Generation IV Reactors

Total Page:16

File Type:pdf, Size:1020Kb

Generation IV Reactors Advances in Reactor Concepts: Generation IV Reactors Research Workshop Future Opportunities in Nuclear Power October 16-17, 2014 Purdue University Prof. Won Sik Yang Purdue University Status of Nuclear Power Production Nuclear energy is a significant contributor to U.S. and international electricity production – 15% world, 20% U.S., 74% France 2 Status of Nuclear Power Production Nuclear energy and hydropower are the only two major established base-load low-carbon energy sources. Efforts to reduce CO2 emissions are thus a major factor in the renewed interest in nuclear energy that has become apparent in recent years. Total: 20130 TWh World Electricity Generation (2009) IEA/NEA, Nuclear Energy Technology Roadmap (2010) 3 Future Use of Nuclear Energy Extended lifetime and optimized operation of existing plants Construction of new plants (evolutionary designs in near term) Closure of fuel cycle to improve waste management – Strengthened international safeguards regime Sustainable generation of electricity, hydrogen and other energy products 4 Generations of Nuclear Reactors 5 Generation IV Systems: Technology Goals Sustainability – Sustainable energy generation through long-term availability of systems and effective fuel utilization – Minimize and manage nuclear waste and reduce the stewardship burden in the future Safety & Reliability – Very low likelihood and degree of reactor core damage – Eliminate the need for offsite emergency response Economics – Life-cycle cost advantage over other energy sources – Level of financial risk comparable to other energy projects Proliferation Resistance & Physical Protection – Unattractive materials diversion pathway – Enhanced physical protection against terrorism 6 Overview of Generation IV Systems Neutron Fuel Coolant Power Plant System Spectrum /Fuel Cycle Temp. (C) (MWe) Effici. (%) Applications Sodium Cooled Fast MOX, Metal 500 - 550 50 42 Electricity, Fast Reactor /Closed 300-600 Actinide Recycle (SFR) 1500 Very High Thermal Coated particles 900 -1000 250 > 47 Electricity, Temperature /Open Hydrogen Production, Reactor (VHTR) Process Heat Gas-Cooled Fast Carbides 850 200- 45 - 48 Electricity, Fast /Closed 1200 Hydrogen Production, Reactor (GFR) Actinide Recycle Supercritical Thermal, UOX, MOX 510 - 625 1500 Max. 50 Electricity Water Reactor Fast /Open; Closed (SCWR) Lead-Cooled Fast Nitrides; MOX 480 - 570 50-150 42 - 44 Electricity, Fast Reactor /Closed 300-600 Hydrogen Production (LFR) 1200 Molten Salt Thermal, Fluorides salts 700 - 800 1000 Max. 45 Electricity, Reactor Fast /Closed Hydrogen Production, (MSR) Actinide Recycle A Technology Roadmap for Generation IV Nuclear Energy Systems, December 2002 GIF R&D Outlook for Generation IV Nuclear Energy Systems, August 2009 7 Sodium-Cooled Fast Reactor (SFR) Features fast spectrum and closed fuel cycle – Can either burn actinides or breed fissile material High level of safety can be achieved through inherent and passive means R&D focus ESFR – Analyses and experiments that demonstrate safety approaches – High-burnup, minor actinide bearing fuels – Develop advanced components and energy conversion systems KALIMER JSFR SMFR 8 Designs Being Developed In the US, innovative fast reactor designs are being developed – Advanced burner sodium-cooled fast reactor (ABR) for waste management – Breed and burn nuclear systems for improved fuel utilization – Small modular reactors for near-term deployment in remote locations and other countries China has constructed CEFR, which achieved the initial criticality on July 21, 2010. Developing CFR-600 with oxide fuel, but will be converted to metallic fuel. In India, the 500 MWe DFBR is expected to be online soon; they plan to construct 4 more 500 MWe units by 2020, and then 1000 MWe plants Russia has constructed a BN-800 reactor, which achieved the initial criticality on June 27, 2014, and is developing the BN-1200 design Japan envisions commercial fast reactors by 2050, and plans to construct a demo plant by 2025 (JSFR) France envisions commercial fast reactors by ~2045, and plans a demo plant by 2020 (ASTRID) Korea is developing the 150 MWe PGSFR design for demonstrating TRU transmutation 9 Very High Temperature Reactor (VHTR) High temperature, helium cooled, graphite moderated reactor – High temperature enables non-electric applications Goal – reach 1000 °C, with near term focus on 700 - 950 °C Reference configurations are the prismatic and the pebble bed 10 Very High Temperature Reactor (VHTR) R&D focus on materials and fuels HTR-PM – Shared irradiation • Confirmed excellent performance of UO2 TRISO fuel – Develop a worldwide material handbook – Benchmarking of computer codes Japanese HTTR (30 MWt) is in operation – 50 days continuous operation at 950 °C completed March 2010 Chinese HTR-PM demonstration plant is under construction – Pebble bed core, 750 °C outlet temperature, steam cycle, 40% efficiency – Two 250 MWt NSSS modules for 210 MWe electricity – First concrete poured in Dec. 2012 – Plant operation expected around end of 2017 11 Gas-Cooled Fast Reactor (GFR) High temperature, helium cooled fast reactor with closed fuel cycle – Fast spectrum enables efficient use of uranium resources and waste minimization – High temperature enables non- electric applications – Non-reactive coolant eliminates material corrosion Very advanced system – Requires advanced materials and fuels Key R&D focus Decay heat removal (LOCA) is a challenge – SiC clad carbide fuel – High power density – High temperature components – Low thermal inertia and materials 12 Supercritical-Water-Cooled Reactor (SCWR) 30 Merges Gen-III+ reactor technology with compressible liquid supercritical fluid 25 advanced supercritical water technology SCWR used in coal plants 20 liquid PWR 15 Operates above the thermodynamic superheated vapor Pressure (MPa) Pressure 10 critical point (374 °C, 22.1 MPa) of water BWR vapor Fast and thermal spectrum options 5 0 Pressure tube or pressure vessel 250 350 450 550 Temperature (C) options Key R&D focus – Materials, water chemistry, and radiolysis – Thermal-hydraulics and safety to address gaps in SCWR heat transfer and critical flow databases – Fuel qualification 13 Lead-Cooled Fast Reactor (LFR) Lead is not chemically reactive with ELFR air or water – Highly corrosive and erosive Fast spectrum and closed fuel cycle Three design thrusts – European Lead Cooled Fast Reactor (Large, central station) – Russian BREST-OD-300 (Medium size) – US SSTAR (Small transportable system) R&D focus – 1500 MWt / 600 MWe – Materials corrosion – MOX fuel – High burnup, MA-bearing fuels – Coolant temp., 400/480C – Max. clad temp., 550C – Safety – Efficiency: ~42% – Breeding ratio: ~1 14 LFR Concepts Being Studied BREST-OD-300 SSTAR – 700 MWt / 300 MWe – SSTAR is a small natural – UN+PuN fuel circulation fast reactor of 20 – Coolant temp: 420/540C MWe/45 MWt, that can be scaled up to 180 MWe/400 MWt. – Max. cladding temp., 650C – Uranium nitride fuel with 15-20 – Efficiency: 42% year lifetime – Breeding ratio: ~1 15 Molten Salt Reactor (MSR) High temperature system Design options – Fuel dissolved in molten salt coolant • Traditional MSF concept • On-line waste management – Solid fuel with molten salt coolant • VHTR + molten salt coolant Key R&D focus – Neutronics – Materials and components – Safety and safety systems MSFR – Since 2005, European R&D interest – Liquid salt chemistry and properties has focused on Molten Salt Fast – Salt processing neutron Reactor (MSFR) as a long term alternative to solid fueled fast neutrons reactors 16 MSR Concepts Studied Two reactors concepts using molten salt are studied in the GIF MSR – Molten salt reactors, in which the salt is both the fuel and the coolant • France and Euratom work on MSFR • Russia works on MOSART (Molten Salt Actinide Recycler & Transmuter) – Reactors with solid fuel cooled by molten salt • USA and China work on FHR (fluoride salt-cooled |high-temperature reactor) concepts 17 Summary Generation-IV systems are being developed worldwide – Gen-IV International Forum was established in 2001 and provides an international framework for development of Gen-IV systems – Collaborative projects started with significant R&D investment worldwide – Prototype demonstration reactors are being designed and/or built • SFR (France and Russia) • VHTR (China) Much still needs to be done before Gen-IV systems become a reality – Continue R&D on Gen-IV systems – Develop advanced research facilities – Engage industry on the design of Gen-IV systems – Develop the workforce for the future 18 .
Recommended publications
  • Transition-Metal-Bridged Bimetallic Clusters with Multiple Uranium–Metal Bonds
    ARTICLES https://doi.org/10.1038/s41557-018-0195-4 Transition-metal-bridged bimetallic clusters with multiple uranium–metal bonds Genfeng Feng1, Mingxing Zhang1, Dong Shao 1, Xinyi Wang1, Shuao Wang2, Laurent Maron 3* and Congqing Zhu 1* Heterometallic clusters are important in catalysis and small-molecule activation because of the multimetallic synergistic effects from different metals. However, multimetallic species that contain uranium–metal bonds remain very scarce due to the difficulties in their synthesis. Here we present a straightforward strategy to construct a series of heterometallic clusters with multiple uranium–metal bonds. These complexes were created by facile reactions of a uranium precursor with Ni(COD)2 (COD, cyclooctadiene). The multimetallic clusters’ cores are supported by a heptadentate N4P3 scaffold. Theoretical investigations indicate the formation of uranium–nickel bonds in a U2Ni2 and a U2Ni3 species, but also show that they exhibit a uranium–ura- nium interaction; thus, the electronic configuration of uranium in these species is U(III)-5f26d1. This study provides further understanding of the bonding between f-block elements and transition metals, which may allow the construction of d–f hetero- metallic clusters and the investigation of their potential applications. ultimetallic molecules are of great interest because of This study offers a new opportunity to investigate d− f heteromul- their fascinating structures and multimetallic synergistic timetallic clusters with multiple uranium–metal bonds for small- Meffects for catalysis and small molecule activation1–7. Both molecule activation and catalysis. biological nitrogen fixation and industrial Haber–Bosch ammonia syntheses, for example, are thought to utilize multimetallic cata- Results and discussion lytic sites8,9.
    [Show full text]
  • Process for the Production of Uranium Trifluoride
    United States Patent im [in 3,964,965 Tagawa [45] June 24, 1976 [54] PROCESS FOR THE PRODUCTION OF URANIUM TRIFLUORIDE [56] References Cited [75] Inventor: Hiroaki Tagawa, Tokaimura, Japan UNITED STATES PATENTS [73] Assignee: Japan Atomic Energy Research 3,034,855 5/1962 Jenkins et al 423/258 Institute, Tokyo, Japan [22] Filed: Dec. 20, 1973 Primary Examiner—Stephen J. Lechert, Jr. Attorney, Agent, or Firm—Stevens, Davis, Miller & [21] Appl. No.: 426,593 Mosher [30] Foreign Application Priority Data [57] ABSTRACT Dec. 26, 1972 Japan 47-129560 A novel method is disclosed for producing a pure ura- nium trifluoride efficiently. Said method is character- [52] U.S. CI 423/258; 423/259; ized by heating a mixture of uranium tetrafluoride and 252/301.1 R uranium nitride in an inert gas stream or under [51] Int. CI.2. C01G 43/06 vacuum. [58] Field of Search 423/258, 259; 252/301.1 R 2 Claims, No Drawings 3,976, 1 2 PROCESS FOR THE PRODUCTION OF URANIUM DETAILED DESCRIPTION OF INVENTION TRIFLUORIDE According to the present invention, uranium trifluo- ride is produced by heating a mixture of uranium tetra- BACKGROUND OF THE INVENTION 5 fluoride and uranium nitride in the form of powder or 1. Field of the Invention molding in a stream of inert gas or under vacuum. In The present invention relates to a method for pro- this invention, uranium sesquinitride (U2N3) or ura- duction of pure uranium trifluoride characterized by nium mononitride (UN) can be used for the starting heating a mixture of uranium tetrafluoride and uranium material.
    [Show full text]
  • Impact of the Synthesis Process on Structure Properties for AFCI Fuel Candidates
    Fuels Campaign (TRP) Transmutation Research Program Projects 2007 Impact of the Synthesis Process on Structure Properties for AFCI Fuel Candidates Kenneth Czerwinski University of Nevada, Las Vegas, [email protected] Follow this and additional works at: https://digitalscholarship.unlv.edu/hrc_trp_fuels Part of the Nuclear Commons, Nuclear Engineering Commons, and the Oil, Gas, and Energy Commons Repository Citation Czerwinski, K. (2007). Impact of the Synthesis Process on Structure Properties for AFCI Fuel Candidates. 60-61. Available at: https://digitalscholarship.unlv.edu/hrc_trp_fuels/72 This Annual Report is protected by copyright and/or related rights. It has been brought to you by Digital Scholarship@UNLV with permission from the rights-holder(s). You are free to use this Annual Report in any way that is permitted by the copyright and related rights legislation that applies to your use. For other uses you need to obtain permission from the rights-holder(s) directly, unless additional rights are indicated by a Creative Commons license in the record and/or on the work itself. This Annual Report has been accepted for inclusion in Fuels Campaign (TRP) by an authorized administrator of Digital Scholarship@UNLV. For more information, please contact [email protected]. Task 28 Impact of the Synthesis Process on Structure Properties for AFCI Fuel Candidates K. Czerwinski BACKGROUND actinide nitrides. x To characterize actinide nitrides structurally and thermally. Synthesis of actinium mononitrides using carbothermic reduction x To use high resolution TEM techniques to explore the micro- of the corresponding oxides has a few outstanding issues, includ- structure of the radioactive samples. ing the formation of secondary phases such as oxides and carbides and low densities of the final product.
    [Show full text]
  • Impact of the Synthesis Process on Structure Properties for AFCI Fuel Candidates
    Fuels Campaign (TRP) Transmutation Research Program Projects 2008 Impact of the Synthesis Process on Structure Properties for AFCI Fuel Candidates Kenneth Czerwinski University of Nevada, Las Vegas, [email protected] Follow this and additional works at: https://digitalscholarship.unlv.edu/hrc_trp_fuels Part of the Nuclear Commons, Nuclear Engineering Commons, Oil, Gas, and Energy Commons, and the Radiochemistry Commons Repository Citation Czerwinski, K. (2008). Impact of the Synthesis Process on Structure Properties for AFCI Fuel Candidates. 60-61. Available at: https://digitalscholarship.unlv.edu/hrc_trp_fuels/73 This Annual Report is protected by copyright and/or related rights. It has been brought to you by Digital Scholarship@UNLV with permission from the rights-holder(s). You are free to use this Annual Report in any way that is permitted by the copyright and related rights legislation that applies to your use. For other uses you need to obtain permission from the rights-holder(s) directly, unless additional rights are indicated by a Creative Commons license in the record and/or on the work itself. This Annual Report has been accepted for inclusion in Fuels Campaign (TRP) by an authorized administrator of Digital Scholarship@UNLV. For more information, please contact [email protected]. Task 28 Impact of the Synthesis Process on Structure Properties for AFCI Fuel Candidates K. Czerwinski BACKGROUND • To use high resolution TEM techniques to explore the micro- structure of the radioactive samples. Synthesis of actinium mononitrides using carbothermic reduction of the corresponding oxides has a few outstanding issues, includ- RESEARCH ACCOMPLISHMENTS ing the formation of secondary phases such as oxides and carbides and low densities of the final product.
    [Show full text]
  • Nitride Fuel for Gen IV Nuclear Power Systems
    Journal of Radioanalytical and Nuclear Chemistry (2018) 318:1713–1725 https://doi.org/10.1007/s10967-018-6316-0 Nitride fuel for Gen IV nuclear power systems Christian Ekberg1 · Diogo Ribeiro Costa2,3 · Marcus Hedberg1 · Mikael Jolkkonen2 Received: 20 October 2018 / Published online: 10 November 2018 © The Author(s) 2018 Abstract Nuclear energy has been a part of the energy mix in many countries for decades. Today in principle all power producing reactors use the same techniqe. Either PWR or BWR fuelled with oxide fuels. This choice of fuel is not self evident and today there are suggestions to change to fuels which may be safer and more economical and also used in e.g. Gen IV nuclear power systems. One such fuel type is the nitrides. The nitrides have a better thermal conductivity than the oxides and a similar melting point and are thus have larger safety margins to melting during operation. In addition they are between 30 and 40% more dense with respect to fssile material. Drawbacks include instability with respect to water and a sometimes complicated fabrication route. The former is not really an issue with Gen IV systems but for use in the present feet. In this paper we discuss both production and recycling potential of nitride fuels. Keywords Nuclear fuel · Nitride nuclear fuels · Gen IV · Production of nitrides · Nuclear fuel recycling · Dissolution of nitrides Introduction sustainability, safety and reliability, economic competitive- ness, and proliferation resistance and physical protection. Nuclear power is today a disputed technique although it is in Such a system comprise fast reactors, separation facilities for principle ­CO2 free and highly energetic.
    [Show full text]
  • Appendix 2: Development of LWR Fuels with Enhanced Accident Tolerance; Task 2 – Description of Research & Development Required to Qualify
    Appendix 2: Development of LWR Fuels with Enhanced Accident Tolerance; Task 2 – Description of Research & Development Required to Qualify the Technical Concept Westinghouse Non-Proprietary Class 3 Award Number DE-NE0000566 Development of LWR Fuels with Enhanced Accident Tolerance Task 2 – Description of Research & Development Required to Qualify the Technical Concept RT-TR-13-8 May 31, 2013 Westinghouse Electric Company LLC 1000 Cranberry Woods Drive Cranberry Woods, PA 16066 Principal Investigator: Dr. Edward J. Lahoda Project Manager: Frank A. Boylan Author: Peng Xu Team Members Westinghouse Electric Company LLC General Atomics Idaho National Laboratory Massachusetts Institute of Technology Texas A&M University Los Alamos National Laboratory Edison Welding Institute Southern NuclearNucl Operating Company Southern Nuclear Company Table of Contents Executive Summary ...................................................................................................................... 3 Introduction ................................................................................................................................ 5 Task 2.1. Cladding Bench Scale Development (Phase 2) ................................................... 5 Subtask 2.1.1. Coated Zr Alloy Tube Processing Bench Scale Development (Phase 2) ...... 5 Subtask 2.1.2. SiC CMC Processing Bench Scale Development (Phase 2) ......................... 6 Subtask 2.1.3. Post ATF Cladding Fabrication Processing ................................................... 8 Subtask 2.1.4.
    [Show full text]
  • First Principles Investigations of Electronic, Magnetic and Bonding Peculiarities of Uranium Nitride-Fluoride UNF
    First principles investigations of electronic, magnetic and bonding peculiarities of uranium nitride-fluoride UNF. Samir F Matar CNRS, University of Bordeaux, ICMCB. 33600 Pessac. France Emails: [email protected] and [email protected] Abstract: Based on geometry optimization and magnetic structure investigations within density functional theory, unique uranium nitride fluoride UNF, isoelectronic with UO2, is shown to present peculiar differentiated physical properties. Such specificities versus the oxide are related with the mixed anionic sublattices and the layered-like tetragonal structure 2+ 2- characterized by covalent like [U2N2] motifs interlayered by ionic like [F2] ones and illustrated herein with electron localization function graphs. Particularly the ionocovalent chemical picture shows, based on overlap population analyses, stronger U-N bonding versus N-F and d(U-N) < d(U-F) distances. Based on LDA+U calculations the ground state magnetic structure is insulating antiferromagnet with ±2 B magnetization per magnetic subcell and ~2 eV band gap. Keywords: Uranium compounds; DFT; magnetism; bonding 1 1. Introduction From the iso-electronic relationship for valence shell states: 2 O (2s2, 2p4) N (2s2, 2p3) + F (2s2, 2p5), nitride-fluorides of formulation MIVNF type can be considered as IV IV pseudo-oxides and isoelectronic with M O2 (M stands for a generic tetravalent metal). Versus homologous oxides, some relevant physical properties can be expected due to differentiated bonding of M with nitrogen and fluorine qualified as less and more ionic respectively. A small number of tetravalent metal nitride-fluorides exist like transition metal based TiNF [1] and ZrNF [2] on one hand and heavier actinide equiatomic ternaries as ThNF [3] and UNF [4,5] on the other hand.
    [Show full text]
  • Achievable Power Uprates in Pressurized Water Reactors Using Uranium Nitride Fuel
    Achievable Power Uprates in Pressurized Water Reactors Using Uranium Nitride Fuel by Guillaume Giudicelli Ingénieur diplômé de l’Ecole Polytechnique, 2016 SUBMITTED TO THE DEPARTMENT OF NUCLEAR SCIENCE AND ENGINEERING IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF MASTER OF SCIENCE IN NUCLEAR SCIENCE AND ENGINEERING AT THE MASSACHUSETTS INSTITUTE OF TECHNOLOGY FEBRUARY 2017 ○c 2017 Massachusetts Institute of Technology. All rights reserved Signature of Author: Department of Nuclear Science and Engineering Certified by: Koroush Shirvan Principal Research Scientist Thesis Supervisor Read by: Ronald G. Ballinger Professor of Nuclear Science and Engineering, and Materials Science and Engineering Thesis Reader Accepted by: Ju Li Battelle Energy Alliance Professor of Nuclear Science and Engineering Professor of Materials Science and Engineering Chair, Committee on Graduate Students Abstract Achievable Power Uprates in Pressurized Water Reactors Using Uranium Nitride Fuel This work aims at investigating the potential benefits of nitride fuel use in pressurized water reactors. The AP1000 is chosen as the reference power plant. Both oxide and nitride fuel are considered and compared using a steady state thermal hydraulics and mechanics parametric optimization study to achieve a maximal core power. A subsequent neutronics study determined the achievable energy extracted per fuel mass (burnup) and sets the core power that allows for an 18-months fuel cycle length. The impact of the change in the core operating temperature on the steam cycle efficiency is considered in order to provide a final evaluation of the electric power uprate. The steady state limits considered are pressure drop, minimum departure from nucleate boiling ratio, fretting and sliding wear and fuel average and centerline temperatures.
    [Show full text]
  • First-Principles Investigations of the Electronic and Magnetic Structures
    Z. Naturforsch. 2017; 72(10)b: 725–730 Samir F. Matar* First-principles investigations of the electronic and magnetic structures and the bonding properties of uranium nitride fluoride (UNF) https://doi.org/10.1515/znb-2017-0096 respectively. A small number of tetravalent metal nitride Received May 12, 2017; accepted June 13, 2017 fluorides exist such as transition metal-based TiNF [1] and ZrNF [2] on one hand and heavier actinide equia- Abstract: Based on geometry optimization and magnetic tomic ternaries such as ThNF [3] and UNX (X = halogen) structure investigations within density functional theory, [4, 5] on the other hand. Besides the actinide-based a unique uranium nitride fluoride, isoelectronic with compounds, only the rare-earth ternary CeNCl was UO , is shown to present peculiar differentiated physical 2 evidenced by Ehrlich et al. [6]. Recently, CeNF [7] was properties. These specificities versus the oxide are related proposed with potential experimental synthesis routes to the mixed anionic substructure and the layered-like besides a full account of physical properties based on tetragonal structure characterized by covalent-like [U N ]2+ 2 2 extended theoretical works within well-established motifs interlayered by ionic-like [F ]2− ones and illustrated 2 density functional theory (DFT) [8, 9]. In fact, it has been herein with electron localization function projections. shown in recent decades that this theory with DFT-based Particularly, the ionocovalent chemical picture shows, methods allowed us not only to explain and interpret based on overlap population analyses, stronger U–N experimental results resolved at the atomic chemical bonding versus U–F and d(U–N) < d(U–F) distances.
    [Show full text]
  • Nitride Fuel for Gen IV Nuclear Power Systems
    Nitride fuel for Gen IV nuclear power systems Downloaded from: https://research.chalmers.se, 2021-10-01 01:42 UTC Citation for the original published paper (version of record): Ekberg, C., Costa, D., Hedberg, M. et al (2018) Nitride fuel for Gen IV nuclear power systems Journal of Radioanalytical and Nuclear Chemistry, 318(3): 1713-1725 http://dx.doi.org/10.1007/s10967-018-6316-0 N.B. When citing this work, cite the original published paper. research.chalmers.se offers the possibility of retrieving research publications produced at Chalmers University of Technology. It covers all kind of research output: articles, dissertations, conference papers, reports etc. since 2004. research.chalmers.se is administrated and maintained by Chalmers Library (article starts on next page) Journal of Radioanalytical and Nuclear Chemistry (2018) 318:1713–1725 https://doi.org/10.1007/s10967-018-6316-0 Nitride fuel for Gen IV nuclear power systems Christian Ekberg1 · Diogo Ribeiro Costa2,3 · Marcus Hedberg1 · Mikael Jolkkonen2 Received: 20 October 2018 / Published online: 10 November 2018 © The Author(s) 2018 Abstract Nuclear energy has been a part of the energy mix in many countries for decades. Today in principle all power producing reactors use the same techniqe. Either PWR or BWR fuelled with oxide fuels. This choice of fuel is not self evident and today there are suggestions to change to fuels which may be safer and more economical and also used in e.g. Gen IV nuclear power systems. One such fuel type is the nitrides. The nitrides have a better thermal conductivity than the oxides and a similar melting point and are thus have larger safety margins to melting during operation.
    [Show full text]
  • Production of Low-Enriched Uranium Nitride Kernels for TRISO Particle Irradiation Testing
    ORNL/SR-2016/268 Revision: 0 Production of Low-Enriched Uranium Nitride Kernels for TRISO Particle Irradiation Testing Fuel Cycle Research & Development Advanced Fuels Campaign J. W. McMurray C. M. Silva G. W. Helmreich T. J. Gerczak J. A. Dyer J. L. Collins R. D. Hunt T. B. Lindemer K. A. Terrani Approved for public release. Distribution is unlimited. Prepared for U. S. Department of Energy Office of Nuclear Energy June 2016 M2FT-16OR020201061 DISCLAIMER This information was prepared as an account of work sponsored by an agency of the U.S. Government. Neither the U.S. Government nor any agency thereof, nor any of their employees, makes any warranty, expressed or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness, of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. References herein to any specific commercial product, process, or service by trade name, trade mark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the U.S. Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the U.S. Government or any agency thereof. ORNL/SR-2016/268 Revision 0 Production of Low-Enriched Uranium Nitride Kernels for TRISO Particle Irradiation Testing J. W. McMurray C. M. Silva G. W. Helmreich T. J. Gerczak J. A. Dyer J. L. Collins R. D. Hunt T. B. Lindemer K. A. Terrani June 2016 Prepared by OAK RIDGE NATIONAL LABORATORY Oak Ridge, TN 37831-6283 managed by UT-BATTELLE, LLC for the US DEPARTMENT OF ENERGY under contract DE-AC05-00OR22725 INTENTIONALLY BLANK v ABSTRACT A large batch of UN microspheres to be used as kernels for TRISO particle fuel was produced using carbothermic reduction and nitriding of a sol-gel feedstock bearing tailored amounts of low-enriched uranium (LEU) oxide and carbon.
    [Show full text]
  • Research and Development of Nitride Fuel Cycle Technology in Japan Is Reviewed and the Research Program PROMINENT Is Introduced
    JAERI-Conf 2004-015 JP0550058 2* Session B: Present State of the Technology Development In Japan 2.1 Research and Development of Nitride Feel Cycle Technology in Japan Kazuo MINATO', Yasuo ARAI \ Mftsuo AKABORI1, Masayoshi UNO 2, Yoshihisa TAMAKI3, Kueihiro ITOH4 Japan Atomic Energy Research Institute ' Graduate School of Engineering, Osaka University 1 Mitsubishi Materials Corporation Nuclear Development Corporation, •25- This is a blank page. JAERI-Conf 2004-015 Research and Development of Nitride Feel Cycle Technology In Japan Kara© MMATO \ Yasuo ARAI \ Mitsuo AKABORI1, 2 3 4 Masayoshi UNO ? Yoshihisa TAMAKI , Kunihiro ITOH 1 Japan Atomic Energy Research Institute, Tokai-mura, Ibaraki-ken, 319-1195 Japan Graduate School of Engineering, Osaka University, Suita-shi, Osaka, 565-0871 Japan Mitsubishi Materials Corporation, Naka-machi, Ibaraki-ken, 311-0102 Japan 4 Nuclear Development Corporation, Tokai-mura, Ibaraki-ken, 319-1111 Japan [email protected] Abstract The research on the nitride fuel was started for an advanced fuel, (U,Pu)N, for fast reactors, and the research activities have been expanded to minor actinide bearing nitride fuels. The fuel fabrication, property measurements, irradiation tests and pyrochemical process experiments have been made. In 2002 a five-year-program named PROMINENT was started for the development of nitride fuel cycle technology within the framework of the Development of Innovative Nuclear Technologies by the Ministry of Education, Culture, Sports, Science and Technology of Japan. In the research program PROMINENT, property measurements, pyrochemical process and irradiation experiments needed for nitride fuel cycle technology are being made. 1. Introduction The research on the nitride fuel was started for an advanced fuel for fast reactors.
    [Show full text]