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Safety Data Sheet SAFETY DATA SHEET Revision Date 05-Jan-2021 Revision Number 2 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product Description: Antimony(III) iodide, ultra dry Cat No. : 42831 Synonyms Antimony (III) Iodide CAS-No 7790-44-5 EC-No. 232-205-8 Molecular Formula I3 Sb Reach Registration Number - 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended Use Laboratory chemicals. Uses advised against No Information available 1.3. Details of the supplier of the safety data sheet Company Thermo Fisher (Kandel) GmbH . Erlenbachweg 2 76870 Kandel Germany Tel: +49 (0) 721 84007 280 Fax: +49 (0) 721 84007 300 E-mail address [email protected] www.alfa.com Product safety Tel + +049 (0) 7275 988687-0 1.4. Emergency telephone number Carechem 24: +44 (0) 1235 239 670 (Multi-language emergency number) Poison Information Center Mainz www.giftinfo.uni-mainz.de Telephone: +49(0)6131/19240 Exclusively for customers in Austria: Poison Information Center (VIZ) Emergency call 0-24 clock: +43 1 406 43 43 Office hours: Monday to Friday, 8am to 4pm, tel: +43 1 406 68 98 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture CLP Classification - Regulation (EC) No 1272/2008 Physical hazards ______________________________________________________________________________________________ ALFAA42831 Page 1 / 11 SAFETY DATA SHEET Antimony(III) iodide, ultra dry Revision Date 05-Jan-2021 ______________________________________________________________________________________________ Based on available data, the classification criteria are not met Health hazards Acute oral toxicity Category 4 (H302) Acute Inhalation Toxicity - Dusts and Mists Category 4 (H332) Environmental hazards Chronic aquatic toxicity Category 2 (H411) Full text of Hazard Statements: see section 16 2.2. Label elements Signal Word Warning Hazard Statements H411 - Toxic to aquatic life with long lasting effects H302 + H332 - Harmful if swallowed or if inhaled Precautionary Statements P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting P312 - Call a POISON CENTER or doctor/physician if you feel unwell P264 - Wash face, hands and any exposed skin thoroughly after handling P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P273 - Avoid release to the environment P391 - Collect spillage P501 - Dispose of contents/ container to an approved waste disposal plant 2.3. Other hazards No information available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Component CAS-No EC-No. Weight % CLP Classification - Regulation (EC) No 1272/2008 Stibine, triiodo- 7790-44-5 EEC No. 232-205-8 98 Acute Tox. 4 (H302) Acute Tox. 4 (H332) Aquatic Chronic 2 (H411) Component Concentration limits M-Factor Component notes ______________________________________________________________________________________________ ALFAA42831 Page 2 / 11 SAFETY DATA SHEET Antimony(III) iodide, ultra dry Revision Date 05-Jan-2021 ______________________________________________________________________________________________ Stibine, triiodo- - - Note 1 Note Note 1: The concentration stated or, in the absence of such concentrations, the generic concentrations of this Regulation (Table 3.1) or the generic concentrations of Directive 1999/45/EC (Table 3.2), are the percentages by weight of the metallic element calculated with reference to the total weight of the mixture Reach Registration Number - Full text of Hazard Statements: see section 16 SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures General Advice If symptoms persist, call a physician. Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician. Ingestion Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur. Inhalation Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur. Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. 4.2. Most important symptoms and effects, both acute and delayed None reasonably foreseeable. 4.3. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Suitable Extinguishing Media Carbon dioxide (CO 2). Dry chemical. Chemical foam. Extinguishing media which must not be used for safety reasons Water. 5.2. Special hazards arising from the substance or mixture Thermal decomposition can lead to release of irritating gases and vapors. Keep product and empty container away from heat and sources of ignition. Hazardous Combustion Products Hydrogen iodide, antimony, Antimony oxide. ______________________________________________________________________________________________ ALFAA42831 Page 3 / 11 SAFETY DATA SHEET Antimony(III) iodide, ultra dry Revision Date 05-Jan-2021 ______________________________________________________________________________________________ 5.3. Advice for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Use personal protective equipment as required. Avoid dust formation. 6.2. Environmental precautions Do not flush into surface water or sanitary sewer system. Should not be released into the environment. Do not allow material to contaminate ground water system. 6.3. Methods and material for containment and cleaning up Sweep up and shovel into suitable containers for disposal. Keep in suitable, closed containers for disposal. 6.4. Reference to other sections Refer to protective measures listed in Sections 8 and 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Wear personal protective equipment/face protection. Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Avoid dust formation. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work. 7.2. Conditions for safe storage, including any incompatibilities Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Keep under nitrogen. Handle and store contents under nitrogen. Protect from moisture. Technical Rules for Hazardous Substances (TRGS) 510 Storage Class (LGK) Storage Class/LGK 13 (Germany) 7.3. Specific end use(s) Use in laboratories SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Exposure limits List source(s): UK - EH40/2005 Work Exposure Limits, Third edition. Published 2018. Component European Union The United Kingdom France Belgium Spain ______________________________________________________________________________________________ ALFAA42831 Page 4 / 11 SAFETY DATA SHEET Antimony(III) iodide, ultra dry Revision Date 05-Jan-2021 ______________________________________________________________________________________________ Stibine, triiodo- STEL: 1.5 mg/m3 15 min TWA / VME: 0.5 mg/m3 TWA / VLA-ED: 0.5 TWA: 0.5 mg/m3 8 hr (8 heures). mg/m3 (8 horas) Component Italy Germany Portugal The Netherlands Finland Stibine, triiodo- TWA: 0.5 mg/m3 8 horas Component Austria Denmark Switzerland Poland Norway Stibine, triiodo- MAK-KZW: 1.5 mg/m3 TWA: 0.5 mg/m3 8 timer 15 Minuten MAK-TMW: 0.5 mg/m3 8 Stunden Biological limit values This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific regulatory bodies Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust Derived No Effect Level (DNEL) No information available Route of exposure Acute effects (local) Acute effects Chronic effects Chronic effects (systemic) (local) (systemic) Oral Dermal Inhalation Predicted No Effect Concentration No information available. (PNEC) 8.2. Exposure controls Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source Personal protective equipment Eye Protection Wear safety glasses with side shields (or goggles) (European standard - EN 166) Hand Protection Protective gloves Glove material Breakthrough time Glove thickness EU standard Glove comments Natural rubber See manufacturers - EN 374 (minimum requirement)
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