Tin, Tungsten, and Tantalum Deposits of South Dakota
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Overview of Tungsten Indicator Minerals Scheelite and Wolframite with Examples from the Sisson W-Mo Deposit, Canada
Overview of tungsten indicator minerals scheelite and wolframite with examples from the Sisson W-Mo deposit, Canada M. Beth McClenaghan1, M.A. Parkhill2, A.A. Seaman3, A.G. Pronk3, M. McCurdy1 & D.J. Kontak4 1Geological Survey of Canada, 601 Booth Street, Ottawa, Ontario, Canada K1A 0E8 (e-mail: [email protected]) 2New Brunswick Department of Energy and Mines, Geological Surveys Branch, P.O. Box 50, Bathurst, New Brunswick, Canada E2A 3Z1 3New Brunswick Department of Energy and Mines, Geological Surveys Branch, P.O. Box 6000, Fredericton, New Brunswick, Canada E3B 5H1 4Department of Earth Sciences, Laurentian University, Sudbury, Ontario, Canada P3E 2C6 These short course notes provide an overview of published lit- Table 1. List of regional surveys and case studies conducted around erature on the use of scheelite and wolframite as indicator min- the world in which scheelite and/or wolframite in surficial sediments erals for W, Mo, and Au exploration. The use of scheelite and have been used as indicator minerals. wolframite in stream sediments is well documented for mineral Mineral Media Location Source of Information exploration but less so for using glacial sediments (Table 1). scheelite stream sediments Pakistan Asrarullah (1982) wolframite stream sediments Burma ESCAP Scretariat (1982) The Geological Survey of Canada has recently conducted a scheelite, wolframite stream sediments USA Theobald & Thompson (1960) glacial till and stream sediment indicator mineral case study scheelite stream sediments, soil Thailand Silakul (1986) around the Sisson W-Mo deposit in eastern Canada. scheelite stream sediments Greenland Hallenstein et al. (1981) Preliminary indicator mineral results from this ongoing study scheelite stream sediments Spain Fernández-Turiel et al. -
L. Jahnsite, Segelerite, and Robertsite, Three New Transition Metal Phosphate Species Ll. Redefinition of Overite, an Lsotype Of
American Mineralogist, Volume 59, pages 48-59, 1974 l. Jahnsite,Segelerite, and Robertsite,Three New TransitionMetal PhosphateSpecies ll. Redefinitionof Overite,an lsotypeof Segelerite Pnur BnnN Moone Thc Departmcntof the GeophysicalSciences, The Uniuersityof Chicago, Chicago,Illinois 60637 ilt. lsotypyof Robertsite,Mitridatite, and Arseniosiderite Peur BmaN Moonp With Two Chemical Analvsesbv JUN Iro Deryrtrnent of GeologicalSciences, Haraard Uniuersity, Cambridge, Massrchusetts 02 I 38 Abstract Three new species,-jahnsite, segelerite, and robertsite,-occur in moderate abundance as late stage products in corroded triphylite-heterosite-ferrisicklerite-rockbridgeite masses, associated with leucophosphite,hureaulite, collinsite, laueite, etc.Type specimensare from the Tip Top pegmatite, near Custer, South Dakota. Jahnsite, caMn2+Mgr(Hro)aFe3+z(oH)rlPC)oln,a 14.94(2),b 7.14(l), c 9.93(1)A, p 110.16(8)", P2/a, Z : 2, specific gavity 2.71, biaxial (-), 2V large, e 1.640,p 1.658,t l.6lo, occurs abundantly as striated short to long prismatic crystals, nut brown, yellow, yellow-orange to greenish-yellowin color.Formsarec{001},a{100},il2oll, jl2}ll,ft[iol],/tolll,nt110],andz{itt}. Segeierite,CaMg(HrO)rFes+(OH)[POdz, a 14.826{5),b 18.751(4),c7.30(1)A, Pcca, Z : 8, specific gaavity2.67, biaxial (-), 2Ylarge,a 1.618,p 1.6t5, z 1.650,occurs sparingly as striated yellow'green prismaticcrystals, with c[00], r{010}, nlll0l and qll2l } with perfect {010} cleavage'It is the Feg+-analogueofoverite; a restudy on type overite revealsthe spacegroup Pcca and the ideal formula CaMg(HrO)dl(OH)[POr]r. Robertsite,carMna+r(oH)o(Hro){Ponlr, a 17.36,b lg.53,c 11.30A,p 96.0o,A2/a, Z: 8, specific gravity3.l,T,cleavage[l00] good,biaxial(-) a1.775,8 *t - 1.82,2V-8o,pleochroismextreme (Y, Z = deep reddish brown; 17 : pale reddish-pink), @curs as fibrous massesand small wedge- shapedcrystals showing c[001 f , a{1@}, qt031}. -
Alteration of Spodumene, Montebrasite and Lithiophilite In
American Mineralogist, Volume 67, pages 97-113, 1982 Alteration of spodumene,montebrasite and lithiophilite in pegmatites of the White PicachoDistrict, Arizona Davrp Lor.rooxrnNo DoNer-uM. Bunr Department of Geology Arizona State University Tempe, Arizona 85281 Abstract The crystallization sequence and metasomatic alteration of spodumene (LiAlSizOe), montebrasite(LiAIPO4(OH,F)), and lithiophilite (Li(Mn,Fe)PO+)are describedfor nine zoned lithium pegmatitesin the White Picacho district, Arizona. The observedcrystalliza- tion trends suggesta progressiveincrease in the activities of lithium species(spodumene follows microcline as the principal alkali aluminosilicate), as well as an increase in the activities of the acidic volatiles phosphorus and fluorine (montebrasite succeedsspodu- mene as the stableprimary lithium phase).Much of the lithiophilite occurs with columbite, apatite, beryl, zircon, and tourmaline in cleavelanditecomplexes that formed in part at the expenseof quartz-spodumenepegmatite. Fracture-controlledpseudomorphic alteration of the primary lithium minerals is widespread and apparently is the result of subsolidus reactionswith residualpegmatitic fluids. Spodumenehas been replacedby eucryptite, albite, and micas. Alteration products of montebrasite include low-fluorine secondary montebrasite,crandallite (tentative), hydroxylapatite, muscovite, brazilianite, augelite (tentative),scorzalite, kulanite, wyllieite, and carbonate-apatite.Secondary phases identi- fied in altered lithiophilite include hureaulite, triploidite, eosphorite, -
The H/F Ratio As an Indicator of Contrasted Wolframite Deposition Mechanisms
Ore Geology Reviews 104 (2019) 266–272 Contents lists available at ScienceDirect Ore Geology Reviews journal homepage: www.elsevier.com/locate/oregeorev Short communication The H/F ratio as an indicator of contrasted wolframite deposition T mechanisms ⁎ Julie Anne-Sophie Michaud , Michel Pichavant Université d'Orléans/CNRS/ISTO/BRGM, UMR 7327, 1A rue de la Férollerie, 45100 Orléans, France ARTICLE INFO ABSTRACT Keywords: Understanding wolframite deposition mechanisms is a key to develop reliable exploration guides for W. In quartz Wolframite veins from the Variscan belt of Europe and elsewhere, wolframites have a wide range of compositions, from Hübnerite hübnerite- (MnWO4) to ferberite-rich (FeWO4). Deposition style, source of Mn and Fe, distance from the heat/ W deposition fluid source and temperature have been proposed to govern the wolframite H/F (hübnerite/ferberite ratio) Magmatic control defined as 100 at. Mn/(Fe + Mn). The Argemela mineralized district, located near the world-class Panasqueira W ore deposit W mine in Portugal, exposes a quartz-wolframite vein system in close spatial and genetic association with a rare- Veins metal granite. Wolframite is absent as a magmatic phase, but W-rich whole-rock chemical data suggest that the granite magma is the source of W. Wolframite occurs as large homogeneous hübnerites (H/F = 64–75%) co- existing with montebrasite, K-feldspar and cassiterite in the latest generation of intragranitic veins corre- sponding to magmatic fluids exsolved from the granite. Locally, early hübnerites evolve to late more Fe-rich compositions (H/F = 45–55%). In a country rock vein, an early generation of Fe-rich hübnerites (H/ F = 50–63%) is followed by late ferberites (H/F = 6–23%). -
Washington State Minerals Checklist
Division of Geology and Earth Resources MS 47007; Olympia, WA 98504-7007 Washington State 360-902-1450; 360-902-1785 fax E-mail: [email protected] Website: http://www.dnr.wa.gov/geology Minerals Checklist Note: Mineral names in parentheses are the preferred species names. Compiled by Raymond Lasmanis o Acanthite o Arsenopalladinite o Bustamite o Clinohumite o Enstatite o Harmotome o Actinolite o Arsenopyrite o Bytownite o Clinoptilolite o Epidesmine (Stilbite) o Hastingsite o Adularia o Arsenosulvanite (Plagioclase) o Clinozoisite o Epidote o Hausmannite (Orthoclase) o Arsenpolybasite o Cairngorm (Quartz) o Cobaltite o Epistilbite o Hedenbergite o Aegirine o Astrophyllite o Calamine o Cochromite o Epsomite o Hedleyite o Aenigmatite o Atacamite (Hemimorphite) o Coffinite o Erionite o Hematite o Aeschynite o Atokite o Calaverite o Columbite o Erythrite o Hemimorphite o Agardite-Y o Augite o Calciohilairite (Ferrocolumbite) o Euchroite o Hercynite o Agate (Quartz) o Aurostibite o Calcite, see also o Conichalcite o Euxenite o Hessite o Aguilarite o Austinite Manganocalcite o Connellite o Euxenite-Y o Heulandite o Aktashite o Onyx o Copiapite o o Autunite o Fairchildite Hexahydrite o Alabandite o Caledonite o Copper o o Awaruite o Famatinite Hibschite o Albite o Cancrinite o Copper-zinc o o Axinite group o Fayalite Hillebrandite o Algodonite o Carnelian (Quartz) o Coquandite o o Azurite o Feldspar group Hisingerite o Allanite o Cassiterite o Cordierite o o Barite o Ferberite Hongshiite o Allanite-Ce o Catapleiite o Corrensite o o Bastnäsite -
Geology of the Hugo Pegmatite Keystone, South Dakota
Geology of the Hugo Pegmatite Keystone, South Dakota GEOLOGICAL SURVEY PROFESSIONAL PAPER 297-B Geology of the Hugo Pegmatite Keystone, South Dakota By J. J. NORTON, L. R. PAGE, and D. A. BROBST PEGMATITES AND OTHER PRECAMBRIAN ROCKS IN THE SOUTHERN BLACK HILLS GEOLOGICAL SURVEY PROFESSIONAL PAPER 297-P A detailed structural and petrologic study of a pegmatite containing seven zones and two replacement bodies UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1962 UNITED STATES DEPARTMENT OF THE INTERIOR STEWART L. UDALL, Secretary GEOLOGICAL SURVEY Thomas B. Nolan, Director For sale by the Superintendent of Documents, U.S. Government Printing Office Washington 25, D.C. CONTENTS Page Page Abstract.. _ ________________________________________ 49 Mineral distribution and paragenesis of the entire Introduction. ______________________________________ 49 pegmatite_ _ ______________________-___---------_ 96 General geology. ___________________________________ 52 Comparison of the zonal sequence with that in other Metamorphic rocks_ ____________________________ 52 pegmatites. ______________________________________ 97 Roy and Monte Carlo pegmatites.- _ __---__-______ 53 Replacement features-______________________________ 100 Structure __________________________________________ 53 Review of the evidence for replacement in pegma Pegmatite units ____________________________________ 53 tites __ _____________________________________ 100 Zone 1 : Albite-quartz-musco vite pegmatite ________ 56 Replacement in the Hugo pegmatite.____-_____-_- 102 -
University of Oklahoma Graduate College
UNIVERSITY OF OKLAHOMA GRADUATE COLLEGE EVOLUTION OF THE HYDROTHERMAL STAGE WITHIN MIAROLITIC CAVITIES IN GRANITIC PEGMATITES OF CALIFORNIA AND MAINE, USA A THESIS SUBMITTED TO THE GRADUATE FACULTY in partial fulfillment of the requirements for the Degree of MASTER OF SCIENCE By CHARLES LORIN DUVAL Norman, Oklahoma 2019 EVOLUTION OF THE HYDROTHERMAL STAGE WITHIN MIAROLITIC CAVITIES IN GRANITIC PEGMATITES OF CALIFORNIA AND MAINE, USA A THESIS APPROVED FOR THE SCHOOL OF GEOSCIENCES BY Dr. David London, Chair Dr. Andrew S. Elwood Madden Dr. Megan E. Elwood Madden © Copyright by CHARLES LORIN DUVAL 2019 All Rights Reserved. Table of Contents Abstract………………………………………………………………..……………………….. vi 1. INTRODUCTION/PROBLEM STATEMENT…………………………………………... 1 2. OBJECTIVES…………………………………………………………………………..…... 2 3. BACKGROUND……………………………………………………………………………. 2 3.1 Minerals present within miarolitic cavities….…………………………………………… 2 3.2 Prior studies……………………………………………………………………………... 5 4. CLAY SAMPLE LOCATIONS……………….…………………………………………. 10 4.1 California………………………………………………………………………………. 10 4.2 Maine…………………………………………………………………………………… 11 5. ALKALI FELDSPAR SAMPLE LOCATIONS………………………………………… 11 6. METHODOLOGY………………………………………………………………………... 11 6.1 X-ray diffraction analysis of clay minerals……………………………………………... 12 6.2 Electron microprobe analysis of clay minerals…………………………………………. 12 6.3 X-ray diffraction analysis of alkali feldspars…………………………………………… 13 7. RESULTS………………………………………………………………………………….. 13 7.1 XRD of pocket clay samples…………………………………………………………….. 13 7.2 EDXA of pocket clay samples…………………………………………………………… -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
The Mineral Industry of Burundi in 2016
2016 Minerals Yearbook BURUNDI [ADVANCE RELEASE] U.S. Department of the Interior January 2020 U.S. Geological Survey The Mineral Industry of Burundi By Thomas R. Yager In 2016, the production of mineral commodities—notably can be found in previous editions of the U.S. Geological Survey gold, tantalum, tin, and tungsten—represented only a minor Minerals Yearbook, volume III, Area Reports—International— part of the economy of Burundi (United Nations Economic Africa, which are available at https://www.usgs.gov/centers/ Commission for Africa, 2017). The legislative framework for nmic/africa-and-middle-east. the mineral sector in Burundi is provided by the Mining Code of Burundi (law No. 1/21 of October 15, 2013). The legislative Reference Cited framework for the petroleum sector is provided by the Mining United Nations Economic Commission for Africa, 2017, Burundi, in African and Petroleum Act of 1976. Data on mineral production are statistical yearbook 2017: United Nations Economic Commission for Africa, in table 1. Table 2 is a list of major mineral industry facilities. p. 113–117. (Accessed November 7, 2018, at https://www.uneca.org/sites/ More-extensive coverage of the mineral industry of Burundi default/files/PublicationFiles/asyb-2017.pdf.) TABLE 1 BURUNDI: PRODUCTION OF MINERAL COMMODITIES1 (Metric tons, gross weight, unless otherwise specified) Commodity2 2012 2013 2014 2015 2016 METALS Gold, mine, Au contente kilograms 500 400 500 500 500 Niobium and tantalum, mine, columbite-tantalite concentrate: Gross weight do. 258,578 73,518 105,547 53,093 r 31,687 Nb contente do. 51,000 14,000 21,000 10,000 r 6,200 Ta contente do. -
Minerals and Mineral Products in Our Bedroom Bed Hematite
Minerals and Mineral Products in our Bedroom Make-Up Kit Muscovite Bed Talc Hematite: hinges, handles, Mica mattress springs Hematite: for color Chromite: chrome plating Bismuth Radio Barite Copper: wiring Plastic Pail Quartz: clock Mica Gold: connections Cassiterite: solder Toilet Bowl / Tub Closet Feldspar: porcelain Chromite: chrome plating Pyrolusite: coloring Hematite: hinges, handles (steel) Chromite: plumbing fixtures Quartz : mirror on door Copper: tubing Desk Toothpaste Hematite: hinges, handles (steel) Apatite: teeth Chromite: chrome plating Fluorite: toothpaste Mirror Rutile: to color false Hematite: handle, frame teeth yellow Chromite: plating Gold: fillings Gold: plating Cinnabar: fillings Quartz: mirror Towels Table Lamp Sphalerite: dyes Brass (an alloy of copper and Chromite: dyes zinc): base Quartz: bulb Water Pipe/Faucet/Shower bulb Wolframite: lamp filament Brass Copper: wiring Iron Nickel Minerals and Mineral Products in our Bedroom Chrome: stainless steel Bathroom Cleaner Department of Environment and Natural Resources Borax: abrasive, cleaner, and antiseptic MINES AND GEOSCIENCES BUREAU Deodorant Spray Can Cassiterite Chromite Copper Carpet Quartz Sphalerite: dyes Telephone Chromite: dyes Drinking Glasses Copper: wiring Sulfur: foam padding Quartz Chromite: plating Gold: red color Clock Silver: electronics Pentlandite: spring Graphite: batteries Refrigerator Quartz: glass, time keeper Hematite Television Chromite: stainless steel Chromite: plating Computer Galena Wolframite: monitor Wolframite: monitor Copper Copper: -
Cycle Processing of Tantalum Bearing Minerals
Journal of Minerals & Materials Characterization & Engineering, Vol. 6, No.1, pp 69-77, 2007 jmmce.org Printed in the USA. All rights reserved Adaptable Technologies for Life – Cycle Processing of Tantalum Bearing Minerals Amuda, M. O. H., Esezobor, D. E., and Lawal, G. I. Department of Metallurgical and Materials Engineering University of Lagos, Lagos, Nigeria. Corresponding Author: [email protected] ABSTRACT Nigeria is richly endowed in convertible natural resources of which solid minerals are a member of the endowments. However, the country is basically a mono-product economy based on its vast oil deposit accounting for over 84% of foreign earnings and 25% of GDP. The triple challenges of the volatile nature of global oil politics, achieving the objectives of the millennium development goals and the national economy empowerment and development strategies calls for diversification into hitherto neglected solid mineral deposits to open a window of opportunities. One of the widely reported mineral deposits in the country with strong international influence is tantalum-bearing mineral. The mineral had in the past few decades experienced a strong growth in demand averaging 10% per annum since 1992 with total world consumption estimated at over 38 thousand tonne in 2005. The total annual supply of the ore concentrate in 2001 was 720 tonnes when demand was 26 thousand tonnes. Thus, pushing the price of the concentrate to an all time high of $165 / kg in 2001. This paper outlines the characteristics of the Nigerian tantalum reserves. It also presents the evaluation of the competing technologies for complete cycle processing of tantalum bearing minerals for adoption in the Nigeria solid mineral industry. -
Compositional Trend in the Specks of Tantalite, Tourmaline and Beryl Hosted Within Complex Basement Rocks Using Geophysical and Geochemical Methods of Exploration
IOSR Journal of Applied Physics (IOSR-JAP) e-ISSN: 2278-4861. Volume 3, Issue 4 (Mar. - Apr. 2013), PP 24-33 www.iosrjournals.org Compositional Trend in the Specks of Tantalite, Tourmaline and Beryl Hosted within Complex Basement Rocks Using Geophysical and Geochemical Methods of Exploration B. S. Badmus, O. D. Akinyemi, *A. M. Gbadebo, P. Babatunde, O. T. Olurin and S. A. Ganiyu Department of Physics, Federal University of Agriculture, Abeokuta, Nigeria *Department of Environmental Management and Toxicology, Federal University of Agriculture, Abeokuta, Abeokuta, Nigeria Abstract: Vertical Electrical Sounding (VES) using Schlumberger array was employed in data collection. Data acquisition was carried out along Oyan river bank with a total of twenty-three (23) soundings. This location was divided into two zones: VES 01 -09 and VES 10 -23. Rock samples hosting specks of tantalite, tourmaline and beryl were collected from the artisan pits within the study area and taken for geochemical analysis in the laboratory. The result of geochemical analyses revealed the quality of the solid minerals in terms of mineral compositions (major, trace and rare earth elements) while geophysical field measurement revealed the resistivity values, vertical and lateral distributions and depth of the solid minerals. The range of electrical resistivity values of these solid minerals as revealed by laboratory measurement is 19.4 - 31.1Ωm while that of the host rock is 10.0 – 100.0Ωm as obtained from field measurements. Specks of tantalite, tourmaline and beryl were suspected to be sparsely distributed in other VES locations except at VES02 and 09, where vast deposits were suspected.