Image by Kyle Cunningham SAFETY DATA SHEETS for Forestry-Labeled Herbicides April 2019 How to Use this Reference Manual This reference document provides Material Safety Data Sheets (MSDS) for most herbicide brands labeled for forestry use by the brand’s herbicide chemical(s). If we were to provide the Material Safety Data Sheets (MSDS) for each of the herbicide brands labeled for forestry use, this document would be overly burdensome. For this reason, this reference manual lists one and only one MSDS for each of the herbicide chemicals. The safety requirements will be similar enough for a specific chemical derivative (e.g., acid, amine, ester, choline, etc.). If the safety requirements differ by chemical derivative then additional MSDS sheets are provided for those derivatives. For example the amine derivative of triclopyr has additional safety concerns beyond that of the ester or choline derivative of triclopyr. As such two MSDS are provided. Steps 1. Locate the Brand Name(s) in the table of contents and determine the corresponding herbicide chemical and page number. Example: Polaris AC includes the herbicide imazapyr listed on page 101 2. Turn to the appropriate page and review the basic information about the herbicide chemical including a. target plant groups b. resistant plant groups c. brand characteristics d. special notes e. signal word and f. use statement. 3. Turn to the next page to read a representative MSDS for all brands using that herbicide chemical(s) and derivative. Example: Page 102 provide MSDS for Arsenal AC which representative of Polaris AC and other brands. 4. Read the safety requirements thoroughly and review important first-aid measures. Sources of Information for this handbook include labels, material safety data sheets and publications of herbicide and equipment manufacturers. The information given herein is for education purposes only. Reference to commercial products or trade names or manufacturer’s names in this publication does not constitute an official endorsement or approval by Texas A&M AgriLife Extension Service, Texas A&M Forest Service, University of Arkansas, or the author of any product or service to the exclusion of any others that may also be suitable. Globally Harmonized System (GHS) Hazard Pictograms Explosive Compressed Gas Harmful • Explosive • Gases Under Pressure • Irritant (skin and eye) • Self-reactive • Skin Sensitizer • Organic Peroxides • Acute Toxicity (harmful) • Narcotic effects • Respiratory Tract Irritant • Hazardous to Ozone Flammable Corrosive Health Hazard • Flammables • Skin Corrosion / Burns • Carcinogen • Pyrophoric • Eye Damage • Mutagenicity • Self-heating • Corrosive to Metals • Reproductive Toxicity • Emits Flammable Gas • Respiratory Sensitizer • Self-reactive • Target Organ Toxicity • Organic Peroxides • Aspiration Toxicity Oxidizing Toxic Environmental Hazard • Oxidizers • Acute Toxicity (fatal or toxic • Acute Toxicity (fatal or toxic) Table of Contents Page Brand Name Active Ingredient(s) Number Accord XRT II glyphosate 75 Arrow 2EC clethodim 33 Arsenal AC imazapyr 101 Atrazine 4L atrazine 24 Atrazine 90DF atrazine 24 Boulder 63 triclopyr 219 Brush-Rhap dicamba & 2,4-D 262 Capstone aminopyralid & triclopyr 249 Chopper Gen2 imazapyr 101 Clean Slate clopyralid 40 Cleantraxx oxyflurofen & penoxsulam 300 Clearcast imazamox 113 Clethodim 2E clethodim 33 Clopyralid 3 clopyralid 40 Dakota clethodim 33 Detail saflufenacil 185 Element 3A triclopyr 209 Element 4 triclopyr 219 Envoy Plus clethodim 33 Escort XP metsulfuron methyl 130 Esplanade F indaziflam 118 Foresters glyphosate 75 Formula 40 2,4-D 5 Freelexx 2,4-D 5 Fusilade DX fluazifop-p-butyl 61 Fusilade II fluazifop-p-butyl 61 Garlon 3A triclopyr 209 Garlon 4 Ultra triclopyr 219 Garlon XRT triclopyr 219 Glyphosate 54 glyphosate 75 Goal 2XL oxyfluorfen 141 Graslan L picloram & 2,4-D 314 Imazapyr 2SL imazapyr 101 Imazapyr 4SL imazapyr 101 Intensity 1 clethodim 33 Krenite S fosamine 70 2 Lineage Clearstand imazapyr & metsulfuron methyl 289 Mad Dog 54 glyphosate 75 Mad Dog Plus glyphosate 75 Makaze glyphosate 75 Milestone aminopyralid 13 Milestone VM Plus aminopyralid & triclopyr 249 MSM 60DF metsulfuron methyl 130 Opensight aminopyralid & metsulfuron methyl 236 Oust Extra sulfometuron methyl & metsulfuron methyl 330 Oust XP sulfometuron methyl 199 Oustart hexazinone & sulfometuron methyl 270 Pathfinder II triclopyr 219 Pathway picloram & 2,4-D 314 Patriot metsulfuron methyl 130 Picloram 22K picloram 161 Picloram Plus D picloram & 2,4-D 314 Polaris AC imazapyr 101 Polaris SP imazapyr 101 Prep-It imazapyr & glyphosate 282 Pronone hexazinone 87 Razor glyphosate 75 Razor Pro glyphosate 75 Relegate RTU triclopyr 219 Rodeo glyphosate 75 Rotary 2SL imazapyr 101 Roundup Custom glyphosate 75 Roundup Pro Concentrate glyphosate 75 Roundup ProMax glyphosate 75 Select 2EC, clethodim 33 Select Max clethodim 33 SFM 75 sulfometuron methyl 199 SFM Extra sulfometuron methyl & metsulfuron methyl 330 Spitfire dicamba & 2,4-D 262 Spyder sulfometuron methyl 199 Spyder Extra sulfometuron methyl & metsulfuron methyl 330 Sterling Blue dicamba 54 Stinger clopyralid 40 Tahoe 3A triclopyr 209 Tordon 101 picloram & 2,4-D 314 3 Tordon 22K picloram 161 Transline clopyralid 40 Triclopyr 3 triclopyr 209 Triclopyr 4 triclopyr 219 Triclopyr RTU triclopyr 219 Trooper P+D picloram & 2,4-D 314 Vanquish dicamba 54 Vastlan triclopyr 209 Velossa hexazinone 87 Velpar DF hexazinone 87 Velpar L hexazinone 87 Weberan 720 dicamba & 2,4-D 262 Weedmaster dicamba & 2,4-D 262 Weedone 2,4-D 5 4 2,4-D Target Plants: Many annual and perennial broadleaf weeds, vines, and some woody plants when actively growing. Resistant Plants: Red maple, ash, elm, persimmon, some oaks/hickories, blackberry. No impact to grasses. Can be applied over conifers once hardened off. Brands: 2,4-D Amine, Freelexx, Weedone, Formula 40 Signal Word: DANGER (on at least one product) Use Statement: General Use 5 SAFETY DATA SHEET Formula 40 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Formula 40 EPA Reg. No.: 228-357 Product Type: Herbicide Company Name: Nufarm Americas Inc 11901 S. Austin Avenue Alsip, IL 60803 1-800-345-3330 Telephone Numbers: For Chemical Emergency, Spill, Leak, Fire, Exposure, or Accident, Call CHEMTREC Day or Night: 1-800-424-9300 For Medical Emergencies Only, Call 1-877-325-1840 This product is an EPA FIFRA registered pesticide. Some classifications on this SDS are not the same as the FIFRA label. Certain sections of this SDS are superseded by federal law governed by EPA for a registered pesticide. Please see Section 15. REGULATORY INFORMATION for explanation. 2. HAZARDS IDENTIFICATION PHYSICAL HAZARDS: Flammable Liquid Category 4 HEALTH HAZARDS: Acute Toxicity Oral Category 4 Eye Damage Category 1 Skin Irritation Category 2 Skin Sensitization Category 1 ENVIRONMENTAL HAZARDS: Hazardous to aquatic environment, acute Category 2 Hazardous to aquatic environment, chronic Category 3 SIGNAL WORD: DANGER HAZARD STATEMENTS: Combustible liquid. Harmful if swallowed. Causes serious eye damage. Causes skin irritation. May cause an allergic skin reaction. Toxic to aquatic life. Harmful to aquatic life with long lasting effects. PRECAUTIONARY STATEMENTS Keep away from flames and hot surfaces. No smoking. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Avoid breathing mist, vapors, or spray. Wear protective gloves and eye protection. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell. Rinse mouth. In case of fire: Use dry chemical or carbon dioxide. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER. May 10, 2015 Page 1 of 7 6 SAFETY DATA SHEET Formula 40 IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice. Take off contaminated clothing and wash it before reuse. Collect spillage. Store in a well-ventilated place. Keep cool. Dispose of contents in accordance with local, state, and federal regulations. 3. COMPOSITION / INFORMATION ON INGREDIENTS COMPONENT CAS NO. % BY WEIGHT Dimethylamine Salt of 2,4-Dichlorophenoxyacetic Acid 2008-39-1 21.3 – 22.7 Triisopropanolamine Salt of 2,4-Dichlorophenoxyacetic Acid 32341-80-3 33 – 35 Other Ingredients Trade Secret Trade Secret Synonyms: Mixture containing 2,4-D TIPA and 2,4-D DMA salts; Triisopropanolamine Salt and Dimethylamine Salt of 2,4-Dichlorophenoxyacetic acid Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications. 4. FIRST AID MEASURES If in Eyes: Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Get immediate medical attention. If on Skin or Clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for severalminutes. If irritation or rash occurs, get medical advice. If Swallowed: Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give anything by mouth to an unconscious person. If symptoms develop, get medical advice. If Inhaled: Move person to fresh air. If breathing is difficult, administer oxygen. If symptoms develop, get medical advice.. Most important symptoms/effects, acute and delayed: Causes severe eye irritation with