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The Regional Distribution of Zeolites in the Basalts of the Faroe Islands and the Significance of Zeolites As Palaeo- Temperature Indicators
The regional distribution of zeolites in the basalts of the Faroe Islands and the significance of zeolites as palaeo- temperature indicators Ole Jørgensen The first maps of the regional distribution of zeolites in the Palaeogene basalt plateau of the Faroe Islands are presented. The zeolite zones (thomsonite-chabazite, analcite, mesolite, stilbite-heulandite, laumontite) continue below sea level and reach a depth of 2200 m in the Lopra-1/1A well. Below this level, a high temperature zone occurs characterised by prehnite and pumpellyite. The stilbite-heulan- dite zone is the dominant mineral zone on the northern island, Vágar, the analcite and mesolite zones are the dominant ones on the southern islands of Sandoy and Suðuroy and the thomsonite-chabazite zone is dominant on the two northeastern islands of Viðoy and Borðoy. It is estimated that zeolitisa- tion of the basalts took place at temperatures between about 40°C and 230°C. Palaeogeothermal gradients are estimated to have been 66 ± 9°C/km in the lower basalt formation of the Lopra area of Suðuroy, the southernmost island, 63 ± 8°C/km in the middle basalt formation on the northernmost island of Vágar and 56 ± 7°C/km in the upper basalt formation on the central island of Sandoy. A linear extrapolation of the gradient from the Lopra area places the palaeosurface of the basalt plateau near to the top of the lower basalt formation. On Vágar, the palaeosurface was somewhere between 1700 m and 2020 m above the lower formation while the palaeosurface on Sandoy was between 1550 m and 1924 m above the base of the upper formation. -
Washington State Minerals Checklist
Division of Geology and Earth Resources MS 47007; Olympia, WA 98504-7007 Washington State 360-902-1450; 360-902-1785 fax E-mail: [email protected] Website: http://www.dnr.wa.gov/geology Minerals Checklist Note: Mineral names in parentheses are the preferred species names. Compiled by Raymond Lasmanis o Acanthite o Arsenopalladinite o Bustamite o Clinohumite o Enstatite o Harmotome o Actinolite o Arsenopyrite o Bytownite o Clinoptilolite o Epidesmine (Stilbite) o Hastingsite o Adularia o Arsenosulvanite (Plagioclase) o Clinozoisite o Epidote o Hausmannite (Orthoclase) o Arsenpolybasite o Cairngorm (Quartz) o Cobaltite o Epistilbite o Hedenbergite o Aegirine o Astrophyllite o Calamine o Cochromite o Epsomite o Hedleyite o Aenigmatite o Atacamite (Hemimorphite) o Coffinite o Erionite o Hematite o Aeschynite o Atokite o Calaverite o Columbite o Erythrite o Hemimorphite o Agardite-Y o Augite o Calciohilairite (Ferrocolumbite) o Euchroite o Hercynite o Agate (Quartz) o Aurostibite o Calcite, see also o Conichalcite o Euxenite o Hessite o Aguilarite o Austinite Manganocalcite o Connellite o Euxenite-Y o Heulandite o Aktashite o Onyx o Copiapite o o Autunite o Fairchildite Hexahydrite o Alabandite o Caledonite o Copper o o Awaruite o Famatinite Hibschite o Albite o Cancrinite o Copper-zinc o o Axinite group o Fayalite Hillebrandite o Algodonite o Carnelian (Quartz) o Coquandite o o Azurite o Feldspar group Hisingerite o Allanite o Cassiterite o Cordierite o o Barite o Ferberite Hongshiite o Allanite-Ce o Catapleiite o Corrensite o o Bastnäsite -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
Key to Rocks & Minerals Collections
STATE OF MICHIGAN MINERALS DEPARTMENT OF NATURAL RESOURCES GEOLOGICAL SURVEY DIVISION A mineral is a rock substance occurring in nature that has a definite chemical composition, crystal form, and KEY TO ROCKS & MINERALS COLLECTIONS other distinct physical properties. A few of the minerals, such as gold and silver, occur as "free" elements, but by most minerals are chemical combinations of two or Harry O. Sorensen several elements just as plants and animals are Reprinted 1968 chemical combinations. Nearly all of the 90 or more Lansing, Michigan known elements are found in the earth's crust, but only 8 are present in proportions greater than one percent. In order of abundance the 8 most important elements Contents are: INTRODUCTION............................................................... 1 Percent composition Element Symbol MINERALS........................................................................ 1 of the earth’s crust ROCKS ............................................................................. 1 Oxygen O 46.46 IGNEOUS ROCKS ........................................................ 2 Silicon Si 27.61 SEDIMENTARY ROCKS............................................... 2 Aluminum Al 8.07 METAMORPHIC ROCKS.............................................. 2 Iron Fe 5.06 IDENTIFICATION ............................................................. 2 Calcium Ca 3.64 COLOR AND STREAK.................................................. 2 Sodium Na 2.75 LUSTER......................................................................... 2 Potassium -
Investigations of Mixed-Anion Analogs of Manganite Perovskites and Bimetallic
Investigations of Mixed-Anion Analogs of Manganite Perovskites and Bimetallic Group II Nitride Fluorides By Oscar Kipruto Keino Submitted in Partial Fulfillment of the Requirements For the Degree of Master of Science in the Chemistry Program YOUNGSTOWN STATE UNIVERSITY December, 2017 Investigations of Mixed-Anion Analogs of Manganite Perovskites and Bimetallic Group II Nitride Fluorides By Oscar Kipruto Keino I hereby release this thesis to the public. I understand that this thesis will be made available from the Ohio LINK ETD Center and the Maag Library Circulation Desk for public access. I also authorize the University or other individuals to make copies of this thesis as needed for scholarly research. Signature: ________________________________________________________________ Oscar Kipruto Keino, Student Date Approvals: ________________________________________________________________ Dr. Timothy R. Wagner, Thesis Advisor Date ________________________________________________________________ Dr. Sherri Lovelace-Cameron, Committee Member Date ________________________________________________________________ Dr. Allen Hunter, Committee Member Date ________________________________________________________________ Dr. Salvatore A. Sanders, Date Dean, College of Graduate Studies iii ABSTRACT Lanthanum manganites are perovskite related materials known in particular for their colossal magnetoresistance (CM) properties. Manganite compositions showing CM behavior are mixed cation compounds such as (CaxLa1-x) MnO3, which contain Mn ions in mixed -
Mineralogy and Metallogenesis of the Sanbao Mn–Ag (Zn-Pb) Deposit in the Laojunshan Ore District, SE Yunnan Province, China
minerals Article Mineralogy and Metallogenesis of the Sanbao Mn–Ag (Zn-Pb) Deposit in the Laojunshan Ore District, SE Yunnan Province, China Shengjiang Du 1,2, Hanjie Wen 3,4,*, Shirong Liu 3, Chaojian Qin 3, Yongfeng Yan 5, Guangshu Yang 5 and Pengyu Feng 5 1 State Key Laboratory of Nuclear Resources and Environment, East China University of Technology, Nanchang 330013, China; [email protected] 2 Chinese Academy of Geological Science, Beijing 100037, China 3 State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China; [email protected] (S.L.); [email protected] (C.Q.) 4 University of Chinese Academy of Sciences, Beijing 100049, China 5 Kunming University of Science and Technology, Kunming 650093, China; [email protected] (Y.Y.); [email protected] (G.Y.); [email protected] (P.F.) * Correspondence: [email protected] Received: 26 June 2020; Accepted: 17 July 2020; Published: 23 July 2020 Abstract: The Sanbao Mn–Ag (Zn-Pb) deposit located in the Laojunshan ore district is one of the most important deposits that has produced most Ag and Mn metals in southeastern Yunnan Province, China. Few studies are available concerning the distribution and mineralization of Ag, restricting further resource exploration. In this study, detailed mineralogy, chronology, and geochemistry are examined with the aim of revealing Ag occurrence and its associated primary base-metal and supergene mineralization. Results show that manganite and romanèchite are the major Ag-bearing minerals. Cassiterite from the Mn–Ag ores yielded a U–Pb age of 436 17 Ma, consistent with ± the Caledonian age of the Nanwenhe granitic pluton. -
Studies of the Zeolites Composition of Zeolites of the Natrolite Group and Compositional Relations Among Thomsonites Gonnardites, and Natrolites
r-'1 ~ Q I ~ c lt') ~ r-'1 'JJ ~ Q.) < ~ ~ ......-~ ..,.;;j ~ <z 0 0 Q.) 1-4 rJ:J rJ:J N r-'1 ~ Q.) 0 ~ ..c ~ ~ ~ I r-'1 ~ > ~ 0 I ~ rJ:J 'JJ ..,.;;j Q.) < .....-~ 0 . 1-4 ~ C"-' 0 ~ ..,.;;j ~ 0 r-'1 00 C"-' Foster-STUDIES•. OF THE ZEOLITES-Geological Survey Professional Paper 504-D, E Studies of the Zeolites Composition of Zeolites of the Natrolite Group and Compositional Relations among Thomsonites Gonnardites, and Natrolites By MARGARET D. FOSTER SHORTER CONTRIBUTIONS TO GENERAL GEOLOGY GEOLOGICAL SURVEY PROFESSIONAL PAPER 504-D, E UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON 1965 UNITED STATES DEPARTMENT OF THE INTERIOR STEWART L. UDALL, Secretory GEOLOGICAL SURVEY Thomas B. Nolan, Director The U.S. Geological Survey Library has cataloged this publication as follows: Foster, Margaret Dorothy, 1895- Studies of the zeolites. D. Composition of zeolites of the natrolite group. E. Compositional relations among thom sonites, gonnardites, and natrolites. Washington, U.S. Govt. Print. Off., 1965. v, 7; iii, 10 p. diagrs., tables. 30 em. (U.S. Geological Survey. Professional paper 504-D, E) Shorter contributions to general geology. Each part also has separate title page. Includes bibliographies. (Continued on next card) Foster, Margaret Dorothy, 1895- Studies of the zeolites. 1965. (Card 2) 1. Zeolites. I. Title. II. Title: Composition of zeolites of the natro lite group. III. Title: Compositional relations among thomsonites, gonnardites, and natrolites. (Series) For sale by the Superintendent of Documents, U.S. Government Printing Office Washington, D.C. 20402 - Price 25 cents (paper cover) Studies of the Zeolites Composition of Zeolites of the N atrolite Group By MARGARET D. -
The Thermal Transformation of Datolite, Cabsio4(OH), to Boron.Melilite
MINERALOGICAL MAGAZINE, JUNE I973, VOL. 39, PP. 158-75 The thermal transformation of datolite, CaBSiO4(OH), to boron.melilite J. TARNEY, A. W. NICOL, and GISELLE F. MARRINER Departments of Geology, Minerals Engineering, and Physics, respectively, University of Birmingham SUMMARY. A kinetic and X-ray study of the dehydroxylation of datolite, CaBSiO4(OH), has shown that the decomposition occurs very rapidly above 7o0 ~ in air, with an activation energy for the reaction of the order of 200 kcal mole-1. The transformation is topotactic, the dehydroxylated phase being tetragonal with a 7" 14/~t, c 4-82 fit, and particularly well formed even at the lowest temperatures of decomposition. Single-crystal studies have shown that two orientations of the new phase exist and that the original a of datolite becomes the unique axis of the tetragonal phase while the tetragonal a axes are oriented either parallel to or at 45 ~ to the b and c axes of datolite. The new phase appears to be a boron-containing analogue of the melilite structure, composition Ca2SiB~OT, but is metastable. The basic sheet structure is preserved during the transformation but a reorganization of the tetra- hedral layer from the 4- and 8-membered rings of datolite to the 5-membered rings of the new phase is involved, together with effective removal of protons and some silicon. The transformation can be explained in terms of an inhomogeneous reaction mechanism involving migration of calcium and boron into the new phase domains and counter-migration of silicon and protons, but with only minor readjustment of oxygens. -
The Thermal Dehydration of Natural Zeolites
549.67:536.4 MEDEDELINGEN LANDBOUWHOGESCHOOL WAGENINGEN • NEDERLAND • 74-9 (1974) THE THERMAL DEHYDRATION OF NATURAL ZEOLITES (with a summary in Dutch) L. P. VAN REEUWIJK Department of Soil Science and Geology, Agricultural University, Wageningen, The Netherlands (Received 11-11-1974) H. VEENMAN & ZONEN B.V. - WAGENINGEN - 1974 Ml Mededelingen Landbouwhogeschool Wageningen 74-9 (1974) (Communications Agricultural University) is also published as a thesis CONTENTS 1. INTRODUCTION 1 1.1. History 1 1.2. Genesis and occurrence of natural zeolites 2 1.3. Structural classification 4 1.4. Practical applications of zeolites 8 2. THE DEHYDRATION OF ZEOLITES - A CRITICAL REVIEW 11 2.1. Introduction 11 2.2. DTA and TG 12 2.3. High temperature X-ray analysis 13 2.4. Vapour pressure 14 2.5. The reaction mechanism 15 2.6. Rehydration 16 3. THE COMPLEXITY OF THE DEHYDRATION PROCESS 17 3.1. Types of dehydration 17 3.2. Examples 18 3.3. Effect of pressure on dehydration 22 3.3.1. Qualitative aspect 22 3.3.2. Quantitative aspect - Calibration of pressure 25 3.4. Dehydration equilibrium and hysteresis 26 3.5. Internal and external adsorption 28 4. DEHYDRATION OF ZEOLITES OF THE NATROLITE GROUP 30 4.1. Materials and procedures 30 4.2. Results and discussion 31 4.2.1. Natrolite 31 4.2.2. Mesolite 33 4.2.3. Scolecite 36 4.2.4. Thomsonite 37 4.2.5. Gonnardite 37 4.2.6. Edingtonite 38 4.3. Conclusions 39 5. PRESSURE-TEMPERATURE RELATIONS 40 5.1. The Clausius-Clapeyron equation 41 5.2. Experimental 43 5.3. -
Gonnardite Na2caal4si6o20 ² 7H2O C 2001 Mineral Data Publishing, Version 1.2 ° Crystal Data: Tetragonal
Gonnardite Na2CaAl4Si6O20 ² 7H2O c 2001 Mineral Data Publishing, version 1.2 ° Crystal Data: Tetragonal. Point Group: 42m: Fibrous crystals, at the centers of radiating spherulites, to 3 cm; massive. Physical Properties: Hardness = 5 D(meas.) = 2.25{2.36 D(calc.) = 2.33 Optical Properties: Translucent. Color: White, yellowish to salmon-red. Luster: Silky. Optical Class: Biaxial (+) or ({); commonly zoned. Orientation: X = c. ® = 1.497{1.508 ¯ = 1.498{1.510 ° = 1.499{1.513 2V(meas.) = 50± Cell Data: Space Group: I42d: a = 13.21(1) c = 6.622(4) Z = 2 X-ray Powder Pattern: Chaux de Bergonne, France; may be confused with natrolite and tetranatrolite. 2.92 (100), 5.93 (80), 6.70 (60), 4.44 (60), 4.74 (50), 3.23 (50), 3.12 (40) Chemistry: (1) (2) (3) SiO2 43.45 43.20 44.58 Al2O3 27.91 27.90 25.22 CaO 6.95 3.61 6.94 Na2O 8.69 13.16 7.66 H2O [13.00] 11.74 15.60 Total [100.00] 99.61 100.00 (1) Chaux de Bergonne, France; by electron microprobe, H2O by di®erence; corresponding to Na2:22Ca0:98Al4:32Si5:71O20 ² 5:70H2O: (2) Aci Trezza, Sicily, Italy; corresponds to Na3:5Ca0:5Al4:5 Si5:9O20:8 ² 5:35H2O: (3) Na2CaAl4Si6O20 ² 7H2O: Mineral Group: Zeolite group. Occurrence: In cavities in basalt, leucite tephrite, and altered skarn. Association: Zeolites, calcite. Distribution: Well characterized material from: in France, at Chaux de Bergonne, Gignat, Puy de D^ome. In Italy, from Capo di Bove, near Rome, Lazio; and at Aci Castello, Aci Trezza, Osilo, and other places on Sardinia. -
Crystal Structure of Protoamphibole
Mineral. Soc. Amer. Spec. Pap. 2, 101-109 (1969). CRYSTAL STRUCTURE OF PROTOAMPHIBOLE G. V. GIBBS Department of Geological Sciences, Virginia Polytechnic Institute Blacksburg, Virginia 24061 ABSTRACT The structure proposed for protoamphibole (Gibbs et al., 1960) has been verified and refined by three-dimensional Fourier and least-squares methods using data collected with a Weissenberg single crystal counter-diffractometer. The symmetry is Pnmn with a = 9.330, b = 17.879 and c = 5.288 A and the unit-cell content is 2(Nao.03Li",oMg, ••) (Si r. ,.Alo.040,1.71) (OHo.15F,.14). The structure consists of layers of interlocking chains of fluorine-centered hexagonal rings of SiO. groups. The layers are bound together by Mg.Li cations which are coordinated between the chains, the coordination being effected by a ~(cI3) stagger between adjacent layers. An additional stagger of ~(-cI3) in the sequence along a gives an overall displacement of zero between alternate layers, accounting for the 9.33 A a cell edge and the orthogonal geometry. The direction of stagger can be related to the placement of the cations in the octahedral layer. The M -cation coordination groups are nearly regular octahedra with the exception of M(4) which is similar to Mg(l) in protoenstatite. The M(3), M(1) and M(2) sites are occupied principally by Mg. In addition to being randomly distributed around the cavity walls of the A-site, Li ions are also segregated in about 25% of the M(4) sites, the others being occupied by Mg ions. The individual Si-O bond distances in the chains are consistent with Cruickshank's d-p -n: bonding model: Si-O(non- bridging) bonds [Si(1)-O(1) = 1.592; Si(2)-0(4) = 1.592; Si(2)-0(2) = 1.605 AJ are significantly shorter, on the average, than the Si-O(bridging) bonds [Si(1)-0(5) = 1.616; Si(1)-0(6) = 1.623; Si(1)-0(7) = 1.624; Si(2)-0(5) = 1.626; Si(2)-0(6) = 1.655 AJ. -
NVMC Nov 2019 Newsletter.Pdf
The Mineral Newsletter Meeting: November 18 Time: 7:45 p.m. Long Branch Nature Center, 625 S. Carlin Springs Rd., Arlington, VA 22204 Volume 60, No. 9 November 2019 Explore our website! November Meeting Program: Making Sugarloaf Mountain (details on page 5) In this issue … Mineral of the month: Datolite ................. p. 2 November program details ........................ p. 5 Annual Holiday Party coming up! ............. p. 5 President’s collected thoughts .................. p. 5 October meeting minutes .......................... p. 7 Nominations for 2019 club officers ........... p. 8 Datolite nodule Club show volunteers needed! .................. p. 8 Quincy Mine, Michigan Bench tip: Sheet wax with adhesives ......... p. 9 Source: Brandes (2019). Photo: Paul T. Brandes. Annual show coming up—Help needed! .. p. 10 EFMLS: Wildacres—finally! ........................ p. 12 AFMS: Scam targets mineral clubs ............ p. 13 Safety: Be prepared ................................... p. 13 Deadline for Submissions Field trip opportunity ................................. p. 14 November 20 Manassas quarry geology, pt. 2 ................. p. 15 Please make your submission by the 20th of the month! Upcoming events ....................................... p. 20 Submissions received later might go into a later newsletter. 28th Annual Show flyer ............................. p. 21 Mineral of the Month Datolite by Sue Marcus Datolite, our mineral this month, is not a zeolite, alt- hough it often occurs with minerals of the Zeolite Group. It can form lustrous crystals or attractive masses that take a nice polish. And, for collectors like Northern Virginia Mineral Club me, it is attainable! members, Etymology Please join our guest speaker, Joe Marx, for dinner at Datolite was named in 1806 by Jens Esmark, a Danish- the Olive Garden on November 18 at 6 p.m.