Chemical Formula of Binary Ionic Compounds – Sheet 1 the Combining Power Or Valency of Silver Is Always 1
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Recycling of Hazardous Waste from Tertiary Aluminium Industry in A
CORE Metadata, citation and similar papers at core.ac.uk Provided by Digital.CSIC 1 Recycling of hazardous waste from tertiary aluminium 2 industry in a value-added material 3 4 Laura Gonzalo-Delgado1, Aurora López-Delgado1*, Félix Antonio López1, Francisco 5 José Alguacil1 and Sol López-Andrés2 6 7 1Nacional Centre for Metallurgical Research, CSIC. Avda. Gregorio del Amo, 8. 28040. 8 Madrid. Spain. 9 2Dpt. Crystallography and Mineralogy. Fac. of Geology. University Complutense of 10 Madrid. Spain. 11 *Corresponding author e-mail: [email protected] 12 13 Abstract 14 15 The recent European Directive on waste, 2008/98/EC seeks to reduce the 16 exploitation of natural resources through the use of secondary resource management. 17 Thus the main objective of this paper is to explore how a waste could cease to be 18 considered as waste and could be utilized for a specific purpose. In this way, a 19 hazardous waste from the tertiary aluminium industry was studied for its use as a raw 20 material in the synthesis of an added value product, boehmite. This waste is classified as 21 a hazardous residue, principally because in the presence of water or humidity, it releases 22 toxic gases such as hydrogen, ammonia, methane and hydrogen sulphide. The low 23 temperature hydrothermal method developed permits the recovery of 90% of the 24 aluminium content in the residue in the form of a high purity (96%) AlOOH (boehmite). 25 The method of synthesis consists of an initial HCl digestion followed by a gel 26 precipitation. In the first stage a 10% HCl solution is used to yield a 12.63 g.l-1 Al3+ 27 solution. -
Transport of Dangerous Goods
ST/SG/AC.10/1/Rev.16 (Vol.I) Recommendations on the TRANSPORT OF DANGEROUS GOODS Model Regulations Volume I Sixteenth revised edition UNITED NATIONS New York and Geneva, 2009 NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory, city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries. ST/SG/AC.10/1/Rev.16 (Vol.I) Copyright © United Nations, 2009 All rights reserved. No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the United Nations. UNITED NATIONS Sales No. E.09.VIII.2 ISBN 978-92-1-139136-7 (complete set of two volumes) ISSN 1014-5753 Volumes I and II not to be sold separately FOREWORD The Recommendations on the Transport of Dangerous Goods are addressed to governments and to the international organizations concerned with safety in the transport of dangerous goods. The first version, prepared by the United Nations Economic and Social Council's Committee of Experts on the Transport of Dangerous Goods, was published in 1956 (ST/ECA/43-E/CN.2/170). In response to developments in technology and the changing needs of users, they have been regularly amended and updated at succeeding sessions of the Committee of Experts pursuant to Resolution 645 G (XXIII) of 26 April 1957 of the Economic and Social Council and subsequent resolutions. -
Decontamination of Indoor and Outdoor Materials with Aqueous Chlorine Dioxide Solutions
EPA 600/R-12/516 | May 2012 | www.epa.gov/ord Decontamination of Indoor and Outdoor Materials with Aqueous Chlorine Dioxide Solutions Office of Research and Development National Homeland Security Research Center EPA/600/R/12/516 May 2012 Decontamination of Indoor and Outdoor Materials with Aqueous Chlorine Dioxide Solutions U.S. Environmental Protection Agency Research Triangle Park, NC 27711 ii Disclaimer The U.S. Environmental Protection Agency (EPA), through its Office of Research and Development’s (ORD) National Homeland Security Research Center (NHSRC), funded, directed and managed this work through Contract Number EP-C-10-001 with Battelle. This report has been peer and administratively reviewed and has been approved for publication as an EPA document. Mention of trade names or commercial products does not constitute endorsement or recommendation for use of a specific product. Questions concerning this document or its application should be addressed to: Joseph Wood National Homeland Security Research Center Office of Research and Development U.S. Environmental Protection Agency Mail Code E343-06 Research Triangle Park, NC 27711 919-541-5029 iii Foreword Following the events of September 11, 2001, addressing the critical needs related to homeland security became a clear requirement with respect to EPA’s mission to protect human health and the environment. Presidential Directives further emphasized EPA as the primary federal agency responsible for the country’s water supplies and for decontamination following a chemical, biological, and/or radiological (CBR) attack. To support EPA’s mission to assist in and lead response and recovery activities associated with CBR incidents of national significance, the National Homeland Security Research Center (NHSRC) was established to conduct research and deliver products that improve the capability of the Agency and other federal, state, and local agencies to carry out their homeland security responsibilities. -
United States Patent 19 11 3,904.425 Young Et Al
United States Patent 19 11 3,904.425 Young et al. (45) Sept. 9, 1975 54) ABSORPTIVE GLASS Primary Examiner-Harvey E. Behrend 75 Inventors: Robert W. Young, Woodstock, Attorney, Agent, or Firm-William C. Nealon; H. R. Conn.; Robert E. Graf, Southbridge, Berkenstock, Jr. Mass. W EXEMPLARY CLAIM 73) Assignee: American Optical Corporation, 1. A glass material having a calculated oxide composi Southbridge, Mass. tion comprising 22 Filed: June 12, 1964 21 Appl. No.: 374,811 Percent by Weight Silicon Dioxidc (SiO) 5.9 Sodium Oxide (NaO) 6.5 (52) U.S. Cl...................................... 106/52; 106/50 Potassium Oxide (KO) 6.8 (51 l Int. Cl........................................... CO3C 13/00 Calcium Oxide (CaO) 6.5 58) Field of Search................................. 106/50, 52 Antimony Trioxide (SbO) 0.4 Aluminum Oxide (AO) 4. Zinc Oxide (ZnO) 2.2 56) References Cited Titanium Dioxidc (TiO) 0.4 Manganese Dioxide (MnO) 23.4 UNITED STATES PATENTS Chromium Oxide (CrO) O.S 2,676,09 4/1954 Barnes ct al.......................... 106752 Tct O).() 2,776,900 l/1957 Duncan et al........................ 106/52 2,898,219 8/1959 Duncan ct al........................ 106/52 2,902,377 9, 1959 Duncan............ ... 106/52 a 100 micron thickness of said glass material having 3,146,2O 8/1964 Upton et al.... ... 106/52 an optical density greater than 0.25 at least for light 3,20386 8/1965 Bull et al.............................. 1 O6/52 from 0.4 to 0.6 microns wavelength. FOREIGN PATENTS OR APPLICATIONS 6 4,357 21 1961 Canada................................. 106/52 6 Claims, No Drawings 3,904,425 2 ABSORPTIVE GLASS als should have optical densities at least as high as 0.25 The field of this invention is that of glass composi in sample thickness as small as 100 microns at least for tions and the invention relates more particularly to light of wavelengths between 0.4 and 0.6 microns. -
Low-Temperature Specific Heat in Caesium Borate Glasses Cristina Crupi, Giovanna D’Angelo, Gaspare Tripodo, Giuseppe Carini, A
Low-temperature specific heat in caesium borate glasses Cristina Crupi, Giovanna d’Angelo, Gaspare Tripodo, Giuseppe Carini, A. Bartolotta To cite this version: Cristina Crupi, Giovanna d’Angelo, Gaspare Tripodo, Giuseppe Carini, A. Bartolotta. Low- temperature specific heat in caesium borate glasses. Philosophical Magazine, Taylor & Francis, 2007, 87 (3-5), pp.741-747. 10.1080/14786430600910764. hal-00513746 HAL Id: hal-00513746 https://hal.archives-ouvertes.fr/hal-00513746 Submitted on 1 Sep 2010 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Philosophical Magazine & Philosophical Magazine Letters For Peer Review Only Low-temperature specific heat in caesium borate glasses Journal: Philosophical Magazine & Philosophical Magazine Letters Manuscript ID: TPHM-06-May-0176.R1 Journal Selection: Philosophical Magazine Date Submitted by the 27-Jun-2006 Author: Complete List of Authors: Crupi, Cristina; Messina University, Physics D'Angelo, Giovanna; university of messina, physics Tripodo, Gaspare; Messina University, Physics carini, giuseppe; University of Messina, Dept of Physics Bartolotta, A.; Istituto per i Processi Chimico-Fisici, CNR amorphous solids, boson peak, calorimetry, disordered systems, Keywords: glass, specific heat, thermal properties Keywords (user supplied): http://mc.manuscriptcentral.com/pm-pml Page 1 of 13 Philosophical Magazine & Philosophical Magazine Letters 1 2 3 LOW TEMPERATURE SPECIFIC HEAT IN CAESIUM BORATE GLASSES 4 5 6 7 8 + 9 Cristina Crupi, Giovanna D’Angelo, Gaspare Tripodo, Giuseppe Carini and Antonio Bartolotta . -
SAFETY DATA SHEET Revision Date 28.07.2021 According to Regulation (EC) No
Version 7.0 SAFETY DATA SHEET Revision Date 28.07.2021 according to Regulation (EC) No. 1907/2006 Print Date 02.10.2021 GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifiers Product name : Aluminum iodide Product Number : 208493 Brand : Aldrich REACH No. : A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline. CAS-No. : 7784-23-8 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances 1.3 Details of the supplier of the safety data sheet Company : Sigma-Aldrich Inc. 3050 SPRUCE ST ST. LOUIS MO 63103 UNITED STATES Telephone : +1 314 771-5765 Fax : +1 800 325-5052 1.4 Emergency telephone Emergency Phone # : 800-424-9300 CHEMTREC (USA) +1-703- 527-3887 CHEMTREC (International) 24 Hours/day; 7 Days/week SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Skin corrosion (Sub-category 1B), H314 Serious eye damage (Category 1), H318 For the full text of the H-Statements mentioned in this Section, see Section 16. 2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Aldrich- 208493 Page 1 of 8 The life science business of Merck operates as MilliporeSigma in the US and Canada Pictogram Signal word Danger Hazard statement(s) H314 Causes severe skin burns and eye damage. -
Influence of Composition on Structure and Caesium Volatilisation from Glasses for HLW Confinement
Influence of Composition on Structure and Caesium Volatilisation from Glasses for HLW Confinement Benjamin Graves Parkinson B.Sc. (Hons.), M.Sc. A thesis submitted to the University of Warwick in partial fulfilment of the requirement for the degree of Doctor of philosophy Department of Physics November 2007 Contents Contents (i) List of Figures (vi) List of Tables (xv) List of Abbreviations (xvii) Acknowledgements (xviii) Declaration (xix) Abstract (xx) Chapter 1...................................................................................................................1 1 Introduction....................................................................................................1 1.1 Overview................................................................................................1 1.2 Aim of the work .....................................................................................1 1.3 References..............................................................................................5 Chapter 2...................................................................................................................7 2 Immobilisation of High Level Nuclear Waste.................................................7 2.1 Introduction............................................................................................7 2.2 High-Level Nuclear Waste......................................................................7 2.3 HLW Immobilisation..............................................................................8 2.3.1 -
WO 2015/025175 Al 26 February 2015 (26.02.2015) P O P C T
(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2015/025175 Al 26 February 2015 (26.02.2015) P O P C T (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every C09K 5/06 (2006.01) kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, (21) International Application Number: BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, PCT/GB2014/052580 DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, (22) International Filing Date: HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, 22 August 2014 (22.08.2014) KZ, LA, LC, LK, LR, LS, LT, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, (25) Filing Language: English OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, (26) Publication Language: English SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, (30) Priority Data: ZW. 13 15098.2 23 August 2013 (23.08.2013) GB (84) Designated States (unless otherwise indicated, for every (71) Applicant: SUNAMP LIMITED [GB/GB]; Unit 1, Satel kind of regional protection available): ARIPO (BW, GH, lite Place, Macmerry, Edinburgh EH33 1RY (GB). GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, (72) Inventors: BISSELL, Andrew John; C/o SunAmp, Unit TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, 1, Satellite Place, Macmerry, Edinburgh EH33 1RY (GB). -
Introduetion
THE CONCENTFL4TION OF RADIUM AND MESO- THORIUM BY FRACTIONAL CRYSTALLIZATION* BY JOHN I,. NIERMAN Introduetion MarkwaldlO and Soddyl' have shown independently that mesothorium is absolutely identical in chemical nature with radium and cannot be separated therefrom.** In consequence all radium separated from uranium minerals containing thorium, contains also the mesothorium in the mineral, and all preparations of mesothorium contain the radium that is present in the mineral from which the thorium is derived. In the extraction and recovery of the minute quantities of mesothorium and radium present in radioactive minerals, these elements become associated with barium and follow the barium throughout the process. The refining of mesothorium and radium then consists in separating these elements from barium, the method generally followed being fractional crystallization of the barium solution, first as chloride, and later as bromide. The mesothorium and radium continue to be enriched in the crystal fractions, and reduced in the succes- sive mother liquors. t In practice, l2 a fair concentration of acid is maintained throughout the chloride and bromide systems, for the reason ' that the factor of enrichment of mesothorium radium chloride from barium chloride and also of mesothorium radium bromide from barium bromide is regarded as more favorable in acid than in neutral solutions. While it has been shown3 that the crystallization factor is higher for bromides than for chlorides, the effect of the acidity of the solutions on the progress of * Abstract of a thesis submitted in partial fulfilment of the requirements for the degree of Master of Arts in the Graduate, School of the University of Missouri, August, 1919. -
Chemistry Workbook
Bridging the gap 2020 Ripon Grammar School 1 2 Introduction Advanced level Chemistry is a demanding and exciting course. In order to be prepared for your start in September a number of areas from GCSE chemistry are needed to be ‘known’ thoroughly. To help you make the transition as smoothly as possible we have put together this series of exercises. When you start in September you will be expected to have completed the exercises within this booklet and know the material within. It is by no means ALL you need to know but the very foundations of the exciting journey you are about to start. If you have difficulties or confusions there are a number of suggested online resources you could try. There will be opportunities to discuss concerns with staff at the beginning of the year but you should have made significant headway independently. This booklet contains some notes to act as a reminder. If you struggle with a particular area you should investigate the suggested support resources including your GCSE notes. There are exercises for you to complete, the answers are at the end. Contents Periodic Table 2 Topics Writing formulae 4 Equations 7 Moles 10 Atomic Structure 15 Identifying Bonding and Structure types 19 Answers to exercises 20 3 Writing formulae Objectives: • Know the common ions • Be able to construct formulae for common ionic substances • Know the formulae of some common covalent substances Common Ions (you need to know these): Putting together an ionic formula: The charges must balance. Molecular ions will need to be contained in brackets. -
Effects of Intravenous Injections of Radium Bromide. by R
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by PubMed Central EFFECTS OF INTRAVENOUS INJECTIONS OF RADIUM BROMIDE. BY R. BURTON-OPITZ AND GUSTAVE M. MEYER. (From the Laboratories of Physiology and Physiological Chemistry of Colum- bia University, at the College of Physicians and Surgeons, New York.) PLATE XVI. The present study was undertaken with a view of determining in a general way the effects of intravenous administration of ra- dium upon the circulation and respiration. The problem was sug- gested to us by Dr. William J. Gies, under whose guidance a number of researches, dealing with the more extensive question of the action of radium upon animal and vegetable cells, have re- cently been carried on in the laboratories of Columbia University.1 For the radium used in these experiments we are greatly in- debted to Mr. Hugo Lieber. It was supplied to us in the form of the bromide, in preparations of 240 , iooo, and io,ooo activities. The strength of the solution used was the same in all cases. It contained 45 rag. of the dry substance in 25 c. c. of the solvent; each cubic centimeter of the solution, therefore, contained 1.8 rag. of the radium preparation. The amount of the radium present varies directly with the ra- dio-activity. Preparations of ~,5oo,ooo activity are said to repre- sent pure radium bromide3 Taking this figure as the standard of purity, ~ .8 rag. of the radium preparation of io,ooo activity contained approximately only o.o~ 26 mg., the same quantity of the preparation of ~ooo activity contained o.ooi26 rag. -
Alphabetical Index of Substances and Articles
ALPHABETICAL INDEX OF SUBSTANCES AND ARTICLES - 355 - NOTES TO THE INDEX 1. This index is an alphabetical list of the substances and articles which are listed in numerical order in the Dangerous Goods List in Chapter 3.2. 2. For the purpose of determining the alphabetical order the following information has been ignored even when it forms part of the proper shipping name: numbers; Greek letters; the abbreviations “sec” and “tert”; and the letters “N” (nitrogen), “n” (normal), “o” (ortho) “m” (meta), “p” (para) and “N.O.S.” (not otherwise specified). 3. The name of a substance or article in block capital letters indicates a proper shipping name. 4. The name of a substance or article in block capital letters followed by the word “see” indicates an alternative proper shipping name or part of a proper shipping name (except for PCBs). 5. An entry in lower case letters followed by the word “see” indicates that the entry is not a proper shipping name; it is a synonym. 6. Where an entry is partly in block capital letters and partly in lower case letters, the latter part is considered not to be part of the proper shipping name. 7. A proper shipping name may be used in the singular or plural, as appropriate, for the purposes of documentation and package marking. - 356 - INDEX Name and description Class UN No. Name and description Class UN No. Accumulators, electric, see 4.3 3292 Acid mixture, nitrating acid, see 8 1796 8 2794 8 2795 Acid mixture, spent, nitrating acid, see 8 1826 8 2800 8 3028 Acraldehyde, inhibited, see 6.1 1092 ACETAL 3 1088