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An Application of Near-Infrared and Mid-Infrared Spectroscopy to the Study of 3 Selected Tellurite Minerals: Xocomecatlite, Tlapallite and Rodalquilarite 4 5 Ray L
QUT Digital Repository: http://eprints.qut.edu.au/ Frost, Ray L. and Keeffe, Eloise C. and Reddy, B. Jagannadha (2009) An application of near-infrared and mid- infrared spectroscopy to the study of selected tellurite minerals: xocomecatlite, tlapallite and rodalquilarite. Transition Metal Chemistry, 34(1). pp. 23-32. © Copyright 2009 Springer 1 2 An application of near-infrared and mid-infrared spectroscopy to the study of 3 selected tellurite minerals: xocomecatlite, tlapallite and rodalquilarite 4 5 Ray L. Frost, • B. Jagannadha Reddy, Eloise C. Keeffe 6 7 Inorganic Materials Research Program, School of Physical and Chemical Sciences, 8 Queensland University of Technology, GPO Box 2434, Brisbane Queensland 4001, 9 Australia. 10 11 Abstract 12 Near-infrared and mid-infrared spectra of three tellurite minerals have been 13 investigated. The structure and spectral properties of two copper bearing 14 xocomecatlite and tlapallite are compared with an iron bearing rodalquilarite mineral. 15 Two prominent bands observed at 9855 and 9015 cm-1 are 16 2 2 2 2 2+ 17 assigned to B1g → B2g and B1g → A1g transitions of Cu ion in xocomecatlite. 18 19 The cause of spectral distortion is the result of many cations of Ca, Pb, Cu and Zn the 20 in tlapallite mineral structure. Rodalquilarite is characterised by ferric ion absorption 21 in the range 12300-8800 cm-1. 22 Three water vibrational overtones are observed in xocomecatlite at 7140, 7075 23 and 6935 cm-1 where as in tlapallite bands are shifted to low wavenumbers at 7135, 24 7080 and 6830 cm-1. The complexity of rodalquilarite spectrum increases with more 25 number of overlapping bands in the near-infrared. -
Washington State Minerals Checklist
Division of Geology and Earth Resources MS 47007; Olympia, WA 98504-7007 Washington State 360-902-1450; 360-902-1785 fax E-mail: [email protected] Website: http://www.dnr.wa.gov/geology Minerals Checklist Note: Mineral names in parentheses are the preferred species names. Compiled by Raymond Lasmanis o Acanthite o Arsenopalladinite o Bustamite o Clinohumite o Enstatite o Harmotome o Actinolite o Arsenopyrite o Bytownite o Clinoptilolite o Epidesmine (Stilbite) o Hastingsite o Adularia o Arsenosulvanite (Plagioclase) o Clinozoisite o Epidote o Hausmannite (Orthoclase) o Arsenpolybasite o Cairngorm (Quartz) o Cobaltite o Epistilbite o Hedenbergite o Aegirine o Astrophyllite o Calamine o Cochromite o Epsomite o Hedleyite o Aenigmatite o Atacamite (Hemimorphite) o Coffinite o Erionite o Hematite o Aeschynite o Atokite o Calaverite o Columbite o Erythrite o Hemimorphite o Agardite-Y o Augite o Calciohilairite (Ferrocolumbite) o Euchroite o Hercynite o Agate (Quartz) o Aurostibite o Calcite, see also o Conichalcite o Euxenite o Hessite o Aguilarite o Austinite Manganocalcite o Connellite o Euxenite-Y o Heulandite o Aktashite o Onyx o Copiapite o o Autunite o Fairchildite Hexahydrite o Alabandite o Caledonite o Copper o o Awaruite o Famatinite Hibschite o Albite o Cancrinite o Copper-zinc o o Axinite group o Fayalite Hillebrandite o Algodonite o Carnelian (Quartz) o Coquandite o o Azurite o Feldspar group Hisingerite o Allanite o Cassiterite o Cordierite o o Barite o Ferberite Hongshiite o Allanite-Ce o Catapleiite o Corrensite o o Bastnäsite -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
Sonoraite Fe3+Te4+O3(OH)•
3+ 4+ Sonoraite Fe Te O3(OH) • H2O c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Bladelike crystals, to 2 mm, flattened on {100}, in subparallel sheaves and rosettes. Physical Properties: Hardness = ∼3 D(meas.) = 3.95(1) D(calc.) = 4.18 Optical Properties: Transparent. Color: Dark yellowish green. Luster: Vitreous. Optical Class: Biaxial (–). α = 2.018(3) β = 2.023(3) γ = 2.025(3) 2V(meas.) = 20◦–25◦ Cell Data: Space Group: P 21/c. a = 10.984(2) b = 10.268(1) c = 7.917(2) β = 108.49(2)◦ Z=8 X-ray Powder Pattern: Moctezuma mine, Mexico. 10.4 (10), 4.66 (8), 3.110 (8), 3.290 (7), 3.66 (6), 5.18 (5), 3.035 (5) Chemistry: (1) (2) TeO2 52.5 59.90 Fe2O3 27.9 29.96 H2O 18.2 10.14 Total 98.6 100.00 • (1) Moctezuma mine, Mexico; H2O taken as loss on ignition. (2) FeTeO3(OH) H2O. Occurrence: A very rare mineral in the oxide zone of a hydrothermal Au–Te ore deposit (Moctezuma mine, Mexico). Association: Emmonsite, anglesite, “limonite”, quartz (Moctezuma mine, Mexico); emmonsite (Mohawk mine, Nevada, USA); rodalquilarite, emmonsite, jarosite, limonite (Tombstone, Arizona, USA). Distribution: From the Moctezuma (Bambolla) mine, 12 km south of Moctezuma, Sonora, Mexico. In the USA, in the Mohawk mine, Goldfield, Esmeralda Co., Nevada; from the Joe shaft, near Tombstone, Cochise Co., Arizona; in the Wilcox district, Catron Co., New Mexico; in Colorado, at the Good Hope mine, Vulcan district, Gunnison Co., and the Hoosier mine, Cripple Creek district, Teller Co. -
An Overview of Minerals Toxicity, by RDG, 2014-2020
AN OVERVIEW OF MINERALS TOXICITY Written by RDG, 2014 Copyright © 2014 - 2020, RDG. All rights reserved. First published electronically November 2014. Last updated December 19, 2020. Disclaimer: This article is not intended as an authoritative text. The author cannot be held responsible for your safety. TABLE OF CONTENTS 1.INTRODUCTION …................................................................................................................. 3 1.1.Why discuss the toxicity of minerals …....................................................................................3 1.2.A few basic notions of toxicology …........................................................................................ 3 1.2.1.Dose …...................................................................................................................................3 1.2.2.Bioavailability …................................................................................................................... 3 1.2.3.Toxicity class, Acute toxicity, and Median lethal dose …......................................................3 1.2.4.Chronic toxicity …................................................................................................................. 4 1.2.5.Carcinogenic, Mutagenic, Reprotoxic …...............................................................................4 1.3.Risk assessment ….................................................................................................................... 4 2.TOXICITY OF MINERALS …............................................................................................... -
New Mineral Names*
AmericanMineralogM, Volume66, pages 1099-l103,IgEI NEW MINERAL NAMES* LouIs J. Cetnt, MrcHeer FtnrscHnn AND ADoLF Pnssr Aldermanlter Choloallte. I. R. Harrowficl4 E. R. Segnitand J. A. Watts (1981)Alderman- S. A. Williams (1981)Choloalite, CuPb(TeO3)z .HrO, a ncw min- ite, a ncw magnesiumalrrminum phosphate.Mineral. Mag.44, eral. Miaeral. Mag. 44, 55-51. 59-62. Choloalite was probably first found in Arabia, then at the Mina Aldermanite o@urs as minute, very thin" talc-likc crystallitcs La Oriental, Moctczuma, Sonora (the typc locality), and finally at with iuellite and other secondaryphosphates in the Moculta rock Tombstone, Arizona. Only thc Tombstone material provides para- phosphatc deposit near thc basc of Lower Cambrisn limestone genetic information. In this material choloalite occurs with cerus- close to Angaston, ca. 60 km NE of Adelaide. Microprobc analy- site, emmonsite and rodalquilarite in severcly brecciated shale that si.q supplcmented by gravimetric water determination gave MgO has been replaced by opal and granular jarosite. Wet chcmical E.4,CaO 1.2, AJ2O328.4, P2O5 25.9, H2O 36.1%,(totat 100),lead- analysisofcholoalitc from the type locality gave CuO 11.0,PbO ing to the formula Mg5Als2(POa)s(OH)zz.zH2O,where n = 32. 33.0,TeO2 50.7, H2O 3.4,total 98.1%,correspolding closcly to thc Thc powder diffraction pattern, taken with a Guinier camera, can formula in the titlc. Powder pattems of thc mineral from thc three be indexed on an orthorhombic. ccll with a = 15.000(7), D = localities can bc indexcd on the basis of a cubic ccll with a : 8.330(6),c - 26.60(l)A, Z = 2,D alc.2.15 from assumedcell con- l2.5l9A for the material from Mina La Oriental, Z: l2,D c,alc. -
New Minerals Approved Bythe Ima Commission on New
NEW MINERALS APPROVED BY THE IMA COMMISSION ON NEW MINERALS AND MINERAL NAMES ALLABOGDANITE, (Fe,Ni)l Allabogdanite, a mineral dimorphous with barringerite, was discovered in the Onello iron meteorite (Ni-rich ataxite) found in 1997 in the alluvium of the Bol'shoy Dolguchan River, a tributary of the Onello River, Aldan River basin, South Yakutia (Republic of Sakha- Yakutia), Russia. The mineral occurs as light straw-yellow, with strong metallic luster, lamellar crystals up to 0.0 I x 0.1 x 0.4 rnrn, typically twinned, in plessite. Associated minerals are nickel phosphide, schreibersite, awaruite and graphite (Britvin e.a., 2002b). Name: in honour of Alia Nikolaevna BOG DAN OVA (1947-2004), Russian crys- tallographer, for her contribution to the study of new minerals; Geological Institute of Kola Science Center of Russian Academy of Sciences, Apatity. fMA No.: 2000-038. TS: PU 1/18632. ALLOCHALCOSELITE, Cu+Cu~+PbOZ(Se03)P5 Allochalcoselite was found in the fumarole products of the Second cinder cone, Northern Breakthrought of the Tolbachik Main Fracture Eruption (1975-1976), Tolbachik Volcano, Kamchatka, Russia. It occurs as transparent dark brown pris- matic crystals up to 0.1 mm long. Associated minerals are cotunnite, sofiite, ilin- skite, georgbokiite and burn site (Vergasova e.a., 2005). Name: for the chemical composition: presence of selenium and different oxidation states of copper, from the Greek aA.Ao~(different) and xaAxo~ (copper). fMA No.: 2004-025. TS: no reliable information. ALSAKHAROVITE-Zn, NaSrKZn(Ti,Nb)JSi401ZJz(0,OH)4·7HzO photo 1 Labuntsovite group Alsakharovite-Zn was discovered in the Pegmatite #45, Lepkhe-Nel'm MI. -
A Review of the Structural Architecture of Tellurium Oxycompounds
Mineralogical Magazine, May 2016, Vol. 80(3), pp. 415–545 REVIEW OPEN ACCESS A review of the structural architecture of tellurium oxycompounds 1 2,* 3 A. G. CHRISTY ,S.J.MILLS AND A. R. KAMPF 1 Research School of Earth Sciences and Department of Applied Mathematics, Research School of Physics and Engineering, Australian National University, Canberra, ACT 2601, Australia 2 Geosciences, Museum Victoria, GPO Box 666, Melbourne, Victoria 3001, Australia 3 Mineral Sciences Department, Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, CA 90007, USA [Received 24 November 2015; Accepted 23 February 2016; Associate Editor: Mark Welch] ABSTRACT Relative to its extremely low abundance in the Earth’s crust, tellurium is the most mineralogically diverse chemical element, with over 160 mineral species known that contain essential Te, many of them with unique crystal structures. We review the crystal structures of 703 tellurium oxysalts for which good refinements exist, including 55 that are known to occur as minerals. The dataset is restricted to compounds where oxygen is the only ligand that is strongly bound to Te, but most of the Periodic Table is represented in the compounds that are reviewed. The dataset contains 375 structures that contain only Te4+ cations and 302 with only Te6+, with 26 of the compounds containing Te in both valence states. Te6+ was almost exclusively in rather regular octahedral coordination by oxygen ligands, with only two instances each of 4- and 5-coordination. Conversely, the lone-pair cation Te4+ displayed irregular coordination, with a broad range of coordination numbers and bond distances. -
INTERNATIONAL GEMMOLOGICAL CONFERENCE Nantes - France INTERNATIONAL GEMMOLOGICAL August 2019 CONFERENCE Nantes - France August 2019
IGC 2019 - Nantes IGC 2019 INTERNATIONAL GEMMOLOGICAL CONFERENCE Nantes - France INTERNATIONAL GEMMOLOGICAL August 2019 CONFERENCE Nantes - France www.igc-gemmology.org August 2019 36th IGC 2019 – Nantes, France Introduction 36th International Gemmological Conference IGC August 2019 Nantes, France Dear colleagues of IGC, It is our great pleasure and pride to welcome you to the 36th International Gemmological Conference in Nantes, France. Nantes has progressively gained a reputation in the science of gemmology since Prof. Bernard Lasnier created the Diplôme d’Université de Gemmologie (DUG) in the early 1980s. Several DUGs or PhDs have since made a name for themselves in international gemmology. In addition, the town of Nantes has been on several occasions recognized as a very attractive, green town, with a high quality of life. This regional capital is also an important hub for the industry (e.g. agriculture, aeronautics), education and high-tech. It has only recently developed tourism even if has much to offer, with its historical downtown, the beginning of the Loire river estuary, and the ocean close by. The organizers of 36th International Gemmological Conference wish you a pleasant and rewarding conference Dr. Emmanuel Fritsch, Dr. Nathalie Barreau, Féodor Blumentritt MsC. The organizers of the 36th International Gemmological Conference in Nantes, France From left to right Dr. Emmanuel Fritsch, Dr. Nathalie Barreau, Féodor Blumentritt MsC. 3 36th IGC 2019 – Nantes, France Introduction Organization of the 36th International Gemmological Conference Organizing Committee Dr. Emmanuel Fritsch (University of Nantes) Dr. Nathalie Barreau (IMN-CNRS) Feodor Blumentritt Dr. Jayshree Panjikar (IGC Executive Secretary) IGC Executive Committee Excursions Sophie Joubert, Richou, Cholet Hervé Renoux, Richou, Cholet Guest Programme Sophie Joubert, Richou, Cholet Homepage Dr. -
IMA Master List
The New IMA List of Minerals – A Work in Progress – Update: February 2013 In the following pages of this document a comprehensive list of all valid mineral species is presented. The list is distributed (for terms and conditions see below) via the web site of the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association, which is the organization in charge for approval of new minerals, and more in general for all issues related to the status of mineral species. The list, which will be updated on a regular basis, is intended as the primary and official source on minerals. Explanation of column headings: Name: it is the presently accepted mineral name (and in the table, minerals are sorted by name). Chemical formula: it is the CNMNC-approved formula. IMA status: A = approved (it applies to minerals approved after the establishment of the IMA in 1958); G = grandfathered (it applies to minerals discovered before the birth of IMA, and generally considered as valid species); Rd = redefined (it applies to existing minerals which were redefined during the IMA era); Rn = renamed (it applies to existing minerals which were renamed during the IMA era); Q = questionable (it applies to poorly characterized minerals, whose validity could be doubtful). IMA No. / Year: for approved minerals the IMA No. is given: it has the form XXXX-YYY, where XXXX is the year and YYY a sequential number; for grandfathered minerals the year of the original description is given. In some cases, typically for Rd and Rn minerals, the year may be followed by s.p. -
Winter 1999 Gems & Gemology
WINTER 1999 VOLUME 35 NO. 4 TABLE OF CONTENTS EDITORIAL 173 Gems & Gemology Turns 65 Richard T. Liddicoat and Alice S. Keller 174 LETTERS FEATURE ARTICLE 176 Classifying Emerald Clarity Enhancement at the GIA Gem Trade Laboratory Shane F. McClure, Thomas M. Moses, Maha Tannous, pg. 185 and John I. Koivula NOTES AND NEW TECHNIQUES 186 Clues to the Process Used by General Electric to Enhance the GE POL Diamonds Karl Schmetzer 192 Diopside Needles as Inclusions in Demantoid Garnet from Russia: A Raman Microspectrometric Study Michael S. Krzemnicki pg. 187 196 Garnets from Madagascar with a Color Change of Blue-Green to Purple Karl Schmetzer and Heinz-Jürgen Bernhardt REGULAR FEATURES 202 Gem Trade Lab Notes 208 Gem News 224 Book Reviews 226 Gemological Abstracts 235 Index pg. 193 ABOUT THE COVER: In response to concerns expressed by the trade over the degree of pg. 201 clarity enhancement in emeralds, GIA Gem Trade Laboratory researchers have devised a methodology to establish the size, number, and position of filled fissures in an emerald, in order to classify the apparent degree of clarity enhancement achieved. The lead article in this issue reports on this research and the resulting classification system. The 10.5 ct emerald crystal in this gold and platinum pendant is from Jos, Nigeria. The pendant was designed by Elena Villa, and manufactured by Hans Dieter Krieger; it is courtesy of Gebrüder Bank, Idar-Oberstein, Germany. Photo © Harold & Erica Van Pelt––Photographers, Los Angeles, California. Color separations for Gems & Gemology are by Pacific Color, Carlsbad, California. Printing is by Fry Communications, Inc., Mechanicsburg, Pennsylvania. -
United States Department of the Interior Geological
UNITED STATES DEPARTMENT OF THE INTERIOR GEOLOGICAL SURVEY MINERAL OCCURRENCES OF THE GUIANA SHIELD, VENEZUELA by Gary B. Sidder1 Open-File Report 90-16 1990 This report is preliminary and has not been reviewed for conformity with U.S. Geological Survey editorial standards. Geological Survey, Denver, Colorado TABLE OF CONTENTS Page INTRODUCTION..........................^ 1 GOLD..............................._ 1 DIAMONDS...................................^ 5 IRON.................................................^ 6 ALUMINUM...............................^ 8 MANGA>ffiSE....................................................._ 10 TIN.......................................................................................................... 12 NIOBIUM, TANTALUM, RARE EARTH ELEMENTS................................ 13 URANIUM................................^ 14 MOLYBDENUM.................................................................................................... 15 TITANIUM........................................................................................... 16 PLATINUM.................................................................................................... 16 OTHERMETALS................................................................ 17 SUMMARY...........................^ 17 REFERENCES CITED............................................................................... 18 ILLUSTRATIONS Table 1. Principal mining districts, mines, and mineral occurrences in the Guiana Shield, Venezuela.................. 27 Plate 1. Mineral