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SCIENCE ADVANCES | RESEARCH ARTICLE CONDENSED MATTER PHYSICS Copyright © 2021 The Authors, some rights reserved; Charge transport physics of a unique class of rigid-rod exclusive licensee American Association conjugated polymers with fused-ring conjugated units for the Advancement of Science. No claim to linked by double carbon-carbon bonds original U.S. Government Mingfei Xiao1†, Remington L. Carey1†, Hu Chen2†, Xuechen Jiao3,4, Vincent Lemaur5, Sam Schott1, Works. Distributed 1 6 1,7 8 1,9 under a Creative Mark Nikolka , Cameron Jellett , Aditya Sadhanala , Sarah Rogers , Satyaprasad P. Senanayak , Commons Attribution 6 1 1 1,10 1 Ada Onwubiko , Sanyang Han , Zhilong Zhang , Mojtaba Abdi-Jalebi , Youcheng Zhang , NonCommercial 1 8 1,11 1 1 Tudor H. Thomas , Najet Mahmoudi , Lianglun Lai , Ekaterina Selezneva , Xinglong Ren , License 4.0 (CC BY-NC). Malgorzata Nguyen1, Qijing Wang1, Ian Jacobs1, Wan Yue12, Christopher R. McNeill3, Guoming Liu1,13,14, David Beljonne5, Iain McCulloch2,6, Henning Sirringhaus1* We investigate the charge transport physics of a previously unidentified class of electron-deficient conjugated polymers that do not contain any single bonds linking monomer units along the backbone but only double-bond linkages. Such polymers would be expected to behave as rigid rods, but little is known about their actual chain Downloaded from conformations and electronic structure. Here, we present a detailed study of the structural and charge transport properties of a family of four such polymers. By adopting a copolymer design, we achieve high electron mobilities 2 −1 −1 up to 0.5 cm V s . Field-induced electron spin resonance measurements of charge dynamics provide evidence for relatively slow hopping over, however, long distances.
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