132 Subpart A—General Subpart B—Table of Hazardous Materials
Total Page:16
File Type:pdf, Size:1020Kb
Load more
Recommended publications
-
Transport of Dangerous Goods
ST/SG/AC.10/1/Rev.16 (Vol.I) Recommendations on the TRANSPORT OF DANGEROUS GOODS Model Regulations Volume I Sixteenth revised edition UNITED NATIONS New York and Geneva, 2009 NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory, city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries. ST/SG/AC.10/1/Rev.16 (Vol.I) Copyright © United Nations, 2009 All rights reserved. No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the United Nations. UNITED NATIONS Sales No. E.09.VIII.2 ISBN 978-92-1-139136-7 (complete set of two volumes) ISSN 1014-5753 Volumes I and II not to be sold separately FOREWORD The Recommendations on the Transport of Dangerous Goods are addressed to governments and to the international organizations concerned with safety in the transport of dangerous goods. The first version, prepared by the United Nations Economic and Social Council's Committee of Experts on the Transport of Dangerous Goods, was published in 1956 (ST/ECA/43-E/CN.2/170). In response to developments in technology and the changing needs of users, they have been regularly amended and updated at succeeding sessions of the Committee of Experts pursuant to Resolution 645 G (XXIII) of 26 April 1957 of the Economic and Social Council and subsequent resolutions. -
The Detection and Determination of Esters
Louisiana State University LSU Digital Commons LSU Historical Dissertations and Theses Graduate School 1958 The etD ection and Determination of Esters. Mohd. Mohsin Qureshi Louisiana State University and Agricultural & Mechanical College Follow this and additional works at: https://digitalcommons.lsu.edu/gradschool_disstheses Recommended Citation Qureshi, Mohd. Mohsin, "The eD tection and Determination of Esters." (1958). LSU Historical Dissertations and Theses. 501. https://digitalcommons.lsu.edu/gradschool_disstheses/501 This Dissertation is brought to you for free and open access by the Graduate School at LSU Digital Commons. It has been accepted for inclusion in LSU Historical Dissertations and Theses by an authorized administrator of LSU Digital Commons. For more information, please contact [email protected]. Copright by Mohcl Mohsin Qureshi 1959 THE DETECTION AND DETERMINATION OF ESTERS A Dissertation Submitted to the Graduate Faculty of the Louisiana State University and Agricultural and Mechanical College in partial fulfillment of the requirements for the degree of Doctor of Philosophy in The Department of Chemistry by Mohd. Mohsin Qureshi M.Sc., Aligarh University, 1944 August, 1958 ACKNOWLEDGMENT The author wishes to express his sincere apprecia tion and gratitude to Dr. Philip W. West under whose guidance this research was carried out. He is grateful to Dr. James G. Traynham for sup plying him with a number of esters and for his many helpful suggestions. The financial support given to him by the Continental Oil Company is gratefully acknowledged. He offers his sincere thanks to Miss Magdalena Usategul for her valuable suggestions and her ungrudging help during the course of this investigation. Dr. Anil K. -
Calculating Heat of Formation Values of Energetic Compounds: a Comparative Study
University of Northern Iowa UNI ScholarWorks Faculty Publications Faculty Work 2016 Calculating Heat of Formation Values of Energetic Compounds: A Comparative Study Michael S. Elioff Millersville University of Pennsylvania Jordon Hoy University of Northern Iowa See next page for additional authors Let us know how access to this document benefits ouy Copyright ©2016 Michael S. Elioff, Jordan Hoy, and John A. Bumpus. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. This work is licensed under a Creative Commons Attribution 4.0 License. Follow this and additional works at: https://scholarworks.uni.edu/che_facpub Part of the Chemistry Commons Recommended Citation Elioff, Michael S.; Hoy, Jordon; and Bumpus, John A., "Calculating Heat of Formation Values of Energetic Compounds: A Comparative Study" (2016). Faculty Publications. 1. https://scholarworks.uni.edu/che_facpub/1 This Article is brought to you for free and open access by the Faculty Work at UNI ScholarWorks. It has been accepted for inclusion in Faculty Publications by an authorized administrator of UNI ScholarWorks. For more information, please contact [email protected]. Authors Michael S. Elioff, Jordon Hoy, and John A. Bumpus This article is available at UNI ScholarWorks: https://scholarworks.uni.edu/che_facpub/1 Hindawi Publishing Corporation Advances in Physical Chemistry Volume 2016, Article ID 5082084, 11 pages http://dx.doi.org/10.1155/2016/5082084 Research Article Calculating Heat of Formation Values of Energetic Compounds: A Comparative Study Michael S. Elioff,1 Jordan Hoy,2 and John A. -
Alphabetical Index of Substances and Articles
ALPHABETICAL INDEX OF SUBSTANCES AND ARTICLES - 355 - NOTES TO THE INDEX 1. This index is an alphabetical list of the substances and articles which are listed in numerical order in the Dangerous Goods List in Chapter 3.2. 2. For the purpose of determining the alphabetical order the following information has been ignored even when it forms part of the proper shipping name: numbers; Greek letters; the abbreviations “sec” and “tert”; and the letters “N” (nitrogen), “n” (normal), “o” (ortho) “m” (meta), “p” (para) and “N.O.S.” (not otherwise specified). 3. The name of a substance or article in block capital letters indicates a proper shipping name. 4. The name of a substance or article in block capital letters followed by the word “see” indicates an alternative proper shipping name or part of a proper shipping name (except for PCBs). 5. An entry in lower case letters followed by the word “see” indicates that the entry is not a proper shipping name; it is a synonym. 6. Where an entry is partly in block capital letters and partly in lower case letters, the latter part is considered not to be part of the proper shipping name. 7. A proper shipping name may be used in the singular or plural, as appropriate, for the purposes of documentation and package marking. - 356 - INDEX Name and description Class UN No. Name and description Class UN No. Accumulators, electric, see 4.3 3292 Acid mixture, nitrating acid, see 8 1796 8 2794 8 2795 Acid mixture, spent, nitrating acid, see 8 1826 8 2800 8 3028 Acraldehyde, inhibited, see 6.1 1092 ACETAL 3 1088 -
Pacs by Chemical Name (Mg/M3) (Pdf)
Table 4: Protective Action Criteria (PAC) Rev 25 based on applicable 60-minute AEGLs, ERPGs, or TEELs. Values are presented in mg/m3. August 2009 Table 4 is an alphabetical listing of the chemicals in the PAC data set. It provides Chemical Abstract Service Registry Numbers (CASRNs)1, PAC values, and technical information on the source of the PAC values. Table 4 presents all values for TEEL-0, PAC-1, PAC-2, and PAC-3 in mg/m3. The conversion of ppm to mg/m3 is calculated assuming 25 ºC and 760 mm Hg. The columns presented in Table 4 provide the following information: Heading Definition No. The ordered numbering of the chemicals as they appear in this alphabetical listing. Chemical Name The chemical name given to the PAC Development Team. CASRN The Chemical Abstract Service Registry Number for this chemical. TEEL-0 This is the threshold concentration below which most people will experience no adverse health effects. This PAC is always based on TEEL-0 because AEGL-0 or ERPG-0 values do not exist. PAC-1 Based on the applicable AEGL-1, ERPG-1, or TEEL-1 value. PAC-2 Based on the applicable AEGL-2, ERPG-2, or TEEL-2 value. PAC-3 Based on the applicable AEGL-3, ERPG-3, or TEEL-3 value. Source of PACs: Technical comments provided by the PAC development team that TEEL-0, PAC-1, indicate the source of the data used to derive PAC values. Future efforts PAC-2, PAC-3 are directed at reviewing, revising, and enhancing this information. -
Basic Description for Ground and Air Hazardous
BASIC DESCRIPTION FOR GROUND AND AIR GROUND AND AIR HAZARDOUS MATERIALS SHIPMENTS GROUND SHIPMENTS AIR SHIPMENTS SHIPMENTS HAZARD DOT DOT CLASS OR MAXIMUM EXEMPTION, GROUND EXEMPTION, HAZARDOUS MATERIALS DESCRIPTIONS DIVISION I.D. NUMBER LABEL(S) REQUIRED OR QUANTITY PER SPECIAL SERVICE TO LABEL(S) REQUIRED OR MAXIMUM NET CARGO SPECIAL NON-BULK AND PROPER SHIPPING NAME (Subsidiary if (ALSO MARK PACKING EXEMPTION, SPECIAL PERMIT INNER PERMIT CANADA EXEMPTION, SPECIAL PERMIT QUANTITY PER AIRCRAFT PERMIT SPECIAL EXCEPTIONS PACKAGING (ALSO MARK ON PACKAGE) applicable) ON PACKAGE) GROUP OR EXCEPTION RECEPTACLE OR 173.13 PERMITTED OR EXCEPTION PACKAGE** QUANTITY OR 173.13 PROVISIONS §173.*** §173.*** (1) (2) (3) (4) (5) (6) (7) (8) (9) (10) (11) (12) (13) (14) (15) Accellerene, see p-Nitrosodimethylaniline Accumulators, electric, see Batteries, wet etc Accumulators, pressurized, pneumatic or hydraulic (containing non-flammable gas), see Articles pressurized, pneumatic or hydraulic (containing non-flammable gas) FLAMMABLE FLAMMABLE Acetal 3 UN1088 II LIQUID * YES LIQUID * 5 L 150 202 FLAMMABLE Acetaldehyde 3 UN1089 I LIQUID YES Forbidden None 201 May not be regulated when shipped via UPS Acetaldehyde ammonia 9 UN1841 III ground YES CLASS 9 * 30 kg 30 kg 155 204 FLAMMABLE FLAMMABLE Acetaldehyde oxime 3 UN2332 III LIQUID * YES LIQUID * 25 L 150 203 CORROSIVE, CORROSIVE, Acetic acid, glacial or Acetic acid solution, FLAMMABLE FLAMMABLE A3, A6, with more than 80 percent acid, by mass 8 (3) UN2789 II LIQUID * YES LIQUID * 1 L A7, A10 154 202 Acetic -
Potentially Explosive Chemicals*
Potentially Explosive Chemicals* Chemical Name CAS # Not 1,1’-Diazoaminonaphthalene Assigned 1,1-Dinitroethane 000600-40-8 1,2,4-Butanetriol trinitrate 006659-60-5 1,2-Diazidoethane 000629-13-0 1,3,5-trimethyl-2,4,6-trinitrobenzene 000602-96-0 1,3-Diazopropane 005239-06-5 Not 1,3-Dinitro-4,5-dinitrosobenzene Assigned Not 1,3-dinitro-5,5-dimethyl hydantoin Assigned Not 1,4-Dinitro-1,1,4,4-tetramethylolbutanetetranitrate Assigned Not 1,7-Octadiene-3,5-Diyne-1,8-Dimethoxy-9-Octadecynoic acid Assigned 1,8 –dihydroxy 2,4,5,7-tetranitroanthraquinone 000517-92-0 Not 1,9-Dinitroxy pentamethylene-2,4,6,8-tetramine Assigned 1-Bromo-3-nitrobenzene 000585-79-5 Not 2,2',4,4',6,6'-Hexanitro-3,3'-dihydroxyazobenzene Assigned 2,2-di-(4,4,-di-tert-butylperoxycyclohexyl)propane 001705-60-8 2,2-Dinitrostilbene 006275-02-1 2,3,4,6- tetranitrophenol 000641-16-7 Not 2,3,4,6-tetranitrophenyl methyl nitramine Assigned Not 2,3,4,6-tetranitrophenyl nitramine Assigned Not 2,3,5,6- tetranitroso nitrobenzene Assigned Not 2,3,5,6- tetranitroso-1,4-dinitrobenzene Assigned 2,4,6-Trinitro-1,3,5-triazo benzene 029306-57-8 Not 2,4,6-trinitro-1,3-diazabenzene Assigned Not 2,4,6-Trinitrophenyl trimethylol methyl nitramine trinitrate Assigned Not 2,4,6-Trinitroso-3-methyl nitraminoanisole Assigned 2,4-Dinitro-1,3,5-trimethyl-benzene 000608-50-4 2,4-Dinitrophenylhydrazine 000119-26-6 2,4-Dinitroresorcinol 000519-44-8 2,5-dimethyl-2,5-diydroperoxy hexane 2-Nitro-2-methylpropanol nitrate 024884-69-3 3,5-Dinitrosalicylic acid 000609-99-4 Not 3-Azido-1,2-propylene glycol dinitrate -
Investigations of the Reactivity of Pyridine Carboxylic Acids with Diazodiphenylmethane in Protic and Aprotic Solvents. Part I
J. Serb. Chem. Soc. 70 (4) 557–567 (2005) UDC 547.821+547.595:543.878 JSCS – 3288 Original scientific paper Investigations of the reactivity of pyridine carboxylic acids with diazodiphenylmethane in protic and aprotic solvents. Part I. Pyridine mono-carboxylic acids ALEKSANDAR D. MARINKOVI]*#, SA[A @. DRMANI]#, BRATISLAV @. JOVANOVI]# and MILICA MI[I]-VUKOVI]# Department of Organic Chemistry, Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, P. O. Box 3503, 11120 Belgrade, Serbia and Montenegro (e-mail: [email protected]) (Received 14 May, revised 26 July 2004) Abstract: Rate constants for the reaction of diazodiphenylmethane with isomeric pyridine carboxylic acids were determined in chosen protic and aprotic solvents at 30 °C, using the well known UV spectrophotometric method. The values of the rate constants of the investigated acids in protic solvents were higher than those in aprotic solvents. The second order rate constants were correlated with solvent pa- rameters using the Kamlet-Taft solvatochromic equation in the form: log k =logk0 + sp*+aa + bb. The correlation of the obtained kinetic data were performed by means of multiple linear regression analysis taking appropriate solvent parameters. The signs of the equation coefficients were in agreement with the postulated reaction mechanism. The mode of the influence of the solvent on the reaction rate in all the investigated acids are discussed on the basis of the correlation results. Keywords: pyridine carboxylic acids, diazodiphenylmethane, rate constants, solvent parameters, protic and aprotic solvents. INTRODUCTION The relationship between the structure of carboxylic acids and their reactivity with diazodiphenylmethane (DDM) has been studied by many authors,1,2 with particular regard to the influence of the solvent. -
List of Reactive Chemicals
LIST OF REACTIVE CHEMICALS Chemical Prefix Chemical Name Reactive Reactive Reactive CAS# Chemical Chemical Chemical Stimulus 1 Stimulus 2 Stimulus 3 111-90-0 "CARBITOL" SOLVENT D 111-15-9 "CELLOSOLVE" ACETATE D 110-80-5 "CELLOSOLVE" SOLVENT D 2- (2,4,6-TRINITROPHENYL)ETHYL ACETATE (1% IN ACETONE & BENZENE S 12427-38-2 AAMANGAN W 88-85-7 AATOX S 40487-42-1 AC 92553 S 105-57-7 ACETAL D 75-07-0 ACETALDEHYDE D 105-57-7 ACETALDEHYDE, DIETHYL ACETAL D 108-05-4 ACETIC ACID ETHENYL ESTER D 108-05-4 ACETIC ACID VINYL ESTER D 75-07-0 ACETIC ALDEHYDE D 101-25-7 ACETO DNPT T 126-84-1 ACETONE DIETHYL ACETAL D 108-05-4 ACETOXYETHYLENE D 108-05-4 1- ACETOXYETHYLENE D 37187-22-7 ACETYL ACETONE PEROXIDE, <=32% AS A PASTE T 37187-22-7 ACETYL ACETONE PEROXIDE, <=42% T 37187-22-7 ACETYL ACETONE PEROXIDE, >42% T S 644-31-5 ACETYL BENZOYL PEROXIDE (SOLID OR MORE THAN 45% IN SOLUTION) T S 644-31-5 ACETYL BENZOYL PEROXIDE, <=45% T 506-96-7 ACETYL BROMIDE W 75-36-5 ACETYL CHLORIDE W ACETYL CYCLOHEXANE SULFONYL PEROXIDE (>82% WITH <12% WATER) T S 3179-56-4 ACETYL CYCLOHEXANE SULFONYL PEROXIDE, <=32% T 3179-56-4 ACETYL CYCLOHEXANE SULFONYL PEROXIDE, <=82% T 674-82-8 ACETYL KETENE (POISON INHALATION HAZARD) D 110-22-5 ACETYL PEROXIDE, <=27% T 110-22-5 ACETYL PEROXIDE, SOLID, OR MORE THAN 27% IN SOLUTION T S 927-86-6 ACETYLCHOLINE PERCHLORATE O S 74-86-2 ACETYLENE D 74-86-2 ACETYLENE (LIQUID) D ACETYLENE SILVER NITRATE D 107-02-08 ACRALDEHYDE (POISON INHALATION HAZARD) D 79-10-7 ACROLEIC ACID D 107-02-08 ACROLEIN, INHIBITED (POISON INHALATION HAZARD) D 107-02-08 ACRYLALDEHYDE (POISON INHALATION HAZARD) D 79-10-7 ACRYLIC ACID D 141-32-2 ACRYLIC ACID BUTYL ESTER D 140-88-5 ACRYLIC ACID ETHYL ESTER D 96-33-3 ACRYLIC ACID METHYL ESTER D Stimulus - Stimuli is the thermal, physical or chemical input needed to induce a hazardous reaction. -
Download (7Mb)
A Thesis Submitted for the Degree of PhD at the University of Warwick Permanent WRAP URL: http://wrap.warwick.ac.uk/139966 Copyright and reuse: This thesis is made available online and is protected by original copyright. Please scroll down to view the document itself. Please refer to the repository record for this item for information to help you to cite it. Our policy information is available from the repository home page. For more information, please contact the WRAP Team at: [email protected] warwick.ac.uk/lib-publications I A STUDY OF OLFACTORY MECHANISMS by DAVID JAMES SQUIRRELL, BSc. A thesis submitted for the degree of Doctor of Philosophy in the Department of Chemistry and Molecular Science at the University of Warwick December. 1978 I i CONTE NTS PAGE CHAPTER 1 INTRODUCTION: THE VERTEBRATE OLFACTORY SYSTEM 1 1.1 Morphology 1 i ) Macroscopic 1 11 ) Microscopic 5 a) Olfactory neurons 7 b) Cilia 9 c) Mucus 10 d) Supporting cells 11 e) Basal cells 11 f) Axons 12 g) Contacts between cells 12 h) The lamina propria 13 ili) Cell dynamics in the olfactory epi thelium 14 Î V ) Experimentally induced degeneration and subsequent regeneration of the olfactory epithelium 15 1.2 Epi thelium 17 i ) The electro-olfactogram or EOG 19 i i ) Pos i t i ve EOG's 31 ili) Frequency of occurence of the various types of EOG 33 iv) Cellular origins of slow potentials in the olfactory epithelium 34 V) Ionic mechanisms 36 vi ) Generator currents in the olfactory epithelium 37 Vi i ) The site of transduction 41 1.3 Pp-~essing of Olfactory Information 43 -
"Synthesis of 1,2-Diacyl-Sn
"Synthesis of 1,2-diacyl-sn-glycerophosphatidylserine from egg phosphatidylcholine by phosphoramidite methodology" Morillo, M., Sagristá, M.L., de Madariaga, M.A., Eritja, R. Lipids, 31(5), 541-546 (1996). doi: 10.1007/BF02522649 Synthesis of 1,2-Diacyl-sn -Glycerophosphatidylserine from Egg Phosphatidyicholine by Phosphoramidite Methodology Margarita Morillo a, M. Luisa Sagristá a,* , M. Africa de Madariaga a, and Ramón Eritja b aDepartment of Biochemistry and Physiology, Faculty of Chemistry, University of Barcelona, O8028 Barcelona, Spain, and bDepartment of Molecular Genetics, CID-CSIC, 08034 Barcelona, Spain *To whom correspondence should be addressed at the Department of Bio chemistry and Physiology, Faculty of Chemistry, University of Barcelona, Martí i Franqués, 1-11,08028 Barcelona, Spain. Abbreviations: BE, N-t-BOC-L-serine benzhydril ester; BEP, N-t-BOC-L- serine benzhydril ester phosphoramidite; DAG, diacylglycerol; DDM, diazodiphenylmethane; NMR, nuclear magnetic resonance; PC, phosphatidylcholine; PS, phosphatidylserine; P Sp, O-(1,2-diacylglycero-3- phospho-)-N-t-BOC-L-serine benzhydril ester; t-BOC, N-tert - butoxycarbonyl; TES, N-tris(hydroxymethyl)methyl-2-aminoethane- sulfonica cid; TFA, trifluoroacetic acid; TLC, thin-layer chromatography ABSTRACT : A simple chemical method for the synthesis of 1,2-diacyl-sn - glycerophosphatidylserine (PS), with the same fatty acid composition in the sn -1 and sn -2 glycerol positions as egg phosphatidylcholine (PC), is described. PS synthesis was carried out by a phosphite-triester approach, using 2-cyanoethyI- N,N,N' ,N' -tetraisopropylphosphorodiamidite (phosphoramiditate) as the phosphorylating agent, for the formation of phosphate linkage between serine and diacylglycerol. 1,2- Diacylglycerol, obtained from PC hydrolysis by phospholipase C, was coupled with N-t-BOC- L-serine benzhydryl ester phosphoramidite with tetrazole as catalyst. -
Ep 0685459 B1
Patentamt Europaisches ||| || 1 1| || || || || || || || || ||| || (19) J European Patent Office Office europeen des brevets (11) EP 0 685 459 B1 (12) EUROPEAN PATENT SPECIFICATION (45) Date of publication and mention (51) mt ci 6: C07C 245/16, C07B 61/00, of the grant of the patent: B01J31/02, B01J31/26, 07.10.1998 Bulletin 1998/41 C07C 245/14 (21) Application number: 95902975.2 (86) International application number: (22) Dateof filing: 16.12.1994 PCT/JP94/02124 (87) International publication number: WO 95/16666 (22.06.1995 Gazette 1995/26) (54) PROCESS FOR PRODUCING DIAZOMETHANE DERIVATIVE VERFAHREN ZUR HERSTELLUNG VON DIAZOMETHANDERIVATEN PROCEDE DE PRODUCTION DE DERIVE DE DIAZOMETHANE (84) Designated Contracting States: • SASAOKA, Michio AT DE GB NL 1 -1 6, Nakanokoshi Aza Nakase (30) Priority: 17.12.1993 JP 318495/93 Tokushima 771-02 (JP) (43) Date of publication of application: (74) Representative: Barz, Peter, Dr. 06.12.1995 Bulletin 1995/49 Patentanwalt Kaiserplatz 2 (73) Proprietor: 80803 Munchen (DE) OTSUKA KAGAKU KABUSHIKI KAISHA Osaka-shi Osaka-fu 540 (JP) (56) References cited: JP-A-49 080 002 (72) Inventors: • KAWAHARA, Ichiro • J. Chem. Soc, Perkin Trans. 1, Vol. 20 (1975), Itano-gun Tokushima 771-12 (JP) ADAMSON, J. ROBERT et al., "Amino Acids and • WADA, Isao Peptides, II. New Method for Preparing Otsu-cho Naruto-shi Tokushima 772 (JP) Diazodiphenylmethane and Related Compounds", p. 2030-2033, particularly Table 4. CO LO LO CO Note: Within nine months from the publication of the mention of the grant of the European patent, give CO any person may notice to the European Patent Office of opposition to the European patent granted.