DOCSLIB.ORG

A Review of Refinery Complexity Applications

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
A Review of Refinery Complexity Applications Pet. Sci. DOI 10.1007/s12182-016-0137-y REVIEW A review of refinery complexity applications Mark J. Kaiser1 Received: 21 June 2016 Ó The Author(s) 2017. This article is published with open access at Springerlink.com Abstract Refinery complexity quantifies the sophistication combinations of temperature, pressure, and catalyst to and capital intensity of a refinery and has found widespread perform their function. application in facility classification, cost estimation, sales All modern refineries have distillation units that perform price models, and other uses. Despite the ubiquity and separation, but not all refineries perform conversion and widespread use of refining complexity, however, surprisingly finishing operations. There are a dozen or so main process little material has been written on its applications. The pur- operations in modern refining (Table 1), and for each pose of this review is to describe the primary applications of process, several technologies have been developed over the refinery complexity and some recent extensions. A secondary past 150 years (Table 2). Different technologies involve purpose of this review is to provide a framework that unifies different trade-offs between operating and capital cost, complexity applications and suggests avenues for future reliability and maintenance requirements (Schobert 2002; research. Examples illustrate the applications considered. Parkash 2003; Raseev 2003; Meyers 2004; Gary et al. 2007; Riazi et al. 2013). Keywords Cost estimation Á Functional complexity Á Inverse problem Á Replacement cost Á Refinery 1.1 Separate, convert, finish classification Á Sales price models Crude oil consists of hundreds of different types of hydrocarbon molecules. Before processing, all refiners 1 Introduction physically separate crude oil into molecular weight ranges by boiling point using a distillation tower (Fig. 1). The A refinery is an industrial plant where crude oil and other longer the carbon chain, the higher the temperature the feedstocks are processed into petroleum products. The hydrocarbon compounds will boil. ‘‘Cuts’’ of similar boil- main principle of refining is to separate and improve the ing point compounds are processed to allow the conversion hydrocarbon compounds that constitute crude oil to pro- steps to operate efficiently. Processes downstream of dis- duce saleable products which satisfy regulatory require- tillation take these cuts, and using various chemical and ments. A refinery is comprised of three main sections— physical operations, improve and change the physical separation, conversion, and finishing—and each section properties of molecules which are subsequently blended for contains one or more process units that apply various fuels and other products (Speight 1998). The conversion units in a modern refinery include thermal cracking, catalytic cracking, hydrocracking and & Mark J. Kaiser coking. Thermal cracking was the first technology used to [email protected] increase gasoline production in 1913, but has been largely 1 Center for Energy Studies, Louisiana State University, replaced by more efficient processes. Conversion units are Energy Coast and Environment Building, Baton Rouge, expensive to build and operate and represent a major LA 70803, USA investment decision, but once installed significantly extend Edited by Xiu-Qin Zhu refinery flexibility and capability. 123 Pet. Sci. Table 1 Refining production process technologies. Source: OGJ Process operation Technology Coking Fluid coking, delayed coking, other Thermal process Thermal cracking, visbreaking Catalytic cracking Fluid, other Catalytic reforming Semiregenerative, cycle, continuous regeneration, other Catalytic hydrocracking Distillate upgrading, residual upgrading, lube oil, other Catalytic hydrotreating Pre-treatment of cat reformer feeds, other naphtha desulfurization, naphtha aromatics saturation, kerosene/jet desulfurization, diesel desulfurization, distillate aromatics saturation, other distillates, pre-treatment of cat cracker feeds, other heavy gas oil hydrotreating, residual hydrotreating, lube oil polishing, post-hydrotreating of FCC naphtha, other Alkylation Sulfuric acid, hydrofluoric acid Polymerization/dimerization Polymerization, dimerization Aromatics BTX, hydrodealkylation, cyclohexane, cumene Isomerization C4 feed, C5 feed, C5, and C6 feed Oxygenates MTBE, ETBE, TAME Hydrogen production Steam methane reforming, steam naphtha reforming, partial oxidation Hydrogen recovery Pressure swing adsorption, cryogenic, membrane, other Table 2 Evolution of refining technologies. Source: OSHA (2005) Year Process Purpose By-products 1862 Atmospheric distillation Produce kerosene Naphtha, tar, etc. 1870 Vacuum distillation Produce lubricants Asphalt, residual coker feedstocks 1913 Thermal cracking Increase gasoline Residual, bunker fuel 1916 Sweetening Reduce sulfur and odor Sulfur 1930 Thermal reforming Improve octane number Residual 1932 Hydrogenation Remove sulfur Sulfur 1932 Coking Produce gasoline basestocks Coke 1933 Solvent extraction Improve lubricant viscosity index Aromatics 1935 Solvent dewaxing Improve pour point Waxes 1935 Catalytic polymerization Improve gasoline yield and octane number Petrochemical feedstocks 1937 Catalytic cracking Higher octane gasoline Petrochemical feedstocks 1939 Visbreaking Reduce viscosity Increased distillate, tar 1940 Alkylation Increase gasoline octane and yield High-octane aviation gasoline 1940 Isomerization Produce alkylation feedstock Naphtha 1947 Fluid catalytic cracking Increase gasoline yield and octane Petrochemical feedstocks 1950 Deasphalting Increase cracking feedstock Asphalt 1952 Catalytic reforming Convert low-quality naphtha Aromatics 1954 Hydrodesulfurization Remove sulfur Sulfur 1956 Inhibitor sweetening Remove mercaptan Disulfides 1957 Catalytic isomerization Convert to molecules with high octane number Alkylation feedstocks 1960 Hydrocracking Improve quality and reduce sulfur Alkylation feedstocks 1974 Catalytic dewaxing Improve pour point Wax 1975 Residual hydrocracking Increase gasoline yield from residual Heavy residuals 123 Pet. Sci. Intermediate products Further processing Final products ＜90 °F ● Refinery fuel gas Propane, butane and lighter ● Propane ● NGLs 90-180 °F Light straight run gasoline ● Gasoline 180-370 °F ● Gasoline Naphtha ● Jet fuel ● Kerosene 370-500 °F ● Jet fuel Kerosene ● Diesel ● Fuel oil Atmospheric distillation 500-650 °F ● Gasoline Atmospheric gas oil ● Diesel ● Fuel oil ● Gasoline Vacuum gas oil ● Diesel ● Fuel oil Vacuum distillation ● Gasoline ● Diesel Residual ● Heavy fuel oil ● Asphalt ● Coke Fig. 1 Distillation separates crude oil into boiling point cuts for further processing and sales Products from the conversion steps frequently require The US is importing less oil as the country’s crude treatment to make them ready for sale. Treatment primarily production increases (Fig. 3), while exports of refined oil involves improving product specification and reducing sul- products have nearly quadrupled over the past decade fur levels to satisfy regulatory requirements. Hydrotreating (Fig. 4). In May 2015, US production of crude oil was 9.5 is the most common finishing process in refineries and use million barrels per day (MMbpd) and 2.8 MMbpd of hydrogen and catalyst to remove sulfur and other impurities refined petroleum products was exported (EIA 2015a, b). A from feedstock and refined products. Most treatment and ban on crude oil exports was enacted in 1973 after the Arab conversion processes employ catalyst to increase the speed oil embargo, and in late 2015 Congress approved lifting the of chemical reactions and enhance conversion rates. ban. 1.2 Production, imports, and exports 1.3 Refinery complexity The products of refining can be classified by form, as gases The primary fixed assets of a refinery are its process units, (e.g., methane, ethane, propane), liquids (e.g., gasoline, and the easiest way to describe the units is in terms of their kerosene, diesel), and solids (e.g., coke, asphalt), or by production capacity, technology application, and capital usage, as transportation fuels (e.g., gasoline, jet fuel, fuel expenditures for acquisition and construction. A refinery oil), non-fuel products (e.g., lubricants, solvents, waxes), represents a collection of integrated process units which are and petrochemical feedstock (e.g., ethylene, propylene, characterized by the number, size, and type of process benzene). Liquid fuel products are by far the largest cate- units, and the technologies applied. It is common to clas- gory of production and in the US, for example, contribute sify refineries broadly by the presence or absence of par- over 90% of total products (Fig. 2). In 2014, US refiners ticular units (e.g., cracking refineries contain cracking processed 5.8 billion barrels of crude oil and feedstocks, units, coking refineries contain cokers). The manner in and almost half of every barrel output was motor gasoline, which the units are integrated and the cost associated with followed by distillate fuel oil (30%) and jet fuels (10%). In the receipt and dispatch of feedstock and refined product, Europe and Asia, a larger proportion of diesel and fuel oils including storage capacity, are important but are usually are produced with smaller quantities of gasoline. considered secondary factors. 123 Pet. Sci. Distillate fuel oil (29.8 %) Diesel fuel Motor gasoline (45 %) Home heating oil Liquified petroleum Residual fuel oil (2.7 %) Industrial fuel gases (4.1 %) Bunker fuel Propane Boiler fuel Ethane Butane Jet fuels (9.5 %) Kerosene (0.1
Load more

Recommended publications
  • Exxonmobil Refinery Proposed Expansion: Operational Review and Neighborhood Demographic Profile
    ExxonMobil Refinery Proposed Expansion: Operational Review and Neighborhood Demographic Profile Louisiana Democracy Project asked EBIC to examine the environmental track record of ExxonMobil’s Baton Rouge Refinery and also provide a demographic analysis of the neighborhoods within 2 miles of the Refinery. The ExxonMobil Refinery, previously knows as the Exxon Refinery, is located at 4045 Scenic Hwy. in Baton Rouge, LA. It borders the Mississippi River to the West and a densely populated neighborhood to the East with additional refineries extending to the north from its property boundary. The facility itself borders another Exxon Chemicals America plant (4999 Scenic Hwy.) which is also a significant source of toxic environmental releases, workplace hazards and regulatory problems. ExxonMobil is seeking a permit to expand its air pollution emissions at the Baton Rouge refinery. The company has claimed that even though the plant will produce more emissions, its overall operational effect on the environment would be make the air cleaner by producing a fuel that would lower automobile emissions. ExxonMobil is seeking permits to increase air pollution emissions at its Baton Rouge refinery. But, the company says the cleaner gasoline created by the project will mean fewer emissions from cars. The refinery wants to make changes so it can produce cleaner, low-sulfur gas as ordered by U.S. Environmental Protection Agency rules for 2004 model year cars and trucks. The new gasoline will mean that each year, vehicles in Baton Rouge's five-parish area will produce 2,238 fewer tons of nitrogen oxides and 842 fewer tons of volatile organic compounds.
    [Show full text]
  • Clean Air Act (CAA) Watch List
    Facilities on the Active May 2012 CAA Watch List The list of facilities below composes OECA's May 2012 Clean Air Act (CAA) Watch List. EPA maintains a "Watch List" to facilitate dialogue between EPA, state and local agencies on enforcement matters relating to facilities with alleged violations identified as either significant or high priority. Being on the Watch List may not mean that the facility has actually violated the law only that an evaluation or investigation by EPA or a state or local environmental agency has led those organizations to allege that an unproven violation has in fact occurred. The Watch List does not identify which alleged violations of environmental laws may pose the greatest risk to public health or the environment. It is an automated report based on data from the Air Facility System (AFS), which is used by federal, state and local agencies to track environmental enforcement and compliance information. Agencies input information into AFS, including information about violations that are identified as high priority violations (HPVs). Some facilities may appear on the Watch List due to data errors, which typically are identified and addressed during the EPA-state-local dialogue. EPA expects the government agency with jurisdiction over a facility with an HPV to initiate an appropriate enforcement response, in a timely manner, and input the action into AFS. Some facilities on the list are the subject of existing orders, are actively participating in negotiations with regulators, or are the subject of an investigation. While progress is being made toward resolving the violations, further activities may be required to achieve compliance.
    [Show full text]
  • Safety Bulletin • Exxonmobil • Baton Rouge, Louisiana
    Key Lessons from the ExxonMobil Baton Rouge Refinery Isobutane Release and Fire SUMMARY OF KEY LESSONS: Incident Date: November 22, 2016 Companies should: 4 Workers Injured • Evaluate human factors associated with No. 2016-02-I-LA equipment design and apply the hierarchy of controls to mitigate identified hazards. • Establish detailed and accurate written procedures and provide training to ensure workers can perform all anticipated job tasks safely. CSB • Safety Bulletin • ExxonMobil • Baton Rouge, Louisiana The U.S. Chemical Safety and Hazard Investigation Board (CSB) is an independent Federal agency whose mission is to drive chemical safety change through independent investigations to protect people and the environment. The CSB is a scientific investigative organization; it is not an enforcement or regulatory body. Established by the Clean Air Act Amendments of 1990, the CSB is responsible for determining accident causes, issuing safety recommendations, studying chemical safety issues, and evaluating the effectiveness of other government agencies involved in chemical safety. More information about the CSB is available at www.csb.gov. The CSB makes public its actions and decisions through investigative publications, all of which may include safety recommendations when appropriate. Examples of the types of publications include: CSB Investigation Reports: formal, detailed reports on significant chemical accidents and include key findings, root causes, and safety recommendations. CSB Investigation Digests: plain-language summaries of Investigation Reports. CSB Case Studies: examines fewer issues than a full investigative report, case studies present investigative information from specific accidents and include a discussion of relevant prevention practices. CSB Safety Bulletins: short, general-interest publications that provide new or timely information intended to facilitate the prevention of chemical accidents.
    [Show full text]
  • Guide to the American Petroleum Institute Photograph and Film Collection, 1860S-1980S
    Guide to the American Petroleum Institute Photograph and Film Collection, 1860s-1980s NMAH.AC.0711 Bob Ageton (volunteer) and Kelly Gaberlavage (intern), August 2004 and May 2006; supervised by Alison L. Oswald, archivist. August 2004 and May 2006 Archives Center, National Museum of American History P.O. Box 37012 Suite 1100, MRC 601 Washington, D.C. 20013-7012 [email protected] http://americanhistory.si.edu/archives Table of Contents Collection Overview ........................................................................................................ 1 Administrative Information .............................................................................................. 1 Arrangement..................................................................................................................... 3 Biographical / Historical.................................................................................................... 2 Scope and Contents........................................................................................................ 2 Names and Subjects ...................................................................................................... 4 Container Listing ............................................................................................................. 6 Series 1: Historical Photographs, 1850s-1950s....................................................... 6 Series 2: Modern Photographs, 1960s-1980s........................................................ 75 Series 3: Miscellaneous
    [Show full text]
  • In the United States District Court for the Northern District of Illinois
    IN THE UNITED STATES DISTRICT COURT FOR THE NORTHERN DISTRICT OF ILLINOIS UNITED STATES OF AMERICA, ) STATE OF ILLINOIS, ) STATE OF LOUISIANA, and the ) STATE OF MONTANA ) ) Plaintiffs, ) ) v. ) ) EXXON MOBIL CORPORATION and ) No. EXXONMOBIL OIL CORPORATION ) ) Defendants. ) ) CONSENT DECREE TABLE OF CONTENTS I. JURISDICTION AND VENUE ............................................6 II. APPLICABILITY AND BINDING EFFECT ..................................7 III. OBJECTIVES ..........................................................9 IV. DEFINITIONS ..........................................................9 V. AFFIRMATIVE RELIEF ................................................17 A. Fluid Catalytic Cracking Units ......................................17 B. NOx Emissions Reductions from the FCCUs ...........................18 C. SO2 Emissions Reductions from the FCCUs ............................28 D. Particulate Matter Emissions Reductions from the FCCUs .................39 E. Carbon Monoxide Emissions Reductions from the FCCUs ................41 F. NSPS Applicability to the FCCU Catalyst Regenerators ..................44 G. NOx Emissions Reductions from Combustion Units .....................49 H. SO2 Emissions Reductions from and NSPS Applicability of Heaters, Boilers and Other Fuel Gas Combustion Devices ..............................56 I. Sulfur Recovery Plant Operations ....................................58 J. Flaring Devices ..................................................67 K. Control of Acid Gas Flaring and Tail Gas Incidents ......................71
    [Show full text]
  • (HDS) Unit for Petroleum Naphtha at 3500 Barrels Per Day
    Available online at www.worldscientificnews.com WSN 9 (2015) 88-100 EISSN 2392-2192 Design Parameters for a Hydro desulfurization (HDS) Unit for Petroleum Naphtha at 3500 Barrels per Day Debajyoti Bose University of Petroleum & Energy Studies, College of Engineering Studies, P.O. Bidholi via- Prem Nagar, Dehradun 248007, India E-mail address: [email protected] ABSTRACT The present work reviews the setting up of a hydrodesulphurization unit for petroleum naphtha. Estimating all the properties of the given petroleum fraction including its density, viscosity and other parameters. The process flow sheet which gives the idea of necessary equipment to be installed, then performing all material and energy balance calculations along with chemical and mechanical design for the entire setup taking into account every instrument considered. The purpose of this review paper takes involves an industrial process, a catalytic chemical process widely used to remove sulfur (S) from naphtha. Keywords: hydro desulfurization, naphtha, petroleum, sulfur Relevance to Design Practice - The purpose of removing the sulfur is to reduce the sulfur dioxide emissions that result from using those fuels in automotive vehicles, aircraft, railroad locomotives, gas or oil burning power plants, residential and industrial furnaces, and other forms of fuel combustion. World Scientific News 9 (2015) 88-100 1. INTRODUCTION Hydrodesulphurization (HDS) is a catalytic chemical process widely used to remove sulfur (S) from natural gas and from refined petroleum products such as gasoline or petrol, jet fuel, kerosene, diesel fuel, and fuel oils. The purpose of removing the sulfur is to reduce the sulfur dioxide (SO2) emissions that result from various combustion practices.
    [Show full text]
  • How Did They Finish? CAN ONE MEGASITE HAVE EVERYTHING YOU NEED?
    The Best of Aerospace in the American South WWW.RAND LER E P O R T . C OM WWW. SB- D . COM WWW. S O UTHE R N A UTO C O RRI D O R . COM Economic Development in the World’s Third Largest Economy SPRING 2018 2018 SB D100 5 Permit No. 21 No. Permit & A V , g Lynchbur PAID ge Posta .S. U D PRSRT ST PRSRT How did they finish? CAN ONE MEGASITE HAVE EVERYTHING YOU NEED? In the Golden Triangle, we’ve got it all—and we give it all. Yes is what we always say here—for whatever you need to succeed. Abundant electricity and water? Yes! Highways, rail, waterway, airport? Yes, yes, yes, and yes! Quality workforce and training? Hell, yes! Our 1,144-acre Infinity Megasite is just one of our feature-filled, ready-to-roll locations. But what’ll really blow you away is our can-do, will-do, do-it-up attitude. Talk to us. Tell us what you need. And expect the answer that makes this region—and your future—golden: YES. www.gtrSaysYes.com or call 662.328.8369 Joe Max Higgins, Jr., CEO GOLDEN TRIANGLE DEVELOPMENT LINK All of These Companies Have Two Things in Common ... 2.5 million square feet 2 million square feet 2.1 million square feet 2 million square feet 1 million square feet 500,000 square feet Alliance Consulting Engineers, Inc., Nationally Recognized, Recognized as the Locally Focused. Leading Economic Development Engineering Firm in South Carolina by They Chose South Carolina. They Chose Alliance Consulting Engineers, Inc.
    [Show full text]
  • BENZENE Disclaimer
    United States Office of Air Quality EPA-454/R-98-011 Environmental Protection Planning And Standards June 1998 Agency Research Triangle Park, NC 27711 AIR EPA LOCATING AND ESTIMATING AIR EMISSIONS FROM SOURCES OF BENZENE Disclaimer This report has been reviewed by the Office of Air Quality Planning and Standards, U.S. Environmental Protection Agency, and has been approved for publication. Mention of trade names and commercial products does not constitute endorsement or recommendation of use. EPA-454/R-98-011 ii TABLE OF CONTENTS Section Page LIST OF TABLES.....................................................x LIST OF FIGURES.................................................. xvi EXECUTIVE SUMMARY.............................................xx 1.0 PURPOSE OF DOCUMENT .......................................... 1-1 2.0 OVERVIEW OF DOCUMENT CONTENTS.............................. 2-1 3.0 BACKGROUND INFORMATION ...................................... 3-1 3.1 NATURE OF POLLUTANT..................................... 3-1 3.2 OVERVIEW OF PRODUCTION AND USE ......................... 3-4 3.3 OVERVIEW OF EMISSIONS.................................... 3-8 4.0 EMISSIONS FROM BENZENE PRODUCTION ........................... 4-1 4.1 CATALYTIC REFORMING/SEPARATION PROCESS................ 4-7 4.1.1 Process Description for Catalytic Reforming/Separation........... 4-7 4.1.2 Benzene Emissions from Catalytic Reforming/Separation .......... 4-9 4.2 TOLUENE DEALKYLATION AND TOLUENE DISPROPORTIONATION PROCESS ............................ 4-11 4.2.1 Toluene Dealkylation
    [Show full text]
  • Optimize Refinery Hydrotreating & Catalytic Reforming Using Fast On
    — ABB MEASUREMENT & ANALYTICS | APPlicatiON NOte Optimize refinery hydrotreating & catalytic reforming Using fast on-line simulated distillation GCs PGC5009 fast gas chromatograph The advantage of on-line fast simulated distillation. Measurement made easy — The challenge Catalytic reforming is a major conversion process in Industry | Refining Improve your control Improving profitability requires refiners to reduce petroleum refinery and petrochemical industries. strategies. the impact of market price volatility and product The process converts low octane naphthas into environmental compliance requirements by higher octane reformate products for gasoline adopting better control strategies. Better control blending and aromatic rich reformate for aromatic strategies enable refiners to handle a wide range of production. Hydrotreating is an important step to feedstocks while maintaining smooth operations remove unwanted sulfur from streams that are used and intermediate product qualities, both key to as feeds to some refinery units. Catalytic reforming sustainable margins and reliable operation. Most and isomerization are examples of refining traditional process and lab gas chromatographs as processes that require low sulfur feeds. The catalyst well as D86 distillation devices do not provide the in these processes are platinum based and sulfur required fast and reliable measurement feedback compounds are catalyst poisons. Controlling the due to long cycle times and poor repeatability. feed distillation properties enable control on not only the product properties but also the monitoring The ABB PGC5009 fast on-line gas chromatograph of the sulfur compounds. Intermediate streams used answers the challenge by providing superior process to feed hydrotreater do not have a uniform amount chromatography for simulate distillation in less than of sulfur compounds across their boiling point range 5 minutes.
    [Show full text]
  • Exxonmobil Oil Spill Response Field Manual
    Oil Spill Response Field Manual Metric Conversion Factors Volume Flow Rate 1 cm3 = 1 ml = .001 L 1 L/min = 0.0167 L/sec 1 L = 1 dm3 = .001 m3 = 60 L/hr = 1440 L/day 1 L = 0.264 Gallon Liquid US 1 L/min = 0.06 m3/hr 1 m3 = 6.29 API bbl 1 L/min = 0.265 gpm (US) 1 L/min = 9.05 API bbl/day Length Velocity 1 m = 10–3 km = 102 cm = 103 mm = 106µ 1 cm/sec = 10–2 m/sec = 36 m/hr 1 cm = 0.3937 in = 0.036 km/hr 1 m = 3.2808 ft = 39.37 in 1 m/sec = 1.94 knots (US) 1 m = 0.5468 fathom 1 km/hr = 0.54 knots (US) 1 km = 0.62 mile = 3273 ft 1 km/hr = 0.621 mph (US) 1 km = 0.54 nautical mile (NM) Area Mass/Weight 1 hectare = 10,000 m2 = 0.01 km2 1g = 10–3 kg = 103 mg 1 m2 = 10.76 ft2 = 1.196 yd2 1 metric tonne = 1000 kg 1 hectare = 2.471 acres = 0.00386 sq mile 1 kg = 2.21 lbs = 0.0685 slug Surface Tension Force 1 kg-f/m = 9.807 N/m = 9807 dyne/cm 1 newton (N) = 105 dyne 1 kg-f/m = 0.672 lbs/ft = 5.61 lb/in 1 newton = 0.102 kg-f 1 N/m = 0.0685 lb/ft 1 newton = 0.2248 lb 1 N/mm = 5.64 lb/in 1 newton = 7.233 pdl Pressure Application Rates 1 N/m2 = 0.102 kg-f/m2 = 1 pascal (Pa) 1 L/m2 = thickness in mm 1 bar = 106 dyne/cm2 = 0.1MPa 1 L/hectare = 0.1 m3/km2 1 mm Hg = 133 Pa 1 L/hectare = 0.1068 gal/acre 1 Pa = 1.450 x 10–4 psi 1 tonne/hectare = 2.5 bbl/acre 1 kg-f/m2 = 0.0206 lb/ft2 1 MPa = 9.869 atm Miscellaneous 1 tonne of oil = 1000 L = 1 m3 = 264.2 gal storage volume for boom, volume/length: ft3/ft x 0.093 = m3/m mg/L = parts per million (ppm) = % x 10–2 x 106 = ppm ice density = 0.8 g/cm3 = 800 kg/m3 viscosity in centipoise (cp) = viscosity in centistokes (cSt) x density temperature centigrade = (temperature Fahrenheit – 32) x 0.555 Oil Spill Response Field Manual Revised 2008 Copyright © 2008, ExxonMobil Research and Engineering Company, All Rights Reserved, Printed in USA.
    [Show full text]
  • 2021 Petition Requesting the Administrator Object to Title V Permit for Exxon Baton Rouge Refinery
    BEFORE THE ADMINISTRATOR UNITED STATES ENVIRONMENTAL PROTECTION AGENCY IN THE MATTER OF: ) ) LDEQ Title V Air Operating Permit ) No. 2363-V8 ) ) Permit No. 2363-V8 For ExxonMobil Fuels & Lubricant ) Company’s Baton Rouge Refinery – ) Utilities Unit ) ) Issued by the Louisiana Department of ) Environmental Quality ) PETITION TO OBJECT TO THE TITLE V OPERATING PERMIT FOR THE UTILITIES UNIT AT EXXONMOBIL FUELS & LUBRICANT COMPANY’S BATON ROUGE REFINERY Pursuant to § 505(b)(2) of the Clean Air Act, 42 U.S.C. § 7661d(b)(2), and 40 C.F.R. § 70.8(d), Louisiana Bucket Brigade, Earthjustice, Environmental Integrity Project, and Sierra Club (“Petitioners”)1 petition the Administrator of the U.S. Environmental Protection Agency (“EPA”) to object to the above-referenced proposed Title V permit issued by the Louisiana Department of Environmental Quality (“LDEQ”) for the “Utilities Unit” at the Baton Rouge, Louisiana refinery owned and operated by ExxonMobil Fuels & Lubricant Company (“Exxon”). The Utilities Unit includes the refinery’s wastewater treatment system, which annually emits hundreds of tons of volatile organic compounds (“VOCs”) and VOC hazardous air pollutants (“HAPs”). Both LDEQ and Exxon concede that the VOC emissions from the treatment system are highly variable. Yet the proposed permit does not contain monitoring and emission calculation methods that can ensure compliance with the limits for total VOCs from the treatment system. Among other problems, the permit fails to require Exxon to perform periodic studies to validate the accuracy of its predictive-modeling calculations of VOC emissions and fails to require Exxon to take into account site-specific biodegradation rates in calculating emissions from its biological treatment units, which are by far the highest emitters of VOCs (and VOC HAPs) in Exxon’s treatment system.
    [Show full text]
  • Simulation and Modeling of Catalytic Reforming Process
    Petroleum & Coal ISSN 1337-7027 Available online at www.vurup.sk/petroleum-coal Petroleum & Coal 54 (1) 76-84, 2012 SIMULATION AND MODELING OF CATALYTIC REFORMING PROCESS Aboalfazl Askari*, Hajir Karimi, M.Reza Rahimi, Mehdi Ghanbari Chemical engineering department, School of engineering,Yasouj University,Yasouj 75918-74831, Iran; [email protected] Received July 26, 2011, Accepted January 5, 2012 Abstract One of the most important processes in oil refineries is catalytic reforming unit in which high octane gasoline is produced. The catalytic reforming unit by using Hysys-refinery software was simulated. The results are validated by operating data, which is taken from the Esfahan oil refinery catalytic reforming unit. Usually, in oil refineries, flow instability in composition of feedstock can affect the product quality. The attention of this paper was focused on changes of the final product flow rate and product’s octane number with respect to the changes in the feedstock composition. Also, the effects of temperature and pressure on the mentioned parameters was evaluated. Furthermore, in this study, Smith kinetic model was evaluated. The accuracy of this model was compared with the actual data and Hysys-refinery’s results. The results showed that if the feed stream of catalytic reforming unit supplied with the Heavy Isomax Naphtha can be increased, more than 20% of the current value, the flow rate and octane number of the final product will be increased. Also, we found that the variations of temperature and pressure, under operating condition of the reactors of this unit, has no effect on octane number and final product flow rate.
    [Show full text]