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Nitrogen Dioxide

Nitrogen Dioxide

Common Name: DIOXIDE

CAS Number: 10102-44-0 RTK Substance number: 1376 DOT Number: UN 1067 Date: May 1989 Revision: April 2000 ------

HAZARD SUMMARY * can affect you when breathed in. * If you think you are experiencing any work-related health * Nitrogen Dioxide may cause mutations. Handle with problems, see a doctor trained to recognize occupational extreme caution. diseases. Take this Fact Sheet with you. * Contact can irritate and burn the skin and eyes with * Exposure to hazardous substances should be routinely possible eye damage. evaluated. This may include collecting personal and area * Nitrogen Dioxide can irritate the nose and air samples. You can obtain copies of sampling results throat. from your employer. You have a legal right to this * Breathing Nitrogen Dioxide can irritate the lungs causing information under OSHA 1910.1020. coughing and/or shortness of breath. Higher exposures can cause a build-up of fluid in the lungs (pulmonary edema), a medical emergency, with severe shortness of WORKPLACE EXPOSURE LIMITS breath. OSHA: The legal airborne permissible exposure limit * High levels can interfere with the ability of the blood to (PEL) is 5 ppm, not to be exceeded at any time. carry causing headache, fatigue, dizziness, and a blue color to the skin and lips (methemoglobinemia). NIOSH: The recommended airborne exposure limit is Higher levels can cause trouble breathing, collapse and 1 ppm, which should not be exceeded at any even death. time. * Repeated exposure to high levels may to permanent lung damage. ACGIH: The recommended airborne exposure limit is 3 ppm averaged over an 8-hour workshift and IDENTIFICATION 5 ppm as a STEL (short term exposure limit). Nitrogen Dioxide is a dark brown to yellowish liquid or reddish-brown with a strong odor. It is used to produce * Nitrogen Dioxide may cause mutations. All contact with other chemicals, as a nitrating and , in this chemical should be reduced to the lowest possible bleaching flour, and in fuels and . level.

REASON FOR CITATION WAYS OF REDUCING EXPOSURE * Nitrogen Dioxide is on the Hazardous Substance List * Where possible, enclose operations and use local exhaust because it is regulated by OSHA and cited by ACGIH, ventilation at the site of chemical release. If local exhaust DOT, NIOSH, DEP, HHAG, NFPA and EPA. ventilation or enclosure is not used, respirators should be * Definitions are provided on page 5. worn. * Wear protective work clothing. HOW TO DETERMINE IF YOU ARE BEING * Wash thoroughly immediately after exposure to Nitrogen EXPOSED Dioxide. The New Jersey Right to Know Act requires most employers * Post hazard and warning information in the work area. In to label chemicals in the workplace and requires public addition, as part of an ongoing education and training employers to provide their employees with information and effort, communicate all information on the health and training concerning chemical hazards and controls. The safety hazards of Nitrogen Dioxide to potentially exposed federal OSHA Hazard Communication Standard, 1910.1200, workers. requires private employers to provide similar training and information to their employees.

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This Fact Sheet is a summary source of information of all If symptoms develop or overexposure is suspected, the potential and most severe health hazards that may result from following are recommended: exposure. Duration of exposure, concentration of the substance and other factors will affect your susceptibility to * Consider chest x-ray after acute overexposure. any of the potential effects described below. * Blood methemoglobin level. ------Any evaluation should include a careful history of past and HEALTH HAZARD INFORMATION present symptoms with an exam. Medical tests that look for damage already done are not a substitute for controlling Acute Health Effects exposure. The following acute (short-term) health effects may occur immediately or shortly after exposure to Nitrogen Dioxide: Request copies of your medical testing. You have a legal right to this information under OSHA 1910.1020. * Contact can irritate and burn the skin and eyes with possible eye damage. Mixed Exposures * Breathing Nitrogen Dioxide can irritate the nose and * Because smoking can cause heart disease, as well as lung throat. cancer, emphysema, and other respiratory problems, it may * Breathing Nitrogen Dioxide can irritate the lungs causing worsen respiratory conditions caused by chemical coughing and/or shortness of breath. Higher exposures exposure. Even if you have smoked for a long time, can cause a build-up of fluid in the lungs (pulmonary stopping now will reduce your risk of developing health edema), a medical emergency, with severe shortness of problems. breath. * High levels can interfere with the ability of the blood to WORKPLACE CONTROLS AND PRACTICES carry Oxygen causing headache, fatigue, dizziness, and a blue color to the skin and lips (methemoglobinemia). Unless a less toxic chemical can be substituted for a hazardous Higher levels can cause trouble breathing, collapse and substance, ENGINEERING CONTROLS are the most even death. effective way of reducing exposure. The best protection is to enclose operations and/or provide local exhaust ventilation at Chronic Health Effects the site of chemical release. Isolating operations can also The following chronic (long-term) health effects can occur at reduce exposure. Using respirators or protective equipment is some time after exposure to Nitrogen Dioxide and can last for less effective than the controls mentioned above, but is months or years: sometimes necessary.

Cancer Hazard In evaluating the controls present in your workplace, consider: * Nitrogen Dioxide may cause mutations (genetic changes). (1) how hazardous the substance is, (2) how much of the * There is no evidence that Nitrogen Dioxide causes cancer substance is released into the workplace and (3) whether in animals. This is based on test results presently available harmful skin or eye contact could occur. Special controls to the New Jersey Department of Health and Senior should be in place for highly toxic chemicals or when Services from published studies. significant skin, eye, or breathing exposures are possible.

Reproductive Hazard In addition, the following control is recommended: * There is limited evidence that Nitrogen Dioxide may damage the developing fetus and decrease fertility in * Where possible, automatically transfer gaseous Nitrogen females. Dioxide or pump liquid Nitrogen Dioxide from drums or other storage containers to process containers. Other Long-Term Effects Good WORK PRACTICES can help to reduce hazardous * Repeated exposure to high levels may lead to permanent exposures. The following work practices are recommended: lung damage.

MEDICAL * Workers whose clothing has been contaminated by Nitrogen Dioxide should change into clean clothing Medical Testing promptly. * Contaminated work clothes should be laundered by Before beginning employment and at regular times after that, individuals who have been informed of the hazards of the following are recommended: exposure to Nitrogen Dioxide.

* Eye wash fountains should be provided in the immediate * Lung function tests. These may be normal if the person is work area for emergency use. not having an attack at the time of the test. * If there is the possibility of skin exposure, emergency

shower facilities should be provided. NITROGEN DIOXIDE page 3 of 6

* On skin contact with Nitrogen Dioxide, immediately wash * Exposure to 20 ppm is immediately dangerous to life and or shower to remove the chemical. At the end of the health. If the possibility of exposure above 20 ppm exists, workshift, wash any areas of the body that may have use a MSHA/NIOSH approved self-contained breathing contacted Nitrogen Dioxide, whether or not known skin apparatus with a full facepiece operated in a pressure- contact has occurred. demand or other positive-pressure mode. * Do not eat, , or drink where Nitrogen Dioxide is handled, processed, or stored, since the chemical can be HANDLING AND STORAGE swallowed. Wash hands carefully before eating, drinking, smoking, or using the toilet. * Prior to working with Nitrogen Dioxide you should be trained on its proper handling and storage. PERSONAL PROTECTIVE EQUIPMENT * Nitrogen Dioxide will react with to form Nitric . WORKPLACE CONTROLS ARE BETTER THAN * Nitrogen Dioxide may react explosively with PERSONAL PROTECTIVE EQUIPMENT. However, for TRIMETHYLTIN; TRIETHYLAMINE; AMMONIA; some jobs (such as outside work, confined space entry, jobs ALCOHOLS; ACETONITRILE; ; METHYL done only once in a while, or jobs done while workplace SULFOXIDE; HYDRAZINES; ALUMINUM POWDER; controls are being installed), personal protective equipment and DISULFIDE. may be appropriate. * Nitrogen Dioxide is not compatible with COMBUSTIBLE MATERIALS; CHLORINATED OSHA 1910.132 requires employers to determine the ; ; ; appropriate personal protective equipment for each hazard and PETROLEUM; NITROBENZENE; ; COPPER to train employees on how and when to use protective ALLOYS; and REDUCING MATERIALS. equipment. * Store in tightly closed containers in a cool, dry, well- ventilated area. The following recommendations are only guidelines and may not apply to every situation. QUESTIONS AND ANSWERS

Clothing Q: If I have acute health effects, will I later get chronic * Avoid skin contact with Nitrogen Dioxide. Wear acid- health effects? resistant gloves and clothing. Safety equipment suppliers/ A: Not always. Most chronic (long-term) effects result manufacturers can provide recommendations on the most from repeated exposures to a chemical. protective glove/clothing material for your operation. * All protective clothing (suits, gloves, footwear, headgear) Q: Can I get long-term effects without ever having short- should be clean, available each day, and put on before term effects? work. A: Yes, because long-term effects can occur from repeated exposures to a chemical at levels not high enough to Eye Protection make you immediately sick. * Wear non-vented, impact resistant goggles when working with fumes, , or . Q: What are my chances of getting sick when I have been * Wear indirect-vent, impact and splash resistant goggles exposed to chemicals? when working with liquids. A: The likelihood of becoming sick from chemicals is * Wear a face shield along with goggles when working with increased as the amount of exposure increases. This is corrosive, highly irritating or toxic substances. determined by the length of time and the amount of material to which someone is exposed. Respiratory Protection IMPROPER USE OF RESPIRATORS IS DANGEROUS. Q: When are higher exposures more likely? Such equipment should only be used if the employer has a A: Conditions which increase risk of exposure include written program that takes into account workplace conditions, physical and mechanical processes (heating, pouring, requirements for worker training, respirator fit testing and spraying, spills and evaporation from large surface areas medical exams, as described in OSHA 1910.134. such as open containers), and "confined space" exposures (working inside vats, reactors, boilers, small * Where the potential exists for exposure over 1 ppm, use a rooms, etc.). MSHA/NIOSH approved supplied-air respirator with a full facepiece operated in a pressure-demand or other positive- Q: Is the risk of getting sick higher for workers than for pressure mode. For increased protection use in community residents? combination with an auxiliary self-contained breathing A: Yes. Exposures in the community, except possibly in apparatus operated in a pressure-demand or other positive- cases of fires or spills, are usually much lower than those pressure mode. found in the workplace. However, people in the community may be exposed to contaminated water as well as to chemicals in the air over long periods. This NITROGEN DIOXIDE page 4 of 6

may be a problem for children or people who are already ------ill. The following information is available from: Q: Can men as well as women be affected by chemicals that cause reproductive system damage? New Jersey Department of Health and Senior Services A: Yes. Some chemicals reduce potency or fertility in both Occupational Health Service men and women. Some damage sperm and eggs, PO Box 360 possibly leading to birth defects. Trenton, NJ 08625-0360 (609) 984-1863 Q: Who is at the greatest risk from reproductive hazards? (609) 292-5677 (fax) A: Pregnant women are at greatest risk from chemicals that harm the developing fetus. However, chemicals may Web address: http://www.state.nj.us/health/eoh/odisweb/ affect the ability to have children, so both men and women of childbearing age are at high risk. Industrial Hygiene Information Industrial hygienists are available to answer your questions Q: What are the likely health problems from chemicals regarding the control of chemical exposures using exhaust which cause mutations? ventilation, special work practices, good housekeeping, good A: There are two primary health concerns associated with hygiene practices, and personal protective equipment mutagens: (1) cancers can result from changes induced including respirators. In addition, they can help to interpret in cells and, (2) adverse reproductive and developmental the results of industrial hygiene survey data. outcomes can result from damage to the egg and sperm cells. Medical Evaluation If you think you are becoming sick because of exposure to chemicals at your workplace, you may call personnel at the Department of Health and Senior Services, Occupational Health Service, who can help you find the information you need.

Public Presentations Presentations and educational programs on occupational health or the Right to Know Act can be organized for labor unions, trade associations and other groups.

Right to Know Information Resources The Right to Know Infoline (609) 984-2202 can answer questions about the identity and potential health effects of chemicals, list of educational materials in occupational health, references used to prepare the Fact Sheets, preparation of the Right to Know Survey, education and training programs, labeling requirements, and general information regarding the Right to Know Act. Violations of the law should be reported to (609) 984-2202. ------

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DEFINITIONS

ACGIH is the American Conference of Governmental A mutagen is a substance that causes mutations. A mutation Industrial Hygienists. It recommends upper limits (called is a change in the genetic material in a body cell. Mutations TLVs) for exposure to workplace chemicals. can lead to birth defects, miscarriages, or cancer.

A carcinogen is a substance that causes cancer. NAERG is the North American Emergency Response Guidebook. It was jointly developed by Transport Canada, The CAS number is assigned by the Chemical Abstracts the United States Department of Transportation and the Service to identify a specific chemical. Secretariat of Communications and Transportation of Mexico. It is a guide for first responders to quickly identify the specific A combustible substance is a , liquid or gas that will or generic hazards of material involved in a transportation burn. incident, and to protect themselves and the general public during the initial response phase of the incident. A corrosive substance is a gas, liquid or solid that causes irreversible damage to human tissue or containers. NCI is the National Cancer Institute, a federal agency that determines the cancer-causing potential of chemicals. DEP is the New Jersey Department of Environmental Protection. NFPA is the National Fire Protection Association. It classifies substances according to their fire and explosion DOT is the Department of Transportation, the federal agency hazard. that regulates the transportation of chemicals. NIOSH is the National Institute for Occupational Safety and EPA is the Environmental Protection Agency, the federal Health. It tests equipment, evaluates and approves respirators, agency responsible for regulating environmental hazards. conducts studies of workplace hazards, and proposes standards to OSHA. A fetus is an unborn human or animal. NTP is the National Toxicology Program which tests A flammable substance is a solid, liquid, or gas that chemicals and reviews evidence for cancer. will ignite easily and burn rapidly. OSHA is the Occupational Safety and Health Administration, The flash point is the temperature at which a liquid or solid which adopts and enforces health and safety standards. gives off vapor that can form a flammable mixture with air. PEOSHA is the Public Employees Occupational Safety and HHAG is the Human Health Assessment Group of the federal Health Act, a state law which sets PELs for New Jersey public EPA. employees.

IARC is the International Agency for Research on Cancer, a ppm means parts of a substance per million parts of air. It is a scientific group that classifies chemicals according to their measure of concentration by volume in air. cancer-causing potential. A reactive substance is a solid, liquid or gas that releases A miscible substance is a liquid or gas that will evenly energy under certain conditions. dissolve in another. A teratogen is a substance that causes birth defects by mg/m3 means milligrams of a chemical in a cubic meter of damaging the fetus. air. It is a measure of concentration (weight/volume). TLV is the Threshold Limit Value, the workplace exposure MSHA is the Mine Safety and Health Administration, the limit recommended by ACGIH. federal agency that regulates mining. It also evaluates and approves respirators. The is a measure of how readily a liquid or a solid mixes with air at its surface. A higher vapor pressure indicates a higher concentration of the substance in air and therefore increases the likelihood of breathing it in.

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Common Name: NITROGEN DIOXIDE ======DOT Number: UN 1067 FOR LARGE SPILLS AND FIRES immediately call your fire NAERG Code: 124 department. You can request emergency information from the CAS Number: 10102-44-0 following:

CHEMTREC: (800) 424-9300 Hazard rating NJDHSS NFPA NJDEP HOTLINE: (609) 292-7172 FLAMMABILITY - 0 ======

REACTIVITY - 0 HANDLING AND STORAGE (See page 3) POISONOUS GASES ARE PRODUCED IN FIRE CONTAINERS MAY EXPLODE IN FIRE FIRST AID

Hazard Rating Key: 0=minimal; 1=slight; 2=moderate; In NJ, for POISON INFORMATION call 1-800-764-7661 3=serious; 4=severe

FIRE HAZARDS Eye Contact * Immediately flush with large amounts of water. Continue

without stopping for at least 30 minutes, occasionally lifting * Extinguish fire using an agent suitable for type of upper and lower lids. Seek medical attention immediately. surrounding fire. Nitrogen Dioxide itself does not burn.

* POISONOUS GASES ARE PRODUCED IN FIRE, including Nitrogen . Skin Contact * CONTAINERS MAY EXPLODE IN FIRE. * Quickly remove contaminated clothing. Immediately wash * Use water spray to keep fire-exposed containers cool. contaminated skin with large amounts of soap and water. * Nitrogen Dioxide may ignite combustibles (wood, paper and oil). Breathing * If employees are expected to fight fires, they must be trained * Remove the person from exposure. and equipped as stated in OSHA 1910.156. * Begin rescue breathing (using universal precautions) if breathing has stopped and CPR if heart action has stopped. SPILLS AND EMERGENCIES * Transfer promptly to a medical facility. * Medical observation is recommended for 24 to 48 hours If liquid Nitrogen Dioxide is spilled or leaked, take the after breathing overexposure, as pulmonary edema may be following steps: delayed.

* Evacuate persons not wearing protective equipment from PHYSICAL DATA area of spill or leak until clean-up is complete. * Absorb liquids in vermiculite, dry , , or a similar Vapor Pressure: 720 mm Hg at 68oF (20oC) material and deposit in sealed containers. Water : Reactive * Ventilate and wash area after clean-up is complete. OTHER COMMONLY USED NAMES If gaseous Nitrogen Dioxide is leaked, take the following steps:

* Evacuate persons not wearing protective equipment from Chemical Name: area of leak until clean-up is complete. Nitrogen * Ventilate area of leak to disperse the gas. Other Names: * Stop flow of gas. If source of leak is a cylinder and the leak Nitrito; Nitrogen ; Nitrogen Tetroxide cannot be stopped in place, remove the leaking cylinder to a safe place in the open air, and repair leak or allow cylinder ------to empty. Not intended to be copied and sold for commercial * It may be necessary to contain and dispose of Nitrogen purposes. Dioxide as a HAZARDOUS WASTE. Contact your ------Department of Environmental Protection (DEP) or your NEW JERSEY DEPARTMENT OF HEALTH AND regional office of the federal Environmental Protection SENIOR SERVICES Agency (EPA) for specific recommendations. Right to Know Program * If employees are required to clean-up spills, they must be PO Box 368, Trenton, NJ 08625-0368 properly trained and equipped. OSHA 1910.120(q) may be (609) 984-2202 applicable. ------

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