Naming Chemical Compounds
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Chemistry Lab Hygiene Plan
UNIVERSITY OF MAINE Department of Chemistry CHEMICAL HYGIENE PLAN October, 2001 Contents I. Personal Protective Equipment .. 3 II. Storage of Chemicals .. 6 III. Disposal of Chemicals .. 16 IV. Reading MSDS .. 19 V. Emergencies and the Emergency Action Plan .. 26 VI. Standard Operating Guidelines .. 33 VII. General Housekeeping and Prudent Practices .. 40 2 I. Laboratory Clothing and Personal Protective Equipment A. Dressing for safety in the laboratory Individuals should prepare for a safe laboratory experience by dressing appropriately for laboratory work. Appropriate clothing includes the following: • Shoes should fully cover the feet to protect against spills; no open-toed shoes or sandals are permitted, and shoes with mesh inserts (such as athletic shoes) are not recommended. One may choose to keep a pair of sturdy leather shoes in the laboratory to change into upon arrival. • Trousers or skirts falling below the knee are preferred; if shorter garments are worn, a lab coat or apron of below knee length is required. Preferred materials are resistant polyester, cotton or wool, since ordinary polyester and acrylics may be dissolved by common laboratory solvents. • Neckties, if worn, should be firmly clipped to the shirt or confined inside a lab coat or apron. • Loose, flowing garments and scarves should be avoided; they may easily pick up spills or trail through a burner flame. • In a laboratory where open flames may be used, long hair should be confined. • Loose jewelry should be avoided, since it may catch on equipment. Also avoid ornate rings that can damage protective gloves or make wearing or removing gloves difficult B. Protective Equipment Every laboratory must have available, and workers must be trained in the use of, safety goggles, face masks, lab coats or aprons, gloves, and reaction shields. -
Transport of Dangerous Goods
ST/SG/AC.10/1/Rev.16 (Vol.I) Recommendations on the TRANSPORT OF DANGEROUS GOODS Model Regulations Volume I Sixteenth revised edition UNITED NATIONS New York and Geneva, 2009 NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory, city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries. ST/SG/AC.10/1/Rev.16 (Vol.I) Copyright © United Nations, 2009 All rights reserved. No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the United Nations. UNITED NATIONS Sales No. E.09.VIII.2 ISBN 978-92-1-139136-7 (complete set of two volumes) ISSN 1014-5753 Volumes I and II not to be sold separately FOREWORD The Recommendations on the Transport of Dangerous Goods are addressed to governments and to the international organizations concerned with safety in the transport of dangerous goods. The first version, prepared by the United Nations Economic and Social Council's Committee of Experts on the Transport of Dangerous Goods, was published in 1956 (ST/ECA/43-E/CN.2/170). In response to developments in technology and the changing needs of users, they have been regularly amended and updated at succeeding sessions of the Committee of Experts pursuant to Resolution 645 G (XXIII) of 26 April 1957 of the Economic and Social Council and subsequent resolutions. -
Decontamination of Indoor and Outdoor Materials with Aqueous Chlorine Dioxide Solutions
EPA 600/R-12/516 | May 2012 | www.epa.gov/ord Decontamination of Indoor and Outdoor Materials with Aqueous Chlorine Dioxide Solutions Office of Research and Development National Homeland Security Research Center EPA/600/R/12/516 May 2012 Decontamination of Indoor and Outdoor Materials with Aqueous Chlorine Dioxide Solutions U.S. Environmental Protection Agency Research Triangle Park, NC 27711 ii Disclaimer The U.S. Environmental Protection Agency (EPA), through its Office of Research and Development’s (ORD) National Homeland Security Research Center (NHSRC), funded, directed and managed this work through Contract Number EP-C-10-001 with Battelle. This report has been peer and administratively reviewed and has been approved for publication as an EPA document. Mention of trade names or commercial products does not constitute endorsement or recommendation for use of a specific product. Questions concerning this document or its application should be addressed to: Joseph Wood National Homeland Security Research Center Office of Research and Development U.S. Environmental Protection Agency Mail Code E343-06 Research Triangle Park, NC 27711 919-541-5029 iii Foreword Following the events of September 11, 2001, addressing the critical needs related to homeland security became a clear requirement with respect to EPA’s mission to protect human health and the environment. Presidential Directives further emphasized EPA as the primary federal agency responsible for the country’s water supplies and for decontamination following a chemical, biological, and/or radiological (CBR) attack. To support EPA’s mission to assist in and lead response and recovery activities associated with CBR incidents of national significance, the National Homeland Security Research Center (NHSRC) was established to conduct research and deliver products that improve the capability of the Agency and other federal, state, and local agencies to carry out their homeland security responsibilities. -
United States Patent 19 11 3,904.425 Young Et Al
United States Patent 19 11 3,904.425 Young et al. (45) Sept. 9, 1975 54) ABSORPTIVE GLASS Primary Examiner-Harvey E. Behrend 75 Inventors: Robert W. Young, Woodstock, Attorney, Agent, or Firm-William C. Nealon; H. R. Conn.; Robert E. Graf, Southbridge, Berkenstock, Jr. Mass. W EXEMPLARY CLAIM 73) Assignee: American Optical Corporation, 1. A glass material having a calculated oxide composi Southbridge, Mass. tion comprising 22 Filed: June 12, 1964 21 Appl. No.: 374,811 Percent by Weight Silicon Dioxidc (SiO) 5.9 Sodium Oxide (NaO) 6.5 (52) U.S. Cl...................................... 106/52; 106/50 Potassium Oxide (KO) 6.8 (51 l Int. Cl........................................... CO3C 13/00 Calcium Oxide (CaO) 6.5 58) Field of Search................................. 106/50, 52 Antimony Trioxide (SbO) 0.4 Aluminum Oxide (AO) 4. Zinc Oxide (ZnO) 2.2 56) References Cited Titanium Dioxidc (TiO) 0.4 Manganese Dioxide (MnO) 23.4 UNITED STATES PATENTS Chromium Oxide (CrO) O.S 2,676,09 4/1954 Barnes ct al.......................... 106752 Tct O).() 2,776,900 l/1957 Duncan et al........................ 106/52 2,898,219 8/1959 Duncan ct al........................ 106/52 2,902,377 9, 1959 Duncan............ ... 106/52 a 100 micron thickness of said glass material having 3,146,2O 8/1964 Upton et al.... ... 106/52 an optical density greater than 0.25 at least for light 3,20386 8/1965 Bull et al.............................. 1 O6/52 from 0.4 to 0.6 microns wavelength. FOREIGN PATENTS OR APPLICATIONS 6 4,357 21 1961 Canada................................. 106/52 6 Claims, No Drawings 3,904,425 2 ABSORPTIVE GLASS als should have optical densities at least as high as 0.25 The field of this invention is that of glass composi in sample thickness as small as 100 microns at least for tions and the invention relates more particularly to light of wavelengths between 0.4 and 0.6 microns. -
Notable Reactivity of Acetonitrile Towards Li2o2/Lio2 Probed By
Topics in Catalysis https://doi.org/10.1007/s11244-018-1072-5 ORIGINAL ARTICLE Notable Reactivity of Acetonitrile Towards Li2O2/LiO2 Probed by NAP XPS During Li–O2 Battery Discharge Tatiana K. Zakharchenko1 · Alina I. Belova1 · Alexander S. Frolov1 · Olesya O. Kapitanova1 · Juan‑Jesus Velasco‑Velez2 · Axel Knop‑Gericke2,5 · Denis Vyalikh3,4 · Daniil M. Itkis1 · Lada V. Yashina1 © Springer Science+Business Media, LLC, part of Springer Nature 2018 Abstract One of the key factors responsible for the poor cycleability of Li–O2 batteries is a formation of byproducts from irreversible reactions between electrolyte and discharge product Li 2O2 and/or intermediate LiO2. Among many solvents that are used as electrolyte component for Li–O2 batteries, acetonitrile (MeCN) is believed to be relatively stable towards oxidation. Using near ambient pressure X-ray photoemission spectroscopy (NAP XPS), we characterized the reactivity of MeCN in the Li–O2 battery. For this purpose, we designed the model electrochemical cell assembled with solid electrolyte. We discharged it first in O2 and then exposed to MeCN vapor. Further, the discharge was carried out in O2 + MeCN mixture. We have dem- onstrated that being in contact with Li–O2 discharge products, MeCN oxidizes. This yields species that are weakly bonded to the surface and can be easily desorbed. That’s why they cannot be detected by the conventional XPS. Our results suggest that the respective chemical process most probably does not give rise to electrode passivation but can decrease considerably the Coulombic efficiency of the battery. Keywords Li–O2 battery · In situ NAP XPS · Acetonitrile · Side reactions 1 Introduction Li–O2 batteries promise extraordinary high specific energy that makes them interesting for the next generation power technologies [1, 2]. -
Chemical Chemical Hazard and Compatibility Information
Chemical Chemical Hazard and Compatibility Information Acetic Acid HAZARDS & STORAGE: Corrosive and combustible liquid. Serious health hazard. Reacts with oxidizing and alkali materials. Keep above freezing point (62 degrees F) to avoid rupture of carboys and glass containers.. INCOMPATIBILITIES: 2-amino-ethanol, Acetaldehyde, Acetic anhydride, Acids, Alcohol, Amines, 2-Amino-ethanol, Ammonia, Ammonium nitrate, 5-Azidotetrazole, Bases, Bromine pentafluoride, Caustics (strong), Chlorosulfonic acid, Chromic Acid, Chromium trioxide, Chlorine trifluoride, Ethylene imine, Ethylene glycol, Ethylene diamine, Hydrogen cyanide, Hydrogen peroxide, Hydrogen sulfide, Hydroxyl compounds, Ketones, Nitric Acid, Oleum, Oxidizers (strong), P(OCN)3, Perchloric acid, Permanganates, Peroxides, Phenols, Phosphorus isocyanate, Phosphorus trichloride, Potassium hydroxide, Potassium permanganate, Potassium-tert-butoxide, Sodium hydroxide, Sodium peroxide, Sulfuric acid, n-Xylene. Acetone HAZARDS & STORAGE: Store in a cool, dry, well ventilated place. INCOMPATIBILITIES: Acids, Bromine trifluoride, Bromine, Bromoform, Carbon, Chloroform, Chromium oxide, Chromium trioxide, Chromyl chloride, Dioxygen difluoride, Fluorine oxide, Hydrogen peroxide, 2-Methyl-1,2-butadiene, NaOBr, Nitric acid, Nitrosyl chloride, Nitrosyl perchlorate, Nitryl perchlorate, NOCl, Oxidizing materials, Permonosulfuric acid, Peroxomonosulfuric acid, Potassium-tert-butoxide, Sulfur dichloride, Sulfuric acid, thio-Diglycol, Thiotrithiazyl perchlorate, Trichloromelamine, 2,4,6-Trichloro-1,3,5-triazine -
TPN Electrolytes (Multiple Electrolyte Additive)
SAFETY DATA SHEET Product Name: TPN Electrolytes (Multiple Electrolyte Additive) 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer Name And Hospira, Inc. Address 275 North Field Drive Lake Forest, Illinois 60045 USA Emergency Telephone CHEMTREC: North America: 800-424-9300; International 1-703-527-3887; Australia - 61-290372994; UK - 44-870-8200418 Hospira, Inc., Non-Emergency 224 212-2000 Product Name TPN Electrolytes (Multiple Electrolyte Additive) Synonyms NA 2. HAZARD(S) IDENTIFICATION Emergency Overview TPN Electrolytes (Multiple Electrolyte Additive) is a concentrated solution of intra- and extracellular ions for intravenous infusion after dilution. In clinical use, this product is used to maintain normal cellular metabolism by supplying sodium, calcium, potassium, magnesium, chloride and acetate to the body during total parenteral nutrition (TPN). In the workplace, this material should be considered potentially irritating to the eyes and respiratory tract. Based on clinical use, possible target organs include the nervous system, the cardiovascular system, and muscles. U.S. OSHA GHS Classification Physical Hazards Hazard Class Hazard Category Not Classified Not Classified Health Hazards Hazard Class Hazard Category Eye Damage / Irritation 2B Label Element(s) Pictogram NA Signal Word Warning Hazard Statement(s) Causes eye irritation Precautionary Statement(s) Prevention Do not breathe vapor or spray Wash hands thoroughly after handling Response Get medical attention if you feel unwell. IF IN EYES: Rinse cautiously with -
BALANCE I: IONIZE (Dissociate) D: DELETE SPECTATOR IONS D: DECOMPOSE Y: YES – YOU DID IT!!
PREDICTING REACTIONS Chapter One | 1 Chapter 1 AP PREDICTING REACTIONS1 NOTE: we will cover this chapter throughout the year. A. Points 15 % of Free Response or 7.5% of final grade Each rxn worth 5 pts for a total of 15 pts possible. Three points for the unbalanced net ionic equation (total nine points). 1 pt reactants, 2 pts products One point for the balanced equation (I am assuming that if the net ionic is wrong, but the equation is balanced correctly, i.e. “internally consistence” then the students will get this point). One point for answering a question about the reaction. Possibilities include: indications of chemical reaction oxidizing agent oxidation number color of solid product general chemistry interest simple stoichiometry Points are deducted for including incorrect species, omitting species or including spectator ions. You don’t need to include states, but I like to include (s) and (g) so I won’t be tempted to dissociate incorrectly! B. Instructions For each of the following three reactions, in part (i) write a BALANCED equation and in part (ii) answer the question about the reaction. In part (i), coefficients should be in the lowest whole numbers. In all cases, a reaction occurs. Assume that solutions are aqueous unless otherwise indicated. Represent substances in solution as ions if the substances are extensively ionized. Omit formulas for any ions or molecules that are unchanged by the reaction. Example: (i) A strip of magnesium is added to a solution of silver nitrate. (ii) Which substance is the oxidizing agent? + 2+ (i) Mg + 2 Ag Mg + 2 Ag (ii) The Ag+ is the oxidizing agent. -
Chemical Formula of Binary Ionic Compounds – Sheet 1 the Combining Power Or Valency of Silver Is Always 1
Chemical Formula of Binary Ionic Compounds – Sheet 1 The combining power or valency of silver is always 1. All other transition metals are 2 unless otherwise indicated. No. Binary compound Formula No. Binary compound Formula 1 potassium fluoride 26 calcium sulfide 2 calcium chloride 27 lithium bromide 3 barium bromide 28 nickel sulfide 4 silver sulfide 29 zinc phosphide 5 aluminium iodide 30 barium iodide 6 potassium iodide 31 caesium chloride 7 lead(IV) oxide 32 copper bromide 8 zinc nitride 33 sodium nitride 9 silver iodide 34 silver chloride 10 barium fluoride 35 sodium hydride 11 lead(II) iodide 36 potassium nitride 12 silver fluoride 37 cobalt chloride 13 sodium sulfide 38 magnesium sulfide 14 sodium bromide 39 potassium chloride 15 calcium oxide 40 calcium bromide 16 zinc fluoride 41 iron(III) oxide 17 strontium phosphide 42 aluminium fluoride 18 barium sulfide 43 magnesium bromide 19 aluminium oxide 44 iron(III) chloride 20 aluminium chloride 45 barium nitride 21 aluminium sulfide 46 sodium fluoride 22 lead(II) oxide 47 lithium fluoride 23 barium chloride 48 lithium iodide 24 copper chloride 49 lithium hydride 25 barium phosphide 50 potassium oxide “Aluminum” and “cesium” are commonly used alternative spellings for "aluminium" and "caesium that are used in the US. May be freely copied for educational use. ©www.chemicalformula.org Chemical Formula of Binary Ionic Compounds – Sheet 2 The combining power or valency of silver is always 1. All other transition metals are 2 unless otherwise indicated. No. Binary compound Formula No. -
UNITED STATES PATENT OFFICE 2,278,867 LEAD-FREE GLAZE of LOW MATURNG TEMPERATURE for USE in DECORATING CERAMCWARE Alden J
Patented Apr. 7, 1942 2,278,867 UNITED STATES PATENT OFFICE 2,278,867 LEAD-FREE GLAZE OF LOW MATURNG TEMPERATURE FOR USE IN DECORATING CERAMCWARE Alden J. Deyrup, Elizabeth, N.J., assignor to E. ... " du Pont de Nemours & Company, Wilmington, Del, a corporation of Delaware No Drawing. Application May 1, 1940, Seria No. 332,732 9 Claims. (C. 106-48) This invention relates to certain improved lead temperature of glaze firing, being utilized. The free glazes or fluxes of the type suitable for use temperature employed in the overglazing fire to in art-glazing or Overglazing ceramic ware. More mature the overglaze is usually 700 to 800' C., particularly, this invention relates to certain new which is of course considérably.lower than the and improved flux compositions free from leadi 5 temperature range in which the glazes used to Oxide which, when used for the artglazing or coat the bisque are fired. At this overglaze fir Overglazing of chinaware and pottery, are capa ing temperature the colored decorative coating ble of melting at fairly low maturing tempera matures and vitrifles, and the ware is thus coat tures to a superior decorative coating of high ed with a colored decorative surface having a resistance to both the action of chemical agents 10 high degree of glossiness. such as acids and alkalies, and to mechanical Bisque ware is sometimes decorated by plac abrasion. ing on the surface of the ware, without prelimi In the manufacture of china and pottery a narily coating the surface of the bisque with a clay mixture is customarily formed into the de vitrified glaze, a mixture of pigment and low sired shape and then fired at a high tempera 15 melting flux which can be matured to a good ture, one within the range 1250 to 1400° C. -
REACH - Registration, Evaluation, Authorisation and Restriction of Chemical Substances
REACH - Registration, Evaluation, Authorisation and Restriction of Chemical Substances TERRITORY European Union RESTRICTION SUBJECT Human Health and Environment Protection against adverse effects of chemical substances The European Commission elaborated a Directive (EC 1907/2006) known as REACH with the aim to ensure Human Health and Environment Protection against adverse effects of chemical substances. The Directive imposes - to all companies conducting business with chemical substances - to adopt compulsorily “a special chemical substances work regime”. (REACH is valid from 1st of July 2007.) Producers, importers and follow-up users of chemical substances and/or substances contained in preparations and in items must, in compliance with the Directive, ask for their registration at the European Chemical Agency as of 1st of June 2008. The obligation to register in relation with chemical composition is mainly related to chemical substances and preparations made of them, but not according to the article 7, the paragraph 1 of the REACH Directive to final products, i.e. items which can be considered – under standard or reasonable foreseeable conditions of use – as completely safe. Preciosa does not supply either chemical substances or chemical preparations or mixtures on the market. The products that we supply are final products that meet the above mentioned requirements. This means that they are not subject to the REACH registration. Preciosa guarantees to the customer that all products of Preciosa are in conformity with requirements specified in COMMISSION REGULATION (EU) No 217/2016 of 16 February 2016 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) as regards Annex XVII. -
Safety Data Sheet
SAFETY DATA SHEET Creation Date 24-Nov-2010 Revision Date 17-Jun-2021 Revision Number 4 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product Description: Potassium tetraborate tetrahydrate Cat No. : 39435 Synonyms Potassium biborate tetrahydrate CAS-No 12045-78-2 Molecular Formula B4 K2 O7 . 4 H2 O Reach Registration Number - 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended Use Laboratory chemicals. Uses advised against No Information available 1.3. Details of the supplier of the safety data sheet Company Alfa Aesar . Avocado Research Chemicals, Ltd. Shore Road Port of Heysham Industrial Park Heysham, Lancashire LA3 2XY United Kingdom Office Tel: +44 (0) 1524 850506 Office Fax: +44 (0) 1524 850608 E-mail address [email protected] www.alfa.com Product Safety Department 1.4. Emergency telephone number Call Carechem 24 at +44 (0) 1865 407333 (English only); +44 (0) 1235 239670 (Multi-language) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture CLP Classification - Regulation (EC) No 1272/2008 Physical hazards Based on available data, the classification criteria are not met Health hazards ______________________________________________________________________________________________ ALFAA39435 Page 1 / 10 SAFETY DATA SHEET Potassium tetraborate tetrahydrate Revision Date 17-Jun-2021 ______________________________________________________________________________________________ Reproductive Toxicity Category 2 (H361d) Environmental hazards Based on available data, the classification criteria are not met Full text of Hazard Statements: see section 16 2.2. Label elements Signal Word Warning Hazard Statements H361d - Suspected of damaging the unborn child Precautionary Statements P201 - Obtain special instructions before use P280 - Wear protective gloves/protective clothing/eye protection/face protection P308 + P313 - IF exposed or concerned: Get medical advice/attention Additional EU labelling Restricted to professional users 2.3.