<<

MATERIAL SAFETY DATA SHEET 825-009 Heat & Fluid Resistant Coating FM5736 Effective Date: 04/25/01

SECTION I - MANUFACTURER AND PRODUCT INFORMATION

PRC-DeSoto International, Inc. A PPG Industries Company Information Phone: (818) 240-2060 5430 San Fernando Road Emergency Phone: (800) 228-5635 P.O. Box 1800 CHEMTREC: (800) 424-9300 Glendale, CA 91209

Trade Name: 825-009 Heat & Fluid Resistant Coating Base component HMIS HAZARD RATING Product Code: FM5736 HEALTH - 2 Form ID No: A05 FLAMMABILITY - 3 Product Class Polyester resin in solvents REACTIVITY - 0 Synonyms: PPE - H None(0) >Extreme(4)

SECTION II - COMPOSITION

INGREDIENTS INFORMATION CAS NUMBER wt ^ CHEMICAL IDENTITY 000108-10-1 10 - 30 Methyl Isobutyl Ketone 068797-54-6 10 - 30 Polyester Polymer 014807-96-6 10 - 30 Talc 013765-19-0 10 - 30 Chromate 000141-78-6 1 - 10 Ethyl Acetate 051274-00-1 1 - 10 Iron Yellow 007429-90-5 1 - 10 Aluminum 000108-88-3 < 5 Toluene 001330-20-7 < 5 Xylene 000078-93-3 < 5 Methyl Ethyl Ketone 008052-41-3 < 5 Stoddard Solvent 064742-95-6 < 5 Naphtha-Light Aromatic 001333-86-4 < 2 Carbon Black

EXPOSURE LIMITS EXPOSURE LIMITS (ppm) ACGIH TLVs OSHA PELs CAS NUMBER TWA STEL TWA STEL 000108-10-1 50 75 50 75 068797-54-6 N/E N/E N/E N/E 014807-96-6

Page Number Continued MATERIAL SAFETY DATA SHEET 825-009 Heat & Fluid Resistant Coating FM5736 Effective Date: 04/25/01

2 mg/m3 N/E 2 mg/m3 N/E S 013765-19-0 0.05 mg/m 3N/E 0.10 mg/m3N/E s 000141-78-6 400 N/E 400 N/E s 051274-00-1 5 mg/m3 N/E 10 N/E s 007429-90-5 5 mg/m3 N/E 15 mg/m3 N/E s 000108-88-3 50 N/E 100 N/E s 001330-20-7 100 150 100 150 s 000078-93-3 200 300 200 300 s 008052-41-3 100 N/E 100 N/E s 064742-95-6 245 mg/m3 N/E 245 mg/m3 N/E R 001333-86-4 3.5 mg/m3 N/E 3.5 mg/m3 N/E s

Footnotes (S) Occupational Exposure Standard (R) Supplier's Recommended Limit

N/Av = Not Available N/Ap = Not Applicable N.E. = Not Established NotknownXXX = CAS Number is not known

SECTION III - HAZARDS IDENTIFICATION

Permissible Exposure Limits for Product: Not established for product. See Section II.

ROUTE OF ENTRY AND EFFECTS OF OVEREXPOSURE ROUTE OF ENTRY: Inhalation and dermal. INHALATION: Vapor and mist will irritate nose, throat and respiratory tract. High vapor concentration may cause dizziness, drowsiness and fatigue. EYE CONTACT: Vapor, mist or liquid is severely irritating to eyes and cause blurred vision, redness and tearing. SKIN CONTACT: Liquid can cause severe skin irritation with drying, defatting, splitting and cracking on repeated contact. INGESTION: Liquid can cause irritation of gastro-intestinal tract followed by nausea and vomiting, abdominal discomfort, and rapid pulse. DELAYED EFFECTS: Repeated overexposure may cause central nervous systems depression.

Page Number Continued MATERIAL SAFETY DATA SHEET 825-009 Heat & Fluid Resistant Coating FM5736 Effective Date: 04/25/01

and kidney/liver damage. Contains an ingredient listed as known or suspected ? NTP: Yes OSHA: No lARC: Yes

SECTION IV - FIRST AID MEASURES

INHALATION: If inhaled, remove from area to fresh air. If not breathing, give artificial respiration. Get immediate medical attention. If breathing is difficult, transport to medical facility and, if available, give supplemental oxygen. EYE CONTACT: For eye contact, immediately flush eyes for at least 15 minutes with running water. Hold eyelids apart to ensure rinsing of the entire eye surface and lids with water. Get immediate medical attention. SKIN CONTACT: For skin contact, wipe excess material with dry towel. Then wash exposed areas with plenty of water, and soap if available, for several minutes. Get medical attention if irritation occurs. INGESTION: If swallowed dilute by giving two (2) glasses of water to drink. Get immediate medical attention. Never give anything by mouth to an unconscious person. GENERAL: In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person

SECTION V - FIRE AND EXPLOSION HAZARD IDENTIFICATION

FLASHPOINT: 22 F -5.56 C Method: Setaflash LEL (%): N/AV UEL (%): N/AV FLAMMABILITY CLASSIFICATION: Flammable FIRE AND EXPLOSION HAZARDS: Decomposition and combustion products may be hazardous. High temperatures may cause pressure build-up in closed containers. Vapors may accumulate in inadequately ventilated or confined areas. Vapors may form explosive mixture with air. Vapors are heavier than air and may travel long distances. Flashback or flame to the

Page Number 3 Continued MATERIAL SAFETY DATA SHEET 825-009 Heat & Fluid Resistant Coating FM5736 Effective Date: 04/25/01

handling site may occur. Closed containers may explode when exposed to extreme heat. EXTINGUISHING MEDIA: Carbon dioxide, dry chemical, foam. FIRE FIGHTING PROCEDURES: Water spray may be ineffective. Cool fire exposed containers with water. Fog nozzles are preferrable. Wear NIOSH/MSHA approved self-contained breathing apparatus and complete protective clothing to prevent contact with skin and eyes.

SECTION VI - ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Remove all ignition sources. Wear an air-supplied respirator for an unventilated spill. Dike and cover spill with non-oxidizable absorbent. Scoop into containers. Sprinkle sodium thiosulfate on the residue and work in. Scoop into disposal container. Clean up with water. Wear appropriate personal protective equipment (See Section VIII).

SECTION VII - HANDLING AND STORAGE

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Keep container tightly closed . Isolate from heat, electrical equipment, sparks and flame. Use grounding and bonding procedures during transfer. Do not store above 120 degrees F. Vapors of this product are heavier than air and may collect in low or confined areas. Empty drums may contain explosive vapors. Do not cut, puncture, or weld on or near drum. Wear proper personal protective equipment (See Section VIII). Wash thoroughly after handling and before smoking or eating.

Page Number 4 Continued MATERIAL SAFETY DATA SHEET 825-009 Heat & Fluid Resistant Coating FM5736 Effective Date: 04/25/01

SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: Local and/or general ventilation as required to maintain hazardous ingredients below recommended (ACGIH-TLV) or regulated (OSHA-PEL) limits. RESPIRATORY PROTECTION: When spraying or applying in any circumstances likely to produce airborne levels of solvent vapors in excess of the TLV, use an organic vapor cartridge or air-supplied respirator. EYE PROTECTION: Chemical goggles or full-face shield. SKIN PROTECTION: Solvent resistant gloves. GENERAL: Safety shower, eye wash station and washing facilities should be available. When using in circumstances where skin contact is likely, use complete protective garments.

SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Green Physical State: Liquid Low Boiling Point: N/Av High Boiling Point: N/Av Evaporation Rate: Slower than n-butyl acetate Vapor Density: Heavier than air % Volatiles by Volume: 58.3 Specific Gravity: 1.257 Liquid Density: Heavier than water Weight Per Gallon; 10.47 VOC (GR/L): 510 VOC (GR/L, Combined): N/Av

Page Number Continued MATERIAL SAFETY DATA SHEET 825-009 Heat & Fluid Resistant Coating FM5736 Effective Date: 04/25/01

SECTION X - STABILITY AND REACTIVITY

STABILITY: Stable. HAZARDOUS POLYMERIZATION: Will not occur. INCOMPATABILITY: Strong oxidizing agents, acids, alkalies, and water. CONDITIONS TO AVOID: See incompatibilities above. HAZARDOUS DECOMPOSITION PRODUCTS: Products of combustion are hazardous including carbon monoxide, carbon dioxide, and of nitrogen.

SECTION XI - TOXICOLOGICAL INFORMATION

ACUTE ORAL, DERMAL AND INHALATION EFFECTS {LD50 AND LC50): CAS NUMBER LD50 LC50 000108-10-1 2080 mg/kg,oral, rat 2000 ppm,rat,4hr. 068797-54-6 N/AV. N/AV. 014807-96-6 5000 mg/kg,oral,rat N/AV. 013765-19-0 5000 ma/kg,oral, rat N/AV. 000141-78-6 10200 mg/kg,oral,rat 19600 ppm,rat,4hr. 051274-00-1 5000 mg/kg,oral,rat N/AV. 007429-90-5 5000 mg/kg,oral,rat N/AV. 000108-88-3 2 600 mg/kg,oral, rat 8800 ppm,rat,4hr. 001330-20-7 5400 mg/kg,oral, rat 6350 ppm,rat,4hr. 000078-93-3 2740 mg/kg,oral, rat 11700 ppm,rat,4hr. 008052-41-3 5000 mg/kg,oral,rat 880 ppm,rat,4hr. 064742-95-6 N/AV. N/AV. 001333-86-4 4 40 mg/kg,oral,rat 6750 mg/m3,rat, 4hr

Carcinogenicity: Carbon Black: Based on an lARC conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of carbon black" and inadequate evidence of carcinogenicity in humans. lARC's overall evaluation is that "carbon black is possibly carcinogenic to humans" (Group 2B).

Page Number Continued MATERIAL SAFETY DATA SHEET 825-009 Heat & Fluid Resistant Coating FM5736 Effective Date: 04/25/01

Carbon black has not been listed as a carcinogen by National Toxicology Program (NTP) or the Occupational Safety and Health Administration (OSHA). The National Institute of Occupational Safety & Health (NIOSH) criteria document on carbon black recommends that only carbon blacks with PAH levels greater than 0.1% be considered suspect .

Chromium Compounds (Calcium chromate):

NTP and lARC have determined that there is sufficient evidence for the carcinogenicity of hexavalent compounds both in humans and experimental animals.

Prolonged or repeated eye contactmay cause conjunctivitis. Prolonged or repeated skin contact, especially with broken skin, may cause "chrome sores". Prolonged or repeated inhalation of mist or fume may cause ulceration and perforation of nasal septum. Prolonged inhalation may cause liver damage. NOTICE: There are no data available on the product itself.

SECTION XII - ECOLOGICAL INFORMATION

NOTICE: There are no data available on the product itself.

SECTION XIII - DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD: When disposing of this material, ensure that it is packaged, stored, transported, and otherwise handled in accordance with local, state, and federal regulations. EPA WASTE NUMBERS: D-OOl (Ignitable) D-007 (Chromium)

Page Number 7 Continued MATERIAL SAFETY DATA SHEET 825-009 Heat s Fluid Resistant Coating FM5736 Effective Date: 04/25/01

SECTION XIV - TRANSPORT INFORMATION

DOT (Non-Bulk): PROPER SHIPPING NAME: Paint HAZARD CLASS: 3 UN NUMBER: UN 1263 PACKING GROUP: II LABEL: Flammable liquid SPECIAL NOTES: None

SECTION XV - REGULATORY INFORMATION

TSCA Section 8(b) - Inventory Status: All ingredients in this product are listed in the TSCA Inventory or are exempt from listing.

CANADIAN EPA - DSL Inventory Status: The DSL status of this product is unknown at this time.

SARA Title III Section 313 - Toxic Chemical List (TCL): This product contains a toxic chemical for routine annual "Toxic Chemical Release Reporting" under Section 313 (40 CFR 372). This information must be included in all MSDS's copied or distributed for this product.

000078-93-3 Methyl Ethyl Ketone 000108-10-1 Methyl Isobutyl Ketone 000108-88-3 Toluene 001330-20-7 Xylene 007429-90-5 Aluminum 013765-19-0 Calcium Chromate

SARA Title III Section 302 - CERCLA: This product contains the following chemicals regulated under Section 302 as extremely hazardous substance(s) for emergency release notification (CERCLA List).

000078-93-3 Methyl Ethyl Ketone 5000 000108-10-1 Methyl Isobutyl Ketone 5000

Page Number Continued MATERIAL SAFETY DATA SHEET 825-009 Heat & Fluid Resistant Coating FM5736 Effective Date: 04/25/01

000108-88-3 Toluene 1000 000141-78-6 Ethyl Acetate 5000 001330-20-7 Xylene 1000 013765-19-0 Calcium Chromate 10

CALIFORNIA PROPOSITION 65 - Reportable ingredients: Chemicals known by the state of CA to cause cancer: This product contains the following chemical which is known to the state of California to cause cancer.

013765-19-0 Calcium Chromate

Chemicals known by the state of CA to cause reproductive toxicity: This product contains the following chemical which is known to the state of California to cause reproductive toxicity.

000108-88-3 Toluene

TSCA Section 12(b) - Export Notification: This product contains following chemical that required annual or one time export notification per chemical and per country.

000108-10-1 Methyl Isobutyl Ketone 000123-86-4 n-Butyl Acetate 000141-78-6 Ethyl Acetate

CLEAN AIR ACT - Hazardous Air Pollutants (CAA Section 112): This product contains the following chemicals regulated under Section 112 for National Emission Standards of Hazardous Air Pollutants notification.

000078-93-3 Methyl Ethyl Ketone 000108-10-1 Methyl Isobutyl Ketone 000108-88-3 Toluene 001330-20-7 Xylene 013765-19-0 Calcium Chromate

Pennsylvania Right to Know - Reportable Ingredients: The following is required composition information. Also, review Section II for additional information for other chemicals.

000078-93-3 Methyl Ethyl Ketone 000108-10-1 Methyl Isobutyl Ketone

Page Number Continued MATERIAL SAFETY DATA SHEET 825-009 Heat & Fluid Resistant Coating FM5736 Effective Date: 04/25/01

000108-88-3 Toluene 000141-78-6 Ethyl Acetate 001330-20-7 Xylene 001333-86-4 Carbon Black 007 42 9-90-5 Aluminum 008052-41-3 Stoddard Solvent 013765-19-0 Calcium Chromate 014807-96-6 Talc

New Jersey Right to Know - Reportable Ingredients: The following is required composition information. Also, review Section II for additional information for other chemicals.

000078-93-3 Methyl Ethyl Ketone 000108-10-1 Methyl Isobutyl Ketone 000108-88-3 Toluene 000141-78-6 Ethyl Acetate 001330-20-7 Xylene 001333-86-4 Carbon Black 007 42 9-90-5 Aluminum 008052-41-3 Stoddard Solvent 013765-19-0 Calcium Chromate 014807-96-6 Talc

SECTION XVI - OTHER INFORMATION

Effective Date: 04/25/01 Supersedes Date: 12/18/2000 Revision Number: 02 Revision Reason: Section 14 Update

The information in this MSDS was obtained from sources which we believe to be reliable. However, since much of the information has been received from sources outside the company, it is provided without any warranty, expressed or implied, regarding its correctness, or suitability for specific situations. The conditions of handling, storage, use, and disposal of this product are beyond our control and may be beyond our knowledge. The user has the sole responsibility to determine the suitability of the material for any use, and the manner and conditions of use. Therefore, we cannot assume responsibility and expressly disclaim liability for loss, damage, injury, or expense arising out of or in any way connected

Page Number 10 Continued MATERIAL SAFETY DATA SHEET 825-009 Heat & Fluid Resistant Coating FM5736 Effective Date: 04/25/01

with the handling, storage, use or disposal of the product. Effects can be aggravated by other materials and/or this material may aggravate or add to the effects of other materials.

End of Document MATERIAL SAFETY DATA SHEET PRC-DeSoto International

Trade Name: 910-175 Heat & Fluid Resistant Ctg Activator Product Identifier: FM8413B Preparation Date 05/23/03

SECTION I - MANUFACTURER AND PRODUCT INFORMATION

Supplier : PRC-DeSoto International Telephone : (905) 629-7999 A PPG Industries Company Emergency Only : (613) 996-6666 5676 Timberlea Blvd. Mississauga, ON L4W 4M6

Trade Name: 910-175 Heat & Fluid Resistant Ctg Activator Product Identifier: FM8413B Product Use: Activator MSDS ID Number: FM8413B-01 Other Names: None

Manufacturer: PRC-DeSoto International, Inc.Information Phone: (818; 240-2060 A PPG Industries Company Emergency Phone : (800 228-5635 5430 San Fernando Road P.O. Box 1800 Glendale CA 91209

SECTION II - COMPOSITION

HAZARDOUS INGREDIENTS

INGREDIENT CAS NUMBER Wt % Polymeric Diphenylmethane Diisocyanate 009016-87-9 30 - 60 4,4'-Diphenylmethane Diisocyanate 000101-68-8 30 - 60 Methyl Ethyl Ketone 000078-93-3 7-13 Diphenylmethane Diisocynate 026447-40-5 3-7

EXPOSURE LIMITS (ppm) ACGIH TLVs OSHA PELS INGREDIENT

Page Number Cont MATERIAL SAFETY DATA SHEET PRC-DeSoto International

Trade Name: 910-175 Heat S Fluid Resistant Ctg Activator Product Identifier: FM8413B Preparation Date: 05/23/03

CAS NUMBER TWA STEL TWA STEL Polymeric Diphenylmethane Diisocyanate 009016-87-9 N/E N/E 0.02 N/E S 4,4'-Diphenylmethane Diisocyanate 000101-68-8 0,005 N/E 0.02 N/E s Methyl Ethyl Ketone 000078-93-3 200 300 200 300 s Diphenylmethane Diisocynate 026447-40-5 N/E N/E N/E N/E

Footnotes (M) Maximum Exposure Limit (S) Occupational Exposure Standard (R) Supplier's Recommended Limit

N/Av = Not Available = X N/Ap = Not Applicable N/E = Not Established

SECTION III - HEALTH HAZARD DATA

Permissible Exposure Limits for Product: Not established for product. See Section II.

ROUTE OF ENTRY AND EFFECTS OF OVER-EXPOSURE EYE CONTACT : Irritation, watering and possible reversible corneal damage. SKIN CONTACT : Local irritation and discoloration. May cause allergic skin rash in sensitized individuals. Prolonged skin contact may result in sensitization in some individuals. Prolonged or repeated skin contact with solvents may cause irritation, defatting or dermatitis. INHALATION: Irritation to nose and throat. Prolonged exposure above TWA may cause headache, fatigue, confusion, dizziness, drowsiness, numbness and unconsciousness. Prolonged exposure can cause liver and kidney damage.

Page Number 2 Continued MATERIAL SAFETY DATA SHEET PRC-DeSoto International

Trade Name: 910-175 Heat & Fluid Resistant Ctg Activator Product Identifier: FM8413B Preparation Date: 05/23/03

Due to low volatility, significant exposure to isocyanate vapours is not expected unless over-heated or sprayed. Excessive inhalation can produce irritation of the nose, throat and respiratory tract. Excessive and extensive exposure to isocyanate vapours can produce reversible symptoms of bronchitis. Sensitized individuals will develop asthma-like symptoms at low exposure. Individuals suffering from asthma or other chronic respiratory conditions may exhibit a heightened sensitivity to isocyanates and should avoid inhalation exposure. INGESTION : Irritation and possible corrosive action in the mouth, stomach tissue and digestive tract. May also result in gastrointestinal irritation, nausea, vomiting and diarrhea. OTHER HEALTH EFFECTS: This material contains no ingredient known or suspected to be a carcinogen, teratogen, mutagen or reproductive toxin unless indicated below. No synergistic materials known unless indicated below.

SECTION IV - FIRST AID MEASURES

EYE CONTACT: Flush with luke-warm water for 15 minutes. If irritation persists, consult a physician. SKIN CONTACT : Wash affected area with soap and water. If irritation persists, consult a physician. INHALATION: Remove victim from exposure to fresh air. If irritation persists, consult a physician. INGESTION: Give milk or water, if conscious. Consult a physician.

Page Number Continued MATERIAL SAFETY DATA SHEET PRC-DeSoto International

Trade Name: 910-175 Heat & Fluid Resistant Ctg Activator Product Identifier: FM8413B Preparation Date: 05/23/03

SECTION V - FIRE AND EXPLOSION HAZARD IDENTIFICATION

FLASHPOINT: 22 F -5.56 C Method: Setaflash LEL (%): N/Av UEL (%): N/Av AUTO-IGNITION TEMPERATURE: N/Av CONDITIONS OF FLAMMABILITY: Material will burn on exposure to a source of ignition. EXTINGUISHING MEDIA: C02, dry chemical, foam SPECIAL FIRE FIGHTING PROCEDURES AND UNUSUAL FIRE HAZARDS: Decomposition and combustion products may be hazardous. Wear an air-supplied respirator and complete personal protection. High temperatures may cause pressure build-up in closed containers. Use water to cool heat exposed containers. Vapours may accumulate in inadequately ventilated or confined areas. Vapours may also travel long distances to a source of ignition. Flashback to the handling site may occur. EXPLOSION DATA: Not sensitive to mechanical impact. High sensitivity to static discharge.

SECTION VI - ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IN CASE MATERIAL IS SPILLED OR RELEASED: Wear an air supplied respirator for a major, unventilated spill. Remove all sources of ignition. Use non-sparking tools. Cover with absorbant material, add decontamination solution made of (5% concentrated ammonia, 2% detergent and 93% water) and allow to react for 10 minutes. Collect in containers, add additional decontamination solution and keep loosely covered for 48 hours. Clean up residue with a suitable cleaning solvent.

Page Number 4 Continued MATERIAL SAFETY DATA SHEET PRC-DeSoto International

Trade Name: 910-175 Heat & Fluid Resistant Ctg Activator Product Identifier: FM8413B Preparation Date: 05/23/03

SECTION VII - HANDLING AND STORAGE

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in closed container in a dry place. Avoid moisture contamination which may cause C02 build-up. If mositure contamination is suspected, do not reseal containers.

SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: Local and/or general ventilation as required to maintain solvent vapours below acceptable limits. RESPIRATORY PROTECTION: When spraying, or applying in other circumstances likely to produce airborne levels of solvent or isocyanate vapours in excess of the TLV, wear an air-supplied respirator. EYE PROTECTION: Chemical goggles or a full face shield. SKIN PROTECTION: Solvent resistant gloves. OTHER PROTECTIVE EQUIPMENT: During spray applications, complete skin protection should be worn,

SECTION IX - PHYSICAL CHARACTERISTICS

Low Boiling Point: 175 F 79.44 C High Boiling Point: N/Av Odour Threshold (ppm): N/Av Vapour Density: Heavier than air. Evaporation Rate: Slower than n-butyl acetate Vapour Pressure (mm Hg); N/Av

Page Number Continued MATERIAL SAFETY DATA SHEET PRC-DeSoto International

Trade Name: 910-175 Heat & Fluid Resistant Ctg Activator Product Identifier: FM8413B Preparation Date: 05/23/03

Freezing Point: N/Av % Volatiles by volume: 14.3 Specific Gravity: 1.185 Appearance and Odour: Clear liquid, solvent odour Coefficient of water/oil: N/Av VOC (GR/L): N/Av pH: N/Av Physical State: Liquid

SECTION X - STABILITY AND REACTIVITY

STABILITY: Stable. INCOMPATIBILITY AND CONDITIONS TO AVOID: Avoid contact with water, alcohols, amines, strong bases and strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Decomposes on combustion producing oxides of carbon and nitrogen possible traces of HON and isocyanate monomer.

SECTION XI - TOXICOLOGICAL PROPERTIES

INGREDIENT CAS NUMBER LD50 LC50 Polymeric Diphenylmethane Diisocyanate 009016-87-9 10000 mg/kg,oral,rat 490 mg/m3,rat,4hr 4,4'-Diphenylmethane Diisocyanate 000101-68-8 10000 mg/kg,oral,rat 400 mg/m3,rat,4hr Methyl Ethyl Ketone 000078-93-3 2740 mg/kg,oral,rat 11700 ppm,rat,4hr Diphenylmethane Diisocynate 026447-40-5 15800 mg/kg,oral,rat 370 mg/m3,rat,4hr NOTICE: There are no data available for the product itself.

Page Number Continued MATERIAL SAFETY DATA SHEET PRC-DeSoto International

Trade Name: 910-175 Heat & Fluid Resistant Ctg Activator Product Identifier: FM8413B Preparation Date 05/23/03

SECTION XII - ECOLOGICAL INFORMATION

NOTICE: There are no data available for the product itself.

SECTION XIII - DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD: Ignitable waste. Dispose of in compliance with local provincial regulations.

SECTION XIV - TRANSPORT INFORMATION

TRANSPORT CANADA DANGEROUS GOODS SHIPPING INFORMATION

PROPER SHIPPING NAME Paint

UN Number UN1263

Class 3

Packing Group II

Page Number Continued MATERIAL SAFETY DATA SHEET PRC-DeSoto International

Trade Name: 910-175 Heat & Fluid Resistant Ctg Activator Product Identifier: FM8413B Preparation Date: 05/23/03

SECTION XV - REGULATORY INFORMATION

CEPA DOMESTIC SUBSTANCE LIST STATUS: All components are listed on the DSL.

WHMIS CLASS(ES): B2, D2A

NOTICE: This MSDS has been prepared in accordance with Canadian Legislation and contains all items required by the Controlled Products Regulations,

SECTION XVI - PREPARATION AND OTHER INFORMATION

Prepared by: Health & Safety Department Preparation Date: 05/23/03 Revision Reason: Change in section 15

The information provided herein is, to the best of the manufacturer's knowledge, current, accurate, and complete, based on information reasonably available.

End of Document MATERIAL SAFETY DATA SHEET PRC-DeSoto International

Trade Name: 020-044 Thinner Product Identifier: FM5908 Preparation Date 05/23/03

SECTION I - MANUFACTURER AND PRODUCT INFORMATION

Supplier : PRC-DeSoto International Telephone 905) 629-7999 A PPG Industries Company Emergency Only 613) 996-6666 5676 Timberlea Blvd. Mississauga, ON L4W 4M6

Trade Name: 020-044 Thinner Product Identifier: FM5908 Product Use: Solvent reducer MSDS ID Number: FM5908-01 Other Names: None

Manufacturer: PRC-DeSoto International, Inc.Information Phone: (818) 240-2060 A PPG Industries Company Emergency Phone : (800) 228-5635 5430 San Fernando Road P.O. Box 1800 Glendale CA 91209

SECTION II - COMPOSITION

HAZARDOUS INGREDIENTS

INGREDIENT CAS NUMBER Wt % Ethyl Acetate 000141-78-6 40 - 70 Cyclohexanone 000108-94-1 15 - 40

EXPOSURE LIMITS (ppm) ACGIH TLVs OSHA PELs INGREDIENT CAS NUMBER TWA STEL TWA STEL Ethyl Acetate 000141-78-6 400 N/E 400 N/E Cyclohexanone 000108-94-1 25 N/E 25 N/E

Page Number Continued MATERIAL SAFETY DATA SHEET PRC-DeSoto International

Trade Name: 020-044 Thinner Product Identifier: FM5908 Preparation Date: 05/23/03

Footnotes (M) Maximum Exposure Limit (S) Occupational Exposure Standard (R) Supplier's Recommended Limit

N/Av = Not Available = X N/Ap = Not Applicable N/E = Not Established

SECTION III - HEALTH HAZARD DATA

Permissible Exposure Limits for Product: Not established for product. See Section II.

ROUTE OF ENTRY AND EFFECTS OF OVER-EXPOSURE EYE CONTACT : Irritation. May cause burning, tearing and reddening. SKIN CONTACT : Prolonged or repeated contact may result in irritation, defatting or dermatitis. INHALATION: May cause irritation to nose and respiratory tract. Prolonged over-exposure may result in central nervous system depression characterized by headache, dizziness, staggering gait, confusion or unconsciousness. INGESTION : May cause gastrointestinal irritation, nausea, vomiting and diarrhea. OTHER HEALTH EFFECTS: This material contains no ingredient known or suspected to be a carcinogen, teratogen, mutagen or reproductive toxin unless indicated below. No synergistic materials known unless indicated below.

Page Number Continued MATERIAL SAFETY DATA SHEET PRC-DeSoto International

Trade Name: 020-044 Thinner Product Identifier: FM5908 Preparation Date: 05/23/03

SECTION IV - FIRST AID MEASURES

EYE CONTACT: Flush with luke-warm water for 15 minutes. If irritation persists, consult a physician. SKIN CONTACT : Wash affected area with soap and water. If irritation persists, consult a physician. INHALATION: Remove victim from exposure to fresh air. If irritation persists, consult a physician. INGESTION: Give milk or water, if conscious. Consult a physician.

SECTION V - FIRE AND EXPLOSION HAZARD IDENTIFICATION

FLASHPOINT: 31 F -.56 C Method: Setaflash LEL (%): N/Av UEL (%): N/Av AUTO-IGNITION TEMPERATURE: N/Av CONDITIONS OF FLAMMABILITY: Material will burn on exposure to a source of ignition. EXTINGUISHING MEDIA: C02, dry chemical, foam SPECIAL FIRE FIGHTING PROCEDURES AND UNUSUAL FIRE HAZARDS: Decomposition and combustion products may be hazardous. Wear an air-supplied respirator and complete personal protection. High temperatures may cause pressure build-up in closed containers. Use water to cool heat exposed containers. Vapours may accumulate in inadequately ventilated or confined areas. Vapours may also travel long distances to a source of ignition. Flashback to the handling site may occur. EXPLOSION DATA: Not sensitive to mechanical impact or to static discharge.

Page Number Continued MATERIAL SAFETY DATA SHEET PRC-DeSoto International

Trade Name: 020-044 Thinner Product Identifier: FM5908 Preparation Date: 05/23/03

SECTION VI - ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IN CASE MATERIAL IS SPILLED OR RELEASED: Remove ignition sources. Wear an air supplied respirator for an unventilated spill. Cover with absorbent. Scoop into containers using non-sparking tools. Clean up residue with a suitable cleaning solvent.

SECTION VII - HANDLING AND STORAGE

PRECAUTIONS TO BE TAKEN IN HANDLING AND STOPPAGE: Store in closed containers in an area away from any incompatible materials. Wash thoroughly before eating, drinking or smoking.

SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: General ventilation to maintain vapours below TWA. RESPIRATORY PROTECTION: When spraying or applying in any circumstances likely to produce airborne levels of solvent vapours in excess of the TLV, use an air-supplied respirator. EYE PROTECTION: Chemical goggles or a full face shield. SKIN PROTECTION: Solvent resistant gloves. OTHER PROTECTIVE EQUIPMENT: During spray applications, complete skin protection should be worn.

Page Number 4 Continued MATERIAL SAFETY DATA SHEET PRC-DeSoto International

Trade Name: 020-044 Thinner Product Identifier: FM5908 Preparation Date 05/23/03

SECTION IX - PHYSICAL CHARACTERISTICS

Low Boiling Point: 171 F 77.21 C High Boiling Point: 312 F 155.54 C Odour Threshold (ppm): N/Av Vapour Density: Heavier than air. Evaporation Rate: N/Av Vapour Pressure (mm Hg): N/Av Freezing Point: N/Av % Volatiles by volume: 100 Specific Gravity: 0.915 Appearance and Odour: Clear liquid, solvent odour Coefficient of water/oil N/Av VOC (GR/L): N/Av pH: N/Av Physical State: Liquid

SECTION X - STABILITY AND REACTIVITY

STABILITY: Stable. INCOMPATIBILITY AND CONDITIONS TO AVOID: None known. HAZARDOUS DECOMPOSITION PRODUCTS: Decomposes on combustion producing oxides of carbon.

Page Number Continued MATERIAL SAFETY DATA SHEET PRC-DeSoto International

Trade Name: 020-044 Thinner Product Identifier: FM5908 Preparation Date: 05/23/03

SECTION XI - TOXICOLOGICAL PROPERTIES

INGREDIENT CAS NUMBER LD50 LC50 Ethyl Acetate 000141-78-6 10200 mg/kg,oral,rat 19600 ppm,rat,4hr Cyclohexanone 000108-94-1 1340 mg/kg,oral,rat 2639 ppm,rat,4hr.

NOTICE: There are no data available for the product itself.

SECTION XII - ECOLOGICAL INFORMATION

NOTICE: There are no data available for the product itself.

SECTION XIII - DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD: Ignitable waste. Dispose of in compliance with local provincial regulations.

SECTION XIV - TRANSPORT INFORMATION

TRANSPORT CANADA DANGEROUS GOODS SHIPPING INFORMATION

PROPER SHIPPING NAME Paint related material UN NUMBER UN 1263 Class 3

Page Number Continued MATERIAL SAFETY DATA SHEET PRC-DeSoto International

Trade Name: 020-044 Thinner Product Identifier FM5908 Preparation Date 05/23/03

Packing Group II

SECTION XV - REGULATORY INFORMATION

CEPA DOMESTIC SUBSTANCE LIST STATUS: All components are listed on the DSL.

WHMIS CLASS(ES): B2, D2B

NOTICE: This MSDS has been prepared in accordance with Canadian Legislation and contains all items required by the Controlled Products Regulations.

SECTION XVI - PREPARATION AND OTHER INFORMATION

Prepared by: Health s Safety Department Preparation Date: 05/23/03 Revision Reason: Update

The information provided herein is, to the best of the manufacturer's knowledge, current, accurate, and complete, based on information reasonably available.

End of Document