDOus (5) PG (4) 172.101 Identi- fication UN3392 Numbers UN3394 UN3398 UN3391 UN3399 UN3393 UN3395 UN3400 UN3396 UN3397 UN3279
§ or 4.2 4.2 4.3 4.2 4.2 4.3 4.2 4.3 4.3 6.1 4.3 (3) Hazard Division class self- solid, solid, solid, solid, solid, toxic, liquid. liquid, liquid, liquid, solid, names descriptions compound, substance, substance, substance, substance, substance. substance, substance. substance, substance, (2) flammable. flammable. self-heating. shipping substance, water-reactive. materials water-reactive. no.s.. proper and Hazardous pyrophoric. pyrophoric, pyrophoric. water-reactive. pyrophoric, heating. water-reactive, water-reactive. water-reactive, water-reactive, flammable, Organometallic Organometallic Organornetallic Organometallic Organometallic Organometallic Organometallic Organometallic Organometallic Orgariometallic Organophosphorus G G 0 G G G G G G G (1) bols Sym- II 6.1, 3 1B2,Til, TP2, TP13, 153 202 243 SL 60 L 8 40 - TP27 G Organophosphorus compound, toxic, UN3278 6.1 5, T14, TP2, TP13, None 201 243 IL 30 L B CD liquid, n.o.s.. TP27 CD 6.1 B II 1B2,Til, TP2, TP27 153 202 243 SL 60 L 6.1 Ill 83, T7, TP1, TP2B 153 203 241 60 L 220 L A G 6.1 0 Organophosphorus compound, toxic, UN3464 1B7, IPI, T6, TP33 None 211 242 5 kg 50 kg B solid, no.s.. 6.1 0. II 6.1 1B8, 1P2, 1P4,T3, TP33 153 212 242 25 kg 100 kg B = Ill 3, 6.1 1B8, 1P3, Ti, TP33 153 213 240 100 kg 200 A 0 kg N Organophosphorus pesticides, liquid, 3, UN2784 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L B 40 a flammable, toxic, flash poinf less a. than 23 degrees C. 3, 6.1 0 II lB2, Til, TP2, TP13, 150 202 243 1L 60 L B 40 C 6.1 TP27 Cl, Organophosphorus pesticides, liquid, 6.1 UN3018 N76, T14, TP2, TP13, None 201 243 L B II 6.1 1L 30 40 toxic. TP27 0 182, N76, Til, TP2, 153 202 243 5L 60 L B 40 CD TP13, TP27 Ill 6.1 1B3, N76, T7, TP2, TP28 153 203 241 60 L 220 L A 40 a 6.1 (I, Organophosphorus pesticides, liquid, UN3017 6.1,3 N76, Ti4, TP2, TPI3, None 201 243 IL 30 L B 40 toxic, flammable, flash point not TP27 acn less than 23 degrees C. B CD Ill 182, N76, Til, TP2, 153 202 243 5L 60 L 40 c) 6.1,3 TPI3, TP27 -A 81, 183, N76, T7, TP2, 153 203 242 60 L 220 L A 40 6.1,3 TP28 a. UN2783 Organophosphorus pesticides, solid, 6.1 lB7, IP1, N77, T6, TP33 None 211 242 S kg 50 kg A 40 3 toxic. 6.1 II IB8, 1P2, lP4, N77, T3, 153 212 242 25 kg 100 kg A 40 TP33 6.1 6.1 Ill lBfl, 1P3,N77, Ti, TP33 153 213 240 100 kg 200 kg A 40 UN2768 6.1 0 Organotin compounds, liquid, no.5. A3, N33, N34, T14, TP2, None 201 243 1L 30 L B 40 -l TP13, TP27 II 6.1 A3, 182, N33, N34, Til, 153 202 243 SL 60 L A 40 6.1 TP2, TPI3, TP27 Ill 6.1 183, T7, TP2, TP28 153 203 241 60 L 220 L A 40 UN3146 Organotin compounds, solid, no.s. 6.1 AS, 187, IP1, T6, TP33 None 211 242 5 kg 50 kg B 40 II 6.1 188, P2, P4, T3, TP33 153 212 242 25 kg 100 kg A 40 Ill 6.1 188, 1P3, Ti, TP33 153 213 240 100 kg 200 kg A 40 UN2787 Organotin pesticides, liquid, flam 3 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L B 40 mable, toxic, flash point less than 23 degrees C. II 3, 6.1 182, Til, TP2, TP13, ISO 202 243 1L 60 L B 40 TP27 UN3020 II Organotin pesticides, liquid, toxic 6.1 6.1 T14, TP2, TP13, TP27 None 201 243 1L 30 L B 40 6.1 182, Til, TP2, TP13, 153 202 243 SL 60 L B 40 TP27 C
III 6.1 1B3,T7, TP2, TP28 153 I 203 .... I 241 60 L 220 L I A 40 — § 172.101 R,z,RDous MATERIALsTABLE—Continued C0
(8) (9) (10) Vessel Packaging Quantity limitations stowage Sym- Hazardous Hazard Identi- 73***) C materials descriptions Label Special provisions 1 (see 17327 and bols and proper shipping names class or ttcstion ( § Division Numbers Codes ( 172.102> — 175.75> Escep- Non- Other tions bulk Bulk Passenger Cargo air- aircraft/rail craft only
(1) (2) (3> (4> (5) (6) (7) (8A( (88) (8C( (9A( (98) (bA> (108)
Organotin pesticides, liquid, toxic, 6.1 UN3019 6.1,3 T14, TP2, TP13, TP27 None ... 201 .... 243 IL 30L B 40 flammable, flash point not less than 23 degrees C. II lB2, Til, TP2, TP13, 153 6.1,3 202 243 5L 60 L B 40 TP27 18 6.1, 3 Bi, lB3, T7, TP2, TP28 153 203 242 60 L 220 L A 40 Organotin pesticides, solid, toxic 6.1 UN2786 6.1 lB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40 II 6.1 1B8, 1P2, lP4, T3, TP33 153 212 242 25 kg 100 kg A 40 Ill 6.1 188, lP3, Ti, TP33 153 213 240 100 kg 200 kg A 40 Orthonitroaniline, see Nitroanilines etc. 6.1 Osmium tetroxide 6.1 UN2471 A8, 87, IP1, N33, N34, None 211 Ill 242 5 kg 50 kg B 40 T6, TP33 DO Other regulated substances, liquid, 9 NA3082 9 1B3,T2, TP1 155 203 241 No limit No limit A no.5.. 9 9 DO Other regulated substances, solid, NA3077 Ill 854, 1B8,lP2, Ti, TP33 155 213 240 No limit No limit A no.5.. 0 Oxidizing liquid, corrosive, no.5 5.1 UN3098 5.1,8 62, A6 None 201 244 Forbidden 2.5 L 0 13, 56, 58, 106, 138 II 5.1,8 62, 181 None 202 .... 243 1L 5L B 13, 34, C) 56, 58, Tl 106, 138 C) III 5.1,8 62, 82 152 203 .... 242 2.5 L 30L B 13, 34, 56, 58, 106, 138 C S Oxidizing liquid, n.o.s 5.1 UN3139 I 5.1 62, 127, A2, A6 None ... 201 .... 243 Forbidden 2.5L D 56, 58, 106, 138 II 5.1 62, 127, A2, 1B2 152 202 .... 242 IL 5L B 56, 58, 106, m 138 C0. III 5.1 62, 127, A2, 182 152 203 .... 241 2.5 L 30L B 56, 58, 106, 0 138 z O Oxidizing liquid toxic, no.5 5.1 UN3099 I 5.1, 62, AS None ... 201 .... 244 .... Forbidden 2.5 L D 56, 58, 6.1. 106, 138 5.1, 62, lBl 152 202 .... 243 .... 1 L 5 L B 56, 58, 5 6.1. 95, (D 106, 0 138 III 5.1, 62, 162 152 203 .,.. 242 .... 2.5 L 30 L B 56, 58, 6.1. 95, 106, 0 138
G Oxidizing solid, corrosive, no.5 5.1 UN3085 I 5.1,8 62 None ... 211 .... 242 .... 1 kg 15kg D 13, 56, 58, ao 106, C 138 II 5.1,8 62, 166, P2, T3, TP33 None ... 212 .... 242 .... Skg 2Skg B 13, 34, 56, 58, 0 106, 138 It 5.1, 8 62, 188, 1P3, Ti, TP33 152 213 .... 240 .... 2kg 100 kg B 13, 34, 2. 56, 58, los, 138 a G Oxidizing solid, flammable, no.s 5.1 UN3137 I 5.1, 62 None ... 214 .... 214 .... Forbidden Forbidden 4.1.
G Oxidizing solid, no.5 5.1 UN1479 I 5.1 62, 165, P1 None ... 211 .... 242 .... 1 kg lSkg D 56, 58, 106, 0. 138 3 II 5.1 62, 88, lP2, 1P4, T3, 152 212 .... 240 .... 5 kg 25 kg B 56, 58, TP33 106, 138 III 5.1 62, 1B8, 1P3, Ti, TP33 152 213 .... 240 .... 25kg 100 kg B 56, 58, Q 106, —f 138
G Oxidizing solid, self-heating, n.o.s 5.1 UN3100 I 5.1, 62 None ... 214 .... 214 .... Forbidden Forbidden 4.2. II 5.1, 62 None ... 214 .... 214 .... Forbidden Forbidden 4.2.
0 Oxidizing solid, toxic, n.o.x 5.1 UN3087 I 5.1, 62 None ... 211 .... 242 .... 1 kg 15kg 0 56, 58, 6.1. 106, 138 II 5.1, 62, 186, P2, T3, TP33 152 212 .... 242 .... 5kg 25kg B 56, 58, 6.1. 95, 106, 138 — III 5.1, 62, 1B8, 1P3, Ti, TP33 152 213 .... 240 .... 25kg 100 kg B 56, S8, 6.1. 95, 106, o 138 — None
§172.101 HAzARDOus MATERIALS TABLE—Continued C0)
(8) (9) (10) Vessel Hazard Identi Packaging Quantity limitations stowage C Sym- Hazardous materials descriptions Label Special provisions 173. ) (see 173.27 and bols and proper shipping names class or fication ( § Division Numbers Codes (172.I02) — — 175.75) Excep- Non- Other tions bulk Bulk Passenger Cargo air- tjon aircraft/rail craft only (1) (2) (3) (4) (5) (6) (7) (8A) (8B( (8C) (9A) (98) (IOA) (lOB)
G Oxidizing solid, water-reactive, no.a. 5.1 UN3121 5.1, 62 None 214 214 Forbid Forbidden 4.3 den. Oxygen, compressed 2.2 UN1072 2.2, A14 306 302 314, 75 kg 150kg A 5.1. 315. difluoride, 2.3 Oxygen compreassd UN2190 2.3, 1, N86 None 304 None Forbidden Forbidden D 13, 40, 5.1, 89, 90 8. Oxygen generator, chemical (includ 5.1 UN3356 II 5.1 168 .... None Forbidden 25kg D 56, 58, ing when contained in assoc/ated 69, 106 equipment, e.g., passenger service units (PSU5), portable breathing equipment (PBE), etc).. + Oxygen generator, chemical, spent 9 NA3356 Ill 9 61 None 213 None Forbidden Forbidden A Oxygen, retrigerated liquid (cryogenic 2.2 UN1073 2.2, T75, TP5, TP22 320 316 318 Forbidden Forbidden D liquid), 5.1. Paint including paint, lacquer, enam 3 UN1263 3 Tn, TP1, TP8, TP27 150 201 243 1L 30 L 8 el, stain, shellac solutions, varnish, polish, liquid filler and liquid lac quer base. 150 II 3 149, 852, 182, T4, TP1, 173 242 5L 60 L B TP8, TP28 C) 3 Ill B1, 852, lB3, T2, TPI, 150 173 242 60 L 220 L A -I, TP29 8 Paint or Paint related material 8 UN3066 It B2, 1B2,T7, TP2, TP28 154 173 242 1L 30 L A 8 Ill B52, 183, T4, TP1, TP29 154 173 A 3 241 5L 60 L E Paint related material including paint 3 UN1263 Til, TP1, TP8, TP27 150 201 243 1L 30 L E thinning, drying, removing, or re ducing compound.
II 3 149, B52, lB2, T4, TP1, 150 173.... 242.... 5L 60 L B TP8, TP28 Ill 3 Bi, B52, 1B3,T2, TP1, 150 173.... 242.... 60 L 220 L A C TP29 m Paint, corrosive, flammable (including 8 UN3470 II 8, 3 .... 182, T7, TP2, TP8, TP28 154 202 .... 243 1L 30 L B 40. paint, lacquei enamel, stain, shel lac, varnish, polish, liquid filler and 0 liquid lacquer base). Paint related material corrosive, 8am- 8 UN3470 II 8, 3 .... 1B2,T7, TP2, TP8, TP28 154 202 .... 243 .... 1 L 30 L B 40. mable (including paint thinning or reducing compound).
Paint, flammable, corrosive (including 3 UN3469 I 3, 8 .... Ti i, TP2, TP27 None ... 20i .... 243 .... 0.5 L 2.5 L E 40.
paint, lacquer, enamel, stain, shel- , (D lac, varnish, polish, liquid filler and liquid lacquer base). a
II 3, 8 .... lB2, T7, TP2, TP8, TP28 150 202 .... 243 .... 1 L 5 L B 40. 0. III 3,8 .... lB3, T4, TP1, TP29 150 203 .... 242 .... 5 L 60 L A 40. Paper, unsaturated oil treated incom- 4.2 UN1379 Ill 4.2 ..... lB8, lP3 None ... 213 .... 241 .... Forbidden Forbidden A 0 pIefely dried (including carbon N paper). — Paraformaldehyde 4.1 UN2213 III 4.1 Al, lB8, P3, Ti, TP33 151 213 .... 240 .... 25kg 100 kg A 0. Paraldehyde 3 UN1264 III 3 Bi, lB3, T2, TP1 150 203 .... 242 .... 60 L 220 L A Paranitroaniline, solid, see U, Nitroanilines etc. D Parathion and compressed gas mix- 2.3 NA1967 2.3 3 None ... 334 .... 245 .... Forbidden Forbidden 8 40 ture. — Paris green, solid, see Copper acetoarsenite. A W PCB, see Polychiorinated biphenyls
+ Pentaborane 4.2 UN1380 I 4.2, 1 None ... 205 .... 245 .... Forbidden Forbidden D 6.1. 0 Pentachioroethane 6.1 UN1669 II 6.1 82, T7, TP2 153 202 .... 243 .... 5 L 60 L A 40 Pentachiorophenol 6.1 UN3155 II 6.1 lB8, P2, P4, T3, TP33 153 212 .... 242 .... 25 kg 100 kg A Pentaerythrite tetranitrate (dry) Forbidden Pentaerythrite tetranitrate mixture, 4.1 UN3344 II 4.1 118, N85 None ... 214 .... None Forbidden Forbidden E desensitized, solid, n.o.s. or Penta erythritol tetranitrate mixture, de- —. sensitized, solid, s.o.s. or PETN mixture, desensitized, solid, no.5., with more than 10 percent but not more than 20 percent PETN, by 0 mass. —4 Pentaerythrite tetranitrate or Penta- liD UNO41I II liD .. None ... 62 None Forbidden Forbidden 10 erythritol tetranitrate or PETN, with not less than 7 percent wax by mass. Pentaerythrite tetranitrate, wetted or liD UNQI5O II lID .. 121 None ... 62 None Forbidden Forbidden 10 Pentaerythritol tetranitrate, wetted, or PETN, wetted with not less than 25 percent water, by mass, or Pentaerythrite tetranitrate, or Pen taerythritol tetranitrate or PETN, desensitized with not less than 15 percent phlegmatizer by mass. — Pentaerythritol tetrsnitrate, see Pentaerythrite tetranitrate, etc. Pentafluoroethane or Refrigerant gas 2.2 UN3220 2.2 T50 306 304 .... 314, 75kg 150 kg A R 125 315. — § 172.101 HAzARDOus MATERIALsTABLE—Continued CO)
(8) (9) (10) Vessel Packaging Quantity limitations stowage Sym- Hazard Identi- 73***) C Hazardous materials descriptions Label Special provisions 1 (see 173.27 and bols and proper shipping names class or fication PG ( § Division Numbers Codes ) 172.102) — — 175.75) Excep- Non- Other tione bulk Bulk Passenger Cargo air- tiofl aircraWrail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (88) (8C) (9A) (98) )IOA) (106)
Pentamethylheptane 3 UN2286 Ill 3 Bi, 1B3,T2, TP1 150 203 .... 242 60 L 220 L A 3 Ill Pentane-2,4-dione UN2310 3, 6.1 61, 63, T4, TP1 150 203 .... L A 3 242 60 220 L Pentanes UN1265 3 Til, TP2 150 201 .... 243 1L 30 L E 3 II 1B2, P8, T4, TP1 150 202 .... 242 5L 60 L B Pentanitroaniline (dry) Forbidden II 3 Pentanols 3 UNIIO5 1B2,T4, 3 TP1, TP29 150 202 .... 242 5L 60 L B Ill 3 Bi, B3, 1B3,T2, TP1 150 203 242 60 L 220 L A 3 1-Pentene (n-amylene) UN11O8 8 T11,TP2 150 201 243 L 8 IL 30 E 1-Pentol UN2705 II 62, 1B2,T7, TP2 154 202 242 IL 30 L B 26, 27 II Pentolite, dry or wetted with less 1.10 UNO151 1.10 None ... 62 None Forbidden Forbidden 10 than 15 percent water; by mass,
Pepper spray, see Aerosols, etc. or II C) Self-defense spray, non-pressur ized. Perchiorates, inorganic, aqueous so 5.1 UN3211 5.1 1B2,T4, TP1 152 202 .... 242 iL 5L B 56, 58, lution, n.o,s.. 133 5.1 B Ill lB2, T4, TP1 152 202 .... 241 2.5 L 30 L 56, 58, 5.1 69, 133 Perchlorates, inorganic, no.5 5.1 UNl481 5.1 1B6, 1P2, T3, TP33 152 212 .... 242 5 kg 25 kg A 56, 58 Ill 1B8,1P3, Ti, TP33 152 213 .... 240 25 kg 100 kg A 56, 58 Perchloric acid, with more than 72 Forbidden percent acid by mass. C-) Perchloric acid with more than 50 5.1 UN1873 5.1,8 A2, A3, N41, Tb, TP1 None ... 201 .... 243 Forbidden 2.5 L 0 66 T1 percent but not more than 72 per cent acid, by mass. C) Perchloric acid with not more than 50 8 UN1802 8, 5.1 lB2, N41, T7, TP2 None ... 202 .... 243 Forbidden 30 L C 66 percent acid by mass. Perchioroethylene, see Tetrachloroethylene. Perchiorornethyl mercaptan 6.1 UN1670 6.1 2, 69, 814, 632, N34, None ... 227 .... 244 Forbidden Forbidden 0 40 T20, TP2, TP13, TP38, TP45 Perchloryl fluoride 2.3 UN3083 2.3, 2, B9, B14 None ... 302 .... 314, Forbidden Forbidden 0 40 C 5.1. 315. m Percussion caps, see Primers, cap 0. type. Perfluoro-2-butene, see 0 Octatluorobut-2-ene. IllIII113,6.1116.1IIIII=0.0
Perfluoro(ethyl vinyl ether) 2.1 UN3154 2.1 306 302, 314, Forbidden 150kg F 40 304, 315. 305. CD Perfluoro(methyl vinyl ether) 2.1 UN3153 2.1 T50 306 302, 314, Forbidden 150kg 6 40 304, 315. CD 305. 0 Perfumery products with flammable 3 UN1266 II 3 149, 1B2, T4, TP1, TP8 150 202 242 15 L 60 L B solvents. 0.
3 BI, 1B3, T2, TP1 I 150 203 242 60 L 220 L A
Permanganates, inorganic, aqueous 5.1 I UN3214 II 5.1 26, 1B2. T4, TP1 152 202 242 iL 5L C 56, 58. 0 solution, no.5.. 133, 138 Pernianganates, inorganic, s.o.s 5.1 UN1482 II 5.1 26, A30, 1B6, 1P2, T3, 152 212 242 5 kg 25 kg C 56, 58, a TP33 138 C 5.1 26, A30, 188, 1P3, Ti, i52 213 240 25 kg 100 kg C 56, 58, TP33 138 Peroxides, inorganic, n.o.s 5,1 UN1483 II 5.1 A7. A20, lBS. 1P2, N34, None 212 242 5 kg 25 kg A 13, 52, 0 T3, TP33 66, 75 A 5.1 A7, A20, lB8, lP3, N34, 152 213 240 25 kg 100 kg 13, 52, Ti, TP33 66, 75 2. Peroxyacelic acid, with more than 43 Forbidden C’, percent and with more than 6 per LI, cent hydrogen peroxide. 0 Persulfates, inorganic, aqueous solu 5.1 UN3216 III 5.1 182, T4, TP1, TP29 152 241 L L A N.) 203 2.5 30 56, 133 !R. C...) tion, -3 n.o.s.. Persulfates, inorganic, no.5 5.1 UN3215 III 5.1 1B8, P3, Ti, TP33 152 240 25 kg 100 kg A 56, 58 213 G Pesticides, liquid, flammable, toxic, 3 UN3O21 I 3. 6.1 85, Ti4, TP2, TPi3, None 201 243 Forbidden 30 L B flash point less than 23 degrees C. TP27 3 182, Til, TP2, TPi3, iso 202 243 1L 60 L B TP27
G Pesticides, liquid, toxic, flammable, 6.1 UN2903 I 6.1, 3 T14. TP2, TPi3, TP27 None 201 243 1L 30 L B 40 n.o.s. flash point not less than 23 0 degrees C. -4 II 6.1, 3 1B2,Til, TP2, TP13, 153 202 243 5L 60 L B 40 TP27 6.1, 3 81, 1B3,T7, TP2 153 203 242 60 L 220 L A 40
G Pesticides, liquid, toxic, no.5 6.1 UN2902 I 6.1 T14, TP2, TP13, TP27 None 201 243 iL 30 L B 40 182, Til, TP2, TP13, 153 202 243 5L 60 L B 40 TP27 6.1 183, T7, TP2, TP28 153 203 241 60 L 220 L A 40 A 0 Pesticides, solid, toxic, no.5 6.1 UN2588 I 6.1 87, T6, TP33 None 211 242 5 kg 50 kg 40 168, lP2, P4, T3, TP33 153 212 242 25 kg 100 kg A 40 A 6.1 188, 1P3, Ti, TP33 153 213 240 iOO kg 200 kg 40 PETN, see Pentaerythrite tetranitrate (0) PETNITNT, see Pentolite, etc Petrol, see Gasoline -3
Petroleum crude oil 3 UN1267 I 3 144, T1i, TP1, TP8 150 201 243 1L 30 L E 3 144, 182, T4, TP1, TP8 150 202 242 5L 60 L B 3 144, Bi, lB3, T2, TPI 150 203 242 60 L 220 L A 0
C0 C) — — C m 0. 40 14 40 40 40 40 40 40 40 40 40 40 (lOB) Other (10) Vessel lion (bA) F 8 E B E A 8 B A B A C 8 B A A B A B B A A
F L L L L L L L L L L L L L L L L kg kg kg 30 60 30 60 60 30 60 30 30 30 60 60L only 220 220 220 220 220 220L and 150 100 100 (9B) craft Forbidden air- limitations (9) 173.27 L L L L L L 175.75) kg kg 1L 1L 5L § 1L 5L IL 1L 5L 1L 5L 5L 60 60 60 60 60 60 25 25 (9A) Quantity (see Forbidden Forbidden Forbidden Passenger aircraft/rail 315. Bulk (BC) 243 —— 314, 242 242 242 243 242 241 242 243 243 241 242 243 242 243 243.... 243 243 241 243 241 .... (8) 73,***) bulk (88) Non- 1 201 202 304 203 201 202 203 212 202.... 203 202 212 202 203 202 201 201 203 — 201 202 202.... 203 I ( Packaging (8A) tione Excep- 150 150 150 150 150 153 153 None 306 153 153 153 154 150 None 153 None None 153 153 None 153 — T3, T50 TP8 TP1 TP2 TP3 TP1 TP2 TP1, TP8, TPI, TP28 TP29 TP29 TP33 TP28 TP27 TP33 TP28 TP27 TP27 TP27 TP27 TP27 TP28 TPI3, TP13, T4, TP1 T7, T4, T7, T7, TABLE—Continued T4, T4, N78, Til, T3, TP1, TP1, TP8, TPI, TP2, TP2, TP2, TP2, TP2, TPI3, TP13, TP13, 1B2, 183, 1B3, provisions 183, lP4, 163, 614, N41. (7) 1P4, T7, T7, 144, Til, T7, T7, 172.102) T11, Til, TIl, Bi, BI, TP2, TP2, TP2, ) lP2, lB2, lB2, lP2, 1B2, 144, 1B3, 183, 82, 82, Special 162, 88, 144, B2, 144, T14, T14, T14, MATERIALs lB8, 144, 144, 3 6.1 6.1 (6) Label Codes 3 3 3 3 2.1 3 3 6.1 6.1 6.1 8 6.1 6.1 6.1 3. 3, 6.1 6.1 6.1,3 6.1 6.1, 6.1,3 II II II II II II II II Ill Ill Ill Ill Ill III HAZARDOus (5) PG 075 (4) 1803 172.101 Identi- tication Numbers UN1268 UN1 NA1270 UN2645 UN2311 UN2821 UN2312 UN UN3346 UN1671
§ UN3348 UN3347 3 3 8 3 or 2.1 8.1 6.1 6.1 6.1 6.1 6.1 6.1 (3) Hazard class Division de pes pes pes flash Petro Lique 23 C. or or toxic flammable, names than descriptions n.o.s. derivative derivative derivative degrees liquid liquefied less toxic, n.o.s.. (2) 23 gas. shipping acid acid acid flammable, acid, toxic. not materials than distillates, gases, oil liquid, bromide proper liquid, liquid, C. molten solid point products, less solutions petroleum and Hazardous leum fled ticide, point ticide, ticide, flash grees Petroleum Petroleum Petroleum Phenol Phenacyl Phenetidines Phenolsulfonic Phenol, Phenol, Phenosyacetic Phenosyacetic Phenosyecetic + + D (1) bols Sym- 0.3ci
Phenoxyacetic acid derivative pes 6.1 UN3345 6.1 1B7, P1, T6, TP33 None 211 242 5 kg 50 kg A 40 ticide, solid, toxic. -o 6.1 68, P2, P4, T3, TP33 153 212 242 25 kg 100 kg A 40 6.1 Ill 1B8, P3, Ti, TP33 153 213 240 100 kg 200 kg A 40 Phenyl chioroformate 6.1 UN2746 6.1,8 1B2,T7, TP2, TP13 153 202 243 1L 30 L A 12, 13, (D 21,25, Q 40, 100 Phenyl isocyanate 6.1 UN2487 6.1,3 2, 69, 614, 632, 677, None ... 227 .... 244 Forbidden Forbidden El 40 N33, N34, T20, TP2, = TP13, TP38, TP45 0 Phenyl mercaptan 6.1 UN2337 2, 69, 614, 632, 677, None ... 227 .... 244 Forbidden Forbidden B 40,52 6.1,3 T20, TP2, TP13, TP38, 0. TP45 0 Phenyl phosphorus dichioride 8 UN2798 8 B2, 615, 1B2,T7, TP2 154 202 242 Forbidden 30 L B 40 Phenyl phosphorus thiodichioride 8 UN2799 8 82, 815, 1B2,T7, TP2 154 202 242 Forbidden 30 L B 40 Phenyl urea pesticides, liquid, toxic 6.1 UN3002 6.1 T14, TP2 TP27 None 201 243 1L 30 L B 40 6.1 T7, TP2 None 202 243 5L 60 L B 40 0 III 6.1 T4, TP1 153 203 241 60 L 220 L A 40 6.1 Phenylacetonitrile, liquid 6.1 UN2470 III 163, T4, TP1 153 203 241 60 L 220 L A 52 Phenylacetyl chloride 8 UN2577 8 82, 182, T7, TP2 154 202 242 1L 30 L C 40 a Phenylcarbylamine chloride 6.1 UN1672 6.1 2, B9, B14, B32, T20, None 227 244 Forbidden Forbidden D 40 TP2, TP13, TP38, TP45 C,, m-Phenylene diaminediperchlorate Forbidden 0 (dry). CD + Phenylenediamines (o-; m-; p-;) 6.1 UN1673 Ill 6.1 68, 1P3, Ti, TP33 153 213 240 100 kg 200 kg A Phenyihydrazine 6.1 UN2572 6.1 82, T7, TP2 153 202 243 5L 60 L A 40 A Phenylmercuric acetate 6.1 UN1674 6.1 88, P2, P4, T3, TP33 153 212 242 25 kg 100 kg 6.1 A Phenylmercuric compounds, n.o.s. 6.1 UN2026 87, P1, T6, TP33 None 211 242 5 kg 50 kg 6,1 6.1 1B8, P2, 1P4, T3, TP33 153 212 242 25 kg 100 kg A Ill 68, P3, TP33 153 213 240 100 kg 200 kg A 6.1 6.1 Ti, UN1894 153 Phenylmercuric hydroxide 6.1 6.1 1B8, P2, 1P4, T3, TP33 212 242 25 kg 100 kg A Phenylmercuric nitrate UN1895 1B8, P2, P4, T3, TP33 153 212 242 25 kg 100 kg A 0 Phenyltrichlorosilane 8 UN1804 8 A7, 66, N34, Tb, TP2, None 206 242 Forbidden 30 L C 40 TP7, TPI3 Phosgene 2.3 UN1076 2.3, 8 1, B7, 846 None 192 314 Forbidden Forbidden D 40 9-Phosphabicyclononanes or 4,2 UN2940 4.2 A19, 66, P2, T3, TP33 None 212 241 15 kg 50 kg A Cyclooctadiene phosphines. Phosphine 2.3 UN2199 2.3, None 192 245 Forbidden Forbidden D 40 2.1. Phosphoric acid solution 8 UN1805 18 8 A7, 1B3,N34, T4, TP1 154 203 241 5L 60 L A Phosphoric acid, solid 8 UN3453 Ill 8 188, P3, TI, TP33 154 213 240 25 kg 100 kg A Phosphoric acid trialhyleneimine, see Tris-(l -eziridiyl)phosphine oxide, solution. C0) Phosphoric anhyd ride, see Phos A phorus pentoxide. 8 8 UN2834 A Phosphorous acid Ill 168, P3, Ti, TP33 154 213 240 25 kg 100 kg 48 Phosphorus, amorphous 4.1 UN1338 Ill 4.1 Al, A19, 61, 69, B26, None 213 243 25 kg 100 kg 74 88, 1P3, Tb, TP33 __
§172.101 HAzARDOus MATERIALSTABLE—Continued (0,
(8) (9) (10) Vessel Hazard ldenti- Packaging Quantity limitations stowage C Sym- Hazardous materials descriptions Label 73,***) Special provisions 1 (see 17327 and bols and proper shipping names class or fication PG ( § Division Numbers Codes ( 172.102) — — 175.75) Escep- Non- Other tiona bulk Bulk Passenger Cargo air- aircratllrail craft only (1) (2) (3) (4) (5) (6) (7) (8A) (8B) )8C) )9A) (98) (bA) (108) Phosphorus bromide, see Phos phorus tribromide. Phosphorus chloride, see Phos phorus trichloride.
Phosphorus heptasulfide, from II free 4.1 UN1339 4.1 A20, 84, N34, T3, TP33 None ... 212 .... 240 15 kg 50kg B 74 yellow or white phosphorus. Phosphorus oxybromide 8 UN1939 II 8 B8, 168, 1P2, lP4, N41, None 212 .... 240 Forbidden 50kg C 12,40 N43, T3, TP33 Phosphorus oxybromide, molten 8 UN2576 II 8 B2, B8, IB1, N41, N43, None 202 .... 242 Forbidden Forbidden C 40 T7, TP3, TP13 + Phosphorus oxychloride 8 UN181O II 8, 6.1 2, 69, 614, B32, B77, None 227 .... 244 Forbidden Forbidden C 40 N34, T20, TP2, TP38, TP45 Phosphorus pentabromide 8 UN2691 II 8 A7, 88, lP2, P4, N34, 154 212 .... 240 Forbidden 50kg 8 12, 40. T3, TP33 53, 55 Phosphorus pentachloride 8 UN1806 II 8 A7, 1B8, 1P2, P4, N34, None 212 .... 240 Forbidden 50kg C 40, 44, T3, TP33 89, 100, 141 Phosphorus Pentafluoride 2.3 UN2198 2.3, 8 2, 89, B14 None 302, 314, Forbidden Forbidden 0 40 304. 315. C) Phosphorus pentasultide, free from 4.3 UN1340 Il 4.3, A20, 859, 1B4,T3, TP33 151 212 .... 242 15 kg 50kg B 74 yellow or white phosphorus. 4,1. C) Phosphorus pentoside 8 UN1807 II 8 A7, 68, P2, P4, N34, 154 212 .... 240 iS kg 50kg A T3, TP33 Phosphorus sesquisulfide, free from 4.1 UN1341 II 4.1 A20, 1B4, N34, T3, TP33 None 212 .... 240 15 kg 50kg B 74 yellow or white phosphorus. Phosphorus tribromide 8 UN1808 II 8 A3, A6, A7, 82, 825, None 202 .... 242 Forbidden 30L C 40 1B2,N34, N43, T7, TP2
Phosphorus trichloride 6.1 UN1809 I 6.1,8 2, 89, 614, 815, B32, None 227 .... 244 Forbidden Forbidden C 40 — 877, N34, T20, TP2, C TPI3, TP38, TP45 m Phosphorus trioside 8 UN2578 III 8 188, P3, Ti, TP33 154 213 .... 240 25 kg 100kg A 12 Phosphorus trisulfide, free from yel 4.1 UN1343 II 4.1 A20, 64, N34, T3, TP33 None 212 .... 240 15 kg 50kg 8 74 low or white phosphorus. Phosphorus, white dry or Phos 4.2 UN1381 4.2, B9, B26, N34, T9, TP3, None 188 243 Forbidden Forbidden E -U phorus, white, under water or 6.1, TP31 Phosphorus white, in solution or CD Phosphorus, yellow dry or Phos
phorus, yellow, under water or CD Phosphorus, yellow, in solution. 188 0 Phosphorus white, molten 4.2 UN2447 4.2, B9, 826, N34, T21, TP3, None 243 Forbidden Forbidden U 6.1. TP7, TP26 0. Phosphorus (white or red) and a Forbidden = chlorate, mixtures of. 0 Phosphoryl chloride, see Phosphorus N oxychloride. 0 Phthslic anhydride with more than 8 UN2214 Ill 8 1B8,lP3, Ti, TP33 154 213 240 25 kg 100kg A 0. .05 percent maleic anhydride. 0 Ill C 3 Picolines 3 UN2313 Bi, lB3, T4, TP1 150 203 242 60 L 220L A 40 (n Picric acid, see Trinitrophenol, etc Picrite, see Nitroguanidine, etc 0 Picryl Ill chloride, see Ill CD Trinitrochlorobenzene. 150 Pine oil 3 UN1272 3 Bi, lB3, T2, TPI 203 242 60 L 220L A 0 3 150 alpha-Pinene 3 UN2368 61, 183, T2, TP1 203 242 60 L 220L A (I, Piperazine 8 UN2579 Ill 8 188, 1P3, Ti, TP33 154 213 240 25 kg 100kg A 12, 52 0 Piperidine 8 UN2401 8, 3 AlO, Tb, TP2 None 201 243 0.5 L 2.5L B 52 Pivaloyl chloride, see Trimethylacetyl CD chloride. Ill Plastic molding compound in dough, 9 UN3314 9 32, lB8, 1P3, lP7 155 221 221 100 kg 200kg 8 19, 21, sheet or extruded rope form evolv 25, 87, 0. ing flammable vapor. Ill 144. 3 Plastic solvent, no.s., see Flam mable liquids, n.o.s.. Plastics, nitrocellulose-based, self 4.2 UN2006 4.2 None ... 213 .... None Forbidden Forbidden C V heating, no.5.. 0 Poisonous gases, n.o.s., see Com -I pressed or liquefied gases, flam mable or toxic, n.o.s.. Polyalkylamines, no.s., see Amines, etc. Polyamines, flammable, corrosive, s.o.s. see Amines, flammable, cor rosive, no.s. Polyamines, liquid, corrosive, s.o.s. see Amines, liquid, corrosive, no.5. Polyamines, liquid, corrosive, flam mable, s.o.s. see Amines, liquid, c0) corrosive, flammable, no.s. Polychlorinsted biphsnyls, liquid 9 UN2315 9 9,81, 140, 183, T4, TP1 155 202 241 100 L 220 L A 95 Polychlorinated biphenyls, solid 9 UN3432 II, 9 9, 81,140, 188, P2, lP4, 155 212 240 100 kg 200 kg A 95 T3, TP33 3 0 Polyester resin kit 3 UN3269 40, 149 152 225 None 5 kg 5 kg B C (0, ,, C) C m
0. —‘ 95 95 52 52 58 52 52 52 52 52 87, 21. 133 133 144. 56, 58 (lOB) 56, Other 19. 25, 56. 58, 56, 58, 69, (10) Vessel stowage (bA) Lca- E 0 A A E B A A A B A B B B A A L L L L kg kg kg kg kg kg kg kg kg 5L air- 30 30 60 only 15kg 15 25 220 25 50 220L and 100 200 100 200 100 (9B( craft Cargo limitations (9) 173.27 L L L kg kg kg 175.75) kg kg kg
§ IL IL 5L 5 kg 5 kg 5 60 2.5 100 25 25 25 100 100 (9A) Quantity (see Forbidden Forbidden aircraft/rail Passenger Bulk (8C) 241 241 221 244 242 242 242 242 242 241 241 242 243 242 243 241 ...... (8) bulk (88) Non- 173.( 204 204 211 221 212 211 212 212 203 212 202 212 211 201 203 202
( Packaging ...... (SA) lions Excep- 155 155 155 153 153 152 None 152 None 152 152 153 None 153 None 153 lB2 TI, 184, N40 TP1 TPI TP7, N34, N74, N75, N74, N74, TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP27 TP33 TP13 TP28 TP13, TP13, P7, T4, T4,
TABLE—Continued T9, B27, T3, T3. 1P4, T3, T3, T3, T3, lB2, IP1, T6, A19, 183, N74, TP2, TP2, TP2, lP3, 1B2, 1B2, provisions P4, (7) lP4, 1P4, lP4, lP4, N34, 1P2, 187, A20, N75, B77, B77, T7, 877, T14, Tl1, A2, A2, 188, (172.l02) N6, 88, lP2, lP2, 1P2, lP2, lP2, B77, A19, B69, 869, N75, 869, 32, Special N75, IP1, AS, lB8, lB8, 1B8, MATERIALs lB8, 188, A7, B69, (6) Label Codes 9 9 9 5.1 6.1 4.3 6.1 5.1 5.1 4.3 5.1 6.1 6.1 6.1 6.1 6.1 II II II II II II Ill Ill III
HAzARDous (5) PG Identi- fication Numbers UN3151 UN2257 UN3152 UN2211 UN1677 UN1678 UN1484 UN1485 UN2427 UN1870 UN1679
§172.101 UN1680 UN3413 9 9 9 or 6.1 5.1 4.3 5.1 6.1 5.1 4.3 6.1 6.1 6.1 (3) (4) Hazard Division class Forbidden or or see min no.s.. evolv solid. liquid. solution solid liquid blasting, with names descriptions solution, solutions, mixed aqueous solid terphenyls terphenyls, solution expandable, biphenyls. biphenyls, (2) Explosive, vapor. shipping materials bisulfite aqueous see chlorate arsenite bromate arsenate borohydride carbonyl chlorate beads chlorate, cyanide, cuprocyanide cyanide proper oil, C. flammable and Hazardous Polyhalogenaled Polyhalogenated ing Bisulfites, type eral Polyhalogenated Polymeric Polyhalogenated Potassium Potassium Potassium Potassium Potassium Potassium Potassium Potassium Potassium Potassium Potassium Potassium Potassium (1) bole Sym- N.) N.) Potassium dichioro isocyanurata or -U Potassium dichtoro-s-lriazinetrione, •0 see Dichioroisocyanuric acid, dry CD or Dichloroisocyanuric acid salts
etc. CD Potassium dithiosite or Potassium 4.2 UN1029 II 4.2 A8, AlO, A20, 166. 1P2. None 212 241 15kg 50 kg 8 13 hydrosuttite. T3, TP33 a Potassium fluoride, solid 6.1 UN1812 Ill 6.1 168, 1P3,Ti, TP33 153 213 240 100kg 200 kg A 52 a Ill Potassism fluoride solutios 6.1 UN3422 6.1 163, T4, TP1 153 203 241 60 L 220 L A 52 Potassium fluoroacetate 6.1 UN2628 6.1 167, IP1. T6, TP33 None 211 242 5 kg 50 kg 8 6.1 a Potassium fluorosilicate 6.1 UN2655 Ill 168, 1P3,Ti, TP33 153 213 240 100 kg 200 kg A 52 N Potassium hydrate, see Potassism a hydroxide, solid. a Potassium hydrogen fluoride, sea 0 C Potassium hydrogen difluoride. C’, Potassium hydrogen fluoride solution, see Corrosive liquid, n.o.s.. a Potassium hydrogen sultate 8 UN2509 II 8 A7, 188, 1P2,1P4, N34, 154 212 240 15 kg 50 kg A CD II T3, TP33 Potassism hydrogendiflsoride solid 8 UN18II 8, 6.1 68, 1P2, 1P4, N3, N34, 154 15kg kg A II 212 240 50 25, 40, a T3, TP33 52 U, A Potassium hydrogesdifisoride solu 8 UN3421 8, 6.1 162, N3, N34, T7, TP2 154 202 243 1L 30 L 25, 40, Cd, lion. 52 a Ill 8, 6.1 163, N3, N34. T4, TP1 154 203 241 5L 60 L A 40, 52 CD N.) Potassium hydrosullite, see Potas C,.) slum dithiosite. Potassium hydroxide, liquid, see Po > tassium hydroside solution. 8 a Potassium hydroxide, solid 8 UN1813 8 168, 1P2, lP4, T3, TP33 154 212 240 15 kg 50 kg A 52. 3 Potassium hydroxide, solution UN1814 II 8 62, 162, T7, TP2 154 202 242 1L 30 L A 52. 8 Ill 183, T4, TP1 154 203 241 5L 60 L A 52. Potassium hypochlorite, solution, see V Hypochlorite solutions, etc. 0 Potassium, metal alloys, liquid 4.3 UN1420 4.3 A7, AlO, A20, 627 None 201 244 Forbidden 1L 8 40, 52 -I Potassium, metal alloys, solid 4.3 UN3403 4.3 A19, A20, 627, 84, IP1, None 211 244 Porbidden 15 kg D TO, TP7, TP33 Potassium metavanadats 6.1 UN2864 6.1 68, 1P2, 1P4,T3, TP33 153 212 242 25 kg 100 kg A Potassium monoxide 8 UN2033 II 8 168, 1P2, 1P4, T3, TP33 154 212 240 15kg 50 kg A 20, 52. Potassium nitrate 5.1 UN1486 Ill 5.1 Al, P.29, 168, 1P3, Ti, 152 213 240 25 kg 100 kg A TP33 5.1 5.1 Potassium nitrate and sodium nitrite UN1487 It 678, 168, P2, P4, T3, 152 212 240 5 kg 25 kg A 56, 58 mixtures. TP33 5.1 Potassium nitrite 5.1 UN1488 II 168, P2, 1P4, T3, TP33 152 212 5 kg 25 kg A 56, 58 II 242 Potassium perchlorate 5.1 UN1480 5.1 86, P2, T3. TP33 152 212 5 kg 25 kg A 56, 58 II 242 Potassium permanganate 5.1 UN1490 5.1 188, 1P2, 1P4, T3, TP33 152 212 240 5 kg 25 kg 0 56, 58, C0 138 5.1 Potassium peroxide UN1401 5.1 P.20, 186, IP1, N34 None 211 None Forbidden 15 kg B 13, 52, 66, 75
Potassium persulfate 5.1 I UN1492 Ill I 5.1 Al, P.20, 168, P3, Ti, 152 1213 .1240 25 kg 100 kg A 58, 145 0 TP33 1.4C..
§ 172.101 HAzARDOUSMATERIALSTABLE—Continued -1 (8) (9) (10) 1” Vessel Hazard Identi Packaging Quanlity limitations stowage C Sym- Hazardous materials descriptions Label Special provisions 173.) (see 173.27 and bols and proper shipping names class or fication PG ( § Division Numbers Codes ( 172102) — — 175.75) Excep- Non- Bulk Other tions bulk Passenger Cargo air- aircraWrail craft only (1) (2) (3) (4) (5) (6) (7) (BA) (88) (BC) (9A) (9B) (bA) (lOB) Potassium phosphide I 4.3 UN2012 4.3, A19, N40 None ... 211 None Forbidden 15kg 6 40, 52, 6.1. 85 Potassium selenate, see Selenates or Selenites. Potassium selenite, see Selenates or Selenites.
Potassium sodium alloys, liquid I 4.3 UN1422 4.3 A7, A19, B27, N34, N40. None 201 244 Forbidden 1L E 40, 52 T9, TP3, TP7, TPSI
Potassium sodium alloys, solid I 4.3 UN3404 4.3 A19, 627, N34, N40, T9, None 211 244 Forbidden 15kg D 52 TP7, TP33 Potassium sulfide, anhydrous or Po 4.2 UN1382 II 4.2 A19, A20, 816, 186, P2, None 212 241 15 kg 50kg A 52 tassium sulfide with less than 30 N34, T3, TP33 percent wafer of crystallization. Potassium sulfide, hydrated with not 8 UN1647 II 8 188, lP2, 1P4, T3, TP33 154 212 .... 240 15 kg 50kg A 52 less than 30 percent water of crys fallization.
Potassium I superoxide 5.1 UN2466 5.1 A20,lB6, lPl None ... 211 .... None Forbidden 15kg B 13, 52, 66, 75 Powder cake, wetted or Powder 1.1C UN0433 II 1.1C None ... 62 None Forbidden Forbidden 10 paste, wetted with not less than 17 percent alcohol by mass.
Powder cake, wetted or Powder 1.3C UN0159 II 1.3C None .. 62 None Forbidden Forbidden 10 C) paste, wetted with not less than 25 -n percent water, by mass. Powder paste, see Powder cake, etc C) Powder, smokeless l.lC UNO16O II 1.1C None 62 None Forbidden Forbidden 26E Powder, smokeless 1.3C UNOI61 II 1.3C None 62 None Forbidden Forbidden 26E D Powder, smokeless 1.4C UNOSO9 None 52 None Forbidden Forbidden 06 Power device, explosive, see Car tridges, power device. cp Primers, cap type 1.4S UN0044 II None None 62 None 25 kg 100 kg 05 Primers, cap type 1.1B UN0377 II 1.18... None 62 None Forbidden Forbidden 11 Primers, cap type 1.48 UN0378 II 1.48... None 62 None Forbidden 75kg 06 C Primers, small arms, see Primers, m cap type. 0. Primers, tubular 1.30 UN0319 Il 1.3G None 62 None Forbidden Forbidden 07 Primers, tubular 1.4G UN0320 II 1.40 None 62 None Forbidden 75kg 06 0 Primers, tubular l.4S UN0376 II None None 62 None 25 kg 100 kg 05 IIIII
Printing ink, flammable or Printing ink 3 UN121O I 3 Til, TP1, TP8 150 ...... 173 .... 243 1 L 30 L E related material (including printing ink thinning or reducing corn- CD pound), flammable, 3 149, lB2, T4, TP1, TP8 150 173 242 5 L 60 LB CD 3 61, lB3, T2, TP1 150 173 242 60 L 220 L A Projectiles, illuminating, see Ammuni- 0 lion, illuminating, etc. Projectiles, inert with tracer 1.4S UN0345 II 1.4S 62 62 25kg 100 kg 01 Projectiles, inert, with tracer 1.3G UN0424 II 1.3G 62 62 Forbidden Forbidden 03 Q Projectiles, inert, with tracer 1.4G UN0425 II 1.4G 62 62 Forbidden 75kg 02 N Projectiles, with burster or expelling 1.2D UN0346 II 1.2D 62 62 Forbidden Forbidden 03 — charge. Projectiles, with burster or expelling 1.4D UN0347 II 1.4D 62 62 Forbidden 75kg 02 charge. Projectiles, with burster or expelling 1.2F UN0426 II 1.2F ... 62 None Forbidden Forbidden 08 charge. Projectiles, with burster or expelling 1.4F UN0427 II 1.4F ... 62 None Forbidden Forbidden 08 — charge. Projectiles, with burster or expelling 1.2G UN0434 II 1.2G .. 62 62 Forbidden Forbidden 03 charge. Projectiles, with burster or expelling 1.4G UN0435 II 1.4G .. 62 62 Forbidden 75kg 02 charge 0 Projectiles, with bursting charge lIP UN0167 II 1.1F ... 62 None Forbidden Forbidden 08 Projectiles, with bursting charge liD UN0168 II liD .. 62 62 Forbidden Forbidden 03 Projectiles, with bursting charge 1.2D UN0169 II 1.2D .. 62 62 Forbidden Forbidden 03 Projectiles, with bursting charge 1.2F UN0324 II 1.2F ... 62 None Forbidden Forbidden 08 Projectiles, with bursting charge 1.4D UN0344 II 1.4D .. 62 62 Forbidden 75kg 02 Propadiene, stabilized 2.1 UN2200 2.1 None ... 304 .... 314, Forbidden 150 kg B 40 —. 315. Propadiene mixed with methyl acety- lene, see Methyl acetylene and propadiene mixtures, stabilized. 0 Propane see also Petroleum gases, 2.1 UN1978 2.1 19, T50 306 304 .... 314, Forbidden 150 kg E 40 liquefied 315. Propanethiols 3 UN2402 II 3 A6, 1B2,T4, TP1, TP13 150 202 .... 242 .... 5 L 60 L E 95, 102 n-Propanol orPropyl alcohol, normal 3 UN1274 Il 3 61, 1B2,T4, TP1 150 202 .... 242 .... 5 L 60 L B 3 61, 1B3,T2, TP1 150 203 .... 242 .... 60 L 220 L A Propellant, liquid 1.3C UN0495 II 1.3C 37 None 62 None Forbidden Forbidden 10 Propellant, liquid 1.1C UN0497 II 1.1C 37 None 62 None Forbidden Forbidden 10 Propellant, solid 1.IC UN0498 II 1.1C None ... 62 None Forbidden Forbidden 26E Propellant, solid 1.3C UN0499 II 1.3C None ... 62 None Forbidden Forbidden 26E Propellant, solid 1.4C UNO5O1 1.4C None ... 62 None Forbidden Forbidden A 24E Propionaldehyde 3 UN1275 II 3 lB2, T7, TP1 150 202 .... 242 .... 5 L 60 L B Propionic acid with not less than 8 UN3463 II 8, 3 .... lB2, T7, TP2 154 202 .... 243 .... 1 L 30 L A. 90% acid by mass. — Propionic acid with not less than 8 UN1848 III 8 lB3, T4, TP1 154 203 .... 241 .... 5 L 60 L A. 10% and less than 90% acid by mass. Propionic anhydride 8 UN2496 Ill 8 lB3, T4, TP1 154 203 .... 241 .... 5 L 60 L A — 11
§172.101 HAzARDOUSMATERIALSTABLE—Continued
(8) (9) (10) Vessel Packaging Quantity limitations stowage Sym- Hszardous materials descriptions Hazard ldenti- (5173.***( 0 ctass or fication Label Special provisions (see §173.27 and bols and proper shipping names PG Codes — Division Numbers (172.1O2) 175.75) - Excep- Non- Bulk Other lions bulk Passenger Cargo air- lion aircraWrail craft only
(1) (2) (3) (4) (5) (6) (7) (8A( (86) (8C) (9A( (9B) (1OA) (108) Propionitrile 3 UN2404 II 3, 6.1 182, T7, TP1, TP13 None 202 243 Forbidden 60 L E 40 Propionyl chloride 3 UN1815 3. 8 81, T7, TP1 150 202 243 1L 5L B 40 n-Propyl acetate 3 UN1276 II 3 162, T4, TP1 150 202 242 5L 60 L B Propyl alcohol, see Propanol n-Propyl benzene 3 UN2364 Ill 3 B1, 1B3,T2, TP1 150 203 242 60 L 220 L A n-Propyl chloroformate 6.1 UN2740 6.1, 3, 2, B9, 614, 632, B77, None 227 244 Forbidden Forbidden B 21, 40, 8 N34, T20, TP2, TP13, 100 TP38, TP44 Propyl chloride see 1-Chloropropane Propyl formates 3 UN1281 II 3 182, T4, TP1 150 202 .... 242 .... 5 L 60 L B n-Propyl isocyanate 6.1 UN2482 I 6.1,3 1, 89, 614, B30, T22, None ... 226 .... 244 .... Forbidden Forbidden D 40 TP2, TP13, TP38, TP44 Propyl mercaptan, see Propanethiols n-Propyl nitrate 3 UN1865 II 3 189 150 202 None 5L 60 L D 44, 89, 90, 100 Propylamine 3 UN1277 It 3, 8 A7, 182, N34, T7, TP1 150 202 243 1L 5L E 40 Propylene see also Petroleum gases, 2.1 UN1077 2.1 19. T50 306 304 314, Forbidden 150 kg E 40 liquefied. 315. Propylene chlorohydrin 6.1 UN2611 II 6.1,3 162, T7, TP2, TP13 153 202 243 5L 60 L A 12,40, 48 Propylene oxide 3 UN1280 3 A3, N34, Til, TP2, TP7 None 201 243 1L 30 L E 40 Propylene tetramer 3 UN2850 III 3 81, 1B3,T2, TP1 150 203 242 60 L 220 L A 1,2-Propylenediamine 8 UN2258 II 8, 3 A3, A6, 1B2, N34, T7, None 202 243 1L 30 L A 40 TP2 C) Propyleneimine, stabilized 3 UN1921 3, 6.1 A3, N34, T14, TP2, None 201 243 1L 30 L 8 40 TP13 Propyltrichlorosilane 8 UN1816 II 8, 3 A7, 82, 86, N34, Tb, None 206 243 Forbidden 30 L C 40 — TP2, TP7, TP13 Prussic acid, see Hydrogen cyanide Pyrethroid pesticide, liquid, flam 3 UN3350 3, 6.1 T14, TP2, TP13, TP27 None ... 201 .... 243 .... Forbidden 30 L B 40 mable, toxic, flash point less than -r 23 degrees C. C 3, 6.1 1B2,T11, TP2, TP13, 150 202 243 1L 60 L B 40 m TP27 0. Pyrethroid pesticide, liquid toxic 6.1 UN3352 6.1 T14, TP2, TP13, TP27 None 211 242 1L 30 L A 6.1 62, Til, TP2, TP27 153 212 242 5L 60 L A 6.1 lB3, T7, TP2, TP28 153 213.... 240.... 60 L 220L A C030
Pyrethroid pesticide, liquid, toxic, 6.1 I UN3351 6.1,3 T14, TP2, TPI3, TP27 None 201 243 1L 30L B 40 flammable, flash point not less V than 23 degrees C. 6.1, 3 1B2,Til, TP2, TPI3, 153 202 243 5L 60L B 40 TP27 6.1,3 1B3,T7, TP2, TP28 153 203 241 60 L 220L B 40 Pyrethroid pesticide, solid, toxic 6.1 UN3349 I 6.1 1B7, IPI, T6, TP33 None 211 242 5 kg 50kg A 40 6.1 1B8, 1P2, 1P4,T3, TP33 153 212 242 25 kg 100kg A 40 6.1 68, P3, Ti, TP33 153 213 240 100 kg 200kg A 40 X Pyridine 3 UN1282 II 3 1B2,T4, TP2 None 202 242 5L 60L B 21, 100 Pyridine perchlorate Forbidden
G Pyrophoric liquid, inorganic, 0.0.5 4.2 UN3194 I 4.2 None 181 244 Forbidden Forbidden D 18
G Pyrophoric liquids, organic, 0.0.5 4.2 UN2845 I 4.2 Bli, T22, TP2, TP7 None 181 244 Forbidden Forbidden D 18 a G Pyrophoric metals, no.s., or 4.2 UN1383 I 4.2 Bil, T2i, TP7, TP33 None 187 242 Forbidden Forbidden D Pyrophoric alloys, no.s.. G Pyrophoric solid, inorganic, s.o.s 4.2 I 187 G UN3200 4.2 T21, TP7, TP33 None 242 Forbidden Forbidden D Pyrophoric solids, organic, s.o.s 4.2 UN2846 I 4.2 None 187 242 Forbidden Forbidden D Pyrosulfuryl chloride 8 UN1817 II 8 B2, 1B2,T8, TP2 154 202 242 1L 30L C 40 Pyroxylin solution or solvent, see Ni trocellulose. 0 150 Pyrrolidine 3 UN1922 II 3, 8 1B2,T7, TP1 202 243 1L SL B 40, 52 Quebrachitol pentanitrate Forbidden Quicklime, see Calcium oxide 0 153 (D Quinoline 6.1 UN2656 Ill 6.1 1B3,T4, TPI 203 241 60 L 220L A 12 R 12, see Dichlorodifluorometharie R l2B1, see Chlorodifluorobromomethane. 0. R 13, see Chlorotrifluoromethane R 1381, see Bromotrifluoromethane F?14, see Tetrafluoromethane R 21, see Dichlorofluoromethane F?22, see Chlorodifluoromethane R 114, see Dichlorotetrafluoroethane -I R 115, see Chloropentafluoroethane R 116, see Hexafluoroethane R 124, see Chlorotetrafluoroethane R 133a, see Chlorotrifluoroethane R 152a, see Ditluoroethane R 500, see Dichlorodifluoromethane and difluorethane, etc. R 502, see Chlorodifluoromethane and chloropentafluoroethane mix ture, etc. R 503, see Chlorotrifluoromethane co and trifluoromethane, etc. Radioactive material, excepted pack 7 UN2909 None 422, 422, 422, A age-articles manufactured from 426. 426. 426. natural uranium or depleted ura C nium or natural thorium. §172.101 HAzARDous MATERIALSTABLE—Continued Lot
(8) (9) (10) Vessel 1 Packaging Quantity limitations Hazard Identi- 73,***) stowage 0 Sym- Hazardous materials I descriptions Label Special provisions 1 (see 173.27 and bols and proper shipping names class or fication PG ( § Division Numbers Codes )172.102) — — 175.75) Excep- Non- Bulk Dther tions bulk Passenger Cargo air- aircraWrail craft only
(1) (2) (3) (4) (5) (6) (7) (BA) (85) (8C) (9A) (98) (1OA) (108)
Radioactive material, excepted pack- 7 UN2908 Empty 422, 422, 422, A age-empty packaging 428 428 428. Radioactive material, excepted pack- 7 UN291 1 None 422, 422 A age-instruments or articles, 424 424. Radioactive material, excepted pack- 7 UN2910 None 421, 421, 421 A age-limited quantity of material. i 422 422 422. Radioactive material, low specific ac- 7 UN2912 7 A56, T5, TP4, W7 421, 427 427 A 95, 129 tivity (LSA-l) non fissile or fissile- 422, excepted 428. Radioactive material, low specific Sc- 7 UN3321 7 A56, T5, TP4, W7 421, 427 427 A 95, 129 tivity (LSA-ll) non flssite or fissile- 422, excepted 428. CO Radioactive material, low specific ac- 7 JN3322 7 A56, T5, TP4, W7 421, 427 427 A 95. 129 tivity (LSA-lll) non fissite or fissile 422, excepted. 428. Radioactive material, surface con- 7 UN2913 7 A56 421, 427 .... 427 A 95 laminated objects (SCO-l or SCO- 422, II)non fissile or tissue-excepted. 428. Radioactive material, transported 7 UN2919 7 A56, 139 A 95, 105 under special arrangement, non tissue or tissue excepted. C-) Radioactive material, transported 7 UN3331 7 A56, 139 A 95, 105 ‘1 under special arrangement, fissile. Radioactive material, Type A pack- 7 UN3327 7 A56, W7, W8 453 417 .... 417 .... A 95, C-) age, fissile non-special form. 105, 131 Radioactive material, Type A pack- 7 UN2915 7 A56, W7, W8 None .. 415. 415, A 95, 130 age non-special form, non tissue or 418. 418, (issue-excepted. 419. 419. Radioactive material, Type A pack- 7 UN3332 7 A56, W7, W8 415, 415, A 95 age, special form non fisslle or 476. 476. 0 fissule-excepted. m Radioactive material, Type A pack- 7 UN3333 7 A56, W7, W8 453 417, 417, A 95, 105 age, special form, tissue. 476. 476. Radioactive material, Type 8(M) 7 UN3329 7 A56 453 417 .... 417 .... A 95, 105 0 package, fissile. Radioactive material, Type 8(M) 7 UN2917 7 A56 416 416 A 95, 105 package non fisslle or fissile-ex cepted. Radioactive material, Type B(U) 7 UN3328 7 A56 453 417 417 A 95, 105 5 package, tissue. CD Radioactive material, Type 8(U) 7 UN2916 7 A56 416 416 A 95, 105 package non fissile or flssile-ex cepted. Radioactive material, uranium 7 UN2978 7, 8 423 420, 420, A 95, 132 = hexafluoride non fissile or tissue- 427 427. 0 excepted. Radioactive material, uranium 7 UN2977 7, 8 453 417, 417 A 95, 132 — hexafluoride, tissue 420 420. 0. A W Rags, oily 4.2 UN1656 III 4.2 151 213 240 Forbidden Forbidden A Railway torpedo, see Signals, railway track, explosive. RC 318, see Octafluorocyclobutane RDX and — cyclotetramethylenetetranitramine, wetted or desensitized see RDX and HMX mixtures, wetted or de sensitized. ROX and HMX mixtures, wetted with lID UN0391 II 1.10 None 62 None Forbidden Forbidden 10 0 not less than 15 percent water by CD mass or RDX and HMX mixtures, desensitized with not less than 10 percent phlegmatizer by mass. RDX and Octogen mixtures, wetted or desensitized see RDX and HMX —. mixtures, wetted or desensitized etc. RDX, see Cyclotrimethylene trinitramine, etc. 0 Receptacles, small, containing gas or 2.1 UN2037 2,1 306 304 .... None 1 kg 15kg B 40 gas cartridges (flammable) without release device, not refillable and not exceeding I L capacity.
Receptacles, smell, containing gas or 2.2 UN2037 2.2 306 304 None 1 kg 15 kg B 40 gas cartridges(non-flammable) without release device, not refill able and not exceeding I L capac ity. Receptacles, small, containing gas or 2.2 UN2037 2.2, A14 306 304 .... None 1 kg 15kg B 40 gas cartridges (oxidizing) without 5.1. release device, not refillable and Cot not exceeding I L capacity. — Red phosphorus, see Phosphorus amorphous. Refrigerant gas R 404A 2.2 UN3337 2.2 T50 306 304 .... 314, 75 kg 150 kg A 315. — !‘ 0 T1 C) p. C) cm 0 m ci’ 0. 0 40 40 40 23E Other (lOB) (10) Vessel stowage tion (1OA) A D D A B B A A E A 05 05 A A 03 04 03 03 L L L kg kg kg kg kg kg kg kg kg kg sir- limit 60 30 only 220 and 150 150 150 150 150 100 100 450 200 220 No (9B) Forbidden craft Forbidden Forbidden Forbidden Cargo limitations (9) 173.27 L kg kg 175.75) kg kg kg kg kg kg iL §5 5L limit 60 75 75 75 75 25 25 100 450 No (9A) Quantity (see Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden aircraft/rail Passenger 315. 315. 315. 315. 315. 307. Bulk (8C) — 314, 314, 197 314, 314, 314, 306 306, 62 242 242 243 240 62 None 62 62 62 (8) bulk (8B) Non- 173.*) 304 304 197 173 304 306 304 306 173 304 — 62 201 62 213 62 62 62 62 ( Packaging 307. )8A) 307. tions Encep- 306 150 306 306 306, 134 150 306 306, None 150 153 306 — None None None None None 109 109 T50 109 109 T50 T50 T50 T50 A53 A13 TP8 TP8. TP1, TP28 TP33 41, T2, TP1 TABLE—Continued T4, Ti, TP1, 163, provisions 152, (7) 1P3, 172.102) Til, (5 652, 652, 168, B52, Special Bi, MATERIALS 149, (6) Label Codes 2.2 2.1 1.4S 2.2 2.2 2.1 2.2 2.2 3 1.4S 1.2J 6.2 1.3C 3 1.2C 1.1C 3 6.1 II II Ill Ill HAzARDOuS (5) 74 (4) 172.101 Identi tication Numbers UN3339 UN3338 NA1954 UN334D UN3358 UN2857 UN1078 UN3291 UN0173 UN2876 UN1866 UNO1 UN0186 UN0280 UND281 UN0395 § 3 or 2.2 2.2 2.1 2.2 2.1 2.2 2.2 6.2 6.1 .3C 1.2J 1.4S 1.4S 1.2C I 1.1C (3) Hazard class Division or or or gas. Med hand Tars, no.s. smoke Dispers or no.s. no.s., gases, see containing containing or names liquefied descriptions no.s. (UN2672). fueled liquid, Grenades, waste, waste, Powder, n.o.s. nO.5 unspecified, 407A 407B 407C eaplosive (2) tar shipping R R R see liquid flammable see machines, machines, waste, or non-toxic, materials n.o.s.. no.5.. solutions gases, Medical gas gsa gas gases, medical 0150). waste, proper etc. devices, etc. motors motors, motors motors explosive (UN solution, waste. asphalt gases, powder, grenade, (BlO) and rifle, cal Hazardous ant Clinical or flammable, non-flammable, non-toxic Biomedical ammonia less or liquid, Refrigerant Refrigerant Refrigerant Refrigerant Refrigerating Refrigerant Refrigerating Release Regulated Resin Resorcinol Rivets, Rifle Road Rocket Rocket Rocket Rocket Rifle 0 0 (1) bols Sym- 1.2C..UNO19O
Rocket motors, liquid fueled 1.3J UN0396 II 1.3J 109 None ... 62 .... None Forbidden Forbidden 04 23E - Rocket motors with hypergolic liquids I.3L UN0250 II 1.3L 109 None ... 62 .... None Forbidden Forbidden 08 8E, with or without an expelling charge. 14E, CD
1SE CD Rocket motors with hypergolic liquids 1.2L UN0322 II l.2L 109 None ... 62 ...... None Forbidden Forbidden 08 8E, with or without an expelling charge. 14E, 0 15E Rockets, line-throwing 1.2G UN0238 II l,2G None 62 None Forbidden Forbidden 07 0. Rockets, line-throwing 1.3G UN0240 II 1.3G None 62 None Forbidden 75 kg 07 x Rockets, line-throwing 1.4G UN0453 II 1.4G None 62 None Forbidden 75 kg 06 0 Rockets, liquid fueled with bursting 1.1J UN0397 II 1.1J None 62 None Forbidden Forbidden 04 23E N charge. 0 Rockets, liquid fueled with bursting 1.2J UN0398 II 1.2J None 62 None Forbidden Forbidden 04 23E 0. charge. 0 C Rockets, with bursting charge 1,1F UNO18O II 1.1F None 62 None Forbidden Forbidden 08 (I, Rockets, with bursting charge 1.10 UNOI81 II liE None 62 62 Forbidden Forbidden 03 Rockets, with bursting charge 1.26 UN0182 II i.2E None 62 62 Forbidden Forbidden 03 0 Rockets, with bursting charge 1.2F UN0295 II i.2F None 62 None Forbidden Forbidden 08 Rockets, with expelling charge 1.2C UN0436 II 1.2C None 62 62 Forbidden Forbidden 03 CD 62 03 Rockets, with expelling charge I .3C UN0437 II 1.3C None 62 Forbidden Forbidden 62 0 Rockets, with expelling charge l.4C UN0438 II 1.4C None 62 Forbidden 75 kg 02 62 Cl, Rockets, with inert head 1.3C UN0183 II l.3C None 62 Forbidden Forbidden 03 62 (I) Rockets, with inert head 1.2C UNOSO2 None 62 Forbidden Forbidden B 1E, SE 0 Rosin oil UN1286 II 3 162, T4, TP1 150 L 202 242 5L 60 B CD III 3 BI, 1B3,T2, TP1 150 203 242 60 L 220 L A Rubber solution 3 UN1287 II 3 149, 82, T4, TP1, TP8 150 202 242 5L 60 L B 61, 83, T2, TP1 150 203 242 60 L 220 L A > Rubber scrap or shoddy, powdered 4.1 UN1345 II 4.1 168, lP2, lP4, T3, TP33 151 212 240 15 kg 50 kg A 0. or granulated, not exceeding 840 3 microns and rubber contend ex D ceeding 45%.
Rubidium 4.3 UN1423 I 4.3 22, A7, A19, 184, IP1, None 211 242 Forbidden 15 kg D 52 N34, N40, N45 0 Rubidium hydroxide 8 UN2678 II 8 168, P2, 1P4, T3, TP33 154 212 240 15 kg 50 kg A 29, 52. -I Rubidium hydroxide solution 8 UN2677 II 8 62, 162, T7, TP2 154 202 242 1L 30 L A 29, 52. A III 8 183, T4, TP1 154 203 241 5L 60 L 29, 52. Safety fuse, see Fuse, safety G Samples, explosive, other than initi 113 None 62 None Forbidden Forbidden 14 ating explosives. Sand acid, see Fluorosilicic acid Seed cake, containing vegetable oil 4.2 UN1386 Ill None 188, 1P3, 1P7, N7 None ... 213 .... 241 ..., Forbidden Forbidden A 13 solvent extractions and expelled seeds, with not more than 10 per cent of oil and when the amount of moisture is higher than II percent, (0) with not more than 20 percent of oil and moisture combined. Seed cake with more than 1.5 per 4.2 UN1386 Ill None 188, P3, 1P7, N7 None ... 213 .... 241 .... Forbidden Forbidden E 13 cent oil and not more than II per 0 cent moisture. — C —
0 0 C g
13
40 40
Other (lOB) V ......
(10)
Vessel
stowage
(1OA) Loc
E B B B A A A B A A 0 E A C C C C C C C C C C C C
L L L L L L L L L L L L L L L
kg kg kg
5 5 5 5 5 5
air- 30L
limit
60
60 60 60 60 60 60
only 2.5
50kg 25kg 50kg 220
and
100 100
200
(98) No
Forbidden Forbidden craft
Cargo
75)
limitations
(9)
17327 V
L L L L L L L L L L L L L L L
175 1L kg kg
5 § 1 1 1 5 1 1 5 5 1 S 5 5
limit
5kg 5kg 60 V
0.5
25kg 25
100
(9A) No
Quantity (aee
Forbidden Forbidden Forbidden
Passenger aircraft/rail ......
Bulk (8C)
241 242 242 243 243 241 242 242 242 None 240 243 None 243 243 241 241 242 241 242 241 241 243 243 241 ......
......
***) ......
(8)
(8B)
173
2l3 211 202 211 201 203 211 212 213 212 302 201 203 202 203 203 202 203 202 202 203 202 203 202 203
(
Packaging V.:
(BA)
None None 153 153 153 None None 153 153 155 None None None None None None None None None None None None None None None
1
N7 62
182 1B2 182 1B2 182 1B2 182 1B2 182 182 182
A37
Tb,
TP33 TP33 TP28 TP33 TP33 TP27 TP27 TP33 TP33 TPI3
1P7,
TABLE—Continued
TB, TB, TB, T3, TI, T3,
N34,
TP2, TP2, TP1, TP2,
102)
P3,
provisions
(7)
IP1, IP1, 1P4, 1P3, lP4,
A7,
N34, T7,
172
T14, Til,
188,
(
88,
A6,
187, 1B7, 1P2, 1P2,
IPI, lB3,
1162, Special
A3,
188, MATERIALS 188,
tB7, .. ..
......
6 8
...... 8 8 8
. .
1
6.1 ......
(6)
1 6.1. 6 61. 6.1. 3. 2, 2 2, 2,
Labet
Codes ...... ,
None 8 6.1 6 6.1 6.1 6.1 61 61 6.1 2 8, 9 4.2, 4 4 4.2 4.2, 4 4.2 4.2 4.2, 4.2, 42, 4
I I I I I
II II II
II II II II II II
Ill III III III Ill Itt
HARDOUS
(5) PG .
(4)
172.101
Ident-
6cation
Numbers UN2217 UN2630 UN1905 UN3440 UN3283 UN2657 UN2194 UN2879 NA3334 UN3188 UN3186 UN3185 UN3183 § UN3187 UN3184
1 8 3 8 9 ...
or 61 42 61 61 6 2 4.2 4.2 4.2 4.2 4.2 4.2
zard
(3)
f-I
class Division
Forbidden
5
II
I .
see
nor-
., a .
s
than
organic, no
organic,
than
nos .
no no.s inorganic,
names .
descriptions
aerosol,
more
more
liquid, solid, toxic,
corrosive,
toxic,
non-pressurized
not inorganic, corrosive, organic,
not
(2) ...... ‘...
shipping
spray,
and
materials liquid,
liquid,
liquid, spray,
with
liquid, liquid, liquid,
etc.
oil
orSelenites
moisture.
compound, compound, disulfide hexafluoride nitride oxVchlOride
proper
no.5
acid
cake
and
Hazardous
percent percent Aerosols, ganic, n.o.S no.5.. s.o.S..
Seed Seteniurn Selenium Selenales Selenic Selenium Selenium Selenium Selenium Self-defense Self-defense Self-heating Self-heating Self-heating Self-heating Self-heating Self-heating
A D G G G G G o
*
(1)
bots
Sym-
III ... . G Self-heating solid, corrosive, inor 4.2 UN3192 II 4.2, 8 1B5, P2, T3, TP33 None 212 242 15 kg 50 kg C -U ganic, n.o.s.. III 4.2, 8 188, 1P3, Ti, TP33 None 213 242 25 kg iOQ kg C CD G Self-heating solid, corrosive, organic, 4.2 UN3126 II 4.2, 8 85, P2, T3, TP33 None 212 242 i5 kg 50 kg C CD n.o.e. C III 4.2, 8 1B8, 1P3, Ti, TP33 None 2i3 242 25 kg 100 kg G 0 Self-heating solid, inorganic, no.5. 4.2 UN319O II 4.2 lB6, 1P2, T3, TP33 None 2i2 241 iS kg 50 kg C G III 4.2 lBS. 1P3, Ti, TP33 None 2i3 241 25 kg 100 kg C 0. Self-heating solid, organic, no.5 4.2 UN3088 II 4.2 lB6, 1P2, T3, TP33 None 212 241 i5 kg 50 kg C I G III 4.2 1B8, 1P3, Ti, TP33 None 2i3 241 25 kg 100 kg C 0 Self-heating solid, oxidizing, no.e 4.2 UN3i27 4.2, None 2i4 214 Forbidden Forbidden N G 51. 0 Self-heating solid, toxic, inorganic, 4.2 UN3i9i II 4.2, 1B5, 1P2, T3, TP33 None 2i2 242 iS kg 50 kg C 0. n.o.s., 6.i. 0 C III 4.2, C G 88, P3, Ti, TP33 None 2i3 242 25 kg 100 kg U, 6.i. C Self-heating solid, toxic, organic, 4.2 UN3128 II 4.2, 1B5, P2, T3, TP33 None 242 15 kg 2i2 50 kg 0 no.5. 61. C III 4.2, 188, lP3, Ti, TP33 None 242 25 kg iOO kg CD 6.i. 2i3 G 0 G Self-propelled vehicle, see Engines U, or Batteries etc. C’, G Self-reactive liquid type B 4.1 UN3221 II 41 53 None 224 None Forbidden Forbidden D 52, 53 0 G Self-reactive liquid type B, tempera 4.1 UN3231 53 D 41 None 224 None Forbidden Forbidden 2, 52, CD II ture controlled. II 53 G 4.1 Self-reactive liquid type C UN3223 None 224 None 5L 10 L C 52, 53 G II 41 Self-reactive liquid type C, tempera 4.1 UN3233 II None 224 41 None Forbidden Forbidden 0 2, 52, ture controlled. II 0. G 4.1 II 53 G Self-reactive liquid type D UN3225 None 224 None iO L D 53 4.1 II 5L 52, Self-reactive liquid type D, tempera UN3235 II 41 None 224 None Forbidden Forbidden 0 2, 52, G ture controlled. 4.1 41 53 G II Self-reactive liquid type E 4.1 UN3227 None 224 None 10 L 25 L 0 52, 53 UN3237 G Self-reactive liquid type B, tempera 41 None 224 None Forbidden Forbidden 0 2, 52, 0ci 4.1 -I G ture controlled. 41 53 4.1 II Self-reactive liquid type F UN3229 None 224 None 10 L 25 L 62, 53 II 0 G Self-reactive liquid type F, tempera UN3239 II None 224 None Forbidden Forbidden D 2, 52, G 41 ture controlled. II 53 53 D Self-reactive solid type B 4. i UN3222 II 41 53 None 224 None Forbidden Forbidden 52, 53 G Self-reactive solid type B, tempera 4,1 UN3232 II None 224 None Forbidden Forbidden 0 2, 52, ture controlled. 41 63 Self-reactive solid type C 4. i UN3224 414.1 None 224 None 5 kg 10 kg 0 52, 53 UN3234 Self-reactive solid type C, tempera 4. i 4.1 None 224 None Forbidden Forbidden 0 2, 52, ture controlled. 63 UN3226 4.1 Self-reactive solid type D 4. i None 224 None 5 kg iO kg D 52, 63 4.1 G Self-reactive solid type D, tempera 41 UN3236 None 224 None Forbidden Forbidden D 2, 52, C0 ture controlled. 53 UN3228 G Self-reactive solid type E 4.i None 224 None 10 kg 25 kg D 52, 53 41 UN3238 G Self-reactive solid type E, tempera 41 4.i None 224 None Forbidden Forbidden D 2, 52, ture controlled. 53 G UN3230 0 Self-reactive solid type F None 224 None iO kg 25 kg D 52, 53 41 41 0 — C m g
‘
,
53 .
40 40
57.
104
. .
.
2,52,
. .
... Other (108)
.. 40,
...
(10)
Vessel
stowage
(bA)
D A 8 B 06 07 05 07 06 05 07 05 06 07 07 07 07 06 05 A C D
L L
L
kg kg kg kg kg .. kg kg
air-
30 60L
30 only
,
75 220 75kg 75 75kg 7Skg
and
100 100 100 100 100
(98)
.
Forbidden Forbidden cratt Forbidden Forbidden Forbidden Forbidden Fothidden Forbidden Forbidden Cargo
75)
limitations
(9)
L L
L
175
1 §517327 5L I
60
. 25kg 2kg 2kg 2Skg 25kg
(9A)
. Quantity (see . .
.
Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbiddan Forbidden Forbidden
Passenger aircraft/rail
..
.
......
. .
Bulk (SC)
None 242 243 242 None None None None None None None None None None None Nona None None None None 240 242 None
.
.
.
.
..
...... ) .
.... .
.
... . .
.
(8) ..
(SB)
224 202 201 203 62 62 62 62 62 62 62 62 62 62 62 62 62 62 62 302 213 202 302
(5173 Packaging
.
. .
. . ...
,
...
(8A)
150 150 None None None None None None None None None None None None None None None None None None None None None
2
TPI
Tb,
TP27
TP33
T2,
TABLE_Continued 86,
Ti.
TP8, 102)
lB3, 82, provision5
(7)
lP3,
TP1,
TP2.TP7,T3
AS,
(5172
t82,T4,TP1,TPS
lBS.
A3, Special Til,
Al, MATERIALS
......
.
(6)
.
Label
Codes
. 1.40 1.45 biG 1.30 4.1 3 3 1.40 i.4S 1.10 I.4S 1.30 1.40 1.40 bIG 1.20 1.30 1.4S 2.1 S 41 2.3,6
l
II It l II II It II It It II It II
Ill
HRDOUS
(5)
(4)
dent:- 172.101
fication
Numbers UN3240 UN12SS UNO191 UN0194 UN0195 UN0373 UN0505 UN0506 UN0193 § uN0192 UN0492 UN0493 UN0196 uN0197 UN0507 UN2203 UN0313 UN0487 UN1346 UN1816 UN1859
3 1 5
4S 4S or 4.1 4G 3G 4G 40 20 30 2 .3G 41 23
1 1 I 110 1,4S 145 1 1 1.10 1.4G 1.1G I 1 1 1
(3)
Hazard
class Division
Forbidden
,
,,
,
.
de
tetra
tempera- Charges
water-ac
water-acti
Signal names
Fluorositicic p,
Silicon descriptions
‘ explosive explosive explosive explosive
.. see
see
see
type
.
see
ship ship ship (2) ship
c.
shipping
distress, track, track, track, track,
hand hand amorphous (do)
materials solid Contrivances,
acid,
etc.
charges.
ship etc. highway. proper
see
distress, distress, distress, distress, railway railway railway railway hand. smoke smoke smoke smoke smoke chloride,
powder. tetrachtoride tetrafluoride controlled devices, devices,
oil
acetylide
and
Hazardous lure shaped, vated, vices, tivated, acid. chloride.
Self-reaCtIVe Shale Shaped Signal Signal Signals, Signals, Signals. signals, Signals. Signals, Signals, Signals, Signals. Signals. Signals, Signals. Signals. Signals. Signals. Silane SilicoflUOric Silicon Silicon Silicon Silicon Silver
0
(1)
hots
Sym-
II 81, Silver arsenite 6,1 UN1683 II 6.1 188, P2, lP4, T3, TP33 153 212 242 25 kg 100 kg A -o Silver aside (dry) Forbidden II Silver chlorite (dry) Forbidden CD II 6.1 A Silver cyanide 6.1 UN1684 1B8, lP2, 1P4, T3, TP33 153 212 242 25 kg 100 kg 40, 52 Silver (dry) fulminate Forbidden 5.1 CD Silver nitrate 5.1 UN1493 188, P2, 1P4, T3, TP33 152 212 242 5 kg 26 kg A 0 Silver oxalate (dry) Forbidden Silver picrate (dry) Forbidden 0. II Silver picrate, wetted with not less 4.1 UN1347 4.1 23 None 211 None Forbidden Forbidden D 28, 36 = than 30 percent water, by mass. 0 UN1906 N Sludge, acid 8 8 A3, A7, 62, 1B2,N34, None 202 242 Forbidden 30 L C 14 0 T8, TP2, TP28 D Smokeless powder for small arms 4.1 NA3178 4.1 16 None 171 None Forbidden 7.3 kg A (100 pounds or less). 0C Soda lime with more than 4 percent 8 UN1907 Ill 8 lB8, P3, Ti, TP33 154 213 240 26 kg 100 kg A 52. sodium hydroxide. Sodium 4.3 UN1428 4.3 A7, A8, A19, A20, B9, None 211 244 Forbidden 15 kg 0 52 0 B48, 868, 1B4,IP1, N34, Ill CD T9, TP7, TP33, TP46 A Sodium aluminate, solid UN2812 8 188, lP3, TI, TP33 154 213 240 25 kg 100 kg A 0 (n Sodium aluminate, solution UN1819 II 8 82, 1B2,T7, TP2 154 202 242 1L 30 L A 52. 8 A III 1B3,T4, TP1 154 203 241 5L 60 L 52. U) Sodium aluminum hydride 4.3 UN2835 II 4.3 A8, A19, A20, 1B4,T3, 151 212 242 Forbidden 50 kg E 52 a CD II TP33 Sodium ammonium vanadate 6.1 UN2863 6.1 88, P2, 1P4, T3, TP33 153 212 242 25 kg 100 kg A Sodium arsanilate 6.1 UN2473 Ill 6.1 lB8, 1P3, Ti, TP33 153 213 240 100 kg 200 kg A 6.1 6.1 A Sodium arsenate UN1685 II 188, 1P2, 1P4,T3, TP33 153 212 242 25 kg 100 kg a. UN1686 II 153 Sodium srsenite, aqueous solutions 6.1 6.1 lB2, T7, TP2 202 243 5L 60 L A 3 Ill 6.1 183, T4, TP2 153 203 241 60 L 220 L A Sodium arsenite, solid 6.1 UN2027 II 6.1 1B8, 1P2, lP4, T3, TP33 153 212 242 25 kg 100 kg A 6.1 II 6.1 Sodium azide UN1687 188, 1P2, lP4 153 212 242 25 kg 100 kg A 36, 52, 91 0 Sodium bitluoride, see Sodium -I hydrogenditluoride. Sodium bisulfite, solution, see Bisulfites, aqueous solutions, no.s.. Sodium borohydride 4.3 UN1426 4.3 N40 None 211 242 Forbidden 15 kg 8 52 UN3320 II Sodium borohydride and sodium hy 8 8 62, 162, N34, T7, TP2 154 202 242 1L 30 L A 52 droxide solution, with not more than 12 percent sodium boro hydride and not more than 40 per cent sodium hydroxide by mass. A 52 Ill 8 B2, 183, N34, T4, TP2 154 203 241 5L 60 L A A 56, 58 Sodium bromate 5.1 UN1494 II 5.1 lB8, lP2, 1P4, T3, TP33 152 212 242 5 kg 25 kg cm II A 52 Sodium cacodylate 6.1 UN1688 II 6.1 lB8, 1P2, lP4, T3, TP33 153 212 242 25 kg 100 kg Sodium carbonate peroxyhydrate 5.1 UN3378 5.1 188, 1P2,lP4, T3, TP33 152 212 240 5 kg 25 kg A 13, 48, 75 Ill 5.1 188, lP3, TI, TP33 152 213 240 25 kg 100 kg 13, 48, 0 75 C Ca, C)
() -Ti C —‘ 58 52 52 58 52 52 52 52 13 36 36 56 58, /33 133 56, Other (lOB) 56, 40, 28, 56, 56, 58, 69, (10) Vessel stowage tjofl )1OA) 8 A B B B A B A A B 10 B A E E L L L L kg kg kg kg kg kg 5L air- 30 30 30 60 only 25 50 50 25 15kg 220L 50kg and 0.5 200 (98) craft Forbidden Cargo limitations (9) L L kg 175.75) kg kg kg kg 1L 1L §173.27 1L 5L 5 kg 5 5 5 1kg 60 2.5 15kg 0.5 100 (9A) Quantity (see Forbidden Passenger aircrattirail Bulk (BC) 240 241 241 240 242 243 242 243 242 243 None 241 None None 241 ...... (8) bulk (88) Non- - 212 202 203 212 213 211 201 211 201 202 203 62 211 211 212
[ (173.**) Packaging ...... (8A) tions Excep- — 152 152 152 153 None None None 153 None None 153 None None None None T3, TP1 TP1 N84 N41 N34, N34, N74, N75, N74, N74, TP33 TP33 TP13 TP33 TP33 TP33 TPI3 TP27 TP28 TP33 TP13, TP13, T4, T4, lP2, TABLE—Cont)nued 67, 1P4, T3, 1P4, T3, TI, T6, T6, lB2, 1B3, N41, N74, TP2, TP2, TP2, TP2, lB2, lB2, lB6, provisions P2, (7) lP3, IP1, 1P2, B77, N75, B77, B77, A19, A20, A19, 172.102) T7, 677, T14, T14, A2, T11, A2, ) A20, 1B8, 168, 1B7, A8, A8, B69, B69, 669, N75, 869, Special N75, A9, A9, 188, 23, MATERIALs A19, 162, (6) 6.1. Label Codes 5.1 5.1 5.1 5.1 6.1 6.1 6.1 6.1 6.1 1.3C 6.1 6.1 4.1 4.2 4.1, I I II II II II II II Ill Ill Ill HAzARDous (5) PG (4) 172.101 Identi- fication Numbers UN1495 UN2428 UN2316 UN2317 UN1496 UN2659 UN1689 UN3414
§ UN3369 UN0234 UN1348 UN1384 or 5.1 5.1 6.1 5.1 6.1 6.1 6.1 6.1 4.1 4.1 4.2 1.3C (3) Hazard Division class or by So see hydro dinitro wetted wetted or dry percent percent blasting, water, solution etc. 15 names with 15 descriptions solid solution 10% acid Sodium than than or mixed Explosive aqueous (2) solid shipping solution than /ess materials less see mass. mass. /ess with proper dinitro-o-cresotate, dinitro-o-cresolate, dinitro-o-cresolate, ch/orate by by dichloroisocyanurate dithionite chlorate chlorate, dich/oro-s-triazinetrione, cuprocyanide, chlorite chloroacetate cuprocyanide, cyanide, cyanide not C. not and Hazardous toluene, type dium Dichloroisocyanuric with wetted water, wate, mass. with sulfite. Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium Sodium (1) bols Sym- cJI Sodium fluoride, solid 6.1 UN1690 Ill 6.1 188, P3, Ti, TP33 153 213 240 100 kg 200kg A 52 - Ill Sodium fluoride solution 6.1 UN3415 6.1 1B3,T4, TP1 153 203 241 60 L 220L A 52 -D 6.1 6.1 Sodium fluoroacetate UN2629 Ill 187, P1, T6, TP33 None 211 242 5 kg 50kg 6 CD 6,1 6.1 Sodium fluorosilicate UN2674 88, 1P3, Ti, TP33 153 213 240 100 kg 200kg A 52 D Sodium hydrate, see Sodium hydrox . . CD ide, solid. Q Sodium hydride 4.3 UN1427 4.3 A19, N40 None 211 242 Forbidden 15kg 6 52 Sodium hydrogendifluorido 8 UN2439 II 8 88, 1P2, 1P4,N3, N34, 154 212 240 15 kg 50kg A 12, 25, a. II T3, TP33 40, S2 Sodium hydrosulfide, with less UN2318 than 4.2 II 4.2 A7, A19, A20, 186, lP2, None 212 241 15 kg 50kg A 52. a 25 percent water of crystallization. T3, TP33 N Sodium hydrosulfids with not less 8 UN2949 8 A7, 188, 1P2, lP4, T7, 154 212 240 15 kg 50kg A 52 a than 25 water of II percent crys II TP2 a. tallization. 0 C Sodium hydrosulfite, see Sodium (I, dithionite. 8 8 Sodium hydroxide, solid 8 UN1823 8 188, P2, 1P4, T3, TP33 154 212 240 15 kg 50kg A 52. Sodium hydroxide solution UN1824 8 B2, lB2, N34, T7, TP2 154 202 242 1L 30L A 52. a Ill 83, N34, T4, TPI 154 203 241 5L 60L A 52. CD Sodium hypochlorite, solution, see a Hypochlorite solutions etc. U, Sodium metal, liquid alloy, see Alkali U, metal alloys, liquid, no.s.. a Sodium rnethylate 4.2 UN1431 II 4.2, 8 A7, A19, 185, 1P2,T3, None 212 242 kg B 15 50kg CD II TP33 Sodium methylate solutions in alco 3 UN1289 3, 8 lB2, T7, TP1, TP8 150 202 243 1L 5L B hol. Ill 3, 8 Bi, 183, T4, TP1 150 203 242 5L 60L A a- 8 Sodium monoxide UN1825 II 8 188, 1P2, 1P4, T3, TP33 154 212 240 15 kg 50kg A 52. 3 Sodium nitrate 5.1 UN1498 Ill 5.1 Al, A29, 1B8,lP3, Ti, 152 213 240 25 kg 100kg A TP33 Ill Sodium nitrate and potassium nitrate 5.1 UN1499 5.1 Al, A29, 1B8,lP3, TI, 152 213 240 25 kg 100kg A mixtures. Ill TP33 152 —I0 Sodium nitrite 5.1 UN1500 5.1, Al, A29, lB8, lP3, TI, 213 240 25 kg 100kg A 56, 58 6.1. TP33 153 Sodium pentachlorophenate 6.1 UN2567 6.1 1B8, 1P2, P4, T3, TP33 212 242 25 kg 100kg A 152 Sodium perborate monohydrate 5.1 UN3377 Ill 5.1 188, P3, Ti, TP33 213 240 25 kg 100kg A 13, 48, 75 5.1 152 Sodium perchlorate 5.1 UN1502 186, P2, T3, TP33 212 242 5 kg 25kg A 56, 58 5.1 5.1 152 Sodium permanganate UN1503 II 1B6, P2, T3, TP33 212 242 5 kg 25kg 0 56, 58, 5.1 138 Sodium peroxide 5.1 UN1504 A20, 185, lPl, N34 None 211 None Forbidden lSkg B 13, 52, 5.1 66, 75 Sodium peroxoborate, anhydrous 5.1 UN3247 5.1 1B8, 1P2, 1P4, T3, TP33 152 212 240 5 kg 25kg A 13,25 5.1 Sodium psrsulfate UN1505 Ill Al, 188, 1P3, Ti, TP33 152 213 240 25 kg 100kg A 58, 145 Sodium phoaphide 4.3 UN1432 4.3, Ai9, N40 None 211 None Forbidden 15kg 5 40, 52, 6.1. 85 picramate, dry or wetted with l.3C UN0235 1.3C Sodium I None...162 INone Forbidden Forbidden 10 SE less than 20 percent watei by mass. 0 C
-n ‘0, C) C) m 0 0
36
52
75
40 40 85
40
52
52,
52,
28, (lOB)
Other 66,
13,
40,
(10)
Vessel
stowage
(10A) Lca-
E
A 6 A B B 6 08 08 6 0 07 C 07 A
A
air
30L
only
15kg
15kg 50kg 50kg 50kg 50kg 15kg
and
100kg 100kg
100kg
)9B)
craft Forbidden Forbidden Forbidden Forbidden Forbidden
Cargo
limitations
(9)
175.75)
§173.27
1L
15kg 15kg lSkg 15kg
25kg 25kg 25kg
(9A)
Quantity (see
Forbidden
Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden
aircraftlrail
Passenger ......
(8C) Bulk
None
241 240.... None
240.... 240 240 62 62 62 62 240.... None 242.... 242 242 ....
(8)
bulk (SB)
Non-
211 212 212 211 212 212 212 62 62 62 202 211 62 213 304 212
)i73.***)
Packaging ......
(8A)
tiOfls
Excep-
None 154
None None 154 151 153 154 None None 154 None None None None 153
b
1
N41
N34
N40 TP2
N34,
TP33 TP33 TP33 TP33 TP33 TP33
TP33
P1,
T7
TABLE—Continued
P2,
T3, A19, T3, T2, T3, T3, Ti,
A19, T3,
66, 182
provisions
66, P4, P2, A8,
(7) P4,
1B2, lBS.
1P3,
172.102)
B2
23,
(
P2, 49, 48,
lBS. IBS,
A20, 1P2,
A20,
Special
47,
MATERIALS 1B8,
168,
A19,
I ......
(6) ......
2.1. 6.1.
Label
Codes
4.1 5.1 1.1F 1.10 4.2 8 1.2F 1.2D 6.1 8 4.1 8 8 2.3,
4.3, 6.1
II II II II II II II
Ill
HAzARDOUS
(5)
PG
(4) 1385
172.101
Identi
ficalion
Numbers UN1349 UN1849 UN UN2547 UN3244 UN3175 UN3243 UN0296 UN0375 UN0204 UN0374 § UN1827 UN2440 UN1433 UN2676 UN1691
I
8
8
8 8
or
4.1 5.1 4.2 4.1 .2F 6.1
4.3 2.3 6.1
I 1.1F
1.10
1.20
(3)
Hazard
Division class
Forbidden
Forbidden
or
by
not
not
bor
liquid, acid
liquid,
Potas
Sodium percent
no.5.
with
with
Batteries,
water;
or
see metal
30
names
Selenates
descriptions
water.
see
liquid,
wetted
than
etc
corrosive
flammable alloys,
see
explosive explosive explosive explosive
Hydrochloric
wet,
hydrated percent
Ferrous
toxic (2)
anhydrous
shipping
pentahydrate
anhydrous
alloys.
less
percent ride
peroxide 20 see
materials
see
Igniters
30
crystallization.
ranit
with devices, devices, devices, devices, arsenite
proper
sulfide, salt;
picramste,
selenate,
of piciyl potassium batteries,
sultide, superoxide tel
containing than
see phosphide chloride, chloride
sodium containing
etc.
than
of
containing
etc.
swart;
and
Hazardous mass. water less Selenites. sulfide sium less no.5.. no.5..
wet
ings,
Sodium Sodium Sodium Sodium
Sodium Sodium Solids Sodium Sodium
Solids Sounding Squibs, Solids Sounding Spirits Sounding Sounding Stannic Stannic Steel Stannic Storage Strontium Stibine
G
G G
(1)
bols
Sym
00 NoneNone
Strontium chlorate 5.1 UN1506 5.1 Al, A9, 1B8, P2, 1P4, 152 212 242 5 kg 25kg A 56, 58 N34, T3, TP33 5.1 5.1 Strontium nitrate UN1507 Ill Al A29, 1B8, 1P3, Ti 152 213 240 25 kg 100kg A TP33 5.1 Strontium perchlorate UN1508 5.1 CD 5.1 66, P2, T3, TP33 152 212 242 5 kg 25kg A 56, 58 Strontium peroxide UN1509 5.1 186, 1P2, T3, TP33 152 212 242 5 kg 25kg A 13, 52, 0 66, 75 Strontium phosphide 4.3 UN2013 4.3, A19, N40 None 211 None Forbidden 15kg 6 40, 52, 0. 6.1. 85 x Strychnine or Strychnine salts 6.1 UN1692 Ill 211 0 6.1 187, IP1, T6, TP33 None 242 5 kg 50kg A 40 N Styphnic acid, see Trinitroresorcinol, 0 etc. 0. Styrene monomer, stabilized 3 UN2055 3 B1, 1B3,T2, TP1 150 203 242 60 L 220L A 0 UN0357 C G Substances, explosive, no.s ilL IlL None 62 None Forbidden Forbidden 86, (I, 14E, 15E, 178. 0 G, Substances, explosive, no.s l.2L UN0358 l.2L 62 None Forbidden Forbidden 8E, CD 14E, 0 15E, (I, 176. C’, G Substances, explosive, n.o.s l.3L UN0359 1.3L 62 None Forbidden Forbidden 86, 0 14E, CD 15E, 17E. G Substances, explosive, no.s l.1A UN0473 l,1A 111 None 62 None 12 G Forbidden Forbidden 0. Substances, explosive, n.o.s l.1C UN0474 l.lC None 62 None Forbidden Forbidden 10 G Substances, explosive, no.s liD UN0475 1.1D None 62 None Forbidden Forbidden 10 3 Substances, explosive, no.5 l.1G UN0476 1,1G.. None 62 None Forbidden Forbidden 08 G Substances, explosive, no.s l.3C UN0477 1,3C None 62 None Forbidden 10 G Forbidden Substances, explosive, no.s 1.3G UN0478 l.3G None 62 None Forbidden Forbidden 08 G UN0479 62 0 G Substances, explosive, no.s l.4C 1.4C None None Forbidden 75kg 09 -I G Substances, explosive, no.s l.4D UN0480 l.4D None 62 None Forbidden 75kg 09 G Substances, explosive, no.s 1.4S UN0481 1.4S None 62 None 25 kg 75kg 05 Substances, explosive, no.s l.4G UN0485 l.4G None 62 None Forbidden 75kg 08 Substances, explosive, very insensi i.5D UN0482 l.5D None 62 None Forbidden Forbidden 10 tive, no.s. or Substances,EVI, no.5. Substituted nitrophenol pesticides, UN2780 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden B 40 ...... I 30L liquid, flammable, toxic, flash point less than 23 degrees C. 3, 6.1 182, Til, TP2, TP13, 150 202 243 1L 60L B 40 TP27 Ce) Substituted nitrophenol pesticides, 6.1 UN3014 6.1 T14, TP2, TP13, TP27 None 201 243 1L 30L 8 40 liquid, toxic. Ill 6.1 182, Til, TP2, TP13, 153 202 243 5L 60L B 4° TP27 C 6.1 1B3,T7, TP2, TP28 153 203 241 60 L 220L A 40 — •1 C C) 0 0 m 0 0 40 40 40 40 40 40 74 61 74 52 40 40 40 40 74. 19, (lOB) 14, 14,40 Other 40, 19, (10) Vessel stowage tic (IOA) B 8 D A A A A A A A D C A C C C C A air- 30L 60L Limit only 2.5L 2.SL 50kg 220L and 100kg 100kg 100kg 150kg 200kg (9B) No Forbidden Forbidden Forbidden Forbidden craft Forbidden Forbidden Cargo limitations (9) 173.27 L 175.75) kg kg kg kg kg kg 1L 5L §5 5 60 Limit 25 25 75 25 100 (9A) Quantity (see No Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Passenger aircraWrail 315. 315. Balk (SC) — 242 243 243 242 242 314, 240 240 240 240 314, 243 247 247 245 244 243 244 (8) bulk (88) Non- 173.”) 202 None 201 212 None 213 213 304 203 211 — 201 304 213 213 302 201 227 227 ( Packaging ... (8A) lions Excep- 153 153 153 153 None 154 None None None None None None None None 306 None None None 3 1P2 TP2 TP3 TP3 BlO, B49, B74. T20, TP4, TP2, TP33 TP27 TP27 TP28 TP33 TP33 TP33 TP19 TP33 TP45 TP13 TP1 TP13, TP26, lB8, Ti, TI, TABLE—Continued T3, Ti, T20, Ti, Ti, T6, 832, N34, AlO, T20, B32, T20, T50, TP2, TP2, TP2, 30, TP13, TP38, 1B3, 161, TP25, P3, provisions (7) 1P4, lP3, IP1, 1P3, A7, N34, Ti, 614, 172.102) 884, N34, 814, N34, B14, Til, 30, 30, (5 A3, 3, 1P2, 188, 188, 1B7, 1B8, 163, B9, B9, TPI3, 677, 5, 877, 877, lB2, Special 2, 2, 30, T14, TP2, MATERIALS 188, Bi. A3, A7, 3 3 8 8 6.1 (6) 6.1 Label Codes 6.1, 6.1,3 6.1 6.1 6.1, 8 9 6.1 8 2.2 2.3, 9 4.1 2.3, 8, 4.1 8.... 8, Ill Ill Ill Ill Ill Ill Ill HAz,RDOuS (5) PG (4) 172.101 Identi- Numbers UN2779 UN3013 NA13SO UN1350 UN1079 UN2967 UN1828 UNIO8O NA2448 UN2448 UN2418 UN1829 UN1831 UN1831
§ 8 9 8 9 8 8 8 or fication 6.1 6.1 2.3 2.2 2.3 4.1 4.1 (3) Hazard Division class Forbidden Forbidden of than point percent chlorides C. Sulfurous Hydrogen less flash pesticides, pesticides. 30 mixtures oxide. names fri descriptions see see with Sulfur with frioxide. loose (dry) degrees sulfur (2) see shipping 23 rate flammable, sulfur stabilized fuming solution, materials fuming nitrophenol nitrophenol free hydrogen, chlorate, than proper acid toxic, octanit acid, acid, toxic. molten molten dioxide dichloride, and chlorides hexafluoride dioxide tetraftuoride trioxide, less and percent more free Hazardous liquid, not solid, 30 acid. or sulfide. Substituted Sucrose Substituted Sulfur Sulfamic Sulfur Sulfur Sulfur Sulfur Sulfur Sulfur Sulfur Sulfur, Sulfuretted Sulfur Sulfur, Sulfur Sulfuric Sulfuric + D 0 (1) bols Sym- CD0(0
Sulfuric acid, spent 8 UN1832 II 8 A3, A7, B2, 683, 884, None 202 242 Forbidden 30 L C 14 II 182, N34, T8, TP2 -D 8 C Sulfuric acid with more than 51 per 8 UN1830 II A3, A7, 83, 883, B84, 154 202 242 1L 30 L 14 cent acid. 1B2,N34, T8, 8 TP2 Sulfuric acid with not more than 51% 8 UN2796 A3, A7, B2, B15, lB2, 154 202 242 1L 30 L B acid. . N6, N34, TB, TP2 0 Sulfuric and hydrofluoric acid mix II tures, see Hydrotluoric and sulfuric 0. acid mixtures. = Sulfuric anhydride, see Sulfur tn- 8 oxide, stabilized. 0N Sulfurous acid 8 UN1833 B3, 1B2,T7, TP2 154 202.... 242.... 1L 30L B 40 — + Sulfuryl chloride 8 UN1834 II 8, 6.1 1, 86, 89, 810, 614, None ... 226 .... 244 Forbidden Forbidden C 40 830, B77, N34, T22, C TP2, TP38, TP44 Sulfuryl fluoride 2.3 UN2191 2.3 4 None ... 304 314, Forbidden Forbidden D 40 315. 0 Tars, liquid including road asphalt 3 UN1999 3 149, B13, 62, T3, TP3, 150 202 242 5L 60 L B m and oils, bitumen and cut backs. TP29 3 Ill 81, 813, 183, Ti, TP3 150 203 242 60 L 220 L A 0 Tear gas candles 61 UNI700 II 6.1, None ... 340 None Forbidden 50 kg D 40 4.1. C,, Tear gas cartridges, see Ammunition, 0 CD tear-producing, etc. D -a D Tear gas devices with more than 2 6.1 NA1693 II 6.1 None 340 .... None Forbidden Forbidden 40 percent tear gas substances, by mass. 0.. 6.1 None ... 340 .... None Forbidden Forbidden D 40 3 Tear gas devices, with not more than 2 percent tear gas substances, by mass, see Aerosols, etc. Tear gas grenades, see Tear gas candles. -I G Tear gas substances, liquid, no.s. 6.1 UN1693 II 6.1 None 201 None Forbidden Forbidden U 40 II 6.1 182 None 202 None Forbidden 5L U 40 G Tear gas substance, solid, no.s 6.1 UN3448 6.1 T6, TP33 None 211 242 Forbidden Forbidden D 40 6.1 D 68, IP2, P4, T3, TP33 212 242 Forbidden 25 kg 6.1 None B 40 Tellurium compound, n.o.s 6.1 UN3284 1B7, P1, TB, TP33 None 211 242 5 kg 50 kg 6.1 188, 1P2, 1P4, T3, TP33 153 212 242 25 kg 100 kg B Ill 6.1 IBS, lP3, Ti, TP33 153 213 240 100 kg 200 kg A Tellurium hexafluoride 2.3 UN2195 2.3, 8 None 302 None Forbidden Forbidden U 40 Terpene hydrocarbons, no.e 3 UN2319 Ill 3 61, 183, T4, TP1, TP29 150 203 242 60 L 220 L A Ill Terpinolene 3 UN2541 3 81, 83, T2, TP1 150 203 242 60 L 220 L A Tetraazido benzene quinone Forbidden A Tetrabromoethane 6.1 UN2504 Ill 6.1 lB3, T4, TP1 153 203 241 60 L L 220 A 6,1 6.1 1,1,2,2-Tetrachloroethane UN1702 II 1B2, N36, T7, TP2 153 202 243 5L 60 L A 40 6.1 6.1 Tetrachloroethylene UN1897 Ill 1B3, N36, T4, TP1 153 203 241 60 L 220 L 40 6.1 6.1 Tetraethyl dithiopyrophosphate UN17O4 II 182, T7, TP2 153 212 242 25 kg 100 kg D 40 Tetraethyl silicate 3 UN1292 Ill 3 B1, 1B3,T2, TP1 150 203 242 60 L 220 L A § 172.101 HAzARDous MATERIALSTABLE—Continued C0
(8) (9) (10) F’., Vessel Hazard Identi Packaging Quantity limitations stowage 0 Sym- Hazardous materials descriptions Label Special provisions 173)’) (see 173.27 and bole and proper shipping names class or fication PG Codes ( § Division Numbers ( 172.102) — 175.75) Excep- Non- Bulk Other tions bulk Passenger Cargo air- tjofl aircraft/rail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (bA) (lOB)
Tetraethylammonium perchlorate Forbidden (dry). Tetraethylenepentamine 8 UN2320 Ill 8 1B3,T4, TP1 154 203 241 5L 60L A 52. 1,1,1,2-Tetratluoroethane or Refrig 2.2 UN3159 2.2 T50 306 304 314, 75 kg 150kg A erant gas R 134a. 315. Tetrsfluoroethylene, stabilized 2.1 UN1O81 2.1 306 304 None Forbidden 150kg F 40 Tetrafluoromethane or Refrigerant 2.2 UN1982 2.2 None 302 None 75 kg 150kg A gas R 14. I ,2,3,6-Tetrshydrobenzaldehyde 3 UN2498 Ill 3 61, 183, T2, TP1 150 203 242 60 L 220L A Tetrahydrofuran 3 UN2056 II 3 1B2,T4, TP1 None 202 242 5L 60L B 3 3 Tetrahydrofurfurylsmine UN2943 Ill Bi, 1B3,T2, TP1 150 203 242 60 L 220L A 8 Ill 8 Tetrahydrophthalic anhydrides with UN2698 lB8, lP3, TI, TP33 154 213 240 25 kg 100kg A more than 0.05 percent of maleic anhyd ride. 3 3 I ,2,3,6-Tetrahydropyridine UN2410 150 3 lB2, T4, TP1 202 242 5L 60L B 8 UN2412 150 Tetrshydrothiophene II 8 182, T4, TP1 202 242 5L 60L B II 154 Tetramethylammonium hydroxide, UN3423 82, 1B8,lP2, 1P4, T3, 213 240 15 kg 50kg A 52 solid. 8 II 8 TP33 154 Tetramethylammonium hydroxide so UN1835 B2, 162, T7, TP2 202 242 1L 30L A 52 lution. 8 154 Ill 82, 183, T7, TP2 203 241 5L SQL A 52 ‘0 Tetramethylene diperox/de Forbidden dicarbamide. C-) Tetramethylsilane 3 UN2749 3 A7, T14, TP2 None 201 243 Forbidden 30L D Tetranitro diglycerin Forbidden C) Tetranitrosniline liD UN0207 lID None 62 None Forbidden Forbidden 10 + UN1510 Tetrsnitromethane 5.1 5.1, 2, 632, T20, TP2, TP13, None 227 None Forbidden Forbidden D 40, 66 6.1. TP38, TP44 2,3,4, 6-Tetranitrophenol Forbidden 2,3,4, 6-Tetranitrophenyl methyl nitra Forbidden mine. 2,3,4,6-Tetranitrophenylnitramine Forbidden Tetranitroresorcinol (dry) Forbidden 0 2,3,5,6-Tetranitroso-1,4- Forbidden m dinitrobenzene. 0. 2,3,5, 6-Tetranitroso nitrobenzene Forbidden (dry). 0 Tetrapropylorthotitanate 3 UN2413 III 3 81, 183, T4, TP1 150 203 242 60 L 220L A Tetrazene, see Guanyl - nitrosanilnoguanyltetrazens, Tetrazine (thy) Forbidden CD Tetrazol-1-acetic acid 1.4C UN0407 II 1.4C None 62 None Forbidden 75kg 09 D 1H-Tetrazole liD UN0504 liD None 62 None Forbidden Forbidden B 18, SE CD Tetrazolyl azide (dry) Forbidden Tetryl, see 0 Trinitrophenylmethylnitramine. 0 Textile waste, wet 4.2 UN1857 Ill 4.2 151 213 240 Forbidden Forbidden A 0 Thallium chlorate 5.1 UN2573 5.1, 1B6,1P2, T3, TP33 152 212 242 5 kg 25kg A 56, 58 N 6.1. 0 Thallium compounds, no.s 6.1 UN1707 II 6,1 1B8, 1P2, lP4, T3, TP33 153 212 242 25 kg 100kg A 0. 6.1 II Thallium nitrate UN2727 6.1, 1B6, 1P2, T3, TP33 153 212 242 5 kg 25kg A 0 5.1, C 6.1 4-Thiapentanal UN2785 Ill 6.1 163, T4, TP1 153 203 241 60 L 220L D 25, 49 UN2436 150 Thioacetic acid 3 II 3 1B2,T4, TPI 202 242 5L 60L B 0 Thiocarbamate pesticide, liquid, flam 3 UN2772 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30L B 40 mable, toxic, flash point less than CD 23 degrees C. 3, 6.1 0 1B2,Til, TP13, TP27 150 202 .... 243 1L 60L B 40 Thiocarbamate pesticide, liquid, toxic, 6.1 UN3005 6.1, 3 T14, TP2, TP13 None ... 201 .... 243 1L 30L B 40 U, flammable, flash point not less 0 than 23 degrees C. CD 6.1, 3 182, Til, TP2, TP13, 153 202 243 5L 60L B 40 TP27 153 Ill 6.1, 3 163, T7, TP2, TP28 203 242 60 L 220L A 40 0. Thiocarbamate pesticide, liquid, toxic 6.1 UN3006 6.1 T14, TP2, TP13 None 201 243 1L 30L B 40 6.1 1B2,Til, TP2, TP13, 153 202 243 5L 60L B 40 3 Ill TP27 D 6.1 lB3, T7, TP2, TP28 153 203 241 60 L 220L A 40 6.1 Thiocarbamate pesticides, solid, toxic 6.1 UN2771 6.1 1B7,IPI, T6, TP33 None 211 242 5 kg 50kg A 40 V 6.1 1B8,1P2, 1P4,T3, TP33 153 212 242 25 kg 100kg A 40 0 Ill 188, 1P3, Ti, TP33 153 213 240 100 kg 200kg A 40 -I Thiocarbonylchloride, see Thiophoxgene. 6.1 6.1 Thioglycol UN2966 lB2, T7, TP2 153 202 243 5L 60L A Thioglycolic acid 8 UN1B4O 8 A7, B2, 1B2, N34, T7, 154 202 242 IL 30L A TP2 Thiolactic acid 6.1 UN2936 6.1 62, T7, TP2 153 202 243 5L 60L A Thionyl chloride 8 UN1836 8 B6, 610, N34, Tb, TP2, None 201 243 Forbidden Forbidden C 40 TP13 3 Thiophene 3 UN2414 162, T4, TP1 150 202 242 5L 60L 6 40 Thiophosgene 6.1 UN2474 6.1 2, 89, 614, B32, N33, None 227 244 Forbidden Forbidden B 40, 52 Ill N34, T20, TP2, TP38, cm TP45 Thiophosphoryl chloride 8 UN1837 8 A3, A7, B2, B8, 625, None 202 242 Forbidden 30L C 40 182, N34, T7, TP2 Thiourea dioxide 4.2 UN3341 4.2 186, lP2, T3, TP33 None 212 241 15 kg 50kg U 0 4.2 lB8, lP3, Ti, TP33 None 213 241 25 kg 100kg D §172.101 HAzARDous MATERIALSTABLE—Continued C0)
(8) (g) (10) Vessel Packaging Quantity limitations Sym- Hazardous materials descriptions Hazard Identi- 73,***) stowage 0 Label Special provisions 1 (see 173.27 and bols and proper shipping names class or fication ( § Division Numbers Codes ( 172.102) —— — 175,75) Excep- Non- Other tions bulk Bulk Passenger I Cargo air- aircraWrail I craft only (1) (2) (3) (4) (5) (6) (7) (8A) (88) (8C) (9A) (98) (1OA) (108) Tin chloride, fuming, see Stannic chloride, arihydrous. Tin perchloride or Tin tetrachloride, see Stannic chloride, anhydrous. Tinctures, medicinal 3 UN1293 3 1B2,T4, TP1, TP8 150 202 242 5L 60L B 3 Ill 81, 163, T2, TP1 150 203 242 60 L 220L A Tinning flux, see Zinc chloride Tires and tire assemblies, see Air, compressed or Nitrogen, com pressed. Titanium disuiphide 4.2 UN3174 III 4.2 188, lP3, Ti, TP33 None 213 241 25 kg 100kg A Titanium hydride 4,1 UN1871 4.1 A19, A20, 84, N34, T3, None 212 241 15 kg 50kg E TP33 Titanium powder, dry 4.2 UN2546 4.2 None 211 242 Forbidden Forbidden D 4.2 A19, A20, 186, 1P2, N5, None 212 241 15 kg 50kg D N34, T3, TP33 III 4.2 188, 1P3, TI, TP33 None 213 241 25 kg 100kg D Titanium powder, wetted with not 4.1 UN1352 4.1 A19, A20, lB6, 1P2, N34, None 212 240 i5 kg 50kg E 74 less than 25 percent water (a visi T3, TP33 ble excess of water must be present) (a) mechanically pro duced, particle size less than 53 microns; (b) chemically produced, -n0 particle size less than 840 microns. Titanium sponge granules or Tita 4.1 III UN2878 4.1 Al, 188, 1P3, TI, TP33 None ... 213 .... 240 .... 25kg 100kg D 74 C) nium sponge powders. + Titanium tetrachloride 8 UN1838 II 8, 6.1 2, B7, B9, Bi4, B32, None ... 227 .... 244 .... Forbidden Forbidden C 40 B77, T20, TP2, TP13, TP38, TP45 Titanium trichloride mixtures 8 UN2869 II 8 A7, 188, lP2, 1P4, N34, 154 212 240 15 kg 50kg A 40 T3, TP33 8 Ill A7, 168, 1P3,N34, Ti, 154 213 240 25 kg 100kg A 40 TP33 0 Titanium trichloride, pyrophoric or Ti 4.2 UN2441 4.2, 8 N34 None 181 244 Forbidden Forbidden D 40 m tanium trichloride mixtures, 0 pyrophoric. TNT mixed with aluminum, see 0 Tritonal. TNT, see Trinitrotoluene, etc Toluene 3 UN1294 Il 3 lB2, T4, TP1 150 202 242 5 L 60 L B V + Toluene disocyanate 6.1 UN2078 II 6.1 1B2,T7, TP2, TP13 153 202 243 5 L 60 L 0 . 25,40 Toluene sulfonic acid, see Alkyl, or 5 Aryl sulfonic acid etc. + Toluidines, liquid 6.1 UN17OB II 6.1 1B2,T7, TP2 153 202 243 5 L 60 L A o Toluidines, solid 6.1 UN3451 Il 6.1 1B8, 1P2, lP4, T3, TP33 153 212 242 25 kg 100 kg A 2,4-Toluylenediamine, solid or 2,4- 6.1 UN1709 III 6.1 lB8, lP3, TI, TP33 153 213 240 100 kg 200 kg A Toluenediamine, solid = 2,4-Toluylenediamine solution or 2,4- 6.1 UN3418 III 6.1 lB3, T4, TP1 153 203 241 60 L 220 L A Toluenediamine solution N Torpedoes, liquid fueled, with inert 1.3J UN0450 II 1.3J 62 None Forbidden Forbidden 04 23E — head 0. Torpedoes, liquid fueled, with or with- 1.IJ UN0449 II 1.1J 62 None Forbidden Forbidden 04 236 out bursting charge. Torpedoes with bursting charge lIE UN0329 II 1.16 62 62 Forbidden Forbidden 03 Torpedoes with bursting charge liE UN0330 II 1.1F 62 None Forbidden Forbidden 08 Torpedoes with bursting charge 1.10 UN0451 II liD 62 62 Forbidden Forbidden 03 —
G Toxic by inhalation liquid, no.s. with 6.1 UN3381 I 6.1 1, B9, B14, 630, T22, None 226 244 Forbidden Forbidden D 40 an inhalation toxicity lower than or TP2, TP13, TP27, TP38, equal to 200 ml/m3 and saturated TP44 vapor concentration greater than or equal to 500 LC50.
G Toxic by inhalation liquid, no.s, with 6.1 UN3382 I 6.1 2, 69, B14, 832, T20, None 227 244 Forbidden Forbidden D 40 an inhalation toxicity lower than or TP2, TP13, TP27, TP38, cji equal to l000ml!m3 and saturated TP45 vapor concentration greater than or equal to 10 LC5O.
G Toxic by inhalation liquid, flammable, 6.1 UN3383 I 6.1,3 1, 89, 814, B30, T22, None 226 244 Forbidden Forbidden 0 40 —. n.o.s. with an inhalation toxicity TP2, TP13, TP27, TP38, lower than or equal to 200 ml/m3 TP44 and saturated vapor concentration greater than or equal to 500 LC5O 0
G Toxic by inhalation liquid, flammable, 6.1 UN3384 I 6.1, 3 2, 89, 814, B32, T20, None 227 244 Forbidden Forbidden D 40 no.s. with an inhalation toxicity TP2, TP13, TP27, TP38, lower than or equal to 1000 ml/m3 TP45 and saturated vapor concentration greater than or equal to 10 LC5O.
G Toxic by inhalation liquid, water-reac- 6.1 UN3385 I 6.1, 1, B9, B14, 830, T22, None 226 244 Forbidden Forbidden D 40 tive, no.s. with an inhalation tox- 4.3 TP2, TP13, TP38, TP44 icity lower than or equal to 200 ml! m3 and saturated vapor concentra tion greater than or equal to 500 LC5O.
G Toxic by inhalation liquid, water-reac- 6.1 UN3386 I 6.1, 2, B9, B14, B32, T20, None 227 244 Forbidden Forbidden D 40 tive, no.s. with an inhalation lox- 4.3 TP2, TP13, TP38, TP44 — icity lower than or equal to 1000 ml/m3 and saturated vapor con centration greater than or equal to o 10 LC5O — § 172.101 HAZARDOUS MATERIALsTABLE—Continued Go,
(8) (9) T (10) Vessel Hazard Identi- Packaging Quantity limitations C Sym- Hazardous materials descriptions Label Special provisions 173.) (see 17327 and bols and proper shipping names class or fication PG ( § Division Numbers Codes ) 172.102) 175.7[ Excep- Non- Bulk Other tions bulk Passenger Cargo air aircrattlrail craft only
(1) (2) (3) (4) (5) (6) (7) (BA) (88) (8C) (9A) (98) (bA) (108)
G Toxic by inhalation liquid, oxidizing, 6.1 UN3387 6.1, 1, B9, B14, B30, T22, None ... 226 ... 244 Forbidden Forbidden D 40 n.o.s. with an inhalation toxicity 5.1. TP2, TPI3, TP38, TP44 lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LCSO. G Toxic by inhalation liquid, oxidizing, 6.1 UN3388 6.1, 2, 89, 814, B32, T20, None ... 227 .... 244 Forbidden Forbidden 0 40 ri.o.s. with an inhalation toxicity 5.1. TP2, TP13, TP38, TP44 lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC5O. G Toxic by inhalation liquid, corrosive, 6.1 UN3389 6.1,8 1, 89, B14, 830, T22, None ... 226 ... 244 Forbidden Forbidden 0 40 n.o.s. with an inhalation toxicity TP2, TP13, TP27, TP38, lower than or equal to 200 ml/m3 TP44 and saturated vapor concentration greater than or equal to 500 LC5O. G Toxic by inhalation liquid, corrosive, 6.1 UN3390 6.1,8 2, 89, B14, 832, T20, None ... 227 .... 244 Forbidden Forbidden 0 40 n.o.s. with an inhalation toxicity TP2, TP13, TP27, TP38, lower than or equal to 1000 ml/rn3 TP45 and saturated vapor concentration greater than or equal to 10 LC5O. G Toxic liquid, corrosive, inorganic, 6.1 UN3289 6.1, 8 T14, TP2, TP13, TP27 None 201 243 0.5 L 2.5L A n.o.s. 0 II 6:1,8 82, Til, TP2, TP27 153 202 243 1L 30L A G Toxic liquid, inorganic, no.5 6.1 UN3287 6.1 T14, TP2, TPI3, TP27 None 201 243 IL 30L A C) 6.1 1B2,Ti i, TP2, TP27 153 202 243 5L 60L A Ill 6.1 1B3,T7, TP1, TP28 153 203 241 60 L 220L A G Toxic liquids, corrosive, organic, 6.1 UN2927 6.1,8 T14, TP2, TPi3, TP27 None 201 243 0.5 L 2.5L B 40 —‘ n.o.x.. 6.1, 8 lB2,T11,TP2TP27 153 202 243 1L 30L B 40 G Toxic liquids, flammable, organic, 6.1 UN2929 6.1, 3 T14, TP2, TP13, TP27 None 201 243 1L 30L 8 40 no.5.. 6.1, 3 lB2, Til, TP2, TP13, 153 202 243 5L 60L B 40 C TP27 m G Toxic, liquids, organic, n.o.s 6.1 UN2810 6.1 Ti4, TP2, TP13, TP27 None 201 243 IL 30L B 40 2- II 6.1 1B2,Tii, TP2, TP13, 153 202 243 5L 60L B 40 TP27 Ill 6.1 83, T7, TPI, TP28 153 203 241 60 L 220L A 40 G Toxic liquids, oxidizing, no.5 6.1 UN3122 6.1, A4INone...1201 243 Forbidden 2.5 L C 5.1. 6.1, 62 153 202 243 1L 5L C CD 5.1.
G Toxic liquids, water-reactive, s.o.s. 6.1 UN3123 6.1, A4 None 201 243 Forbidden 1L B 40 CD 4.3. 0 6.1, 1B2 None 202 243 1L 5L E 40 D 4.3. 0. G Toxic solid, corrosive, inorganic, 6.1 UN3290 6.1,8 87, T6, TP33 None 211 242 1 kg 25 kg A = S.O.S.. 0 1B6, 1P2, T3, TP33 153 212 242 15 kg 50 kg A N 6.1,8 A G Toxic solid, inorganic, n.o.s 6.1 UN3288 6.1 lB7, T6, TP33 None 211 242 5 kg 50 kg 0 6.1 A 168, 1P2, 1P4,T3, TP33 153 212 242 25 kg 100 kg A 0. 6.1 Ill 1B8, 1P3, Ti, TP33 153 213 240 100 kg 200 kg 0 G Toxic solids, 6.1 C corrosive, organic, UN2928 6.1,8 1B7,T6, TP33 None 211 242 1 kg 25 kg B 40 C’, n.o.s.. 6,1,8 1B6, 1P2, T3, TP33 153 212 242 15 kg 50 kg B 40 0 G Toxic solids, flammable, organic, 6,1 UN2930 6.1, 1B6,T6, TP33 None 211 242 1 kg 15 kg B n.o.s.. 4.1. CD 6.1, 1B8, 1P2, 1P4, T3, TP33 153 212 242 15 kg 50 kg B 0 4.1, G Cl, Toxic solids, organic, no.5 6.1 UN2811 6.1 87, T6, TP33 None 211 242 5 kg 50 kg B U, 6.1 1B8, 1P2, 1P4, T3, TP33 153 212 242 25 kg 100 kg B 0 Ill 6.1 188, 1P3, Ti, TP33 153 213 240 100 kg 200 kg A G CD Toxic solids, oxidizing, n.o.s 6.1 UN3086 6.1, T6, TP33 None 211 242 1 kg 15 kg C 5.1. 6.1, 1B6, P2, T3, TP33 153 212 242 15 kg 50 kg C > 5.1. 0. G Toxic solids, self-heating, no.5 6.1 UN3124 6.1, A5, T6, TP33 None 211 242 5 kg 15 kg D 40 4.2. 6.1, lBS. 1P2, T3, TP33 None 212 242 15kg 50 kg D 40 G 4.2. Toxic solids, water-reactive, no.5 6.1 UN3125 6.1, A5, T6, TP33 None 211 242 5 kg 15 kg C 40 0 4.3. -I 6.1, 1B6, 1P2, T3, TP33 153 212 242 15 kg 50 kg C 40 G 4.3. Toxins, extracted from living sources, 6.1 UN3172 6.1 141 None 201 243 IL 30 L 8 40 liquid, no.5.. 6.1 141, 1B2 None 202 243 5L 60 L B 40 G Ill 6.1 141, 1B3 153 203 241 60 L 220 L B 40 B Toxins, extracted from living sources, 6.1 UN3462 6.1 141, 187, IP1, T6, TP33 None 211 243 5 kg 50 kg solid, no.5.. B 6.1 141, 188, lP2, 1P4, T3 None 212 243 25 kg 100 kg TP33 Ill 6.1 141, 1B8, P3, Ti TP33 153 213 241 100 kg 200 kg A CO) D Toy Caps 1.4S NA0337 II 1.4S None 62 None 25 kg 100 kg 05 II
i Tracers for ammunition 1.3G UN0212 1.3G None 62 None Forbidden Forbidden 07 Tracers for ammunition 1.4G UN0306 1.4G None 62 None Forbidden 75 kg 06 Tractorx, xee Vehicle, etc C Tri-(b-nitroxyethyl) ammonium nitrate Forbidden C
C.) C0 -n C) C m 0
0. 8 13 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 136 (lOB) Other 25, (10) Vessel stowage tiofl (bA) B B 8 B A A B B D — A A A A B 0 B A A A A A A A L L L L L L L L L L L L L L kg kg kg kg air- 60L 30L 30 60 30 60 60 60 30 60 60 only 220L 50 220 50 220 220 220 220 and 100 200 (9B) craft Forbidden Forbidden Cargo limitations (9) 173.27 L L L L L L 175.75) kg kg kg kg 1L 1L IL
§ 5L 5L IL 5L 5L 5L 5L 60 5 60 60 60 60 60 15 25 100 (9A) Quantity (see Forbidden Forbidden Forbidden aircraftlrail Passenger Bulk (8C) 241 242 243 243 243 243 243 241 242 242 243 242 242 240 —— 240 243 244 241 242 241 243 241 241 ...... (8) bulk (8B) Non- 173.*) 203 201 203 202 201 202 203 201 202 203 211 211 212 213 202 212 202 203 202 227 203 203 203
( Packaging ...... (SA) tions Excep- 153 None 150 None None 153 153 153 153 153 153 153 None None 154 154 None 153 154 153 153 153 None 63 TP1 182. TP2 TP2 TP1 TP2 TP1 N34, N34, N34, TP27 TP27 TP27 TP27 TP28 TP27 TP28 TP33 TP33 TP27 TP33 TP33 TP33 TP45 TPI3, TPI3, TP13, T4, B2, T7, T7, T4, TP1 T4, T4, TP1 T4, 17, TABLE—Continued T6, T3, Ti, 1P4, T3, 183, 832, TP2, TP2, TP7, TP2, TP2, TP2, TP13, TP13, TPI3, TP38, A7, 182, 183, 182, provisions (7) N34, N36, N36, A7, IP1, lP4, lP3, 1P2, T7, T7, 172.102) B14, T21, TIl, Til, Til, 81,63, TP2, TP2, TP2,
( A6, 88, 1B3, 163, 187, 1P2, 168, lB3, 183, B9, A3, A6, l82, 182, 182, Special A3, 2, T14, T14, T14, T20, TP2, A7,
MATERIALS 1B8, I 3 6.1 (6) 6.1 Label Codes 3,8.... 3,6.1 6.1 3, 6.1 6.1 6.1,3 6.1, 6.1,3 6.1 6.1 6.1 6.1 6.1 4.2 8 8, 8 6.1 8 6.1 6.1 6.1 I II II III III Ill Ill Ill Ill Ill Ill Ill
HAzARDous (5) PG (4)
172.101 Identi- fication Numbers UN2764 UN2609 UN2610 UN2998 UN2997 UN2763 UN2542 UN1839 UN3254 UN2442 UN2321 § UN2564 UN2322 UN2831 UN171O
I I 3 3 8 8 8 or 6.1 6.1 6.1 6.1 4.2 6.1 6.1 6.1 6.1 6.1 (3) Hazard Division class 23 de with flam 23 than available dry, flammable, toxic toxic, names toxic than less descriptions not solution less liquid, liquid, liquid, solid, liquid percent (2) Trichloroisocyanuric shipping point 39 acid acid, chloride point materials see C. proper flash than pesticides, C. pesticides, pesticides, flash pesticides, dry. borate and Hazardous toxic, mable, degrees grees acid, more chlorine, Triallyl Triazine Triazine Trichloro-s-triazinetrione Triallylamine Triazine 1,1,1-Trichloroethane Triazirie Tributylamine Tributylphosphane Trichloroacetic Trichloroacetic Trichloroacetyl Trichloroethylene Trichlorobenzenes, Trichiorobutene + (1) bols Sym- E’3 00 0.0V
Trichioroisocyanuric acid, dry 5.1 UN2468 5.1 1B8, 1P2, 1P4,T3, TP33 152 ...... 212 .... 240 .... 5kg 25kg A 13 Trichloromethyl perchlorate Forbidden Trichlorosilane 4.3 UN1295 4.3, 3, N34, T14, TP2, TP7, None ... 201 ,... 244 .... Forbidden Forbidden D 21,28, 8. TP13 40, 49, 100 (D Tricresyl phosphate with more than 3 6.1 UN2574 6.1 A3, 1B2,N33, N34, T7, 153 202 243 5L 60 L A percent ortho isomer. TP2 0 Triethyl phosphite 3 UN2323 III 3 BI, 1B3,T2, TP1 150 203 242 60 L 220 L A Triethylamine 3 UN1296 3, 8 182, T7, TP1 150 202 243 1L 5L B 40 8 = Triethylenetetramine UN2259 8 82, 1B2,T7, TP2 154 202 242 1L 30 L B 40,52 8 0 Trifuoroacetic acid UN2699 8 A3, A6, A7,B4, N3, None 201 243 0.5 L 2.5 L B 12,40 N34, N36, T1Q, TP2 Trifuoroacetyl chloride 2.3 UN3057 2.3, 8 2, B7, B9, B14, T50, None 304 314, Forbidden Forbidden D 40 TP21 315. D C Trifluorochloroethylene, stabilized 2.3 UN1OS2 2.3, 3, B14, T50 None 304 314, Forbidden Forbidden 40 2.1. 315. Tritluoromethane or Refrigerant gas 2.2 UN1984 2.2 306 304 314, 75 kg 150 kg A R 23. 315. 0 Trifluoromethane, refrigerated liquid 2.2 UN3136 2.2 T75, TP5 306 None 314, 50 kg 500 kg D CD 315. 0 1,1,1-Trifluoroethane or Refrigerant 2.1 UN2035 2.1 T50 306 304 314, Forbidden 150 kg B 40 gas, R 143a. 315. C,, 6.1 2-Trifuoromethylaniline 6.1 UN2942 Ill lB3 153 203 241 60 L 220 L A 3-Trifuorornethylaniline 5.1 UN2948 6.1 lB2, T7, TP2 153 202 243 5L 60 L A 40 Triformoxime trinitrate Forbidden UN2324 150 A Trisobutylene 3 III 3 B1, lB3, T4, TP1 203 242 60 L 220 L A 3 150 Trisopropyl borate 3 UN2616 III 82, T4, TP1 202 242 5L 60 L A 3 B1, lB3, T2, TPI 150 203 242 60 L 220 L D Trirnethoxysilane 6.1 NA9269 6.1,3 2, 89, 814, 832, T20, None 227 244 Forbidden Forbidden E 40 TP4, TP13, TP38, TP45 Trimethyl borate 3 UN2416 3 52, T7, TP1 150 202 242 5L 60 L B Trirnethyl phosphite 3 UN2329 Ill 3 81, 183, T2, TPI 150 203 242 60 L 220 L A 1,3,5-Trimethyl-2,4, 8-trinitrobenzene Forbidden 0 Trimethylacetyl chloride 5.1 UN2438 6.1,8, 2, 83, 89, 614, 632, None 227 244 Forbidden Forbidden D 25,40 3. N34, T20, TP2, TP13, TP38, TP45 Trimethylamine, anhydrous 2.1 UN1083 2.1 N87, T50 306 304 .... 314, Forbidden 150kg B 40 315. Trimethylamine, aqueous solutions 3 UN1297 3, 8 Til, TP1 None ... 201 .... 243 0.5 L 2.5L D 40, 135 with not more than 50 percent trimethylamine by mass. 3, 8 81, lB2, T7, TP1 150 202 243 1L 5L B 40, 41 Ill 3, 8 61, 83, T7, TP1 150 203 242 5L 60 L A 40, 41 1,3,5-Trimethylbenzene 3 UN2325 Ill 3 81, 183, T2, TP1 150 203 242 60 L 220 L A Trimethylchlorosilane 3 UN1298 3, 8 A3, A7, 877, N34, T10, None 206 243 1L 5L 8 40 GO TP2, TP7, TP13 Trirnethylcyclohexylamine 8 UN2326 Ill 8 1B3,T4, TP1 154 203 241 5L 60 L A Trimethylene glycol diperchlorate Forbidden Ill Trirnethylhexamethylene disocyanate 6.1 UN2328 Ill 6.1 1B3,T4, TP2, TPI3 153 203 241 60 L 220 L B 241 C Trimethylhexamethylenediamines 8 UN2327 8 183, T4, TP1 154 203 5L 60 L A §172.101 HAzARDOUSMATERIALSTABLE—Continued c0 -J (8) (9) 1 (10) Vessel Packaging Quantity limitations stowage Sym- Hazardous matedals descriptions Hazard Identi- C class or fication Label Special provisions 173.) (see 173.27 and bole and proper shipping names Codes 172.102) ( § LI Division Numbers ( — — 175 75) Excep- Non- Other tions bulk Bulk Passenger irl tion aircraft/rail craft only
(1) (2) (3) (4) (5) (6) (7) ISA) (8B( (8C) (9A) (9B) (1OA) (lOB)
Trirnethylolnitromethane trinitrate Forbidden Trinitro-meta-cresol lID UNO21S II 1.10 None ,.. 62 None Forbidden Forbidden 10 SE 2,4,6-Trinitro-l,3-diazobenzene Forbidden 2,4,6-Trinitro-l,3,5-triazido benzene Forbidden (dry). Trinitroacetic acid Forbidden Trinitroacetonitrile Forbidden Trinitroamine cobalt Forbidden Trinitroaniline or Picramide 1.10 UN0153 II lID None 82 None Forbidden Forbidden 10 Trinitroanisole 1.10 UN0213 II liD None 62 None Forbidden Forbidden 10 Trinitrobenzene, wetted, with not less 4,1 UN3367 I 4.1 162, AS. A19, N41, N84 None 211 None 0.5 kg 0.5kg E 36 than 10% water, by mass. Trinitrobenzene, dry or wetted with liD UNO214 II 1.10 None 62 None Forbidden Forbidden 10 less than 30 percent water, by mass.
Trinitrobenzene, wetted with not less 4.1 UN1354 I 4.1 23, A2. A8, A19, N41 None 211 None 0.5 kg 0.5kg E 28 than 30 percent water, by mass. Trinitrobenzenesulfonic acid 1.10 UNO3SS II 1.10 None 62 None Forbidden Forbidden 10 SE Trinitrobenzoic acid, dry or wetted liD UN0215 Il 1.10 None 62 None Forbidden Forbidden 10 with less than 30 percent water, by mass. ‘0 Trinitrobenzoic acid, wetted with not 4.1 UN3368 I 4.1 162, AS, A19, N41, N84 None ... 211 .... None 0.5 kg 0.5kg E 36 () less than 10% water by mass, -I, Trinitrobenzoic acid, wetted with not 4.1 UN1355 I 4.1 23, A2, A8, A19, N41 None ... 211 .... None 0.5 kg 0.5kg B 28 less than 30 percent water, by C, mass. Trinitrochlorobenzene or Picryl chlo 1.10 UN0155 II 1.10 None ... 62 None Forbidden Forbidden 10 ride.
Trinitrochlorobenzene (picryl chlo 4.1 UN3365 I 4.1 162, A8, A19, N41, N84 None ... 211 .... None 0.5 kg 0.5kg E 36 ride), wetted, with not less than 10% water by mass. Trinitroethanol Forbidden Trinitroethylnitrate Forbidden 0 Trinilrotluorenone 1.10 UN0387 II 1.10 None 62 None Forbidden Forbidden 10 m Trinitromelhane Forbidden 0 l,3,5-Trinitronaphthalene Forbidden Trinitronaphthalene 1.10 UN0217 II liD None 62 None Forbidden Forbidden 10 0 Trinitrophenetole 1.10 UN0218 II lID None 62 None Forbidden Forbidden 10 N0.C>
Trinitrophenol (picric acid), wetted, 4.1 UN3364 4.1 162, A8, A19, N41, N84 None ... 211 .... None 0.5 kg 0.5kg 8 36 3! with not less than 10 percent water .t3 by mass. CD Trinitrophenol or Picric acid, dry or liD UN0154 liD None ... 62 None Forbidden Forbidden 10 SE wetted with less than 30 percent CD watet by mass. 0 Trinitrophenol, wetted or Picric acid, 4.1 UN1344 4.1 23, A8, A19, N41 None ... 211 None 1 kg 15kg E 28,36 wetted, with not less than 30 per 0. cent water by mass. = 2,4,6-Trinitrophenyl guanidine (dry) Forbidden 0 2,4,6-Trinitrophenyl nitramine Forbidden 0 2,4,6-Trinitrophenyl trimethylol methyl Forbidden nitramine trinitrate (dry). 0 Trinitrophenylmethylnitramine or Tet liD UN0208 lID None ... 62 None Forbidden Forbidden 10 ryl. (I, Trinitroresorcinol or Styphnic acid, liD UN0219 liD None ... 62 None Forbidden Forbidden 10 5E dry or wetted with less than 20 0 percent wate, or mixture of alco CD hol and watei by mass. Trinitroresorcinol, wetted or Styphnic liD UN0394 None ... 62 None Forbidden Forbidden 10 SE acid, wetted with not less than 20 U, percent water, or mixture of alco liD U, hol and water by mass. 0 2,4,6-Trinitroso-3-methyl Forbidden CD nitraminoanisole. Trinitrotetramine cobalt nitrate Forbidden Trinitrotoluene and Trinitrobenzene liD UN0388 None ... 62 None Forbidden Forbidden 10 0. mixtures or TNT and 3 trinitrobenzene mixtures or TNT and hexanitrostilbene mixtures or Trinitrotoluene and hexanitrostilnene mixtures. liD 0 Trinitrotoluene mixtures containing liD UN0389 None ... 62 None Forbidden Forbidden 10 —I Trinitrobenzene and Hexanitrostilbene or TNT mixtures containing trinitrobenzene and hexanitrostilbene. Trinitrotoluene or TNT, dry or wetted liD UNQ2O9 liD None ... 62 None Forbidden Forbidden 10 with less than 30 percent water, by mass. Trinitrotoluene (TNT), wetted, with 4.1 UN3366 4.1liD 162, A8, A19, N41, N84 None ... 211 .... None 0.5 kg 0.5kg E 36 not less than 10 percent water by mass. 4.1 Trinitrotoluene, wetted or TNT, 4.1 UN1356 23, A2, A8, A19, N41 None ... 211 .... None 0.5 kg 0.5kg F 28, 36 LO) wetted, with not less than 30 per cent water by mass. Tripropylamine 3 UN2260 3, 8 81, 83, T4, TPI 150 203 .... 242 5L 60L A 40 Tripropylene 3 UN2057 3 182, T4, TP1 150 202 .... 242 5L 60L B C 3 81, 183, T2, TP1 150 203 .... 242 60 L 220L A § 172.101 HAzARDous MATERIALS TABLE—Continued (0,
(8) (9) (10) Vessel Hszard Identi- Packaging Quantity imitations stowage 0 Sym- Hazardous materials descriptions Label Special provisions i73.) (see 173.27 and bols and proper shipping names class or fication PG ( § Division Numbers Codes (172.1O2) 175.75) Excep- Non- Bulk Other tions bulk Passenger Cargo air- tjofl aircraWrait craft only (1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (1OA) (108)
Tris-(1-aziridinyl)phosphine oxide, II so 6.1 UN2501 6.1 182, T7, TP2 153 202 243 5L 60 L A lution. III 6.1 lB3, T4, TP1 153 203 241 60 L 220 L A Tris, bis-bifluoroamino diethoxy pro Forbidden pane (TVOPA). Tritonal 1.10 UN0390 II 1.10 None 62 None Forbidden Forbidden 10 Tungsten hexafluoride 2.3 UN2196 2.3, 8 2, N86 None 338 None Forbidden Forbidden 0 40 Turpentine 3 UN1299 III 3 Bi, lB3, T2, TP1 150 203 242 60 L 220 L A 3 Turpentine substitute UN1300 I 3 Til, TPI, TP8, TP27 None 201 243 IL 30 L 8 II 3 182, T4, TP1 150 202 242 5L 60 L B III 3 81, lB3, T2, TP1 150 203 242 60 L 220 L A C’) Undecane 3 UN2330 III 3 81, 1B3,T2, TPI 150 203 242 60 L 220 L A —1 Urea hydrogen peroxide 5.1 UN1511 lIt 5.1,8 Al, A7, A29, 1B8, 1P3, 152 213 240 25 kg 100 kg A 13 C’) Tl, TP33 Urea nitrate, dry or wetted with less 1.10 UN0220 II 1.10 119 None 62 None Forbidden Forbidden 10 than 20 percent watet by mass.
Urea nitrate, wetted, with not tess 4.1 UN3370 I 4.1 162, A8, A19, N41, N84 None 211 None 0.5 kg 0.5 kg E 36 than 10 percent water by mass. E Urea nitrate, wetted with 4.1 I not less UN1357 4.1 23, 39, A8, A19, N41 None 211 None 1 kg 15 kg 28, 36 than 20 percent water, by mass. Urea peroxide, see Urea hydrogen peroxide. B C) Valeraldehyde 3 UN2058 II 3 82, T4, TP1 150 202 242 5L 60 L -Il Valeric acid, see Corrosive liquids, 0.0.5.. 8 C) Valeryl chloride II UN2502 8, 3 A3, AS, A7,82, 162, 154 202 243 iL 30 L C 40 p. N34, T7, TP2
Vanadium compound, n.o.s 6.1 UN3285 I 6.1 lB7, IPi, T6, TP33 None 211 242 5 kg 50 kg B II 6.1 lB8, lP2, lP4, T3, TP33 153 212 242 25 kg 100 kg B III 6.1 188, P3, TI, TP33 153 213 240 100 kg 200 kg A Vanadium oxytrichloride 8 UN2443 II 8 A3, A6,A7, B2, 816, 154 202 242 Forbidden 30 L C 40 182, N34, T7, TP2 Vanadium pentoxide, non-fused form 6.1 UN2862 III 6.1 188, lP3, Ti, TP33 153 213 240 100 kg 200 kg A 40 0 Vanadium tetrachloride 8 UN2444 I 8 A3, A6, A7,B4, N34, None 201 243 Forbidden 2.5 L C 40 m Tb, TP2 0. 8 Vanadium trichloride UN2475 III 8 188, lP3, Ti, TP33 154 213 240 25 kg 100 kg A 40 Vanadyl sulfate 6.1 UN2931 It 6.1 188, 1P2, 1P4, T3, TP33 153 212 242 25 kg 100 kg A 0 Vehicle, flammable gas powered 9 UN3166 9 135, 157 220 220.... 220.... Forbidden No limit A Vehicle, flammable liquid powered 9 UN3166 ‘9 135, 157 220 220 220 No limit No limit A . .... Very signal cartridge, see Cartridges, signel. CD 3 Vinyl acetate, stabilized UN13O1 3 1B2,T4, TP1 150 202 242 5L 60L B D Vinyl bromide, stabilized 2.1 UN1085 2.1 N86, T50 306 304 314, Forbidden 150kg B 40 CD 315. a Vinyl butyrate. stabilized 3 UN2838 3 182, T4, TP1 150 202 242 5L 60L B Vinyl chloride, stabilized 2.1 UN1086 2.1 21, 844, N86, T50 306 304 314, Forbidden 150kg B 40 a. 315. x Vinyl chloroacetate 6.1 UN2589 6.1.3 162, Ti, TP2 153 202 243 5L 60L A a Vinyl ethyl ether, stabilized 3 UN1302 3 A3, T11, TP2 None 201 243 1L 30L 0 N Vinyl fluoride, stabilized 2.1 UN1860 2.1 N86 306 304 314, Forbidden 150kg F 40 a 315. a. Vinyl isobutyl ether, stabilized 3 3 1B2, TP1 150 0 UN1304 T4, 202 242 5L 60L B C Vinyl methyl ether, stabilized 2.1 UN1087 2.1 844, T50 306 304 314, Forbidden 150kg 8 40 ‘ft 315. Wnyl nitrate polymer Forbidden Vinylidene chloride, stabilized 3 UN1303 3 T12, TP2, TP7 150 201 243 1L 30L E 40 a Vinylpyridines, stabilized 6.1 UN3073 6.1,3, IB1, T7, TP2, TP13 153 202 243 1L 30L B 21, 40, CD 8. 52. 0 Vinyltoluenes, stabilized 3 UN2618 Ill 3 Bi, 1B3.T2, TP1 150 203 242 60 L 220L A (ft Vinyltrichlorosilane, stabilized 3 UN1305 3, 8 A3, A7, B6, N34, Tb, None 206 243 1L 5L B 40 C,, TP2, TP7, TP13 0 rocket with burster or 1.4D 1.4D Warheads, ex UN0370 None 62 62 Forbidden 75kg 02 CD pelling charge. Warheads, rocket with burster or ex 1.4F UN0371 1.4F None 62 None Forbidden Forbidden 08 pelling charge. > 0. Warheads, rocket with bursting liD UN0286 liD None 62 62 Forbidden Forbidden 03 charge. 3 Warheads, rocket with bursting 1.2D UN0287 1.2D None 62 62 Forbidden Forbidden 03 charge. Warheads, rocket with bursting 1.1F UN0369 1.1F None 62 None Forbidden Forbidden 08 charge. 0 Warheads, torpedo with bursting 1.1D UN0221 liD None 62 62 Forbidden Forbidden 03 - charge. G Water-reactive liquid, corrosive, n.o.s 4.3 UN3129 4.3, 8 T14, TP2, TP7 201 243 1L None Forbidden 0 4.3, 8 81, TIl, TP2 None 202 243 IL 5L F 85 Ill 4.3, 8 1B2,T7, TP1 None 203 242 5L 60L F 0 Water-reactive liquid, no.5 4.3 UN3148 4.3 T9, TP2, TP7 None 201 244 Forbidden 1L E 40 Ill 4.3 lBl, T7, TP2 None 202 243 1L 5L E 40 4.3 1B2,Ti, TP1 None 203 242 5L 60L E 40 G Water-reactive liquid, toxic, n.o.s 4.3 UN3130 4.3, A4 None 201 243 Forbidden 1L 0 6.1. 4.3, IB1 None 202 243 1L 5L E 85 6.1. Go, 1B2 Ill 4.3, None 203 242 5L 60L E 85 6.1. G Water-reactive solid, corrosive, no.5 4.3 UN3131 4.3, 8 1B4, IPI, N40, T9, TP7, None 211 242 Forbidden 15kg D TP33 C 4,3, 8 1B6, 1P2, T3, TP33 151 212 242 15 kg 50kg F 85 C
0 C0 ,, p.
0 m
C 0. 85 40 40 40 40 40 85 85 40 40 (108) Other 34, (10) Vessel stowage (bA) Li- E D E E E E 6 E 8 E E E E B E B D D A A A L L kg kg kg kg kg kg kg kg kg kg kg kg kg kg air- 60 only 15 15 50 15 50 15 50 50 50kg 220 and 100 100 100 100 100 100kg 200 (98) Forbidden craft Forbidden Forbidden Cargo limitations (9) 17327 L kg 175.75) kg kg kg kg kg kg kg kg kg kg kg
§ 5L 60 15 15 25 15 25 15 25 25 15 25 25 200 (9A) Quantity (see Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden Forbidden aircraft/rail Passenger Bulk (8C) — 242 242 241 241 242 242 214 242 241 242 214 241 242 242 241 240 241 242 242 241 240 ...... (8) bulk (8B) Non- 173:**) 213 211 212 213 211 212 213 214 212 214 — 211 213 211 212 213 202 203 213 216 212 213
( Packaging ...... (8A) lions Excep- 151 151 151 151 None 151 None None None None 151 None None 151 None 150 150 155 151 None None Ti, N40 N40 N40 TP1 TP8 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 TP33 P3, 84, T2,
TABLE—Continued IP1, T3, Ti, TI, T3, Ti, T3, Ti, T3, Ti, T3, Ti, TP1, TP7, 1P2, 1B3, provisions P4, 1B4, P2, (7) 184, T4, 186, 1P2, 1P4, lP2, lP4, 1P2, 1P4, lP3, T9, 172.102) 81, lB8, A8, ( lB2, 188. 187, 188, 185, 188, lBS. lB8, 1B8, lB6, N40, Special 156,
MATERIALS 149, lB4, 8 (6) 4.1. 5.1. 4.1. 4.1. 6.1. 5.1. 4.2. 6.1. 4.2. 4.2. 6.1. Label Codes 4,3, 4.3, 4.3, 4.3 4.3, 4.3, 4.3 4.3 4.3, 4.3, 4.3, 4.3, 4.3, 4.3, 3 3 4.3, 9 4.2 4.2 4.2 II II Ill Ill Ill Ill Ill Ill Ill Ill Ill Ill
HAzARDous (5) 306
172.101 ldenti- fication Numbers UN3132 UN2813 UN3135 UN3133 UN3134 UN1 § UN3342 UN2590 UN1387 9 3 or 4.3 4.3 4.3 4.3 4.3 4.2 4.2 (3) (4) Hazard Division class pow no.5. Battery acid actinolite, n.o.s flammable, names self-heating, see Battery descriptions oxidizing, no.s toxic, liquid or solid, (2) solid, shipping (chrysotile, Hydrofluoric tremotite). solid, solid, electric, solid, materials wet vehicle see proper chair, equipment. asbestos preservatives, acid, waste, and Hazardous n.s.a.. no.5.. powered anthophyltite, ered Water-reactive Water-reactive Wheel White Water-reactive, Water-reactive Water-reactive Wood Wool White Xanthates S S C C G
w Al (1) bols Sym- od
Xenon, compressed 2.2 UN2036 2.2 306, 302 None 75 kg 150 kg A 307. Xenon, refrigerated liquid (cryogenic 2.2 UN2591 2.2 T75, TP5 320 None None 50 kg 500 kg B CD liquids).
Xylenes 3 UN1307 3 1B2, T4, TP1I15O 1202.... 242 5L 60 L B CD Ill 3 81. 183, T2, TP1 150 203 242 60 L 220 L A 0 Xylenots, solid 6.1 UN2261 6.1 lB8, lP2, 1P4, T3, TP33 153 212 242 25 kg 100 kg A A Xylenols, liquid 6.1 UN3430 6.1 lB2, T7, TP2 153 202 243 5L 60 L 0. 6.1 6.1 A Xylidines, liquid UN171 1 1B2. T7, TP2 153 202 243 60 L 6.1 5L A x Xylidines, solid 6.1 UN3452 lB8. P2, 1P4, T3, TP33 153 212 242 25 kg 100 kg 6.1 0 bromide, liquid II Xylyt 6.1 UN17O1 A3, A6, A7. lB2,N33, None 340 None Forbidden 60 L D 40 0N 6.1 T7, TP2, TP13 6.1 B Xylyl bromide, solid UN3417 A3, A6, A7, 188, lP2, None 340 None 25 kg 100 kg 40 0. II 1P4, N33, T3, TP33 0 II C p-Xylyl diazide Forbidden 5.1 E C,, Zinc amrnonium nitrite 5.1 UN1512 6.1 1B8. lP2, 1P4, T3, TP33 None 212 242 5 kg 25 kg Zinc arsenate or Zinc arsenite or 6.1 UN1712 1B8, 1P2, 1P4,T3, TP33 153 212 242 25 kg 100 kg A Zinc arsenate and zinc arsenite 0 mistures. CD A Zinc ashes 4.3 UN1435 Ill 4.3 Al. A19, lB8, P4, Ti. 151 213 241 25 kg 100 kg 0 TP33 (I, Zinc bisulfite solution, see Bisulfites. (I, aqueous solutions, no.5.. A 0 Zinc bromate 5.1 Ill 5.1 Al, A29, lB8, lP3, Ti, 152 213 UN2469 240 25 kg 100 kg 56, 58 CD 1) TP33 A 5.1 Zinc chlorate 5.1 UN1513 II A9, lB8, 1P2, 1P4, N34, 152 212 242 5 kg 25 kg 56, 58 T3, TP33 A > Zinc chloride, anhydrous 8 UN2331 Ill 8 1B8, 1P3, Ti, TP33 None 213 240 25 kg 100 kg 0 Ill Zinc chloride, solution 8 UN1840 8 163, T4, TPI 154 203 241 5L 60 L A 3 Zinc cyanide 6.1 UN1713 6.1 lB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 52 Zinc dithionite or Zinc hydrosultite 9 UN1931 Ill None lB8, P3, Ti, TP33 155 204 240 100 kg 200 kg A 49 Zinc ethyl, Diethylzinc see Ill Zinc tluorosilicate 6.1 UN2855 6.1 68. 1P3, Tl, TP33 153 213 240 200 kg A 52 0 Zinc hydrosulfite. see Zinc dithionite -4 Zinc muriate solution, see Zinc chlo ride, solution. Zinc nitrate 5.1 UN1514 II 5.1 lB8, 1P2, P4, T3, TP33 152 212 240 5 kg 25 kg A II Zinc permanganate 5.1 UN1515 5.1 166, P2, T3, TP33 152 212 242 5 kg 25 kg D 56. 58, II 138 Zinc peroside 5.1 UN1516 5.1 lB6, lP2, T3, TP33 152 212 242 5 kg 25 kg A 13, 52, 66, 75 Zinc phosphide 4.3 UN1714 4.3, A19, N40 None 211 None Forbidden 15 kg E 40, 52, 6.1. 85 Zinc powder or Zinc dust 4.3 UN1436 4.3, A19, 184, P1, N40 None 211 242 Forbidden 15 kg A 52, 53 4.2. 4.3, Ai9, lB7, 1P2, T3, TP33 None 212 242 15kg 50 kg A 52, 53 4.2. Ill 4.3, 1B8, 1P4, TI, TP33 None 213 242 25 kg 100 kg A 52, 53 4.2. A 0 Zinc resinate 4.1 UN2714 Ill 4.1 Al, 186, Ti, TP33 151 213 240 25 kg 100 kg § 172.101 HAzARDous MATERIALS TABLE—Continued (0,
(8) (9) (10) Vessel Packaging Quantity limitations stowage Sym- Hazardous Hazard Identi- 73***) 0 materials descriptions Label Special provisions 1 (see 173.27 and bols and proper shipping names class or fication PG ( § Division Numbers Codes (172.102) — — 175.75) Escep- Non- Bulk Other tions bulk Passenger Cargo air- aircraftlrail craft only
(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (ftC) (9A) (9B) (1OA) (lOB) Zinc selenate, see Selenates or Selenites. Zinc selenite, see Selenates or Selenites. Zinc silicofltjoride, see Zinc fluorosilicate. Zirconium, dry, coiled wire, finished 4.1 UN2858 III 4.1 Al 151 213.... 240 25 kg 100 kg A metal sheets, strip (thinner than 254 microns but not thinner than 18 microns). Zirconium, dry, finished sheets, strip 4.2 UN2009 Ill 4.2 A1,A19 None ... 213 240 25 kg 100 kg D or coiled wire. 0, Zirconium hydride 4.1 UN1437 4.1 A19, A20, lB4, N34, T3, None ... 212 240 15 kg 50 kg F TP33 Zirconium nitrate 5.1 UN2728 Ill 5.1 Al, A29, 1B8, 1P3, Ti, 152 213 240 25 kg 100 kg A TP33 Zirconium picramate, dry or wafted 1.30 UN0236 II 1.3C None... 62 None Forbidden Forbidden 10 SE with less than 20 percent watet; by mass. Zirconium picramate, wetted with not 4.1 UN1517 4.1 23, N41 None ... 211 .... None 1kg 15kg D 28, 36 tess than 20 percent watet; by mass. C) -Il Zirconium powder, dry 4.2 UN2008 4.2 T21,TP7,TP33 None ... 211 242 Forbidden Forbidden U II 4.2 A19, A20, 166, 1P2, NS, None ... 212 241 15 kg 50 kg U C) N34, T3, TP33 U Ill 4.2 168, lP3, TI, TP33 None ... 213 241 25 kg 100 kg Zirconium powder, wetted with not 4.1 UN1358 II 4.1 A19, A20, 1B6,1P2, N34, None ... 212 241 15 kg 50 kg F 74 less than 25 percent water (a visi T3, TP33 ble excess of water must be present) (a) mechanically pro duced, particle size less than 53 microns; (b) chemically produced, 0 particle size less than 840 microns. m Zirconium scrap 4.2 UN1932 Ill 4.2 1B8, 1P3, N34, Tl, TP33 None 213 240 Forbidden Forbidden U 0. Zirconium suspended in a liquid 3 UN1308 3 None 201 243 Forbidden Forbidden B Ill 3 1B2 None 202 242 5L 60 L B 0 3 B 61, lB2 150 203 242 60 L 220 L Pipeline and Hazardous Materials Safety Admin., DOT § 172.101
CC
C C
LI) (N
C IN
CL)
(N
IL,
‘:1- I
(C) 0
(0 0 (I) zIN D
IL)
0
(0 0) E
0
N
277 § 172.101 49 CFP Ch. 1(10—1—10 Edition)
APPENDIx A TO § 172.101—LIST OF HAZARDOUS able quantity (RQ), in pounds and kilograms, SUBSTANCES AND REPORTABLE QUANTITIES for each hazardous substance listed in Col I. This appendix lists materials and their umn I of TABLE I. corresponding reportable quantities (RQ’s) 5. A series of notes is used throughout that are listed or designated as ‘hazardous TABLE I and TABLE 2 to provide additional substances” under section 101 (14) of the Com information concerning certain hazardous prehensive Environmental Response, Com substances. These notes are explained at the pensation, and Liability Act, 42 U.S.C. end of each TABLE. 9601(14) (CERCLA; 42 U.S.C. 9601 et seq). This 6. TABLE 2 lists radionuclides that are listing fulfills the requirement of CERCLA, hazardous substances and their cor 42 U.S.C. 9656(a), that all “hazardous sub responding RQ’s. The RQ’s in table 2 for stances,” as defined in 42 U.S.C. 9601(14), be radionuclides are expressed in units of curies listed and regulated as hazardous materials and terabecquerels, whereas those in table I under 49 U.S.C. 5101-5127. That definition in are expressed in units of pounds and kilo cludes substances listed under sections grams. If a material is listed in both table 1 311(b)(2)(A) and 307(a) of the Federal Water and table 2, the lower RQ shall apply. Radio Pollution Control Act, 33 U.S.C. 1321(b)(2)(A) nuclides are listed in alphabetical order. The and 1317(a), section 3001 of the Solid Waste RQ’s for radionuclides are given in the radio Disposal Act, 42 U.S.C. 6921, and section 112 logical unit of measure of curie, abbreviated of the Clean Air Act, 42 U.S.C. 7412. In addi “Ci”. followed, in pai-entheses, by an equiva tion, this list contains materials that the lent unit measured in tel-abecquerels, abbre Administrator of the Environmental Protec viated “TBq”. tion Agency has determined to be hazardous 7. For mixtures of radionuclides, the fol substances in accordance with section 102 of lowing requirements shall be used in deter CERCLA, 42 U.S.C. 9602. should noted It be mining if a package contains an RQ of a haz that 42 USC. 9656(b) provides that common ardous substance: (i) if the identity and and contract carriers may be held liable quantity (in curies or terabecquerels) of each under laws other than CERCLA for the re radionuclide in a mixture or solution is lease of a hazardous substance as defined in known, the ratio between the quantity per that Act, during transportation that com package (in curies menced before the effective date of the list or terabecquerels) and the RQ for the radionuclide ing and regulating of that substance as a must be determined hazardous material under 49 U.S.C. 5101-5127. for each radionuclide. A package contains an 2. This appendix is divided into two TA RQ of a hazardous substance when the sum of BLES which are entitled “TABLE I—HAZ the ratios for the radionuclides in the mix ARDOUS SUBSTANCES OTHER THAN ture or solution is equal to or greater than RADIONUCLIDES” and “TABLE 2—RADIO- one; (ii) if the identity of each radionuclide NUCLIDES.” A material listed in this appen in a mixture or solution is known but the dix is regulated as a hazardous material and quantity per package (in curies or a hazardous substance under this subchapter terabecquerels) of one or more of the radio if it meets the definition of a hazardous sub nuclides is unknown, an RQ of a hazardous stance in § 171.8 of this subchapter. substance is present in a package when the 3. The procedure for selecting a proper total quantity (in curies or terabecquerels) shipping name for a hazardous substance is of the mixture or solution is equal to or set forth in §172.101(c). greater than the lowest RQ of any individual 4. Column 1 of TABLE 1, entitled “Haz radionuclide in the mixture or solution; and ardous substance”, contains the names of (iii) if the identity of one or more radio those elements and compounds that are haz nuclides in a mixture or solution is unknown ardous substances. Following the listing of (or if the identity of a radionuclide by itself elements and compounds is a listing of waste is unknown), an RQ of a hazardous substance streams. These waste streams appear on the is present when the total quantity (in curies list in numerical sequence and ai-e referenced or terabecquerels) in a package is equal to or by the appropriate “D”. “F”, or “K” num greater than either one curie or the lowest bers. Column 2 of TABLE 1, entitled “Re RQ of any known individual radionuclide in portable quantity (RQ)”, contains the report- the mixture or solution, whichever is lower.
TABLE 1 TO APPENDIX A—HAzRDous SUBSTANCES OTHER THAN RADIONUCLIDES
Reportable Hazardous substance quantity (RQ) pounds (kilograms)
A2213 5000 (2270) Acenaphthene 100 (45.4) Acenaphthylane 5000 (2270) Acetaldahyde 1000 (454) Acetaldehyde, chloro- 1000 (454)
278 Pipeline and Hazardous Materials Safety Admin., DOT § 172.101
TABLE 1 TO APPENDIX A—HAzARDous SUBSTANCES OTHER THAN RADI0NucLIDEs—Continued
Reportable Hazardous substance quantity(RQ) (kilograms)
Acetaldehyde, trichioro- 5000 (2270) Acetamide 100 (45.4) Acetarnide, N-(aminothioxomethyl)- 1000 (454) Acetanjide, N-(4-ethoxyphenyl)- 100 (45.4) Acetamide, N-9H-fluoren-2-yI- 1 (0.454) Acetamide, 2-fluoro- 100 (45.4) Acetic acid 5000 (2270) Acetic acid, (2,4-dichlorophenoxy)-, salts & esters 100 (45.4) Acetic acid, ethyl ester 5000 (2270) Acetic acid, fluoro-, sodium salt 10 (4.54) Acetic acid, Iead(2+) salt 10 (4.54) Acetic acid, thallium(1+) salt 100 (45.4) Acetic acid, (2,4,5-trichiorophenoxy)- 1000 (454) Acetic anhydride 5000 (2270) Acetone 5000 (2270) Acetone cysnohydrin 10 (4.54) Acetonitrile 5000 (2270) Acetophenone 5000 (2270) 2-Acetylaminofluorene 1(0.454) Acetyl bromide 5000 (2270) Acetyl chloride 5000 (2270) 1-Acetyl-2-thiourea 1000 (454) Acrolein 1 (0.454) Acrylamide 5000 (2270) Acrylic acid 5000 (2270) Acrylonitrile 100 (45.4) Adipic acid 5000 (2270) Aldicarb 1 (0.454) Aldicarb sulfone 100 (45.4) Aldrin 1 (0.454) Allyl alcohol 100 (45.4) Allyl chloride 1000 (454) Aluminum phosphide 100 (45.4) Aluminum sulfate 5000 (2270) 4-Aminobiphenyl 1 (0.454) 5-(Aminomethyl)-3-isosazolol 1000 (454) 4-Aminopyridine 1000 (454) Amitrole 10 (4.54) Ammonia 100 (45.4) Ammonium acetate 5000 (2270) Ammonium bsnzoate 5000 (2270) Ammonium bicarbonate 5000 (2270) Ammonium bichromate 10 (4.54) Ammonium biftuoride 100 (45.4) Ammonium bisulfite 5000 (2270) Ammonium carbamate 5000 (2270) Ammonium carbonate 5000 (2270) Ammonium chloride 5000 (2270) Ammonium chromate 10 (4.54) Ammonium citrate, dibasic 5000 (2270) Ammonium dichromate@ 10 (4.54) Ammonium fluoborate 5000 (2270) Amrnonium fluoride 100 (45.4) Ammonium hydroxide 1000 (454) Ammonium oxalate 5000 (2270) Ammonium picrate 10 (4.54) Ammonium silicofluoride 1000 (454) Ammonium sulfamate 5000 (2270) Ammonium sulfide 100 (454) Ammonium sulfite 5000 (2270) Ammonium tartrate 5000 (2270) Ammonium thiocyanate 5000 (2270) Ammonium vanadate 1000 (454) Amyl acetate 5Q00 (2270) iso-Amyl acetate. sec-Amyl acetate. tert-Amyl acetate. Aniline 5000 (2270) o-Anisidine 100 (45.4) Anthracene 5000 (2270)
279 § 172.101 49 CFR Ch. I (10—1—10 Edition)
TABLE 1 TO APPENDIX A—HAzARDous SUBSTANCES OTHER THAN RADIONUcuDES—Contirtued
Reportable Hazardous substance (kilograms)
Antimony 5000 (2270) Antimony pentachioride 1000 (454) Antimony potassium tartrate 100 (45.4) Antimony tribromide 1000 (454) Antimony trichloride 1000 (454) Antimony trifluoride 1000 (454) Antimony trioxide 1000 (454) Argentate(1-), bis(cyano-C)-, potassium 1(0.454) Aroclor 1016 1(0.454) Aroclor 1221 1(0.454) Aroclor 1232 1(0.454) Aroclor 1242 1(0.454) Aroclor 1248 1(0.454) Aroclor 1254 1(0.454) Aroclor 1260 1(0.454) Aroclors 1 (0.454) Arsenic 1 (0.454) Arsenic acid HAsO 1 (0.454) Arsenic disulfide 1(0.454) Arsenic oside As,0 1 (0.454) Arsenic oside As0 1 (0.454) Arsenic pentoside 1 (0.454) Arsenic trichloride 1 (0.454) Arsenic trioside 1 (0.454) Arsenic trisulfide 1 (0.454) Arsine, diethyl- 1 (0.454) Arsinic acid, dimethyl- 1(0.454) Arsonous dichioride, phenyl- 1(0.454) Asbestos cc 1(0.454) Auramine 100 (45.4) Azaserine 1(0.454) Aziridine 1(0.454) Aziridine, 2-methyl- 1(0.454) Azirino[2’,3’:3,4)pyrrolo[1,2-a]indole-4,7-dione, 6-amino-8-[1(aminocarbonyl)oxy]methylj-1,la,2,8,8a,8b- hexahydro-8a-methoxy-5-methyl-, [1 aS-(1 aalpha,8beta,8aalpha, 8balpha(]- 10 (4.54) Barban 10 (4.54) Barium cyanide 10 (4.54) Bendiocarb 100 (45.4) Bendiocarb phenol 1000 (454) Benomyl 10 (4.54) Benz[j]aceanthrylene, 1 ,2-dihydro-3-methyl- 10 (4.54) Benz[c]acridine 100 (45.4) Benzal chloride 5000 (2270) Benzamide, 3,5-dichloro-N-(1 1 -dimethyl-2-propynyl)- 5000 (2270) Benz[ajanthracene 10 (4.54) 1,2-Benzanthracene 10(4.54) Benz[a]anthracene, 7,12-dimethyl- 1(0.454) Benzenamine 5000 (2270) Benzenamine, 4,4’-carbonimidoylbis (N,N dimethyl- 100 (45.4) Benzenamine, 4-chloro- 1000 (454) Benzenarnine, 4-chloro-2-methyl-, hydrochloride 100 (45.4) Benzenamine, N,N-dirnethyt-4-(phenytazo)- 10 (4.54) Benzenamine, 2-methyl- 100 (45.4) Benzenamine, 4-methyl- 100 (45.4) Benzenamine, 4,4’-methylenebis[2-chloro- 10 (4.54) Benzenamine, 2-methyl-, hydrochloride 100 (45.4) Benzenamine, 2-methyl-5-riitro- 100 (45.4) Benzenamine, 4-nitro- 5000 (2270) Benzene 10 (4.54) Benzeneacetic acid, 4-chloro-o-(4-chlorophenyl)-a-hydroxy-, ethyl ester 10 (4.54) Benzene, 1-bromo-4-phenoxy- 100 (45.4) Renzenebutanoic acid, 4-[bis(2-chloroethyl)arnino]- 10 (4.54) Benzene, chloro- 100 (45.4) Benzene, (chloromethyl)- 100 (45.4) Benzenediamine, ar-methyl- 10 (4.54) I ,2-Benzenedicarbosylic acid, bis(2-ethylhexyl) ester 100 (45.4) I ,2-Benzenedicarboxylic acid, dibutyl ester 10 (4.54) 1,2-Benzenedicarboxylic acid, diethyl ester 1000(454) 1,2-Benzenedicarbosylic acid, dimethyl ester 5000 (2270) 1,2-Benzenedicarboxylic acid, dioctyl ester 5000 (2270)
280 Pipeline and Hazardous Materials Safety Admin., DOT § 172101
TABLE 1 TO APPENDIX A—HAzARDous SUBSTANCES OTHER THAN RADIONucLIDES—Continued
Reportable Hzardous substance quantity(RQ) (kilograms>
Benzene, 1,2-dichioro- 100 (45.4) Benzene, 1,3-dichloro- 100 (45.4) Benzene, 1,4-dichioro- 100 (45.4) Benzene, 1,1’-(2,2-dichloroethylidene) bis[4-chloro- 1 (0.454) Berizene, (dichioromethyl)- 5000 (2270) Benzene, 1,3-dilsocyanatomethyl- 100 (45.4) Benzene, dimethyl- 100 (45.4) 1 ,3-Benzenediol 5000 (2270> 1 ,2-Benzenediol,4-[1 -hydrosy-2-(methylamino( ethyl]- 1000 (454) Benzeneethanamine, alpha,alpha-dimethyl- 5000 (2270) Benzene, hesachloro- 10 (4.54) Benzene, hesahydro- 1000 (454) Benzene, methyl- 1000 (454) Benzene, 1-methyl-2,4-dinitro- 10 (4.54) Benzene, 2-methyl-i ,3-dinitro- 100 (45.4) Benzene, (1-methylethyl)- 5000 (2270) Benzene, nitro- 1000 (454) Benzene, pentachloro- 10 (4.54) Benzene, pentachloronitro- 100 (45.4) Benzenesulfonic acid chloride 100 (45.4) Benzenesulfonyl chloride 100 (45.4) Benzene, 1 ,2,4,5-tetrachloro- 5000 (2270> Benzenethiol 100 (45.4) Benzene,1 ,1 ‘-(2,2,2-trichloroethylidene) bis[4-chloro- 1 (0.454> Benzene,1,i’-(2,2,2-trichloroethylidene) bis[4-methosy- 1(0.454> Benzene, (trichloromethyl)- 10 (4.54) Benzene, 1,3,5-trinitro- 10(4.54> Benzidine 1(0.454> 1 ,2-Benzisothiazol-3(2H)-one, 1 i-dioxide, & salts 100 (45.4) Benzo[a]anthracene 10 (4.54) 1 ,3-Benzodiosole, 5-(1-propsnyl)-1 100 (45.4) 1 ,3-Benzodiosole, 5-(2-propenyl)- 100 (45.4) 1,3-Benzodiosole, 5-propyl- 10(4.54> 1 ,3-Benzodiosol-4-ol, 2,2-diniethyl- 1000 (454) 1,3-Benzodioxol-4-ol, 2,2-dimsthyl-, methyl carbamate 100 (45.4) Benzo[b]tluoranthene 1 (0.454) Benzo(k)fluoranthene 5000 (2270> 7-Benzofuranol, 2,3-dihydro-2,2-dimethyl- 10 (4.54) 7-Benzofuranol, 2,3-dihydro-2,2-dimethyl-, methylcarbamate 10 (4.54) Benzoic acid 5000 (2270) Benzoic acid, 2-hydrosy-, compd. with (3aS-cis)-1,2,3,3a,S,8a-hesahydro-1,3a,8-trimethylpyrrolo [2,3-b]indol-5-yl methylcarbamate ester (1:1> 100 (45.4) Benzonitrile 5000 (2270> Benzo[rst]pentaphene 10 (4.54) Benzo[ghi]perylene 5000 (2270) 2H-1 -Benzopyrari-2-one, 4-hydrosy-3-(3-oso-1 -phenylbutyl)-, & salts 100 (45.4) Benzo[a]pyrene 1 (0.454) 3,4-Berizopyrene 1 (0.454) p-Benzoquinone 10 (4.54) Benzotrichloride 10 (4.54) Benzoyl chloride 1000 (454) Benzyl chloride 100 (45.4) Berylliumy 10(4.54) Beryllium chloride 1 (0.454) Beryllium fluoride 1 (0.454) Beryllium nitrate 1 (0.454) Beryllium powdery 10 (4.54) alpha-BHC 10(4.54) beta-BHC 1 (0.454) delta-BHC 1 (0.454) gamma-RHO 1 (0.454) 2,2’-Biosirane 10 (4.54) Biphenyl 100 (45.4) [1,1’-Biphenyl]-4,4’-diamine 1(0.454) [1,l’-Biphenyl]-4,4’-diarnine,3,3’-dichloro- 1(0.454) [1,1’-Biphenyl]-4,4’-diarnine,3,3’-dimethosy- 100 (45.4) [1,1’-Biphenyl]-4,4’-diamine,3,3’-dimethyl- 10 (4.54) Bis(2-chloroethosy) methane 1000 (454) Bis(2-chloroethyl) ether 10 (4.54) Bis(chloromethyl) ether 10 (4.54)
281 § 172101 49 CFR Ch. I (10—1—10 Edition)
TABLE 1 TO APPENDIX A—HAzARDOus SUBSTANCES OTHER THAN RADIONUCLIDES—Continued
Reportable Hazardous substance (kilograms)
Bis(2-ethylhexyl) phthalate 100 (45.4) Bromoacetone 1000 (454) Bromoform 100 (45.4) Bromomethane 1000 (454) 4-Bromophenyl phenyl ether 100 (45.4) Brucine 100 (45.4) 1,3-Butadiene 10(4.54) 1.3-Butadiene, 1,1,2,3,4,4-hexachloro- 1(0.454) 1-Butanamine, N-butyl-N-nitroso- 10 (4.54) 1-Butanol 5000 (2270) 2-Butanone 5000 (2270) 2-Butanone, 3,3-dimethyl-1 (methylthio)-, 0 [(methylamino) carbonyl] oxime 100 (45.4) 2-Butanone peroxide 10 (4.54) 2-Butenal 100 (45.4) 2-Butane, 1 ,4-dichloro- 1 (0.454) 2-Butenoic acid, 2-methyl-, 7-[[2,3-dihydroxy-2-(1-methoxyethy-3-methyI-1-oxobutoxy] methyl]-2,3,5,7a- letrahydro-1H-pyrrolizin-1-yl ester, [1S-[lalpha(Z), 7(2S.3R),7aalpha]]- 10(4.54) Butyl acetate 5000 (2270) iso-Butyl acetate. sec-Butyl acetate. tert-Butyl acetate. n-Butyl alcohol 5000 (2270) Butylamine 1000 (454) iso-Butylamine. sec-Butylarnine. tert-Butylamine. Butyl benzyl phthalate 100 (45.4) n-Butyl phthalate 10 (4.54) Butyric acid 5000 (2270) iso-Butyric acid. Cacodylic acid 1 (0.454) Cadmiumy 10(4.54) Cadmium acetate 10(4.54) Cadmium bromide 10 (4.54) Cadmium chloride 10 (4.54) Calcium arsenate 1 (0.454) Calcium arsenite 1 (0.454) Calcium carbide 10 (4.54) Calcium chromate 10 (4.54) Calcium cyanamide 1000 (454) Calcium cyanide Ca(CN)2 10 (4.54) Calcium dodecylbenzenesulfonate 1000 (454) Calcium hypochiorite 10 (4.54) Captan 10 (4.54) Carbamic acid, 1H-benzimidazol-2-yl, methyl ester 10 (4.54) Carbamic acid, [1-[(butylamino)carbonyl)-1H-benzimidazol-2-yl]-, methyl ester 10(4.54) Carbamic acid, (3-chlorophenyl)-, 4-chloro-2-butynyl ester 10 (4.54) Carbamic acid, [(dibutylamino)-thio]methyl-, 2,3-dihydro-2,2-dimethyl-7-benzofuranyl ester 1000 (454) Carbamic acid, dimethyl-,1-[(dimethyl-amino)carbonyl]-5-methyl-IH-pyrazol-3-yl ester 1(0.454) Carbamic acid, dimethyl-, 3-methyl-1-(1-methylethyl)-1H-pyrazol-5-yl ester 100 (45.4) Carbamic acid, ethyl ester 100 (45.4) Carbamic acid, methyl-, 3-methylphenyl ester 1000 (454) Carbamic acid, methylnitroso-, ethyl ester 1 (0.454) Carbamic acid, [1 ,2-phenylenebis(iminocarbonothioyl)] bis-, dimethyl ester 10 (4.54) Carbamic acid, pheriyl-, 1-methylethyl ester 1000 (454) Carbamic chloride, dimethyl- 1 (0.454) Carbamodithioic acid, 1,2-ethanediylbis-, salts & esters 5000 (2270) Carbsmothioic acid, bis(1 -methylethyl)-, S-(2,3-dichloro-2-propenyl) ester 100 (45.4) Carbamothioic acid, bis(1-methylethyl)-, S-(2,3,3-trichloro-2-propenyl) ester 100 (45.4) Carbamothioic acid, dipropyl-, S-(phenylmethyl) ester 5000 (2270) Carbaryl 100 (45.4) Carbendazim 10 (4.54) Carbofuran 10 (4.54) Carbofuran phenol 10 (4.54) Carbon disulfide 100 (45.4) Carbonic acid, dithallium(1+) salt 100 (45.4) Carbonic dichloride 10(4.54) Carbonic clitluoride 1000(454) Carbonochloridic acid, methyl ester 1000 (454) Carbon oxyfluoride 1000 (454)
282 Pipeline and Hazardous Materials Safety Admin., DOT § 172.101
TABLE 1 TO APPENDIX A—HAzARDous SUBSTANCES OTHER THAN RADloNucuDEs—Contirtued
Reportable Hazardous substance quQ) (kilograms)
Carbon tetrachloride 10 (4.54) Carbonyl sulfide 100 (45.4) Carbosulfan 1000 (454) Catechol 100 (45.4) Chloral 5000 (2270) Chloramben 100 (45.4) Chiorambucil 10 (4.54) Chiordane 1(0.454) Chlordane, alpha & gamma isomers 1 (0.454) CHLORDANE (TECHNICAL MIXTURE AND METABOLITES) 1(0.454) Chlorinated camphene 1 (0.454) Chlorine 10 (4.54) Chlornaphazine 100 (45.4) Chloroacetaldehyde 1000 (454) Chloroacetic acid 100 (45.4) 2-Chioroacetophenone 100 (45.4) p-Chloroaniline 1000 (454) Chlorobenzene 100 (45.4) Chlorobenzilate 10 (4.54) p-Chloro-m-cresol 5000 (2270) Chlorodibromomethane 100 (45.4) 1 -Chloro-2,3-eposypropane 100 (45.4) Chioroethane 100 (45.4) 2-Chioroethyl vinyl ether 1000 (454) Chloroform 10 (4.54) Chloromethane 100 (45.4) Chloromethyl methyl ether 10 (4.54) beta-Chloronaphthalene 5000 (2270) 2-Chloronaphthalene 5000 (2270) 2-Chlorophenol 100 (45.4) o-Chlorophenol 100 (45.4) 4-Chlorophenyl phenyl ether 5000 (2270) 1-(o-Chlorophenyl)thiourea 100 (45.4) Chioroprene 100 (45.4) 3-Chioropropionitrile 1000 (454) Chlorosulfonic acid 1000 (454) 4-Chloro-o-toluidine, hydrochloride 100 (45.4) Chlorpyrifos 1 (0.454) Chromic acetate 1000 (454) Chromic acid 10 (4.54) Chromic acid H2CrO, calcium salt 10 (4.54) Chromic sulfate 1000 (454) Chromium 5000 (2270) Chromous chloride 1000 (454) Chrysene 100 (45.4) Cobaltous bromide 1000 (454) Cobaltous formate 1000 (454) Cobaltous sulfamate 1000 (454) Coke Oven Emissions 1 (0.454) Copper y 5000 (2270) Copper chloride @ 10 (4.54) Copper cyanide Cu(CN) 10 (4.54) Coumaphos 10 (4.54) Creosote 1 (0.454) Cresol (cresylic acid) 100 (45.4) m-Cresol 100 (45.4) o-Cresol 100 (45.4) p-Cresol 100 (45.4) Cresols (isomers and mixture) 100 (45.4) Cresylic acid (isomers and mixture) 100 (45.4) Crotonaldehyde 100 (45.4) Cumene 5000 (2270) m-Cumenyl rnethylcarbamate 10 (4.54) Cupric acetate 100 (45.4) Cupric acetoarsenite 1 (0.454) Cupric chloride 10 (4.54) Cupric nitrate 100 (45.4) Cupric oxalate 100 (45.4) Cupric sulfate 10 (4.54) Cupric sulfate, ammoniated 100 (45.4)
283 § 172.101 49 CFR Ch. 1(10—1—10 Edition)
TABLE 1 TO APPENDIx A—HAzARDous SUBSTANCES OTHER THAN RADIONuCLIDES—Contjnued
Reportable Hazardous substance qu,j0) (kilograms)
Cupric tartrate 100 (45.4) Cyanides (soluble salts and complexes) not otherwise specified 10 (4.54) Cyanogen 100 (45.4) Cyanogen bromide (CN)Br 1000 (454) Cyariogen chloride (CN)Cl 10 (4.54) 2,5-Cyclohexadiene-1 4-dions 10 (4.54) Cyclohexane 1000 (454) Cyclohexane, 1,2,3,4,5,6-hexachloro-, (lo, 2o, 3-, 4a, 5a, 6) 1(0.454) Cyclohexanone 5000 (2270) 2-Cyclohexyl-4,6-dinitrophenol 100 (45.4) I ,3-Cyclopentadiene, 1,2,3,4,5,5-hexachloro- 10(4.54) Cyclophosphamide 10 (4.54) 24-D Acid 100 (45.4) 24-D Ester 100 (45.4) 2,4-D, salts and esters 100 (45.4) Daunomycin 10 (4.54) DDD 1(0.454) 4,4’-DDD 1 (0.454) DDE (72-55-9) 1(0.454) DDE (3547-04-4) 5000 (2270) 4,4’-DDE 1(0.454) DDT 1)0.454) 4,4’-DDT 1)0.454) DEHP 100 (45.4) Diallate 100 (45.4) Diazinon 1 (0.454) Diezomethane 100 (45.4) Dibenz[a,h]anthracene 1(0.454) 1 ,2:5,6-Dibenzanthracene I (0.454) Dibenzo[a,h]anthracene 1 (0.454) Dibenzofuran 100 (45.4) Dibenzo[a,i]pyrene 10 (4.54) 1,2-Dibromo-3-chloropropsne 1(0.454) Dibromoethane 1)0.454) Dibutyl phthalate 10 (4.54) Di-n-butyl phthalate 10 (4.54) Dicamba 1000 (454) Dichiobenil 100 (45.4) Dichlone 1 (0.454) Dichlorobenzsne 100 (45.4) 1,2-Dichlorobenzene 100 (45.4) 1,3-Dichlorobenzene 100 (45.4) I ,4-Dichlorobenzene 1 QO (45.4) m-Dichlorobenzene 100 (45.4) o-Dichlorobenzene 100 (45.4) p-Dichlorobenzene 100 (45.4) 3,3’-Dichlorobenzidine 1(0.454) Dichlorobromomethane 5000 )2270) 1 ,4-Dichloro-2-buterie 1 (0.454) Dichlorodifluoromethane 5000 (2270) 1,1-Dichloroethane 1000 (454) I ,2-Dichloroethane 100 (45.4) 1 ,1-Dichloroethylene 100 (45.4) 1 ,2-Dichloroethylerre 1000 (454) Dichioroethyl ether 10 (4.54) Dichioroisopropyl ether 1000 (454) Dichioromethane 1000 (454) Dichloromethoxyethane 1000 (454) Dichloromethyl ether 10(4.54) 2,4-Dichlorophenol 100 (45.4) 2,6-Dichlorophenol 100 (45.4) Dichlorophenylarsine 1 (0.454) Dichloropropane 1000 (454) I ,1-Dichloropropane. 1 ,3-Dichloropropane. 1 ,2-Dichloropropane 1000 (454) Dichioropropane-Dichloropropene (mixture) 100 (45.4) Dichloropropene 100 (45.4) 2,3-Dichioropropene. 1,3-Dichloropropene 100 (45.4)
284 Pipeline and Hazardous Materials Safety Admin., DOT § 172.101
TABLE 1 TO APPENDIX A—HAZARDOUS SUBSTANCES OTHER THAN RADIONuCLIDES—Continued
Reportable Hazardous substance qu0) (kilograms)
2,2-Dichloropropionic acid 5000 (2270) Dichiorvos 10 (4.54) Dicofol 10 (4.54) Dieldriri 1(0.454) 1,2:3,4-Diepoxybutane 10(4.54) Diethanolamine 100 (45.4) Diethylamine 100 (45.4) N,N-Diethylaniline 1000 (454) Diethylarsine 1(0.454) Diethylene glycol, dicarbamate 5000 (2270) 1 ,4-Diethyleneoside 100 (45.4) Diethylhesyl phthalate 100 (45.4) N,N’-Diethylhydrszine 10 (4.54) 0,0-Diethyl S-methyl dithiophosphate 5000 (2270) Diethyl-p-nitrophenyl phosphate 100 (45.4) Diethyl phthslate 1000 (454) 0,0-Diethyl 0-pyrazinyl phosphorothioate 100 (45.4) Diethylstilbestrol 1 (0.454) Diethyl sulfate 10 (4.54) Dihydrosafrole 10 (4.54) Diisopropylfluorophosphate (DFP) 100 (45.4) 1 ,4:5,8-Dimethanonaphthalene, 1 ,2,3,4,10,10-hexachloro-1,4,4s,5,8,8a-hesahydro-, (laipha, 4alpha, 4abeta, Salpha, 8alpha, Sabeta)- 1 (0.454) 1,4:5,8-Dimethsnonaphthslene, 1,2,3,4,1O,10-hexachloro-1,4,4a,5,8,8a-hexahydro-, (laipha, 4alpha, 4abeta, Sbeta, Obeta, Sabeta)-1 (0.454). 2,7:3,6-Dimethsnonaphth[2,3-b}oxirene,3,4,5,6,9,9-hexachloro-la,2,2a,3,6,6s,7,7a-octahydro-, (laalpha, 2beta, 2aalpha, 3beta, 6beta, Saalpha, 7beta, 7aalpha)- 1(0.454) 2,7:3,6-Dimethanonaphth[2, 3-b]osirerie,3,4,5,6,9,9-hesachloro-la,2,2a,3,6,Sa,7,7a-octahydro-, (laalpha, 2beta, 2abeta, 3alphs, 6alpha, 6abeta, 7beta, 7aalpha)-, & metsbolites 1 (0.454) Dimethoate 10 (4.54) 3,3’-Dimethosyberizidine 100 (45.4) Dimethylamine 1000 (454) Dimethyl aminoazobenzene 10 (4.54) p-Dimethylsminoazobenzene 10 (4.54) N,N-Dimethylaniline 100 (45.4) 7,1 2-Dimethylbenz[a]anthracene 1 (0.454) 3,3’-Dimethylbenzidirie 10 (4.54) alpha,alpha-Dimethylbenzylhydroperoside 10 (4.54) Dimethylcsrbamoyl chloride 1 (0.454) Dimethylformamide 100 (45.4) 1,1-Dimethylhydrazine 10 (4.54) 1 ,2-Dimethylhydrazine 1 (0.454)
Dimethylhydrszine, unsymmetrical ‘ 10 (4.54) alpha,alpha-Dimethylphenethylamine 5000 (2270) 2,4-Dimethylphenol 100 (45.4) Dimethyl phthalste 5000 (2270) Dimethyl sulfate 100 (45.4) Dimetilsn 1(0.454) Dinitrobenzene (mised) 100 (45.4) m-Dinitrobenzene. o-Dinitrobenzene. p-Dinitrobenzene. 4,6-Dinitro-o-cresol, and salts 10 (4.54) Dinitrogen tetroside(’ 10(4.54) Dinitrophenol 10 (4.54) 2,5-Dinitrophenol. 2,6-Dinitrophenol. 2,4-Dinitrophenol 10 (4.54) Dinitrotoluene 10 (4.54) 3,4-Diriitrotoluene. 2,4-Dinitrotoluene 10 (4.54) 2,6-Dinitrotoluene 100 (45.4) Dinoseb 1000 (454) Di-n-octyl phthalate 5000 (2270) 1,4-Dioxane 100 (45.4) I ,2-Diphenylhydrazine 10 (4.54) Diphosphoramide, octamethyl- 100 (45.4) Diphosphoric acid, tetrsethyl ester 10 (4.54) Dipropylamine 5000 (2270) Di-n-propylnitrosamine 10 (4.54)
285 § 172.101 49 CFR Ch. 1(10—1—10 Edition)
TABLE 1 TO APPENDIX A—HAZARDOUS SUBSTANCES OTHER THAN RADIONUCLIDES—Continued
Reportable Hazardous substance quj0) (kilograms)
Diquat 1000 (454) Disulfoton 1 (0.454) Dithiobiuret 100 (45.4) 1 ,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O-[(methylamino).carbonyl]oxime 100 (45.4) Diuron 100 (45.4) Dodecylbenzenesulfonic acid 1000 (454) Endosulfan 1 (0.454) alpha-Endosulfan 1(0.454) beta-Endosulfan 1)0.454) Endosulfan sulfate 1 (0.454) Endothall 1000 (454) Endrin 1)0.454) Endrin aldehyde 1(0.454) Endrin, & metabolites 1(0.454) Epichlorohydrin 100 (45.4) Epinephrine 1000 (454) 1,2-Epoxybutane 100 (45.4) Ethanal 1000 (454) Ethanamine, N,N-diethyl- 5000 (2270) Ethanamine, N-ethyl-N-nitroso- 1 (0.454) 1,2-Ethanediamine, N,N-dirnethyl-N’-2-pyridinyl-N’-)2-thienylmethyl)- 5000 (2270) Ethane, 1 ,2-dibromo- 1 (0.454) Ethane, 1,1-dichloro- 1000 (454) Ethane, 1,2-dichloro- 100 (45.4) Ethanedinitrile 100 (45.4) Ethane, hexachloro- 100 (45.4) Ethane, 1,1 ‘-[methylenebis(oxy)]bis[2-chloro- 1000 (454) Ethane, 1,1’-oxybis- 100 (45.4) Ethane, 1,1’-oxybis[2-chloro- 10)4.54) Ethane, pentachloro- 10 (4.54) Ethane, 1,1,1,2-tetrachloro- 100 (454) Ethane, 1,1,2,2-tetrachloro- 100 (45.4) Ethanethioamide 10 (4.54) Ettiane, 1,1,1-trichloro— 1000(454) Ethane, 1,1,2-trichloro- 100 (45.4) Ethanimidothioic acid, 2-(dimethylamino)-t’J-hydroxy-2-oxo-, methyl ester 5000 (2270) Ethanimidothioic acid, 2-(dimethylamino)-N-[[(methylamino) carbonyl]oxy]-2-oxo-, methyl ester 100 (45.4) Ethanimidothioic acid, N-[[(methylarnino) carbonyl]oxy]-, methyl ester 100 (45.4) Ethanimidothioic acid, N,N’[thiobis[(methylimino)carbonyloxy]J his-, diniethyl ester 100 (45.4) Ethanol, 2-ethoxy- 1000 (454) Ethanol, 2,2’-(nitrosoimino)bis- 1 (0.454) Ethanol, 2,2’-oxybis-, dicarbaniate 5000 (2270) Ethanone, 1-phenyl- 5000 (2270) Ethene, chloro- 1 (0.454) Etherre. (2-chioroethoxy)- 1000 (454) Ethene, 1,1-dichloro- 100 (45.4) Ethene, 1,2-dichloro-(E) 1000 (454) Ethene, tetrachloro- 100 (45.4) Ethene, trichloro- 100 (45.4) Ethion 10 (4.54) Ethyl acetate 5000 (2270) Ethyl acrylate 1000 (454) Ethylbenzene 1000 (454) Ethyl carbamate 100 (45.4) Ethyl chloride 100 (454) Ethyl cyanide 10 (454) Ethylenebisdithiocarbamic acid, salts & esters 5000 (2270) Ethylenediamine 5000 (2270) Ethylenediamine-tetraacetic acid )EDTA) 5000 (2270) Ethylene dibromide 1 (0.454) Ethylene dichloride 100 (45.4) Ethylene glycol 5000 (2270) Ethylene glycol monoethyl ether 1000 (454) Ethylene oxide 10 (4.54) Ethylenethiourea 10 (4.54) Ethylenimine 1(0.454) Ethyl ether 100 (45.4) Ethylidene dichloride 1000 (454) Ethyl niethacrylate 1000 (454) Ethyl rnethanesulfonate 1 (0.454)
286 Pipeline and Hazardous Materials Safety Admin., DOT § 172.101
TABLE 1 TO APPENDIX A—HAZARDOUS SUBSTANCES OTHER THAN RADI0NUcLIDE5—Continued
Reportable Hazardous substance (kilograms)
Ethyl methyl ketone 5000 (2270) Famphur 1000 (454) Ferric ammonium citrate 1000 (454) Ferric ammonium oxalate 1000 (454) Ferric chloride 1000 (454) Ferric fluoride 100 (45.4) Ferric nitrate 1000 (454) Ferric sulfate 1000 (454) Ferrous ammonium sulfate 1000 (454) Ferrous chloride 100 (45.4) Ferrous sulfate 1000 (454) Fluoranthene 100 (45.4) Fluorene 5000 (2270) Fluorine 10 (4.54) Fluoroacetamide 100 (45.4) Fluoroacetic acid, sodium salt 10 (4.54) Formaldehyde 100 (45.4) Formetanate hydrochloride 100 (45.4) Formic acid 5000 (2270) Formparanate 100 (45.4) Fulminic acid, mercury(2+(salt 10 (4.54) Fumaric acid 5000 (2270) Furan 100 (45.4) 2-Furancarbosyaldehyde 5000 (2270) 2,5-Fursndione 5000 (2270) Furan, tetrahydro- 1000 (454) Furfural 5000 (2270) Furfuran 100 (45.4) Glucopyranose, 2-deoxy-2-(3-methyl-3-nitrosoureido)-, D- 1 (0.454) D-Glucose, 2-deoxy-2-[[(methylnitrosoamino)-carbonyl]amino]- 1 (0.454) Glycidylaldehyde 10 (4.54) Guanidine, N-methyl-N’-nitro-N-nitroso- 10 (4.54) Guthion 1 (0.454) Heptachlor 1 (0.454) Heptachlor eposide 1 (0.454) Hesachlorobenzene 10 (4.54) Hesachlorobutadiene 1(0.454) Hexachlorocyclopentadiene 10 (4.54) Hesachloroethane 100 (45.4) Hesachlorophene 100 (45.4) Hexachloropropene 1000 (454) Hexaethyl tetraphosphate 100 (45.4) Hesamethylene-1 ,6-diisocyanate 100 (45.4) Hexamethylphosphoramide 1(0.454) Hesane 5000 (2270) Hexone 5000 (2270) Hydrazine 1(0.454) Hydrazinecarbothioamide 100 (45.4) Hydrazine, 1,2-diethyl- 10 (4.54) Hydrazine, 1,1-dimethyl- 10(4.54) Hydrazine, 1,2-dimethyl- 1(0.454) Hydrazine, 1,2-diphenyl- 10(4.54) Hydrazine, methyl- 10 (4.54) Hydrochloric acid 5000 (2270) Hydrocyanic acid 10 (4.54) Hydrofluoric acid 100 (45.4) Hydrogen chloride 5000 (2270) Hydrogen cyanide 10 (4.54) Hydrogen fluoride 100 (45.4) Hydrogen phosphide 100 (45.4) Hydrogen sulfide H2S 100 (45.4) Hydroperoside, 1-methyl-I -phenylethyl- 10 (4.54) Hydroquinone 100 (45.4) 2-Imidazolidiriethione 10 (4.54) lrideno(1,2,3-cd)pyrene 100 (45.4) lodomethane 100 (45.4) 1 ,3-lsobenzofurandione 5000 (2270) Isobutyl alcohol 5000 (2270) lsodrin 1(0.454) nolan 100 (45.4)
287 § 172101 49 CFR Ch. 1(10—1—10 Edition)
TABLE 1 TO APPENDIX A—HAZARDOus SUBSTANCES OTHER THAN RADIONUCLIDES—Continued
Reportable Hazardous substance quantity(RQ) (kilograms)
tsophorone 5000 (2270) lsoprene 100 (45.4) lsopropanolamine dodecylbenzenesulfonate 1000 (454) 3-Isopropytphenyl N-methylcarbamate 10 (4.54) Isosafrole 100 (45.4) 3(2H)-lsoxazolone, 5-(aminomethyl)- 1000 (454) Kepone 1(0.454) Lasiocarpine 10 (4.54) Lead 10 (4.54) Lead acetate 10 (4.54) Lead arsenate 1(0.454) Lead, bis(acetato-O)tetrahydroxytri- 10 (4.54) Lead chloride 10 (4.54) Lead tluoborate 10 (4.54) Lead fluoride 10 (4.54) Lead iodide 10 (4.54) Lead nitrate 10 (4.54) Lead phosphate 10(4.54) Lead stearate 10 (4.54) Lead subacetate 10 (4.54) Lead sulfate 10 (4.54) Lead sulfide 10 (4.54) Lead thiocyanate 10 (4.54> Lindane 1 (0.454) Lindane (all isomers) 1 (0.454) Lithium chromate 10 (4.54) Malathion 100 (45.4) Mateic acid 5000 (2270) Maleic anhydride 5000 (2270> Maleic hydrazide 5000 (2270) Malorionitrile 1000 (454) Manganese, bis)dimethylcarbamodithioato-S,S’)- 10 (4.54) Manganese dimethyldithiocarbamate 10 (4.54) MDI 5000 (2270) MEK 5000 (2270) Metphalan 1(0.454> Mercaptodimethur 10 (4.54) Mercuric cyanide I (0.454> Mercuric nitrate 10 (4.54) Mercuric sulfate 10 (4.54) Mercuric thiocyanate 10 (4.54) Mercurous nitrate 10 (4.54) Mercury 1 (0.454) Mercury, (acetato-O)phenyt- 100 (45.4) Mercury fulminate 10 (4.54) Methacryloriitrile 1000 (454) Methanamine, N-methyl- 1000 (454) Methanamine, N-methyl-N-nitroso- 10 (4.54) Methane, bromo- 1000 (454) Methane, chtoro- 100 (45.4) Methane. chloromethoxy- 10 (4.54) Methane, dibromo- 1000 (454) Methane, dichloro- 1000 (454) Methane, dichlorodifluoro- 5000 (2270) Methane, iodo- 100 (45.4) Methane, isocyanato- 10 (4.54) Methane, oxybis(chtoro- 10 (4.54) Methanesulfenyl chloride, trichloro- 100 (45.4) Methanesulfonic acid, ethyl ester 1 (0.454> Methane, tetrachloro- 10 (4.54) Methane, tetranitro- 10 (4.54) Methanethiol 100 (45.4) Methane, tribromo- 100 (45.4) Methane, trichloro- 10 (4.54) Methane, trichlorofluoro- 5000 (2270> Methanimidamide, N,N-dimethyl-N’-[3-[[(methylarnino) carbonyl] oxy] phenyl]-, monohydrochloride 100 (45.4) Methanimidamide, N,N-dimethyl-N’-[2-methyl-4-[[(methytamino)carbonyt] oxy]phenyl]- 100 (45.4) 6,9-Methano-2,4,3-benzodioxathiepin,6,7,8,9,10,10-hexachloro-1,5,5a,6,9,ga-hexahydro., 3-oxide 1(0.454) 4,7-Methano-1 H-indene, 1 ,4,5,6,7,8,8-heptachloro-3a,4,7,7a-tetrahydro- 1(0.454)
288 Pipeline and Hazardous Materials Safety Admin., DOT § 172.10 1
TABLE 1 TO APPENDIx A—HAzARDOus SUBSTANCES OTHER THAN RADIONUCLIDES—Continued
Reportable Hazardous substance quanbty(RQ) (kilograms)
4,7-Methano-1H-indene, 12456788-octachloro-2,33a,4,77a-hexahydro- ...... 1(0.454) Methanol 5000 (2270) Methapyrilene 5000 (2270) 1 ,3,4-Metheno-2H-cyclobuta[cdjpentalen-2-one, 1la33a4,555a5b6-decachlorooctahydro- 1(0.454) Methiocarb 10 (4.54) Methomyl 100 (45.4) Methoxychlor 1 (0.454) Methyl alcohol 5000 (2270) Methylamine @ 100 (45.4) 2-Methyl aziridine 1 (0.454) Methyl bromide 1000 (454) 1-Methylbutadiene 100 (45.4) Methyl chloride 100 (45.4) Methyl chlorocarbonate 1000 (454) Methyl chloroform 1000 (454) Methyl chloroformate @ 1000 (454) Methyl chloromethyl ether 0 10 (4.54) 3-Methyicholanthrene 10 (4.54) 4,4’-Mathylenebia(2-chloroaniline) 10 (4.54) Methylene bromide 1000 (454) Methylene chloride 1000 (454) 4,4’-Methylenedianiline 10 (4.54) Methylene diphenyl diisocyanate 5000 (2270) Methyl ethyl ketone 5000 (2270) Methyl ethyl ketone peroxide 10 (4.54) Methyl hydrazirie 10 (4.54) Methyl iodide 100 (45.4) Methyl iaobstyl ketone 5000 (2270) Methyl iaocyanate 10 (4.54) 2-Methyllactonitrile 10 (4.54) Methyl mercaptan 100 (45.4) Methyl methacrylate 1000 (454) Methyl parathion 100 (45.4) 4-Methyl-2-pentanone 5000 (2270) Methyl tert-butyl ether 1000 (454) Methylthiouracil 10 (4.54) Metolcarb 1000 (454) Mevinphos 10 (4.54) Mexacarbate 1000 (454) Mitomycin C 10 (4.54) MNNG 10 (4.54) Monoethylamine 100 (45.4) Monomethylamine 100 (45.4) Haled 10 (4.54) 512-Naphthacenedione, 8-acetyl-10-[(3-amino-2,3,6-trideoxy-alpha-L-lyxo-hexopyranosyl)oxyj-78,910- tetrahydro-68, 1 1-trihydroxy-1 -methoxy-, (8S-cis)- 10 (4.54) 1-Naphthalenamine 100 (45.4) 2-Naphthalenamine 10 (4.54) Naphthalenamine, N,N’-bis(2-chloroethyl)- 100 (45.4) Naphthalene 100 (45.4) Naphthalene, 2-chloro- 5000 (2270) 1 ,4-Naphthalenedione 5000 (2270) 2,7-Naphthalenedisulfonic acid, 3,3’-[(3,3’-dimethyl-(1 ,1’-biphenyl)-4,4’-diyl)-bia(azo)]bia(5-amino-4-hydroxy)- tetrasodium salt 10 (4.54) 1-Naphthalenol, methylcarbamate 100 (45.4) Naphthenic acid 100 (45.4) 1 ,4-Naphthoquinone 5000 (2270) alpha.Naphthylamine 100 (45.4) beta-Naphthylamine 10 (4.54) alpha-Naphthylthiourea 100 (45.4) Nickely 100 (45.4) Nickel ammonium sulfate 100 (45.4) Nickel carbonyl Ni(CO)4, (T-4)- 10 (4.54) Nickel chloride 100 (45.4) Nickel cyanide Ni(CN) 10 (4.54) Nickel hydroxide 10 (4.54) Nickel nitrate 100 (45.4) Nickel sulfate 100 (45.4) Nicotine, & salts 100 (45.4) Nitric acid 1000 (454)
289 § 172.101 49 CR? Ch. 1(10—1—10 Edition)
TABLE 1 TO APPENDIX A—HAZARDOus SUBSTANCES OTHER THAN RADIONUCLIDES—Cortt)nued
Reportable Hazardous substance quanhty(RQ) (kilograms)
Nitric acid, thallium (1+) salt 100 (45.4) Nitric oxide 10 (4.54) p-Nitroaniline 5000 (2270) Nitrobenzene 1000 (454) 4-Nitrobiphenyl 10 (4.54) Nitrogen dioxide 10 (4.54) Nitrogen oxide NO 10 (4.54) Nitrogen oxide NO 10 (4.54) Nitroglycerine 10 (4.54) Nitrophenol (mixed) 100 (45.4) m-Nitrophenol. o-Nitrophenol 100 (45.4) p-Nitrophenol 100 (45.4) 2-Nitrophenol 100 (45.4) 4-Nitrophenol 100 (45.4) 2-Nitropropane 10 (4.54) N-Nitrosodi-n-butylamine 10 (4.54) N-Nitrosodiethanolamine 1 (0.454) N-Nilrosodiethylamine 1 (0.454) N-Nitrosodimethylamine 10 (4.54) N-Nitrosodiphenylamine 100 (45.4) N-Nitroso.N-ethylurea 1 (0.454) N-Nitroso-N-methylurea 1 (0.454) N-Nitroso-N-methylurethane 1 (0.454) N-Nitrosomethylvinylamine 10 (4.54) N-Nitrosomorpholine 1(0.454) N-Nitrosopiperidine 10 (4.54) N-Nitrosopyrrolidine 1(0.454) Nitrotoluene 1000 (454) m-Nitrotoluene. o-Nitrotoluene. p-Nitrotoluene. 5-Nitro-o-toluidine 100 (45.4) Octamelhylpyrophosphoramide 100 (45.4) Osmium oxide OsO, (T-4)- 1000 (454) Osmium tetroxide 1000 (454) 7-Oxabicyclo[2.2.1]heptane-2,3-dicarboxylic acid 1000 (454) Oxamyl 100 (45.4) 1,2-Oxathiolane, 2,2-dioxide 10 (4.54) 2H-1 ,3,2-Oxazaphosphorin-2-amine, N,N-bis(2-chloroethyl) tetrahydro-, 2-oxide 10 (4.54) Oxirane 10 (4.54) Oxiranecarboxyaldehyde 10 (4.54) Oxirane, (chloromethyl)- 100 (45.4) Paraformaldehyde 1000 (454) Paraldehyde 1000 (454) Parathion 10 (4.54) PCBs 1 (0.454) PCNB 100 (45.4) Peritachlorobenzene 10 (4.54) Penlachloroethane 10 (4.54) Pentachloronitrobenzene 100 (45.4) Pentachlorophenol 10 (4.54) 1,3-Pentadiene 100 (45.4) Perchioroethylene 100 (45.4) Perchioromethyl mercaptan” 100 (45.4) Phenacetin 100 (45.4) Phenanthrene 5000 (2270) Phenol 1000 (454) Phenol, 2-chloro- 100 (45.4) Phenol, 4-chloro-3-methyl- 5000 (2270) Phenol, 2.cyclohexyl-4,6-dinitro- 100 (45.4) Phenol, 2,4-dichloro- 100 (45.4) Phenol, 2,6-dichloro- 100 (45.4) Phenol, 4,4’-(1,2-dielhyl-1,2-ethenediyl)bis-, (6) 1(0.454) Phenol, 2,4-dimethyl- 100 (45.4) Phenol, 4-(dimethylamino)-3,5-dimethyl-, methylcarbamate (ester) 1000 (454) Phenol, (3,5-dimethyl-4-(methytthio)-, methylcarbamate 10 (4.54) Phenol, 2,4-dinitro- 10 (4.54) Phenol, methyl- 100 (45.4) Phenol, 2-methyl-4,6-dinitro-, & salts 10 (4.54) 290 Pipeline and Hazardous Materials Safety Admin., DOT § 172101
TABLE 1 TO APPENDIx A—HAzARDous SUBSTANCES OTHER THAN RADIONuCLIDE5—Continued
Reportable Hazardous substance qu0) (kilograms)
Phenol, 2,2’-methylenebis(34,6-trichloro- 100 (45.4) Phenol, 2-(1-methylethoxy)-, methylcarbamate 100 (45.4) Phenol, 3-(1-methylethyl)-, methyl carbamate 10(4.54) Phenol, 3-methyl-5-(1-methylethyl)-, methyl carbamate 1000 (454) Phenol, 2-(1 -methylpropyl)-46-dinitro- 1000 (454) Phenol, 4-nitro- 100 (45.4) Phenol, pentachloro- 10 (4.54) Phenol, 2,3,4,6-tetrachloro- 10 (4.54) Phenol, 2,4,5-trichloro- 10 (4.54) Phenol, 2,4,6-trichloro- 10 (4.54) Phenol, 2,4,6-trinitro-, ammonium salt 10 (4.54) L-Phenylalanine, 4-[bis(2-chloroethyl)amino]- 1 (0.454) p-Phenylenediamine 5000 (2270) Phenyl mercaptan” 100 (45.4) Phsnylmercury acetate 100 (45.4) Phenylthiourea 100 (45.4) Phorate 10 (4.54) Phosgene 10 (4.54) Phosphine 100 (45.4) Phosphoric acid 5000 (2270) Phosphoric acid, diethyl 4-nitrophenyl ester 100 (45.4) Phosphoric acid, lead(2+) salt (2:3) 10(4.54) Phosphorodithioic acid, 0,0-diethyl S-[2-(ethylthio)ethyl] ester 1 (0.454) Phosphorodithioic acid, 0,0-diethyl S-[(ethylthio)methyl] ester 10 (4.54) Phosphorodithioic acid, 0,0-diethyl S-methyl ester 5000 (2270) Phosphorodithioic acid, 0,0-dimethyl S-[2-(methylamino)-2-oxoethyl] ester 10 (4.54) Phosphorofluoridic acid, bis(1-methylethyl) ester 100 (45.4) Phosphorothioic acid, 0,0-diethyl O-(4-nitrophenyl) ester 10 (4.54) Phosphorothioic acid, 0,0-diethyl 0-pyrazinyl ester 100 (45.4) Phosphorothioic acid, O-[4-[(dimethylamino) sultonyl]phenyl] 0,0-dimethyl ester 1000 (454) Phosphorothioic acid, 0,0-dimethyl O-(4-nitrophenyl) ester 100 (45.4) Phosphorus 1 (0.454) Phosphorus osychloride 1000 (454) Phosphorus pentasulfide 100 (45.4) Phosphorus sulfide 100 (45.4) Phosphorus trichloride 1000 (454) Phthalic anhydride 5000 (2270) Physostigmine 100 (45.4) Physostigmine salicylate 100 (45.4) 2-Picoline 5000 (2270) Piperidine, 1-nitroso- 10 (4.54) Plumbane, tetraethyl- 10 (4.54) POLYCHLORINATED BIPHENYLS 1(0.454) Potassium arsenate 1 (0.454) Potassium arsenite 1 (0.454) Potassium bichromate 10 (4.54) Potassium chromate 10 (4.54) Potassium cyanide K(CN) 10 (4.54) Potassium hydroxide 1000 (454) Potassium permanganate 100 (45.4) Potassium silver cyanide 1 (0.454) Promecarb 1000 (454) Pronamide 5000 (2270) Propanal, 2-methyl-2-(methyl-sulfonyl)-, O-[(methylamino)carbonyl] oxime 100 (45.4) Propanal, 2-methyl-2-(methylthio)-, O-[(methylamino)carbonyl] oxime 1 (0.454) 1-Propanamine 5000 (2270) 1-Propanamine, N-propyl- 5000 (2270) 1-Propanamine, N-nitroso-N-propyl- 10 (4.54) Propane, I ,2-dibromo-3-chloro- 1 (0.454) Propane, 1 ,2-dichloro- 1000 (454) Propanedinitrile 1000 (454) Propanenitrile 10 (4.54) Propanenitrile, 3-chloro- 1000 (454) Propanenitrile, 2-hydroxy-2-methyl- 10 (4.54) Propane, 2-nitro- 10 (4.54) Propane, 2,2’-oxybix[2-chloro- 1000 (454) 1,3-Propane sultone 10 (4.54) 1,2,3-Propanetriol, trinitrate 10 (4.54) Propanoic acid, 2-(2,4,5-trichlorophenoxy)- 100 (45.4) 1-Propanol, 2,3-dibromo-, phosphate (3:1) 10 (4.54)
291 § 172.101 49 CFR Ch. 1(10—1—10 Edition)
TABLE 1 TO APPENDIX A—HAzARDous SUBSTANCES OTHER THAN RADIONUCLIDES—Continued
Reportable Hazardous substance qQ) (kilograms)
1 -Propanol, 2-methyl- 5000 (2270) 2-Propanone 5000 (2270) 2-Propanone, 1-bromo- 1000 (454) Propargite 10 (4.54) Propargyl alcohol 1000 (454) 2-Propenal 1 (0.454) 2-Propenamide 5000 (2270) 1-Propene, 1,3-dichloro- 100 (45.4) 1-Propene, 1,1,2,3,3,3-hexschloro- 1000 (454) 2-Propenenitrile 100 (45.4) 2-Propenenitrile, 2-methyl- 1000 (454) 2-Propenoic acid 5000 (2270) 2-Propenoic acid, ethyl ester 1000 (454) 2-Propenoic acid, 2-methyl-, ethyl ester 1000 (454) 2-Propenoic acid, 2-methyl-, methyl ester 1000 (454) 2-Propen-1-ol 100 (45.4) Propham 1000 (454) beta-Propiolactone 10 (4.54) Propionaldehyde 1000 (454) Propionic acid 5000 (2270) Propionic anhydride 5000 (2270) Propoxur (Baygon) 100 (45.4) ri-Propylamine 5000 (2270) Propylene dichloride 1000 (454) Propylene oxide 100 (45.4) 1 ,2-Propylenimine 1 (0.454) 2-Propyn-1-ol 1000 (454) Prosulfocarb 5000 (2270) Pyrene 5000 (2270) Pyrethrins 1 (0.454) 3,6-Pyridazinedione, 1,2-dihydro- 5000 (2270) 4-Pyridinamine 1000 (454) Pyridine 1000 (454) Pyridine, 2-methyl- 5000 (2270) Pyridine, 3-)1-methyl-2-pyrrolidinyl)-, )S)-, & salts 100 (45.4) 2,4-)ll-l,3H)-Pyrimidinedione, 5-[bis(2-chloroethyl)amino]- 10 (4.54) 4(1 H)-Pyrimidinone, 2,3-dihydro-6-methyl-2-thioxo- 10 (4.54) Pyrrolidine, 1-nitroso- 1(0.454) Pyrroloj2,3-b] indol-5-ol,1,2,3,3a,8,8a-hexahydro-1,3a,8-trimethyl-, methylcarbamate (ester), (3aS-cis)- 100 (45.4) Quinoline 5000 (2270) Quinone 10 (4.54) Quintobenzene 100 (45.4) RADIONUCLIDES See Table 2 Reserpine 5000 (2270) Resorcinol 5000 (2270) Saccharin & salts 100 (45.4) Safrole 100 (45.4) Selenious acid 10 (4.54) Selenious acid, dithallium (1+) salt 1000 (454) Selenium p 100 (45.4) Selenium dioxide 10 (4.54) Selenium oxide 10 (4.54) Selenium sulfide SeS2 10 (4.54) Selenourea 1000 (454) L-Serine, diazoscetate (ester) 1 (0.454) Silvery 1000 (454) Silver cyanide Ag(CN) 1(0.454) Silver nitrate 1(0.454) Silvex (2,4,5-TP) 100 (45.4) Sodium 10)4.54) Sodium arsenate 1 (0.454) Sodium arsenite 1 (0.454) Sodium azide 1000 (454) Sodium bichromate 10 (4.54) Sodium bifluoride 100 (45.4) Sodium bisulfite 5000 (2270) Sodium chromate 10 (4.54) Sodium cyanide Na(CN) 10 (4.54) Sodium ctodecylbenzenesulfonate 1000 (454) Sodium fluoride 1000 (454)
292 Pipeline and Hazardous Materials Safety Admin., DOT § 172.101
TABLE 1 TO APPENDIX A—HAzARDOus SUBSTANCES OTHER THAN RADIONUCLIDES—Continued
Reportable Hazardous substance quanhty(RQ) (kilograms)
Sodium hydrosulfide 5000 (2270) Sodium hydroxide 1000 (454) Sodium hypochlorite 100 (45.4) Sodium methylate 1000 (454) Sodium nitrite 100 (45.4) Sodium phosphate, dibasic 5000 (2270) Sodium phosphate, tribasic 5000 (2270) Sodium selenite 100 (45.4) Streptozotocin 1 (0.454) Strontium chromate 10 (4.54) Strychnidin-1 0-one, & salts 10 (4.54) Strychnidin-1 0-one, 2,3-dimethoxy- 100 (45.4) Strychnine, & salts 10 (4.54) Styrene 1000 (454) Styrene oxide 100 (45.4) Sulfur chlorides@ 1000 (454) Sulfuric acid 1000 (454) Sulfuric acid, dimethyl ester 100 (45.4) Sulfuric acid, dithallium (1+) salt 100 (45.4) Sulfur monochloride 1000 (454) Sulfur phosphide 100 (45.4) 2,4,5-T 1000 (454) 2,4,5-T acid 1000 (454) 2,4,5-T amines 5000 (2270) 2,4,5-T esters 1000 (454) 2,4,5-T salts 1000 (454) TCDD 1 (0.454) TDE 1(0.454) 1 ,2,4,5-Tetrachlorobenzene 5000 (2270) 2,3,7,8-Tetrachlorodibenzo-p-dioxin 1 (0.454) 1,1,1,2-Tetrachloroethane 100 (45.4) 1,1 ,2,2-Tetrachloroethane 100 (45.4) Tetrachloroethylene 100 (45.4) 2,3,4,6-Tetrachlorophenol 10 (4.54) Tetraethyl pyrophosphate 10 (4.54) Tetraethyl lead 10 (4.54) Tetraethyldithiopyrophouphate 100 (45.4) Tetrahydrofuran 1000 (454) Tetranitromethane 10 (4.54) Tetraphosphoric acid, hexaethyl ester 100 (45.4) Thallic oxide 100 (45.4) Thalliumy 1000 (454) Thallium (I) acetate 100 (45.4) Thallium (I) carbonate 100 (45.4) Thallium chloride TICI 100 (45.4) Thallium (I) nitrate 100 (45.4) Thallium oxide Tl2O 100 (45.4) Thallium (I) selenite 1000 (454) Thallium (I) sulfate 100 (45.4) Thioacetamide 10 (4.54) Thiodicarb 100 (45.4) Thiodiphosphoric acid, tetraethyl ester 100 (45.4) Thiofanox 100 (45.4) Thioimidodicarbonic diarriide [(H,N)C(S)]NH 100 (45.4) Thiomethanol 100 (45.4) Thioperoxydicarbonic diamide [(H2N)C(S)]S, tetramethyl- 10 (4.54) Thiophanate-methyl 10 (4.54) Thiophenol 100 (45.4) Thiosemicarbazide 100 (45.4) Thiourea 10 (4.54) Thiourea, (2-chlorophenyl)- 100 (45.4) Thiourea, 1 -naphthalenyl- 100 (45.4) Thiourea, phenyl- 100 (45.4) Thiram 10 (4.54) Tirpate 100 (45.4) Titanium tetrachloride 1000 (454) Toluene 1000 (454) Toluenediamine 10 (4.54) 2,4-Toluene diamine 10 (4.54) Toluene diisocyanate 100 (45.4) 293 172.101 49 CFR Ch. I (10—1—10 Edition)
TABLE 1 TO APPENDIX A—HAZARDOus SUBSTANCES OTHER THAN RADIONUCLIDES—Continued
Reportable Hazardous substance (kilograms)
2,4-Toluene diisocyanate 100 (45.4) o-Toluidine 100 (45.4) p-Toluidine 100 (45.4) o-Toluidine hydrochloride 100 (45.4) Toxaphene 1(0.454) 2,4,5-TP acid 100 (45.4) 2,4,5-TP esters 100 (45.4) Trialtate 100 (45.4) IH-1,2,4-Triazol-3-amine 10(4.54) Trichlorfon 100 (45.4) 1 ,2,4-Trichlorobenzene 100 (45.4) 1 1,1 -Trichloroethane 1000 (454) 1,1 ,2-Trichloroethane 100 (45.4) Trichloroethylene 100 (45.4) Trichioromethanesutfenyl chloride 100 (45.4) Trichioromonofluoromethane 5000 (2270) Trichiorophenol 10 (4.54) 2,3,4-Trichlorophenol. 2,3,5.Trichlorophenol. 2,3,6-Trichiorophenol. 3,4,5-Trichlorophenol. 2,4,5-Trichtorophenol 10 (4.54) 2,4,6-Trichlorophenol 10 (4.54) Triethanolamirie dodecylbenzenesulfonate 1000 (454) Triethylamine 5000 (2270) Trifturalin 10 (4.54) Trimethylamine 100 (45.4) 2,2,4-Trimethylpentane 1000 (454) 1,3,5-Trinitrobenzene 10 (4.54) 1 ,3,5-Trioxane, 2,4,6-trimethyl- 1000 (454) Tris(2,3-dibromopropyl) phosphate 10 (4.54) Trypan blue 10 (4.54) 0002 Unlisted Hazardous Wastes Characteristic of Corrosivity 100 (45.4) 0001 Unlisted Hazardous Wastes Characteristic of Ignitability 100 (45.4) 0003 Unlisted Hazardous Wastes Characteristic of Reactivity 100 (45.4) 0004—D043 Unlisted Hazardous Wastes Characteristic of Toxicity: Arsenic (0004) 1 (0.454) Barium (0005) 1000 (454) Benzene )D018) 10 (4.54) Cadmium (0006) 10 (4.54) Carbon tetrachloride (0019) 10 (4.54) Chtordane (0020) 1 (0.454) Chlorobenzene (0021) 100 (45.4) Chloroform (0022) 10 (4.54) Chromium (0007) 10 (4.54) o-Cresot )D023) 100 (45.4) m-Cresol (D024) 100 (45.4) p-Cresol (0025) 100 (45.4) Cresol (0026) 100 (45.4) 2,4-0 (0016) 100 (45.4) 1,4-Dichlorobenzene (0027) 100 (45.4) 1,2-Dichloroethane (0028) 100 (45.4) l,1-Dichtoroethylene (0029) 100 (45.4) 2,4-Dinitrotoluene (0030) 10 (4.54) Endrin (D012) 1(0.454) Heptachlor (and epoxide) (D031) 1(0.454) Hexachlorobenzene (0032) 10 (4.54) Hexachlorobutadiene (0033) 1 (0.454) Hexachloroethane (0034) 100 (45.4) Lead (0008) 10 (4.54) Lindane (0013) 1 (0.454) Mercury (D009) 1 (0.454) Methoxychlor (0014) 1 (0.454) Methyl ethyl ketone (0035) 5000 (2270) Nitrobenzene (0036) 1000 (454) Pentachlorophenol (0037) 10 (4.54) Pyridine (0038) 1000 (454) Selenium (0010) 10 (4.54) Silver (0011) 1(0.454) Tetrachloroethylene (0039) 100 (45.4)
294 Pipeline and Hazardous Materials Safety Admin., DOT § 172.101
TABLE 1 TO APPENDIX A—HAzARDOus SUBSTANCES OTHER THAN RADIONUCLIDES—Continued
Reportable Hazardous substance quankty(RQ) (kilograms)
Toxaphene (D015) 1(0.454) Trichioroethylene (D040) 100 (45.4) 2,4,5-Trichlorophenol (0041) 10(4.54) 2,4,6-Trichiorophenol (D042) 10 (4.54) 2,4,5-TP (D017) 100 (45.4) Vinyl chloride (D043) 1 (0.454) Uracil mustard 10 (4.54) Uranyl acetate 100 (45.4) Uranyl nitrate 100 (45.4) Urea, N-ethyl-N-nitroso- 1 (0.454) Urea, N-methyl-N-nitroso- 1 (0.454) Urethane 100 (45.4) Vanadic acid, ammonium salt 1000 (454) Vanadium oside V2O 1000 (454) Vanadium pentoside 1000 (454) Vanadyl sultate 1000 (454) Vinyl acetate 5000 (2270) Vinyl acetate monomer 5000 (2270) Vinylamine, N-methyl-N-nitroso- 10 (4.54) Vinyl bromide 100 (45.4) Vinyl chloride 1 (0.454) Vinylidene chloride 100 (45.4) Wartarin, & salts 100 (45.4) Xylene 100 (45.4) m-Xylene 1000 (454) o-Xylene 1000 (454) p-Xylene 100 (45.4) Xylene (mised) 100 (45.4) Xylenss (isomers and mixture) 100 (45.4) Xylenol 1000 (454) Yohimban-1 6-carbosylic acid,1 1,1 7-dimethoxy-1 8-[(3,4,5-trimethoxybenzoyl) osy]-, methyl ester (3beta,l6beta,l7alpha,l8bsta, 20alpha) 5000 (2270) Zincy 1000 (454) Zinc acetate 1000 (454) Zinc ammonium chloride 1000 (454) Zinc, bis(dimethylcarbamodithioato-S,S’)- 10 (4.54) Zinc borate 1000 (454) Zinc bromide 1000 (454) Zinc carbonate 1000 (454) Zinc chloride 1000 (454) Zinc cyanide Zn(CN)2 10 (4.54) Zinc fluoride 1000 (454) Zinc formate 1000 (454) Zinc hydrosulfite 1000 (454) Zinc nitrate 1000 (454) Zinc phenolsulfonate 5000 (2270) Zinc phosphide Zn3P2 100 (45.4) Zinc silicofluoride 5000 (2270) Zinc sulfate 1000 (454) Ziram 10 (4.54) Zirconium nitrate 5000 (2270) Zirconium potassium fluoride 1000 (454) Zirconium sulfate 5000 (2270) Zirconium tetrachloride 5000 (2270) FOOl 10 (4.54) (a) Tetrachloroethylene 100 (45.4) (b) Trichloroothylene 100 (45.4) (c) Methylene chloride 1000 (454) (d) 1,1,1-Trichloroethane 1000 (454) (e) Carbon tetrachioride 10 (4.54) )f) Chlorinated fluorocarbons 5000 (2270) F002 10 (4.54) (a) Tetrachloroethylene 100 (45.4) (b) Methylene chloride 1000 (454) (c) Trichloroethylene 100 (45.4) (d) 1,1,1-Trichloroethane 1000 (454) (a) Chlorobenzene 100 (45.4) (f) 1,1 ,2-Trichloro-1 ,2,2-trifluoroethane 5000 (2270) (g) o-Dichlorobenzene 100 (45.4) (h) Trichlorofluoromethane 5000 (2270) 295 § 172.101 49 CFR Ch. I (10—1—10 Edition)
TABLE 1 TO APPENDIX A—HAZARDOUS SUBSTANCES OTHER THAN RADIONUCLIDES—Continued
Reportable Hazardous substance quantdy(RQ) (kilograms)
(i) 1,1 2-Trichloroethane 100 (45.4) P003 100 (45.4) (a) Xylene 1000 (454) (b) Acetone 5000 (2270) (c) Ethyl acetate 5000 (2270) )d) Ethylbenzene 1000 (454) (e) Ethyl ether 100 (45.4) (f) Methyl isobutyt ketone 5000 (2270) (g) n-Butyl alcohol 5000 (2270) (h) Cyclohexanone 5000 (2270) (i) Methanol 5000 (2270) P004 100 (45.4) (a) Cresols/Cresylic acid 100 (45.4) (b) Nitrobenzene 1000 (454) F005 100 (45.4) (a) Toluene 1000 (454) (b) Methyl ethyl ketone 5000 (2270) (c) Carbon disulfide 100 (45.4) (d) lsobutanot 5000 (2270) (e) Pyridine 1000 (454) FOOG 10 (4.54) F007 10 (4.54) P008 10 (4.54) F009 10 (4.54) FOlO 10 (4.54) FOil 10(4.54) F012 10 (4.54) F019 10 (4.54) F020 1 (0.454) F021 1(0.454) P022 1(0.454) P023 1(0.454) F024 1 (0.454) F025 1(0.454) F026 1 (0.454) F027 1 (0.454) F028 1(0.454) P032 1 (0.454) F034 1 (0.454) F035 1 (0.454) F037 1(0.454) F038 1 (0.454) P039 1 (0.454) KOOl 1(0.454) K002 10(4.54) K003 10 (4.54) K004 10 (4.54) K005 10 (4.54) K005 10 (4.54) K007 10 (4.54) K008 10 (4.54) K009 10 (4.54) KOlO 10 (4.54) KOhl 10 (4.54) K013 10 (4.54) K014 5000 (2270) K015 10 (4.54) K016 1(0.454) K017 10)4.54) K018 1 (0.454) K019 1(0.454) K020 1(0.454) K021 10 (4.54) K022 1 (0.454) K023 5000 (2270) K024 5000 (2270) K025 10 (4.54) K026 1000 (454) K027 10 (4.54) K028 I (0.454) 296 Pipeline and Hazardous Materials Safety Admin., DOT § 172.101
TABLE 1 TO APPENDIX A—HAzARD0us SUBSTANCES OTHER THAN RADI0NucLIDEs—Continued
Reportable Hazardous substance quanbty(RQ) (kilograms)
K029 1 (0.454) K030 1 (0.454) K031 1 (0.454) K032 10 (4.54) K033 10 (4.54) K034 10 (4.54) K035 1 (0.454) K036 1 (0.454) K037 1 (0.454) K038 10 (4.54) K039 10 (4.54) K040 10 (4.54) K041 1 (0.454) K042 10 (4.54) K043 10 (4.54) K044 10 (4.54) K045 10 (4.54) K046 10)4.54) K047 10(4.54) K048 10 (4.54) K049 10 (4.54) K050 10 (4.54) K051 10 (4.54) K052 10 (4.54) K060 1 (0.454) K061 10 (4.54) K062 10 (4.54) K064 10 (4.54) K065 10 (4.54) K066 10 (4.54) K069 10 (4.54) K071 1(0.454) K073 10 (4.54) K083 100 (45.4) K084 1 (0.454) K085 10 (4.54) K086 10 (4.54) K087 100 (45.4) K088 10 (4.54) K090 10 (4.54) K091 10 (4.54) K093 5000 (2270) K094 5000 (2270) K095 100 (45.4) K096 100 (45.4) K097 1 (0.454) K098 1(0.454) K099 10)4.54) K100 10 (4.54) KiOl 1(0.454) K102 1(0.454) K103 100 (45.4) K104 10 (4.54) K105 10(4.54) K106 1(0.454) K107 10(4.54) K108 10(4.54) K109 10 (4.54) Kilo 10 (4.54) Kill 10 (4.54) K112 10 (4.54) Ki13 10 (4.54) K1i4 10 (4.54) K115 10 (4.54) K116 10 (4.54) K117 1(0.454) K118 1(0.454) Ki23 10 (4.54) K124 10 (4.54) K125 10 (4.54)
297 § 172.101 49 CFR Ch. 1(10—1—10 Edition)
TABLE 1 TO APPENDIX A—HAzARDous SUBSTANCES OTHER THAN RADIONUCLIDEs—Continued
Reportable Hazardous substance quantity (RQ) pounds (kilograms)
1<126 10 (4.54) 1<131 100 (45.4) K132 1000 (454) 1<136 1(0.454) 1<141 1 (0.454) K142 1 (0.454) K143 1(0.454) K144 1(0.454) 1<145 1(0.454) K147 1(0.454) K148 1 (0.454) 1<149 10 (4.54) K150 10 (4.54) 1<151 10 (4.54) K156 10 (4.54) 1<157 10(4.54) 1<158 10(4.54) 1<159 10 (4.54) K161 1(0.454) 1<169 10 (4.54) K170 1 (0.454) 1<171 1(0.454) K172 1(0.454) K174 1(0.454) 1<175 1(0.454) 1<176 1(0.454) K177 5000 (2270) K178 1000 (454) 1<181 1(0.454) The RQ for these hazardous substances is limited to those pieces of the metal having a diameter smaller than 100 microm eters (0.004 inches). The RO for asbestos is limited to friable forms only. @lndicates that the name was added by PHMSA because (1) the name is a synonym for a specific hazardous substance and (2) the name appears in the Hazardous Materials Table as a proper shipping name. To provide consistency with EPA regulations, two entries with different CAS numbers are provided. Refer to the EPA Table 302.4—List of Hazardous Substances and Reportable Quantities for an eaplanation of the two entries.
LIST OF HAzARDOus SUBSTANCES AND TABLE 2 TO APPENDIX A—RADI0NuCLIDEs— REPORTABLE QUANTITIES Continued
TABLE 2 TO APPENDIX A—RADI0NucLIDEs (2)- Atomic (3)—Reportable (1 )—Radionuclide Quantity (RQ) (2)— Num- (3)—Reportable ber Ci (TBq) (1 )—Radionuctide Atomic Num- Quantity )RQ) her Ci (TBq) Antimorry-116m 51 100 (3.7) Antimony-117 51 1000 (37) Actinium-224 89 100 (3.7) Antimony-i 18m 51 10 (.37) Actinium-225 89 1 (.037) Antimony-i 19 51 1000 (37) Actinium-226 89 10 (.37) Antimony-120 (16 mm) 51 1000 (37) Actinium-227 89 0.001 (.000037) Antimony-120 (5.76 day) 51 10 (.37) Actinium-228 89 10 (.37) Antimony-122 51 10 (.37) Aluminum-26 13 10 (.37) Antimony-i24 51 10 (.37) Americium-237 95 1000 (37) Antimony-124m 51 1000 (37) Americium-238 95 100 (3.7) Antimony-125 51 10 (.37) Americium-239 95 100 (3.7) Antimony-126 51 10 (.37) Americium-240 95 10 (.37) Antimony-126m 51 1000 (37) Americium-241 95 0.01 (.00037) Antimony-127 51 10 (.37) Americium-242 95 100 (3.7) Antimony-128 (10.4 mm) 51 1000 (37) Americium-242m 95 0.01 (.00037) Antimony-128 (9.01 hr) 51 10 (.37) Americium-243 95 0.01 (.00037) Antmmony-129 51 100 (3.7) Americium-244 95 10 (.37) Antimony-130 51 100 (3.7) Americiurn-244m 95 1000 (37) Aritimony-131 51 1000 (37) Americium-245 95 1000 (37) Argon-39 18 1000 (37) Americium-246 95 1000 (37) Argon-41 18 10 (.37) Americium-246m 95 1000 (37) Arsenic-69 33 1000 (37) Antimony-115 51 1000 (37) Arsenic-70 33 100 (3.7) Antiniony-116 51 1000 (37) Arsenic-71 33 100 (3.7)
298 Pipeline and Hazardous Materials Safety Admin., DOT § 172101
TABLE 2 TO APPENDIX A—RADIONucLIDEs— TABLE 2 TO APPENDIX A—RADI0NucLIDEs— Continued Continued
(2)- (3)—Reportable (2)— (3)—Reportable (1 )—Radionuclide Atomic Atomic Num- Quantity (RQ) (l)—Radionuclide Quantity (RQ) Ci (TBq) Num- ber bar Ci (TBq)
Arsenic-72 33 10 (.37) Califorriium-254 98 01 (.0037) Arsenic-73 33 100 (3.7) Carbon-il 6 1000 (37) Arsenic-74 33 iO (.37) Carbon-14 6 iO (.37) Arsenic-76 33 100 (3.7) Cerium-i 34 58 10 (.37) Araenic-77 33 1000 (37) Cerium-i 35 58 10 (.37) Arsenic-78 33 mO (3.7) Cerium-i 37 58 1000 (37) Aatatine-207 85 100 (3.7) Cerium-i 37m 58 100 (3.7) Aatatine-21 1 85 100 (3.7) Cerium-i 39 58 100 (3.7) Barium-126 56 1000 (37) Cerium-i41 58 10 (.37) Barium-128 56 10 (.37) Cerium-i43 58 iOO (3.7) Barium-131 56 10 (.37) Cerium-144 58 1 (.037) Barium-131m 56 1000 (37) Ceaium-i25 55 1000 (37) Barium-i 33 56 10 (.37) Ceaium-i27 55 100 (3.7) Barium-i 33m 56 iOO (3.7) Cesium-129 55 100 (3.7) Barium-i 35m 56 1000 (37) Ceaium-13O 55 1000 (37) Barium-i 39 56 1000 (37) Cesium-131 55 1000 (37) Barium-140 56 10 (.37) Cesium-132 55 10 (.37) Barium-14i 56 1000 (37) Cesium-134 55 i (.037) Barium-142 56 1000 (37) Ceaium-134m 55 1000 (37) Berkelium-245 97 100 (3.7) Cesium-135 55 iO (.37) Berkelium-246 97 10 (.37) Ceaium-i35m 55 100 (3.7) Berkelium-247 97 0.01 (.00037) Caaium-i36 55 iO (.37) Berkelium-249 97 1 (.037) Ceaium-i37 55 i (.037) Berkelium-250 97 100 (3.7) Ceaium-i38 55 iOO (3.7) Beryllium-b 4 1 (.037) Chlorine-36 17 10 (.37) Beryllium-7 4 iOO (3.7) Chlorina-38 17 100 (3.7) Biamuth-200 83 100 (3.7) Chlorine-39 17 100 (3.7) Biamuth-201 83 iOO (3.7) Chromium-48 24 iOO (3.7) Bismuth-202 83 i000 (37) Chromium-49 24 i000 (37) Biamuth-203 83 10 (.37) Chromium-Si 24 i000 (37) Bismuth-205 83 10 (.37) Cobalt-SS 27 10 (.37) Bismuth-206 83 10 (.37) Cobalt-56 27 10 (.37) Biamuth-207 83 10 (.37) Cobalt-57 27 100 (3.7) Biamuth-210 83 10 (.37) Cobalt-SB 27 10 (.37) Biamuth-2iOm 83 0.1 (.0037) Cobalt-58m 27 1000 (37) Biamuth-212 83 100 (3.7) CobaIt-60 27 10 (.37) Bismuth-2i3 83 100 (3.7) Cobalt-60m 27 1000 (37) Biamuth-2i4 83 100 (3.7) Cobalt-61 27 1000 (37) Bromine-74 35 100 (3.7) Cobalt-62m 27 1000 (37) Bromina-74m 35 iOO (3.7) Copper-SO 29 100 (3.7) Bromina-75 35 iOO (3.7) Copper-6l 29 100 (3.7) Bromine-76 35 iO (.37) Copper-64 29 1000 (37) Bromine-77 35 100 (3.7) Copper-67 29 100 (3.7) Bromine-SO 35 1000 (37) Curium-238 96 1000 (37) Bromine-80m 35 1000 (37) Curium-240 96 1 (.037) Bromine-82 35 10 (.37) Curium-24i 96 iO (.37) Bromine-83 35 i000 (37) Curium-242 96 i (.037) Bromirie-84 35 100 (3.7) Curium-243 96 0.01 (.00037) Cadmium-i04 48 1000 (37) Curium-244 96 0.01 (.00037) Cadmium-i07 48 1000 (37) Curium-245 96 0.01 (.00037) Cadmium-109 48 1 (.037) Curium-246 96 0.01 (.00037) Cadmium-113 48 0.1 (.0037) Curium-247 96 0.01 (.00037) Caclmium-113m 48 0.1 (.0037) Curium-248 96 0.001 (.000037) Cadmium-115 48 100 (3.7) Curium-249 96 1000 (37) Cadmium-ilSm 48 10 (.37) Dysproaium-155 66 100 (3.7) Cadmium-117 48 100 (3.7) Dysproaium-157 66 100 (3.7) Cadmium-117m 48 10 (.37) Dysproaium-159 66 100 (3.7) Calcium-41 20 10 (.37) Dyaproaium-165 66 1000 (37) Calcium-45 20 10 (.37) Dysproaium-166 66 iO (.37) Calcium-47 20 iO (.37) Einateiriium-250 99 iO (.37) Californium-244 98 1000 (37) Einsteinium-25i 99 1000 (37) Californium-246 98 iO (.37) Einateinium-253 99 10 (.37) Californium-248 98 0.i (.0037) Einatainium-254 99 0.1 (.0037) Californium-249 98 0.Oi (.00037) Einsteinium-254m 99 i (.037) Californium-250 98 0.01 (.00037) Erbium-i Si 68 100 (3.7) Californium-251 98 0.01 (.00037) Erbium-i65 68 1000 (37) Californium-252 98 0.1 (.0037) Erbium-i 69 68 100 (3.7) Californium-253 98 iO (.37) Erbium-i 71 68 iOO (3.7)
299 § 172.101 49 CFR Ch. 1(10—1—10 Edition)
TABLE 2 TO APPENDIx A—RADI0NucLIDEs— TABLE 2 TO APPENDIX A—RADIONucLIDEs— Continued Continued
(2)— (3)—Reportable (2)— (3)—Reportable (i)—Radionuclide Atomic Atomic Num- Quantity (RQ) (1 )—Radionuclide Quantity (RQ) Ci (TBq) Num- ber her Ci (TBq)
Erbium-i 72 68 10 (.37) Hafnium-184 72 100 (3.7) Europium-145 63 10 (.37) Holmium-i 55 67 1000 (37) Europium-146 63 10 (.37) Holmium-i57 67 1000 (37) Europium-147 63 10 (.37) Holmium-i59 67 1000 (37) Europium-148 63 10 (.37) Holmium-i6i 67 1000 (37) Europium-149 63 100 (3.7) Holmium-162 67 1000 (37) Europium-i 50 (12.6 hr) 63 1000 (37) Holmium-162m 67 1000 (37) Europium-i 50 (34.2 yr) 63 10 (.37) I-lolmium-164 67 1000 (37) Europium-152 63 10 (.37) Holmium-i 64m 67 i000 (37) Europium-152rn 63 100 (3.7) Holmium-i 66 67 100 (3.7) Europium-i 54 63 10 (.37) Holmium-i66m 67 1 (.037) Europium-i 55 63 10 (.37) Holmium-i67 67 100 (3.7) Europium-i56 63 10 (.37) Hydrogen-3 100 (3.7) Europium-i57 63 10 (.37) Indium-i 09 49 100 (3.7) Europium-158 63 1000 (37) Indium-hO (4.9 hi) 49 10 (.37) Fermium-252 100 10 (.37) Indium-hO (69.1 mm) 49 100 (3.7) Fermium-253 100 10 (.37) Indium-ill 49 100 (3.7) Fermium-254 100 100 (3.7) lndium-1i2 49 1000 (37) Fermium-255 100 100 (3.7) Indium-li3m 49 i000 (37) Fermium-257 100 1 (.037) Indium-114m 49 10 (.37) Fluorine-18 1000 (37) Indium-i 15 49 0.1 (.0037) Francium-222 87 100 (3.7) Indium-i 1 Sm 49 100 (3.7) Francium-223 87 100 (3.7) lndium-116m 49 100 (3.7) Gadolinium-145 64 100 (3.7) Indium-hi7 49 1000 (37) Gadolinium-146 64 10 (.37) lndium-li7m 49 100 (3.7) Gadolinium-147 64 10 (.37) Indium-li9m 49 1000 (37) Gadolinium-148 64 0.001 (.000037) Iodine-120 53 10 (.37) Gadolinium-149 64 100 (3.7) Iodine-120m 53 100 (3.7) Gadolinium-I 51 64 100 (3.7) Iodine-12i 53 100 (3.7) Gadolinium-I 52 64 0.001 (.000037) Iodine-i23 53 10 (.37) Gadolinium-i 53 64 10 (.37) Iodine-i24 63 0.1 (.0037) Gadolinium-i 59 64 1000 (37) Iodine-i25 53 0.01 (.00037) Galtium-65 31 1000 (37) Iodine-i26 53 0.01 (.00037) Gallium-66 31 10 (.37) lodine-i28 53 1000 (37) Gallium-67 31 100 (3.7) lodine-l29 53 0.001 (.000037) Gallium-68 31 1000 (37) Iodine-i 30 53 1 (.037) Gallium-70 31 1000 (37) Iodine-13i 53 0.01 (.00037) Gallium-72 31 10 (.37) Iodine-i32 53 10 (.37) Galliurn-73 31 100 (3.7) Iodine-132m 53 10 (.37) Germanium-66 32 100 (3.7) Iodine-133 53 0.1 (.0037) Germaniurn-67 32 1000 (37) Iodine-i34 53 100 (3.7) Germanium-68 32 10 (.37) Iodine-i35 53 10 (.37) Germanium-69 32 10 (.37) Iridium-i82 77 i000 (37) Germanium-71 32 1000 (37) Iridium-184 77 100 (3.7) Germanium-75 32 1000 (37) Iridium-i 85 77 100 (3.7) Germanium-77 32 10 (.37) Iridium-i 86 77 10 (.37) Gerrnanium-78 32 1000 (37) Iridium-187 77 100 (3.7) Gold-i93 79 100 (3.7) lridium-i88 77 10 (.37) Gold-194 79 10 (.37) Iridium-189 77 100 (3.7) Gold-i 95 79 100 (3.7) Iridium-i90 77 10 (.37) Gold-i 98 79 100 (3.7) Iridium-i9Om 77 1000 (37) Gold-i 98m 79 10 (.37) Iridiurn-192 77 10 (.37) Gold-i 99 79 100 (3.7) Iridiurn-i92m 77 100 (3.7) Gold-200 79 1000 (37) Iridium-i94 77 100 (3.7) Gold-200m 79 10 (.37) Iridium-l94m 77 10 (.37) Gold-20i 79 1000 (37) lridium-i95 77 1000 (37) Hafnium-i 70 72 100 (3.7) Iridium-i 95m 77 100 (3.7) Hafnium-i 72 72 1 (.037) Iron-52 26 100 (3.7) Hafnium-i 73 72 100 (3.7) Iron-55 26 100 (3.7) Hafnium-I 75 72 100 (3.7) Iron-59 26 10 (.37) Hafnium-i 77m 72 1000 (37) Iron-60 26 0.1 (.0037) Hafnium-i78m 72 0.1 (.0037) Krypton-74 36 10 (.37) Hafniurn-i79m 72 100 (3.7) Krypton-76 36 10 (.37) Hafnium-180m 72 100 (3.7) Krypton-77 36 10 (.37) Hafnium-18i 72 10 (.37) Krypton-79 36 100 (3.7) Hafnium-182 72 0.1 (.0037) Krypton-81 36 1000 (37) Hafnium-182m 72 100 (3.7) Krypton-83m 36 1000 (37) Hafnium-183 72 100 (3.7) Krypton-85 36 1000 (37)
300 Pipeline and Hazardous Materials Safety Admin., DOT § 172.101
TABLE 2 TO APPENDIX A—RADI0NucLIDEs— TABLE 2 TO APPENDIX A—RADIONucLIDEs— Continued Continued
(2)— (2)— (3)—Reportable (3)—Reportable (I)—Radionuclide Atomic Atomic Num- Quantity (RO) (l)—Radionuclide Quantity (RQ) Ci (TBq) Num- ber bar Ci (TBq)
Krypton-85m 36 100 (3.7) Neodymium-i47 60 10 (.37) Krypton-87 36 10 (.37) Neodymium-i49 60 100 (3.7) Krypton-88 36 10 (.37) Neodymium-isi 60 1000 (37) Lanthanum-i31 57 1000 (37) Neptunium-232 93 1000 (37) Lanthanum-i32 57 100 (3.7) Neptunium-233 93 1000 (37) Lanthanum-i 35 57 1000 (37) Neptunium-234 93 10 (.37) Lanthanum-I 37 57 10 (.37) Neptunium-235 93 1000 (37) Lanthanum-i 38 57 1 (.037) Neptunium-236 (1.2 6 5 yr) 93 0.1 (.0037) Lanthanum-140 57 10 (.37) Neptunium-236 (22.5 hr) 93 100 (3.7) Lanthanum-141 57 1000 (37) Neptunium-237 93 0.01 (.00037) Lanthanum-142 57 100 (3.7) Neptunium-238 93 10 (.37) Lanthanum-i43 57 1000 (37) Neptunium-239 93 100 (3.7) Lead-195m 82 1000 (37) Neptunium-240 93 100 (3.7) Lead-198 82 100 (3.7) Nickel-56 28 10 (.37) Lead-i 99 82 100 (3.7) Nickel-57 28 10 (.37) Lead-200 82 100 (3.7) Nickel-59 28 100 (3.7) Lead-20i 82 100 (3.7) Nickel-63 28 100 (3.7) Lead-202 82 1 (.037) Nickel-65 28 100 (3.7) Lead-202m 82 10 (.37) Nickel-66 28 10 (.37) Lead-203 82 100 (3.7) Niobium-88 41 100 (3.7) Lead-205 82 100 (3.7) Niobium-89 (122 mm) 41 100 (3.7) Lead-209 82 1000 (37) Niobium-89 (66 mm) 41 100 (3.7) Lead-2i0 82 0.01 (.00037) Niobium-90 4i 10 (.37) Lead-211 82 100 (3.7) Niobium-93m 4i 100 (3.7) Lead-212 82 10 (.37) Niobium-94 41 10 (.37) Lead-214 82 100 (3.7) Niobium-95 41 10 (.37) Lutetium-i 69 71 10 (.37) Niobium-95m 41 100 (3.7) Lutetium-I 70 71 10 (.37) Niobium-96 41 10 (.37) Lutetium-i 71 71 10 (.37) Niobium-97 41 100 (3.7) Lutetium-i 72 71 10 (.37) Niobium-98 41 1000 (37) Lutetium-i 73 71 100 (3.7) Osmium-i80 76 1000 (37) Lutetium-i74 71 10 (.37) Osmium-i8i 76 100 (3.7) Lutetium-i74m 71 10 (.37) Osmium-182 76 100 (3.7) Lutetium-176 71 1 (.037) Osmium-i85 76 iO (.37) Lutetium-i 76m 7i i000 (37) Osmium-i89m 76 1000 (37) Lutetium-i 77 71 100 (3.7) Osmium-19i 76 100 (3.7) Lutetium-i 77m 71 10 (.37) Osmium-I91m 76 1000 (37) Lutetium-i 78 71 1000 (37) Osmium-i 93 76 100 (3.7) Lutetium-i 78m 71 1000 (37) Osmium-i 94 76 1 (.037) Lutetium-i 79 71 1000 (37) Palladium-iOO 46 100 (3.7) Magneaium-28 12 10 (.37) Palladium-lOl 46 100 (3.7) Manganese-Si 25 1000 (37) Palladium-i03 46 100 (3.7) Manganeae-52 25 10 (.37) Palladium-i07 46 100 (3.7) Manganese-52m 26 1000 (37) Palladium-i09 46 1000 (37) Manganese-53 26 1000 )37) Phosphorus-32 15 0.1 (.0037) Manganese-54 25 10 (.37) Phosphorus-33 15 1 (.037) Manganese-56 25 100 (3.7) Platinum-186 78 100 (3.7) Mendelevium-257 101 100 (3.7) Platinum-188 78 100 (3.7) Mendelevium-258 101 1 (.037) Platinum-i89 78 100 (3.7) Mercury-193 80 100 (3.7) Platinum-i9i 78 100 (3.7) Mercury-i 93m 80 10 (.37) Platinum-i93 78 1000 (37) Mercury-i94 80 0.1 (.0037) Platinum-i93m 78 100 (3.7) Mercury-i95 80 100 (3.7) Platinum-195m 78 100 (3.7) Mercury-i95m 80 100 (3.7) Platinum-197 78 1000 (37) Mercury-197 80 1000 (37) Platinum-i97m 78 1000 (37) Mercury-i97m 80 1000 (37) Platinum-i99 78 1000 (37) Mercury-i99m 80 1000 (37) Platinum-200 78 100 (3.7) Mercury-203 80 10 (.37) Plutonium-234 94 1000 (37) Molybdenum-lOl 42 1000 (37) Plutonium-235 94 1000 (37) Molybdenum-90 42 100 (3.7) Plutonium-236 94 0.1 (.0037) Molybdenum-93 42 100 (3.7) Plutonium-237 94 1000 (37) Molybdenurn-93m 42 10 (.37) Plutonium-238 94 0.01 (.00037) Molybdenun,-99 42 100 (3.7) Plutonium-239 94 0.01 (.00037) Neodymium-i36 60 1000 (37) Plutonium-240 94 0.01 (.00037) Neodymium-i38 60 1000 (37) Plutonium-241 94 1 (.037) Neodyniium-i39 60 1000 (37) Plutonium-242 94 0.01 (.00037) Neodyrnium-139m 60 100 (3.7) Plutonium-243 94 1000 (37) Neodymium-I4i 60 1000 (37) Plutonium-244 94 0.01 (.00037)
301 § 172.101 49 CFR Ch. 1(10—1—10 Edition)
TABLE 2 TO APPENDIx A—RADI0NucLIDEs— TABLE 2 TO APPENDIX A—RADI0NucLIDEs— Continued Continued
(2)- (3)—Reportable (2)— Atomic Atomic (3)—Reportable (1 (—Radionuclide Quantity (RQ( (I )—Radionuclide Quantity (RQ( Num- Ci (TBq) Num- ber ber Ci (TBq(
Plutonium-245 94 100 (3.7) Rhodium-107 45 1000 (37) Polorsum-203 84 100 (3.7) Rhodiuni-99 45 10 (.37) Polonium-205 84 100 (3.7) Rhodium-99m 45 100 (3.7) Polonium-207 84 10 (.37) Rubidium-79 37 1000 (37) Polonium-210 84 0.01 (.00037) Rubidium-Si 37 100 (3.7) Potassium-40 19 1 (.037) Rubidium-81m 37 1000 (37) Potassium-42 19 100 (3.7) Rubidiurn-82m 37 10 (.37) Potassium-43 19 10 (.37) Rubidium-83 37 10 (.37) Potassium-44 19 100 (3.7) Rubidmm-84 37 10 (.37) Potassium-45 19 1000 (37) Rubidium-86 37 10 (.37) Preseodymium-136 59 1000 (37) Rubidium-87 37 10 (.37) Praseodymium-137 59 1000 (37) Rubidium-68 37 1000 (37) Praseodymium-i 38m 59 100 (3.7) Rubidium-89 37 1000 (37) Praseodymium-i 39 59 1000 (37) Ruthenium-103 44 10 (.37) Praseodymium-142 59 100 (3.7) Ruthenium-105 44 100 (3.7) Praseodymium-142m 69 1000 (37) Ruthenium-106 44 1 (.037) Praseodymium-143 59 10 (.37) Ruthenium-94 44 1000 (37) Praseodymium-144 59 1000 (37) Ruthenium-97 44 100 (3.7) Praseodymium-145 59 1000 (37) Samarium-141 62 1000 (37) Praseodymium-147 59 1000 (37) Samarium-141n, 62 1000 (37) Promethium-141 61 1000 (37) Samarium-142 62 1000 (37) Promethium-143 61 100 (3.7) Samarium-145 62 100 (3.7) Promethiurn-144 61 10 (.37) Samarium-146 62 0.01 (.00037) Promethium-145 61 100 (3.7) Samanum-147 62 0.01 (.00037) Promethium-146 61 10 (.37) Samarium-ISi 62 10 (.37) Promethium-147 81 10 (.37) Samarium-153 62 100 (3.7) Promethium-146 61 10 (.37) Samarium-155 62 1000 (37) Promethium-148m 61 10 (.37) Samarium-i 56 62 100 (3.7) Promethium-149 61 100 (3.7) Scandium-43 21 1000 (37) Promethium-150 61 100 (3.7) Scandium-44 21 100 (3.7) Promethium-151 61 100 (3.7) Scaridium-44m 21 10 (.37) Protactinium-227 91 100 (3.7) Scandium-46 21 10 (.37) Protactinium-228 91 10 (.37) Scandium-47 21 100 (3.7) Protactinium-230 91 10 (.37) Scandium-48 21 10 (.37) Protactinium-23i 91 0.01 (.00037) Scandium-49 21 1000 (37) Protactinium-232 91 10 (.37) Selenium-70 34 1000 (37) Protactinium-233 91 100 (3.7) Selenium-73 34 10 (.37) Protactinium-234 91 10 (.37) Selenium-73m 34 100 (3.7) RADIONUCLIDES St 1 (.037) Selenium-75 34 10 (.37) Radium-223 88 1 (.037) Selenium-79 34 10 (.37) Red ium-224 88 10 (.37) Selenium-Si 34 1000 (37) Radium-225 88 1 (.037) Selenium-61m 34 1000 (37) Radium-226 ** 88 0.1 (.0037) Selenium-83 34 1000 (37) Radium-227 88 1000 (37) Silicon-31 14 1000 (37) Radium-228 68 0.1 (.0037) Silicon-32 14 1 (.037) Radon-220 86 0.1 (.0037) Silver-102 47 100 (3.7) Radon-222 86 0.1 (.0037) Silver-103 47 1000 (37) Rhenium-177 75 1000 (37) Silver-104 47 1000 (37) Rhenium-178 75 1000 (37) Silver-104m 47 1000 (37) Rhenium-181 75 100 (3.7) Silver-lOS 47 10 (.37) Rhenium-182 (12.7 hr) 75 10 (.37) Silver-106 47 1000 (37) Rhenium-182 (64.0 hr) 75 10 (.37) Silver-106m 47 10 (.37) Rhenium-184 75 10 (.37) Silver-108m 47 10 (.37) Rhenium-184m 75 10 (.37) Silver-hOrn 47 10 (.37) Rhenium-186 75 100 (3.7) Silver-ill 47 10 (.37) Rhenium-186m 75 10 (.37) Silver-112 47 100 (3.7) Rhenium-187 75 1000 (37) Silver-1i5 47 1000 (37) Rhenium-188 75 1000 (37) Sodium-22 11 10 (.37) Rhenium-188m 75 1000 (37) Sodium-24 11 10 (.37) Rhenium-189 75 1000 (37) Strontium-80 38 100 (3.7) Rhodium-100 45 10 (.37) Slrontium-81 38 1000 (37) Rhodium-lOl 45 10 (.37) Strontium-83 38 100 (3.7) Rhodium-lOim 45 100 (3.7) Strontium-85 38 10 (.37) Rhodium-102 45 10 (.37) Strontium-85m 38 1000 (37) Rhodium-102m 45 10 (.37) Strontium-87m 38 100 (3.7) Rhodium-103m 45 1000 (37) Strontium-89 38 10 (.37) Rhodium-105 45 100 (3.7) Strontium-90 38 0.1 (.0037) Rhodium-106m 45 10 (.37) Strontium-91 38 10 (.37) 302 Pipeline and Hazardous Materials Safety Admin., DOT § 172.101
TABLE 2 TO APPENDIX A—RADIONucLIDEs— TABLE 2 TO APPENDIX A—RADIONucLIDEs— Continued Continued
(2>- (2)— (3)—Reportable (3)—Reportable (i)—Radionuclide Atomic Atomic Num- Quantity (RQ) (1 )—Radionuclide Quantity (RQ( Ci (TBq) Num- ber bar Ci (TBq)
Strontium-92 38 iOO (3.7) Thallium-200 81 10 (.37) Sulfur-35 16 i (.037) Thallium-201 81 1000 (37) Tantalum-172 73 iOO (3.7) Thallium-202 Si 10 (.37) Tantalum-173 73 100 (3.7) Thallium-204 Si iO (.37) Tantalum-174 73 100 (3.7) Thorium (Irradiated) 90 Tantalum-175 73 100 (3.7) Thorium (Natural) 90 Tantalum-i 76 73 10 (.37) Thorium-226 90 100 (3.7) Tantalum-i77 73 1000 (37) Thorium-227 90 i (.037) Tantalum-178 73 1000 (37) Thorium-228 90 0.Oi (.00037) Tantalum-179 73 1000 (37) Thorium-229 90 0.001 (.000037) Tantalum-180 73 100 (3.7) Thorium-230 90 0.01 (.00037) Tantalum-180m 73 1000 (37) Thorium-231 90 100 (3.7) Tantalum-i82 73 10 (.37) Thorium-232 ** go 0.001 (.000037) Tantalum-i82m 73 i000 (37) Thorium-234 90 100 (3.7) Tantalum-i83 73 iOO (3.7) Thulium-162 69 1000 (37) Tantalum-i84 73 10 (.37) Thulium-166 69 10 (.37) Tantalum-185 73 1000 (37) Thulium-167 69 100 (3.7) Tantalum-186 73 1000 (37) Thulium-170 69 10 (.37) Technetium-i Oi 43 1000 (37) Thulium-171 69 100 (3.7) Technetium-i 04 43 1000 (37) Thulium-172 69 100 (3.7) Technetium-93 43 100 (3.7) Thulium-173 69 100 (3.7) Technetium-93m 43 1000 (37) Thuliurn-175 69 1000 (37) Techrietium-94 43 10 (.37) Tin-ii0 50 100 (3.7) Technetium-94m 43 100 (3.7) Tin-ui 50 1000 (37) Technetium-96 43 iO (.37) Tin-i13 50 10 (.37) Technetium-96m 43 i000 (37) Tin-117m 50 100 (3.7) Technetium-97 43 iOO (3.7) Tin-119m 50 10 (.37) Technetium-97m 43 100 (3.7) Tin-121 50 1000 (37) Technetium-98 43 10 (.37) Tin-121m 50 10 (.37) Technetium-99 43 10 (.37) Tin-123 50 10 (.37) Technetium-99m 43 100 (3.7) Tin-123m 50 1000 (37) Tellurium-116 52 1000 (37) Tin-125 50 iO (.37) Tellurium-121 52 10 (.37) Tin-126 50 i (.037) Tellurium-121m 52 10 (.37) Tin-127 50 100 (3.7) Tellurium-i23 52 10 (.37) Tin-128 50 1000 (37) Tellurium-i23m 52 10 (.37) Titanium-44 22 i (.037) Tellurium-i25m 52 10 (.37) Titanium-45 22 1000 (37) Tellurium-i27 52 i000 (37) Tungsteri-176 74 1000 (37) Tellurium-i27m 52 iO (.37) Tungsten-177 74 iOO (3.7) Tellurium-129 52 1000 (37) Tungsten-178 74 100 (3.7) Tellurium-129m 52 10 (.37) Tungsten-179 74 1000 (37) Tellurium-131 52 1000 (37) Tungsten-181 74 100 (3.7) Tellurium-131m 52 10 (.37) Tungsten-185 74 iO (.37) Tellurium-132 52 10 (.37) Tungsteri-187 74 iOO (3.7) Tellurium-133 52 1000 (37) Tungsten-188 74 10 (.37) Tellurium-i 33m 52 1000 (37) Uranium (Depleted) 92 Tellurium-i34 52 1000 (37) Uranium (Irradiated) 92 Terbium-147 65 100 (3.7) Uranium (Natural) 92 Terbium-149 65 100 (3.7) Uranium Enriched 20% or great Terbium-150 65 100 (3.7) er 92 Terbium-151 65 10 (.37) Uranium Enriched less than Terbium-153 65 iOO (3.7) 20% 92 Terbium-154 65 10 (.37) Uranium-230 92 i (.037) Terbium-i55 65 100 (3.7) Uranium-23i 92 i000 (37) Terbium-i 56 65 10 (.37) Uranium-232 92 0.01 (.00037) Terbium-i 56m (24.4 hr) 65 i000 (37) Uranium-233 92 01 (.0037) Terbium-i 56m (5.0 hr) 65 i000 (37) Uranium-234 ** 92 0.1 (.0037) Terbium-i 57 65 100 (3.7) Uranium-235 ** 92 0.1 (.0037) Terbium-i 58 65 10 (.37) Uranium-236 92 0.1 (.0037) Terbium-i 60 65 10 (.37) Uranium-237 92 100 (3.7) Terbium-161 65 100 (3.7) Uranium-238 ** 92 01 (.0037) Thallium-194 Si 1000 (37) Uranium-239 92 1000 (37) Thallium-194m Si 100 (3.7) Urariium-240 92 1000 (37) Thallium-195 Si 100 (3.7) Vanadium-47 23 1000 (37) Thalliurn-197 81 100 (3.7) Vanadium-48 23 iO (.37) Thallium-198 81 10 (.37) Vanadium-49 23 1000 (37) Thallium-198m 81 100 (3.7) Xenon-i20 54 100 (3.7) Thallium-199 81 100 (3.7) Xenon-i21 54 iO (.37) 303 § 172.101 49 CFR CI,. I (10—1—10 Edition)
TABLE 2 TO APPENDIX A—RADIONUcLIDES— APPENDtX B TO § 172.101—LIST OF MARINE Continued POLLUTANTS 1. See 171.4 of this subchapter for applica (2)— § (3)—Reportable bility to marine pollutants. This appendix (1 )—Radionuclide Atomic Num- Quantity (RQ) lists potential marine Ci (TBq) pollutants as defined bar in § 171.8 of this subchapter. 2. Marine pollutants listed in this Xenon-122 54 100 (3.7) appendix are not necessarily listed Xenon-123 54 10 (.37) by name in the 172.101 Table. If Xenon-125 54 100 (3.7) § a marine pollutant not list ed by name Xenon-127 54 100 (3.7) or by synonym in the §172.101 Xenon-129m 54 1000 (37) Table meets the definition of any hazard Xenon-131m 54 1000 (37) Class 1 through 8, then you must determine Xenon-133 54 1000 (37) the class and division of the material in ac Xenon-i33m 54 1000 (37) cordance with § 173.2a of this subchapter. You Xenon-135 54 100 (3.7) must also select the most appropriate haz Xenon-135m 54 10 (.37) ardous material description and proper ship Xenon-138 54 10 (.37) ping name. If a marine pollutant not listed Ytterbium-162 70 1000 (37) by name or by synonym in the §172.101 Table Ytterbiurn-166 70 10 (.37) does not meet the definition of any Class 1 Ytterbium-167 70 1000 (37) through 8, then you must offer it for trans Ytterbium-169 70 10 (.37) portation under the most appropriate of the Ytterbium-i75 70 100 (3.7) following two Class 9 entries: “Environ Ytterbium-i 77 70 1000 (37) mentally hazardous substances, liquid, Ytterbium-178 70 1000 (37) no.s.,” UN3082, or ‘Environmentally haz Yttrium-86 39 10 (.37) ardous substances, solid, no.s.” UN3077. Yttrium-86m 39 1000 (37) 3. This appendix contains two columns. Yttnum-87 39 10 (.37) The first column, entitled “S.M.P.” (for se Yltrium-88 39 10 (.37) vere marine pollutants). identifies whether a Yttrium-90 39 10 (.37) material is a severe marine pollutant. If the Yttrium-90m 39 100 (3.7) letters “PP’ appear in this column for a ma Yttrium-9i 39 10 (.37) terial, the material is a severe marine Yttrium-91m 39 1000 (37) pol lutant, otherwise it is Ytlrium-92 39 100 (3.7) not, The second col umn, . Yttrium-93 39 100 (3.7) entitled “Marine Pollutant” lists the Yttrium-94 39 1000 (37) marine pollutants. Yttriurn-95 39 1000 (37) 4. If a material is not listed in this appen Zinc-62 30 100 (3.7) dix and meets the criteria for a marine pol Zinc-63 30 1000 (37) lutant as provided in Chapter 2,9 of the Zinc-65 30 10 (.37) IMDG Code, (incorporated by reference; see Zinc-69 30 1000 (37) §171.7 of this subchapter), the material may Zinc-69m 30 100 (3.7) be transported as a marine pollutant in ac Zinc-7i m 30 100 (3.7) cordance with the applicable requirements of Zinc-72 30 100 (3.7) this subchapter, Zirconium-86 40 100 (3.7) 5. If a material or a solution meeting the Zirconium-88 40 10 (.37) definition of a marine pollutant in § 171,8 of Zirconium-89 40 100 (3.7) this subchapter does not meet the criteria Zirconium-93 40 1 (.037) for a marine pollutant as provided in section Zirconium-95 40 10 (.37) 2.9.3.3 and 2.9.3.4 of the IMDG Code, (incor Zirconium-97 40 10 (.37) porated by reference; see §171.7 of this sub $ The ROe for all radionuclides apply to chemical com chapter), it may be excepted from the re pounds containing the radionuclides and elemental forms re quirements of this subchapter as a marine gardless of the diameter of pieces of solid material. pollutant if that exception is approved f The RQ of one curie applies to all radionuclides not other by wise listed. Whenever the ROe ri TABLE 1—HAZARDOUS the Associate Administrator. SUBSTANCES OTHER THAN RADIONUCLIDES and this table conflict, the lowest RO shall apply. For example, uranyl LIST OF MARINE POLLUTANTS acetate and uranyl nitrate have ROs shown in TABLE 1 of 100 pounds, equivalent to about one-tenth the RO level for uranium-238 in this table. S.M.P. Marine pollutant ** The method to determine the ROs for mixtures or solu (2) tions of radionuclides can be found in paragraph 7 of the note preceding TABLE 1 of this appendix. RQs for the following Acetone cyanohydrin, stabilized four common radioriuclide mixtures are provided: radiurn-226 Acetylene tetrabromide in secular equilibrium with its daughters (0.053 curie); natural Acetylene tetrachloride uranium (0.1 curie); natural uranium in secular equilibrium Acraldehyde, inhibited its daughters with (0.052 curie); and natural thorium in secular Acrolein. inhibited equilibrium with its daughters (0.011 curie). Acrolein, stabilized Indicates that the name was added by PHMSA becauee it appears in the list of radionuclides in 49 CFR 173.435. The Acrylic aldehyde, inhibited reportable quantity (RQ), if not specifically listed elsewhere in Alcohol C-I2 - C-16 poly(1-6) ethoxylate this appendix, shall be determined in accordance with the pro Alcohol C-6 - C-i 7 (secondary)poly(3-6) ethoxylate cedures in paragraph 7 of this appendix. Aldicarb
304 Pipeline and Hazardous Materials Safety Admin., DOT § 172.101
LIST OF MARINE POLLUTANTS—Continued LIST OF MARINE POLLUTANTS—Continued
S.M.P. Marine pollutant S.MP. Marine pollutant W (2) (2)
PP Aidrin 1 -Chlorohexane Alkyl (c12-c14( dimethylamine Chloronitroanilines Alkyl (c7-c9) nitrates Chtoronitrotoluenes, liquid Alkybenzenesutphonates, branched and straight Chloronitrotoluenes, solid chain (excluding C11—C13 straight chain or 1 -Chlorooctane branched chain homotogues) PP Chiorophenolates, liquid Allyt bromide PP Chiorophenolates, solid ortho-Aminoanisole Chiorophenyltrichiorosilane Aminocarb Chioropicrin Ammonium dinitro-o-cresolate aipha-Chloropropylene n-Amylbenzene Chtorotoluenes (meta-;para-) PP Azinphos-ethyl PP Chtorpyriphos PP Azinphos-methyl PP Chlorthiophos Barium cyanide Cocculus Bendiocarb Coconitrile Benomyl Copper acetoarsenite Benquinox Copper arsenite Berizyl chlorocarbonate PP Copper chloride Benzyl chloroformate PP Copper chloride solution PP Binapacryl PP Copper cyanide N,N-Bis (2-hydroxyethyl) oleamide (LOA) PP Copper metal powder PP Brodifacoum PP Copper sulphate, anhydrous, hydrates Bromine cyanide Coumachior Bromoacetone PP Coumaphos Bromoallylene PP Cresyl diphenyl phosphate Bromobenzene Crotonatdehyde, stabilized ortho-Bromobenzyl cyanide Crotonic aldehyde, stabilized Bromocyane Crotoxyphos Bromotorm Cupric arsenite PP Bromophos-ethyl PP Cupric chloride 3-Bromopropene PP Cupric cyanide Brornoxynil PP Cupric sulfate Butanedione Cupriethylenediarnine solution 2-Butenal, stabilized PP Cuprous chloride Butyl benzyl phthalate Cyanide mixtures N-tert-bulyl-N-cyclopropyl-6-methylthio-1 ,3,5-triazine- Cyanide solutions 2,4-diamine Cyanides, inorganic, n.os. 2,4-Di-tert-butylphenol Cyanogen bromide PP 2, 6-Di-tert-Butylphenot Cyanogen chloride, inhibited para.tertiary-butyltoluene Cyanogen chloride, stabilized PP Cadmium compounds Cyanophos Cadmium sutphide PP 1 ,5,9-Cyclododecatriene Calcium arsenate PP Cyhexatin Calcium arsenate and calcium arsenite, mixtures, PP Cymenes (o-;m-;p-) solid PP Cypermethrin Calcium cyanide Decyl acrylate PP Camphechtor PP DDT Carbaryl Decycloxytetrahydrothiophene dioxide Carbendazim DEF Carbofuran Desmedipham Carbon tetrabromide Di-allate Carbon tetrachloride Di-n-Butyl phthalate PP Carbophenothion PP Dialifos Carlap hydrochloride 4,4’-Diaminodiphenylmethane PP Chlordane PP Diazinon Chlortenvinphos 1 ,3-Dibromobenzene
PP Chlorinated paraflins (C-b - C-13) PP Dichtotenthion PP Chlorinated paraffinx (C14—C17(, with more than 1% Dichloroanilines shorter chain length 1 ,3-Dichloroberizene Chlorine 1 ,4-Dichlorobenzene Chlorine cyanide, inhibited Dichtorobenzene (mete-; para-) Chtormephos 2,2-Dichlorodiethyl ether Chloroacetone, stabilized Dichtorodimethyl ether, symmetrical 1 -Chloro-2,3-Epoxypropane Di-(2-chloroethyt) ether 2-Chloro-6-nitrotoluene 1 ,1-Dichloroethylene, inhibited 4-Chloro-2-nitrotoluene 1 ,6-Dichlorohexane Chloro-ortho-nitrotoluene Dichlorophenyltrichlorosilane 2-Chloro-5-trifluoromethylnitrobenzene PP Dichtorvos para-Chlorobenzyl chloride, liquid or solid PP Diclofop-methyl Chlorodinitrobenzenes, liquid or solid Dicrotophos 1 -Chloroheptane PP Dieldrin
305 § 172.101 49 CFR Ch. I (10—1—10 Edition)
LIST OF MARINE POLLUTANTS—Continued LIST OF MARINE POLLUTANTS—Continued
S.M.P. Marine pollutant S.MP. Marine pollutant (1) (2) (2)
Diisopropylbenzenes PP Furathiocarb (ISO) Diisopropylnaphthalenes, mixed isomers PP gamma-BHC PP Dimethoate Gasoline, leaded PP N,N-Dimethyldodecylamine PP Heptachlor Dimethylhydrazine, symmetrical Heptenophos Dimethylhydrazine, unsymmetrical n-Heptaldehyde Dinitro-o-cresol, solid n-Heptylbenzene Dinitro-o-cresol, solution normal-Heptyl chloride Dinitrochlorobenzenes, liquid or solid Pp Hexachlorobutadierre Dinitrophenol, dry or wetted with less than 15 per PP 1 ,3-Hexachlorobutadiene cent water; by mass Hexaethyl tetraphosphate liquid Dinitrophenol solufions Hexaethyl tetraphosphate, solid Dinitrophenol, wetted with not less than 15 per cent normal-Hexyl chloride wate, by mass n-Hesylbenzene Dinitrophenolates alkali metals, dry or wetted with Hydrocyanic acid, anhydrous, stabilized, containing less than 15 per cent water; by mass less than 3% water Dinitrophenolates, wetted with not less than 15 per Hydrocyanic acid, anhydrous, stabilized, containing cent water; by mass less than 3% water and absorbed in a porous inert Dinobuton material Dinoseb Hydrocyanic acid, aqueous solutions not more than Dinoseb acetate 20% hydrocyanic acid Dioxacarb Hydrogen cyanide solution in alcohol, with not more Dioxathion than 45% hydrogen cyanide Dipentene Hydrogen cyanide, stabilized with less than 3% Diphacinone water Diphenyl Hydrogen cyanide, stabilized with less than 3% PP Diphenylamine chloroarsine water and absorbed in a porous hart material PP Diphenylchloroarsine, solid or liquid Hydroxydimethylbenzenes, liquid or solid Disultoton loxynil I ,4-Di-tert-butylbenzene lsobenzan DNOC Isobutyl butyrate DNOC (pesticide) lsobutylbenzene Dodecyl diphenyl oxide disulphonate Isodecyl acrylate PP Dodecyl hydroxypropyl sulfide Isodecyl diphenyl phosphate 1 -Dodecylamine lsotenphos PP Dodecylphenol Isooctyl nitrate Drazoxolon lsoprocarb Edifenphos lsotetramethylbenzene PP Endosulfan PP Isoxathion PP Endrin Lead acetate Epibromohydrin Lead arsenates Epichlorohydrin Lead arsenites PP EPN Lead compounds, soluble, n.o.s. PP Estenvalerate Lead cyanide PP Ethion Lead nitrate Ethoprophos Lead parchlorate, solid or solution Ethyl fluid Lead tetraethyl Ethyl mercaptan Lead tetramethyl 2-Ethylhexyl nitrate PP Lindane 2-Ethyl-3-propylacrolein Linuron Ethyl tetraphosphate London Purple Ethyldichloroarsine Magnesium arsenate Ethylene dibromide and methyl bromide mixtures, Malathion liquid Mancozeb (ISO) 2-Ethylhexaldehyde Maneb Fenamiphos Maneb preparations with not less than 60% maneb PP Fenbutatin oxide Maneb preparation, stabilized against sell-heating PP Fenchlorazole-ethyl Maneb stabilized or Maneb preparations, stabilized PP Fenitrothion against self-heating PP Fenoxapro-ethyl Manganese ethylene-i ,2-bis dithiocarbamate PP Fenoxaprop-P-ethyl Manganese ethylene-I ,2-bis-dithiocarbamata, sta PP Fenpropathrin bilized against self-heating Fensultothion Mecarbam PP Fenthion Mephosfolan Pp Fentin acetate Mercaptodimethur PP Fentin hydroxide PP Mercuric acetate Ferric arsenate PP Mercuric ammonium chloride Ferric arsenite PP Mercuric arsenate Ferrous arsenate PP Mercuric benzoate PP Fonotos PP Mercuric bisulphate Formetanate PP Mercuric bromide
306 Pipeline and Hazardous Materials Safety Admin., DOT § 172.101
LIST OF MARINE POLLUTANTS—Continued LIST OF MARINE POLLUTANTS—Continued
S.M.P. Marine pollutant S.M.P. Marine pollutant W (2) L (2) PP Mercuric chloride 3-Nitro-4-chlorobenzotrifluoride Pp Mercuric cyanide Nitrobenzene pp Mercuric gluconate Nilrobenzotrifluorides, liquid or solid Mercuric iodide Nonylphenol PP Mercuric nitrate normal-Octatdehyde PP Mercuric oleate Oleylarnine PP Mercuric oxide Pp Organotin compounds, liquid, n.s.a. PP Mercuric oxycyanide, desensitized PP Organotin compounds (pesticides) Pp Mercuric potassium cyanide Pp Organotin compounds, solid, n_os. PP Mercuric Sulphate PP Organotin pesticides, liquid, flammable, toxic, n.o.s., PP Mercuric thiocyanate flash point less than 23de9 C pp Mercurol pp Organotin pesticides, liquid, tosic, flammable, no.s. pp Mercuroue acetate PP Organotin pesticides, liquid, toxic, n.o.s. PP Mercurous bisuiphate PP Organolin pesticides, solid, toeic, no.5. PP Mercurous bromide Orthoarsenic acid Pp Mercurous chloride Pp Osmium tetroxide PP Mercurous nitrate Oxamyl PP Mercurous salicylate Oxydisulfoton PP Mercuroue sulphate Paraoxon PP Mercury acetates PP Parathion PP Mercury ammonium chloride PP Parathion-methyl PP Mercury based pesticide, liquid, flammable, toxic PP PCBs. PP Mercury based pesticides, liquid, toxic, flammable Pentachloroethane PP Mercury based pesticides, liquid, toxic PP Pentachlorophenol pp Mercury based pesticides, solid, toxic Pentalin PP Mercury benzoate n-Pentylbenzene PP Mercury bichloride Perchloroethylene PP Mercury bisulphates Perchloromethylmercaptan PP Mercury bromides Petrol, leaded pp Mercury compounds, liquid, nos. PP Phenarsazine chloride Pp Mercury compounds, solid, s.o.s. d-Phenothrin PP Mercury cyanide PP Phenthoate PP Mercury gluconate 1 -Phenylbutane pp Mercury (I) (mercurous) compounds (pesticides) 2-Phenylbutane PP Mercury (II) (mercuric) compounds (pesticides) Phenylcyclohexane Mercury iodide PP Phenylmercuric acetate PP Mercury nucleate PP Phenytmercuric compounds, n_os. PP Mercury oleate PP Phenylmercuric hydroxide PP Mercury oxide pp Phenylmercuric nitrate PP Mercury oxycyanide, desensitized PP Phorate PP Mercury potassium cyanide PP Phosalone PP Mercury potassium iodide Phosmet PP Mercury salicytate PP Phosphamidon PP Mercury sulfates PP Phosphorus, white, molten PP Mercury thiocyanate PP Phosphorus, white or yetlow dry or under water or in Metam-sodium solution Methamidophos PP Phosphorus white, or yellow, molten Methanethiol PP Phosphorus, yellow, molten Methidathion Pindone (and salts of) Methomyl Pirimicarb ortho-Methoxyaniline pp Pirimiphoe-ethyl Methyl bromide and ethylene dibromide mixtures, liq PP Polychlorinated biphenyle uid PP Polyhalogenated biphenyls, liquid or Terphenyls liq Methyl mercaptan uid 3-Methylacroleine, stabilized PP Polyhatogenated biphenyls, solid or Terphenyts, Methylchlorobenzenee solid Methylnitrophenols PP Potassium cuprocyanide 3-Methylpyradine Potassium cyanide, solid Methyltrithion Potassium cyanide, solution Methytvinylbenzenes, inhibited pp Potassium cyanocuprate (I) PP Mevinphos PP Potassium cyanomercurate Mexacarbate PP Potassium mercuric iodide Mires Promecarb Monocrotophos Propachior Motor fuel anti-knock mixtures Propaphos Motor fuel anti-knock mixtures or compounds Propenal, inhibited Nabam Propoxur Naled Prothoate PP Nickel carbonyl Prussic acid, anhydrous, stabilized PP Nickel cyanide Prussic acid, anhydrous, stabilized, absorbed in a PP Nickel tetracarbonyl porous inert material
307 § 172.102 49 CFP Ch. 1(10—1—10 Edition)
LIST OF MARINE POLLuTANTS—Continued LIST OF MAR/NE POLLUTANTS—Continued
S.M.P. Marine pollutant S.M.P. Marine pollutant (2)
PP Pyrazophos PP Triphenyltin compounds Quinaiphos Tritolyl phosphate (less than 1% ortho-isomer) PP Quizalofop PP Quizalofop—p-ethyl PP Tritolyl phosphate (not less than 1% ortho-isomer) Rotenone Trixylenyt phosphate Salithion Vinylidene chloride, stabilized PP Silafluofen Warfarin (and salts of) Silver arsenite PP White phosphorus, dry Silver cyanide PP White phosphorus, wet Silver orthoarsenite White spirit, low (15-20%) aromatic PP Sodium copper cyanide, solid PP Yellow phosphorus, dry PP Sodium copper cyanide solution PP PP Sodium cuprocyanide, solid Yellow phosphorus, wet PP Sodium cuprocyanide, solution Zinc bromide Sodium cyanide, solid Zinc cyanide Sodium cyanide, solution Sodium dinitro-o-cresolate, dry or wetted with /ess than 15 per cent water, by mass [Amdt. 172—173, 55 FR 52474, Dec. 21, 1990] Sodium dinitro-ortho-cresolate, wetted with not tess than 15 percent water, by mass EDtT0RIAL NOTE: For FEDERAL REGISTER ci PP Sodium pentachiorophenate tations affecting § 172.101. see the List of CFR Strychnine or Strychnine salts Sections Affected which appears in the Find Sulfotep ing Aids section of the printed volume and PP Sulprophos on GPO Access. Tallow nitrite Temephos TEPP § 172.102 Special provisions. PP Terbufos Tetrabromoethane (a) General. When column 7 of the Tetrabromomethane §172.101 table refers to a special provi 1,1 ,2,2-Tetrachloroethane sion for a hazardous material, the Tetrachtoroethylene Tetrachloromethane meaning and requirements of that pro Tetraethyl dithiopyrophosphate vision are as set forth in this section. PP Tetraethyl lead, liquid When a special provision specifies Tetramethrin Tetramethyllead packaging or packaging require Thaltium chlorate ments— Thallium compounds, nos. (1) The special provision is in addi Thallium compounds (pesticides) Thallium nitrate tion to the standard requirements for Thallium sulfate all packagings prescribed in §173.24 of Thallous chlorate this subchapter and any other applica Thiocarbonyl tetrachloride ble packaging requirements Triaryl phosphates, isopropylated in subparts PP Triaryl phosphates, no.5. A and B of part 173 of this subchapter: Triazophos and Tribromomethane (2) To PP Tributyltin compounds the extent a special provision Trichlorfon imposes limitations or additional re PP 1 ,2,3—Trichlorobenzene quirements on the packaging provi Trichlorobenzenes, liquid sions set forth in column 8 of Trichtorobutene the Trichlorobutylene §172.101 table, packagings must con Trichloromethane sulphuryl chloride form to the requirements of the special Trichloromethyl sulphochloride provision. Trichtoronat Tricresyl phosphate (less than 1% ortho-isomer) (b) Description of codes for special pro PP Tricresyl phosphate, not less than 1% ortho—isomer visions. Special provisions contain but not more than 3% orthoisomer packaging provisions, prohibitions, ex PP Tricresyl phosphate with more than 3 per cent ortho isomer ceptions from requirements for par Triethylbenzene ticular quantities or forms of materials Trisopropylated phenyl phosphates and requirements or prohibitions appli Trimethylene dichtoride PP Triphenylphosphate cable to specific modes of transpor Triphenyt phosphate/tert-butylated triphenyl tation, as follows: phosphates mixtures containing 5% to 10% (1) A code consisting only of numbers triphenyl phosphates (for example, is PP Triphenyl phosphate/tert-butytated triphenyl “11”) multi-modal in phosphates mixtures containing 10% to 48% application and may apply to bulk and triphenyl phosphates non-bulk packagings.
308 Pipeline and Hazardous Materials Safety Admin., DOT § 172.102 (2) A code containing the letter “A’ and must be described as an inhalation refers to a special provision which ap hazard under the provisions of this sub plies only to transportation by air chapter. craft. 4 This material is poisonous by inhalation (3) A code containing the letter “B” (see § 171.8 of this subchapter) in Hazard Zone D (see §173.116(a) of this subchapter), refers to a special provision that ap and must be described as an inhalation plies only to bulk packaging require hazard under the provisions of this sub ments. Unless otherwise provided in chapter. this subchapter, these special provi 5 If this material meets the definition for a sions do not apply to UN, IM Specifica material poisonous by inhalation (see tion portable tanks or IBCs. §171.8 of this subchapter), a shipping name (4) A code containing the letters “TB” must be selected which identifies the inha or “TP” refers to a special provision lation hazard. in Division 2.3 or Division that applies only 6.1, as appropriate. to transportation in 6 This material is poisonous-by-inhalation IBCs. and must be described as an inhalation (5) A code containing the letter “N” hazard under the provisions of this sub refers to a special provision which ap chapter. plies only to non-bulk packaging re 8 A hazardous substance that is not a haz quirements. ardous waste may be shipped under the (6) A code containing the letter “R” shipping description “Other regulated sub refers to a special provision which ap stances, liquid or solid, no.s.”, as appro plies only to transportation by rail. priate. In addition, for solid materials, spe (7) A code containing the letter “T” cial provision B54 applies. 9 Packaging for certain PCBs for disposal refers to a special provision which ap and storage is prescribed by EPA in 40 CFR plies only to transportation in UN or 761,60 and 761.65. TM Specification portable tanks. 11 The hazardous material must be pack (8) A code containing the letters aged as either a liquid or a solid, as appro “TP” refers to a portable tank special priate, depending on its physical form at 55 provision for UN or IM Specification °C (131 °F) at atmospheric pressure. portable tanks that is in addition to 12 In concentrations greater than 40 per those provided by the portable tank in cent, this material has strong oxidizing structions or the requirements in properties and is capable of starting fires part in contact with combustible materials. If 178 of this subchapter. appropriate, a package containing this ma (9) A code containing the letter “W” terial must conform to the additional la refers to a special provision that ap beling requirements of §172.402 of this sub plies only to transportation by water. chapter. (c) Tables of special provisions. The fol 13 The words “Inhalation Hazard” shall be lowing tables list, and set forth the re entered on each shipping paper in associa quirements of, the special provisions tion with the shipping description, shall be marked referred to in column 7 of the 172.101 on each non-bulk package in asso § ciation with the proper shipping name and table. identification number, and shall be marked (I) Numeric provisions. These provi on two opposing sides of each bulk pack sions are multi-modal and apply to age. Size of marking on bulk package must bulk and non-bulk packagings: conform to § 172.302(b) of this subchapter. The requirements of §1172.203(m) and Code/Special Provisions 172.505 of this subchapter do not apply. 1 This material is poisonous by inhalation 14 Motor fuel antiknock mixtures are: (see §171.8 of this subchapter) in Hazard a. Mixtures of one or more organic lead Zone A (see §173.116(a) or §173.133(a) of this mixtures (such as tetraethyl lead, subchapter), and must be described as an triethylmethyl lead, diethyldimethyl inhalation hazard under the provisions of lead, ethyltrimethyl lead, and this subchapter. tetramethyl lead) with one or more halo 2 This material is poisonous by inhalation gen compounds (such as ethylene (see §171.8 of this subchapter) in Hazard dibromide and ethylene dichioride), hy Zone B (see §173.116(a) or §173.133(a) of this drocarbon solvents or other equally effi subchapter), and must be described as an cient stabilizers; or inhalation hazard under the provisions of b. tetraethyl lead. this subchapter. 15 This entry applies to “Chemical kits” 3 This material is poisonous by inhalation and “First aid kits” containing one or (see § 171.8 of this subchapter) in Hazard more compatible items of hazardous mate Zone C (see § 173.116(a) of this subchapter), rials in boxes, cases, etc. that, for example, 309 § 172.102 49 CFR Ch. 1(10—1—10 Edition)
are used for medical, analytical, diag packed that the percentage of diluent will nostic, testing, or repair purposes. For not fall below that stated in the shipping transportation by aircraft, materials for description at any time during transport. bidden for transportation by passenger air Quantities of not more than 500 g per pack craft or cargo aircraft may not be included age with not less than 10 percent water by in the kits. Chemical kits and first aid kits mass may also be classed in Division 4.1, are excepted ft-nm the specification pack provided a negative test result is obtained aging requirements of this subchapter when tested in accordance with test series when packaged in combination packagings. 6(c) of the UN Manual of Tests and Criteria Chemical kits and first aid kits are also ex (IBR. see §171.7 of this subchapter). cepted from the labeling and placarding re 24 Alcoholic beverages containing more quirements of this subchapter, except when than 70 percent alcohol by volume must be offered for transportation or transported transported as materials in Packing Group by air. Chemical and fit-st aid kits may be II. Alcoholic beverages containing more transported in accordance with the con than 24 percent but not more than 70 per sumer commodity and ORM exceptions in cent alcohol by volume must be trans §173.156, provided they meet all required ported as materials in Packing Group III. conditions. Kits that are carried on board 26 This entry does not include ammonium transport vehicles for operating first aid or permanganate, the transport of which is purposes are not subject to the require prohibited except when approved by the ments of this subchapter. Associate Administrator. 16 This description applies to smokeless 28 The dihydrated sodium salt of powder and other solid propellants that are dichloroisocyanuric acid is not subject to used as powder for small arms and have the requirements of this subchapter. been classed as Division 1.3 and 4.1 in ac 29 For transportation cordance with 173.56 of this subchapter. by motor vehicle, § rail car or production 18 This description is authorized only for fire vessel, runs (excep tions for prototypes extinguishers listed in 173.309(b) of this can be found in § §173.185(e)) subchapter meeting the following condi of not more than 100 lithium cells tions: or batteries are excepted from the testing re a. Each fire extinguisher may only have quirements ofl73.l85(a)(l) if— extinguishing contents that are nonflam a. For a lithium metal cell or battery, the mable, non-poisonous, non-corrosive and lithium content is not more than 1.0 g per commercially free from corroding com cell and the aggregate lithium content is not ponents. more than 2.0 g per battery, and, for a lith b. Each fire extinguisher must be charged ium-ion cell or battery, the equivalent lith with a nonflammable, non-poisonous. dry ium content is not more than 1.5 g per cell gas that has a dew-point at or below and the aggregate equivalent lithium con minus 46.7 °C (minus 52 °F) at 101 kPa (I tent is not more than 8 g per battery: atmosphere) and is free of corroding com b. The cells and batteries are transported ponents, to not more than the service in an outer packaging that is a metal, plas pressure of the cylinder. tic or plywood drum or metal, plastic or c. A fire extinguisher may not contain wooden box that meets the criteria for Pack more than 30% carbon dioxide by volume ing Group I packagings; and or any other corrosive extinguishing c. Each cell and battery is individually agent. packed in an inner packaging inside an outer d. Each fire extinguisher must be protected packaging and is surrounded by cushioning externally by suitable corrosion-resisting material that is non-combustible, and non- coating. conductive. 19 For domestic transportation only, the 30 Sulfur is not subject to the requirements identification number “UN1075” may be of this subchapter if transported in a non- used in place of the identification number bulk packaging or if formed to a specific specified in column (4) of the § 172.101 table. shape (for example, prills, granules, pel The identification number used must be lets, pastilles, or flakes). A bulk packaging consistent on package markings, shipping containing sulfur is not subject to the papers and emergency response informa placarding requirements of subpart F of tion. this part, if it is marked with the appro 21 This material must be stabilized by ap priate identification number as required by propriate means (e.g., addition of chemical subpart D of this part. Molten sulfur must inhibitor, purging to remove oxygen) to be marked as required by §172.325 of this prevent dangerous polymerization (see subchapter. §173.21(f) of this subchapter). 31 Materials which have undergone suffi 22 If the hazardous material is in dispersion cient heat treatment to render them non in organic liquid, the organic liquid must hazardous are not subject to the require have a flash point above 50 °C (122 °F). ments of this subchapter. 23 This material may be transported under 32 Polymeric beads and molding compounds the provisions of Division 4.1 only if it is so may be made from polystyrene,
310 Pipeline and Hazardous Materials Safety Admin., DOT § 172.102
poly(methyl methacrylate) or other poiy 43 The membrane filters, including paper meric material. separators and coating or backing mate 33 Amnionium nitrites and mixtures of an rials, that are present in transport, must inorganic nitrite with an ammonium salt not be able to propagate a detonation as are prohibited. tested by one of the tests described in the 34 The commercial grade of calcium nitrate UN Manual of Tests and Criteria, Part I, fertilizer, when consisting mainly of a dou Test series 1(a) (IBR, see § 171.7 of this sub ble salt (calcium nitrate and ammonium chapter). On the basis of the results of nitrate) containing not more than 10 per suitable burning rate tests, and taking cent ammonium nitrate and at least 12 per into account the standard tests in the UN cent water of crystallization, is not subject Manual of Tests and Criteria, Part III, sub to the requirements of this subchapter. section 33.2.1 (IBR, see §171.7 of this sub 35 Antimony sulphides and oxides which do chapter), nitrocellulose membrane filters not contain more than 0.5 percent of ar in the form in which they are to be trans senic calculated on the total mass do not ported that do not meet the criteria for a meet the definition of Division 6.1. Division 4.1 material are not subject to the 37 Unless it can be demonstrated by testing requirements of this subchapter. Pack that the sensitivity of the substance in its agings must be so constructed that explo frozen state is no greater than in its liquid sion is not possible by reason of increased internal state, the substance must remain liquid pressure. Nitrocellulose mem brane filters during normal transport conditions. It covered by this entry, each with mass not must not freeze at temperatures above —15 a exceeding 0.5 g, are not subject to the °C (5°F). requirements of this sub chapter when contained individually in an 38 If this material shows violent a effect in article or a sealed packet. laboratory tests involving heating under 44 The formulation must be prepared so confinement, the labeling requirements of that it remains homogenous and does not Special Provision 53 apply, and the mate separate during transport. Formulations be rial must packaged in accordance with with low nitrocellulose contents and nei packing method 0P6 in § 173.225 of this sub ther showing dangerous properties when chapter. If the SADT of the technically tested for their ability to detonate. pure substance is higher than 75 °C. the deflagrate or explode when heated under technically pure substance and formula defined confinement by the appropriate tions derived from it are not self-reactive test methods and criteria in the UN Man materials and, if not meeting any other ual of Tests and Criteria (IBR, see §171.7 of hazard class, are not subject to the re this subchapter), nor classed as a Division quirements of this subchapter. 4.1 (flammable solid) when tested in ac 39 This substance may be carried under pro cordance with the procedures specified in visions other than those of Class 1 only if §173.124 of this subchapter (chips, if nec it is so packed that the percentage of essary, crushed and sieved to a particle water will not fall below that stated at any size of less than 1.25 mm), are not subject time during transport. When phlegmatized to the requirements of this subchapter. with water and inorganic inert material, 45 Temperature should be maintained be the content of urea nitrate must not ex tween 18 °C (64.4 °F) and 40 °C (104 °F). ceed 75 percent by mass and the mixture Tanks containing solidified methacrylic should not be capable of being detonated acid must not be reheated during trans by test l(a)(i) or test 1(a)(ii) in the UN port. Manual of Tests and Criteria (IBR, see 46 This material must be packed in accord §171.7 of this subchapter). ance with packing method 0P6 (see § 173.225 40 Polyester resin kits consist of two com of this subchapter). During transport, it ponents: a base material (Class 3, Packing must be protected from direct sunshine Group II or III) and an activator (organic and stored (or kept) in a cool and well-ven peroxide), each separately packed in an tilated place, away from all sources of inner packaging. The organic peroxide heat. must be type D, E, or F, not requiring tem 47 Mixtures of solids that are not subject to perature control, and be limited to a quan this subchapter and flammable liquids may tity of 125 mL (4.22 ounces) per inner pack be transported under this entry without aging if liquid, and 500 g (1 pound) if solid. first applying the classification criteria of The components may be placed in the same Division 4.1, provided there is no free liquid outer packaging provided they will not visible at the time the material is loaded interact dangerously in the event of leak or at the time the packaging or transport age. Packing group will be II or Ill, accord unit is closed. Except when the liquids are ing to the criteria for Class 3, applied to fully absorbed in solid material contained the base material. in sealed bags, each packaging must cor 41 This material at the Packing Group II respond to a design type that has passed a hazard criteria level may be transported in leakproofness test at the Packing Group II Large Packagings. level. Small inner packagings consisting of
311 § 172.102 49 CFR Ch. 1(10—1—10 Edition)
sealed packets and articles containing less transported by motor vehicle, rail car, or than 10 mL of a Class 3 liquid in Packing aircraft. Group Il or III absorbed onto a solid mate 55 This device must be approved in accord rial are not subject to this subchapter pro ance with § 173.56 of this subchapter by the vided there is no free liquid in the packet Associate Administrator. or article. 56 A means to interrupt and prevent deto 48 Mixtures of solids which are not subject nation of the detonator from initiating the to this subchapter and toxic liquids may be detonating cord must be installed between transported under this entry without first each electric detonator and the detonating applying the classification criteria of Divi cord ends of the jet perforating guns before sion 6.1, provided there is no free liquid the charged jet perforating guns are of visible at the time the material is loaded fered for transportation. or at the time the packaging or transport 57 Maneb or Maneb preparations stabilized unit is closed. Each packaging must cor against self-heating need not be classified respond to a design type that has passed a in Division 4.2 when it can be dem leakproofness test at the Packing Group II onstrated by testing that a volume of 1 m3 level. This entry may not be used for solids of substance does not self-ignite and that containing a Packing Group I liquid. the temperature at the center of the sam 49 Mixtures of solids which are not subject ple does not exceed 200 °C, when the sample to this subchapter and corrosive liquids is maintained at a temperature of not less may be transported under this entry with than 75 C ±2 C for a period of 24 hours, in out first applying the classification cri accordance with procedures set forth for teria of Class 8, provided there is no free testing self-heating materials in the UN liquid visible at the time the material is Manual of Tests and Criteria (IBR, see 171.7 loaded or at the time the packaging or § of this subchapter). 58 Aqueous transport unit is closed. Each packaging solutions of Division 5.1 inor ganic solid must correspond to a design type that has nitrate substances are consid ered not passed a leakproofness test at the Packing as meeting the criteria of Division Group II level. 5.1 if the concentration of the substances in solution at the minimum temperature 50 Cases, cartridge, empty with primer encountered in transport which are made of metallic or plastic cas is not greater than 80% of the saturation limit. ings and meeting the classification criteria 59 Ferrocerium, stabilized of Division 1.4 are not regulated against corro for domes sion. with tic transportation. a minimum iron content of 10 percent is not subject to the requirements 51 This description applies to items pre of this subchapter. viously described as “Toy propellant de 61 A chemical oxygen generator is spent if vices, Class C” and includes reloadable its means of ignition and all or a part of its kits. Model rocket motors containing 30 chemical contents have been expended. grams or less propellant classed are as Di 62 Oxygen generators (see 171.8 of this sub vision l.4S and items containing § more than chapter) are not authorized for transpor 30 grams of propellant but not more than tation under this entry. 62.5 grams of propellant are classed as Di 64 The group of alkali metals includes lith vision l.4C. ium, sodium, potassium, rubidium, and 52 This entry may only be used for sub caesium. stances that do not exhibit explosive prop 65 The group of alkaline earth metals in erties of Class 1 (explosive) when tested in cludes magnesium, calcium, strontium, accordance with Test Series 1 and 2 of and barium. Class I (explosive) in the UN Manual of 66 Formulations of these substances con Tests and Criteria, Part I (incorporated by taining not less than 30 percent non-vola reference; see §171.7 of this subchapter). tile, non-flammable phlegmatizer are not 53 Packages of these materials must bear subject to this subchapter. the subsidiary risk label, “EXPLOSIVE”, 70 Black powder that has been classed in ac and the subsidiary hazard class/division cordance with the requirements of §173.56 must be entered in parentheses imme of this subchapter may be reclassed and of diately following the primary hazard class fered for domestic transportation as a Di in the shipping description, unless other vision 4.1 material if it is offered for trans wise provided in this subchapter or portation and transported in accordance through an approval issued by the Asso with the limitations and packaging re ciate Administrator, or the competent au quirements of § 173.170 of this subchapter. thority of the country of origin. A copy of 74 During transport, this material must be the approval shall accompany the shipping protected from direct sunshine and stored papers. or kept in a cool and well-ventilated place, 54 Maneb or rnaneb preparations not meet away from all sources of heat. ing the definition of Division 4.3 or any 77 Mixtures containing not more than 23.5% other hazard class are not subject to the oxygen by volume may be transported requirements of this subchapter when under this entry when no other oxidizing
312 Pipeline and Hazardous Materials Safety Admin., DOT § 172.102
gases are present. A Division 5.1 subsidiary cartridges (cartridges, power device of Di risk label is not required if this special vision l.4C or l.4S), without changing the provision applies. classification of Division 2.2, provided the 78 This entry may not be used to describe aggregate quantity of deflagrating (propel compressed air which contains more than lant) explosives does not exceed 3.2 grams 23.5 percent oxygen. An oxidizer label is per extinguishing unit. not required for any oxygen concentration 111 Explosive substances of Division 1.1 of 23.5 percent or less. Compatibility Group A (l.lA) are forbidden 79 This entry may not be used for mixtures for transportation if dry or not desen that meet the definition for oxidizing gas. sitized, unless incorporated in a device. 81 Polychlorinated biphenyl items, as de 113 The sample must be given a tentative fined in 40 CFR 761.3, for which specifica approval by an agency or laboratory in ac tion packagings are impractical, may be cordance with § 173.56 of this subchapter. packaged in non-specification packagings 114 Jet perforating guns, charged, oil well, meeting the general packaging require without detonator may be reclassed to Di ments of subparts A and B of part 173 of vision 1.4 Compatibility Group D (l.4D) if this subchapter. Alternatively, the item the following conditions are met: itself may be used as a packaging if it a. The total weight of the explosive contents meets the general packaging requirements of the shaped charges assembled in the of subparts A and B of part 173 of this sub guns does not exceed 90.5 kg (200 pounds) chapter. per vehicle; and 102 The ends of the detonating cord must be b. The guns are packaged in tied fast so that the explosive cannot es accordance with Packing Method US I as specified in 173.62 cape. The articles may be transported as in § Division 1.4 Compatibility Group D (l.4D) if of this subchapter. 115 Boosters with detonator, detonator as all of the conditions specified in § 173.63(a) of this subchapter are met. semblies and boosters with detonators in 103 Detonators which will not mass deto which the total explosive charge per unit nate and undergo only limited propagation does not exceed 25 g, and which will not in the shipping package may be assigned to mass detonate and undergo only limited 1.4B classification code. Mass detonate propagation in the shipping package may means that more than 90 percent of the de be assigned to l.4B classification code. vices tested in a package explode prac Mass detonate means more than 90 percent tically simultaneously. Limited propaga of the devices tested in a package explode tion means that if one detonator near the practically simultaneously. Limited propa center of a shipping package is exploded, gation means that if one booster near the the aggregate weight of explosives, exclud center of the package is exploded, the ag ing ignition and delay charges, in this and gregate weight of explosives, excluding ig all additional detonators in the outside nition and delay charges, in this and all packaging that explode may not exceed 25 additional boosters in the outside pack grams. aging that explode may not exceed 25 g. 105 The word Agents’ may be used instead 116 Fuzes, detonating may be classed in Di of “Explosives” when approved by the As vision 1.4 if the fuzes do not contain more sociate Administrator. than 25 g of explosive per fuze and are 106 The recognized name of the particular made and packaged so that they will not explosive may be specified in addition to cause functioning of other fuzes, explosives the type. or other explosive devices if one of the 107 The classification of the substance is ex fuzes detonates in a shipping packaging or pected to vary especially with the particle in adjacent packages. size and packaging but the border lines 117 If shipment of the explosive substance is have not been experimentally determined; to take place at a time that freezing appropriate classifications should be weather is anticipated, the water con verified following the test procedures in tained in the explosive substance must be § 173.57 and 173.58 of this subchapter. mixed with denatured alcohol so that 108 Fireworks must be so constructed and freezing will not occur. packaged that loose pyrotechnic composi 118 This substance may not be transported tion will not be present in packages during under the provisions of Division 4.1 unless transportation. specifically authorized by the Associate 109 Rocket motors must be nonpropulsive Administrator. in transportation unless approved in ac 119 This substance, when in quantities of cordance with § 173.56 of this subchapter. A not more than 11.5 kg (25.3 pounds), with rocket motor to be considered “nonpropul not less than 10 percent water, by mass, sive” must be capable of unrestrained also may be classed as Division 4.1, pro burning and must not appreciably move in vided a negative test result is obtained any direction when ignited by any means. when tested in accordance with test series 110 Fire extinguishers transported under 6(c) of the UN Manual of Tests and Criteria UN1O44 may include installed actuating (IBR, see §171.7 of this subchapter).
313 § 172.102 49 CFR Ch. 1(10—1—10 Edition)
120 The phiegmatized substance must be overcharged and therefore, differentiating significantly less sensitive than dry PETN. them from non-spillable batteries. “Bat 121 This substance, when containing less al teries, dry, sealed, n.o.s.” are not subject cohol, Water or phiegmatizer than speci to any other requirements of this sub fied, may not be transported unless ap chapter except for the following: proved by the Associate Administrator. (1) Incident reporting requirements. For 123 Any explosives, blasting, type C con transportation by aircraft, a telephone re taining chlorates must be segregated from port in accordance with §171.15(a) is required explosives containing ammonium nitrate if a fire, violent rupture, explosion or dan or other ammonium salts. gerous evolution of heat (i.e., an amount of 125 Lactose or glucose or similar materials heat sufficient to be dangerous to packaging may be used as a phlegrnatizer provided or personal safety to include charring of that the substance contains not less than packaging, melting of packaging, scorching 90%, by mass, of phlegmatizer. These mix of packaging, or other evidence) occurs as a tures may be classified in Division 4.1 when direct result of a dry battery. For all modes tested in accordance with test series 6(c) of of transportation, a written report sub the UN Manual of Tests and Criteria (IBR, mitted, retained, and updated in accordance see § 171.7 of this subchapter) and approved with § 171.16 is required if a fire, violent rup by the Associate Administrator. Testing ture, explosion or dangerous evolution of must be conducted on at least three pack heat occurs as a direct result of a dry bat ages as prepared for transport. Mixtures tery or battery-powered device; containing at least 98%. by mass, of (2) Batteries and battery-powered device(s) phlegmatizer are not subject to the re containing batteries must be prepared and quirements of this subchapter. Packages packaged for transport in a manner to pre containing mixtures with not less than 90% vent: by mass, of phlegmatizer need not bear a (i) A dangerous evolution of heat; POISON subsidiary risk label. (ii) Short circuits, including but not lim 127 Mixtures containing oxidizing and or ited to the following methods: ganic materials transported under this (a) Packaging each battery or each bat entry may not meet the definition and cri tery-powered device when practicable. in teria of a Class 1 material. (See § 173.50 of fully enclosed inner packagings made of non- this subchapter.) conductive material; 128 Regardless of the provisions of (b) Separating or packaging batteries in a § 172.101(c) (12), aluminum smelting by-prod manner to prevent contact with other bat ucts and aluminum remelting by-products teries, devices or conductive materials (e.g., described under this entry, meeting the metal) in the packagings; or definition of Class 8, Packing Group II and (c) Ensuring exposed terminals or connec III may be classed as a Division 4.3 mate tors are protected with non-conductive caps, rial and transported under this entry. The non-conductive tape, or by other appropriate presence of a Class 8 hazard must be com means; and municated as required by this Part for sub (iii) Damage to terminals. If not impact re sidiary hazards. sistant, the outer packaging should not be 129 These materials may not be classified used as the sole means of protecting the bat and transported unless authorized by the tery terminals from damage or short Associate Administrator on the basis of re circuiting. Batteries must be securely cush sults from Series 2 Test and a Series 6(c) ioned and packed to prevent shifting which Test from the UN Manual of Tests and Cri could loosen terminal caps or reorient the teria (IBR, see §171.7 of this subchapter) on terminals to produce short circuits. Bat packages as prepared for transport. The teries contained in devices must be securely packing group assignment and packaging installed. Terminal protection methods in must be approved by the Associate Admin clude but are not limited to the following: istrator for Hazardous Materials Safety on (a) Securely attaching covers of sufficient the basis of the criteria in §173.21 of this strength to protect the terminals; subchapter and the package type used for (b) Packaging the battery in a rigid plastic the Series 6(c) test. packaging; or 130 Dry batteries not specifically covered (c) Constructing the battery with termi by another entry in the § 172.101 Table must nals that are recessed or otherwise protected be described using this entry. Batteries de so that the terminals will not be subjected to scribed as “Batteries, dry, sealed, no.s” damage if the package is dropped. are hermetically sealed and generally uti (3) When transported by aircraft, for a bat lize metals (other than lead) and/or carbon tery whose voltage (electrical potential) ex as electrodes. These batteries are typically ceeds 9 volts: used for portable power applications. The (i) When contained in a device, the device rechargeable (and some non-rechargeable) must be packaged in a manner that prevents types have gelled alkaline electrolytes unintentional activation or must have an (rather than acidic) making it difficult for independent means of preventing uninten them to generate hydrogen or oxygen when tional activation (e.g., packaging restricts
314 Pipeline and Hazardous Materials Safety Admin., DOT § 172.102 access to activation switch, switch caps or required when liquid hazardous materials locks, recessed switches, trigger locks, tem may escape due to incorrect orientation. perature sensitive circuit breakers, etc.); and The machinery or apparatus, if (ii) An indication of compliance with this unpackaged, or the packaging in which it special provision must be provided by mark is contained shall be marked “Dangerous ing each package with the words “not re goods in machinery” or “Dangerous goods stricted” or by including the words “not re in apparatus”, as appropriate, with the stricted” on a transport document such as an identification number UN3363. For trans air waybill accompanying the shipment. portation by aircraft, machinery or appa 131 This material may not be offered for ratus may not contain any material forbid transportation unless approved by the As den for transportation by passenger or sociate Administrator, cargo aircraft. The Associate Adminis 132 This entry may only be used for uni trator may except from the requirements form, ammonium nitrate based fertilizer of this subchapter, equipment, machinery mixtures, containing nitrogen, phosphate and apparatus provided: or potash, meeting the following criteria: a. It is shown that it does not pose a sig (I) Contains not more than 70% ammonium nificant risk in transportation; nitrate and not more than 0.4% total com b. The quantities of hazardous materials do bustible, organic material calculated as not exceed those specified in § 173.4a of carbon or (2) Contains not more than 45% this subchapter; and ammonium nitrate and unrestricted com c. The equipment, machinery or apparatus bustible material, conforms with § 173.222 of this sub 134 This entry only applies to vehicles, ma chapter. chinery and equipment powered by wet 137 Cotton, dry; flax, dry; sisal, dry; and batteries, sodium batteries, or lithium bat tampico fiber, dry are not subject to the teries that are transported with these bat requirements of this subchapter when they teries installed. Examples of such items are baled in accordance with ISO 8115, are electrically-powered cars, lawn mow “Cotton Bales—Dimensions and Density” ers, wheelchairs, and other mobility aids. (IBR, see §171.7 of this subchapter) to a Self-propelled vehicles that also contain an density of not less than 360 kg/rn3 (22.1 lb/ internal combustion engine must be con ft3) for cotton, 400 kg/rn3 (24.97 lb/ft) for signed under the entry “Vehicle, flam flax, 620 kg/m3 (38.71 lb/ft) for sisal and 360 mable gas powered” or “Vehicle, flam kg/m3 (22.1 lb/ft3) for tampico fiber and mable liquid powered”, as appropriate. Ex transported in a freight container or closed cept as provided in Special Provision AlOl, transport vehicle. vehicles, machinery and equipment pow 138 Lead compounds which, when mixed in a ered by primary lithium batteries that are ratio of 1:1,000 with 0.07 M (Molar con transported with these batteries installed centration) hydrochloric acid and stirred are forbidden aboard passenger-carrying for one hour at a temperature of 23°C ± aircraft. 2°C, exhibit a solubility of 5% or less are 135 The entries “Vehicle, flammable gas considered insoluble and are not subject to powered” or “Vehicle, flammable liquid the requirements of this subchapter unless powered,” as appropriate, must be used they meet criteria as another hazard class when internal combustion engines are in or division. stalled in a vehicle. These entries include 139 Use of the “special arrangement” proper hybrid electric vehicles powered by both an shipping names for international ship internal combustion engine and batteries. ments must be made under an IAEA Cer 136 This entry only applies to machinery tificate of Competent Authority issued by and apparatus containing hazardous mate the Associate Administrator in accordance rials as in integral element of the machin with the requirements in §173.471, §173.472, ery or apparatus. It may not be used to de or §173.473 of this subchapter. Use of these scribe machinery or apparatus for which a proper shipping names for domestic ship proper shipping name exists in the §172.101 ments may be made only under a DOT spe Table. Except when approved by the Asso cial permit, as defined in, and in accord ciate Administrator, machinery or appa ance with the requirements of subpart B of ratus may only contain hazardous mate part 107 of this subchapter. rials for which exceptions are referenced in 140 This material is regulated only when it Column (8) of the §172.101 Table and are meets the defining criteria for a hazardous provided in part 173, subpart D, of this sub substance or a marine pollutant. In addi chapter. Hazardous materials shipped tion, the column 5 reference is modified to under this entry are excepted from the la read “III” on those occasions when this beling requirements of this subchapter un material is offered for transportation or less offered for transportation or trans transported by highway or rail. ported by aircraft and are not subject to 141 A toxin obtained from a plant, animal, the placarding requirements of part 172, or bacterial source containing an infec subpart F, of this subchapter. Orientation tious substance, or a toxin contained in an markings as described in §172.312 (a)(2) are infectious substance, must be classed as
315 § 172.102 49 CFR Ch. 1(10—1—10 Edition)
Division 13.2, described as an infectious sub monomethylamine nitrate: 5-30% water: 2- stance, and assigned to UN 2814 or UN 2900, 15% fuel; 0.5—4% thickening agent; 0—10% as appropriate. soluble flame suppressants; and trace addi 142 These hazardous materials may not be tives. Other inorganic nitrate salts may re classified and transported unless author place part of the ammonium nitrate. These ized by the Associate Administrator. The substances must satisfactorily pass Test Associate Administrator will base the au Series 8 of the UN Manual of Tests and Cri thorization on results from Series 2 tests teria, Part I, Section 18 (IBR, see §171.7 and a Series 6(c) test from the UN Manual of this subchapter), and may of Tests and Criteria (IBR, see §171.7 of not be classified and transported this subchapter) on packages as prepared unless approved by the As sociate for transport in accordance with the re Administrator. quirements of this subchapter. 149 When transported as a limited quantity 144 If transported as a residue in an under or a consumer commodity, the maximum ground storage tank (UST), as defined in 40 net capacity specified in §173.150(b)(2) of CFR 280.12, that has been cleaned and this subchapter for inner packagings may purged or rendered inert according to the be increased to 5 L (1.3 gallons). American Petroleum Institute (API) 150 This description may be used only for Standard 1604 (IBR, see § 171.7 of this sub uniform mixtures of fertilizers containing chapter), then the tank and this material ammonium nitrate as the main ingredient are not subject to any other requirements within the following composition limits: of this subchapter. However, sediments re a. Not less than 90% ammonium nitrate maining in the tank that meet the defini with not more than 0.2% total combustible. tion for a hazardous material are subject organic material calculated as carbon, and to the applicable regulations of this sub with added matter, if any, that is inorganic chapter. and inert when in contact with ammonium 145 This entry applies to formulations that nitrate; or neither detonate in the cavitated state nor b. Less than 90% deflagrate in laboratory testing, show no but more than 70% ammo nium nitrate effect when heated under confinement, ex with other inorganic materials, hibit no explosive power, and are ther or more than 80% but less than 90% ammo mally stable (self-accelerating decomposi nium nitrate mixed with calcium carbonate tion temperature (SADT) at 60 °C (140 F) and/or dolomite and/or mineral calcium or higher for a 50 kg (110.2 lbs.) package). sulphate, and not more than 0.4% total com Formulations not meeting these criteria bustible, organic material calculated as car must be transported under the provisions bon: or applicable to the appropriate entry in the c. Ammonium nitrate-based fertilizers con Organic Peroxide Table in § 173.225 of this taining mixtures of ammonium nitrate and subchapter. amn1onium sulphate with more than 45% but 146 This description may be used for a ma less than 70% ammonium nitrate, and not terial that poses a hazard to the environ more than 0.4% total combustible, organic ment but does not meet the definition for material calculated as carbon such that the a hazardous waste or a hazardous sub sum of the percentage of compositions of stance, as defined in §171.8 of this sub ammonium nitrate and ammonium sulphate chapter, or any hazard class, as defined in exceeds 70%. part 173 of this subchapter, if it is des 151 If this material meets the definition of ignated as environmentally hazardous by a flammable liquid in §173.120 of this sub another Competent Authority. This provi chapter, a FLAMMABLE LIQUID label is sion may be used for both domestic and also required and the basic description on international shipments. the shipping paper must indicate the 147 This entry applies to non-sensitized Class 3 subsidiary hazard. emulsions, suspensions, and gels consisting 155 Fish primarily of a mixture of ammonium ni meal or fish scrap may not be transported trate and fuel, intended to produce a Type if the temperature at the time E blasting explosive only after further of loading either exceeds 35 °C (95 °F), or processing prior to use. The mixture for exceeds 5 °C (41 F) above the ambient tem emulsions typically has the following com perature, whichever is higher. position; 60-85% ammonium nitrate; 5-30% 156 Asbestos that is immersed or fixed in a water; 2—8% fuel; 0.5—4% emulsifier or natural or artificial binder material, such thickening agent; 0-10% soluble flame sup as cement, plastic, asphalt, resins or min pressants; and trace additives. Other inor eral ore, or contained in manufactured ganic nitrate salts may replace part of the products is not subject to the requirements ammonium nitrate. The mixture for sus of this subchapter. pensions and gels typically has the fol 157 This entry includes hybrid electric vehi lowing composition: 60—85% ammonium ni cles powered by both an internal combus trate; 0-5% sodium or potassium per- tion engine and wet, sodium or lithium chlorate; 0—17% hexamine nitrate or batteries installed. Vehicles containing an 316 Pipeline and Hazardous Materials Safety Admin., DOT § 172.102
internal combustion engine must be con 166 When transported in non-friable tablet signed under the entry “Vehicle, flam form, calcium hypochlorite, dry, may be mable gas powered” or “Vehicle, flam transported as a Packing Group III mate mable liquid powered’, as appropriate. Ex rial. cept as provided in Special Provision AlOl, 167 These storage systems shall always be vehicles powered by primary lithium bat considered as containing hydrogen. teries, that are transported with these bat 168 For lighters containing a Division 2.1 teries installed are forbidden aboard pas gas (see §171.8 of this subchapter), rep senger-carrying aircraft. resentative samples of each new lighter de 159 This material must be protected from sign must be examined and successfully direct sunshine and kept in a cool, well- tested as specified in §173.308(b) (3). For cri ventilated place away from sources of heat, teria in determining what is a new lighter 160 This entry applies to articles that are design, see §173.308(b)(l). For transpor used as life-saving vehicle air bag infla tation of new lighter design samples for ex tors, air bag modules or seat-belt amination and testing, see §l73,308(b)(2). pretensioners containing Class I (explo The examination and testing of each light sive) materials or materials of other haz er design must be performed by a person ard classes, Air bag inflators and modules authorized by the Associate Administrator must be tested in accordance with Test se under the provisions of subpart E of part of ries 6(c) Part I of the UN Manual of 107 of this chapter, as specified in Tests and Criteria (incorporated by ref §173.308(a) (4). For continued use of approv erence; of this with see §171.7 subchapter), als dated prior to January 1, 2012. see no explosion of the device, no fragmenta 173.308(b) (5). tion of device casing or pressure vessel, § lighters and no projection hazard or thermal effect For non-pressurized containing a that would significantly hinder fire-fight Class 3 (flammable liquid) material, its de ing or other emergency response efforts in sign, description, and packaging must be ap the immediate vicinity. If the air bag in proved by the Associate Administrator prior flator unit satisfactorily passes the series to being offered for transportation or trans 6(c) test, it is not necessary to repeat the ported in commerce. In addition, a lighter test on the air bag module. design intended to contain a non-pressurized 161 For domestic transport, air bag infla Class 3 material is excepted from the exam tors, air bag modules or seat belt ination and testing criteria specified in pretensioners that meet the criteria for a §173.308(b) (3). An unused lighter or a lighter Division l.4G explosive must be trans that is cleaned of residue and purged of va ported using the description, “Articles, py pors is not subject to the requirements of rotechnic for technical purposes,” UN0431. this subchapter. 162 This material may be transported under 169 This entry applies to lighter refills (see the provisions of Division 4.1 only if it is §171.8 of this subchapter) that contain a packed so that at no time during transport Division 2.1 (flammable) gas but do not will the percentage of diluent fall below contain an ignition device. Lighter refills the percentage that is stated in the ship offered for transportation under this entry ping description. may not exceed 4 fluid ounces capacity 163 Substances must satisfactorily pass (7.22 cubic inches) or contain more than 65 Test Series 8 of the UN Manual of Tests grams of fuel. A lighter refill exceeding 4 and Criteria, Part I, Section 18 (IBR, see fluid ounces capacity (7,22 cubic inches) or §171.7 of this subchapter). containing more than 65 grams of fuel 164 Substances must not be transported must be classed as a Division 2.1 material, under this entry unless approved by the described with the proper shipping name Associate Administrator on the basis of appropriate for the material, and packaged the results of appropriate tests according in the packaging specified in part 173 of to Part I of the UN Manual of Tests and this subchapter for the flammable gas con Criteria (IBR, see §171.7 of this sub tained therein. In addition, a container ex chapter). The material must be packaged ceeding 4 fluid ounces volumetric capacity so that the percentage of diluent does not (7.22 cubic inches) or containing more than fall below that stated in the approval at 65 grams of fuel may not be connected or any time during transportation. manifolded to a lighter or similar device 165 These substances are susceptible to and must also be described and packaged exothermic decomposition at elevated tem according to the fuel contained therein. peratures. Decomposition can be initiated For transportation by passenger-carrying by heat, moisture or by impurities (e.g., aircraft, the net mass of lighter refills may powdered metals (iron, manganese, cobalt, not exceed 1 kg per package, and, for magnesium)). During the course of trans cargo-only aircraft, the net mass of lighter portation, these substances must be shaded refills may not exceed 15 kg per package, from direct sunlight and all sources of heat See § 173.306(h) of this subchapter. and be placed in adequately ventilated 170 Air must be eliminated from the vapor areas. space by nitrogen or other means.
317 § 172.102 49 CFR Ch. I (10—1—10 Edition)
171 This entry may only be used when the f. Effective October 1, 2008, except when material is transported in non-friable tab contained in equipment, each package con let form or for granular or powered mix taining more than 24 lithium cells or 12 lith tures that have been shown to meet the PG ium batteries must be: III criteria in173.l27. (1) Marked to indicate that it contains 172 This entry includes alcohol mixtures lithium batteries, and special procedures containing up to 5% petroleum products. should be followed if the package is dam 175 This substance must be stabilized when aged; in concentrations of not more than 99%. (2) Accompanied by a document indicating 177 Gasoline, or, ethanol and gasoline mix that the package contains lithium batteries tures, for use in internal combustion en and special procedures should be followed if gines (e.g., in automobiles, stationary en the package is damaged; gines and other engines) must be assigned (3) Capable of withstanding a 1.2 meter to Packing Group II regardless of vari drop test in any orientation without damage ations in volatility. to cells or batteries contained in the pack 188 Small lithium cells and batteries. Lithium age, without shifting of the contents that cells or batteries, including cells or bat would allow short circuiting and without re teries packed with or contained in equip lease of package contents; and ment, are not subject to any other require (4) Gross weight of the package may not nients of this subchapter if they meet all of exceed 30 kg (66 pounds). This requirement the following: does not apply to lithium cells or batteries a. Primary lithium batteries and cells. packed with equipment; (1) Primary lithium batteries and cells are g. Electrical devices must conform to forbidden for transport aboard passenger-car § 17321; l’ying aircraft. The outside of each package h. For transportation by aircraft, a tele that contains primary (nonrechargeable) phone report in accordance with §171.15(a) is lithium batteries or cells must be marked required if a fire, violent rupture, explosion “PRIMARY LITHIUM BATTERIES—FOR or dangerous evolution of heat (i.e., an BIDDEN FOR TRANSPORT ABOARD PAS amount of heat sufficient to be dangerous to SENGER AIRCRAFT” or “LITHIUM METAL packaging or personal safety to include char BATTERIES—FORBIDDEN FOR TRANS ring of packaging, melting of packaging, PORT ABOARD PASSENGER AIRCRAFT” scorching of packaging, or other evidence) on a background of contrasting color. The occurs as a direct result of a lithium battery. letters in the marking must be: For all modes of transportation, a written (i) At least 12 mm (0.5 inch) in height on report submitted, retained, and updated in packages having a gross weight of more than accordance with §171.16 is required if a fire, 30 kg (66 pounds); or violent rupture, explosion or dangerous evo (ii) At least 6 mm (0.25 inch) on packages lution of heat occurs as a direct result of a having a gross weight of 30 kg (66 pounds) or lithium battery or battery-powered device; less, except that smaller font may be used as and necessary to fit package dimensions; and i. Lithium batteries or cells are not au (2) The provisions of paragraph (a)(l) do thorized aboard an aircraft in checked or not apply to packages that contain 5 kg (11 carry-on luggage except as provided in pounds) net weight or less of primary lith §175.10. ium batteries or cells that are contained in 189 Medium lithium cells and batteries. Effec or packed with equipment and the package tive October 1, 2008, when transported by contains no more than the number of lith motor vehicle or rail car, lithium cells or ium batteries or cells necessary to power the batteries, including cells or batteries piece of equipment; packed with or contained in equipment, b. For a lithium metal or lithium alloy are not subject to any other requirements cell, the lithium content is not more than 1.0 of this subchapter if they meet all of the g. For a lithium-ion cell, the equivalent lith following: ium content is not more than 1.5 g; a. The lithium content anode of each cell, c. For a lithium metal or lithium alloy when fully charged, is not more than 5 battery, the aggregate lithium content is not grams. more than 2.0 g. For a lithium-ion battery, b. The aggregate lithium content of the the aggregate equivalent lithium content is anode of each battery, when fully charged, is not more than 8 g; not more than 25 grams. d. Effective October 1, 2009, the cell or bat c. The cells or batteries are of a type prov tery must be of a type proven to meet the re en to meet the requirements of each test in quirements of each test in the UN Manual of the UN Manual of Tests and Criteria (IBR; Tests and Criteria (IBR; see §171.7 of this see §171.7 of this subchapter). A cell or bat subchapter); tery and equipment containing a cell or bat e. Cells or batteries are separated or pack tery that was first transported prior to Janu aged in a manner to prevent short circuits ary 1, 2006 and is of a type proven to meet and are packed in a strong outer packaging the criteria of Class 9 by testing in accord or are contained in equipment; ance with the tests in the UN Manual of 318 Pipeline and Hazardous Materials Safety Admin., DOT § 172.102
Tests and Criteria, Third revised edition, TERIES—FORBIDDEN FOR TRANSPORT 1999, need not be retested. ABOARD PASSENGER AIRCRAFT” on a d. Cells or batteries are separated or pack background of contrasting color, The letters aged in a manner to prevent short circuits in the marking must be: and are packed in a strong outer packaging (i) At least 12 mm (0,5 inch) in height on or are contained in equipment. packages having a gross weight of more than e. The outside of each package must be 30 kg (66 pounds); or marked “LITHIUM BATTERIES—FORBID (ii) At least 6 mm (0.25 inch) on packages DEN FOR TRANSPORT ABOARD AIR having a gross weight of 30 kg (66 pounds) or CRAFT AND VESSEL” on a background of less, except that smaller font may be used as contrasting color, in letters: necessary to fit package dimensions; and (1) At least 12 mm (0,5 inch) in height on (2) The provisions of paragraph (a) (1) do packages having a gross weight of more than not apply to packages that contain 5 kg (11 30 kg (66 pounds); or pounds) net weight or less of primary lith (2) At least 6 mm (0.25 inch) on packages ium batteries or cells that are contained in having a gross weight of 30 kg (66 pounds) or or packed with equipment and the package less, except that smaller font may be used as contains no more than the number of lith necessary to fit package dimensions. ium batteries or cells necessary to power the f. Except when contained in equipment, piece of equipment. each package containing more than 24 lith b. The lithium content of each cell, when ium cells or 12 lithium batteries must be: fully charged, is not (1) Marked to indicate that it contains more than 5 grams. lithium batteries, and special procedures c. The aggregate lithium content of each should be followed if the package is dam battery, when fully charged, is not more aged; than 25 grams. (2) Accompanied by a document indicating d. The cells or batteries are of a type prov that the package contains lithium batteries en to meet the requirements of each test in and special procedures should be followed if the UN Manual of Tests and Criteria (IBR; the package is damaged; see §171.7 of this subchapter), A cell or bat (3) Capable of withstanding a 1.2 meter tery and equipment containing a cell or bat drop test in any orientation without damage tery that was first transported prior to Janu to cells or batteries contained in the pack ary 1, 2006 and is of a type proven to meet age, without shifting of the contents that the criteria of Class 9 by testing in accord would allow short circuiting and without re ance with the tests in the UN Manual of lease of package contents; and Tests and Criteria, Third Revised Edition, (4) Gross weight of the package may not 1999, need not be retested. exceed 30 kg (66 pounds). This requirement e, Cells or batteries are separated so as to does not apply to lithium cells or batteries prevent short circuits and are packed in a packed with equipment. strong outer packaging or are contained in g. Electrical devices must conform to equipment. § 173,21 of this subchapter; and f. Electrical devices must conform to h. A written report submitted, retained, § 173.21 of this subchapter. and updated in accordance with §171.16 is re 198 Nitrocellulose solutions containing not quired if a fire, violent rupture, explosion or more than 20% nitrocellulose may be dangerous evolution of heat (i.e., an amount transported as paint or printing ink, as ap of heat sufficient to be dangerous to pack plicable. See UN121O, UN1263, UN3066, aging or personal safety to include charring UN3469, and UN3470. of packaging, melting of packaging, scorch 237 “Batteries, dry, containing potassium ing of packaging, or other evidence) occurs hydroxide solid, electric storage” must be as a direct result of a lithium battery or bat prepared and packaged in accordance with tery-powered device, the requirements ofl73.l59(a), (b), and (c). 190 Until the effective date of the standards For transportation by aircraft, the provi set forth in Special Provision 189, medium sions of § 173.159(b) (2) are applicable. lithium cells or batteries, including cells 332 Magnesium nitrate hexahydrate is not or batteries packed with or contained in subject to the requirements of this sub equipment, are not subject to any other re chapter. quirements of this subchapter if they meet 335 Mixtures of solids that are not subject all of the following: to this subchapter and environmentally a. Primary lithium batteries and cells. (1) Pri hazardous liquids or solids may be classi mary lithium batteries and cells are forbid fied as “Environmentally hazardous sub den for transport aboard passenger-carrying stances, solid, no.s,” UN3077 and may be aircraft. The outside of each package that transported under this entry, provided contains primary (nonrechargeable) lithium there is no free liquid visible at the time batteries or cells must be marked “PRI the material is loaded or at the time the MARY LITHIUM BATTERIES—FORBIDDEN packaging or transport unit is closed. Each FOR TRANSPORT ABOARD PASSENGER transport unit must be leakproof when AIRCRAFT” or “LITHIUM METAL BAT- used as bulk packaging, 319 § 172.102 49 CFR Ch. 1(10—1—10 Edition)
(2) ‘A” codes. These provisions apply A34 Aerosols containing a corrosive liquid only to transportation by aircraft: in Packing Group II charged with a gas are not permitted for transportation by air Code/Special Provisions craft. A35 This includes any material which is not Al Single packagings are not permitted on covered by any of the other classes but passenger aircraft. which has an anesthetic, narcotic, noxious A2 Single packagings are not permitted on or other similar properties such that, in aircraft. the event of spillage or leakage on an air A3 For combination packagings, if glass craft, extreme annoyance or discomfort inner packagings (including ampoules) are could be caused to crew members so as to used, they must be packed with absorbent prevent the correct performance of as material in tightly closed metal recep signed duties. tacles before packing in outer packagings. A37 This entry applies only to a material A4 Liquids having an inhalation toxicity of meeting the definition in §171.8 of this sub Packing Group I are not permitted on air chapter for self-defense spray. craft. A53 Refrigerating machines and refrig A5 Solids having an inhalation toxicity of erating machine components are not sub Packing Group I are not permitted on pas ject to the requirements of this subchapter senger aircraft and may not exceed a max when containing less than 12 kg (26.4 imum net quantity per package of 15 kg (33 pounds) of a non-flammable gas or when pounds) on cargo aircraft. containing 12 L (3 gallons) or less of ammo A6 For combination packagings, if plastic nia solution (UN2672) (see §173.307 of this inner packagings are used, they must be subchapter). packed in tightly closed metal receptacles A54 Lithium batteries or lithium batteries before packing in outer packagings. contained or packed with equipment that A7 Steel packagings must be corrosion-re exceed the maximum gross weight allowed sistant or have protection against corro by Column (9B) of the §172.101 Table may sion. only be transported on cargo aircraft if ap A8 For combination packagings, if glass proved by the Associate Administrator. inner packagings (including ampoules) are A55 Prototype lithium batteries and cells used, they must be packed with cushioning that are packed with not more than 24 material in tightly closed metal recep cells or 12 batteries per packaging that tacles before packing in outer packagings. have not completed the test requirements in Sub-section A9 For combination packagings, if plastic 38.3 of the UN Manual of Tests and Criteria (incorporated by ref bags are used, they must be packed in erence: see 171.7 of this subchapter) tightly closed metal receptacles before § may transported packing in outer packagings. be by cargo aircraft if ap proved by the Associate Administrator and AlO When aluminum or aluminum alloy provided the following requirements are construction materials are used, they must met: be resistant to corrosion. a. The cells and batteries must be trans All For combination packagings, when ported in rigid outer packagings that metal inner packagings are permitted, conform to the requirements of Part 178 only specification constructed cylinders of of this subchapter at the Packing Group metals which are compatible with the haz I performance level: and ardous material may be used. b. Each cell and battery must be protected Al3 Bulk packagings are not authorized for against short circuiting, must be sur transportation by aircraft. rounded by cushioning material that is A14 This material is not authorized to be non-combustible and non-conductive, and transported as a limited quantity or con must be individually packed in an inner sumer commodity in accordance with packaging that is placed inside an outer § 173.306 of this subchapter when trans specification packaging. ported aboard an aircraft. A56 Radioactive material with a subsidiary A19 Combination packagings consisting of hazard of Division 4.2, Packing Group I, outer fiber drums or plywood drums, with must be transported in Type B packages inner plastic packagings, are not author when offered for transportation by air ized for transportation by aircraft. craft. Radioactive material with a sub A20 Plastic bags as inner receptacles of sidiary hazard of Division 2.1 is forbidden combination packagings are not authorized from transport on passenger aircraft. for transportation by aircraft. A59 Sterilization devices, when containing A29 Combination packagings consisting of less than 30 mL per inner packaging with outer expanded plastic boxes with inner no more than 300 mL per outer packaging plastic bags are not authorized for trans may be transported in accordance with portation by aircraft. provisions in § l73.4a, irrespective of A30 Ammonium permanganate is not au §173.4a(b). In addition, after filling, each thorized for transportation on aircraft. inner packaging must be determined to be 320 Pipeline and Hazardous Materials Safety Admin., DOT § 172.102
leak-tight by placing the inner packaging ages that are authorized aboard passenger in a hot water bath at a temperature and carrying aircraft. for a period of time sufficient to ensure an A105 The total net quantity of dangerous internal pressure equal to the vapor pres goods contained in one package, excluding sure of ethylene oxide at 55 °C is achieved. magnetic material, must not exceed the fol Any inner packaging showing evidence of lowing: leakage, distortion or other defect under a. 1 kg (2.2 pounds) in the case of solids; this test may not be transported under the b. 0.5 L (0.1 gallons) in the case of liquids; terms of this special provision. In addition c. 0.5 kg (1.1 pounds) in the case of Division to the packaging required in §173.4a, inner 2.2 gases; or packagings must be placed in a sealed plas d. any combination thereof. tic bag compatible with ethylene oxide and capable of containing the contents in the (3) “B” codes, These provisions apply event of breakage or leakage of the inner only to bulk packagings. Except as packaging. Glass inner packagings must be otherwise provided in this subchapter, placed within a protective shield capable of these special provisions do not apply to preventing the glass from puncturing the UN portable tanks or IBCs: plastic bag in the event of damage to the packaging (e.g., crushing). Code/Special Provisions A60 Sterilization devices, when containing Bl If the material has a flash point at or less than 30 mL per inner packaging with above 38 °C (100 °F) and below 93 °C (200 °F), not more than 150 mL per Outer packaging, then the bulk packaging requirements of may be transported in accordance with the § 173.241 of this subchapter are applicable. provisions in § 173.4a, irrespective of If the material has a flash point of less § 173.4a(b), provided such packagings were than 38 °C (100 °F), then the bulk packaging first subjected to comparative fire testing. requirements of § 173.242 of this subchapter Comparative fire testing must show no dif are applicable. ference in burning rate between a package B2 MC 300, MC 301, MC 302, MC 303, MC 305, as prepared for transport (including the and MC 306 and DOT 406 cargo tanks are substance to be transported) and an iden not authorized. tical package filled with water. B3 MC 300, MC 301, MC 302, MC 303, MC 305, A82 The quantity limits in columns (9A) and MC 306 and DOT 406 cargo tanks and and (9B) do not apply to human or animal DOT 57 portable tanks are not authorized. body parts, whole organs or whole bodies B4 MC 300, MC 301, MC 302, MC 303, MC 305, known to contain or suspected of con and MC 306 and DOT 406 cargo tanks are taining an infectious substance. not authorized. A100 Primary (non-rechargeable) lithium B5 Only ammonium nitrate solutions with batteries and cells are forbidden for trans 35 percent or less water that will remain port aboard passenger carrying aircraft. completely in solution under all conditions Secondary (rechargeable) lithium batteries of transport at a maximum lading tem and cells are authorized aboard passenger perature of 116 °C (240 °F) are authorized carrying aircraft in packages that do not for transport in the following bulk pack exceed a gross weight of 5 kg. agings: MC 307, MC 312, DOT 407 and DOT AlOl A primary lithium battery or cell 412 cargo tanks with at least 172 kPa (25 packed with or contained in equipment is psig) design pressure. The packaging shall forbidden for transport aboard a passenger be designed for a working temperature of carrying aircraft unless the equipment and at least 121 °C (250 °F). Only Specifications the battery conform to the following provi MC 304, MC 307 or DOT 407 cargo tank sions and the package contains no more motor vehicles are authorized for transpor than the number of lithium batteries or tation by vessel. cells necessary to power the intended piece B6 Packagings shall be made of steel. of equipment: B7 Safety relief devices are not authorized (I) The lithium content of each cell, when on multi-unit tank car tanks. Openings for fully charged, is not more than 5 grams. safety relief devices on multi-unit tank car (2) The aggregate lithium content of the tanks shall be plugged or blank flanged. anode of each battery, when fully charged, is B8 Packagings shall be made of nickel, not more than 25 grams. stainless steel, or steel with nickel, stain (3) The net weight of lithium batteries does less steel, lead or other suitable corrosion not exceed 5 kg (11 pounds). resistant metallic lining. A103 Equipment is authorized aboard pas B9 Bottom outlets are not authorized. senger carrying aircraft if the gross weight BlO MC 300, MC 301, MC 302, MC 303, MC 305, of the inner package of secondary lithium and MC 306 and DOT 406 cargo tanks, and batteries or cells packed with the equip DOT 57 portable tanks are not authorized. ment does not exceed 5 kg (11 pounds). B1l Tank car tanks must have a test pres Al04 The net weight of secondary lithium sure of at least 2,068.5 kPa (300 psig). Cargo batteries or cells contained in equipment and portable tanks must have a design may not exceed 5 kg (11 pounds) in pack- pressure of at least 1,207 kPa (175 psig).
321 § 172.102 49 CFR Ch. 1(10—1—10 Edition)
B13 A nonspecification cargo tank motor ture range. In addition, the material also vehicle authorized in § 173.247 of this sub must be covered with an inert gas or the chapter must be at least equivalent in de container must be filled with water to sign and in construction to a DOT 406 the tank’s capacity. After unloading, the cargo tank or MC 306 cargo tank (if con residual material also must be covered structed before August 31, 1995), except as with an inert gas or the container must follows: be filled with water to the tank’s capac a. Packagings equivalent to MC 306 cargo ity. tanks are excepted from the certifi B27 Tanks must have a service pressure of cation. venting, and emergency flow re 1,034 kPa (150 psig). Tank car tanks must quirements of the MC 306 specification. have a test pressure rating of 1,379 kPa (200 b. Packagings equivalent to DOT 406 cargo psig). Lading must be blanketed at all tanks are excepted from §l78.345—7(d)(5), times with a dry inert gas at a pressure not circumferential reinforcements; 178,345— to exceed 103 kPa (15 psig). 10, pressure relief: 178.345—Il, outlets; B28 Packagings must be made of stainless 178.345—14, marking, and 178.345—15, cer steel. tification. B30 MC 312, MC 330, MC 331 and DOT 412 c. Packagings are excepted from the design cargo tanks and DOT 51 portable tanks stress limits at elevated temperatures, as must be made of stainless steel, except described in Section VIII of the ASME that steel other than stainless steel may Code (IBR, see §171.7 of this subchapter). be used in accordance with the provisions However, the design stress limits may of 173.24b(b) of this subchapter. Thickness not exceed 25 percent of the stress for 0 § of stainless steel for tank and heads temper at the maximum design tempera shell for cargo tanks and portable tanks must ture of the cargo tank, as specified in the be the greater of Aluminum Association’s ‘Aluminum 7.62 mm (0.300 inch) or the thickness required for a design Standards and Data” (IBR, see §171.7 of tank with a pressure this subchapter). at least equal to 1.5 times the vapor pressure B14 Each bulk packaging, except a tank car of the lading at 46 °C (115 CF). In or a multi-unit-tank car tank, must be in addition, MC 312 and DOT 412 cargo tank sulated with an insulating material so that motor vehicles must: the overall thermal conductance at 15.5 °C a. Be ASME Code (U) stamped for 100% ra (60 F) is no more than 1.5333 kilojoules per diography of all pressure-retaining welds; hour per square meter per degree Celsius b. Have accident damage protection which (0.075 Btu per hour per square foot per de conforms with § 178.345—8 of this sub gree Fahrenheit) temperature differential. chapter; Insulating materials must not promote c. Have a MAWP or design pressure of at corrosion to steel when wet. least 87 psig: and B15 Packagings must be protected with d. Have a bolted manway cover. non-metallic linings impervious to the lad B32 MC 312, MC 330, MC 331, DOT 412 cargo ing or have a suitable corrosion allowance. tanks and DOT 51 portable tanks must be B16 The lading must be completely covered made of stainless steel, except that steel with nitrogen, inert gas or other inert ma other than stainless steel may be used in terials. accordance with the provisions of B18 Open steel hoppers or bins are author § l73.24b(b) of this subchapter. Thickness of ized. stainless steel for tank shell and heads for B23 Tanks must be made of steel that is cargo tanks and portable tanks must be rubber lined or unlined. Unlined tanks the greater of 6.35 mm (0.250 inch) or the must be passivated before being placed in thickness required for a tank with a design service. If unlined tanks are washed Out pressure at least equal to 1.3 times the with water, they must be repassivated vapor pressure of the lading at 46 C (115 prior to return to service. Lading in un °F). In addition, MC 312 and DOT 412 cargo lined tanks must be inhibited so that the tank motor vehicles must: corrosive effect on steel is not greater than a. Be ASME Code (U) stamped for 100% radi that of hydrofluoric acid of 65 percent con ography of all pressure-retaining welds; centration. b. Have accident damage protection which B25 Packagings must be made from monel conforms with §178.345—8 of this sub or nickel or monel-lined or nickel-lined chapter; steel. c. Have a MAWP or design pressure of at B26 Tanks must be insulated. Insulation least 87 psig; and must be at least 100 mm (3.9 inches) ex d. Have a bolted manway cover. cept that the insulation thickness may B33 MC 300, MC 301, MC 302, MC 303, MC 305, be reduced to 51 mm (2 inches) over the MC 306, and DOT 406 cargo tanks equipped exterior heater coils. Interior heating with a I psig normal vent used to transport coils are not authorized. The packaging gasoline must conform to Table I of this may not be loaded with a material out Special Provision. Based on the volatility side of the packaging’s design tempera- class determined by using ASTM D 439 and 322 Pipeline and Hazardous Materials Safety Admin., DOT § 172.102
the Reid vapor pressure (RVP) of the par B49 Tanks equipped with interior heater ticular gasoline, the maximum lading pres coils are not authorized. Single unit tank sure and maximum ambient temperature car tanks must have a reclosing pressure permitted during the loading of gasoline relief device having a start-to-discharge may not exceed that listed in Table I. pressure set at no more than 1551 kPa (225 psig). TABLE I—MAxIMuM AMBIENT TEMPERATuRE— B50 Each valve outlet of a multi-unit tank GASOLINE car tank must be sealed by a threaded solid plug or a threaded cap with inert luting or Maximum lading and gasket material. Valves must be of stain ASTM D439 volatility class ambient temperature less steel and the plugs, and (see note 1) caps, valve seats must be of a material that will not A 131F deteriorate as a result of contact with the (RVP<=9.0 psia) lading. B 124SF B52 Notwithstanding the provisions of (RVP<10.O psia) § 173.24b of this subchapter, non-reclosing C 116F pressure relief devices are authorized on (RVP<=11.5 psia) DOT 57 portable tanks. 0 I07F B53 (RVP<=13.5 psia) Packagings must be made of either alu E 100F minum or steel, (RVP<=15.O psia) B54 Open-top, sift-proof rail cars are also authorized. NOTE 1: Based on maximum lading pressure of 1 psig at top of cargo tank. B55 Water-tight, sift-proof, closed-top, metal-covered hopper cars, equipped with a B35 Tank cars containing hydrogen cyanide venting arrangement (including flame ar may be alternatively marked restors) approved by the Associate Admin ‘Hydrocyanic acid, liquefied” if otherwise istrator are also authorized. conforming to marking requirements in B56 Water-tight, sift-proof, closed-top. subpart D of this part. Tank cars marked metal-covered hopper cars are also author “HYDROCYANIC ACID” prior to October ized if the particle size of the hazardous 1, 1991 do not need to be remarked. material is not less than 149 microns. B37 The amount of nitric oxide charged into B57 Class ll5A tank car tanks used to trans any tank car tank may not exceed 1,379 port chloroprene must be equipped with a kPa (200 psig) at 21 C (70 °F). non-reclosing pressure relief device of a di B42 Tank cars constructed before March 16, ameter not less than 305 mm (12 inches) 2009, must have a test pressure of 34.47 Bar with a maximum rupture disc pressure of (500 psig) or greater and conform to Class 310 kPa (45 psig). 105J. Each tank car must have a reclosing B59 Water-tight, sift-proof, closed-top, pressure relief device having a start-to-dis metal-covered hopper cars are also author charge pressure of 10.34 Bar (150 psig). The ized provided that the lading is covered tank car specification may be marked to with a nitrogen blanket. indicate a test pressure of 13.79 Bar (200 B60 DOT Specification 106A500X multi-unit psig). tank car tanks that are not equipped with B44 All parts of valves and safety relief de a pressure relief device of any type are au vices in contact with lading must be of a thorized. For the transportation of phos material which will not cause formation of gene, the outage must be sufficient to pre acetylides. vent tanks from becoming liquid full at 55 B45 Each tank must have a reclosing com C (130 OF) bination pressure relief device equipped B6l Written procedures covering details of with stainless steel or platinum rupture tank car appurtenances, dome fittings, discs approved by the AAR Tank Car Com safety devices, and marking, loading. han niittee. dling, inspection, and testing practices B46 The detachable protective housing for must be approved by the Associate Admin the loading and unloading valves of multi- istrator before any single unit tank car unit tank car tanks must withstand tank tank is offered for transportation. test pressure and must be approved by the B65 Tank cars constructed before March 16, Associate Administrator. 2009, must have a test pressure of 34.47 Bar B47 Each tank may have a reclosing pres (500 psig) or greater and conform to Class sure relief device having a start-to-dis 105A. Each tank car must have a reclosing charge pressure setting of 310 kPa (45 psig). pressure relief device having a start-to-dis B48 Portable tanks in sodium metal service charge pressure of 15.51 Bar (225 psig). The may be visually inspected at least once tank car specification may be marked to every 5 years instead of being retested indicate a test pressure of 20.68 Bar (300 hydrostatically. Date of the visual inspec psig). tion must be stenciled on the tank near B66 Each tank must be equipped with gas the other required markings. tight valve protection caps. Outage must 323 § 172.102 49 CFR Ch. 1(10—1—10 Edition)
be sufficient to prevent tanks from becom B83 Bottom outlets are prohibited on tank ing liquid full at 55 °C (130 °F). Specifica car tanks transporting sulfuric acid in con tion 110A500W tanks must be stainless centrations over 65.25 percent. steel. B84 Packagings must be protected with B67 All valves and fittings must be pro non-metallic linings impervious to the lad tected by a securely attached cover made ing or have a suitable corrosion allowance of metal not subject to deterioration by for sulfuric acid or spent sulfuric acid in the lading, and all valve openings, except concentration up to 65.25 percent. safety valve, must be fitted with screw B85 Cargo tanks must be marked with the plugs or caps to prevent leakage in the name of the lading in accordance with the event of valve failure. requirements of § 172.302(b). B68 Sodium must be in a molten condition B90 Steel tanks conforming or equivalent when loaded and allowed to solidify before to ASME specifications which contain shipment. Outage must be at least 5 per solid or semisolid residual motor fuel anti cent at 98 °C (208 °F). Bulk packagings knock mixture (including rust, scale, or must have exterior heating coils fusion other contaminants) may be shipped by welded to the tank shell which have been rail freight or highway. The tank must properly stress relieved. The only tank car have been designed and constructed to be tanks authorized are Class DOT 105 tank capable of withstanding full vacuum. All cars having a test pressure of 2.069 kPa (300 openings must be closed with gasketed psig) or greater. blank flanges or vapor tight threaded clo B69 Dry sodium cyanide or potassium cy sures. anide may be shipped in the following sift- Bl15 Rail cars, highway trailers, roll-on/ proof and weather-resistant packagings: roll-off bins, or other non-specification metal covered hopper cars, covered motor bulk packagings are authorized. Pack vehicles, portable tanks, or non-specification agings must be sift-proof, prevent liquid bins. water from reaching the hazardous mate B70 If DOT 1O3ANW tank car tank is used: rial, and be provided with sufficient vent All cast metal in contact with the lading ing to preclude dangerous accumulation of must have 96.7 percent nickel content; and flammable, corrosive, or toxic gaseous the lading must be anhydrous and free emissions such as methane, hydrogen, and from any impurities. ammonia. The material must be loaded B76 Tank cars constructed before March 16, dry. 2009, must have a test pressure of 20.68 Bar (300 psig) or greater and conform to Class (4) lB Codes and IP Codes. These pro 105S, 112J, ll4J or l2OS. Each tank car visions apply only to transportation in must have a reclosing pressure relief de IBCs and Large Packagings. Table 1 au vice having a start-to-discharge pressure of thorizes IBCs for specific proper ship 10.34 Bar (150 psig). The tank car specifica ping names through the use of TB Codes tion may be marked to indicate a test pres assigned in the §172.101 table of this sure of 13.79 Bar (200 psig). subchapter. Table 2 defines IP Codes on B77 Other packaging are authorized when approved by the Associate Administrator. the use of IBCs that are assigned to B78 Tank cars must have a test pressure of specific commodities in the § 172.101 4.14 Bar (60 psig) or greater and conform to Table of this subchapter. Table 3 au Class 103, 104. 105, 109, 111, 112, 114 or 120. thorizes Large Packagings for specific Heater pipes must be of welded construc proper shipping names through the use tion designed for a test pressure of 500 psig. of lB Codes assigned in the §172.101 A 25 mm (1 inch) woven lining of asbestos table of this subchapter. Large Pack or other approved material must be placed agings are authorized for the Packing between the bolster slabbing and the bot Group tom of the tank. If a tank car tank is III entries of specific proper equipped with a non-reclosing pressure re shipping names when either Special lief device, the rupture disc must be per Provision 1B3 or 1B8 is assigned to that forated with a 3.2 mm (0.13 inch) diameter entry in the § 172.101 Table. When no TB hole. If a tank car tank is equipped with a code is assigned in the §172.101 Table reclosing pressure relief valve, the tank for a specific proper shipping name, or must also be equipped with a vacuum relief in §173.225(e) Organic Peroxide Table valve. for Type F organic peroxides, use of an B80 Each cargo tank must have a minimum IBC or Large Packaging the design pressure of 276 kPa (40 psig). for mate B81 Venting and pressure relief devices for rial may be authorized when approved tank car tanks and cargo tanks must be by the Associate Administrator. The approved by the Associate Administrator. letter “Z” shown in the marking code B82 Cargo tanks and portable tanks are not for composite IBCs must be replaced authorized. with a capital code letter designation
324 Pipeline and Hazardous Materials Safety Admin., DOT § 172.102
found in § 178.702(a)(2) of this sub the other packaging. Tables 1, 2, and 3 chapter to specify the material used for follow:
TABLE 1—lB CODES (IBC CODES)
BC Code Authorized IBCs
181 Authorized lBCs: Metal (31A, 31B and 31N). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 CF), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized. 182 Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (3IHZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 SF), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized. 183 Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 311-12); Composite (31HZ1 and 31HA2, 31H82, 31t-1N2, 31HD2 and 31HH2). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 SF), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized, except for UN2672 (also see Special Provision 1P8 in Table 3 for UN2672). For authorized Large Packagings, see Table 3. 184 Authorized tBCs: Metal (hA, 118, uN, 21A, 218, 21N, 31A, 318 and 31N). 185 Authorized IBCs: Metal (hA, 11B, uN, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 211-Il, 21H2, 31H1 and 31H2); Composite (11HZ1, 21HZ1 and 31HZ1). 186 Authorized lBCs: Metal (hA, 11B, 11N, 21A, 21B, 21N, 31A. 318 and 31N): Rigid plastics (11H1, 111-12, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2). Additional Requirement: Composite IBC5 11 HZ2 and 21 HZ2 may not be used when the hazardous mate rials being transported may become liquid during transport. 187 Authorized IBCs: Metal (hA, 11B, uN, 21A, 21B, 21N, 31A, 318 and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 2h1-lZ2, 31HZI and 31HZ2); Wooden (11C, liD and hF). Additional Requirement: Liners of wooden lBCs must be sift- proof. 188 Authorized lBCs: Metal (1 1A, 11 B, 11 N, 21A, 21 B, 21 N, 31A, 31 B and 31 N); Rigid plastics (11 Hi, hi H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, I1HZ2, 2IHZ1, 21HZ2, 31HZ1 and 31HZ2); Fiber board (hG); Wooden (I1C, lID and hF): Flesible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2). For authorized Large Packagings, see Table 3. 189 lBCs are only authorized if approved by the Associate Administrator.
TABLE 2—IP CODES
PP Code
Ipi IBCs must be packed in closed freight containers or a closed transport vehicle. 1P2 When lBCs other than metal or rigid plastics lBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle. P3 Flexible lBCs must be sift-proof and waler-resistant or must be filled with a sift-proof and water-resistant liner. 1P4 Flexible, fiberboard or wooden IBCs must be sift-proof and waler-resistant or be fitted with a sift-proof and water-resistant liner. 1P5 IBCs must have a device to allow venting. The inlet to the venting device must be located in the vapor space of the IBC under maximum filling conditions. 1P6 Non-specification bulk bins are authorized. P7 For UN identification numbers 1327, 1363, 1364, 1365, 1386, 1841, 2211, 2217, 2793 and 3314, IBCs are not required to meet the IBC performance tests specified in part 178, subpart N of this subchapter. lP8 Ammonia solutions may be transported in rigid or composite plastic IBCs (31H1, 311-12 and 31HZI) that have successfully passed, without leakage or permanent deformation, the hydrostatic test specified in § 178.814 of this subchapter at a test pressure that is not less than 1.5 times the vapor pressure of the contents at 55 C (131 CF). 1P13 Transportation by vessel in IBCs is prohibited. 1P14 Air must be eliminated from the vapor space by nitrogen or other means. P15 For UN2031 with more than 55% nitric acid, rigid plastic IBCs and composite IBCs with a rigid plastic inner receptacle are authorized for two years from the date of BC manufacture. lP2O Dry sodium cyanide or potassium cyanide is also permitted in siftproof, water-resistant, fiberboard IBCs when transported in closed freight containers or transport vehicles.
TABLE 3—lB CODES [Large packaging authorizations]
183 Authorized Large Packagings (LIQUIDS) (PG III materials only) 2
Inner packagings: Large outer packagings: Glass 10 steel (50A). liter. Plastics 30 aluminum (50B). liter.
325 § 172.102 49 CFR Ch. 1(10—1—10 Edition)
TABLE 3—lB CODES—Continued [Large packaging authorizations]
lB3 Authorized Large Packagings (LIOUIDS) (PG III materials only) 2
Metal 40 metal other than steel or aluminum (50f’J). liter. rigid plastics (50H). natural wood (5OC). plywood (500). reconstituted wood (50F). rigid fiberboard (50G).
lB8 Authorized Large Packagings (SOLIDS) (PG III materials only)2
Inner packagings: Large outer packagings: Glass 10 kg steel (50A). Plastics 50 kg aluminum (SOB). Metal 50 kg metal other than steel or aluminum (50N(. Paper 50 kg flesible plastics (51 H).’ Fiber 50 kg rigid plastics (SOH). natural wood (50C). plywood (500). reconstituted wood (50F). rigid fiberboard (50G). ‘Flexible plastic (51 H) Large Packagings are only authorized for use with flesible inner packagings. 2 Escept when authorized under Special Provision 41.
(5) ‘N’ codes. These provisions apply strong, tight non-bulk packaging meeting only to non-bulk packagings: the requirements of subparts A and B of part 173 of this subchapter. Code/Special Provisions Nl2 Plastic packagings are not authorized. N3 Glass inner packagings are permitted in N20 A 5M1 multi-wall paper bag is author combination or composite packagings only ized if transported in a closed transport ve if the hazardous material is free from hicle. hydrofluoric acid. N25 Steel single packagings are not author N4 For combination or composite pack ized. agings, glass inner packagings, other than N32 Aluminum materials of construction ampoules, are not permitted. are not authorized for single packagings. N5 Glass materials of construction are not N33 Aluminum drums are not authorized. authorized for any part of a packaging N34 Aluminum construction materials are which is normally in contact with the haz not authorized for any part of a packaging ardous material. which is normally in contact with the haz N6 Battery fluid packaged with electric ardous material. storage batteries, wet or dry, must con N36 Aluminum or aluminum alloy construc form to the packaging provisions of tion materials are permitted only for halo § 173.159 (g) or (h) of this subchapter. genated hydrocarbons that will not react N7 The hazard class or division number of with aluminum. the material must be marked on the pack N37 This material may be shipped in an in age in accordance with § 172.302 of this sub tegrally-lined fiber drum (IC) which meets chapter. However, the hazard label cor the general packaging requirements of sub responding to the hazard class or division part B of part 173 of this subchapter, the may be substituted for the marking. requirements of part 178 of this subchapter N8 Nitroglycerin solution in alcohol may be at the packing group assigned for the ma transported under this entry only when the terial and to any other special provisions solution is packed in metal cans of not of column 7 of the § 172.101 table. more than I L capacity each, overpacked N40 This material is not authorized in the in a wooden box containing not more than following packagings: 5 L. Metal cans must be completely sur a. A combination packaging consisting of a rounded with absorbent cushioning mate 4G fiberboard box with inner receptacles rial. Wooden boxes must be completely of glass or earthenware; lined with a suitable material impervious b. A single packaging of a 4C2 sift-proof, to water and nitroglycerin. natural wood box; or Nil This material is excepted for the speci c. A composite packaging 6PG2 (glass, por fication packaging requirements of this celain or stoneware receptacles within a subchapter if the material is packaged in fiberboard box). 326 Pipeline and Hazardous Materials Safety Admin., DOT § 172.102
N41 Metal construction materials are not uid contents are absorbed in an inert mate authorized for any part of a packaging rial. which is normally in contact with the haz N78 Packages consisting of inner glass, ardous material. earthenware, or polyethylene or other non- N42 IAI drums made of carbon steel with fragile plastic bottles or jars not over 0.5 thickness of body and heads of not less kg (1.1 pounds) capacity each, or metal than 1.3 mm (0.050 inch) and with a corro cans not over five pounds capacity each, sion-resistant phenolic lining are author packed in outer wooden boxes, barrels or ized for stabilized benzyl chloride if tested kegs, or fiberboard boxes are authorized and certified to the Packing Group I per and need not conform to the requirements formance level at a specific gravity of not of part 178 of this subchapter. Net weight less than 1.8. of contents in fiberboard boxes may not ex N43 Metal drums are permitted as single ceed 29 kg (64 pounds). Net weight of con packagings only if constructed of nickel or tents in wooden boxes, barrels or kegs may monel. not exceed 45 kg (99 pounds). N45 Copper cartridges are authorized as N79 Packages consisting of tightly closed inner packagings if the hazardous material metal inner packagings not over 0.5 kg (1.1 is not in dispersion. pounds) capacity each, packed in Outer N65 Outage must be sufficient to prevent wooden or fiberboard boxes, or wooden bar cylinders or spheres from becoming liquid rels, are authorized and need not conform full at 55 C (130 CF). The vacant space (out to the requirements of part 178 of this sub age) may be charged with a nonflammable chapter. Net weight of contents may not nonliquefied compressed gas if the pressure exceed 15 kg (33 pounds). in the cylinder or sphere at 55 °C (130 °F) N80 Packages consisting of one inner metal does not exceed 125 percent of the marked can, not over 2.5 kg (5.5 pounds) capacity, service pressure. packed in an outer wooden or fiberboard N72 Packagings must be examined by the box, or a wooden barrel, are authorized and Bureau of Explosives and approved by the need not conform to the requit-ements of Associate Administrator. part 178 of this subchapter. N73 Packagings consisting of outer wooden N82 See §173.115 of this subchapter for clas or fiberboard boxes with inner glass, metal sification criteria for flammable aerosols. or other strong containers; metal or fiber N83 This material may not be transported drums; kegs or barrels; or strong metal in quantities of more than 11.5 kg (25.4 Ibs) cans are authorized and need not conform per package. to the requirements of part 178 of this sub N84 The maximum quantity per package is chapter. 500 g (1.1 lbs.). N74 Packages consisting of tightly closed N85 Packagings certified at the Packing inner containers of glass, earthenware, Group I performance level may not be metal or polyethylene, capacity not over used. 0.5 kg (1.1 pounds) securely cushioned and N86 UN pressure receptacles made of alu packed in outer wooden barrels or wooden minum alloy are not authorized. or fiberboard boxes, not over 15 kg (33 N87 The use of copper valves on UN pressure pounds) net weight, are authorized and receptacles is prohibited. need not conform to the requirements of N88 Any metal part of a UN pressure recep part 178 of this subchapter. tacle in contact with the contents may not N75 Packages consisting of tightly closed contain more than 65% copper. with a tol inner packagings of glass, earthenware or erance of 1%. metal, securely cushioned and packed in N89 When steel UN pressure receptacles are outer wooden barrels or wooden or fiber used, only those bearing the “H” mark are board boxes, capacity not over 2.5 kg (5.5 authorized. pounds) net weight, are authorized and N90 Metal packagings are not authorized. need not conform to the requirements of (6) “R” codes. These provisions apply part 178 of this subchapter. only to transportation N76 For materials of not more than 25 per by rail. iRe- cent active ingredient by weight, packages served] consisting of inner metal packagings not (7) “T” codes. (I) These provisions greater than 250 mL (8 ounces) capacity apply to the transportation of haz each, packed in strong outer packagings ardous materials in UN portable tanks. together with sufficient absorbent mate Portable tank instructions specify the rial to completely absorb the liquid con requirements applicable to a portable tents are authorized and need not conform tank when used for the transportation requirements part 178 to the of of this sub of a chapter. specific hazardous material. These N77 For materials of not more than two requirements must be met in addition percent active ingredients by weight, pack to the design and construction speci agings need not conform to the require fications in part 178 of this subchapter. ments of part 178 of this subchapter, if Iiq Portable tank instructions TI through 327 § 172.102 49 CFR Ch. I (10—1—10 Edition)
T22 specify the applicable minimum hydrostatic testing required by § 180.605 test pressure, the minimum shell of this subchapter must be conducted. thickness (in reference steel), bottom Column 3 specifies the section ref opening requirements and pressure re erence for minimum shell thickness or, lief requirements. Liquefied com alternatively, the minimum shell pressed gases are assigned to portable thickness value. Column 4 specifies the tank instruction T50. Refrigerated liq applicability of § 178.275(g)(3) of this uefied gases that are authorized to be subchapter for the pressure relief de transported in portable tanks are spec vices. When the word “Normal” is indi ified in tank instruction T75. cated, § 178.275(g)(3) of this subchapter (ii) The following table specifies the does not apply. Column 5 references the portable tank requirements applicable applicable requirements for bottom to ‘T” Codes TI through T22. Column 1 openings in part 178 of this subchapter specifies the “T” Code. Column 2 speci or references “Prohibited” which fies the minimum test pressure, in bar means bottom openings are prohibited. (1 bar = 14.5 psig), at which the periodic The table follows: TABLE OF PORTABLE TANK T CODES T1—T22 [Portable tank codes T1—T22 apply to liquid and solid hazardous materials of Classes 3 through 9 which are transported in portable tanks.l
MinErnurn test Minimum hll thickness Portable tank Pressure-relief requirements B opening ins wc On (bar) (See 178.274(d)) § (s)) § (4) (See § 1 78.275(d)) (2) (3) (5)
TI 1.5 §178.274(d)(2) Normal §178.275(d)(2) T2 1.5 §178.274(d)(2) Normal §178.275(d)(3) T3 2.65 §178.274(d)(2) Normal §178.275(d)(2) T4 2.65 §178.274(d)(2) Normal §178.275(d)(3) T5 2.65 §178.274(d)(2) §178.275(g))3) Prohibited T6 4 §178.274(d)(2) Normal §178.275(d)(2) Ti’ 4 §178.274(d)(2) Normal §178.275(d)(3) T8 4 §178.274(d))2) Normal Prohibited T9 4 6 mm Normal Prohibited T10 4 6mm §178.275(g)(3) Prohibited TIl 6 §178.274(d)(2) Normal §178.275(d)(3) T12 6 §178.274(d)(2) §178.275(g)(3) §178.275(d)(3) T13 6 6 mm Normal Prohibited T14 6 6 mm § 178.275(g)(3) Prohibited T15 10 §178.274(d)(2) Normal §178.275(d)(3) T16 10 §178.274(d)(2) §178.275(g)(3) §178.275(d)(3) T17 10 6mm Normal §178.275(d)(3) T18 10 6mm §178.275(g)(3) §178.275(d)(3) T19 10 6mm §178.275(g)(3) Prohibited T20 10 8 mm § 178.275(g)(3) Prohibited T21 10 10 mm Normal Prohibited T22 10 10mm §178.275(g)(3) Prohibited
(iii) T50. When portable tank instruc tank instruction is specified by a “T” tion T50 is referenced in Column (7) of Code in Column (7) of the §172.101 Table the § 172.101 Table, the applicable lique for a specific hazardous material, a fied compressed gases are authorized to specification portable tank conforming be transported in portable tanks in ac to an alternative tank instruction may cordance with the requirements of be used if: § 173.313 of this subchapter. (A) The alternative portable tank has (iv) T75. When portable tank instruc a higher or equivalent test pressure tion T75 is referenced in Column (7) of (for example, 4 bar when 2.65 bar is the §172.101 Table, the applicable re specified); frigerated liquefied gases are author (B) The alternative portable tank has ized to be transported in portable greater or equivalent wall thickness tanks in accordance with the require (for example, 10 mm when 6 mm is ments of178.277 of this subchapter. specified); (v) UN and IMportable tank codes/spe (C) The alternative portable tank has cial provisions. When a specific portable a pressure relief device as specified in 328 Pipeline and Hazardous Materials Safety Admin., DOT § 172.102 the T’ Code. If a frangible disc is re TP2 a. The maximum degree of filling quired in series with the reclosing pres must not exceed the degree of filling deter sure relief device for the specified port mined by the following: able tank, the alternative portable tank must be fitted with a frangible disc in series with the reclosing pres Degree of filling = sure relief device; and l+a(tr—tf) (D) With regard to bottom openings— Where: (1) When two effective means are t, is the maximum mean bulk temperature specified, the alternative portable tank during transport, is fitted with bottom openings having t is the temperature in degrees celsius of the two or three effective means of closure liquid during filling, and a is the mean coefficient of cubical expan or no bottom openings; or sion of the liquid between the mean tem ( When three effective means are perature of the liquid during filling (ti and specified, the portable tank has no bot the maximum mean bulk temperature dur tom openings or three effective means ing transportation (t,) both in degrees cel of closure; or sius. (. When no bottom openings are au b. For liquids transported under ambient thorized, the alternative portable tank conditions a may be calculated using the for must not have bottom openings. mula: (vi) Except when an organic peroxide = d15 — d50 is authorized under § 173.225(g), if a haz ardous material is not assigned a port 35 d able tank “T” Code, the hazardous ma Where: terial may not be transported in a d15 and d50 are the densities (in units of mass portable tank unless approved by the per unit volume) of the liquid at 15 °C (59 Associate Administrator. °F) and 50 °C (122 °F), respectively. (8) “TP” codes. (i) These provisions TP3 The maximum degree of filling (in %) apply to the transportation of haz for solids transported above their melting ardous materials in TM and UN Speci points and for elevated temperature liquids fication portable tanks. Portable tank shall be determined by the following: special provisions are assigned to cer tain hazardous materials to specify re = 95L quirements that are in addition to Degree of filling those provided by the portable tank in structions or the requirements in part Where: df and d,. are the mean densities of the 178 of this subchapter. Portable tank liquid at the mean temperature of the liquid special provisions are designated with during filling and the maximum mean bulk the abbreviation TP (tank provision) temperature during transport respectively. and are assigned to specific hazardous TP4 The maximum degree of filling for portable tanks must not materials in Column (7) of the 172.101 exceed 90%. § TP5 For a portable tank used for the Table. transport of flammable refrigerated liquefied (ii) The following is a list of the port gases or refrigerated liquefied oxygen, the able tank special provisions: maximum rate at which the portable tank may be filled must not exceed the liquid flow Code/Special Provisions capacity of the primary pressure relief sys TP1 The maximum degree of filling must tem rated at a pressure not exceeding 120 not exceed the degree of filling determined percent of the portable tank’s design pres by the following: sure. For portable tanks used for the trans port of refrigerated liquefied helium and re frigerated liquefied atmospheric gas (except oxygen), the maximum rate at which the Degree of filling = tank is filled must not exceed the liquid flow l+fY(trtf) capacity of the pressure relief device rated at 130 percent of the portable tank’s design Where: pressure. Except for a portable tank con tr is the maximum mean bulk temperature taining refrigerated liquefied helium, a port during transport, and t1 is the temperature able tank shall have an outage of at least in degrees celsius of the liquid during fill two percent below the inlet of the pressure ing. relief device or pressure control valve, under
329 § 172.102 49 CFR Ch. 1(10—1—10 Edition)
conditions of incipient opening, with the TP2O This hazardous material must only portable tank in a level attitude. No outage be transported in insulated tanks under a ni is required for helium. trogen blanket. TP6 The tank must be equipped with a TP21 The wall thickness must not be less pressure release device which prevent a tank than 8 mm. Portable tanks must be hydrau from bursting under fire engulfment condi lically tested and internally inspected at in tions (the conditions prescribed in CGA pam tervals not exceeding 2.5 years. phlet S—l.2 (see §171.7 of this subchapter) or TP22 Lubricants for portable tank fit alternative conditions approved by the Asso tings (for example, gaskets, shut-off valves. ciate Administrator may be used to consider flanges) must be oxygen compatible. the fire engulfment condition), taking into TP24 The portable tank may be fitted account the properties of the hazardous ma with a device to prevent the build up of ex terial to be transported. cess pressure due to the slow decomposition TP7 The vapor space must be purged of of the hazardous material being transported. air by nitrogen or other means. The device must be in the vapor space when TP8 A portable tank having a minimum the tank is filled under maximum filling test pressure of 1.5 bar (150 kPa) may be used conditions. This device must also prevent an when the flash point of the hazardous mate unacceptable amount of leakage of liquid in rial transported is greater than 0 °C (32 °F). the case of overturning. TP9 A hazardous material assigned to TP25 Sulphur trioxide 99.95% pure and special provision TP9 in Column (7) of the above may be transported in tanks without §172.101 Table may only be transported in a an inhibitor provided that it portable tank if approved by the Associate is maintained Administrator. at a temperature equal to or above 32.5 °C (90.5 CF). TPIO The portable tank must be fitted with a lead lining at least 5 mm (0.2 inches) TP26 The heating device must be exterior thick. The lead lining must be tested annu to the shell. For UN 3176, this requirement ally to ensure that it is intact and func only applies when the hazardous material re tional. Another suitable lining material may acts dangerously with water. be used if approved by the Associate Admin TP27 A portable tank having a minimum istrator. test pressure of 4 bar (400 kPa) may be used TPI2 This material is considered highly provided the calculated test pressure is 4 bar corrosive to steel. or less based on the MAWP of the hazardous TP13 Self-contained breathing apparatus material, as defined in § 178.275 of this sub must be provided when this hazardous mate chapter, where the test pressure is 1.5 times rial is transported by sea. the N4AWP. TPI6 The portable tank must be pro TP28 A portable tank having a minimum tected against over and tinder pressurization test pressure of 2.65 bar (265 kPa) may be which may be experienced during transpor used provided the calculated test pressure is tation. The means of protection must be ap 2.65 bar or less based on the MAWP of the proved by the approval agency designated to hazardous material, as defined in § 178.275 of approve the portable tank in accordance this subchapter, where the test pressure is with the procedures in part 107, subpart F, of 1.5 times the MAWP. this subchapter. The pressure relief device TP29 A portable tank having a minimum must be preceded by a frangible disk in ac test pressure of 1.5 bar (150.0 kPa) may be cordance with the requirements in used provided the calculated test pressure is § l78.275(g)(3) of this subchapter to prevent 1.5 bar or less based on the MAWP of the haz crystallization of the product in the pressure ardous materials, as defined in § 178.275 of relief device. this subchapter, where the test pressure is TP17 Only inorganic non-combustible ma 1.5 times the MAWP. terials may be used for thermal insulation of TP3O This hazardous material may only the tank. be transported in insulated tanks. TP18 The temperature of this material TP31 This hazardous material may only must be maintained between 18 C (64.4 °F) be transported in tanks in the solid state. and 40 °C (104 F) while in transportation. TP32 Portable tanks may be used subject Portable tanks containing solidified meth to the following conditions: acrylic acid must not be reheated during a. Each portable tank constructed of metal transportation. must be fitted with a pressure-relief device TPI9 The calculated wall thickness must consisting of a reclosing spring loaded type, be increased by 3 mm at the time of con a frangible disc or a fusible element. The set struction. Wall thickness must be verified to discharge for the spring loaded pressure ultrasonically at intervals midway between relief device and the burst pressure for the periodic hydraulic tests (every 2.5 years). frangible disc, as applicable, must not be The portable tank must not be used if the greater than 2.65 bar for portable tanks with wall thickness is less than that prescribed by minimum test pressures greater than 4 bar: the applicable T code in Column (7) of the b. The suitability for transport in tanks Table for this material. must be demonstrated using test 8(d) in Test 330 Pipeline and Hazardous Materials Safety Admin., DOT § 172.200
Series 8 (See UN Manual of Tests and Cr1- least equal to 1.5 times the vapor pressure of teria, Part 1, Sub-section 187) (IBR, see the hazardous material at 46 °C (115 °F). §171.7 of this subchapter) or an alternative TP45 Each portable tank must be made of means approved by the Associate Adminis stainless steel, except that steel other than trator. stainless steel may be used in accordance TP33 The portable tank instruction as with the provisions of 173.24b(b) of this sub signed for this substance applies for granular chapter. Thickness of stainless steel for port and powdered solids and for solids which are able tank shells and heads must be the great filled and discharged at temperatures above er of 6.35 mm (0.250 inch) or the thickness re their melting point which are cooled and quired for a portable tank with a design pres transported as a solid mass. Solid substances sure at least equal to 1.3 times the vapor transported or offered for transport above pressure of the hazardous material at 46 °C their melting point are authorized for trans (115 °F). portation in portable tanks conforming to TP46 Portable tanks in sodium metal the provisions of portable tank instruction service are not required to be T4 for solid substances of packing group III hydrostatically retested. or T7 for solid substances of packing group II, unless a tank with more stringent re (9) ‘W” codes. These provisions apply quirements for minimum shell thickness, only to transportation by water: maximum allowable working pressure, pres sure-relief devices or bottom outlets are as Code/Special Provisions signed in which case the more stringent tank W7 Vessel category instruction and special provisions shall stowage for uranyl ni trate hexahydrate solution apply. Filling limits must be in accordance is “D” as de fined in §172.101(k) with portable tank special provision TP3. (4). Solids meeting the definition of an elevated W8 Vessel stowage category for pyrophoric temperature material must be transported in thorium metal or pyrophoric uranium accordance with the applicable requirements metal is ‘‘D’’ as defined in §172.101(k) (4). of this subchapter. W9 When offered for transportation by TP37 IM portable tanks are only author water, the following Specification pack ized for the shipment of hydrogen peroxide agings are not authorized unless approved solutions in water containing 72% or less hy by the Associate Administrator: woven drogen peroxide by weight. Pressure relief plastic bags, plastic film bags, textile bags, devices shall be designed to prevent the paper bags. IBCs and bulk packagings. entry of foreign matter, the leakage of liquid W41 When offered for transportation by and the development of any dangerous excess water, this material must be packaged in pressure. In addition, the portable tank must bales and be securely and tightly bound be designed so that internal surfaces may be with rope, wire or similar means. effectively cleaned and passivated. Each [Amdt. 172—123, 55 FR 52582, Dec. 21, 1990] tank must be equipped with pressure relief devices conforming to the following require EDtT0RIAL NOTE: For FEDERAL REGtSTER ci ments: tations affecting §172.102, see the List of CFR Sections Affected which appears in the Find Concentration of hydrogen per peroxide solution Total’ ing Aids section of the printed volume and on GPO Access. 52%orless 11 Over 52%, but not greater than 60% 22 Over 60%, but not greater than 72% 32 Subpart C—Shipping Papers ‘Total venting capacity in standard cubic feet hour (S.C.F.H.) per pound of hydrogen peroxide solution. § 172.200 Applicability. TP38 Each portable tank must be insu (a) Description of hazardous materials lated with an insulating material so that the required. Except as otherwise provided overall thermal conductance at 15.5 °C (60 °F) in this subpart, each person who offers is no more than 1.5333 kilojoules per hour per square meter per degree Celsius (0.075 Btu a hazardous material for transpor per hour per square foot per degree Fahr tation shall describe the hazardous ma enheit) temperature differential. Insulating terial on the shipping paper in the materials may not promote corrosion to manner required by this subpart. steel when wet. (b) This subpart does not apply to TP44 Each portable tank must be made of any material, other than a hazardous stainless steel, except that steel other than substance, hazardous waste or marine stainless steel may be used in accordance pollutant, that is— with the provisions of § 173.24b(b) of this sub chapter. Thickness of stainless steel for tank (1) Identified by the letter “A” in col shell and heads must be the greater of 7.62 umn 1 of the § 172.101 table, except mm (0.300 inch) or the thickness required for when the material is offered or in a portable tank with a design pressure at tended for transportation by air; or
331 § 172.201 49 CFR Ch. 1(10—1—10 Edition)
(2) Identified by the letter ‘W’ in (4) A shipping paper may contain ad column 1 of the §172.101 table, except ditional information concerning the when the material is offered or in material provided the information is tended for transportation by water: or not inconsistent with the required de (3) An ORM-D, except when the mate scription. Unless otherwise permitted rial is offered or intended for transpor or required by this subpart, additional tation by air. information must be placed after the (4) Category B infectious substances basic description required by prepared in accordance with § 173.199. § 172.202(a). (b) [Reserved] [Amdt. 172—29A. 41 FR 40677, Sept. 20, 1976, as amended by Amdt. 172-58, 45 FR 34697, May (c) Continuation page. A shipping 22, 1980; Amdt. 172—74, 47 FR 43065, Sept. 30, paper may consist of more than one 1982; Amdt. 172—112. 53 FR 17160, May 13, 1988; page, if each page is consecutively Amdt. 172—127, 57 FR 52938, Nov. 5, 1992; 71 FR numbered and the first page bears a no 32258, June 2, 2006] tation specifying the total number of pages included in the shipping paper. § 172.201 Preparation and retention of For example, “Page 1 of 4 pages.” shipping papers. (d) Emergency response telephone num (a) Contents. When a description of ber. Except as provided in §172.604(c), a hazardous material is required to be in shipping paper must contain an emer cluded on a shipping paper, that de gency response telephone number and, scription must conform to the fol if utilizing an emergency response in lowing requirements: formation telephone number service (1) When a hazardous material and a provider, identify the person (by name material not subject to the require or contract number) who has a contrac ments of this subchapter are described tual agreement with the service pro on the same shipping paper, the haz vider, as prescribed in subpart G of this ardous material description entries re part. quired by §172.202 and those additional (e) Retention and Recordkeeping. Each entries that may be required by person who provides a shipping paper § 172.203: must retain a copy of the shipping (1) Must be entered first, or paper required by §172.200(a), or an (ii) Must be entered in a color that electronic image thereof, that is acces clearly contrasts with any description sible at or through its principal place on the shipping paper of a material not of business and must make the ship subject to the requirements of this sub ping paper available, upon request, to chapter, except that a description on a an authorized official of a Federal, reproduction of a shipping paper may State, or local government agency at be highlighted, rather than printed, in reasonable times and locations. For a a contrasting color (the provisions of hazardous waste, the shipping paper this paragraph apply only to the basic copy must be retained for three years description required by § 172.202(a) (1), after the material is accepted by the (2), (3), and (4)), or initial carrier. For all other hazardous (iii) Must be identified by the entry materials, the shipping paper must be of an ‘X” placed before the basic ship retained for two years after the mate ping description required by § 172.202 in rial is accepted by the initial carrier. a column captioned “HM.” (The “X” Each shipping paper copy must include may be replaced by “RQ,” if appro the date of acceptance by the initial priate.) carrier, except that, for rail, vessel, or (2) The required shipping description air shipments, the date on the ship on a shipping paper and all copies ment waybill, airbill, or bill of lading thereof used for transportation pur may be used in place of the date of ac poses, must be legible and printed ceptance by the initial carrier. A (manually or mechanically) in English. motor carrier (as defined in §390.5 of (3) Unless it is specifically authorized subchapter B of chapter III of subtitle or required in this subchapter, the re B) using a shipping paper without quired shipping description may not change for multiple shipments of one contain any code or abbreviation. or more hazardous materials having
332 Pipeline and Hazardous Materials Safety Admin., DOT § 172.202 the same shipping name and identifica signed a packing group (e.g., Class 7) tion number may retain a single copy are excepted from this requirement. of the shipping paper, instead of a copy The packing group may be preceded by for each shipment made, if the carrier the letters “PC” (for example, “PG also retains a record of each shipment II”); and made, to include shipping name, identi (5) Except for transportation by air fication number, quantity transported, craft, the total quantity of hazardous and date of shipment. materials covered by the description [Amdt. 172—29A, 41 FR 40677, Sept. 20, 1976] must be indicated (by mass or volume, or by activity for Class 7 materials) EDITORIAL NOTE: For FEDERAL REGISTER ci tations affecting §172.201, see the List of CFR and must include an indication of the Sections Affected which appears in the Find applicable unit of measurement, for ex ing Aids section of the printed volume and ample, “200 kg” (440 pounds) or “50 L” on GPO Access. (13 gallons). The following provisions also apply: § 172.202 Description of hazardous ma (i) For Class 1 materials, the quan terial on shipping papers. tity must be the net explosive mass. (a) The shipping description of a haz For an explosive that is an article, ardous material on the shipping paper such as Cartridges, small arms, the net must include: explosive mass may be expressed in (1) The identification number pre terms of the net mass of either the ar scribed for the material as shown in ticle or the explosive materials con Column (4) of the § 172.101 table; tained in the article. (2) The proper shipping name pre (ii) For hazardous materials in sal scribed for the material in Column (2) vage packaging, an estimate of the of the §172.101 table; total quantity is acceptable. (3) The hazard class or division num (iii) The following are excepted from prescribed ber for the material, as the requirements of paragraph (a) (5) of shown in Column (3) of the §172.101 this section: table. The subsidiary hazard class or (A) Bulk packages, provided some in division number is not required to be dication of the total quantity is shown, entered when a corresponding sub for example, “1 cargo tank” or “2 sidiary hazard label is not required. Ex IBCs.” cept for combustible liquids, the sub sidiary hazard class(es) or subsidiary (B) Cylinders, provided some indica division number(s) must be entered in tion of the total quantity is shown, for parentheses immediately following the example, “10 cylinders.” primary hazard class or division num (C) Packages containing only residue. ber. In addition— (6) For transportation by aircraft, (i) The words ‘Class” or “Division” the total net mass per package, must may be included preceding the primary be shown unless a gross mass is indi and subsidiary hazard class or division cated in Columns (9A) or (9B) of the numbers. § 172.101 table in which case the total (ii) The hazard class need not be in gross mass per package must be shown; cluded for the entry “Combustible liq or, for Class 7 materials, the quantity uid, n.o.s.” of radioactive material must be shown (iii) For domestic shipments, pri by activity. The following provisions mary and subsidiary hazard class or di also apply: vision names may be entered following (i) For empty uncleaned packaging, the numerical hazard class or division, only the number and type of packaging or following the basic description. must be shown; (4) The packing group in Roman nu (ii) For chemical kits and first aid merals, as designated for the hazardous kits, the total net mass of hazardous material in Column (5) of the §172.101 materials must be shown. Where the table. Class 1 (explosives) materials; kits contain only liquids, or solids and self-reactive substances; batteries liquids, the net mass of liquids within other than those containing lithium, the kits is to be calculated on a 1 to 1 lithium ions, or sodium; Division 5.2 basis, i.e., 1 L (0.3 gallons) equals 1 kg materials; and entries that are not as- (2.2 pounds); 333 § 172.203 49 CFR Ch. 1(10—1—10 Edition)
(iii) For dangerous goods in machin constituent may also be used. For ex ery or apparatus, the individual total ample: “Flammable liquids, n.o.s. (con quantities or an estimate of the indi tains Xylene and Benzene), 3, UN 1993, vidual total quantities of dangerous II’,. goods in solid, liquid or gaseous state, (e) Except for those materials in the contained in the article must be shown; UN Recommendations, the ICAO Tech (iv) For dangerous goods transported nical Instructions, or the IMDG Code in salvage a packaging, an estimate of (IBR, see §171.7 of this subchapter), a the quantity of dangerous goods per material that is not a hazardous mate package must be shown; rial according to this subchapter may (v) For cylinders, total quantity may not be offered for transportation or be indicated by the number of cyl transported when its description on a inders, for example, “10 cylinders;” shipping paper includes a hazard class (vi) For items where “No Limit” is or an identification number shown in Column (9A) or (9B) of the specified the 172.101 §172.101 table, the quantity shown must in § Table. be the net mass or volume of the mate [Amdt. 172—101, 45 FR 74665. Nov. 10, 1980, as rial. For articles (e.g., UN2800 and amended by Amdt. 172-103, 51 FR 5970, Feb. UN3166) the quantity must be the gross 18. 1986: Amdt. 172—123, 55 FR 52589, Dec. 21, mass, followed by the letter “G”; and 1990: 56 FR 66252, Dec. 20, 1991; Amdt. 172—127, (7) The number and type of packages 57 FR 52938, Nov. 5, 1992; Amdt. 172—130, 58 FR must be indicated. The type of pack 51531, Oct. 1, 1993: 66 FR 33425, June 21, 2001: ages must be indicated by description 68 FR 45030, July 31, 2003; 68 FR 75741, Dec. 31, 2003: 69 FR 34611, June 22, 2004; FR 54046, of the package (for example, 69 “12 Sept. 7, 2004; 69 FR 76153, Dec. 20, 2004: 70 FR drums”). Indication of the packaging 34397, June 14, 2005; 71 FR 78626, Dec 29, 200672 specification number (“lHl”) may be FR 55692, Oct. 1, 2007: 73 FR 57005, Oct. 1, 2008; included in the description of the pack 74 FR 2252. Jan. 14, 2009: 75 FR 72, Jan. 4, 2010 age (for example, “12 IH1 drums” or “12 drums (UN lAl)”). Abbreviations may § 172.203 Additional description re be used for indicating packaging types quirements. (for example, “cyl.” for “cylinder”) (a) Special permits. Except as provided provided the abbreviations are com in § 173.23 of this subchapter, each ship monly accepted and recognizable. ping paper issued in connection with a (b) Except as provided in this sub shipment made under a special permit part, the basic description specified in must bear the notation “DOT-SP” fol paragraphs (a) (1), (2), (3) and (4) of this lowed by the special permit number as section must be shown in sequence signed and located so that the notation with no additional information inter is clearly associated with the descrip spersed. For example, “UN2744, tion to which the special permit ap Cyclobutyl chloroformate, 6.1, (8, 3), PG II.” plies. Each shipping paper issued in connection with a shipment (c) The total quantity of the material made under covered by one description must appear an exemption or special permit issued prior before or after, or both before and to October 1, 2007, may after, the description required and au bear the notation “DOT-E” followed by thorized by this subpart. The type of the number assigned and so located packaging and destination marks may that the notation is clearly associated be entered in any appropriate manner with the description to which it ap before or after the basic description. plies. Abbreviations may be used to express (b) Limited quantities. The description units of measurement and types of for a material offered for transpor packagings. tation as “limited quantity,” as au (d) Technical and chemical group thorized by this subchapter, must in names may be entered in parentheses clude the words “Limited Quantity” or between the proper shipping name and “Ltd Qty” following the basic descrip hazard class or following the basic de tiorl. scription. An appropriate modifier, (c) Hazardous substances. (1) Except such as “contains” or “containing,” for Class 7 (radioactive) materials de and/or the percentage of the technical scribed in accordance with paragraph 334 Pipeline and Hazardous Materials Safety Admin., DOT § 172.203
(d) of this section, if the proper ship may be inserted in addition to the ac ping name for a material that is a haz tivity units. ardous substance does not identify the (4) The category of label applied to hazardous substance by name, the each package in the shipment. For ex name of the hazardous substance must ample: “RADIOACTIVE WHITE-I.” be entered in parentheses in associa (5) The transport index assigned to tion with the basic description. If the each package in the shipment bearing material contains two or more haz RADIOACTIVE YELLOW-Il or RADIO ardous substances, at least two haz ACTIVE YELLOW-Ill labels. ardous substances, including the two (6) For a package containing fissile with the lowest reportable quantities Class 7 (radioactive) material: (RQs), must be identified. For a haz (i) The words “Fissile Excepted” if ardous waste, the waste code (e.g., the package is excepted pursuant to DOOl), if appropriate, may be used to § 173.453 of this subchapter; or other identify the hazardous substance. wise (2) The letters “RQ” must be entered (ii) The criticality safety index for on the shipping paper either before or that package. after the basic description required by (7) For a package approved by the § 172.202 for each hazardous substance U.S. Department of Energy (DOE) or (see definition in §171.8 of this sub U.S. Nuclear Regulatory Commission chapter). For example: “RQ, UN 1098, (NRC), a notation of the package iden Allyl alcohol, 6.1, I, Toxic-inhalation tification marking as prescribed in the hazard, Zone B”; or “UN 3077, Environ applicable DOE or NRC approval (see mentally hazardous substances, solid, § 173.471 of the subchapter). n.o.s., 9, III, RQ (Adipic acid)”. (8) For an export shipment or a ship (d) Radioactive material. The descrip ment in a foreign made package, a no tion for a shipment of a Class 7 (radio tation of the package identification active) material must include the fol marking as prescribed in the applicable lowing additional entries as appro International Atomic Energy Agency priate: (IAEA) Certificate of Competent Au (1) The name of each radionuclide in thority which has been issued for the the Class 7 (radioactive) material that package (see § 173.473 of the sub is listed in § 173.435 of this subchapter. chapter). For mixtures of radionuclides, the (9) For a shipment required by this radionuclides required to be shown subchapter to be consigned as exclusive must be determined in accordance with use: § 173.433(g) of this subchapter. Abbre (i) An indication that the shipment is viations, e.g., “Mo,” are authorized. consigned as exclusive use; or (2) A description of the physical and (ii) If all the descriptions on the ship chemical form of the material, if the ping paper are consigned as exclusive material is not in special form (generic use, then the statement “Exclusive Use chemical description is acceptable for Shipment” may be entered only once chemical form). on the shipping paper in a clearly visi (3) The activity contained in each ble location. package of the shipment in terms of (10) For the shipment of a package the appropriate SI units (e.g., containing a highway route controlled Becquerels (Bq), Terabecquerels (TBq), quantity of Class 7 (radioactive) mate etc.). The activity may also be stated rials (see § 173.403 of this subchapter) in appropriate customary units (Curies the words “Highway route controlled (Ci), milliCuries (mCi), microCuries quantity” or “HRCQ” must be entered (uCi), etc.) in parentheses following the in association with the basic descrip SI units. Abbreviations are authorized. tion. Except for plutonium-239 and pluto (e) Empty packagings. (1) The descrip nium-241, the weight in grams or kilo tion on the shipping paper for a pack grams of fissile radionuclides may be aging containing the residue of a haz inserted instead of activity units. For ardous material may include the words plutonium-239 and plutonium-241, the “RESIDUE: Last Contained ** “ in weight in grams of fissile radionuclides association with the basic description 335 § 172.203 49 CFR Ch. 1(10—1—10 Edition) of the hazardous material last con ized by §173.315(a), Note 15 of this sub tained in the packaging. chapter, or (2) The description on the shipping (ii) The words “NOT FOR Q and T paper for a tank car containing the res TANKS” for grades of liquefied petro idue of a hazardous material must in leum gas other than “Noncorrosive”. clude the phrase, “RESIDUE: LAST (i) Transportation by water. Each ship * * *“ CONTAINED before the basic de ment by water must have the following scription. additional shipping paper entries: (f) Transportation by air. A statement (1) The name of the shipper. indicating that the shipment is within (2) Minimum flash point if 60 °C (140 the limitations prescribed for either °F) or below (in °C closed cup (c.c.)) in passenger and cargo aircraft or cargo association with the basic description. aircraft only must be entered on the (3) For a hazardous material con shipping paper. signed under an “n.o.s.” entry not in Transportation (g) by rail. (1) A ship cluded in the segregation groups listed ping paper prepared by a rail carrier in section 3.1.4 of the IMDG Code but for a rail car, freight container, trans belonging, in the opinion of the con port vehicle or portable tank that con signor, to one of these groups, the ap tains hazardous materials must include propriate segregation group must be the reporting mark and number when shown in association with the basic displayed on the rail car, freight con de scription (for example, tainer, transport vehicle or portable IMDG Code seg tank. regation group—i Acids). When no seg regation group is applicable, there (2) The shipping paper for each DOT- is no requirement to indicate 113 tank car containing a Division 2.1 that condi material or its residue must contain an tion. appropriate notation, such as “DOT (j) [Reserved] 113”, and the statement “Do not hump (k) Technical names for “n.o.s.” and or cut off car while in motion.” other generic descriptions. Unless other (3) When shipments of elevated tem wise excepted, if a material is de perature materials are transported scribed on a shipping paper by one of under the exception permitted in the proper shipping names identified by § 173.247(h) (3) of this subchapter, the the letter “G” in column (1) of the shipping paper must contain an appro § 172.101 Table, the technical name of priate notation, such as “Maximum op the hazardous material must be en erating speed 15 mph.”. tered in parentheses in association (h) Transportation by highway. Fol with the basic description. For example lowing the basic description for a haz “Corrosive liquid, n.o.s., (Octanoyl ardous material in a Specification MC chloride), 8, UN 1760, II”, or “Corrosive 330 or MC 331 cargo tank, there must be liquid, no.5., 8, UN 1760, II (contains entered for— Octanoyl chloride)”. The word “con (1) Anhydrous ammonia. (i) The words tains” may be used in association with “0.2 PERCENT WATER” to indicate the technical name, if appropriate. For the suitability for shipping anhydrous organic peroxides which may qualify ammonia in a cargo tank made of for more than one generic listing de quenched and tempered steel as author pending on concentration, the tech ized by § 173.315(a), Note 14 of this sub nical name must include the actual chapter, or concentration being shipped or the con (ii) The words “NOT FOR Q and T centration range for the appropriate TANKS” when the anhydrous ammonia generic listing. For example, “Organic does not contain 0.2 percent or more peroxide type B, solid, 5.2, UN 3102 water by weight. (dibenzoyl peroxide, 52—100%)” or “Or (2) Liquefied petroleum gas. (1) The ganic peroxide type E, solid, 5.2, UN word “NONCORROSIVE” or 3108 (dibenzoyl peroxide, paste, <52%)”. “NONCOR” to indicate the suitability Shipping descriptions for toxic mate for shipping “Noncorrosive” liquefied rials that meet the criteria of Division petroleum gas in a cargo tank made of 6.1, PG I or II (as specified in § 173.132(a) quenched and tempered steel as author- of this subchapter) or Division 2.3 (as
336 Pipeline and Hazardous Materials Safety Admin., DOT § 172.203 specified in § 173.115(c) of this sub ardous materials of different classes chapter) and are identified by the let meeting the definition of more than ter “G” in column (1) of the § 172.101 one hazard class) contains the name of Table, must have the technical name of the chemical element or group respon the toxic constituent entered in paren sible for the material meeting the defi theses in association with the basic de nition of one of these classes. In such scription. A material classed as Divi cases, only the technical name of the sion 6.2 and assigned identification component that is not appropriately number UN 2814 or UN 2900 that is sus identified in the n.o.s. description shall pected to contain an unknown Cat be entered in parentheses. egory A infectious substance must (1) Marine pollutants. (1) If the proper have the words “suspected Category A shipping name for a material which is infectious substance” entered in paren a marine pollutant does not identify by theses in place of the technical name name the component which makes the as part of the proper shipping descrip material a marine pollutant, the name tion. For additional technical name op of that component must appear in pa tions, see the definition for “Technical rentheses in association with the basic name” in §171.8. A technical name description. Where two or more compo should not be marked on the outer nents which make a material a marine package of a Division 6.2 material (see pollutant are present, the names of at § 172.301(b)). least two of the components most pre (1) If a hazardous material is a mix dominantly contributing to the marine ture or solution of two or more haz pollutant designation must appear in ardous materials, the technical names parentheses in association with the of at least two components most pre basic description. dominately contributing to the hazards (2) The words “Marine Pollutant” of the mixture or solution must be en shall be entered in association with the tered on the shipping paper as required basic description for a material which by paragraph (k) of this section. For is a marine pollutant. example, “Flammable liquid, corrosive, (3) Except for transportation by ves n.o.s., 3, UN 2924, II (contains Meth sel, marine pollutants subject to the anol, Potassium hydroxide)”. provisions of 49 CFR 130.11 are excepted (2) The provisions of this paragraph from the requirements of paragraph (1) do not apply— of this section if a phrase indicating (i) To a material that is a hazardous the material is an oil is placed in asso waste and described using the proper ciation with the basic description. shipping name “Hazardous waste, liq (4) Except when all or part of trans uid or solid, n.o.s.”, classed as a mis portation is by vessel, marine pollut cellaneous Class 9, provided the EPA ants in non-bulk packagings are not hazardous waste number is included on subject to the requirements of para the shipping paper in association with graphs (1) (1) and (1) (2) of this section the basic description, or provided the (see § 171.4 of this subchapter). material is described in accordance (m) Poisonous Materials. Notwith with the provisions of § 172.203(c) of this standing the hazard class to which a part. material is assigned, for materials that (ii) To a material for which the haz are poisonous by inhalation (see §171.8 ard class is to be determined by testing of this subchapter), the words “Poison- under the criteria in §l72.10l(c)(1l). Inhalation Hazard” or “Toxic-Inhala (iii) If the n,o.s. description for the tion Hazard” and the words “Zone A”, material (other than a mixture of haz “Zone B”, “Zone C”, or “Zone D” for ardous materials of different classes gases or “Zone A” or “Zone B” for liq meeting the definitions of more than uids, as appropriate, shall be entered one hazard class) contains the name of on the shipping paper immediately fol the chemical element or group which is lowing the shipping description. The primarily responsible for the material word “Poison” or “Toxic” need not be being included in the hazard class indi repeated if it otherwise appears in the cated. shipping description. (iv) If the n.o.s. description for the (n) Elevated temperature materials. If a material (which is a mixture of haz liquid material in a package meets the 337 § 172.204 49 CFR Ch. 1(10—1—10 Edition)
definition of an elevated temperature (1) “This is to certify that the above- material in §171.8 of this subchapter, named materials are properly classi and the fact that it is an elevated tem fied, described, packaged, marked and perature material is not disclosed in labeled, and are in proper condition for the proper shipping name (for example, transportation according to the appli when the words ‘Molten” or “Elevated cable regulations of the Department of temperature” are part of the proper Transportation.” shipping name), the word “HOT” must NOTE: In line one of the certification immediately precede the proper the ship words “herein-named” may be substituted ping name of the material on the ship for the words “above-named”. ping paper. (o) Organic peroxides and self-reactive (2) “I hereby declare that the con materials. The description on a shipping tents of this consignment are fully and paper for a Division 4.1 (self-reactive) accurately described above by the prop material or a Division 5.2 (organic per er shipping name, and are classified, oxide) material must include the fol packaged, marked and labelled/plac lowing additional information, as ap arded, and are in all respects in proper propriate: condition for transport according to (1) If notification or competent au applicable international and national thority approval is required, the ship governmental regulations.” ping paper must contain a statement of (b) Exceptions. (1) Except for a haz approval of the classification and con ardous waste, no certification is re ditions of transport. quired for a hazardous material offered (2) For Division 4.1 (self-reactive) and for transportation by motor vehicle Division 5.2 (organic peroxide) mate and transported: rials that require temperature control (i) In a cargo tank supplied by the during transport, the control and emer carrier, or gency temperature must be included on (ii) By the shipper as a private car the shipping paper. rier except for a hazardous material (3) The word “SAMPLE” must be in that is to be reshipped or transferred cluded in association with the basic de from one carrier to another. scription when a sample of a Division (2) No certification is required for the 4.1 (self-reactive) material (see return of an empty tank car which pre § 173.224(c) (3) of this subchapter) or Di viously contained a hazardous material vision 5.2 (organic peroxide) material and which has not been cleaned or (see § 173.225(b) (2) of this subchapter) is purged. offered for transportation. (c) Transportation by air—(l) General. Certification containing the following [Amdt. 172—29A, 41 FR 40677, Sept. 20, 1976] language may be used in place of the EDITORIAL NOTE: For FEDERAL REGISTER ci certification required by paragraph (a) tations affecting § 172.203, see the List of CFR of this section: Sections Affected which appears in the Find ing Aids section of the printed volume and I hereby certify that the contents of this on GPO Access. consignment are fully and accurately de scribed above by proper shipping name and § 172.204 Shipper’s certification. are classified, packaged, marked and labeled, and in proper condition for carriage by air (a) General. Except as provided in according to applicable national govern paragraphs (b) and (c) of this section, mental regulations. each person who offers a hazardous ma NOTE TO PARAGRAPH (c)(I): In the certifi terial for transportation shall certify cation, the word “packed” may be used in that the material is offered for trans stead of the word “packaged” until October portation in accordance with this sub 1, 2010. chapter by printing (manually or me (2) Certificate in duplicate. Each per chanically) on the shipping paper con son who offers a hazardous material to taining the required shipping descrip an aircraft operator for transportation tion the certification contained in by air shall provide two copies of the paragraph (a)(l) of this section or the certification required in this section. certification (declaration) containing (See §175.30 of this subchapter.) the language contained in paragraph (3) Additional certification require (a) (2) of this section. ments. Effective October 1, 2006, each 338 Pipeline and Hazardous Materials Safety Admin., DOT § 172.205 person who offers a hazardous material EDITORIAL NOTE: For FEDERAL REGISTER ci for transportation by air must add to tations affecting § 172.204. see the List of CFR the certification required in this sec Sections Affected which appears in the Find tion the following statement: ing Aids section of the printed volume and on GPO Access. “I declare that all of the applicable air transport requirements have been § 172.205 Hazardous waste manifest. met.” (i) Each person who offers any pack (a) No person may offer, transport, age or overpack of hazardous materials transfer, or deliver a hazardous waste for transport by air must ensure that: (waste) unless an EPA Form 8700—22 (A) The articles or substances are not and 8700—22A (when necessary) haz prohibited for transport by air (see the ardous waste manifest (manifest) is §172.101 Table); prepared in accordance with 40 CFR (B) The articles or substances are 262.20 and is signed, carried, and given properly classed, marked and labeled as required of that person by this sec and otherwise in a condition for trans tion. port as required by this subchapter; (b) The shipper (generator) shall pre (C) The articles or substances are pare the manifest in accordance with 40 packaged in accordance with all the CFR part 262. applicable air transport requirements, (c) The original copy of the manifest including appropriate types of pack must be dated by, and bear the hand aging that conform to the packing re written signature of, the person rep quirements and the “A” Special Provi resenting: sions in §172.102; inner packaging and (1) The shipper (generator) of the maximum quantity per package limits; waste at the time it is offered for the compatibility requirements (see, transportation, and for example, § 173.24 of this subchapter); (2) The initial carrier accepting the and requirements for closure for both waste for transportation. inner and outer packagings, absorbent (d) A copy of the manifest must be materials, and pressure differential in dated by, and bear the handwritten sig § 173.27 of this subchapter. Other re nature of the person representing: quirements may also apply. For exam (I) Each subsequent carrier accepting ple, single packagings may be prohib the waste for transportation, at the ited, inner packaging may need to be time of acceptance, and packed in intermediate packagings, (2) The designated facility receiving and certain materials may be required the waste, upon receipt. to be transported in packagings meet (e) A copy of the manifest bearing all ing a more stringent performance required dates and signatures must be: level. (1) Given to a person representing (ii) [Reserved] each carrier accepting the waste for (4) Radioactive material. Each person transportation, who offers any radioactive material for (2) Carried during transportation in transportation aboard a passenger-car the same manner as required by this rying aircraft shall sign (mechanically subchapter for shipping papers, or manually) a printed certificate stat (3) Given to a person representing the ing that the shipment contains radio designated facility receiving the waste, active material intended for use in, or (4) Returned to the shipper (gener incident to, research, or medical diag ator) by the carrier that transported nosis or treatment. the waste from the United States to a (d) Signature. The certifications re foreign destination with a notation of quired by paragraph (a) or (c) of this the date of departure from the United section: States, and (1) Must be legibly signed by a prin (5) Retained by the shipper (gener cipal, officer, partner, or employee of ator) and by the initial and each subse the shipper or his agent; and quent carrier for three years from the (2) May be legibly signed manually, date the waste was accepted by the ini by typewriter, or by other mechanical tial carrier. Each retained copy must means. bear all required signatures and dates [Amdt. 172—29A, 41 FR 40677, Sept. 20, 19761 up to and including those entered by 339 § 172.300 49 CFR Ch. 1(10—1—10 Edition) the next person who received the (5) Before accepting hazardous waste waste from a rail transporter, a non-rail (f) Transportation by rail. Notwith transporter must sign and date the standing the requirements of para manifest and provide a copy to the rail graphs (d) and Ce) of this section, the transporter. following requirements apply: (g) The person delivering a hazardous (1) When accepting hazardous waste waste to an initial rail carrier shall from a non-rail transporter, the initial send a copy of the manifest, dated and rail transporter must: signed by a representative of the rail (i) Sign and date the manifest ac carrier, to the person representing the knowledging acceptance of the haz designated facility. ardous waste; (h) A hazardous waste manifest re (ii) Return a signed copy of the mani quired by 40 CFR part 262, containing fest to the non-rail transporter; all of the information required by this (iii) Forward at least three copies of subpart, may be used as the shipping the manifest to: paper required by this subpart. (A) The next non-rail transporter, if (i) The shipping description for a haz any; ardous waste must be modified as re (B) The designated facility, if the quired by §172.101(c) (9). shipment is delivered to that facility by rail; or jAmdt. 172-58, 45 Fl? 34698, May 22, 1980, as amended by Amdt. 172—90, (C) The rail 49 FR 10510, Mar. last transporter des 20, 1984; 49 FR 11184, Mar. 26, 1984; Arndt. 172— ignated to handle the waste in the 248, 61 FR 28675, June 5, 1996; 70 FR 34075, United States; and June 13, 2005] (iv) Retain one copy of the manifest and rail shipping paper in accordance Subpart D—Marking with 40 CFR 263.22. (2) Rail transporters must ensure § 172.300 Applicability. that a shipping paper containing all (a) Each person the information required on the mani who offers a haz ardous fest (excluding the EPA identification material for transportation shall mark each package, numbers, generator certification and freight con tainer, and transport signatures) and, for exports, an EPA vehicle con taining the hazardous Acknowledgment of Consent accom material in the manner required this panies the hazardous waste at all by subpart. When times. Intermediate rail transporters (b) assigned the function by this are not required to sign either the subpart, each carrier that trans manifest or shipping paper. ports a hazardous material shall mark each package, (3) When delivering hazardous waste freight container, and transport to the designated facility, a rail trans vehicle containing the haz porter must: ardous material in the manner required (i) Obtain the date of delivery and by this subpart. handwritten signature of the owner or lAmdt. 172—101, 45 FR 74666, Nov. 10, 1980] operator of the designated facility on the manifest or the shipping paper (if § 172.301 General marking require the manifest has not been received by ments for non-bulk packagings. the facility); and (a) Proper shipping name and identi (ii) Retain a copy of the manifest or fication number. (1) Except as otherwise signed shipping paper in accordance provided by this subchapter, each per with 40 CFR 263.22. son who offers a hazardous material for (4) When delivering hazardous waste transportation in a non-bulk packaging to a non-rail transporter, a rail trans must mark the package with the prop porter must: er shipping name and identification (i) Obtain the date of delivery and number (preceded by ‘UN” or “NA,” as the handwritten signature of the next appropriate) for the material as shown non-rail transporter on the manifest; in the §172.101 Table. Identification and numbers are not required on pack (ii) Retain a copy of the manifest in agings that contain only ORM-D mate accordance with 40 CFR 263.22. rials or limited quantities, as defined 340 Pipeline and Hazardous Materials Safety Admin., DOT § 172.302 in § 171.8 of this subchapter, except for assigned. Packages authorized by an limited quantities marked in accord exemption issued prior to October 1, ance with the marking requirements in 2007, may be plainly and durably § 172.315. marked “DOT-P’ in lieu of “DOT-SP” (2) The proper shipping name for a followed by the number assigned as hazardous waste (as defined in §171.8 of specified in the most recent version of this subchapter) is not required to in that exemption. clude the word ‘waste” if the package (d) Consignee s or consignor s name and bears the EPA marking prescribed by address. Each person who offers for 40 CFR 262.32. transportation a hazardous material in (3) Large quantities of a single haz a non-bulk package shall mark that ardous material in non-bulk packages. A package with the name and address of transport vehicle or freight container the consignor or consignee except when containing only a single hazardous ma the package is— terial in non-bulk packages must be (I) Transported by highway only and marked, on each side and each end as will not be transferred from one motor specified in the § 172.332 or § 172.336, carrier to another; or with the identification number speci (2) Part of a carload lot, truckload fied for the hazardous material in the lot or freight container load, and the 172.101 Table, subject to the following § entire contents of the rail car, truck or provisions and limitations: freight container are shipped from one (1) Each package is marked with the consignor to one consignee. same proper shipping name and identi fication number; (e) Previously marked packagings. A (ii) The aggregate gross weight of the package which has been previously hazardous material is 4,000 kg (8,820 marked as required for the material it pounds) or more; contains and on which the marking re (Hi) All of the hazardous material is mains legible, need not be remarked. loaded at one loading facility; (For empty packagings, see §173.29 of (iv) The transport vehicle or freight this subchapter.) container contains no other material, (f) NON-ODORIZED marking on cyl hazardous or otherwise; and inders containing LPG. After September (v) The identification number mark 30, 2006, no person may offer for trans ing requirement of this paragraph (a) (3) portation or transport a specification does not apply to Class 1, Class 7, or to cylinder, except a Specification 2P or non-bulk packagings for which identi 2Q container or a Specification 39 cyl fication numbers are not required. inder, that contains an unodorized Liq (b) Technical names. In addition to the uefied petroleum gas (LPG) unless it is marking required by paragraph (a) of legibly marked NON-ODORIZED or this section, each non-bulk packaging NOT ODORIZED in letters not less containing a hazardous material sub than 6.3 mm (0.25 inches) in height near ject to the provisions of § 172.203(k) of the marked proper shipping name re this part, except for a Division 6.2 ma quired by paragraph (a) of this section. terial, must be marked with the tech [Amdt. 172—123, 55 FR 52590, Dec. 21, 1990, as nical name in parentheses in associa amended by Amdt. 172-151, 62 FR 1227, Jan. 8, tion with the proper shipping name in 1997; 62 FR 39404. July 22. 1997; 63 FR 16075, accordance with the requirements and Apr. 1, 1998; 66 FR 45182, Aug. 28, 2001; 68 FR exceptions specified for display of tech 45030. July 31. 2003; 69 FR 64471, Nov. 4, 2004; nical descriptions on shipping papers in 70 FR 73164. Dec. 9, 2005; 71 FR 32258, June 2, § 172.203(k) of this part. A technical 2006] name should not be marked on the outer package of a Division 6.2 mate § 172.302 General marking require rial. ments for bulk packagings. (c) Special permit packagings. Except (a) Identification numbers. Except as as provided in § 173.23 of this sub otherwise provided in this subpart, no chapter, the outside of each package person may offer for transportation or authorized by a special permit must be transport a hazardous material in a plainly and durably marked “DOT-SP” bulk packaging unless the packaging is followed by the special permit number marked as required by § 172.332 with the 341 § 172.303 49 CFR Ch. I (10-1—10 Edition) identification number specified for the scribed in § 172.326, 172.328, 172.330, and material in the §172.101 table— 172.331, respectively, of this subpart. (1) On each side and each end, if the (f) A bulk packaging marked prior to packaging has a capacity of 3,785 L October 1, 1991, in conformance to the (1,000 gallons) or more; regulations of this subchapter in effect (2) On two opposing sides, if the pack on September 30, 1991, need not be re aging has a capacity of less than 3,785 marked if the key words of the proper L (1,000 gallons); or shipping name are identical to those (3) For cylinders permanently in currently specified in the §172.101 stalled on a tube trailer motor vehicle, table. For example, a tank car marked on each side and each end of the motor “NITRIC OXIDE” need not be re vehicle. marked “NITRIC OXIDE, COM (b) Size of markings. Except as other PRESSED”. wise provided, markings required by (g) A rail car, freight container, this subpart on bulk packagings truck body or trailer in which the lad must— ing has been fumigated with any haz (1) Have a width of at least 6.0 mm ardous material, or is undergoing fumi (0.24 inch) and a height of at least 100 gation, must be marked as specified in mm (3.9 inches) for rail cars; § 173.9 of this subchapter. (2) Have a width of at least 4.0 mm 172-123, 52591, (0.16 inch) and a height of least 25 lAmdt. 55 FR Dec. 21, 1990, as at amended at 56 FR 66254, Dec. mm (one 20, 1991; Amdt. inch) for portable tanks with 172—150, 61 FR 50624, Sept. 26, 1996; Amdt. 172— capacities of less than 3,785 L (1,000 gal- 151. 62 FR 1228, Jan. 8, 1997; 62 FR 39398. July ions) and IBCs; and 22. 1997; 66 FR 45379, Aug. 28, 2001; 70 FR 73164, (3) Have a width of at least 6.0 mm Dec. 9, 2005; 72 FR 55692, Oct. 1, 20071 (0.24 inch) and a height of at least 50 mm (2.0 inches) for cargo tanks and § 172.303 Prohibited marking. other bulk packagings. (a) No person may offer for transpor (c) Special permit packagings. Except tation or transport a package which is as provided in § 173.23 of this sub marked with the proper shipping name, chapter, the outside of each package the identification number of a haz used under the terms of a special per ardous material or any other markings mit must be plainly and durably indicating that the material is haz marked ‘DOT—SP” followed by the spe ardous (e.g., RQ, INHALATION HAZ cial permit number assigned. Packages ARD) unless the package contains the authorized by an exemption issued identified hazardous material or its prior to October 1, 2007 may be plainly residue. and durably marked “DOT.-E” in lieu (b) This section does not apply to— of ‘DOT-SF” followed by the number (1) Transportation of a package in a assigned as specified in the most recent transport vehicle or freight container version of that exemption. if the package is not visible during (d) Each bulk packaging marked with transportation and is loaded by the a proper shipping name, common name shipper and unloaded by the shipper or or identification number as required by consignee. this subpart must remain marked when (2) Markings on it is emptied unless it is— a package which are securely covered in transportation. (1) Sufficiently cleaned of residue and (3) The marking of shipping purged of vapors to remove any poten a name tial hazard; or on a package when the name describes a material not regulated under (2) Refilled, with a material requiring this subchapter. different markings or no markings, to such an extent that any residue re [Amdt. 172-123, 55 FR 52591, Dec. 21, 1990, as maining in the packaging is no longer amended at 56 FR 66254, Dec. 20, 1991; 72 FR hazardous. 55692. Oct. 1, 20071 (e) Additional requirements for marking portable tanks, cargo tanks, § 172.304 Marking requirements. tank cars, multi-unit tank car tanks, (a) The marking required in this sub and other bulk packagings are pre part—
342 Pipeline and Hazardous Materials Safety Admin., DOT § 172.312
(1) Must be durable, in English and design must be legibly and durably printed on or affixed to the surface of a marked on the outside of the pack package or on a label, tag, or sign. aging with the international vehicle (2) Must be displayed on a back registration code of the country of ori ground of sharply contrasting color; gin of the design. The international ve (3) Must be unobscured by labels or hicle registration code for packages de attachments; and signed by a United States company or (4) Must be located away from any agency is the symbol “USA.” other marking (such as advertising) (d) Each package which conforms to that could substantially reduce its ef fectiveness. a Type B(U) or Type B(M) package de (b) [Reservedi sign must have the outside of the out ermost receptacle, which is resistant to [Amdt. 172—29, 41 FR 15996, Apr. 15, 1976, as the effects of fire and water, plainly amended Amdt. 172—29B, by 41 FR 57067, Dec marked by embossing, stamping or 30, 19761 other means resistant to the effects of § 172.306 [Reservedl fire and water with a radiation symbol that conforms to the requirements of § 172.308 Authorized abbreviations. Appendix B of this part. (a) Abbreviations may not be used in (e) Each Type B(U), Type B(M) or a proper shipping name marking except fissile material package destined for as authorized in this section. export shipment must also be marked (b) The abbreviation “ORM” may be “USA” in conjunction with the speci used in place of the words “Other Reg fication marking, or other package cer ulated Material.” tificate identification. (See §173,47l, (c) Abbreviations which appear as au 173.472, and 173.473 of this subchapter.) thorized descriptions in column 2 of the §172.101 table (e.g., “TNT” and “PCB”) [Docket No. RSPA-99-6283 (HM-230), 69 FR are authorized. 3668, Jan. 26, 20041 [Amdt. 172-123, 55 FR 52591, Dec. 21, 1990, as § 172.312 Liquid hazardous materials amended by Amdt. 172—145, 60 FR 49110, Sept. in non-bulk packagings. 21, 19951 (a) Except as provided in this section, § 172.310 Class 7 (radioactive) mate each non-bulk combination package rials. having inner packagings containing In addition to any other markings re liquid hazardous materials, single quired by this subpart, each package packaging fitted with vents, or open containing Class 7 (radioactive) mate cryogenic receptacle intended for the rials must be marked as follows: transport of refrigerated liquefied (a) Each package with a gross mass gases must be: greater than 50 kg (110 ib) must have (1) Packed with closures upward, and its gross mass including the unit of (2) Legibly marked with package ori measurement (which may be abbre entation markings that are similar to marked on viated) the outside of the the illustration shown in this para package. graph, on two opposite vertical sides of (b) Each industrial, Type A, Type the package with the arrows pointing B(U), or Type B(M) package must be in the correct legibly and durably marked on the out upright direction, The side of the packaging, in letters at arrows must be either black or red on least 13 mm (0,5 in) high, with the white or other suitable contrasting words “TYPE IP-l,” “TYPE IP-2,” background and commensurate with “TYPE IP-3,” “TYPE A,” “TYPE the size of the package. Depicting a B(U)” or “TYPE B(M),” as appropriate. rectangular border around the arrows A package which does not conform to is optional. Type IP-l, Type IP-2, Type IP-3, Type A, Type B(U) or Type B(M) require ments may not be so marked. (c) Each package which conforms to an IP-l, IP-2, IP-3 or a Type A package 343 § 172.313 49 CFR Ch. I (10—1--la Edition)
(7) Class 7 radioactive material in Type A, IP-2, IP-3, Type B(U), or Type B(M) packages. [Amdt. 172—123. 55 FR 52591, Dec. 21, 1990, as amended at 56 FR 66254, Dec. 20, 1991; 57 FR 45458, Oct. 1, 1992; 64 FR 51918, Sept. 27, 1999; 66 FR 45379, Aug. 28, 2001; 68 FR 45030, July 31, 2003; 71 FR 54395, Sept. 14, 2006; 7IFR 78627, Dec. 29, 2006]
§ 172.313 Poisonous hazardous mate rials. In addition to any other markings re quired by this subpart: (a) A material poisonous by inhala tion (see § 171.8 of this subchapter) shall be marked “Inhalation Hazard” in as sociation with the required labels or 11 placards, as appropriate, and shipping name when required. The marking Packa9e orientation must be on two opposing sides of a bulk packaging. (See §172.302(b) of this sub (b) Arrows for purposes other than part for size of markings on bulk pack indicating proper package orientation ages.) When the words “Inhalation Haz may not be displayed on a package con ard” appear on the label, as prescribed taining a liquid hazardous material. in § 172.416 and 172.429, or placard, as (c) The requirements of paragraph (a) prescribed in § 172.540 and 172.555, the of this section do not apply to— “Inhalation Hazard” marking is not re (1) A non-bulk package with inner quired on the package. packagings which are cylinders. (b) Each non-bulk plastic outer pack (2) Except when offered or intended aging used as a single or composite for transportation by aircraft, pack packaging for materials meeting the ages containing flammable liquids in definition of Division 6.1 (in § 173.132 of inner packagings of 1 L or less prepared this subchapter) shall be permanently in accordance with §173.150 (b) or (c) of marked, by embossment or other dura this subchapter. ble means, with the word “POISON” in (3) When offered or intended for letters at least 6.3 mm (0.25 inch) in transportation by aircraft, packages height. Additional text or symbols re containing flammable liquids in inner lated to hazard warning may be in packagings of 120 mL (4 fluid oz.) or cluded in the marking. The marking less prepared in accordance with shall be located within 150 mm (6 §173.150 (b) or (c) of this subchapter inches) of the closure of the packaging. when packed with sufficient absorption (c) A transport vehicle or freight con material between the inner and outer tainer containing a material poisonous packagings to completely absorb the by inhalation in non-bulk packages liquid contents. shall be marked, on each side and each (4) Liquids contained in manufac end as specified in § 172.332 or § 172.336, with the identification tured articles (e.g., alcohol or mercury number speci fied for the hazardous material in the in thermometers) which are leak-tight §172.101 table, subject to the following in all orientations. provisions and limitations: (5) A non-bulk package with hermeti (1) The material is in Hazard Zone A cally sealed inner packagings. or B; (6) Packages containing liquid infec (2) The transport vehicle or freight tious substances in primary receptacles container is loaded at one facility with not exceeding 50 mL (1.7 oz.). 1,000 kg (2,205 pounds) or more aggre gate gross weight of the material in non-bulk packages marked with the 344 Pipeline and Hazardous Materials Safety Admin., DOT § 172.317
same proper shipping name and identi the square-on-point border containing fication number; and the identification (ID) number. (3) If the transport vehicle or freight [68 FR 45030. July 31, 2003, as amended at 69 container contains more than one ma FR 76153, Dec. 20. 2004; 73 FR 4716, Jan. 28, terial meeting the provisions of this 20081 paragraph (c), it shall be marked with the identification number for one ma § 172.316 Packagings containing mate. terial, determined as follows: rials classed as ORM-D. (i) For different materials in the (a) Each non-bulk packaging con same hazard zone, with the identifica taining a material classed as ORM-D tion number of the material having the must be marked on at least one side or greatest aggregate gross weight; and end with the ORM-D designation imme (ii) For different materials in both diately following or below the proper Hazard Zones A and B, with the identi shipping name of the material. The fication number for the Hazard Zone A ORM designation must be placed with material in a rectangle that is approximately 6.3 (d) For a packaging containing a Di mm (0.25 inches) larger on each side vision 6.1 PG III material, “PG III” than the designation. The designation may be marked adjacent to the POI for ORM-D must be: SON label. (See §172.405(c).) (1) ORM-D-AIR for an ORM-D that is prepared for air shipment and packaged [Amdt. 172-123, 55 FR 52592, Dec. 21, 1990, as amended at 57 FR 46624, Oct. 9, 1992; Amdt. in accordance with the provisions of 172—151, 62 FR 1228, Jan. 8, 1997; 62 FR 39398, § 173.27 of this subchapter. 39405, July 22, 1997: 63 FR 16075, Apr. 1, 1998; (2) ORM-D for an ORM-D other than 64 FR 10776, Mar. 5, 19991 as described in paragraph (a)(l) of this section. § 172.315 Packages containing limited (b) When the ORM-D marking includ quantities. ing the proper shipping name can not Except for transportation by aircraft be affixed on the package surface, it or as otherwise provided in this sub may be on an attached tag. chapter, a package containing a lim (c) The marking ORM-D is the cer ited quantity of hazardous materials is tification by the person offering the not required to be marked with the packaging for transportation that the proper shipping name provided it is material is properly described, classed, marked with the identification (ID) packaged, marked and labeled (when number, preceded by the letters “UN” appropriate) and in proper condition or “NA,” as applicable, for the entry as for transportation according to the ap shown in the §172.101 Table, and placed plicable regulations of this subchapter. within a square-on-point border in ac This form of certification does not pre cordance with the following: clude the requirement for a certificate (a) The ID number marking must be on a shipping paper when required by durable, legible and of such a size rel subpart C of this part. ative to the package as to be readily [Amdt. 172—29, 41 FR 15996, Apr. 15, 1976, as visible. The width of line forming the amended by Amdt. 172-123, 55 FR 52592, Dec. square-on-point must be at least 2 mm 21, 1990; 56 FR 66254, Dec. 20, 19911 and the height of the ID number must be at least 6 mm. The marking must be § 172.317 KEEP AWAY FROM HEAT applied on at least one side or one end handling mark. of the outer packaging. (a) General. For transportation by (b) When two or more hazardous ma aircraft, each package containing self- terials with different ID numbers are reactive substances of Division 4.1 or contained in the package, the pack organic peroxides of Division 5.2 must aging must be marked with either indi be marked with the KEEP AWAY vidual square-on-points bearing a sin FROM HEAT handling mark specified gle ID number, or a single square-on- in this section. point large enough to include each ap (b) Location and design. The marking plicable ID number. must be a rectangle measuring at least (c) As applicable, the letters “RQ” 105 mm (4.1 inches) in height by 74 mm must be marked in association with (2.9 inches) in width. Markings with 345 § 172.320 49 CFR Ch. 1(10—1—10 Edition)
not less than half this dimension are HEAT handling mark must conform to permissible where the dimensions of the following: the package can only bear a smaller (1) Except for size, the KEEP AWAY mark. FROM HEAT handling mark must ap (c) KEEP AWAY FROM HEAT han pear as follows: dling mark. The KEEP AWAY FROM
F-—----
-- - keep away from heat
L
(2) The symbol, letters and border § 172.320 Explosive hazardous mate must be black and the background rials. white, except for the starburst which (a) Except as otherwise provided in must be red. paragraphs (b), (c), (d) and (e) of this (3) The KEEP AWAY FROM HEAT section, each package containing a handling marking required by para Class 1 material must be marked with graph (a) of this section must be dura the EX-number for each substance, ar ble, legible and displayed on a back ticle or device contained therein. ground of contrasting color. (b) Except for fireworks approved in [69 FR 76153, Dec. 20, 20041 accordance with § 173.56(j) of this sub chapter, a package of Class 1 materials
346 Pipeline and Hazardous Materials Safety Admin., DOT § 172.322 may be marked, in lieu of the EX-num does not identify by name the compo ber required by paragraph (a) of this nent which makes the material a ma section, with a national stock number rine pollutant, the name of that com issued by the Department of Defense or ponent must be marked on the package identifying information, such as a in parentheses in association with the product code required by regulations marked proper shipping name. Where for commercial explosives specified in two or more components which make a 27 CFR part 555, if the national stock material a marine pollutant are number or identifying information can present, the names of at least two of be specifically associated with the EX the components most predominantly number assigned. contributing to the marine pollutant (c) When more than five different designation must appear in parentheses Class 1 materials are packed in the in association with the marked proper same package, the package may be shipping name; and marked with only five of the EX-num (2) The MARINE POLLUTANT mark hers, national stock numbers, product shall be placed in association with the codes, or combination thereof. hazard warning labels required by sub (d) The requirements of this section part E of this part or, in the absence of do not apply if the EX-number, product any labels, in association with the code or national stock number of each marked proper shipping name. explosive item described under a proper (b) A bulk packaging that contains a shipping description is shown in asso marine pollutant must— ciation with the shipping description (1) Be with the required by §172.202(a) of this part. marked MARINE POLLUTANT Product codes and national stock num mark on at least two op bers must be traceable to the specific posing sides or two ends other than the EX-number assigned by the Associate bottom if the packaging has a capacity Administrator. of less than 3,785 L (1,000 gallons). The (e) The requirements of this section mark must be visible from the direc do not apply to the following Class 1 tion it faces. The mark may be dis materials: played in black lettering on a square (1) Those being shipped to a testing on-point configuration having the same agency in accordance with § 173.56(d) of outside dimensions as a placard; or this subchapter; (2) Be marked on each end and each (2) Those being shipped in accordance side with the MARINE POLLUTANT with § 173.56(e) of this subchapter, for mark if the packaging has a capacity the purposes of developmental testing; of 3,785 L (1,000 gallons) or more. The (3) Those which meet the require mark must be visible from the direc ments of §173.56(h) of this subchapter tion it faces. The mark may be dis and therefore are not subject to the ap played in black lettering on a square- proval process of § 173.56 of this sub on-point configuration having the same chapter; outside dimensions as a placard. (4) [Reserved]; (c) A transport vehicle or freight con (5) Those that are transported in ac tainer that contains a package subject cordance with § 173.56(c)(2) of this sub to the marking requirements of para chapter and, therefore, are covered by graph (a) or (b) of this section must be a national security classification cur marked with the MARINE POLLUT rently in effect. ANT mark. The mark must appear on [Amdt. 172—123, 56 FR 66254, Dec. 20, 1991. as each side and each end of the transport amended by Amdt. 172-139, 59 FR 67487, Dec. vehicle or freight container, and must 29, 1994; 66 FR 45379, Aug. 28, 2001; 74 FR 53188, be visible from the direction it faces. Oct. 16, 2009] This requirement may be met by the marking displayed on a freight con § 172.322 Marine pollutants. tainer or portable tank loaded on a (a) For vessel transportation of each motor vehicle or rail car. This mark non-bulk packaging that contains a may be displayed in black lettering on marine pollutant— a white square-on-point configuration (1) If the proper shipping name for a having the same outside dimensions as material which is a marine pollutant a placard.
347 § 172.323 49 CFR Ch. 1(10—1—10 Edition)
(d) The MARINE POLLUTANT mark (A) Non-bulk packages, except in the is not required— case of packages which, because of (1) On single packagings or combina their size, can only bear smaller tion packagings where each single marks; package or each inner packaging of (B) Bulk packages with a capacity of combination packagings has: less than 3,785 L (1,000 gallons); or Ci) A net quantity of 5 L (1.3 gallons) (ii) At least 250 mm (10 inches) for or less for liquids: or marks applied to all other bulk pack (ii) A net mass of 5 kg (11 pounds) or ages. less for solids (f) Exceptions. See §171.4(c). (2) On a combination packaging con taining a marine pollutant, other than lAmdt. 172—127. 57 FR 52938, Nov. 5, 1992, as a severe marine pollutant, in inner amended by Amdt. 172-136, 59 FR 38064, July 26. 1994; Amdt. 172—145. 60 FR 49110, packagings each of which contains: Sept. 21, 1995: 66 FR 45379, Aug. 28, 2001; 70 FR 56098, (i) 5 L (1.3 gallons) or less net capac Sept. 23, 2005; 74 FR 2252, Jan. 14, 20091 ity for liquids: or (ii) 5 kg (11 pounds) or less net capac § 172.323 Infectious substances. ity for solids. (a) In addition other (3) Except for transportation by ves to requirements of this subpart, after September sel, on a bulk packaging, freight con 30, 2003, a bulk packaging containing tainer or transport vehicle that bears a a regulated medical waste, as defined label or placard specified in subparts E in §173.134(a)(5) of or F of this part. this subchapter, must be marked with a BIOHAZARD (e) MARINE POLLUTANT mark. Ef mark ing conforming fective January 14, 2010 the MARINE to 29 CFR 1910.1030(g) (1) (i)— POLLUTANT mark must conform to the following: (I) On two opposing sides or two ends other (1) Except for size, the MARINE POL than the bottom if the packaging LUTANT mark must appear as follows: has a capacity of less than 3,785 L (1,000 gallons). The BIOHAZARD marking must measure at least 152.4 mm (6 inches) on each side and must be visi ble from the direction it faces. (2) On each end and each side if the packaging has a capacity of 3,785 L (1,000 gallons) or more. The BIO HAZARD marking must measure at least 152.4 mm (6 inches) on each side and must be visible from the direction it faces. (b) For a bulk packaging contained in or on a transport vehicle or freight container, if the BIOHAZARD marking on the bulk packaging is not visible, the transport vehicle or freight con Symbol (fish and tree): Black on white tainer must be marked as required by or suitable contrasting background. paragraph (a) of this section on each (2) The symbol and border must be side and each end. black and the background white, or the (c) The background color for the BlO symbol, border and background must HAZARD marking required by para be of contrasting color to the surface graph (a) of this section must be or to which the mark is to be affixed. ange and the symbol and letters must Each side of the mark must be— be black. Except for size the BlO (1) At least 100 mm (4 inches) for HAZARD marking must appear as fol marks applied to: lows:
348 Pipeline and Hazardous Materials Safety Admin., DOT § 172.324
— r — — I —
BIOHAZARD
(d) The BIOHAZARD marking re § 172.324 Hazardous substances in quired by paragraph (a) of this section non-bulk packagings. must be displayed on a background of For each non-bulk package that con contrasting color. It may be displayed tains a hazardous substance— on a plain white square-on-point con (a) Except for packages of radio figuration having the same outside di active material labeled in accordance mensions as a placard, as specified in with § 172.403, if the proper shipping §172.519(c) of this part. name of a material that is a hazardous [67 FR 53135, Aug. 14, 2002] substance does not identify the haz ardous substance by name, or if the package contains a limited quantity marked in accordance with § 172.315, 349 § 172.325 49 CFR Ch. 1(10—1—10 Edition)
the name of the hazardous substance posing sides with the word “HOT” in must be marked on the package, in pa black or white Gothic lettering on a rentheses, in association with the prop contrasting background. The marking er shipping name or the identification must be displayed on the packaging number as applicable. If the material itself or in black lettering on a plain contains two or more hazardous sub white square-on-point configuration stances, at least two hazardous sub having the same outside dimensions as stances, including the two with the a placard. (See §172.302(b) for size of lowest reportable quantities (RQs), markings on bulk packagings.) must be identified. For a hazardous (b) Bulk packagings containing mol waste, the waste code (e.g., DOOl), if ap ten aluminum or molten sulfur must be propriate, may be used to identify the marked “MOLTEN ALUMINUM” or hazardous substance. “MOLTEN SULFUR”, respectively, in (b) The letters “RQ” must be marked the same manner as prescribed in para on the package in association with the graph (a) of this section. proper shipping name or the identifica (c) If the identification number is tion number displayed in accordance displayed on a white-square-on-point with § 172.315. display configuration, as prescribed in §172.336(b), the word “HOT” may be [73 FR 4716, Jan. 28, 20081 displayed in the upper corner of the same white-square-on-point display § 172.325 Elevated temperature mate configuration. rials. The word “HOT” must be in black letters having a height of (a) Except as provided in paragraph at least 50 mm (2.0 inches). Except for (b) of this section, a bulk packaging size, these markings shall be as illus containing an elevated temperature trated for an Elevated temperature ma material must be marked on two op terial, liquid, n.o.s.:
350 Pipehne and Hazardous Materials Safety Admin., DOT § 172.326
[Amdt. 172—125, 58 FR 3348, Jan. 8, 1993, as amended by Amdt. 172—139, 59 FR 67487, Dec. 29, 1994]
§ 172.326 Portable tanks. taming a hazardous material must be marked on each side and each end as (a) Shipping name. No person may required by §172.332 with the identifica offer for transportation or transport a tion number specified for the material portable tank containing a hazardous in the § 172.101 table. material unless it is legibly marked on (2) Each person who offers a portable two opposing sides with the proper tank containing a hazardous material shipping name specified for the mate to a motor carrier, for transportation the rial in § 172.101 table. in a transport vehicle or freight con (b) Owner’s name. The name of the tainer, shall provide the motor carrier owner or of the lessee, if applicable, with the required identification num must be displayed on a portable tank bers on placards, orange panels, or the that contains a hazardous material. white square-on-point configuration, as (c) Identification numbers. (1) If the appropriate, for each side and each end identification number markings re of the transport vehicle or freight con quired by §172.302(a) are not visible, a tainer from which identification num transport vehicle or freight container bers on the portable tank are not visi used to transport a portable tank con- ble.
351 § 172.328 49 CFR Ch. I (10—1—10 Edition)
(d) NON-ODORIZED marking on port (b) Required markings: Gases. Except able tanks containing LPG. After Sep for certain nurse tanks which must be tember 30, 2006, no person may offer for marked as specified in § 173.315(m) of transportation or transport a portable this subchapter, each cargo tank trans tank containing liquefied petroleum porting a Class 2 material subject to gas (LPG) that is unodorized as author this subchapter must be marked, in let ized in § 173.315(b) (1) unless it is legibly tering no less than 50 mm (2.0 inches), marked NON-ODORIZED or NOT on each side and each end with— ODORIZED on two opposing sides near (1) The proper shipping name speci the marked proper shipping name re fied for the gas in the §172.101 table; or quired by paragraph (a) of this section, (2) An appropriate common name for or near the placards. the material (e.g., “Refrigerant Gas”). [Amdt. 172—123, 55 FR 52592, Dec. 21, 1990, as (c) QT/NQT markings. Each MC 330 amended at 56 FR 66255, Dec. 20, 1991; 69 FR and MC 331 cargo tank must be marked 64471, Nov. 4, 2004] near the specification plate, in letters no less than 50 mm (2.0 inches) in § 172.328 Cargo tanks. height, with— (a) Providing and affixing identification (I) “QT”, if the cargo tank is con numbers. Unless a cargo tank is already structed of quenched and tempered marked with the identification num steel; or bers required by this subpart, the iden (2) “NQT”, if the cargo tank is con tification numbers must be provided or structed of other than quenched and affixed as follows: tempered steel. (1) A person who offers a hazardous (d) After October 3, 2005, each on-ve material to a motor carrier for trans hicle manually-activated remote shut portation in a cargo tank shall provide off device for closure of the internal the motor carrier the identification self-closing stop valve must be identi numbers on placards or shall affix or fied by marking “Emergency Shutoff” ange panels containing the required in letters at least 0.75 inches in height, identification numbers, prior to or at in a color that contrasts with its back the time the material is offered for ground, and located in an area imme transportation. diately adjacent to the means of clo (2) A person who offers a cargo tank sure. containing a hazardous material for (e) NON-ODORIZED marking on cargo transportation shall affix the required tanks containing LPG. After September identification numbers on panels or 30, 2006, no person may offer for trans placards prior to or at the time the portation or transport a cargo tank cargo tank is offered for transpor containing liquefied petroleum gas tation. (LPG) that is unodorized as authorized (3) For a cargo tank transported on in §l73.315(b)(l) unless it is legibly or in a transport vehicle or freight con marked NON-ODORIZED or NOT tainer, if the identification number ODORIZED on two opposing sides near marking on the cargo tank required by the marked proper shipping name as § 172.302(a) would not normally be visi specified in paragraph (b) (1) of this sec ble during transportation— tion, or near the placards. (i) The transport vehicle or freight [Amdt. 172—123, 55 FR 52592, Dec. 21, 1990, container must be marked required as as amended at 56 FR 66255, Dec. 20, 1991; Amdt. by §172.332 on each side and each end 172—151, 62 FR 1228, Jan. 8, 1997; 62 FR 39045, with the identification number speci July 22, 1997; 68 FR 19277, Apr. 18, 2003; 69 FR fied for the material in the § 172.101 64471, Nov. 4, 20041 table; and (ii) When the cargo tank is perma § 172.330 Tank cars and multi-unit nently installed within an enclosed tank car tanks. cargo body of the transport vehicle or (a) Shipping name and identification freight container, the identification number. No person may offer for trans number marking required by § 172.302 (a) portation or transport a hazardous ma need only be displayed on each side and terial— end of a cargo tank that is visible when (1) In a tank car unless the following the cargo tank is accessed. conditions are met: 352 Pipeline and Hazardous Materials Safety Admin., DOT § 17Z331 (i) The tank car must be marked on ance with § 172.302(a) and 172.332 of this each side and each end as required by subpart. § 172.302 with the identification number (b) A motor vehicle or rail car used specified for the material in the to transport a multi-unit tank car §172.101 table; and tank containing a hazardous material (ii) A tank car containing any of the must be marked on each side and each following materials must be marked on end, as required by § 172.332, with the each side with the key words of the identification number specified for the proper shipping name specified for the material in the § 172.101 table. material in the §172.101 table, or with a (c) After September 30, 2006, no per common name authorized for the mate son may offer for transportation or rial in this subchapter (e.g., “Refrig transport a tank car or multi-unit erant Gas”): tank car tank containing liquefied pe Acrolein, stabilized troleum gas (LPG) that is unodorized Ammonia, anhydrous, liquefied unless it is legibly marked NON-ODOR Ammonia solutions (more than 50% ammo IZED or NOT ODORIZED on two oppos nia) ing sides near the marked proper ship Bromine or Bromine solutions ping name required by paragraphs Bromine chloride (a) (1) and (a) (2) of this section, or near Chioroprene, stabilized the placards. The NON-ODORIZED or Dispersant gas or Refrigerant gas (as defined NOT ODORIZED marking may appear in §173.115 of this subchapter) on tank car or multi-unit tank car Division 2.1 materials a Division 2.2 materials (in Class DOT 107 tank tank used for both unodorized and cars only) odorized LPG. Division 2.3 materials [Amdt. 172—123, 55 FR 52593, Dec. 21, 1990, as Formic acid amended at 56 FR 66255, Dec. 20, 1991; 57 FR Hydrocyanic acid, aqueous solutions 45458. Oct. 1, 1992; Amdt. 172—148, 61 FR 28676, Hydrofluoric acid, solution June 5, 1996; Amdt. 172—148, 61 FR 50254, Sept. Hydrogen cyanide, stabilized (less than 3% 25, 1996; 66 FR 33425, June 21, 2001; 69 FR water) 64471, Nov. 4, 2004] Hydrogen fluoride, anhydrous Hydrogen peroxide, aqueous solutions (great § 172.331 Bulk packagings other than er than 20% hydrogen peroxide) portable tanks, cargo tanks, tank Hydrogen peroxide, stabilized cars and multi-unit tank car tanks. Hydrogen peroxide and peroxyacetic acid mixtures (a) Each person who offers a haz Nitric acid (other than red fuming) ardous material to a motor carrier for Phosphorus, amorphous transportation in a bulk packaging Phosphorus, white dry or Phosphorus, white, shall provide the motor carrier with under water or Phosphorus white, in solu the required identification numbers on tion, or Phosphorus, yellow dry or Phos phorus, yellow, under water or Phosphorus, placards or plain white square-on-point yellow, in solution display configurations, as authorized, Phosphorus white, molten or shall affix orange panels containing Potassium nitrate and sodium nitrate mix the required identification numbers to tures the packaging prior to or at the time Potassium permanganate the material is offered for transpor Sulfur trioxide, stabilized tation, unless the packaging is already Sulfur trioxide, uninhibited marked with the identification number (2) In a multi-unit tank car tank, un as required by this subchapter. less the tank is marked on two oppos (b) Each person who offers a bulk ing sides, in letters and numerals no packaging containing a hazardous ma less than 50 mm (2.0 inches) high— terial for transportation shall affix to (i) With the proper shipping name the packaging the required identifica specified for the material in the tion numbers on orange panels, square § 172.101 table or with a common name on-point configurations or placards, as authorized for the material in this sub appropriate, prior to, or at the time chapter (e.g., “Refrigerant Gas”); and the packaging is offered for transpor (ii) With the identification number tation unless it is already marked with specified for the material in the identification numbers as required by §172.101 table, unless marked in accord- this subchapter. 353 § 172.332 49 CFR Ch. I (10—1—10 Edition)
(c) For a bulk packaging contained in or on a transport vehicle or freight container, if the identification number marking on the bulk packaging (e.g., an IBC) required by §172.302(a) is not visible, the transport vehicle or freight container must be marked as required by §172.332 on each side and each end with the identification number speci fied for the material in the §172.101 LiZ(c) Placards. Display of an identifica table. tion number on a hazard warning placard shall be in conformance with [Amdt. 172—123, 55 FR 52593. Dec. 21, 1994. as the following: amended by Amdt. 172-151, 62 FR 1228, Jan. 8, 1997; 62 FR 39398, July 22, 1997] (1) The identification number shall be displayed across the center area of § 172.332 Identification number mark the placard in 88 mm (3.5 inches) black ings. Alpine Gothic or Alternate Gothic No. 3 numerals (a) General. When required by on a white background 100 mm (3.9 inches) high and approxi § 172.301, § 172.302, § 172.313, § 172.326, mately 215 mm (8.5 inches) § 172.328, § 172.330, or § 172.331, identifica wide and may be tion number markings must be dis outlined with a solid or dotted line border. played on orange panels or placards as specified in this section, or on white (2) The top of the 100 mm (3.9 inches) square-on-point configurations as pre high white background shall be ap proximately scribed in § 172.336(b). 40 mm (1.6 inches) above placard (b) Orange panels. Display of an iden the horizontal center line. tification number on an orange panel (3) An identification number may be shall be in conformance with the fol displayed only on a placard cor lowing: responding to the primary hazard class (1) The orange panel must be 160 mm of the hazardous material. (6.3 inches) high by 400 mm (15.7 inches) (4) For a COMBUSTIBLE placard wide with a 15 mm (0.6 inches) black used to display an identification num outer border. The identification num ber, the entire background below the ber shall be displayed in 100 mm (3.9 white background for the identifica inches) black Helvetica Medium nu tion number must be white during merals on the orange panel. Measure transportation by rail and may be ments may vary from those specified white during transportation by high plus or minus 5 mm (0.2 inches). way. (2) The orange panel may be made of (5) The name of the hazardous mate any durable material prescribed for rial and the hazard class may be shown placards in § 172.519, and shall be of the in letters not more than 18 points high orange color specified for labels or immediately within the upper border of placards in appendix A to this part. the space on the placard bearing the identification (3) The name and hazard class of a number of the material. material may be shown in the upper (6) If an identification number is left border of the orange panel in let placed over the word(s) on a placard, ters not more than 18 points (0.25 in.) the word(s) should be substantially high. covered to maximize the effectiveness of (4) Except for size and color, the or the identification number. ange panel and identification numbers (d) Except for size and color, the dis shall be as illustrated for Liquefied pe play of an identification number on a troleum gas: placard shall be as illustrated for Ace tone:
354 Pipeline and Hazardous Materials Safety Admin., DOT § 172.336 unless it is the correct identification number for all hazardous materials of the same class in the transport vehicle or freight container on which it is dis played. (e) Except as specified in §172.338, an 1% identification number may not be dis played on an orange panel on a cargo 2% tank unless affixed to the cargo tank by the person offering the hazardous material for transportation in the it. cargo tank. (f) If a placard is required by § 172.504, an identification number may not be displayed on an orange panel unless it is displayed in proximity to the [Amdt. 172—101, 45 FR 74667, Nov. 10, 1980, as amended by Amdt. 172-81, 48 FR 28099, June placard. 20, 1983; Amdt. 172—110, 52 FR 29527, Aug. 10, (g) No person shall add any color, 1987; Amdt. 172—123, 55 FR 52593, Dec. 21, 1990; number, letter, symbol, or word other 56 FR 66255, Dec. 20, 1991; Amdt. 172—151, 62 than as specified in this subchapter, to FR 1228, Jan. 8, 1997; 65 FR 50459, Aug. 18, any identification number marking 2000; 68 FR 57632, Oct. 6, 2003] display which is required or authorized § 172.334 Identification numbers; pro by this subchapter. hibited display. [Amdt. 172—101, 45 FR 74667, Nov. 10, 1980, as (a) No person may display an identi amended by Amdt. 172-104. 51 FR 23078, June fication number on a RADIOACTIVE, 25, 1986; Amdt. 172—110, 52 FR 29528, Aug. 10, EXPLOSIVES 1.1, 1.2, 1.3, 1.4, 1.5 or 1.6, 1987; Amdt. 172—123, 55 FR 52593, Dec. 21, 1990; DANGEROUS, or subsidiary hazard 56 FR 66255, Dec. 20, 1991; Amdt. 172—127, 59 placard. FR 49133, Sept. 26, 1994] (b) No person may display an identi fication number on a placard, orange § 172.336 Identification numbers; spe panel or white square-on-point display cial provisions. configuration unless— (a) When not required or prohibited (1) The identification number is spec by this subpart, identification numbers ified for the material in § 172.101; may be displayed on a transport vehi (2) The identification number is dis cle or a freight container in the man played on the placard, orange panel or ner prescribed by this subpart. white square-on-point configuration (b) Identification numbers, when re authorized by §172.332 or §172.336(b), as quired, must be displayed on either or appropriate, and any placard used for ange panels (see §172.332(b)) or on a display of the identification number plain white square-on-point display corresponds to the hazard class of the configuration having the same outside material specified in 172.504; § dimensions placard. In addition, (3) Except as provided under §172.336 as a (c) (4) or (c) (5), the package, freight con for materials in hazard classes for tainer, or transport vehicle on which which placards are specified and identi the number is displayed contains the fication number displays are required, hazardous material associated with but for which identification numbers that identification number in § 172.101. may not be displayed on the placards (c) Except as required by authorized for the material (see §172.332(c)(4) for a combustible liquid, § 172.334(a)), identification numbers the identification number of a material must be displayed on orange panels or may be displayed only on the placards on the plain white square-on-point dis required by the tables in § 172.504. play configuration in association with (d) Except as provided in §172.336, a the required placards. An identifica placard bearing an identification num tion number displayed on a white her may not be used to meet the re square-on-point display configuration quirements of subpart F of this part is not considered to be a placard.
355 § 172.338 49 CFR Ch. I (10—1—10 Edition)
(1) The 100 mm (3.9 inch) by 215 mm ber is displayed for the liquid petro (8.5 inches) area containing the identi leum distillate fuel having the lowest fication number shall be located as pre flash point. After October 1, 2010, if a scribed by §172.332 (c)(l) and (c)(2) and cargo tank is used to transport a gaso may be outlined with a solid or dotted line and alcohol fuel blend containing line border. more than ten percent ethanol, the (2) [Reserved] identification number “3475” must also (c) Identification numbers are not re be displayed in addition to the identi quired: fication number for the liquid petro (1) On the ends of a portable tank, leum distillate fuel having the lowest cargo tank or tank car having more flash point. than one compartment if hazardous (7) On nurse tanks meeting the provi materials having different identifica sions of § 173.3 15(m) of this subchapter. tion numbers are being transported [Amdt. 172—101, 45 FR 74667, Nov. 10, 1980, as therein. In such a circumstance, the amended by Amdt. 172-74, 47 FR 40365, Sept. identification numbers on the sides of 30, 1982: Amdt. 172—109, 52 FR 13038, Apr. 20, the tank shall be displayed in the same 1987: Amdt. 172—110, 52 FR 29528, Aug. 10, 1987; sequence as the compartments con Amdt. 172—123, 55 FR 52593, Dec. 21, 1990; 56 taining the materials they identify. FR 66255, Dec. 20, 1991; 65 FR 50459, Aug. 18, (2) On a cargo tank containing only 2000; 73 FR 4716, Jan. 28, 2008] gasoline, if the cargo tank is marked § 172.338 Replacement of identification ‘Gasoline” on each side and rear in let numbers. ters no less than 50 mm (2 inches) high, If more than or is placarded in accordance with one of the identification 172.542(c). number markings on placards, orange § panels, or white (3) On a cargo tank containing only square-on-point dis play configurations that fuel oil, if the cargo tank is marked are required to be displayed are lost, damaged or “Fuel Oil” on each side and rear in let de stroyed during transportation, the car ters no less than 50 mm (2 inches) high, rier shall replace all the missing or is placarded in or accordance with damaged 172.544(c). identification numbers as § soon as practicable. However, in such a (4) For each of the different liquid pe case, the numbers may be entered by troleum distillate fuels, including gas hand on the appropriate placard, oline and gasohol, in a compartmented or ange panel or white square-on-point cargo tank or tank car, if the identi display configuration providing the fication number is displayed for the correct identification numbers are en distillate fuel having the lowest flash tered legibly using an indelible mark point. After October 1, 2010, if a com ing material. When entered by hand, partmented cargo tank or tank car the identification numbers must be lo contains such fuels together with a cated in the white display area speci gasoline and alcohol fuel blend con fied in 172.332. This section does not taining more than ten percent ethanol, § preclude required compliance with the the identification number “3475” or placarding requirements of subpart F “1987” must also be displayed as appro of this subchapter. priate in addition to the identification number for the liquid petroleum dis [Amdt. 172—1 10, 52 FR 29528, Aug. 10, 1987] tillate fuel having the lowest flash point. Subpart E—Labeling (5) For each of the different liquid pe troleum distillate fuels, including gas § 172.400 General labeling require oline and gasohol transported in a ments. cargo tank, if the identification num (a) Except as specified in § 172.400a, ber is displayed for the liquid petro each person who offers for transpor leum distillate fuel having the lowest tation or transports a hazardous mate flash point. rial in any of the following packages or (6) For each of the different liquid pe containment devices, shall label the troleum distillate fuels, including gas package or containment device with la oline and gasohol, transported in a bels specified for the material in the cargo tank, if the identification num §172.101 table and in this subpart:
356 Pipeline and Hazardous Materials Safety Admin., DOT § 1 72.400a (1) A non-bulk package; arded in accordance with subpart F of (2) A bulk packaging, other than a this part; and cargo tank, portable tank, or tank car, (5) An overpack, freight container or with a volumetric capacity of less than unit load device, of less than 18 m3 (640 18 m3 (640 cubic feet), unless placarded cubic feet), which contains a package in accordance with subpart F of this for which labels are required, unless part; placarded or marked in accordance (3) A portable tank of less than 3785 L with § 172.512 of this part. (1000 gallons) capacity, unless plac (b) Labeling is required for a haz arded in accordance with subpart F of ardous material which meets one or this part; more hazard class definitions, in ac (4) A DOT Specification 106 or 110 cordance with column 6 of the § 172.101 multi-unit tank car tank, unless plac table and the following table:
Label de sign or:ec Hazard class or division Label name erence
1.1 EXPLOSIVES 1.1 ...... 172.411 1.2 EXPLOSIVES 1.2 172.411 1.3 EXPLOSIVES 1.3 172.411 1.4 EXPLOSIVES 1.4 172.411 1.5 EXPLOSIVES 1.5 172.411 1.6 EXPLOSIVES 1.6 172.411 2.1 FLAMMABLE GAS 172.417 2.2 NONFLAMMABLE GAS 172.415 2.3 POISON GAS 172.416 3 (flammable liquid) Combustible liquid FLAMMABLE LIOUID (none) 172.419 4.1 FLAMMABLE SOLID 172.420 4.2 SPONTANEOUSLY COMBUSTIBLE 172.422 4.3 DANGEROUS WHEN WET 172.423 5.1 OXIDIZER 172.426 5.2 ORGANIC PEROXIDE 172.427 6.1 (material poisonous by inhalation (see §171.8 of POISON INHALATION HAZARD 172.429 this subchapter)). 6.1 (other than material poisonous by inhalation) POISON 172.430 6.1 (inhalation hazard, Zone A or B) POISON INHALATION HAZARD 172.429 6.1 (other than inhalation hazard, Zone A or B) POISON 172.430 6.2 INFECTIOUS SUBSTANCE1 172.432 7 (see §172.403) RADIOACTIVE WHITE-I 172.436 7 RADIOACTIVE YELLOW-Il 172.438 7 RADIOACTIVE YELLOW-Ill 172.440 7 (fissile radioactive material; see §172.402) FISSILE 172.441 7 (empty packages, see § 173.428 of this subchapter) EMPTY 172.450 8 CORROSIVE 172.442 9 CLASS 9 172.446 1 The ETIOLOGIC AGENT label specified in regulations of the Department of Health and Human Services at 42 CFR 72.3 may apply to packages of infectious substances.
[Amdt. 172—123, 55 FR 52593, Dec. 21, 1990, as amended at 56 FR 66255, Dec. 20, 1991; Amdt. 172— 151, 62 FR 1228, Jan. 8, 1997; 64 FR 10776, Mar. 5. 1999; 64 FR 51918, Sept. 27, 1999; 69 FR 3668, Jan. 26, 2004; 69 FR 64471, Nov. 4, 2004]
§ 172.400a Exceptions from labeling. (2) A package or unit of military ex plosives (including ammunition) (a) Notwithstanding the provisions of shipped by or on behalf of the DOD 172.400, a label is not required on— § when in— (1) A Dewar flask meeting the re (i) Freight containerload, carload or quirements in 173.320 of this sub § truckload shipments, if loaded and un chapter or a cylinder containing a Di loaded by the shipper or or vision 2.1, 2.2, or 2.3 material that is— DOD; (ii) Unitized break-bulk (i) Not overpacked; and or palletized shipments by cargo vessel under char (ii) Durably and legibly marked in ter to DOD if at least one required accordance with CGA C-7, Appendix A label is displayed on each unitized or (IBR; see 171.7 of this subchapter). § palletized load. 357 § 172.401 49 CFR Ch. I (10—1—10 Edition)
(3) A package containing a hazardous placard, under the conditions set forth material other than ammunition that in § 171.23(b) (11) of this subchapter. is— lAmdt. 172-123, 55 FR 52594, Dec. (1) Loaded and unloaded under the 21, 1990, as su amended by Amdt. 172-132. 58 FR 50501, pervision Sept. of DOD personnel, and 27, 1993; 172—130, 58 FR 51531, Oct. 1, 1993; (ii) Escorted by DOD personnel in a Amdt. 172—139, 59 FR 67490, Dec. 29, 1994; separate vehicle. Amdt. 172—145. 60 FR 49110, Sept. 21, 1995; 63 (4) A compressed gas cylinder perma FR 52849, Oct. 1, 1998; 64 FR 10776, Mar. 5, nently mounted in or on a transport 1999; 65 FR 58626, Sept. 29, 2000; 66 FR 44255, vehicle. Aug. 22, 2001; 68 FR 75742, Dec. 31, 2003; 69 FR 64472, Nov. 4, 2004; 72 FR 25176, May (5) A freight container, aircraft unit 3. 2007; 73 FR 4716, Jan. 28. 2008; 74 FR 2252, Jan. 14. load device or portable tank, which— 20091 (1) Is placarded in accordance with subpart F of this part, or § 172.401 Prohibited labeling. (ii) Conforms to paragraph (a)(3) or (a) Except as otherwise provided in (b)(3) ofl72.5l2. this section, no person may offer for An (6) overpack or unit load device in transportation and no carrier may or on which labels representative of transport a package bearing a label each hazardous material in the over- specified in this subpart unless: pack or unit load are device visible. (1) The package contains a material (7) A package of low specific activity that is a hazardous material, and radioactive material surface and con (2) The label represents a hazard of taminated objects, when transported the hazardous material in the package. under §173.427(a)(6)(vi) of this sub (b) No person may offer for transpor chapter. tation and no carrier may transport a (b) Certain exceptions to labeling re package bearing any marking or label quirements are provided for small which by its color, design, or shape quantities and limited quantities in ap could be confused with or conflict with plicable sections in part 173 of this sub a label prescribed by this part. chapter. (c) The restrictions in paragraphs (a) (c) Notwithstanding the provisions of and (b) of this section, do not apply to 172.402(a), a Division § 6.1 subsidiary packages labeled in conformance with: hazard label is not required on a pack (1) The UN Recommendations (IBR, age containing Class a 8 (corrosive) see § 171.7 of this subchapter); material which has a subsidiary hazard (2) The IMDG Code (IBR, see of of Division 6.1 (poisonous) if §171.7 the tox this subchapter); icity of the material is based solely on (3) The ICAO Technical Instructions the corrosive destruction of tissue (IBR, see §171.7 of this subchapter); rather than systemic poisoning. In ad (4) The TDG Regulations dition, a Division 4.1 subsidiary hazard (IBR, see 171.7 of this subchapter). label is not required on a package bear § (5) The ing a Division 4.2 label. Globally Harmonized System of Classification (d) A package containing a material and Labelling of Chemicals (GHS) (IBR, see §171.7 poisonous by inhalation (see §171.8 of of this subchapter). this subchapter) in a closed transport (d) The provisions of paragraph vehicle or freight container may be ex (a) of this cepted from the POISON INHALATION section do not apply to a pack aging bearing HAZARD or POISON GAS label or a label if that packaging is: (1) Unused or cleaned and purged of all residue; (2) Transported in a transport vehicle or freight container in such a manner that the packaging is not visible dur ing transportation; and
358 Pipeline and Hazardous Materials Safety Admin., DOT § 172.402
(3) Loaded by the shipper and un cordance with the display requirements loaded by the shipper or consignee. in this subchapter. [Amdt. 172—9, 41 FR 15996, Apr. 15, 1976, as (c) Cargo Aircraft Only label. Each per amended by Amdt. 172-75, 47 FR 44471, Oct. 7, son who offers for transportation or 1982; Amdt. 172—77, 47 FR 54822, Dec. 6, 1982; transports by aircraft a package con Amdt. 172—94, 49 FR 38134, Sept. 27, 1984; taining a hazardous material which is Amdt. 172—100, 50 FR 41521, Oct. 11, 1985; authorized on cargo aircraft only shall Amdt. 172—123, 55 FR 52594, Dec. 21, 1990; label the package with a CARGO AIR Amdt. 172—132, 58 FR 50501, Sept. 27, 1993; 66 CRAFT ONLY label FR 8647, Feb. 1, 2001; 66 FR 45379, Aug. 28, specified in 2001; 68 FR 75741, 75742, Dec. 31, 2003; 74 FR § 172.448 of this subpart. 2252, Jan. 14, 2009] (d) Class 7 (Radioactive) Materials. Ex cept as otherwise provided in this para § 172.402 Additional labeling require graph, each package containing a Class ments. 7 material that also meets the defini (a) Subsidiary hazard labels. Each tion of one or more additional hazard package containing a hazardous mate classes must be labeled as a Class 7 ma rial— terial as required by §172.403 and for (1) Shall be labeled with primary and each additional hazard. subsidiary hazard labels as specified in (1) For a package containing a Class column 6 of the § 172.101 table (unless 7 material that also meets the defini excepted in paragraph (a) (2) of this sec tion of one or more additional hazard tion); and classes, whether or not the material (2)For other than Class 1 or Class 2 satisfies § l73.4a(b) (7) of this sub materials (for subsidiary labeling re chapter, a subsidiary label is not re quirements for Class 1 or Class 2 mate quired on the package if the material rials see paragraph (e) or paragraphs (I) conforms to the remaining criteria in and (g), respectively, of this section), if § 173.4a of this subchapter. not already labeled under paragraph (2) Each package or overpack con (a)(l) of this section, shall be labeled taining fissile material, other than with subsidiary hazard labels in ac fissile-excepted material (see § 173.453 cordance with the following table: of this subchapter) must bear two FISSILE labels, affixed to opposite SUBSIDIARY HAzARD LABELS sides of the package or overpack, which Subsidiary hazard Subsidiary Hazard (Class or Division) conforms to the figure shown in level (packing §172.441; such labels, where applicable, group) 3 4.1 4.2 4.3 5.1 6.1 8 must be affixed adjacent to the labels X X X X X for radioactive materials. II X X X XX X X Ill * X X XX X X (e) Class I (explosive) Materials. In ad dition to the label specified in column X—Required for all nodes. Required for all modes, except for a material with a flash 6 of the §172.101 table, each package of point at or above 38 *C (100 F) transported by rail or high Class 1 material that also meets the way. **Reseed definition for: ***_lmpossible as subsidiary hazard. (1) Division 6.1, Packing Groups I or (b) Display of hazard class on labels. II, shall be labeled POISON or POISON The appropriate hazard class or divi INHALATION HAZARD, as appro sion number must be displayed in the priate. lower corner of a primary hazard label (2) Class 7, shall be labeled in accord and a subsidiary hazard label. A sub ance with § 172.403 of this subpart. sidiary label meeting the specifications (f) Division 2.2 materials. In addition of this section which were in effect on to the label specified in column 6 of the September 30, 2001, such as, a label §172.101 table, each package of Division without the hazard class or division 2.2 material that also meets the defini number displayed in the lower corner tion for an oxidizing gas (see § 171.8 of of the label) may continue to be used this subchapter) must be labeled OXI as a subsidiary label in domestic trans DIZER. portation by rail or highway until Oc (g) Division 2.3 materials. In addition tober 1, 2005, provided the color toler to the label specified in column 6 of the ances are maintained and are in ac § 172.101 table, each package of Division 359 § 172.403 49 CFR Ch. I (10—1—10 Edition)
2.3 material that also meets the defini (b) The proper label to affix to a tion for: package of Class 7 (radioactive) mate (1) Division 2.1, must be labeled rial is based on the radiation level at Flammable Gas; the surface of the package and the (2) Division 5.1, must be labeled Oxi transport index. The proper category of dizer; and label must be determined in accord (3) Class 8, must be labeled Corrosive. ance with paragraph (c) of this section. [Amdt. 172—123, 55 FR 52594, Dec. 21, 1990, as The label to be applied must be the amended at 56 FR 66255, Dec. 20, 1991; Amdt. highest category required for any of 172—139, 59 FR 67490, Dec. 29, 1994; Amdt. 172.- the two determining conditions for the 140, 60 FR 26805, May 18, 1995; Amdt. 172—149, package. RADIOACTIVE WHITE-I is 61 FR 27173, May 30. 1996; 62 FR 39405, July 22, 1997; 66 FR 33425, June 21, 2001; 69 FR 3668, the lowest category and RADIO Jan. 26, 2004; 74 FR 2252, Jan. 14, 20091 ACTIVE YELLOW-Ill is the highest. For example, a package with a trans § 172.403 Class 7 (radioactive) mate port index of 0.8 and a maximum sur rial. face radiation level of 0.6 millisievert (a) Unless excepted from labeling by (60 millirems) per hour must bear a § 173.421 through 173.427 of this sub RADIOACTIVE YELLOW-Ill label. chapter, each package of radioactive (c) Category of label to be applied to material must be labeled as provided in Class 7 (radioactive) materials pack this section. ages:
Transport index Maximum radiation level at any point on the external surface Label category1
92 Less than or equal to 0.005 mSv/h (0.5 WHITE-I. mrem/h).
More than 0 but not more than 1 ...... Greater than 0.005 mSv/h (0.5 mrem/h) YELLOW-li. but less than or equal to 0.5 mSv)h (50 mremih). More than 1 but not more than 10 Greater than 0.5 mSv/h (50 mrem/h) YELLOW-ill. but less than or equal to 2 mSv/h (200 mrem/h). More than 10 Greater than 2 mSv/h (200 mrern/h) YELLOW-ill (Must be shipped under but less than or equal to 10 mSv/h exclusive use provisions; see (1,000 mremTh). 173.441(b) of this subchapter). ‘Any package containing a highway route controlled quantity” (9173.403 of this subchapter) must be labelled as RADIO ACTIVE YELLOW-Ill. 2 If the measured TI is not greater than 0.05, the value may be considered to be zero.
(d) EMPTY label. See § 173.428(d) of ACTIVE label must have two of these this subchapter for EMPTY labeling re labels, affixed to opposite sides of the quirements. package. (See § 172.406(e) (3) for freight (e) FISSILE label. For packages re container label requirements). quired in §172.402 to bear a FISSILE (g) The following applicable items of label, each such label must be com information must be entered in the pleted with the criticality safety index blank spaces on the RADIOACTIVE (CSI) assigned in the NRC or DOE label by legible printing (manual or package design approval, or in the cer mechanical), using a durable weather tificate of approval for special arrange resistant means of marking: ment or the certificate of approval for (1) Contents. Except for LSA-l mate the package design issued by the Com rial, the names of the radionuclides as petent Authority for import and export taken from the listing of radionuclides shipments. For overpacks and freight in § 173.435 of this subchapter (symbols containers required in § 172.402 to bear which conform to established radiation a FISSILE label, the CSI on the label protection terminology are authorized, must be the sum of the CSIs for all of i.e., 99Mo, 60Co, etc.). For mixtures of the packages contained in the over- radionuclides, with consideration of pack or freight container. space available on the label, the radio (f) Each package required by this sec nuclides that must be shown must be tion to be labeled with a RADIO- determined in accordance with 360 Pipeline and Hazardous Materials Safety Admin., DOT § 172.405 § 173.433(g) of this subchapter. For LSA (5) The category of the Class 7 label I material, the term ‘LSA-I” may be of the overpack, and not that of any of used in place of the names of the radio the packages contained therein, must nuclides. be used in accordance with Table I of (2) Activity. The activity in the pack §172.504(e) to determine when the age must be expressed in appropriate transport vehicle must be placarded. SI units (e.g., Becquerels (Bq), (6) For fissile material, the criti Terabecquerels (TBq), etc.). The activ cality safety index which must be en ity may also be stated in appropriate tered on the overpack FISSILE label is customary units (Curies (Ci), the sum of the criticality safety indi milliCuries (mCi), microCuries (uCi), ces of the individual packages in the etc.) in parentheses following the SI overpack, as stated in the certificate of units. Abbreviations are authorized. approval for the package design issued Except for plutonium-239 and pluto by the NRC or the U.S. Competent Au nium-241, the weight in grams or kilo thority. grams of fissile radionuclides may be [Amdt. 172—29, 41 FR 15996, Apr. 15, 1976] inserted instead of activity units. For EDITORIAL NOTE: For FEDERAL REGISTER ci plutonium-239 and plutonium-241, the tations affecting § 172.403, see the List of CFR weight in grams of fissile radionuclides Sections Affected which appears in the Find may be inserted in addition to the ac ing Aids section of the printed volume and tivity units. on GPO Access. (3) Transport index. (see §173.403 of § 172.404 Labels for mixed and consoli.. this subchapter.) dated packaging. (h) When one or more packages of Class 7 (radioactive) material are (a) Mixed packaging. When hazardous placed within an overpack, the over- materials having different hazard pack must be labeled as prescribed in classes are packed within the same this section, except as follows: packaging, or within the same outside container or overpack as described in (I) The “contents” entry on the label 173.25 and authorized by 173.21 of this may state ‘mixed” in place of the § § subchapter, the packaging, outside names of the radionuclides unless each container or overpack must be labeled inside package contains the same as required for each class of hazardous radionuclide(s). material contained therein. (2) The “activity” entry on the label (b) Consolidated packaging. When two must be determined by adding together or more packages containing compat the number of becquerels of the Class 7 ible hazardous material (see § 173.21 of (radioactive) materials packages con this subchapter) are placed within the tained therein. same outside container or overpack, (3) For an overpack, the transport the outside container or overpack must index (TI) must be determined by add be labeled as required for each class of ing together the transport indices of hazardous material contained therein. the Class 7 (radioactive) materials packages contained therein, except § 172.405 Authorized label modifica. that for a rigid overpack, the transport tions. index (TI) may alternatively be deter (a) For Classes 1, 2, 3, 4, 5, 6, and 8, mined by direct measurement as pre text indicating a hazard (for example scribed in § 173.403 of this subchapter FLAMMABLE LIQUID) is not required under the definition for “transport on a primary or subsidiary label. index,” taken by the person initially (b) For a package containing Oxygen, offering the packages contained within compressed, or Oxygen, refrigerated the overpack for shipment. liquid, the OXIDIZER label specified in (4) The category of Class 7 label for § 172.426 of this subpart, modified to dis the overpack must be determined from play the word “OXYGEN” instead of the table in §172.403(c) using the TI de “OXIDIZER”, and the class number rived according to paragraph (h)(3) of “2” instead of “5.1”, may be used in this section, and the maximum radi place of the NON-FLAMMABLE GAS ation level on the surface of the over- and OXIDIZER labels. Notwithstanding pack. the provisions of paragraph (a) of this 361 § 172.406 49 CFR Ch. 1(10—1—10 Edition) section, the word ‘OXYGEN” must ap ever, duplicate labels must be dis pear on the label. played on at least two sides or two (c) For a package containing a Divi ends (other than the bottom) of— sion 6.1, Packing Group III material, (1) Each package or overpack having the POISON label specified in § 172.430 a volume of 1.8 m3 (64 cubic feet) or may be modified to display the text more; “PG III” instead of “POISON” or (2) Each non-bulk package containing “TOXIC” below the mid line of the a radioactive material; label. Also see § 172.313(d). (3) Each DOT 106 or 110 multi-unit tank car tank. Labels must [Amdt. 172—123, 55 FR 52594, Dec. 21, 1990, as be dis amended at 56 FR 66255, Dec. 20, 1991; 57 FR played on each end; 45458, Oct. 1, 1992; 64 FR 10776, Mar. 5, 1999; 66 (4) Each portable tank of less than FR 33425, June 21, 2001] 3,785 L (1000 gallons) capacity; (5) Each freight container or aircraft § 172.406 Placement of labels. unit load device having a volume of 1.8 (a) General. (I) Except as provided in m3 (64 cubic feet) or more, but less than paragraphs (b) and (e) of this section, 18 m3 (640 cubic feet). One of each re each label required by this subpart quired label must be displayed on or must— near the closure; and (i) Be printed on or affixed to a sur (6) An IBC having a volume of 1.8 m3 face (other than the bottom) of the (64 cubic feet) or more. package or containment device con (I) Visibility. A label must be clearly taining the hazardous material; and visible and may not be obscured by (ii) Be located on the same surface of markings or attachments. the package and near the proper ship [Amdt. 172—123, 55 FR 52594, Dec. 21, 1990, as ping name marking, if the package di amended at 56 FR 66255, Dec. 20, 1991; Amdt. mensions are adequate. 172—130, 58 FR 51531, Oct. 1, 1993; 73 FR 4716, (2) Except as provided in paragraph Jan. 28, 20081 (e) of this section, duplicate labeling is not required on a package or contain § 172.407 Label specifications. ment device (such as to satisfy redun (a) Durability. Each label, whether dant labeling requirements). printed on or affixed to a package, (b) Exceptions. A label may be printed must be durable and weather resistant. on or placed on a securely affixed tag, A label on a package must be able to or may be affixed by other suitable withstand, without deterioration or a means to; substantial change in color, a 30-day (1) A package that contains no radio exposure to conditions incident to active material and which has dimen transportation that reasonably could sions less than those of the required be expected to be encountered by the label; labeled package. (2) A cylinder; and (b) Design. (I) Except for size and (3) A package which has such an ir color, the printing, inner border, and regular surface that a label cannot be symbol on each label must be as shown satisfactorily affixed. in §5172.411 through 172.448 of this sub (c) Placement of multiple labels. When part, as appropriate. primary and subsidiary hazard labels (2) The dotted line border shown on are required, they must be displayed each label is not part of the label speci next to each other. Placement con fication, except when used as an alter forms to this requirement if labels are native for the solid line outer border to within 150 mm (6 inches) of one an meet the requirements of § 172.406(d) of other. this subpart. (d) Contrast with background. Each (c) Size. (1) Each diamond (square-on- label must be printed on or affixed to a point) label prescribed in this subpart background of contrasting color, or must be at least 100 mm (3.9 inches) on must have a dotted or solid line outer each side with each side having a solid border. line inner border 5.0 to 6.3 mm (0.2 to (e) Duplicate labeling. Generally, only 0.25 inches) from the edge. one of each different required label (2) The CARGO AIRCRAFT ONLY must be displayed on a package. How- label must be a rectangle measuring at 362 Pipeline and Hazardous Materials Safety Admin., DOT § 172.407 least 110 mm (4.3 inches) in height by Office of Hazardous Materials Stand 120 mm (4.7 inches) in width. The words ards, Room 8422, Nassif Building, 400 “CARGO AIRCRAFT ONLY” must be Seventh Street, SW., Washington DC shown in letters measuring at least 6.3 20590—0001. mm (0.25 inches) in height. (5) The following color standards in (3) Except as otherwise provided in the PANTONE® formula guide coated! this subpart, the hazard class number, uncoated (see §171.7(b) of this sub or division number, as appropriate, chapter) may be used to achieve the re must be at least 6.3 mm (0.25 inches) quired colors on markings and hazard and not greater than 12.7 mm (0.5 warning labels and placards: inches). (i) For Red—Use PANTONE® 186 U (4) When text indicating a hazard is (ii) For Orange—Use PANTONE® 151 displayed on a label, the label name U must be shown in letters measuring at least 7.6 mm (0.3 inches) in height. For (iii) For Yellow—Use PANTONE® 109 SPONTANEOUSLY COMBUSTIBLE or U DANGEROUS WHEN WET labels, the (iv) For Green—Use PANTONE® 335 words “Spontaneously” and “When U Wet” must be shown in letters meas (v) For Blue—Use PANTONE® 285 U uring at least 5.1 mm (0.2 inches) in (vi) For Purple—Use PANTONE® 259 height. U (5) The symbol on each label must be (6) Where specific colors from the proportionate in size to that shown in PANTONE MATCHING SYSTEM® are the appropriate section of this subpart. applied as opaque coatings, such as (d) Color. (1) The background color on paint, enamel, or plastic, or where la each label must be as prescribed in bels are printed directly on the surface § 172.411 through 172.448 of this sub of a packaging, a spectrophotometer or part, as appropriate. other instrumentation must be used to (2) The symbol, text, numbers, and ensure a proper match with the color border must be shown in black on a standards in the PANTONE® formula label except that— guide coated/uncoated for colors pre (i) White may be used on a label with scribed in paragraph (d) (5) of this sec a one color background of green, red or tion. PANTONE® is the property of blue. Pantone, Inc. (ii) White must be used for the text (7) The specified label color must ex and class number for the CORROSIVE tend to the edge of the label in the area label. designated on each label, except for the (iii) White may be used for the sym CORROSIVE, RADIOACTIVE YEL bol for the ORGANIC PEROXIDE label. LOW-Il, and RADIOACTIVE YELLOW (3) Black and any color on a label III labels on which the color must ex must be able to withstand, without tend only to the inner border. substantial change, a 72-hour fadeometer test (for a description of (e) Form identification. A label may equipment designed for this purpose, contain form identification informa see ASTM G 23—69 (1975) or ASTM G 26— tion, including the name of its maker, 70). provided that information is printed (4) (i) A color on a label, upon visual outside the solid line inner border in no examination, must fall within the color larger than 10-point type. tolerances— (I) Exceptions. Except for materials (A) Displayed on color charts con poisonous by inhalation (See §171.8 of forming to the technical specifications this subchapter), a label conforming to for charts set forth in table 1 or 2 in ap specifications in the UN Recommenda pendix A to this part; or tions may be used in place of a cor (B) For labels printed on packaging responding label that conforms to the surfaces, specified in table 3 in appen requirements of this subpart. dix A to this part. (g) Trefoil symbol. The trefoil symbol (ii) Color charts conforming to ap on the RADIOACTIVE WHITE-I, RA pendix A to this part are on display in DIOACTIVE YELLOW-Il, and RADIO Office of Hazardous Materials Safety, ACTIVE YELLOW-Ill labels must meet 363 § 172.411 49 CFR Ch. 1(10—1—10 Edition)
the appropriate specifications in ap EXPLOSIVE 1.4: pendix B of this part. [Amdt. 172—123, 55 FR 52595, Dec. 21, 1990, as amended at 56 FR 66256. Dec. 20, 1991; Amdt. 172—143, 60 FR 50305, Sept. 28, 1995; 64 FR 10776, Mar. 5, 1999; 66 FR 8647, Feb. 1, 2001; 66 FR 44255, Aug. 22, 2001; 67 FR 61013, Sept. 27, 2002; 69 FR 64472, Nov. 4, 2004; 71 FR 78627, Dec. 29, 2006; 75 FR 72, Jan. 4, 2010]
§172.411 EXPLOSIVE 1.1, 1.2, 1.3, 1.4, 1.5 and 1.6 labels, and EXPLOSIVE Subsidiary label. (a) Except for size and color, the EX PLOSIVE 1.1, EXPLOSIVE 1.2 and EX PLOSIVE 1.3 labels must be as follows:
EXPLOSIVE 1.5:
(b) In addition to complying with § 172.407, the background color on the EXPLOSIVE 1.1, EXPLOSIVE 1.2 and EXPLOSIVE 1.3 labels must be orange. The “*“ must be replaced with the ap propriate division number and compat ibility group letter. The compatibility group letter must be the same size as the division number and must be shown as a capitalized Roman letter. (c) Except for size and color, the EX PLOSIVE 1.4, EXPLOSIVE 1.5 and EX PLOSIVE 1.6 labels must be as follows:
364 Pipeline and Hazardous Materials Safety Admin., DOT § 172.415
EXPLOSIVE 1.6:
(f) The EXPLOSIVE subsidiary label must comply with § 172.407. (d) In addition to complying with [Amdt. 172—123, 56 FR 66256, Dec. 20, 1991, as §172.407, the background color on the amended by Amdt. 172-139, 59 FR 67490, Dec. 29, 66 FR 33425, June 21, 2001; EXPLOSIVE 1.4, EXPLOSIVE 1994; 68 FR 1.5 and 45031, July 31, 2003] EXPLOSIVE 1.6 label must be orange. The “*“ must be replaced with the ap § 172.415 NON-FLAMMABLE GAS propriate compatibility group. The label. compatibility group letter must be (a) Except for size and color, the shown as a capitalized Roman letter. NON-FLAMMABLE GAS label must be Division numbers must measure at as follows: least 30 mm (1.2 inches) in height and at least 5 mm (0.2 inches) in width. (e) An EXPLOSIVE subsidiary label is required for materials identified in Column (6) of the HMT as having an ex plosive subsidiary hazard. The division number or compability group letter may be displayed on the subsidiary hazard label. Except for size and color, the EXPLOSIVE subsidiary label must be as follows: GAS
(b) In addition to complying with §172.407, the background color on the NON-FLAMMABLE GAS label must be green. [Amdt. 172—123. 5666256, Dec. 20, 1991]
365 § 172.416 49 CFR Ch. 1(10—1—10 Edition)
§ 172.416 POISON GAS label. (b) In addition to complying with (a) Except for size and color, the POI §172.407, the background color on the FLAMMABLE SON GAS label must be as follows: GAS label must be red. [Amdt. 172—123, 56 FR 66257, Dec. 20, 1991]
§ 172.419 FLAMMABLE LIQUID label. (a) Except for size and color the FLAMMABLE LIQUID label must be as follows:
INHALATION “N, HAZARD
2,./
(b) In addition to complying with §172.407, the background on the POI SON GAS label and the symbol must be white. The background of the upper di amond must be black and the lower point of the upper diamond must be 14 mm (0.54 inches) above the horizontal (b) In addition to complying with center line. §172.407, the background color on the FLAMMABLE LIQUID label must be 162 FR 39405, July 22, 19971 red. § 172.417 FLAMMABLE GAS label. [Amdt. 172—123, 56 FR 66257, Dec. 20, 1991] (a) Except for size and color, the FLAMMABLE GAS label must be as § 172.420 FLAMMABLE SOLID label. follows: (a) Except for size and color, the FLAMMABLE SOLID label must be as follows:
366 Pipeline and Hazardous Materials Safety Admin., DOT § 172.427 (b) In addition to complying with § 172.407, the background on the FLAM MABLE SOLID label must be white with vertical red stripes equally spaced on each side of a red stripe placed in the center of the label. The red vertical stripes must be spaced so that, vis ually, they appear equal in width to the white spaces between them. The symbol (flame) and text (when used) must be overprinted. The text “FLAM DANGE:us WET MABLE SOLID” may be placed in a white rectangle. [Amdt. 172—123, 56 FR 66257, Dec. 20, 1991]
§ 172.422 SPONTANEOUSLY COMBUS TIBLE label. (a) Except for size and color, the (b) In addition to complying with SPONTANEOUSLY COMBUSTIBLE § 172.407, the background color on the label must be as follows: DANGEROUS WHEN WET label must be blue. [Amdt. 172—123, 56 FR 66257, Dec. 20, 1991]
§ 172.426 OXIDIZER label. (a) Except for size and color, the OXI DIZER label must be as follows:
OX ID IZ ER
(b) In addition to complying with §172.407, the background color on the lower half of the SPONTANEOUSLY COMBUSTIBLE label must be red and the upper half must be white. [Amdt. 172—123, 56 FR 66257, Dec. 20, 1991, as (b) In addition to complying with amended at 57 FR 45458, Oct. 1, 1992] § 172.407, the background color on the OXIDIZER label must be yellow. § 172.423 DANGEROUS WHEN WET label. [Amdt. 172—123, 56 FR 66257, Dec. 20. 19911 (a) Except for size and color, the § 172.427 ORGANIC PEROXIDE label. DANGEROUS WHEN WET label must (a) Except for size and color, the OR be as follows: GANIC PEROXIDE label must be as follows:
367 § 172.427 49 CFR Ch. 1(10—1—10 Edition)
ORGANIC PEROXIDE
368 Pipeline and Hazardous Materials Safety Admin., DOT § 172.432
(b) In addition to complying with § 172.430 POISON label. §172.407, the background on the OR Except GANIC PEROXIDE label must be red in (a) for size and color, the POI the top half and yellow in the lower SON label must be as follows: half. [71 FR 78627, Dec. 29, 20061
§ 172.429 POISON INHALATION HAZ ARD label. (a) Except for size and color, the POI SON INHALATION HAZARD label must be as follows:
“S....,
INHALATION (b) In addition to complying with §172.407, the background on the POI HAZARD SON label must be white. The word “TOXIC” may be used in lieu of the word “POISON”. [Amdt. 172—123, 56 FR 66258, Dec. 20, 1991, as amended by Amdt. 172-139, 59 FR 67490, Dec. 29, 1994[ (b) In addition to complying with §172.407, the background on the POI § 172.431 [Reserved] SON INHALATION HAZARD label and the symbol must be white. The back § 172.432 INFECTIOUS SUBSTANCE ground of the upper diamond must be label. black and the lower point of the upper (a) Except for size and color, the IN diamond must be 14 mm (0.54 inches) FECTIOUS SUBSTANCE label must be above the horizontal center line. as follows: [62 FR 39406, July 22. 1997[
369 § 172.436 49 CFR Ch. I (10—1—10 Edition)
iNFECTIOUS SUBSTANCE IN CASE OF DAMAGE OR LEAKAGE IMMEDIATELY NOTIFY PUBLIC HEALTH AUTHORITY IN U.S.A.
NOTIFY DIRECTOR . CDC ATLANTA, GA. i800-232-0124
(b) In addition to complying with § 172.407, the background on the INFEC TIOUS SUBSTANCE label must be white. [Amdt. 172—123, 56 FR 66258, Dec. 20, 1901, as amended at 67 FR 53136, Aug. 14. 20021
§ 172.436 RADIOACTIVE WHITE.I label. (a) Except for size and color, the RA DIOACTIVE WHITE-I label must be as follows:
370 Pipeline and Hazardous Materials Safety Admin., DOT § 172.441 (b) In addition to complying with bol must be black, except for the “II” § 172.407, the background on the RADIO which must be red. ACTIVE WHITE-I label must be white. [Amdt. 172—123, 56 FR 66259. Dec. 20, 19911 The printing and symbol must be black, except for the “I” which must be § 172.440 RAIJIOACTIVE YELLOW-Ill red. label. [Amdt. 172-123, 56 FR 66259. Dec. 20, 1991] (a) Except for size and color, the RA DIOACTIVE YELLOW-Ill label must be § 172.438 RADIOACTIVE YELLOW-Il as follows: label. (a) Except for size and color, the RA DIOACTIVE YELLOW-Il must be as follows:
çoA)
KvEII
(b) In addition to complying with §172.407, the background color on the RADIOACTIVE YELLOW-Ill label must be yellow in the top half and white in the lower half. The printing (b) In addition to complying with and symbol must be black, except for §172.407, the background color on the the “III” which must be red. RADIOACTIVE YELLOW-Il label must [Amdt. 172—123, 56 FR 66259, Dec. 20, 1991] be yellow in the top half and white in the lower half. The printing and sym § 172.44 1 FISSILE label. (a) Except for size and color, the FISSILE label must be as follows:
371 § 172.442 49 CFR Ch. 1(10—1—10 Edition)
t _ S I I 1 S S S
I S
S
S I S I
S S I
I S S S
I FISSILE S 1 S
4 S S
S S S S
S
4. S I
S
I S I I S S
S I
S S V
(b) In addition to complying with §172.407, the background color on the FISSILE label must be white. [69 FR 3669, Jan. 26, 2004]
§ 172.442 CORROSIVE label. (a) Except for size and color, the CORROSIVE label must be as follows:
‘V
372 Pipeline and Hazardous Materials Safety Admin., DOT § 172.448 (b) In addition to complying with (b) In addition to complying with §172.407, the background on the COR §172.407, the background on the CLASS ROSIVE label must be white in the top 9 label must be white with seven black half and black in the lower half. vertical stripes on the top half. The lAmdt. 172—123, 56 FR 66259, Dec. 20, 1991] black vertical stripes must be spaced, so that, visually, they appear equal in § 172.444 [Reserved] width to the six white spaces between them. The lower half of the label must CLASS § 172.446 9 label. be white with the class number “9” un (a) Except for size and color, the derlined and centered at the bottom. “CLASS 9” (miscellaneous hazardous The solid horizontal line dividing the materials) label must be as follows: lower and upper half of the label is op tional. ]Amdt. 172—123, 56 FR 66259, Dec. 20, 1991, as amended at 74 FR 2252, Jan. 14, 20091
§ 172.448 CARGO AIRCRAFT ONLY label. (a) Except for size and color, the CARGO AIRCRAFT ONLY label must be as follows:
(b) The CARGO AIRCRAFT ONLY (c) A CARGO AIRCRAFT ONLY label label must be black on an orange back conforming to the specifications in this ground. section and in §172.407(c)(2) in effect on
373 § 172.450 49 CFR Ch. I (10—1—10 Edition)
October 1, 2008, may be used until Jan provisions of § 173.4, l73.4a, 173.4b of uary 1, 2013. this subchapter; and [74 FR 2252, Jan. 14, 2009, as amended at 75 (6) Combustible liquids in non-bulk FR 72, Jan. 4, 2010] packagings.
§ 172.450 EMPTY label. [Amdt. 172—123, 55 FR 52599, Dec. 21, 1990, as amended by Amdt. 172—149, 61 FR 27173. May (a) Each EMPTY label, except for 30, 1996; 74 FR 2253, Jan. 14, 2009] size, must be as follows: § 172.502 Prohibited and permissive 6 inch’s placarding. (a) Prohibited piacarding. Except as provided in paragraph (b) of this sec tion, no person may affix or display on a packaging, freight container, unit load device, motor vehicle or rail car— (1) Any placard described in this sub part unless— (1) The material being offered or EMPTY transported is a hazardous material; (ii) The placard represents a hazard of the hazardous material being offered or transported; and (iii) Any placarding conforms to the requirements of this subpart. (2) Any sign, advertisement, slogan (such as “Drive Safely”), or device that, by its color, design, shape or con (1) Each side must be at least 6 tent, could be confused with any inches (152 mm.) with each letter at placard prescribed in this least 1 inch (25.4 mm.) in height. subpart. (2) The label must be white with (b) Exceptions. (1) The restrictions in black printing. paragraph (a) of this section do not (b) jReserved] apply to a bulk packaging, freight con tainer, unit load device, transport vehi Subpart F—Placarding cle or rail car which is placarded in conformance with TDG Regulations, § 172.500 Applicability of placarding the IMDG Code or the UN Rec requirements. ommendations (IBR, see §171.7 of this subchapter). (a) Each person who offers for trans portation or transports any hazardous (2) The restrictions of paragraph (a) material subject to this subchapter of this section do not apply to the dis shall comply with the applicable play of a BIOl-Il-IAZARD marking, a placarding requirements of this sub “HOT” marking, or an identification part. number on a white square-on-point (b) This subpart does not apply to— configuration in accordance with (1) Infectious substances; §172.323(c), 172.325(c), or 172.336(b) of (2) Hazardous materials classed as this part, respectively. ORM-D; (3) The restrictions in paragraph (3) Hazardous materials authorized (a)(2) of this section do not apply until by this subchapter to be offered for October 1, 2001 to a safety sign or safe transportation as Limited Quantities ty slogan (e.g., “Drive Safely” or when identified as such on shipping pa “Drive Carefully”), which was perma pers in accordance with § 172.203(b); nently marked on a transport vehicle, (4) Hazardous materials prepared in bulk packaging, or freight container on accordance with §173.13 of this sub or before August 21, 1997. chapter; (c) Permissive piacarding. Placards (5) Hazardous materials which are may be displayed for a hazardous mate packaged as small quantities under the rial, even when not required, if the
374 Pipeline and Hazardous Materials Safety Admin., DOT § 172.504 placarding otherwise conforms to the this section. However, when 1,000 kg requirements of this subpart. (2,205 pounds) aggregate gross weight [Amdt. 172—123, 55 FR 52599, Dec. 21, 1990, as or more of one category of material is amended at 56 FR 66259, Dec. 20, 1991; Amdt. loaded therein at one loading facility 172—151, 62 FR 1230, Jan. 8, 1997; 62 FR 39389 on a freight container, unit load de and 39407. July 22, 1997; 66 FR 8647, Feb. 1, vice, transport vehicle, or rail car, the 2001; 66 FR 33426, June 21, 2001; 67 FR 53137, placard specified in table 2 of para Aug. 14, 2002; 68 FR 75741, Dec. 31, 2003] graph (e) of this section for that cat egory § 172.503 Identification number dis must be applied. play on placards. (c) Exception for less than 454 kg (1,001 pounds). Except for bulk packagings For procedures and limitations per and hazardous materials subject taining to the display of identification to 172.505, when hazardous materials numbers on placards, see 172.334. § cov § ered by table 2 of this section are [Amdt. 172—58, 45 FR 34701, May 22, 1980] transported by highway or rail, plac ards are not required on— § 172.504 General placarding require ments. (1) A transport vehicle or freight con tainer which contains less than 454 kg (a) General. Except as otherwise pro (1001 pounds) aggregate gross weight of vided in this subchapter, each bulk hazardous materials covered by table 2 packaging, freight container, unit load of paragraph (e) of this section; or device, transport vehicle or rail car (2) A rail car loaded with transport containing any quantity of a hazardous vehicles or freight containers, none of material must placarded be on each which is required to be placarded. side and each end with the type of plac ards specified in tables 1 and 2 of this The exceptions provided in paragraph section and in accordance with other (c) of this section do not prohibit the placarding requirements of this sub display of placards in the manner pre part, including the specifications for scribed in this subpart, if not otherwise the placards named in the tables and prohibited (see § 172.502), on transport described in detail in § 172.519 through vehicles or freight containers which 172.560. are not required to be placarded. (b) DANGEROUS placard. A freight (d) Exception for empty non-bulk pack container, unit load device, transport ages. Except for hazardous materials vehicle, or rail car which contains non- subject to §172.505, a non-bulk pack bulk packages with two or more cat aging that contains only the residue of egories of hazardous materials that re a hazardous material covered by Table quire different placards specified in 2 of paragraph (e) of this section need table 2 of paragraph (e) of this section not be included in determining may be placarded with a DANGEROUS placarding requirements. placard instead of the separate (e) Placarding tables. Placards are placarding specified for each of the ma specified for hazardous materials in ac terials in table 2 of paragraph (e) of cordance with the following tables:
TABLE 1
Placard de Category of material (Hazard class or division number Placard name sign section and additional description, as appropriate) reference (9) 1.1 EXPLOSIVES 1.1 172.522 1.2 EXPLOSIVES 1.2 172.522 1.3 EXPLOSIVES 1.3 172.522 2.3 POISON GAS 172.540 4.3 DANGEROUS WHEN WET 172.548 5.2 (Organic peroside, Type B, liquid or solid, tempera- ORGANIC PEROXIDE 172.552 ture controlled). 6.1 (material poisonous by inhalation (see §171.8 of POISON INHALATION HAZARD 172.555 this subchapter)). 7 (Radioactive Yellow Ill label only) RADIOACTIVE1 172.556 1 RADIOACTIVE placard also required for esclusive use shipments of low specific activity material and surface contaminated objects transported in accordance with § 173.427(b)(4) and (5) or (c) of this subchapter. 375 § 172.504 49 CFR Ch. 1(10—1—10 Edition)
TABLE 2
Placard de Category of material (Hazard class or division number Placard name sign section and additional description, as appropriate) reference
1.4 EXPLOSIVES 1.4 172.523 1.5 EXPLOSIVES 1.5 172.524 1.6 EXPLOSIVES 1.6 172.525 2.1 FLAMMABLE GAS 172.532 2.2 NON-FLAMMABLE GAS 172.528 3 FLAMMABLE 172.542 Combustible liquid COMBUSTIBLE 172.844 4.1 FLAMMABLE SOLID 172.546 4.2 SPONTANEOUSLY COMBUSTIBLE 172.547 5.1 OXIDIZER 172.550 5.2 (Other than organic peroside, Type B, liquid or ORGANIC PEROXIDE 172.552 solid, temperature controlled). 6,1 (other than material poisonous by inhalation) POISON 172.554 6.2 (None) 8 CORROSIVE 172.558 9 Class 9 (see §172.504(f)(9)) 172.560 ORM-D (None)
(I) Additional placarding exceptions. (1) (6) The EXPLOSIVE 1.4 placard is not When more than one division placard is required for those Division 1.4 Compat required for Class 1 materials on a ibility Group S (l.4S) materials that transport vehicle, rail car, freight con are not required to be labeled l.4S. tainer or unit load device, only the (7) For domestic transportation of placard representing the lowest divi oxygen, compressed or oxygen, refrig sion number must be displayed. erated liquid, the OXYGEN placard in (2) A FLAMMABLE placard may be § 172.530 of this subpart may be used in used in place of a COMBUSTIBLE place of a NON-FLAMMABLE GAS placard on— placard. (i) A cargo tank or portable tank. (8) For domestic transportation, a (ii) A compartmented tank car which POISON INHALATION HAZARD contains both flammable and combus placard is not required on a transport tible liquids. vehicle or freight container that is al ready placarded with the POISON (3) A NON-FLAMMABLE GAS GAS placard. placard is not required on a transport (9) For Class CLASS vehicle which contains non-flammable 9, a 9 placard is not required for domestic transpor gas if the transport vehicle also con tation, including that portion of inter tains flammable gas or oxygen and it is national transportation, defined in placarded with FLAMMABLE GAS or § 171.8 of this subchapter, which occurs OXYGEN placards, as required. within the United States. However, a (4) OXIDIZER placards are not re bulk packaging must be marked with quired for Division 5.1 materials on the appropriate identification number freight containers, unit load devices, on a CLASS 9 placard, an orange panel, transport vehicles or rail cars which or a white square-on-point display con also contain Division 1.1 or 1.2 mate figuration as required by subpart D of rials and which are placarded with EX this part. PLOSIVES 1.1 or 1.2 placards, as re (10) For Division 6.1, PG III mate quired. rials, a POISON placard may be modi (5) For transportation by transport fied to display the text “PG III” below vehicle or rail car only, an OXIDIZER the mid line of the placard. placard is not required for Division 5.1 (11) For domestic transportation, a materials on a transport vehicle, rail POISON placard is not required on a car or freight container which also con transport vehicle or freight container tains Division 1.5 explosives and is required to display a POISON INHALA placarded with EXPLOSIVES 1.5 plac TION HAZARD or POISON GAS ards, as required. placard.
376 Pipeline and Hazardous Materials Safety Admin., DOT § 172.506 (g) For shipments of Class 1 (explo tion of the POISON INHALATION sive materials) by aircraft or vessel, HAZARD or POISON GAS placard is the applicable compatibility group let not required. ter must be displayed on the placards, (b) In addition to the RADIOACTIVE or labels when applicable, required by placard which may be required by this section. When more than one com § 172.504(e) of this subpart, each trans patibility group placard is required for port vehicle, portable tank or freight Class 1 materials, only one placard is container that contains 454 kg (1001 required to be displayed, as provided in pounds) or more gross weight of fissile paragraphs (g) (1) through (g) (4) of this or low specific activity uranium section. For the purposes of paragraphs hexafluoride shall be placarded with a (g) (1) through (g) (4), there is a distinc CORROSIVE placard on each side and tion between the phrases explosive art] each end. des and explosive substances. Explosive (c) Each transport vehicle, portable article means an article containing an tank, freight container or unit load de explosive substance; examples include vice that contains a material which a detonator, flare, primer or fuse. Ex has a subsidiary hazard of being dan plosive substance means a substance gerous when wet, as defined in § 173.124 contained in a packaging that is not of this subchapter, shall be placarded contained in an article; examples in with DANGEROUS WHEN WET plac clude black powder and smokeless pow ards, on each side and each end, in ad der. dition to the placards required by (I) Explosive articles of compat § 172.504. ibility groups C, D or E may be plac (d) Hazardous materials that possess arded displaying compatibility group secondary hazards may exhibit sub E. sidiary placards that correspond the (2) Explosive articles of compat to placards described in this part, even ibility groups C, D, or E, when trans when not required by this part (see also ported with those in compatibility 172.519(b) (4) of this subpart). group N, may be placarded displaying § compatibility group D. [Amdt. 172—123, 55 FR 52601, Dec. 21, 1990, as (3) Explosive substances of compat amended at 56 FR 66260, Dec. 20, 1991; 57 FR ibility groups C and D may be plac 45460, Oct. 1, 1992; Amdt. 172—127, 59 FR 49133, arded displaying compatibility group Sept. 26, 1994; Amdt. 172—151, 62 FR 1231, Jan. D. 8, 1997; 62 FR 39398, July 22, 1997; 65 FR 58626, Sept. 29, 2000; 72 (4) Explosive articles of compat FR 55692, Oct. 1, 2007] ibility groups C, D, E or G, except for § 172.506 Providing and affixing plac fireworks, may be placarded displaying ards: Highway. compatibility group E. (a) Each person offering a motor car [Amdt. 172—123, 55 FR 52600, Dec. 21, 1990] rier a hazardous material for transpor EDITORIAL NOTE: For FEDERAL REGISTER ci tation by highway shall provide to the tations affecting § 172.504, see the List of CFR motor carrier the required placards for Sections Affected which appears in the Find the material being offered prior to or ing Aids section of the printed volume and at the same time the material is of on GPO Access. fered for transportation, unless the § 172.505 Placarding for subsidiary carrier’s motor vehicle is already plac hazards. arded for the material as required by this subpart. (a) Each transport vehicle, freight (1) No motor carrier may transport container, portable tank, unit load de a hazardous material in vice, or rail car that contains a poi a motor vehicle, unless the placards required for sonous material subject to the “Poison the hazardous material Inhalation Hazard” shipping descrip are affixed thereto as required by this subpart. tion of §172.203(m) must be placarded with a POISON INHALATION HAZARD (2) [Reservedl or POISON GAS placard, as appro (b) [Reserved] priate, on each side and each end, in [Amdt. 172—29, 41 FR 15996, Apr. 15, 1976, as addition to any other placard required amended by Amdt. 172-29A, 41 FR 40679, Sept. for that material in § 172.504. Duplica 20, 19761
377 § 172.507 49 CFR Ch. I (10—1—10 Edition)
§ 172.507 Special placarding provi rail car, including tank cars containing sions: Highway. only a residue of the material; and (a) Each motor vehicle used to trans (3) Class DOT 113 tank cars used to transport port a package of highway route con a Division 2.1 (flammable gas) material, including trolled quantity Class 7 (radioactive) tank cars con taining only a residue of the material. materials (see 173.403 of this sub § (b) Chemical ammunition. Each rail chapter) must have the required RA car containing Division 1.1 or 1.2 (ex DIOACTIVE warning placard placed on plosive) ammunition which also meets a square background as described in the definition of a material poisonous 172.527. § by inhalation (see §171.8 of this sub (b) A nurse tank, meeting the provi chapter) must be placarded EXPLO sions of § 173.315(m) of this subchapter, SIVES 1.1 or EXPLOSIVES 1.2 and is not required to be placarded on an POISON GAS or POISON INHALATION end containing valves, fittings, regu HAZARD. lators or gauges when those appur tenances prevent the markings and [Amdt. 172—29, 41 FR 15996, Apr. 15, 1976, as placard from being amended by Amdt. 172-103, 51 FR 5971. Feb. properly placed and 18, 1986; Amdt. 172—110, 52 FR 29528, Aug. 10, visible. 1987; Amdt. 172—111, 52 FR 36671, Sept. 30, 1987; Amdt. 172—123, 55 FR 52601, Dec. 21, 56 [Amdt. 172—103, 51 FR 5971, Feb. 18, 1986, as 1990: FR 66260, Dec. 20, 1991; amended by Amdt. 172-143, 60 FR 50305, 57 FR 45460, Oct. 1, Sept. Amdt. 28, 1995] 1992: 172—248, 61 FR 28676, June 5, 1996: Amdt. 172—151, 62 FR 1231. Jan. 8, 1997: 62 FR 39398, July 22, 1997] § 172.508 Placarding and affixing plac ards: Rail. § 172.512 Freight containers and air (a) Each person offering a hazardous craft unit load devices. material for transportation by rail (a) Capacity of 640 cubic feet or more. shall affix to the rail car containing Each person who offers for transpor the material, the placards specified by tation, and each person who loads and this subpart. Placards displayed on transports, a hazardous material in a motor vehicles, transport containers, freight container or aircraft unit load or portable tanks may be used to sat device having a capacity of 640 cubic isfy this requirement, if the placards feet or more shall affix to the freight otherwise conform to the provisions of container or aircraft unit load device this subpart. the placards specified for the material (b) No rail carrier may accept a rail in accordance with § 172.504. However: car containing a hazardous material (1) The placarding exception provided for transportation unless the placards in § 172.504(c) applies to motor vehicles for the hazardous material are affixed transporting freight containers and thereto as required by this subpart. aircraft unit load devices, (2) The placarding exception provided [Amdt. 172—29. 41 FR 15996, Apr. 15, 1976, as in § 172.504(c) applies to each freight amended by Amdt. 172-123, 55 FR 52601, Dec. container and aircraft unit load device 21, 1990] being transported for delivery to a con signee § 172.510 Special placarding provi immediately following an air or sions: Rail. water shipment, and, (3) Placarding is not required on a (a) White square background. The fol freight container or aircraft unit load lowing must have the specified plac device if it is only transported by air ards placed on a white square back and is identified as containing a haz ground, as described in § 172.527: ardous material in the manner pro (1) Division 1.1 and 1.2 (explosive) ma vided in part 7, chapter 2, section 2.7, of terials which require EXPLOSIVES 1.1 the ICAO Technical Instructions (IBR, or EXPLOSIVES 1.2 placards affixed to see § 171.7 of this subchapter). the rail car; (b) Capacity less than 18 m3 (640 cubic (2) Materials classed in Division 2.3 feet). Each person who offers for trans Hazard Zone A or 6.1 Packing Group I portation by air, and each person who Hazard Zone A which require POISON loads and transports by air, a haz GAS or POISON placards affixed to the ardous material in a freight container 378 Pipeline and Hazardous Materials Safety Admin., DOT § 172.516 or aircraft unit load device having a (2) Is refilled, with a material requir capacity of less than 18 m3 (640 cubic ing different placards or no placards, to feet) shall affix one placard of the type such an extent that any residue re specified by paragraph (a) of this sec maining in the packaging is no longer tion unless the freight container or air hazardous; or craft unit load device: (3) Contains the residue of a haz (1) Is labeled in accordance with sub ardous substance in Class 9 in a quan part E of this part, including tity less than the reportable quantity, § 172.406(e) and conforms to §173.29(b)(1) of this (2) Contains radioactive materials re subchapter. quiring the Radioactive Yellow III (c) Exceptions. The following pack label and is placarded with one Radio agings may be placarded on only two active placard and is labeled in accord opposite sides or, alternatively, may be ance with subpart F of this part, in labeled instead of placarded in accord cluding §172.406(e); or, ance with subpart E of this part: (3) Is identified as containing a haz (1) A portable tank having a capacity ardous material in the manner pro of less than 3,785 L (1000 gallons); vided in part 7, chapter 2, section 2.7, of (2) A DOT 106 or 110 multi-unit tank the ICAO Technical Instructions. When car tank; hazardous materials are offered for (3) A bulk packaging other than a transportation, not involving air trans portable tank, cargo tank, or tank car portation, in a freight container having (e.g., a bulk bag or box) with a volu a capacity of less than 640 cubic feet metric capacity of less than 18 cubic the freight container need not be plac meters (640 cubic feet); arded. However, if not placarded, it (4) An IBC; and must be labeled in accordance with (5) A Large Packaging as defined in subpart F of this part. § 171.8 of this subchapter. (c) Notwithstanding paragraphs (a) [Amdt. 172—136, 59 FR 38064, July 26, 1994; and (b) of this section, packages con Amdt. 172—148, 61 FR 50255, Sept. 25, 1996, as taining hazardous materials, other amended by 66 FR 45379, Aug. 28, 2001; 69 FR than ORM-D, offered for transportation 64473, Nov. 4, 2004; 75 FR 5392, Feb. 2, 20101 by air in freight containers are subject to the inspection requirements of § 172.516 Visibility and display of plac ards. § 175.30 of this chapter. (a) Each placard on a motor vehicle [Amdt. 172—29, 41 FR 15996, Apr. 15, 1976, as and each placard on a rail car must be amended by Amdt. 172-29A, 41 FR 40680, Sept. clearly visible 20, 1976; Amdt. 172—87, 48 FR 53712, Nov. 29, from the direction it 1983; 48 FR 55469, Dec. 13, 1983: Amdt. 172—103, faces, except from the direction of an 51 FR 5971, Feb. 18, 1986; Amdt. 172—111, 52 FR other transport vehicle or rail car to 36671, Sept. 30, 1987; Amdt. 172—123, 55 FR which the motor vehicle or rail car is 52601, Dec. 21, 1990; 66 FR 33426, June 21, 2001; coupled. This requirement may be met 66 FR 45182, Aug. 28, 2001; 68 FR 75741, Dec. 31, by the placards displayed on the 2003; 69 FR 54046, Sept. 7, 2004] freight containers or portable tanks loaded on a motor vehicle or rail car. § 172.514 Bulk packagings. (b) The required placarding of the (a) Except as provided in paragraph front of a motor vehicle may be on the (c) of this section, each person who of front of a truck-tractor instead of or in fers for transportation a bulk pack addition to the placarding on the front aging which contains a hazardous ma of the cargo body to which a truck- terial, shall affix the placards specified tractor is attached. for the material in § 172.504 and 172.505. (c) Each placard on a transport vehi (b) Each bulk packaging that is re cle, bulk packaging, freight container quired to be placarded when it contains or aircraft unit load device must— a hazardous material, must remain (1) Be securely attached or affixed placarded when it is emptied, unless thereto or placed in a holder thereon. it— (See appendix C to this part.); (1) Is sufficiently cleaned of residue (2) Be located clear of appurtenances and purged of vapors to remove any po and devices such as ladders, pipes, tential hazard; doors, and tarpaulins;
379 § 172.519 49 CFR Ch. I (10—1—10 Edition)
(3) So far as practicable, be located so must be able to pass a 414 kPa (60 p.s.i.) that dirt or water is not directed to it Mullen test. from the wheels of the transport vehi (3) Reflective or retroreflective mate c le; rials may be used on a placard if the (4) Be located away from any mark prescribed colors, strength and dura ing (such as advertising) that could bility are maintained. substantially reduce its effectiveness, (b) Design. (1) Except as provided in and in any case at least 3 inches (76.0 § 172.332 of this part, each placard must mm.) away from such marking; be as described in this subpart, and ex (5) Have the words or identification cept for size and color, the printing, number (when authorized) printed on it inner border and symbol must be as displayed horizontally, reading from shown in 172.521 through 172.560 of right; § left to this subpart, as appropriate. (6) Be maintained the carrier by in a (2) The dotted line border shown on condition so that the format, leg each placard is not part of the placard ibility, color, and visibility of the specification. However, a dotted or placard will not be substantially re solid line outer border may be used duced due to damage, deterioration, or when needed to indicate obscurement by dirt or other matter; the full size of a placard that is part of a larger for (7) Be affixed to a background of con mat or is on a background of a non- trasting color, or must have a dotted contrasting color. or solid line outer border which con trasts with the background color. (3) For other than Class 7 or the DANGEROUS (d) Recommended specifications for a placard, text indicating placard holder are set forth in appendix a hazard (for example, “FLAM C of this part. Except for a placard MABLE”) is not required. Text may be holder similar to that contained in ap omitted from the OXYGEN placard pendix C to this part, the means used only if the specific identification num to attach a placard may not obscure ber is displayed on the placard. any part of its surface other than the (4) For a placard corresponding to the borders. primary or subsidiary hazard class of a (e) A placard or placard holder may material, the hazard class or division be hinged provided the required format, number must be displayed in the lower color, and legibility of the placard are corner of the placard. However, a per maintained. manently affixed subsidiary placard meeting the specifications of this sec lAmdt. 172—29, 41 FR 15996, Apr. 15, 1976, as tion which were effect amended by Amdt. 172-101, 45 FR 74668, Nov. in on October 1, 10, 1980; Amdt. 172—123, 55 FR 52601, Dec. 21, 2001, (such as, a placard without the 1990; 65 FR 50460, Aug. 18. 20001 hazard class or division number dis played in the lower corner of the § 172.519 General specifications for placard) and which was installed prior placards. to September 30, 2001, may continue to (a) Strength and durability. Placards be used as a subsidiary placard in do must conform to the following; mestic transportation by rail or high (1) A placard may be made of any way, provided the color tolerances are plastic, metal or other material capa maintained and are in accordance with ble of withstanding, without deteriora the display requirements in this sub tion or a substantial reduction in effec chapter. Stocks of non-permanently af tiveness, a 30-day exposure to open fixed subsidiary placards in compliance weather conditions. with the requirements in effect on Sep (2) A placard made of tagboard must tember 30, 2001, may continue to be be at least equal to that designated used in domestic transportation by rail commercially as white tagboard. Tag- or highway until October 1, 2005, or board must have a weight of at least 80 until current stocks are depleted, kg (176 pounds) per ream of 610 by 910 whichever occurs first. mm (24 by 36-inch) sheets, water (c) Size. (1) Each placard prescribed in proofing materials included. In addi this subpart must measure at least 273 tion, each placard made of tagboard mm (10.8 inches) on each side and must 380 Pipeline and Hazardous Materials Safety Admin., DOT § 172.521 have a solid line inner border approxi in place of a corresponding placard mately 12.7 mm (0.5 inches) from each conforming to the requirements of this edge. subpart. However, a bulk packaging, (2) Except as otherwise provided in transport vehicle, or freight container this subpart, the hazard class or divi containing a material poisonous by in sion number, as appropriate, must be halation (see § 171.8 of this subchapter) shown in numerals measuring at least must be placarded in accordance with 41 mm (1.6 inches) in height. this subpart (see § 171.23(b)(ll) of this (3) Except as otherwise provided in subchapter). this subpart, when text indicating a (g) Trefoil symbol. The trefoil symbol hazard is displayed on a placard, the on the RADIOACTIVE placard must printing must be in letters measuring meet the appropriate specification at least 41 mm (1.6 inches) in height. in (d) Color. (1) The background color, appendix B of this part. symbol, text, numerals and inner bor lAmdt. 172.423, 55 FR 52601, Dec. 21, 1990, as der on a placard must be as specified in amended at 56 FR 66260, Dec. 20, 1991; 57 FR § 172.521 through 172.560 of this sub 45460, Oct. 1, 1992; Amdt. 172-143, 60 FR 50305, part, as appropriate. Sept. 28, 1995; 65 FR 50460, Aug. 18, 2000; 66 FR (2) Black and any color on a placard 33426, June 21, 2001: 66 FR 44255, Aug. 22, 2001: must be able to withstand, without 67 FR 15743, Apr. 3. 2002; 70 FR 34075. June 13, substantial change— 2005; 69 FR 64473, Nov. 4, 2004; 72 FR 25176, (1) A 72-hour fadeometer test (for a May 3, 20071 description of equipment designed for 172.521 DANGEROUS placard. this purpose, see ASTM G 23-69 or § ASTM G 26-70); and (a) Except for size and color, the (ii) A 30-day exposure to open weath DANGEROUS placard must be as fol er. lows: (3) Upon visual examination, a color on a placard must fall within the color tolerances displayed on the appropriate Hazardous Materials Label and Placard Color Tolerance Chart (see §172.407(d)(4)). As an alternative, the PANTONE formula guide coated! uncoated as specified for colors in §172.407(d) (5) maybe used. (4) The placard color must extend to the inner border and may extend to the edge of the placard in the area des ignated on each placard except the color on the CORROSIVE and RADIO ACTIVE placards (black and yellow, re spectively) must extend only to the inner border. (e) Form identification. A placard may contain form identification informa (b) In addition to meeting the re tion, including the name of its maker, quirements of § 172.519, and appendix B provided that information is printed to this part, the DANGEROUS placard the solid line inner outside of border in must have a red upper and lower tri no larger than 10-point type. angle. The placard center area and ‘/2- (f) Exceptions. When hazardous mate inch (12.7 mm.) border must be white. rials are offered for transportation or The inscription must black with the transported under the provisions of be ‘/8-inch marker subpart C of part 171 of this subchapter. (3.2 mm.) border in the a placard conforming to the specifica white area at each end of the inscrip tions in the ICAO Technical Instruc tion red. tions, the IMDG Code, or the Transport jAmdt. 172—29, 41 FR 15996, Apr. 15, 1976, as Canada TDG Regulations (IBR, see amended by Amdt. 172-29A, 41 FR 40680, Sept. § 171.7 of this subchapter) may be used 20, 1976] 381 § 172.522 49 CFR Ch. 1(10—1—10 Edition)
§ 172.522 EXPLOSiVES 1.1, EXPLO SWES 1.2 and EXPLOSWES 1.3 placards. (a) Except for size and color, the EX PLOSIVES 1.1, EXPLOSIVES 1.2 and EXPLOSIVES 1.3 placards must be as follows:
(b) In addition to complying with § 172.5 19 of this subpart, the background color on the EXPLOSIVES 1.4 placard
must be orange. The ““ shall be re placed, when required, with the appro priate compatibility group letter. The division numeral, 1.4, must measure at (b) In addition to complying with least 64 mm (2.5 inches) in height. The §172.519 of this subpart, the background text, numerals and inner border must color on the EXPLOSIVES 1.1, EXPLO be black. SIVES 1.2, and EXPLOSIVES 1.3 plac lAmdt. 172—123. 55 FR 52602, Dec. 21, 1990, as ards must be orange. The “*“ shall be amended at 56 FR 66261. Dec. 20. 1991] replaced with the appropriate division number and, when required, appro § 172.524 EXPLOSIVES 1.5 placard. priate compatibility group letter. The (a) Except for size and color, the EX symbol, text, numerals and inner bor PLOSIVES 1.5 placard must be as fol der must be black. lows: [Amdt. 172—123, 55 FR 52602, Dec. 21, 1990, as amended at 56 FR 66260, Dec. 20, 1991]
§ 172.523 EXPLOSWES 1.4 placard. (a) Except for size and color, the EX PLOSIVES 1.4 placard must be as fol lows:
BLASTING .... AGENTS
(b) In addition to complying with the § 172.5 19 of this subpart, the background color on EXPLOSIVES 1.5 placard 382 Pipeline and Hazardous Materials Safety Admin., DOT § 172.528
must be orange. The “ shall be re placed, when required, with the appro priate compatibility group letter. The division numeral, 1.5, must measure at least 64 mm (2.5 inches) in height. The text, numerals and inner border must be black. [Amdt. 172—123, 55 FR 52602, Dec. 21, 1990, as amended at 56 FR 66261, Dec. 20, 1991]
§ 172.525 EXPLOSiVES 1.6 placard. (a) Except for size and color the EX PLOSIVES 1.6 placard must be as fol lows:
(b) In addition to meeting the re quirements of § 172.5 19 for minimum du rability and strength, the square back 1.6 ground must consist of a white square measuring 14V4 inches (362.0 mm.) on each side surrounded by a black border EXPLOSIVES extending to 15¼ inches (387.0 mm.) on each side. [Amdt. 172—29, 41 FR 15996, Apr. 15, 1976. as amended by Amdt. 172-64, 46 FR 5316, Jan. 19, 1981; Amdt. 172—78, 48 FR 10226, Mar. 10, 1983] § 172.528 NON-FLAMMABLE GAS placard. (a) Except for size and color, the (b) In addition to complying with NON-FLAMMABLE GAS placard must § 172.519 of this subpart, the background be as follows: color on the EXPLOSIVES 1.6 placard must be orange. The ““ shall be re placed, when required, with the appro priate compatibility group letter. The division numeral, 1.6, must measure at least 64 mm (2.5 inches) in height. The text, numerals and inner border must be black. [Amdt. 172—123, 55 FR 52603, Dec. 21, 1990, as amended at 56 FR 66261. Dec. 20, 1991; Amdt. 172—130, 58 FR 51531, Dct. 1, 1993]
§ 172.526 [Reserved]
§ 172.527 Background requirements for certain placards. (a) Except for size and color, the square background required by § 172.510(a) for certain placards on rail (b) In addition to complying with cars, and § 172.507 for placards on motor §172.519, the background color on the vehicles containing a package of high NON-FLAMMABLE GAS placard must way route controlled quantity radio be green. The letters in both words active materials, must be as follows: must be at least 38 mm (1.5 inches) 383 § 172.530 49 CFR Ch. I (10—1—10 Edition)
high. The symbol, text, class number FLAMMABLE GAS placard must be and inner border must be white. red. The symbol, text, class number ]Amdt. 172—123, 56 FR 66261, Dec. 20, 1991] and inner border must be white. lAmdt. 172—123, 56 FR 66262, Dec. 20, 1991] § 172.530 OXYGEN placard. (a) Except for size and color, the OX § 172.536 [Reservedl YGEN placard must be as follows: § 172.540 POISON GAS placard. (a) Except for size and color, the POI SON GAS placard must be as follows:
OXYGEN INHALATION HAZARD
(b) In addition to complying with § 172.5 19 of this subpart, the background color on the OXYGEN placard must be yellow. The symbol, text, class number (b) In addition to complying with and inner border must be black. §172.519, the background on the POI [Amdt. 172—123. 56 FR 66262, Dec. 20, 1991] SON GAS placard and the symbol must be white. The background of the upper § 172.532 FLAMMABLE GAS placard. diamond must be black and the lower (a) Except for size and color, the point of the upper diamond must be 65 FLAMMABLE GAS placard must be as mm (2% inches) above the horizontal follows: center line. The text, class number, and inner border must be black. 162 FR 39408, July 22, 19971
§ 172.542 FLAMMABLE placard. (a) Except for size and color, the FLAMMABLE placard must be as fol lows:
(b) In addition to complying with §172.519, the background color on the 384 Pipeline and Hazardous Materials Safety Admin., DOT § 172.547
The symbol, text, class number and inner border must be white. On a COM BUSTIBLE placard with a white bot tom as prescribed by §172.332(c)(4), the class number must be red or black. (c) The words “FUEL OIL” may be used in place of the word “COMBUS TIBLE” on a placard that is displayed on a cargo tank or portable tank being used to transport by highway fuel oil that is not classed as a flammable liq uid. The words “FUEL OIL” must be white. [Amdt. 172—123, 56 FR 66262, Dec. 20, 1991]
§ 172.546 FLAMMABLE SOLID placard. (a) Except for size and color, the (b) In addition to complying with FLAMMABLE SOLID placard must be §172.519, the background color on the as follows: FLAMMABLE placard must be red. The symbol, text, class number and inner border must be white. (c) The word GASOLINE” may be used in place of the word “FLAM MABLE” on a placard that is displayed on a cargo tank or a portable tank being used to transport gasoline by highway. The word “GASOLINE” must be shown in white. [Amdt. 172—123, 56 FR 66262, Dec. 20, 1991]
§ 172.544 COMBUSTIBLE placard. (a) Except for size and color, the COMBUSTIBLE placard must be as fol lows: (b) In addition to complying with § 172.519, the background on the FLAM MABLE SOLID placard must be white with seven vertical red stripes. The stripes must be equally spaced, with one red stripe placed in the center of the label. Each red stripe and each white space between two red stripes must be 25 mm (1.0 inches) wide. The letters in the word “SOLID” must be at least 38.1 mm (1.5 inches) high. The symbol, text, class number and inner border must be black. [Amdt. 172—123, 56 FR 66263. Dec. 20, 1991]
§ 172.547 SPONTANEOUSLY COMEUS TIBLE placard. (b) In addition to complying with (a) Except for size and color, the §172.519, the background color on the SPONTANEOUSLY COMBUSTIBLE COMBUSTIBLE placard must be red. placard must be as follows: 385 § 172.548 49 CFR Ch. I (10—1—10 Edition)
(b) In addition to complying with § 172.519, the background color on the DANGEROUS WHEN WET placard must be blue. The letters in the words “WHEN WET” must be at least 25 mm (1.0 inches) high. The symbol, text, class number and inner border must be SPONTANEOUSLY white. .. I_._. — ]Amdt. 172—123, 56 FR 66263, Dec. 20, 1991]
§ 172.550 OXIDIZER placard. (a) Except for size and color, the OXI. DIZER placard must be as follows:
(b) In addition to complying with §172.519, the background color on the SPONTANEOUSLY COMBUSTIBLE placard must be red in the lower half and white in upper half. The letters in the word SPONTANEOUSLY” must be at least 12 mm (0.5 inch) high. The symbol, text, class number and inner OXIDER border must be black. [Amdt. 172-123, 56 FR 66263, Dec. 20. 1991. as amended by Amdt. 172-139, 59 FR 67490, Dec. 29, 1994]
§ 172.548 DANGEROUS WHEN WET placard. (a) Except for size and color, the DANGEROUS WHEN WET placard (b) In addition to complying with must be as follows: §172.519, the background color on the OXIDIZER placard must be yellow. The symbol, text, division number and inner border must be black. lAmdt. 172—123, 56 FR 66263, Dec. 20, 1991]
§ 172.552 ORGANIC PEROXIDE placard. (a) Except for size and color, the OR GANIC PEROXIDE placard must be as follows:
386 Pipeline and Hazardous Materials Safety Admn., DOT § 172.554
ROXI
(b) In addition to complying with §172.519, the background on the OR GANIC PEROXIDE placard must be red in the top half and yellow in the lower half. The text, division number and inner border must be black; the symbol may be either black or white. [71 FR 78628, Dec. 29. 2006]
§ 172.553 [Reservedl
§ 172.554 POISON placard. (a) Except for size and color, the POI SON placard must be as follows:
387 § 172.555 49 CFR Ch. 1(10—1—10 Edition)
(b) In addition to complying with (b) In addition to complying with §172.519, the background on the POI §172.519, the background on the POI SON placard must be white. The sym SON INHALATION HAZARD placard bol, text, class number and inner bor and the symbol must be white. The der must be black. The word “TOXIC” background of the upper diamond must may be used in lieu of the word “POI be black and the lower point of the SON”. upper diamond must be 65 mm (2/8 {Amdt. 172-423, 56 FR 66264, Dec. 20, 1991, as inches) above the horizontal center amended by Amdt. 172-139, 59 FR 67490, Dec. line. The text, class number, and inner 29, 1994} border must be black. § 172.555 POISON INHALATION HAZ [62 FR 39409, July 22, 1997J ARD placard. (a) Except for size and color, the POI § 172.556 RAIMOACTIVE placard. SON INHALATION HAZARD placard (a) Except for size and color, the RA must be as follows: DIOACTIVE placard must be as fol lows:
INHALATION HAZARD
388 Pipeline and Hazardous Materials Safety Admin., DOT § 172.558
.....KAbibiCtiVE>
(b) In addition to complying with symbol, text, class number and inner §172519, the background color on the border must be black. RADIOACTIVE placard must be white [Amdt. 172-123, 56 FR 66264, Dec. 20, 1991: in the lower portion with a yellow tri Amdt. 172—130, 58 FR 51531, Oct. 1, 1993; 65 FR angle in the upper portion. The base of 58627, Sept. 29, 20001 the yellow triangle must be 29 mm ±5 mm (1.1 inches ±0.2 inches) above the § 172.558 CORROSIVE placard. placard horizontal center line. The (a) Except for size and color, the CORROSIVE placard must be as fol lows:
389 § 172.560 49 CFR Ch. I (10—1—10 Edition)
(b) In addition to complying with §172.519, the background color on the CORROSIVE placard must be black in the lower portion with a white triangle in the upper portion. The base of the white triangle must be 38 mm ±5 mm (1.5 inches ±0.2 inches) above the placard horizontal center line. The text and class number must be white. The symbol and inner border must be black. [Amdt. 172—123, 56 FR 66264, Dec. 20, 1991, as amended at 65 FR 58627, Sept. 29, 2000]
§ 172.560 CLASS 9 placard. (a) Except for size and color the CLASS 9 (miscellaneous hazardous ma terials) placard must be as follows:
390 Pipeline and Hazardous Materials Safety Admin., DOT § 172.602
(b) In addition to conformance with shipping paper requirements of this §172.519, the background on the CLASS subchapter or a material properly clas 9 placard must be white with seven sified as an ORM-D. black vertical stripes on the top half extending from the top of jAmdt. 172—116, 54 FR 27145, June 27, 1989; 54 the placard FR 28750, July 5. 1989, as amended at 55 FR to one inch above the horizontal cen 33712, Aug. 17, 1990: 172—127, 59 FR 49133, Sept. terline. The black vertical stripes must 26, 1994; Amdt. 172—149, 61 FR 27173, May 30, be spaced so that, visually, they appear 1996] equal in width to the six white spaces between them. The space below the § 172.602 Emergency response infor vertical lines must be white with the mation. class number 9 underlined and centered (a) Information required. For purposes at the bottom. of this subpart, the term “emergency [Amdt. 172—123, 56 FR 66264, Dec. 20, 1991, as response information” means informa amended at 57 FR 45460, Oct. 1, 1992] tion that can be used in the mitigation of an incident involving hazardous ma Subpart G—Emergency Response terials and, as a minimum, must con Information tain the following information: (1) The basic description and tech § 172.600 Applicability and general re nical name of the hazardous material quirements. as required by § 172.202 and 172.203(k), (a) Scope. Except as provided in para the ICAO Technical Instructions, the graph (d) of this section, this subpart IMDG Code, or the TDG Regulations, prescribes requirements for providing as appropriate (IBR, see §171.7 of this and maintaining emergency response subchapter); information during transportation and (2) Immediate hazards to health; at facilities where hazardous materials (3) Risks of fire or explosion; are loaded for transportation, stored (4) Immediate precautions to be incidental to transportation or other taken in the event of an accident or in wise handled during any phase of trans cident; portation. (5) Immediate methods for handling (b) Applicability. This subpart applies fires; to persons who offer for transportation, (6) Initial methods for handling spilis accept for transportation, transfer or or leaks in the absence of fire; and otherwise handle hazardous materials (7) Preliminary first aid measures. during transportation. (b) Form of information. The informa (c) General requirements. No person to tion required for a hazardous material whom this subpart applies may offer by paragraph (a) of this section must for transportation, accept for transpor be: tation, transfer, store or otherwise (1) Printed legibly in English; handle during transportation a haz (2) Available for use away from the ardous material unless: package containing the hazardous ma (1) Emergency response information terial; and conforming to this subpart is imme (3) Presented— diately available for use at all times (i) On a shipping paper; the hazardous material is present; and (ii) In a document, other than a ship (2) Emergency response information, ping paper, that includes both the basic including the emergency response tele description and technical name of the phone number, required by this subpart hazardous material as required by is immediately available to any person §l72.2O2 and 172.203(k), the ICAO Tech who, as a representative of a Federal, nical Instructions, the IMDG Code, or State or local government agency, re the TDG Regulations, as appropriate, sponds to an incident involving a haz and the emergency response informa ardous material, or is conducting an tion required by this subpart (e.g., a investigation which involves a haz material safety data sheet); or ardous material. (iii) Related to the information on a (d) Exceptions. The requirements of shipping paper, a written notification this subpart do not apply to hazardous to pilot-in-command, or a dangerous material which is excepted from the cargo manifest, in a separate document 391 § 172.604 49 CFR Ch. 1(10—1—10 Edition)
(e.g., an emergency response guidance volving the hazardous material. For document), in a manner that cross-ref telephone numbers outside the United erences the description of the haz States, the international access code or ardous material on the shipping paper the “+“ (plus) sign, country code, and with the emergency response informa city code, as appropriate, must be in tion contained in the document. cluded. The telephone number must Aboard aircraft, the ICAO ‘Emergency be— Response Guidance for Aircraft Inci (1) Monitored at all times the haz dents Involving Dangerous Goods” and, ardous material is in transportation, aboard vessels, the IMO “Emergency including storage incidental to trans Procedures for Ships Carrying Dan portation; gerous Goods”, or equivalent docu (2) The telephone number of a person ments, may be used to satisfy the re who is either knowledgeable of the haz quirements of this section for a sepa ardous material being shipped and has rate document. comprehensive emergency response and (c) Maintenance of information. Emer incident mitigation information for gency response information shall be that material, or has immediate access maintained as follows: to a person who possesses such knowl (1) Carriers. Each carrier who trans edge and information. A telephone ports a hazardous material shall main number that requires a call back (such tain the information specified in para as an answering service, answering ma graph (a) of this section and § 17 2.606 of chine, or beeper device) does not meet this part in the same manner as pre the requirements of paragraph (a) of scribed for shipping papers, except that this section; and the information must be maintained in (3) Entered on a shipping paper, as the same manner aboard aircraft as the follows: notification of pilot-in-command, and (i) Immediately following the de aboard vessels in the same manner as scription of the hazardous material re the dangerous cargo manifest. This in quired by subpart C of this part; or formation must be immediately acces (ii) Entered once on the shipping sible to train crew personnel, drivers of paper in a prominent, readily identifi motor vehicles, flight crew members, able, and clearly visible manner that and bridge personnel on vessels for use allows the information to be easily and in the event of incidents involving haz quickly found, such as by highlighting, ardous materials. use of a larger font or a font that is a (2) Facility operators. Each operator of different color from other text and in a facility where a hazardous material formation, or otherwise setting the in is received, stored or handled during formation apart to provide for quick transportation, shall maintain the in and easy recognition. This provision formation required by paragraph (a) of may be used only if the telephone num this section whenever the hazardous ber applies to each hazardous material material is present. This information entered on the shipping paper, and if it must be in a location that is imme is indicated that the telephone number diately accessible to facility personnel is for emergency response information in the event of an incident involving (for example: “EMERGENCY CON the hazardous material. TACT: * * The lAmdt. 172—116, 54 FR 27146, June 27, 1989; 54 (b) telephone number required by FR 28750, July 5, 1989, as amended by Amdt. paragraph (a) of this section must be - 172—116, 55 FR 875, Jan. 10, 1990; Amdt. 172—151, (1) The number of the person offering 62 FR 1234, Jan. 8, 1997; 66 FR 45379, Aug. 28, the hazardous material for transpor 2001; 68 FR 75741, Dec. 31, 20031 tation when that person is also the emergency response information pro § 172.604 Emergency response tele vider (ERI provider). The name of the phone number. person, or contract number or other (a) A person who offers a hazardous unique identifier assigned by an ERI material for transportation must pro provider, identified with the emer vide an emergency response telephone gency response telephone number must number, including the area code, for be entered on the shipping paper imme use in the event of an emergency in- diately before, after, above, or below 392 Pipeline and Hazardous Materials Safety Admin., DOT § 172.606 the emergency response telephone Fish meal, stabilized. number unless the name is entered Fish scrap, stabilized. elsewhere on the shipping paper in a Refrigerating machine. prominent, readily identifiable, and Vehicle, flammable gas powered. clearly visible manner that allows the Vehicle, flammable liquid powered. information easily to be and quickly Wheelchair, electric. found; or (2) The number of an agency or orga (3) Transportation vehicles or freight nization capable of, and accepting re containers containing lading that has sponsibility for, providing the detailed been fumigated and displaying the FU information required by paragraph MIGANT marking (see §172.302(g)) as (a)(2) of this section. The person who is required by §173.9 of this subchapter, registered with the ERI provider must unless other hazardous materials are ensure that the agency or organization present in the cargo transport unit. has received current information on [74 FR 53422, Oct. 19, 2009, as amended at 75 the material before it is offered for FR 53596, Sept. 1. 2010] transportation. The person who is reg istered with the ERI provider must be § 172.606 Carrier information contact. identified by name, or contract number (a) Each carrier who transports or ac or other unique identifier assigned by cepts for transportation a hazardous the ERI provider, on the shipping paper material for which a shipping paper is immediately before, after, above, or required shall instruct the operator of below the emergency response tele a motor vehicle, train, aircraft, or ves phone number in a prominent, readily sel to contact the carrier (e.g., by tele identifiable, and clearly visible manner phone or mobile radio) in the event of allows the information that to be eas an incident involving the hazardous ily and quickly found, unless the name material. or identifier is entered elsewhere in a prominent manner as provided in para (b) For transportation by highway, if transport graph (b) (1) of this section. a vehicle, (e.g., a semi-trailer (c) A person preparing shipping pa or freight container-on-chassis) con pers for continued transportation in tains hazardous material for which a commerce must include the informa shipping paper is required and the vehi tion required by this section. If the cle is separated from its motive power person preparing shipping papers for and parked at a location other than a continued transportation in commerce facility operated by the consignor or elects to assume responsibility for pro consignee or a facility (e.g., a carrier’s viding the emergency response tele terminal or a marine terminal) subject phone number required by this section, to the provisions of §l72.602(c)(2), the the person must ensure that all the re carrier shall— quirements of this section are met. (1) Mark the transport vehicle with (d) The requirements of this section the telephone number of the motor car do not apply to— rier on the front exterior near the (1) Hazardous materials that are of brake hose and electrical connections fered for transportation under the pro or on a label, tag, or sign attached to visions applicable to limited quan the vehicle at the brake hose or elec tities; and trical connection; or (2) Materials properly described (2) Have the shipping paper and emer under the following shipping names: gency response information readily Battery powered equipment. available on the transport vehicle. Battery powered vehicle. (c) The requirements specified in Carbon dioxide, solid. paragraph (b) of this section do not Castor bean. apply to an unattended motor vehicle Castor flake. separated from its motive power when Castor meal. the motor vehicle is marked on an or Castor pomace. ange panel, a placard, or a plain white Consumer commodity. square-on-point configuration with the Dry ice. identification number of each haz Engines, internal combustion. ardous material loaded therein, and the 393 § 172.700 49 CFR Ch. 1(10—1—10 Edition) marking or placard is visible on the requirements of this subchapter may outside of the motor vehicle. not perform that function unless in structed in the requirements of this [Amdt. 172—151. 62 FR 1234. Jan. 8. 1997. as amended at 62 FR 39398 and 39409. July 22, subchapter that apply to that function. 1997; 63 FR 16076, Apr. 1, 1998) It is the duty of each hazmat employer to comply with the applicable require Subpart H—Trainhig ments of this subchapter and to thor oughly instruct each hazmat employee in relation thereto. SOURCE: Amdt. 172-126, 57 FR 20952. May 15, (c) Training may be provided by the 1992. unless otherwise noted. hazmat employer or other public or private sources. § 172.700 Purpose and scope. (d) A hazmat employer shall ensure (a) Purpose. This subpart prescribes that each of its hazmat employees is requirements for training hazmat em tested by appropriate means on the ployees. training subjects covered in § 172.704. (b) Scope. Training as used in this [Amdt. 172-126. 57 FR 20952, May 15. 1992; 57 subpart means a systematic program FR 22182, May 27, 1992, as amended by Amdt. that ensures a hazmat employee has fa 172—149. 61 FR 27173, May 30. 1996] miliarity with the general provisions of this subchapter, is able to recognize § 172.704 Training requirements. and identify hazardous materials, has (a) Hazmat employee training must knowledge of specific requirements of include the following: this subchapter applicable to functions (1) General awareness/familiarization performed by the employee, and has training. Each hazmat employee shall knowledge of emergency response in be provided general awareness/famil formation, self-protection measures iarization training designed to provide and accident prevention methods and familiarity with the requirements of procedures (see § 172.704). this subchapter, and to enable the em (c) Modal-specific training require ployee to recognize and identify haz ments. Additional training require ardous materials consistent with the ments for the individual modes of hazard communication standards of transportation are prescribed in parts this subchapter. 174, 175, 176, and 177 of this subchapter. (2) Function-specific training. (i) Each hazmat employee must be provided § 172.701 Federal-State relationship. function-specific training concerning This subpart and the parts referenced requirements of this subchapter, or ex in § 172.700(c) prescribe minimum train emptions or special permits issued ing requirements for the transpor under subchapter A of this chapter, tation of hazardous materials. For that are specifically applicable to the motor vehicle drivers, however, a State functions the employee performs. may impose more stringent training (ii) As an alternative to function-spe requirements only if those require cific training on the requirements of ments— this subchapter, training relating to (a) Do not conflict with the training the requirements of the ICAO Tech requirements in this subpart and in nical Instructions and the IMDG Code part 177 of this subchapter; and may be provided to the extent such (b) Apply only to drivers domiciled in training addresses functions authorized that State. by subpart C of part 171 of this sub chapter. § 172.702 Applicability and responsi (3) Safety training. Each hazmat em bility for training and testing. ployee shall receive safety training (a) A hazmat employer shall ensure concerning— that each of its hazmat employees is (i) Emergency response information trained in accordance with the require required by subpart G of part 172; ments prescribed in this subpart. (ii) Measures to protect the employee (b) Except as provided in from the hazards associated with haz §172.704(c)(l), a hazmat employee who ardous materials to which they may be performs any function subject to the exposed in the work place, including 394 Pipeline and Hazardous Materials Safety Admin., DOT § 172.704 specific measures the hazmat employer training components specified in para has implemented to protect employees graph (a) of this section. from exposure: and (c) Initial and recurrent training—(l) (iii) Methods and procedures for Initial training. A new hazmat em avoiding accidents, such as the proper ployee, or a hazmat employee who procedures for handling packages con changes job functions may perform taining hazardous materials. those functions prior to the completion (4) Security awareness training. No of training provided— later than the date of the first sched (i) The employee performs those uled recurrent training after March 25, functions under the direct supervision 2003, and in no case later than March of a properly trained and knowledge 24, 2006, each hazmat employee must able hazmat employee; and receive training that provides an (ii) The training is completed within awareness of security risks associated 90 days after employment or a change with hazardous materials transpor in job function. tation and methods designed to en (2) Recurrent training. A hazmat em hance transportation security. This ployee must receive the training re training must also include a compo quired by this subpart at least once nent covering how to recognize and re every three years. For in-depth secu spond to possible security threats. rity training required under paragraph After March 25, 2003, new hazmat em (a)(5) of this section, a hazmat em ployees must receive the security ployee must be trained at least once every three awareness training required by this years or, if the security plan for which paragraph within 90 days after employ training is required is ment. revised during the three-year recurrent training cycle, within 90 days of imple (5) In-depth security training. Each nientation of the revised plan. hazmat employee of person a required (3) Relevant Training. Relevant train security plan to have a in accordance ing received from a previous employer with I of this part who subpart handles or other source may be used to satisfy hazardous materials covered by the the requirements of this subpart pro plan, performs a regulated function re vided a current record of training is ob lated to the hazardous materials cov tained from hazmat employees’ pre ered by the plan, or is responsible for vious employer. implementing the plan must be trained (4) Compliance. Each hazmat em concerning the security plan and its ployer is responsible for compliance implementation. Security training with the requirements of this sub must include company security objec chapter regardless of whether the tives, organizational security struc training required by this subpart has ture, specific security procedures, spe been completed. cific security duties and responsibil (d) Recordkeeping. A record of current ities for each employee, and specific training, inclusive of the preceding actions to be taken by each employee three years, in accordance with this in the event of a security breach. section shall be created and retained (b) OSHA, EPA, and other training. by each hazmat employer for as long as Training conducted by employers to that employee is employed by that em comply with the hazard communica ployer as a hazmat employee and for 90 tion programs required by the Occupa days thereafter. The record shall in tional Safety and Health Administra clude: tion of the Department of Labor (29 (1) The hazmat employee’s name; CFR 1910.120 or 1910.1200) or the Envi (2) The most recent training comple ronmental Protection Agency (40 CFR tion date of the hazmat employee’s 311.1), or training conducted by em training; ployers to comply with security train (3) A description, copy, or the loca ing programs required by other Federal tion of the training materials used to or international agencies, may be used meet the requirements in paragraph (a) to satisfy the training requirements in of this section; paragraph (a) of this section to the ex (4) The name and address of the per tent that such training addresses the son providing the training; and 395 § 172.800 49 CFR Ch. I (10—1—10 Edition)
(5) Certification that the hazmat em motor vehicle, portable tank, tank car, ployee has been trained and tested, as or other bulk container. required by this subpart. (1) Any quantity of a Division 1.1, 1.2, (e) Limitations. The following limita or 1.3 material; tions apply: (2) A quantity of a Division 1.4, 1.5, or (1) A hazmat employee who repairs, 1.6 material requiring placarding in ac modifies, reconditions, or tests pack cordance with subpart F of this part; agings, as qualified for use in the (3) A large bulk quantity of Division transportation of hazardous materials, 2.1 material; and who does not perform any other (4) A large function subject to the requirements of bulk quantity of Division 2.2 material this subchapter, is not subject to the with a subsidiary hazard of 5.1; training requirement of paragraph (a) (3) of this section. (5) Any quantity of a material poi (2) A railroad maintenance-of-way sonous by inhalation, as defined in employee or railroad signalman, who §171.8 of this subchapter; does not perform any function subject (6) A large bulk quantity of a Class 3 to the requirements of this subchapter, material meeting the criteria for Pack is not subject to the training require ing Group I or II; ments of paragraphs (a) (2), (a) (4), or (7) A quantity of desensitized explo (a)(5) of this section. Initial training sives meeting the definition of Division for a railroad maintenance-of-way em 4.1 or Class 3 material requiring ployee or railroad signalman in accord placarding in accordance with subpart ance with this section must be com F of this part; pleted by October 1. 2006. (8) A large bulk quantity of a Divi [Arndt. 172—126, 57 FR 20952. May 15, 1992, as sion 4.2 material meeting the criteria amended by Amdt. 172-126, 58 FR 5851, Jan. for Packing Group I or II; 22, 1993; Amdt. 172—145, 60 FR 49110, Sept. 21, (9) A quantity of a Division 4.3 mate 1995: Amdt. 172—149, 61 FR 27173, May 30. 1996; rial requiring placarding in accordance 65 FR 50460, Aug. 18, 2000; 68 FR 14521. Mar. with subpart F of this part; 25, 2003; 70 FR 73164, Dec. 9, 2005; 73 FR 4716, Jan. 28, 2008; 73 FR 57005, Oct. 1, 2008; 75 FR (10) A large bulk quantity of a Divi 10988, Mar. 9, 20101 sion 5.1 material in Packing Groups I and II; perchlorates; or ammonium ni Subpart I—Safety and Security trate, ammonium nitrate fertilizers, or Plans ammonium nitrate emulsions, suspen sions, or gels; (11) Any quantity of organic per SouRce: 68 Mar. FR 14521, 25, 2003, unless oxide, Type B, liquid otherwise noted. or solid, tempera ture controlled; § 172.800 Purpose and applicability. (12) A large bulk quantity of Division (a) Purpose. This subpart prescribes 6.1 material (for a material poisonous requirements for development and im by inhalation see paragraph (5) above); plementation of plans to address secu (13) A select agent or toxin regulated rity risks related to the transportation by the Centers for Disease Control and of hazardous materials in commerce. Prevention under 42 CFR part 73 or the (b) Applicability. Each person who of United States Department of Agri fers for transportation in commerce or culture under 9 CFR part 121; transports in commerce one or more of (14) A quantity of uranium the following hazardous materials hexafluoride requiring placarding must develop and adhere to a transpor under § 172.505(b); tation security plan for hazardous ma (15) International Atomic Energy terials that conforms to the require Agency (IAEA) Code of Conduct Cat ments of this subpart. As used in this egory 1 and 2 materials including High section, “large bulk quantity” refers to way Route Controlled quantities as de a quantity greater than 3,000 kg (6,614 fined in 49 CFR 173.403 or known as pounds) for solids or 3,000 liters (792 radionuclides in forms listed as RAM gallons) for liquids and gases in a sin QC by the Nuclear Regulatory Commis gle packaging such as a cargo tank sion;
396 Pipeline and Hazardous Materials Safety Admin., DOT § 172.804
(16) A large bulk quantity of Class 8 origin to destination, including ship material meeting the criteria for Pack ments stored incidental to movement. ing Group I. (b) The security plan must also in (c) Exceptions. Transportation activi clude the following: ties of a farmer, who generates less (1) Identification by job title of the than $500,000 annually in gross receipts senior management official responsible from the sale of agricultural commod for overall development and implemen ities or products, are not subject to tation of the security plan; this subpart if such activities are: (2) Security duties for each position (1) Conducted by highway or rail; or department that is responsible for (2) In direct support of their farming implementing the plan or a portion of operations; and the plan and the process of notifying (3) Conducted within a 150-mile ra employees when specific elements of dius of those operations. the security plan must be imple mented; and [68 FR 14521, Mar. 25, 2003, as amended at 70 (3) A plan for training hazmat em FR 73164, Dec. 9, 71 FR 32258, June 2, 2005; ployees in accordance with 172.704 2006; 75 FR 10988, Mar. 9, 2010; 75 FR 53597, § Sept. 1, 2010] (a) (4) and (a) (5) of this part. (c) The security plan, including the § 172.802 Components of a security transportation security risk assess plan. ment developed in accordance with (a) The security plan must include an paragraph (a) of this section, must be assessment of transportation security in writing and must be retained for as risks for shipments of the hazardous long as it remains in effect. The secu materials listed in § 172.800, including rity plan must be reviewed at least an site-specific or location-specific risks nually and revised and/or updated as associated with facilities at which the necessary to reflect changing cir hazardous materials listed in § 172.800 cumstances. The most recent version of are prepared for transportation, stored, the security plan, or portions thereof, or unloaded incidental to movement, must be available to the employees and appropriate measures to address who are responsible for implementing the assessed risks. Specific measures it, consistent with personnel security put into place by the plan may vary clearance or background investigation commensurate with the level of threat restrictions and a demonstrated need at a particular time. At a minimum, a to know. When the security plan is up security plan must include the fol dated or revised, all employees respon lowing elements: sible for implementing it must be noti (1) Personnel security. Measures to fied and all copies of the plan must be confirm information provided by job maintained as of the date of the most applicants hired for positions that in recent revision. volve access to and handling of the haz (d) Each person required to develop ardous materials covered by the secu and implement a security plan in ac rity plan. Such confirmation system cordance with this subpart must main must be consistent with applicable tain a copy of the security plan (or an Federal and State laws and require electronic file thereof) that is acces ments concerning employment prac sible at, or through, its principal place tices and individual privacy. of business and must make the security (2) Unauthorized access. Measures to plan available upon request, at a rea address the assessed risk that unau sonable time and location, to an au thorized persons may gain access to thorized official of the Department of the hazardous materials covered by the Transportation or the Department of security plan or transport conveyances Homeland Security. being prepared for transportation of [68 FR 14521, Mar. 25, 2003, as amended at 75 the hazardous materials covered by the FR 10989, Mar. 9, 2010] security plan. (3) En route security. Measures to ad § 172.804 Relationship to other Federal dress the assessed security risks of requirements. shipments of hazardous materials cov To avoid unnecessary duplication of ered by the security plan en route from security requirements, security plans 397 § 172.820 49 CFR Ch. I (10—I—la Edition) that conform to regulations, standards, lected as required by paragraph (b) of protocols, or guidelines issued by other this section. The route analysis must Federal agencies, international organi be in writing and include the factors zations, or industry organizations may contained in Appendix D to this part, be used to satisfy the requirements in as applicable. this subpart, provided such security (1) The safety and security risks plans address the requirements speci present must be analyzed for the route fied in this subpart. and railroad facilities along the route. For purposes of this section, railroad § 172.820 Additional planning require ments for transportation by rail. facilities are railroad property includ ing, but not limited to, classification (a) General. Each rail carrier trans and switching yards, storage facilities, porting in commerce one or more of and non-private sidings. This term does the following materials is subject to not include an offeror’s facility, pri the additional safety and security plan vate track, private siding, or con ning requirements of this section: signee’s facility. (1) More than 2,268 kg (5,000 ibs) in a (2) In performing the analysis single carload of a Division 1.1, 1.2 or re quired by this 1.3 explosive; paragraph, the rail car rier must seek relevant information (2) A quantity of a material poi from state, local, and sonous by inhalation in a single bulk tribal officials, packaging; or as appropriate, regarding security risks (3) A highway route-controlled quan to high-consequence targets along or in tity of a Class 7 (radioactive) material, proximity to the route(s) utilized. If a carrier as defined in § 173.403 of this sub rail is unable to acquire rel chapter. evant information from state, local, or (b) Commodity data. Not later than 90 tribal officials, then it must document days after the end of each calendar that in its analysis. For purposes of year, a rail carrier must compile com this section, a high-consequence target modity data for the previous calendar means a property, natural resource, lo year for the materials listed in para cation, area, or other target designated graph (a) of this section, except that by the Secretary of Homeland Security for calendar year 2008, data may be that is a viable terrorist target of na compiled for the 6-month period begin tional significance, the attack of which ning July 1, 2008. The following stipula by railroad could result in catastrophic tions apply to data collected: loss of life, significant damage to na (1) Commodity data must be col tional security or defense capabilities, lected by route, a line segment or se or national economic harm. ries of line segments as aggregated by (d) Alternative route analysis. (1) For the rail carrier. Within the rail carrier each calendar year, a rail carrier must selected route, the commodity data identify practicable alternative routes must identify the geographic location over which it has authority to operate, of the route and the total number of if an alternative exists, as an alter shipments by UN identification number native route for each of the transpor for the materials specified in para tation routes analyzed in accordance graph (a) of this section. with paragraph (c) of this section. The (2) A carrier may compile commodity carrier must perform a safety and secu data, by UN number, for all Class 7 ma rity risk assessment of the alternative terials transported (instead of only routes for comparison to the route highway route controlled quantities of analysis prescribed in paragraph (c) of Class 7 materials) and for all Division this section. The alternative route 6.1 materials transported (instead of analysis must be in writing and include only Division 6.1 poison inhalation haz the criteria in Appendix D of this part. ard materials). When determining practicable alter (c) Rail transportation route analysis. native routes, the rail carrier must For each calendar year, a rail carrier consider the use of interchange agree must analyze the safety and security ments with other rail carriers. The risks for the transportation route(s), written alternative route analysis identified in the commodity data col must also consider: 398 Pipeline and Hazardous Materials Safety Admin., DOT § 172.820 (i) Safety and security risks pre (1) A rail carrier may complete the sented by use of the alternative initial process by September 1, 2009, route(s); using data for the six month period (ii) Comparison of the safety and se from July 1, 2008 to December 31, 2008; curity risks of the alternative(s) to the or primary rail transportation route, in (ii) A rail carrier may complete the cluding the risk of a catastrophic re initial process by March 31, 2010, using lease from a shipment traveling along data for all of 2008, provided the rail each route; carrier notifies the FRA Associate Ad (iii) Any remediation or mitigation ministrator of Safety in writing by measures implemented on the primary September 1, 2009 that it has chosen or alternative route(s); and this second option. (iv) Potential economic effects of (2) Beginning in 2010, the rail trans using the alternative route(s), includ portation route analysis, alternative ing but not limited to the economics of route analysis, and route selection the commodity, route, and customer process required under paragraphs (c), relationship. (d), and (e) of this section must be com pleted no later than the end of the cal (2) In performing the analysis re endar year following the year to which quired by this paragraph, the rail car the analyses apply. rier should seek relevant information (3) The initial analysis and route se from state, local, and tribal officials, lection determinations required under as appropriate, regarding security risks paragraphs (c), (d), and (e) of this sec high-consequence targets along or to in tion must include a comprehensive re proximity to the alternative routes. If view of the entire system. Subsequent a rail carrier determines that it is not analyses and route selection deter appropriate to seek such relevant in minations required under paragraphs formation, then it must explain its rea (c), (d), and (e) of this section must in soning for that determination in its clude a comprehensive, system-wide re analysis. view of all operational changes, infra (e) Route Selection. A carrier must use structure modifications, traffic adjust the analysis performed as required by ments, changes in the nature of high- paragraphs (c) and (d) of this section to consequence targets located along, or select the route to be used in moving in proximity to, the route, and any the materials covered by paragraph (a) other changes affecting the safety or of this section. The carrier must con security of the movements of the mate sider any remediation measures imple rials specified in paragraph (a) of this mented on a route. Using this process, section that were implemented during the carrier must at least annually re the calendar year. view and select the practicable route (4) A rail carrier need not perform a posing the least overall safety and se rail transportation route analysis, al curity risk. The rail carrier must re ternative route analysis, or route se tain in writing all route review and se lection process for any hazardous ma lection decision documentation and re terial other than the materials speci strict the distribution, disclosure, and fied in paragraph (a) of this section. availability of information contained (g) Rail carrier point of contact on rout in the route analysis to covered per ing issues. Each rail carrier must iden sons with a need-to-know, as described tify a point of contact (including the in parts 15 and 1520 of this title. This name, title, phone number and e-mail documentation should include, but is address) on routing issues involving not limited to, comparative analyses, the movement of materials covered by charts, graphics or rail system maps. this section in its security plan and (f) Completion of route analyses. (1) provide this information to: Rail carriers have the following op (I) State and/or regional Fusion Cen tions for completing the initial route ters that have been established to co analysis, alternative route analysis, ordinate with state, local and tribal of and route selection process required ficials on security issues and which are under paragraphs (c), (d), and (e) of this located within the area encompassed section: by the rail carrier’s rail system; and 399 § 172.822 49 CR? Ch. I (10—1—10 Edition)
(2) State, local, and tribal officials in (c), (d), (e), and (f) of this section to jurisdictions that may be affected by a covered persons with a need-to-know, rail carrier’s routing decisions and who as described in parts 15 and 1520 of this directly contact the railroad to discuss title. routing decisions. (j) Compliance and enforcement. If the (h) Storage, delays in transit, and noti carrier’s route selection documenta fication. With respect to the materials tion and underlying analyses are found specified in paragraph (a) of this sec to be deficient, the carrier may be re tion, each rail carrier must ensure the quired to revise the analyses or make safety and security plan it develops changes in route selection. If DOT finds and implements under this subpart in that a chosen route is not the safest cludes all of the following: and most secure practicable route (1) A procedure under which the rail available, the FRA Associate Adminis carrier must consult with offerors and trator for Safety, in consultation with consignees in order to develop meas TSA, may require the use of an alter ures for minimizing, to the extent native route. Prior to making such a practicable, the duration of any stor determination, FRA and TSA will con- age of the material incidental to move suit with the Surface Transportation ment (see § 171.8 of this subchapter). Board (STB) regarding whether the (2) Measures to prevent unauthorized contemplated alternative route(s) access to the materials during storage would be economically practicable. or delays in transit. [73 FR 20771, April 16, 2008, as amended at 73 (3) Measures to mitigate risk to pop FR 72193, Dec. 26, 2008] ulation centers associated with in- transit storage. § 172.822 Limitation on actions by (4) Measures to be taken in the event states, local governments, and In of an escalating threat level for mate dian tribes. rials stored in transit. A law, order, or other directive of a (5) Procedures for notifying the con state, political subdivision of a state, signee in the event of a significant or an Indian tribe that designates, lim delay during transportation; such noti its, or prohibits the use of a rail line fication must be completed within 48 (other than a rail line owned by a hours after the carrier has identified state, political subdivision of a state, the delay and must include a revised or an Indian tribe) for the transpor delivery schedule. A significant delay tation of hazardous materials, includ is one that compromises the safety or ing, but not limited to, the materials security of the hazardous material or specified in §172.820(a), is preempted. 49 delays the shipment beyond its normal U.S.C. 5125, 20106. expected or planned shipping time. No [73 FR 20772, April 16, 2008] tification should be made by a method acceptable to both the rail carrier and APPENDIX A TO PART 172—OFFICE OF consignee. HAZARDOUS MATERIALS TRANSPOR (i) Recordkeeping. (1) Each rail carrier TATION COLOR TOLERANCE CHARTS must maintain a copy of the informa AND TABLES tion specified in paragraphs (b), (c), (d), (e), and (f) of this section (or an elec The following are Munsell notations and tronic image thereof) that is accessible Commission Internationale de L’Eclairage (CIE) coordinates which at, or through, its principal describe the Office place of of Hazardous Materials Transportation Label business and must make the record and Placard Color Tolerance Charts in tables available upon request, at a reasonable 1 and 2, and the CIE coordinates for the color time and location, to an authorized of tolerances specified in table 3. Central colors ficial of the Department of Transpor and tolerances described in table 2 approxi tation or the Department of Homeland mate those described in table 1 while allow Security. Records must be retained for ing for differences in production methods a minimum of two years. and materials used to manufacture labels and placards surfaced (2) Each rail carrier must with printing inks. restrict the Primarily, the color charts based on table 1 distribution, disclosure, and avail are for label or placard colors applied as ability of information collected or de opaque coatings such as paint, enamel or veloped in accordance with paragraphs plastic, whereas color charts based on table 400 Pipeline and Hazardous Materials Safety Admin., DOT Pt. 172, App. A
2 are intended for use with labels and plac- that the colors of labels printed directly on ards surfaced only with inks, package surfaces are outside the table I or 2 For labels printed directly on packaging tolerances, a spectrophotonieter or other in- surfaces, table 3 may be used, although com- strumentation may be required to insure pliance with either table 1 or table 2 5 51 compliance with table 3. cient. However, if visual reference indicates
TABLE 1—SPECIFICATIONS FOR COLOR TOLERANCE CHARTS FOR USE WITH LABELS AND PLACARDS SURFACED WITH PAINT, LACQUER, ENAMEL, PLASTIC, OTHER OPAQUE COATINGS, OR INK I
CIE data for source C Color Munsell notations Y x y
Red: Central color 7.5R 4.0/14 12.00 .5959 .3269 Orange 8.5R 4.0/14 12.00 .6037 .3389 Purple and vivid 6.5R 4.0/14 12.00 .5869 .3184 Grayish 7.5R4.O/12 12.00 .5603 .3321 Vivid 7.5R4.O/16 12.00 .6260 .3192 Light 7.5R 4.5/14 15.57 .5775 .3320 Dark 7. 5R 3.5/14 09.00 .6226 .3141 Orange: Central color 5.OYR 6.0/15 30.05 .5510 .4214 Yellow and Grayish 6.25YR 6.0/15 30.05 .5452 .4329 Red and vivid 3.75YR 6.0/15 30,05 .5552 .4091 Grayish 5.DYR 6.0/13 30.05 .5311 .4154 Vivid 5.OYR 6.0/16 30.05 .5597 .4239 Light 5.OYR 6.5/15 36.20 .5427 .4206 Dark 5.OYR 5.5/15 24.58 .5606 .4218 Yellow: Central color 5.OY 8.0/12 59.10 .4562 .4788 Green 6.5Y 8.0/12 59.10 .4498 .4865 Orange and vivid 3.5Y 8.0/12 59.10 .4632 .4669 Grayish 5.OY 8.0/10 59.10 .4376 .4601 Vivid 5.OY 8.0/14 59.10 .4699 .4920 Light 5.OY 8.5/12 68.40 .4508 .4754 Dark 5.OY 7.5/12 50.68 .4620 .4823 Green: Central color 7.5G 4.0/9 12.00 .2111 .4121 Bluish 0.5BG 4.0/9 12.00 .1974 .3809 Green-yellow 5.00 4.0/9 12.00 .2237 .4399 Grayish A 7,5G 4.0/7 12.00 .2350 .3922 Grayish B2 7.5G 4.0/6 12.00 .2467 .3822 Vivid 7.5G4.0/11 12.00 .1848 .4319 Light 7.5G 4.5/9 15.57 .2204 .4060 Dark 7.5G 3.5/9 09.00 .2027 .4163 Blue: Central color 2.5PB 3.5/10 09.00 .1691 .1744 Purple 4.SPB 3.5/10 09.00 .1796 .1711 Green and vivid bOB 3.5/10 09.00 .1557 .1815 Grayish 2.5PB 3.5/8 09.00 .1888 .1964 Vivid 2.5PB 3.5/12 09.00 .1516 .1547 Light 2.5PB 4.0/10 12.00 .1805 .1888 Dark 2.5PB 3.0/10 06.55 .1575 .1600 Purple: Central color lOOP 4.5/10 15.57 .3307 .2245 Reddish purple 2.5RP 4.5/10 15.57 .3584 .2377 Blue purple 7,5P 4.5/10 15.57 .3068 .2145 Reddish gray lOOP 4.5/8 15.57 .3280 .2391 Gray2 lOOP 4.5/6.5 15.57 .3254 .2519 Vivid lOOP 4.5/12 15.57 .3333 .2101 Light lOOP 5.0/10 19.77 .3308 .2328 Dark lOOP 4.0/10 12.00 .3306 .2162 1 Maximum chrome is not limited. 2 For the colors green and purple, the minimum saturation (chrome) limits for porcelain enamel on metal are lower than for most other surface coatings. Therefore, the minimum chrome limits of these two colors as displayed on the Charts for compari son to porcelain enamel on metal is low, as shown for green (grayish B) and purple (gray). NOTE: CIE=Commission Internationale de L’Eclairage.
401 Pt. 172, App. A 49 CFR Ch. 1(10—1—10 Edition)
TABLE 2—SPEcIFIcATI0Ns FOR COLOR TOLERANcE CHARTS FOR USE WITH LABELS AND PLAcARDS SURFACED WITH INK
CIE data for source C Color/senes Munsell notation Y 5 y Red: Central series: Central color 6.8R 4.47/12.8 15.34 .5510 .3286 Grayish 7.2R 4.72/12.2 17.37 .5368 .3348 Purple 6.4R 4.49/12.7 15.52 .5442 .3258 Purple and vivid 6.1R4.33/13.1 14.25 .5529 .3209 Vivid 6.7R 4.29/13.2 13.99 .5617 .3253 Orange 7.3R 4.47/12.8 15.34 .5572 .3331 Orange and grayish 7.65R 4.70/12.4 17.20 .5438 .3382 Light series: Light 7.OR 4.72/1 3.2 17.32 .5511 .3322 Light and orange 7.4R 4.98/12.6 19.38 .5365 .3382 Light and purple 6.6R 4.79/12.9 17.94 .5397 .3289 Dark series: Dark A 6.7R 4.19/12.5 13.30 .5566 .3265 Dark B 7.OR 4.25/12.35 13.72 .5522 .3294 Dark and purple 7.5R 4.23/12.4 13.58 .5577 .3329 Orange: Central series: Central color 5.OYR 6.10/12.15 31.27 .5193 .4117 Yellow and grayish A 5.8YR 6.22/11.7 32.69 .5114 .4155 Yellow and grayish B 6.1YR 6.26/11.85 33.20 .5109 .4190 Vivid 5.1YR 6.07/12.3 30.86 .5226 .4134 Red and vivid A 3.9YR 5.87/1 2.75 28.53 .5318 .4038 Red and vivid B 3.6YR 5.91/1 2.6 29.05 .5291 .4021 Grayish 4.9YR 6.10/11.9 31.22 .5170 .4089 Light series: Light and vivid A 5.8YR 8.78/12.7 39.94 .5120 .4177 Light and yellow 6.OYR 6.80/12.8 40.20 .5135 .4198 Light and vivid B 4.9YR 6.60/12.9 37.47 .5216 .4126 Dark series: Dark and yellow 5.8YR 5.98/11.0 29.87 .5052 .4132 Dark A 5.1YR 5.80/11.1 27.80 .5127 .4094 Dark B 5.OYR 5.80/1 1.0 27.67 .5109 .4068 Yellow: Central series: Central color 4.3Y 7.87/1 0.3 56.81 .4445 .4589 Vivid A 4.5Y 7.82/1 0.8 55.92 .4503 .4658 Vivid B 3.3Y 7.72/11.35 54.24 .4612 .4624 Vivid and orange 3.2Y 7.72/10.8 54.25 .4576 .4572 Grayish A 4.1Y 7.95/9.7 58.18 .4380 .4516 Grayish B 5.1Y 8.06/9.05 60.12 .4272 .4508 Green-yellow 5.2Y 7.97/9.9 58.53 .4356 .4605 Light series: Light 5.4Y 8.59/105 70.19 .4351 .4628 Light and green-yellow 5.4Y 8.56/11.2 69.59 .4414 .4692 Light and vivid 4.4Y 8.45/11.4 67.42 .4490 .4662 Dark series: Dark and green-yellow 4.4Y 7.57/9.7 51.82 .4423 .4562 Dark and orange A 3.4Y 7.39/1 0.4 48.86 .4584 .4590 Dark and orange B 3.5Y 7.41/1 0.0 49.20 .4517 .4544 Green: Central series: Central color 9.75G 4.26/7.75 13.80 .2214 .3791 Grayish lOG 4.46/7.5 15.25 .2263 .3742 Blue A 1 .4BG 4.20/7.4 13.36 .2151 .3625 Blue B I .OBG 4.09/7.75 12.60 .2109 .3685 Vivid 8.4G 4.09/8.05 12.59 .2183 .3954 Vivid green-yellow 7.OG 4.23/8.0 13.54 .2292 .4045 Green-yellow 7.85G 4.46/7.7 15.23 .2313 .3914 Light series: Light and vivid 9.5G 4.45/8.8 15.21 .2141 .3863 Light and blue 0.2BG 4.31/8.8 14.12 .2069 .3814 Light and green-yellow 8.3G 4.29/9.05 14.01 .2119 .4006 Dark series: Dark and green-yellow 7.1G 4.08/7.1 12.55 .2354 .3972 Dark and grayish 9.5G 4.11/6.9 12.70 .2282 .3764 Dark 8.5G 3.97/7.2 11.78 .2269 .3874
402 Pipeline and Hazardous Materials Safety Admin., DOT Pt. 172, App. B
TABLE 2—SPEcIFIcATIoNs FOR COLOR TOLERANCE CHARTS FOR USE WITH LABELS AND PLACARDS SURFACED WITH INK—Continued
CIE data for source C Color/series Munsell notation Y x y Blue: Central series:
Central color 3.5PB 3.94/9.7 11.58 .1885 .1911
Green and grayish A ...... 2.OPB 4.35/8.7 ...... 14.41 .1962 .2099
Green and grayish B ...... 1.7PB 4.22/9.0 13.50 .1898 .2053 Vivid 2.9PB 3.81/9.7 10.78 .1814 .1852 Purple and vivid A 4.7PB 3.53/10.0 9.15 .1817 .1727 Purple and vivid B 5.OPB 3.71/9.9 10.20 .1888 .1788 Grayish 3.75PB 4.03/9.1 12.17 .1943 .1961 Light series: Light and green A 1.7PB 4.32/9.2 14.22 .1904 .2056 Light and green B 1.5PB 4.11/9.6 12.72 .1815 .1971 Light and vivid 3.2PB 3.95/10.05 11.70 .1831 .1868 Dark series: Dark and grayish 3.9PB 4.01/8.7 12.04 .1982 .1992 Dark and purple A 4.8P8 3.67/9.3 9.95 .1918 .1831 Dark and purple B 5.2PB 3.80/9.05 10.76 .1985 .1885 Purple: Central series: Central color 9.5P 4.71/11.3 17.25 .3274 .2165 Red 1.ORP 5.31/10.8 22.70 .3404 .2354 Red and vivid A 1.4RP 5.00/11.9 19.78 .3500 .2274 Red and vivid B 0.2RP 4.39/12.5 14.70 .3365 .2059 Vivid 8.OP 4.04/12.0 12.23 .3098 .1916 Blue 7.OP 4.39/10.8 14.71 .3007 .2037 Grayish 8.8P 5.00/10.3 19.73 .3191 .2251 Light series: Light and red A 0.85RP 5.56/1 1.1 25.18 .3387 .2356 Light and red B 1.1RP 5.27/12.3 22.27 .3460 .2276 Light and vivid 9.2P 4.94/11.95 19.24 .3247 .2163 Dark series: Dark and grayish 9.6P 4.70/10.9 17.19 .3283 .2204 Dark and vivid 8.4P 4.05/11.6 12.35 .3144 .1970 Dark and blue 7.5P 4.32/10.5 14.19 .3059 .2078
TABLE 3—SPECIFICATION FOR COLORS FOR USE WITH LABELS PRINTED ON PACKAGINGS SURFACES
CIE data for source C Red Orange Yellow Green Bke Purple
5 .424 .460 .417 .228 .200 .377 y .306 .370 .392 .354 .175 .205 x .571 .543 .490 .310 .255 .377 y .306 .400 .442 .354 .250 .284 x .424 .445 .390 .228 .177 .342 y .350 .395 .430 .403 .194 .205 x .571 .504 .440 .310 .230 .342 y .350 .430 .492 .403 .267 .284 Y (high> 23.0 41.6 72.6 20.6 15.9 21.2 Y (low) 7.7 19.5 29.1 7.4 6.5 8.2
[Amdt. 172—50, 44 FR 9757, Feb. 15, 1979; Amdt. 172-50, 44 FR 10984, Feb. 26, 1979, as amended by Amdt. 172—50, 44 FR 22467, Apr. 16, 1979; 50 FR 45731, Nov. 1, 1985; Amdt. 172-127, 59 FR 49133, Sept. 26, 1994]
APPENDIx B TO PART 172—TREFOIL materials must conform to the design and SYMBOL size requirements of this appendix. 2. RADIOACTIVE labels and placards that 1. Except as provided in paragraph 2 of this were printed prior to April 1, 1996, in con appendix, the trefoil symbol required for RA formance with the requirements of this sub DIOACTIVE labels and placards and required chapter in effect on March 30, 1996, may con to be marked on certain packages of Class 7 tinue to be used.
403 Pt. 172, App. B 49 CFR Ch. I (10—1—10 Edition) 6O0
60
3
1=Radius of Circle— 3=5 radii for markings and labels Minimum dimensions 4½ radii for placards. 4 mm (0.16 inch) for markings and labels 12.5 mm (0.5 inch) for placards [60 FR 50306, Sept. 28, 1995, as amended by 2=l’/z Radii 172—143, 61 FR 20750, May 8, 1996]
404 Pipeline and Hazardous Materials Safety Admin., DOT Pt. 172, App. D
APPENDIx C TO PART 172—DIMENSIONAL SPECIFICATIONS FOR RECOMMENDED PLACARD HOLDER
Legend in. mm. 1/4 6.3 3/8 9.5 1/2 12.7 3/4 19 11/2 38 2318 60 1/4” on all 25/8 67 4 sides 23/16 55 2 5/16 58 213/16 71 10314 273 121/2 317 Note: Round to nearest mm.
Placard Outhne.
APPENDIX D TO PART 172—RAIL RISK description of the threats, identified ANALYSIS FACTORS vulnerabilities, and mitigation measures im plemented to address identified A. This appendix sets forth the minimum vulnerabilities. criteria that must be considered by rail car B. In evaluating the safety and security of riers when performing the safety and secu hazardous materials transport, selection of rity risk analyses required by §172.820. The the route for transportation is critical. For risk analysis to be performed may be quan the purpose of rail transportation route titative. qualitative, or a combination of analysis, as specified in §172.820(c) and (d), a both. In addition to clearly identifying the route may include the point where the car hazardous material(s) and route(s) being ana rier takes possession of the material and all lyzed, the analysis must provide a thorough track and railroad facilities up to the point
405 Pt. 173 49 CFR Ch. 1(10—1—10 Edition)
where the material is relinquished to an 24. Past incidents; other entity. Railroad facilities are railroad 25. Overall times in transit; property including, but not limited to, clas 26. Training and skill level of crews; and sification and switching yards, storage fa 27. Impact on rail network traffic and con cilities, and non-private sidings; however, gestion. they do not include an offeror’s facility, pri [73 FR 20772, April 16, vate track, private siding, or consignee’s fa 2008] cility. Each rail carrier must use best efforts to communicate with its shippers, con PART 173—SHIPPERS—GENERAL RE signees, and interlining partners to ensure QUIREMENTS FOR SHIPMENTS the safety and security of shipments during all stages of transportation. AND PACKAGINGS C. Because of the varying operating envi ronments and interconnected nature of the Subpart A—General rail system, each carrier must select and document the analysis method/model used Sec. and identify the routes to be analyzed. 173.1 Purpose and scope. D. The safety and security risk analysis 173.2 Hazardous materials classes and index must consider current data and information to hazard class definitions. as well as changes that may reasonably be 173.2a Classification of a material having anticipated to occur during the analysis more than one hazard. year. Factors to be considered in the per 173.3 Packaging and exceptions. formance of this safety and security risk 173.4 Small quantity exceptions. analysis include: 173.4a Excepted quantities. I. Volume of hazardous material trans 173.5 Agricultural operations. ported; l73.5a Oilfield service vehicles and mechan 2. Rail traffic density; ical displacement meter provers. 3. Trip length for route; l73.5b Portable and mobile refrigeration 4. Presence and characteristics of railroad systems, facilities; 173.6 Materials of trade exceptions, 5. Track type, class, and maintenance 173.7 Government operations and materials. schedule; 173.8 Exceptions for non-specification pack 6. Track grade and curvature; agings used in intrastate transportation. 7. Presence or absence of signals and train 173.9 Transport vehicles or freight con control systems along the route (“dark” tainers containing lading which has been versus signaled territory); fumigated. 8. Presence or absence of wayside hazard 173.10 Tank car shipments. detectors; 173.12 Exceptions for shipment of waste ma 9. Number and types of grade crossings; terials. 10. Single versus double track territory; 173.13 Exceptions for Class 3, Divisions 4.1, 11. Frequency and location of track turn 4.2, 4.3, 5.1, 6.1, and Classes 8 and 9 mate outs; rials. 12. Proximity to iconic targets; 13. Environmentally sensitive or signifi Subpart B—Preparation of Hazardous cant areas; Materials for Transportation 14. Population density along the route; 15. Venues along the route (stations, 173.21 Forbidden materials and packages. events, places of congregation); 173.22 Shipper’s responsibility, 16. Emergency response capability along 173.22a Use of packagings authorized under the route; special permits. 17. Areas of high consequence along the 173.23 Previously authorized packaging. route, including high consequence targets as 173.24 General requirements for packagings defined in §172.820(c); and packages. 18. Presence of passenger traffic along 173.24a Additional general requirements for route (shared track); non-bulk packagings and packages. 19. Speed of train operations; 173.24b Additional general requirements for 20. Proximity to en-route storage or repair bulk packagings. facilities; 173.25 Authorized packagings and over- 21. Known threats, including any non-pub packs. lic threat scenarios provided by the Depart 173.26 Quantity limitations. ment of Homeland Security or the Depart 173.27 General requirements for transpor ment of Transportation for carrier use in the tation by aircraft. development of the route assessment; 173.28 Reuse, reconditioning and remanufac 22. Measures in place to address apparent ture of packagings. safety and security risks; 173.29 Empty packagings. 23. Availability of practicable alternative 173.30 Loading and unloading of transport routes; vehicles.
406