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8323 Hexabromobenzene

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8323 Hexabromobenzene H0363 Material Safety Data Sheet HAZARD WARNINGS RISK PHRASES PROTECTIVE CLOTHING Irritating to skin, eyes, and the respiratory system. Section I. Chemical Product and Company Identification Chemical Name Hexabromobenzene Catalog Number H0363 Supplier TCI America 9211 N. Harborgate St. Synonym Perbromobenzene Portland OR 1-800-423-8616 Chemical Formula C6Br6 In case of Chemtrec® CAS Number 87-82-1 Emergency (800) 424-9300 (U.S.) Call (703) 527-3887 (International) Section II. Composition and Information on Ingredients Chemical Name CAS Number Percent (%) TLV/PEL Toxicology Data Hexabromobenzene 87-82-1 Min. 99.0 Not available. Not available. (GC) Section III. Hazards Identification Acute Health Effects Irritating to eyes and skin on contact. Inhalation causes irritation of the lungs and respiratory system. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound. Chronic Health Effects CARCINOGENIC EFFECTS : Not available. MUTAGENIC EFFECTS : Not available. TERATOGENIC EFFECTS : Not available. DEVELOPMENTAL TOXICITY: Not available. There is no known effect from chronic exposure to this product. Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions. Section IV. First Aid Measures Eye Contact Check for and remove any contact lenses. DO NOT use an eye ointment. Flush eyes with running water for a minimum of 15 minutes, occasionally lifting the upper and lower eyelids. Seek medical attention. Treat symptomatically and supportively. Skin Contact After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cover the irritated skin with an emollient. Seek medical attention. Treat symptomatically and supportively. Wash any contaminated clothing before reusing. Inhalation If the victim is not breathing, perform artificial respiration. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, oxygen can be administered. Seek medical attention. Treat symptomatically and supportively. Ingestion INDUCE VOMITING by sticking finger in throat. Lower the head so that the vomit will not reenter the mouth and throat. Loosen tight clothing such as a collar, tie, belt, or waistband. If the victim is not breathing, administer artificial respiration. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the toxic material was ingested; the absence of such signs, however, is not conclusive. Seek immediate medical attention and, if possible, show the chemical label. Treat symptomatically and supportively. Section V. Fire and Explosion Data Flammability Combustible. Auto-Ignition Not available. Flash Points Not available. Flammable Limits Not available. Combustion Products These products include toxic carbon oxides (CO,CO 2), halogenated combustion products. Fire Hazards No specific information is available regarding the flammability of this compound in the presence of various materials. Explosion Hazards Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. No additional information is available regarding the risks of explosion. Fire Fighting Media SMALL FIRE: Use DRY chemicals, CO 2, water spray or foam. and Instructions LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet. Continued on Next Page Emergency phone number (800) 424-9300 Printed 2/25/2005. H0363 Hexabromobenzene Page 2 Section VI. Accidental Release Measures Spill Cleanup Irritating material. Instructions In case of a spill and/or a leak, always shut off any sources of ignition, ventilate the area, and exercise caution. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning the spill by rinsing any contaminated surfaces with copious amounts of water. Consult federal, state, and/or local authorities for assistance on disposal. Section VII. Handling and Storage Handling and Storage IRRITANT. Keep away from heat and sources of ignition. Mechanical exhaust required. When not in use, tightly seal the Information container and store in a dry, cool place. Avoid excessive heat and light. DO NOT ingest. DO NOT breathe dust. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Treat symptomatically and supportively. Avoid contact with skin and eyes. Always store away from incompatible compounds such as oxidizing agents. Section VIII. Exposure Controls/Personal Protection Engineering Controls Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Personal Protection Splash goggles. Lab coat. Dust respirator. Boots. Gloves. A MSHA/NIOSH approved respirator must be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure Limits Not available. Section IX. Physical and Chemical Properties Physical state @ 20°C Off-white powder. Solubility Soluble in benzene, chloroform. Partially soluble in methanol, diethyl ether. Specific Gravity Not available. Insoluble in cold water, hot water. Molecular Weight 551.49 Partition Coefficient log Kow = 6.07 Boiling Point Not available. Vapor Pressure 3.1 x 10-9mm of Hg (@ 25°C) Melting Point 327°C (620.6°F) Vapor Density Not available. Refractive Index Not available. Volatility Not available. Critical Temperature Not available. Odor Not available. Viscosity Not available. Taste Not available. Section X. Stability and Reactivity Data Stability This material is stable if stored under proper conditions. (See Section VII for instructions) Conditions of Instability Avoid excessive heat and light. Incompatibilities Reactive with strong oxidizing agents. Section XI. Toxicological Information RTECS Number Not available. Routes of Exposure Eye contact. Ingestion. Inhalation. Skin contact. Toxicity Data Not available. Chronic Toxic Effects CARCINOGENIC EFFECTS : Not available. MUTAGENIC EFFECTS : Not available. TERATOGENIC EFFECTS : Not available. DEVELOPMENTAL TOXICITY: Not available. There is no known effect from chronic exposure to this product. Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions. Acute Toxic Effects Irritating to eyes and skin on contact. Inhalation causes irritation of the lungs and respiratory system. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound. Continued on Next Page Emergency phone number (800) 424-9300 Printed 2/25/2005. H0363 Hexabromobenzene Page 3 Section XII. Ecological Information Ecotoxicity Not available. Environmental Fate Hexabromobenzene's possible production and use as a flame retardant may result in its release to the environment through various waste streams. Hexabromobenzene may also enter the environmentas a result of the high temperature breakdown of other brominated fire retardants. If released to the atmosphere, hexabromobenzene will exist solely in the particulate phase in the ambient atmosphere, based on an estimated vapor pressure of 1.6X10-8 mm Hgat 25 deg C. Particulate-phase hexabromobenzene may be physically removed from the air by dry deposition. An estimated Koc value of 48,000 suggests that hexabromobenzene will be immobile in soil. Volatilization from moist soil surfaces may occur based on an estimated Henry's Law constant of 2.8X10-5 atm-cu m/mole. Volatilization from dry soil surfaces is not expected given the vapor pressure of this compound. Based on limited data, hexabromobenzene is expected to be resistant to microbial degradation in both soil and aquatic environments; 8 and 10% biodegradation was reported for river water and sea water, respectively, after a 3 day incubation. In water, hexabromobenzene should adsorb to sediment or particulate matter based on its Koc value. This compound may volatilize from water surfaces given its estimated Henry's Law constant. Estimated half-lives for a model river and model lake are 3 and 32 days, respectively, although adsorption to sediment and particulate matter may attenuate this process. The volatilization half-life from a model pond, taking into account adsorptive processes, is 114 months. Information on the bioaccumulation of hexabromobenzene in fish is conflicting with biocentration potential ranges from low to very high. In short-term studies, hexabromobenzene was non-accumulative in fish. However, in a 96 day study using rainbow trout, a mean BCF value of 1,100 was measured. It was suggested that non-accumulation was due to the size of hexabromobenzene, resulting in a lack of membrane permeation. Occupational exposure to hexabromobenzene may occur by dermal contact or respiratory routes during its production
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