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Thickness of the

(from Meteorology Today) Lecture 1: A Brief Survey of the Atmosphere ‰ The thickness of the atmosphere is only about 2% 90% of ’s thickness (Earth’s 70% ‰ Origins of the atmosphere radius = ~6400km). ‰ Vertical structures of the atmosphere ‰ Most of the atmospheric mass is confined in the lowest 100 ‰ maps km above the .

‰ Because of the shallowness of the atmosphere, its motions over large areas are primarily horizontal. ÎTypically, horizontal wind speeds are a thousands time greater than vertical wind speeds. (But the small vertical displacements of air have an important impact on

ESS55 the state of the atmosphere.) ESS55 Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

Vertical Structure of the Atmosphere Vertical Structure of Composition

up to ~500km composition Dominated by lighter gases Heterosphere wihiith increasi ng al lititud e, such as hydrogen and helium. temperature ~80km

This part of the atmosphere electricity continually circulates, so that the principal atmospheric Homosphere gases are well mixed. 80km Î For most purpose, we consider the homosphere virtually the entire atmosphere. (from Meteorology Today) ESS55 ESS55 Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

1 Composition of the Atmosphere Origins of the Atmosphere (inside the DRY homosphere)

‰ When the Earth was formed 4.6 billion years ago, Earth’s atmosphere was probably mostly hydrogen (H) and helium (He) plus hydrogen

compounds, such as methane (CH4) and ammonia (NH3). Î Those gases eventually escaped to the space.

‰ The release of gases from rock through volcanic eruption (so-called outgassing) was the principal source of atmospheric gases. Water vapor (0 -0.25%) Î The primeval atmosphere produced by the outgassing was mostly

water vapor (H2O), with some Nitrogen (N2) and Carbon dioxide (CO2), and trace amounts of other gases.

(from The Blue Planet) ESS55 ESS55 Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

What Happened to H2O? Saturation Vapor Pressure ‰ Saturation vapor pressure describes how much water vapor is needed to make the ‰ The atmosphere can only hold air saturated at any given temperature. small fraction of the mass of water vapor that has been ‰ Saturation vapor pressure depends primarily on the air temperature in the injected into it during volcanic following way: eruption, most of the water The vapor was condensed into Clausius-Clapeyron and and gave rise to Equation rivers, lakes, and oceans. Î Î The concentration of water vapor in the atmosphere was

(from Atmospheric Sciences: An Introductory Survey) substantially reduced. ‰ Saturation pressure increases exponentially with air temperature.

ESS55 ESS55 Prof. Jin-Jin-YiYi Yu L: latent heat of evaporation; α: specific volume of vapor and liquid Prof. Jin-Jin-YiYi Yu

2 Carbon Inventory What happened to CO2?

‰ Chemical weather is the primary process to remove CO2 from the atmosphere. Î In this process, CO2 dissolves in rainwater producing weak carbonic acid that reacts chemically with bedrock and produces carbonate compounds.

‰ This biogeochemical process reduced CO2 in the atmosphere

(from Earth’s Climate: Past and Future) and locked carbon in rocks and mineral. (from Atmospheric Sciences: An Introductory Survey)

ESS55 ESS55 Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

What Happened to N2? Where Did O2 Come from?

‰ Photosynthesis was the primary ‰ Nitrogen (N2): process to increase the amount of (1) is iner t c hem ica lly, oxygen ithtin the atmosph ere. (2) has molecular speeds too slow to escape to space, Î Primitive forms of life in oceans (3) is not very soluble in water. began to produce oxygen through photosynthesis probably 2.5 billion ÎThe amount of nitrogen being cycled out of the atmosphere years ago. was limited. Î With the concurrent decline of CO2, oxygen became the second most ÎNitrogen became the most abundant gas in the atmosphere. abundant atmospheric as after nitrogen.

(from Earth’s Climate: Past and Future) ESS55 ESS55 Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

3 Permanent and Variable Gases Where Did Argon Come from? Those gases that form a constant portion of the atmospheric mass . ‰ Radioactive decay in the planet’s bedrock added argon (Ar) to the evolving atmosphere.

Î Argon became the third abundant gas in the atmosphere. Those gases whose concentrations changes from time to time and from place to place, and are important to weather and climate. ESS55 ESS55 Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

Carbon Dioxide (CO2) Water Vapor (H2O) (Mauna Loa, Hawaii) current Early spring maximum: takes less CO2 due to ‰ Water vapor is supplied to the atmosphere by evaporation from level slow plant growth in winter plus CO2 the surface and is removed from the atmosphere by proddfduced from tree leave condensation (clouds and rains). decomposing.

Late summer minimum: ‰ The concentration of water vapor is maximum near the surface summer growth removes (from CO2 from the and the tropics (~ 0.25% of the atmosphere) and decreases Understanding atmosphere. rapidly toward higher altitudes and latitudes (~ 0% of the Weather atmosphere). & Climate) ‰ Carbon dioxide is supplied into the atmosphere by plant and ‰ Water vapor is important to climate because it is a greenhouse animal respiration, the decay of organic material, volcanic gas that can absorb thermal energy emitted by Earth, and can eruptions, and natural and anthropogenic combustion. release “latent heat” to fuel weather phenomena. ‰ Carbon dioxide is removed from the atmosphere by photosynthesis. ESS55 ESS55 Prof. Jin-Jin-YiYi Yu ‰ CO2 is an important greenhouse gas. Prof. Jin-Jin-YiYi Yu

4 Formation of (O3) Ozone (O3)

‰ With oxygen emerging as a major component of the “good” ozone atmosphere, the concentration ~ 15ppm of ozone increased in the atmosphere through a photodissociation process.

“bad” ozone ~ 0.15ppm

ESS55 (from WMO Report 2003) ESS55 Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu (from WMO Report 2003)

Other Atmospheric Constituents Air Pressure Can Be Explained As:

‰ Aerosols: small solid particles and liquid droplets in the air. They serve as condensation nuclei for formation. weight of the air motion of ‰ Air Pollutant: a gas or aerosol produce by human air molecules activity whose concentration threatens living organisms or the environmentenvironment.

The weight of air above a surface The bombardment of air molecules (due to Earth’s gravity) on a surface (due to motion)

ESS55 ESS55 Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

5 Air Pressure and Air Density How Soon Pressure Drops With Height?

‰ Weight = mass x gravity Ocean Atmosphere

‰ Density = mass / volume

‰ Pressure = force / area = weight / area

(from Is The Temperature Rising?) ‰ In the ocean, which has an essentially constant density, pressure increases linearly with depth. ‰ In the atmosphere, both pressure and density decrease exponentially with elevation. ESS55 ESS55 (from Meteorology Today) Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

One Atmospheric Pressure

‰ The average air pressure at sea level is equ iva le nt to t he pressure produced by a column of water about 10 meters (or about 76 cm of mercury column). ‰ This standard atmosphere pressure is often expressed as 1013 mb (millibars), which means a pressure of about 1 kilogram per square centimeter. (from The Blue Planet) ESS55 ESS55 (from The Atmosphere) Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

6 Units of Atmospheric Pressure and Pressure

‰ Pascal (Pa): a SI (Systeme Internationale) unit for air pressure. ‰Atmospheric pressure 1 Pa = a force of 1 newton acting on a surface of one square meter tells you how much 1 hectopascal (hPa) = 1 millibar (mb) [hecto = one hundred =100] atmospheric mass is

‰ Bar: a more popular unit for air pressure. above a particular 1 bar = a force of 100,000 newtons acting on a surface of one altitude. square meter = 100,000 Pa ‰ Atmospheric pressure = 1000 hPa dbbtdecreases by about = 1000 mb 10mb for every 100 meters increase in ‰ One atmospheric pressure = standard value of atmospheric pressure elevation. at lea level = 1013.25 mb = 1013.25 hPa.

ESS55 (from Meteorology Today) ESS55 Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

Units of Air Temperature “Absolute Zero” Temperature

‰ Fahrenheit (ºF)

‰ Celsius (ºC)

Î ºC = (ºF-32)/1.8 (from Is The Temperature Rising?) ‰ The absolute zero temperature is the temperature that the molecules do not move at all. ‰ Kelvin (K): a SI unit Î K= ºC+273 ‰ This temperature occurs at –273°C. ‰ The Kelvin Scale (K) is a new temperature scale that has 1 K = 1 ºC > 1 ºF its “zero” temperature at this absolute temperature:

ESS55 K = °C + 273 ESS55 Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

7 Vertical Thermal Structure Variations in Tropopause Height

Troposphere (“overturning” sphere) ƒ contains 80% of the mass Standard Atmosphere ƒ surface heated by solar radiation ƒ strong vertical motion ƒ where most weather events occur

Stratosphere (“layer” sphere) middle ƒ weak vertical motions atmosphere ƒ dominated by radiative processes ƒ heated by ozone absorption of solar ultraviolet (UV) radiation ƒ warmest (coldest) temperatures at summer (winter) pole Mesosphere ƒ heated by solar radiation at the base ƒ heat dispersed upward by vertical motion (from Understanding Weather & Climate) (from The Atmosphere) ƒ very little mass = 6.5 C/km ESS55 ESS55 Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

Dry Adiabatic Lapse Rate Moist Adiabatic Lapse Rate

(from Meteorology: Understanding the Atmosphere) ESS55 (from Meteorology: Understanding the Atmosphere) ESS55 Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

8 Ozone Distribution

Standard Atmosphere ‰ The reasons for the inversion in the stratosphere is due to the ozone AtAntarc tic absorption of ultraviolet solar Ozone energy. Hole ‰ Although maximum ozone concentration occurs at 25km, much is absorbed in (from The Earth System) the upper stratosphere and can not ‰ The greatest production of ozone occurs in the tropics, where the solar UV reachhh the l evel of ozone maxi mum. flux is the highest. ‰ However, the general circulation in the stratosphere transport ozone-rich air ‰ Also, the lower air density at from the tropical upper stratosphere to mid-to-high latitudes. 50km allows solar energy to heat ‰ Ozone column depths are highest during springtime at mid-to-high latitudes. (from Understanding Weather & Climate) up temperature there at a much ‰ Ozone column depths are the lowest over the equator. lapse rate = 6.5 C/km greater degree. ESS55 ESS55 Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

Temperatures in Stratosphere Mesosphere

Northern Winter Northern Summer Standard Atmosphere ‰ There is little ozone to absorb solar energy in the mesosphere, and therefore, the air temperature in the mesosphere decreases with height. ‰ Also, air molecules are able to mesosphere lose more energy than they absorb. This cooling effect is particularly here pp large near the top of the mesosphere. stratos

(from Understanding Weather & Climate)

lapse rate = 6.5 C/km (from Dynamic Meteorology) ESS55 ESS55 Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

9 Thermosphere

Standard Atmosphere ‰ The ionosphere is an electrified ‰ In thermosphere, oxygen reggppion within the upper molecules absorb solar rays and atmosphere where large warms the air. concentration of ions and free electrons exist. ‰ Because this layer has a low air density, the absorption of small ‰ The ionosphere starts from about amount of solar energy can cause 60km above Earth’s surface and large temperature increase. extends upward to the top of the athMtfthtmosphere. Most of the ‰ The air temperature in the ionosphere is in the thermosphere. thermosphere is affected greatly by solar activity. ‰ The ionosphere plays an important (from Understanding Weather & Climate) (from Meteorology Today) role in radio communication. lapse rate = 6.5 C/km ESS55 ESS55 Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

Ionosphere and AM Radio Weather Maps

‰ The D- and E-layers absorb AM ‰ Many variables are needed radio, while the F-layer reflect to described weather radio waves . conditions. ‰ When night comes, the D-layer disappears and the E-layer ‰ Local weathers are affected weakens. Radio waves are able by weather pattern. to reach the F-layer and get Î We need to see all the reflected further. numbers describing ‰ The repeated refection of radio weathers at many locations. waves between Earth surface Î We need weather maps. and the F-layer allows them to overcome the effect of Earth’s ‰ “A picture is worth a curvature. (from Understanding Weather & Climate) thousand words”. (from Understanding Weather & Climate)

ESS55 ESS55 Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

10 Weather Map on 7/7/2005 The Station Model

‰ Meteorologists need a way to condense all the numbers describing the current weather at a location into a compact diagram that takes up as little space as possible on a weather map.

‰ This compressed geographical (from Meteorology: Understanding the Atmosphere) weather report is called a station model.

ESS55 (from Meteorology: Understanding the Atmosphere) ESS55 Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

Isobar The Station Model: Cloudiness

‰ It is useful to examine horizontal pressure differences across space. ‰ Pressure maps depict isobars, lines of equal pressure. ‰ Through analysis of isobaric charts, pressure gradients are apparent. ‰ Steep (weak) pressure gradients are indicated by closely (widely)

spaced isobars. ESS55 ESS55 Prof. Jin-Jin-YiYi Yu (from Meteorology: Understanding the Atmosphere) Prof. Jin-Jin-YiYi Yu

11 The Station Model: Wind The Station Model: Pressure Wind speed is indicated to the right (Northeasterly wind) (left) side of the coming wind vector ‰ The pressure value shown is in the Northern (Southern) Hemisphere the measured atmospheric pressure adjusted to sea level.

‰ The units used are “mb”.

50 ‰ To save space, the “thousand” 5 and the “hundred” values, and 10 15 the decimal point are dropped. ƒ Wind speeds are indicated in units of “knot”. Î So “138” means 1013.8 mb ƒ 1 international knot = 1 nautical mile per hour (exactly), To decode the value of pressure on the station model, add a 9 if the = 1.852 kilometres per hour (exactly), first number is 7, 8, or 9; otherwise add a 10. = 0.514 meters per second, = 1.15077945 miles per hour ESS55 ESS55 (approximately) Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

Pressure Correction for Elevation The Station Model: Pressure Tendency

‰ The change in surface pppressure in the past three hours is plotted numerically and graphically on the lower right of the station model.

‰ Pressure decreases with height. ‰ Recording actual pressures may be misleading as a result. ‰ All recording stations are reduced to sea level pressure equivalents to facilitate horizontal comparisons. The pressure rose and then fell over the past three hours, a total ‰ Near the surface, the pressure decreases about 100mb by change of 0.3 mb.

moving 1km higher in elevation. ESS55 ESS55 Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

12 The Station Model: Dew Point Temperature Saturation Vapor Pressure

‰ Saturation vapor pressure describes how much water vapor is needed to make the air saturated at any given temperature. ‰ Dew point temperature (in ‰ Saturation vapor pressure depends primarily on the air temperature in the united of ºF) indicates the following way: moisture content. The ‰ A higher value indicates a Clausius-Clapeyron larger amount of moisture. Equation

Î

‰ Saturation pressure increases exponentially with air temperature.

ESS55 ESS55 Prof. Jin-Jin-YiYi Yu L: latent heat of evaporation; α: specific volume of vapor and liquid Prof. Jin-Jin-YiYi Yu

The Station Model: Current Weather Satellite Picture on 7/7/2005

ESS55 (from Meteorology: Understanding the Atmosphere) ESS55 (from Meteorology: Understanding the Atmosphere) Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

13 Weather Map on 7/7/2005 Observation Time for Weather Map

‰ Weather organizations throughout the world use the UTC (Coordinated Universal Time) as the reference clock for weather observations.

‰ UTC i s al so d enot ed b y th e abb revi ati on GMT (Greenwi ch M eridi an Time) or, often as the last two zeroes omitted, Z (Zulu).

‰ Observations of the upper atmosphere are coordinately internationally to be made at 0000 UTC (midnight at Greenwich; 0Z; 0GMT) and 1200 UTC (noon at Greenwich; 12Z; 12GMT).

‰ Synoptic observations have traditionally been done every 6 hours or every 3 hours, depending on the station.

‰ Local time should be 1 hour earlier for every (360/24)=15° of longitude west of Greenwich. ÎLocal time in Los Angeles (118 ° W) and the rest of the Pacific Standard Time is 8 (= 118°/15°) hours earlier than Greenwich.

(from Meteorology: Understanding the Atmosphere) ESS55 ESS55 Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

Rawinsondes Surface Measurements: ASOS/AWOS • To understand weather systems, measurements are required through the depth of the and well • Automated Surface (Weather) Observing Systems ihinto the stratosph ere. (ASOS or AWOS) are now used to make standard • Raiwinsondes are designed for this measurements of atmospheric properties at most purpose. location in North America.

• A rawinsonde is a balloonballoon--borneborne • The measurements are reported hourly in North instruments system that measure America and every three hours worldwide, at 0000, pressure, temperature, dewpoint 0300, 0600, 0900, 1200, 1500, 1800, and 2100 temperature, wind direction, and UTC.C speed.

ESS55 ESS55 Prof. Jin-Jin-YiYi Yu Prof. Jin-Jin-YiYi Yu

14 Time Zone (from Meteo r ology: Understandingthe A tmosphere )

7/7/2005 7/8/2005 7/7/2005 ESS55 Prof. Jin-Jin-YiYi Yu

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