Dunnill, Charles W. H. (2008) Synthesis, characterisation and properties of tantalum based inorganic nanofibres. PhD thesis. http://theses.gla.ac.uk/173/ Copyright and moral rights for this thesis are retained by the author A copy can be downloaded for personal non-commercial research or study, without prior permission or charge This thesis cannot be reproduced or quoted extensively from without first obtaining permission in writing from the Author The content must not be changed in any way or sold commercially in any format or medium without the formal permission of the Author When referring to this work, full bibliographic details including the author, title, awarding institution and date of the thesis must be given Glasgow Theses Service http://theses.gla.ac.uk/
[email protected] SYNTHESIS, CHARACTERISATION AND PROPERTIES OF TANTALUM BASED INORGANIC NANOFIBRES A thesis submitted to the University of Glasgow for the degree of Doctor of Philosophy By Charles W. H. Dunnill MSci School of Chemistry University of Glasgow December 2007 © Charles W. H. Dunnill. December 2007 Abstract This thesis describes the synthesis and characterisation of 1-dimensional nanometric phases using simple preparative reactions and a variety of characterisation methods. Comparison of properties between the bulk and nanomorphology has played a large part and is a common theme throughout. High aspect ratio tantalum disulfide, TaS 2 nanofibres were prepared from a 1:2 stoichiometric mixture of elemental powders in a one-step synthesis utilising silica ampoules. A surface assisted growth phenomena was investigated and found to significantly increase the yield, both in quality and quantity. The resulting nanofibres were seen to retain and indeed enhance some of the bulk properties, e.g.