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1. EXECUTIVE SUMMARY M/s. Jayshree Aromatics Pvt. Ltd. is located at Plot No. 4703,4704, 4705/1/2/3/4, GIDC, Ankleshwar-393002, District: Bharuch, Gujarat. The unit has valid CCA No. AWH:69365 & its Amendment A-87838which is valid till 11.12.2020 for manufacturing of Aromatics Compounds. Total existing production capacity is 441.2MT/Month. After expansion, total proposed production capacity will be 7662 MT/Month. The proposed products by the unit fall in the Schedule attached to the EIA Notification, i.e. Project No. 5(f), Synthetic Organic Chemicals (Aromatics Chemicals). The site is situated in notified industrial estate, Ankleshwar, Dist.: Bharuch so, it is categorized as category B. The details of products are given below table. TABLE: 1 LIST OF EXISTING PRODUCTS GROUP: A – 100 MT/Month Sr.No. Product Name Quantity (MT/Month) 1 Aurantine 2 Citral Pure 3 Citronellal 4 Ambrettolide Extra 5 Benzal Chloride 6 Benzaldehyde& Sodium Benzoate 7 Benzo Tri Chloride 8 Benzyl Acetone Extra 9 Benzyl Chloride 10 Benzyl Cinnamate Benzyl Alcohol 11 Benzyl Cinnamate Ex Benzyl Chloride 12 Benzyl Formate Ex Benzyl Alcohol 13 Benzyl Formate Ex Benzyl Chloride 14 Benzyl Phenyl Acetate 15 Beta Methyl Ionone 16 Cineole 98 % Rectified 17 Cinnamic Acid Extra 18 Cinnamylidene Acetaldehyde 19 Citronellyl Butyrate 20 CitronellylFormate 21 Citronellyl Propionate 22 D Limonene 23 DCPD Iso Butyrate 24 DCPD Propionate 25 Decanal 26 Decanoic Acid 27 Decyl Alcohol 28 Delta Damascone Extra 29 Di Ethyl Phthalate Extra 30 Ebanol Extra 31 Ethyl Butyrate 32 Ethyl Cinnamate 33 Ethyl Phenyl Acetate 34 Ethyl Propionate 35 Eucalyptol 100 36 Eugenol 37 Geraniol Extra 38 GeranylFormate 39 Geranyl Propionate 40 Greenone 41 Hydro Cinnamic Acid Extra 42 Hydro Cinnamic Aldehyde Extra 43 Indole Extra 44 Iso Amyl Alcohol Flavor Grade 45 Iso Butyl Phenyl Acetate 46 Iso Butyl Salicylate 47 IsoNonyl Acetate 48 LevoSandecol Extra 49 Methyl Cinnamate 50 Methyl Heptenone Extra 51 Methyl Phenyl Acetate 52 Nerol Super 53 NerolineBromelia Extra 54 Normal Amyl Phenyl Acetate 55 Normal Butyl Phenyl Acetate 56 Octanal 57 Octanoic Acid 58 Octanol 59 Orange Oil 10 Fold 60 Orange Oil 25 Fold 61 Orange Oil 4 Fold 62 Orange Oil 40 Fold 63 Orange Oil 5 Fold 64 Para Anisic Alcohol Extra 65 Para Anisic Aldehyde Extra 66 Para Cresyl Phenyl Acetate Extra 67 Phenyl Ethyl Alcohol Extra 68 Phenyl Ethyl Cinnamate 69 Phenyl Ethyl Formate 70 Phenyl Ethyl Iso Butyrate 71 Phenyl Ethyl Valerinate 72 Phenyl Propyl Alcohol Pure 73 Rhodinol IPL 74 Schiff Base Of Citronella 75 Skatole Extra 76 Styrallyl Extra 77 YaraYara Pure 78 Pseudo Methyl Ionone GROUP: B – 160 MT/Month Sr.No. Product Name Quantity (MT/Month) 1 Amyl Acetate 2 Benzyl Acetate 3 Benzyl Butyrate 4 Benzyl Iso Butyrate 5 Benzyl Propionate 6 Cinnamic Aldehyde 7 Citronellol 8 Clove oil rectified 9 Di methyl octanol 10 Gamma methyl ionone/ methyl ionone 11 Hexyl cinnamic aldehyde 12 Jasma floor 13 Phenyl ethyl propionate 14 Schiff base of cinnamic aldehyde 160 15 2 Ethyl butyl propionate 16 Amyl propionate 17 Amyl cinnamate 18 Cinnamyl acetate 19 Citronellidene acetone 20 Hexyl benzoate 21 Hydroxy dimethyl acetal 22 Iso amyl phenyl ether 23 Methyl ionone 24 Phenyl acetic acid extra 25 Phenyl ethyl butyrate 26 Ionone 100% 27 Ionone Alpha GROUP:C – 60 MT/Month Sr.No. Product Name Quantity (MT/Month) 1 Alpha amyl cinnamic aldehyde 2 Citronellyl acetate 3 Amyl butyrate 4 Amyl benzoate 5 Citral di methyl acetal 6 Cyclohexyl salicylate 60 7 Geranyl acetate 8 Glycogrenal 9 Di methyl octanyl acetate 10 Gamma pseudo methyl ionone/ pseudo methyl ionone 11 Phenyl ethyl acetate 12 Phenyl ethyl phenyl acetate 13 Aldehyde C16 14 Alpha methyl cinnamic aldehyde 15 Hexyl salicylate 16 Lillal 17 Mixed amyl salicylate 18 Neryl acetate 19 Para cresyl benzyl ether 20 Phenyl ethyl salicylate 21 Benzyl Alcohol 22 Amyl Salicylate 23 Benzyl Benzoate 24 Benzyl Salicylate 25 Cinnamic Alcohol 26 Pseudo Ionone GROUP: D – 40 MT/Month Sr.No. Product Name Quantity (MT/Month) 1 Phenyl ethyl methyl ether 2 2 Ethyl butyl ether 3 Cinnamyl butyrate 4 Cinnamylformate 5 Cinnamyl propionate 40 6 Citral diethyl acetal 7 DCPD acetate 8 Hydro aldehyde dimethyl acetal 9 Styrallyl acetate 10 Styrallyl propionate GROUP: E – 15 MT/Month Sr.No. Product Name Quantity (MT/Month) 1 Cinnamic Nitrile 2 Citronellyl Nitrile 3 Geranyl Nitrile 15 4 Hydroxy Citronellal 5 Hydroxy Citronellal Extra 6 Iso Amyl Benzyl Ether GROUP: F – 25 MT/Month Sr.No. Product Name Quantity (MT/Month) 1 Beta Ionone 25 INDIVIDUAL PRODUCTS: Sr.No. Product Name Quantity (MT/Month) 1 Benzyl Acetate 2 2 Benzyl Alcohol 2 3 Benzyl Benzoate 2 4 Benzyl Propionate 2 5 Benzyl Salicylate 2 6 Benzyl Butyrate 2 7 Amyl Salicylate 2 8 Alpha Amyl Cinnamic aldehyde 3 9 Cinnamic Aldehyde 2 10 Cinnamic Alcohol 3 11 Ionone Alpha 2 12 Ionone 100% 2 13 Pseudo Methyl Ionone 2 14 Pseudo Ionone 2 By-products 1. High boiling compound 1.2 2. Sodium benzoate 10 Summary for Groups: Sr.No. Product Name Quantity (MT/Month) 1. Group A 100 2. Group B 160 3. Group C 60 4. Group D 40 5. Group E 15 6. Group F 25 7. Individual products 30 8. By-products 11.2 Total 441.2 TABLE 2: LIST OF PROPOSED PRODUCTS Quantity Sr.No. Product Name (MT/Month) (proposed) Perfumery Esters by hot esterification / Addition of organic acid in to 1 olefins/ Transesterification/ Reacting Alkali halide with sodium salt of 160 corresponding acid. Perfumery alcohol by Grignard reaction / By reduction of aldehyde or ketone by hydrogen/ By addition of water into Olefins / By saponification of esters. Perfumery aldehyde by ester rearrangement / de hydrogenation of alcohols / 2 160 Reduction of acids / Aldol condensation Ketal/ Acetals/ Substituted 1,3 - propanidids/ Ambrettolide / Ketone by aldol condensation / Nitriles/ cyclo propyl acetylene in organic salts. Alpha Damascone Beta Damascone 3 150 Bourgenol Muguet alcohol 4 Sodium salt of various acids 800 Chlorination of Organics compound /Esterification of Alkyl halide with 5 sodium salts of acids/Hydrolysis of Alkyl halide/ Condensation & 800 Cyclization of aldehyde & Ketone. Hydrogenation of Organic Compounds / 6 800 Hydrogenation of Nitro to Amino 7 Mixing and distillation process. 500 8 Safranal 1 9 CycloCitral 5 10 Cinnamic aldehyde 300 11 Citronellal 200 12 Citronellol extra 200 13 Hexyl cinnamic aldehyde 160 14 Phenyl ethyl alcohol 250 15 Phenyl propyl alcohol 100 16 Methyl Benzoate 160 17 Phenoxy ethyl iso butyrate 160 18 cyclogalbanate 60 19 Styrallyl alcohol 200 20 Beta ionone 100 21 Gamma methyl ionone 200 22 Gamma pseudo methyl ionone/ pseudo methyl ionone 200 23 Hydroxy citronellal 150 24 Ionone 100% 200 25 Ionone alpha 200 26 Methyl ionone/Beta methyl ionone 200 27 Pseudo ionone 200 28 Benzyl alcohol and Di Benzyl ether 100 29 Amyl acetate 160 30 Styrallyl acetate 200 31 Woody sols (High boilers) 586 Total 7662 1.1COST OF PROJECT The expansion will be carried out at existing plot in GIDC Ankleshwar. The expected cost of proposed project is Rs.15 Crores 1.2 LAND The total plot area of the unit is 19000Square Meter. The green belt area will be 1868.33 Square Meter. 1.3 FUEL CONSUMPTION As per CCA As per CCA, the unit is consuming, Agro-waste/ Briquettes for its 3TPH & 4TPH Boilers, at the consumption rate of 1450 kg/hr. and Natural gas containing 1600 m3/day and 600 m3/day for 10 Lac kcal/hr and 4Lac kcal/hr of Thermic fluid heater respectively. Diesel is being used for the DG Set of 385 KVA at the rate of 165 lit /hr, which is being used only in-case of emergencies/Power failure. Proposed scenario For the proposed project, unit will consume Agro-waste/ Briquettes for its proposed additional boilers of 5 TPH & 6 TPH boiler with the consumption rate of 2.1 MT/Hr. natural gas at the rate of 1600 m3/day will be consumed for its proposed additional thermic fluid heater. Additional Diesel will be used for the DG Set of 500 KVA at the rate of 165 lit /hr., which will be used only in-case of emergencies/Power failure. Total Proposed Flue Gas Emission Stack Sr. Fuel APCM Paramet Permissible Stack attached to Height no er Limit in meter 3 D.G. Sets PM 150 mg/Nm 1. 385 KVA stand 9 Diesel NA SO2 100 ppm by NOX 50 ppm Boiler-1(3 THP) Boiler-2 (3 THP 2. Common Bag filter, stand by) PM 150 mg/Nm3 stack Multi Agro waste/ Boiler-3(4 THP) cyclone, SO 100 ppm Briquettes 2 Water Boiler-IV (5 THP) NOX 50 ppm 33 scrubber 3. Boiler –V (6 TPH) PM 150 mg/NM3 Thermic fuel 4. heater (4 lac 15 N.A. SO2 100 PPM Kcal/hr) Natural Gas NOx 50 PPM Thermic fuel 5. heater (10 lac PM 150 mg/NM3 kcal/hr) 15 N.A. SO2 100 PPM Thermic fuel Natural gas 6. heater (10 lac NOx 50 PPM kcal/hr) WATER As per consent, total water consumption is 169.4 KLD out of which the unit is consuming 147.9 KLD water for industrial activities (127.9 KLD freshwater and 20 KLD of recycled water) and rest 21.5 KLD for domestic and greenbelt. The total water consumption after expansion will be 513 KLD (227 KLD Fresh Water & 286 KLD of treated water will be reused). Out of 513 KLD, 488 KLD will be used for Industrial manufacturing activities whereas 10 KLD for domestic activities and 15 KLD for Gardening. Stream wise bifurcation of water consumption is given in Table 8.
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    Ollass 54 1 .33 y&vok^o. 16971 pkary p CHEMfSTRY LIBRARY RULES This book may be kept... Q/?.£? weeks. A fine of two cents will be charged for each day books or magazines are kept overtime. Two books may be borrowed from the Library at one time. Any book injured or lost shall be paid for by the person to whom it is charged. No member shall transfer his right to use the Library to any other person. CATALYTIC PROCESSES IN APPLIED CHEMISTRY A SERIES OF MONOGRAPHS ON APPLIED CHEMISTRY Under the Editorship of E. Howard Tripp, Ph.D. Already Published. THE MANUFACTURE OF ARTIFICIAL SILK. With Special Reference to the Viscose Process. By E. Wheeler, M.B.E., A.C.G.I., A.I.C., with a Foreword by Sir William J. Pope, K.B.E., D.Sc. Demy8vo. 165 pages. 50 illustrations. 12/6 net. CATALYTIC PROCESSES IN APPLIED CHEMISTRY. By T. P. Hilditch, D.Sc, F.I.C. Demy 8vo. 370 pages. 16/- net. In the Press. HYDROGEN ION CONCENTRATIONS. Their Determination and Industrial Importance. By H. T. S. Britton, D.Sc, B.Sc, D.I.C., F.I.C. In Preparation. SOLVENTS. T. H. Durrans, D.Sc, F.I.C. MINERAL LUBRICATING OILS. A. E. Dunstan, D.Sc, F.I.C. ARTIFICIAL RESINS AND RELATED COLLOIDS. A. A. Drummond, M.Sc, A.I.C. METHODS OF CELLULOSE CHEMISTRY. C. Doree, M.A., D.Sc, F.I.C. <><> Other volumes are in course of preparation, and detailed particulars will be sent from time to time to anyone sending a request.
  • (19) United States (12) Patent Application Publication (10) Pub

    (19) United States (12) Patent Application Publication (10) Pub

    US 20070088508A1 (19) United States (12) Patent Application Publication (10) Pub. No.: US 2007/0088508 A1 Childs (43) Pub. Date: Apr. 19, 2007 (54) COCRYSTALLIZATION METHODS Related US. Application Data (60) Provisional application No. 60/721,115, ?led on Sep. (76) Inventor: Scott Childs, Atlanta, GA (US) 28, 2005. Publication Classi?cation Correspondence Address: (51) Int. Cl. FINNEGAN, HENDERSON, FARABOW, GARRETT & DUNNER G06F 19/00 (2006.01) (52) US. Cl. .............................................................. .. 702/19 LLP 901 NEW YORK AVENUE, NW (57) ABSTRACT WASHINGTON, DC 20001-4413 (US) Methods for preparing cocrystals Wherein solutions of active agents in suitable liquids are combined With solutions of (21) Appl. No.: 11/527,395 guests, both With and Without suitable liquids, in an interface region are described herein. Methods for analyzing the (22) Filed: Sep. 27, 2006 cocrystals are also described. Patent Application Publication Apr. 19, 2007 Sheet 1 0f 2 US 2007/0088508 A1 Patent Application Publication Apr. 19, 2007 Sheet 2 0f 2 US 2007/0088508 A1 US 2007/0088508 A1 Apr. 19, 2007 COCRYSTALLIZATION METHODS costs, and manufacturing method may be modi?ed by using [0001] This application claims the bene?t of priority to a cocrystal rather than the active agent alone, or as a salt. provisional application No. 60/721,115, ?led on Sep. 28, [0006] An active agent can be screened for possible coc 2005, the contents of Which are incorporated by reference rystals Where polymorphic forms, hydrates, or solvates are herein. especially problematic. For example, a neutral compound that can only be isolated as amorphous material could be [0002] Cocrystals are crystals that contain tWo or more cocrystalliZed.