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Aldrich FT-IR Collection Edition I Library
Aldrich FT-IR Collection Edition I Library Library Listing – 10,505 spectra This library is the original FT-IR spectral collection from Aldrich. It includes a wide variety of pure chemical compounds found in the Aldrich Handbook of Fine Chemicals. The Aldrich Collection of FT-IR Spectra Edition I library contains spectra of 10,505 pure compounds and is a subset of the Aldrich Collection of FT-IR Spectra Edition II library. All spectra were acquired by Sigma-Aldrich Co. and were processed by Thermo Fisher Scientific. Eight smaller Aldrich Material Specific Sub-Libraries are also available. Aldrich FT-IR Collection Edition I Index Compound Name Index Compound Name 3515 ((1R)-(ENDO,ANTI))-(+)-3- 928 (+)-LIMONENE OXIDE, 97%, BROMOCAMPHOR-8- SULFONIC MIXTURE OF CIS AND TRANS ACID, AMMONIUM SALT 209 (+)-LONGIFOLENE, 98+% 1708 ((1R)-ENDO)-(+)-3- 2283 (+)-MURAMIC ACID HYDRATE, BROMOCAMPHOR, 98% 98% 3516 ((1S)-(ENDO,ANTI))-(-)-3- 2966 (+)-N,N'- BROMOCAMPHOR-8- SULFONIC DIALLYLTARTARDIAMIDE, 99+% ACID, AMMONIUM SALT 2976 (+)-N-ACETYLMURAMIC ACID, 644 ((1S)-ENDO)-(-)-BORNEOL, 99% 97% 9587 (+)-11ALPHA-HYDROXY-17ALPHA- 965 (+)-NOE-LACTOL DIMER, 99+% METHYLTESTOSTERONE 5127 (+)-P-BROMOTETRAMISOLE 9590 (+)-11ALPHA- OXALATE, 99% HYDROXYPROGESTERONE, 95% 661 (+)-P-MENTH-1-EN-9-OL, 97%, 9588 (+)-17-METHYLTESTOSTERONE, MIXTURE OF ISOMERS 99% 730 (+)-PERSEITOL 8681 (+)-2'-DEOXYURIDINE, 99+% 7913 (+)-PILOCARPINE 7591 (+)-2,3-O-ISOPROPYLIDENE-2,3- HYDROCHLORIDE, 99% DIHYDROXY- 1,4- 5844 (+)-RUTIN HYDRATE, 95% BIS(DIPHENYLPHOSPHINO)BUT 9571 (+)-STIGMASTANOL -
1 Abietic Acid R Abrasive Silica for Polishing DR Acenaphthene M (LC
1 abietic acid R abrasive silica for polishing DR acenaphthene M (LC) acenaphthene quinone R acenaphthylene R acetal (see 1,1-diethoxyethane) acetaldehyde M (FC) acetaldehyde-d (CH3CDO) R acetaldehyde dimethyl acetal CH acetaldoxime R acetamide M (LC) acetamidinium chloride R acetamidoacrylic acid 2- NB acetamidobenzaldehyde p- R acetamidobenzenesulfonyl chloride 4- R acetamidodeoxythioglucopyranose triacetate 2- -2- -1- -β-D- 3,4,6- AB acetamidomethylthiazole 2- -4- PB acetanilide M (LC) acetazolamide R acetdimethylamide see dimethylacetamide, N,N- acethydrazide R acetic acid M (solv) acetic anhydride M (FC) acetmethylamide see methylacetamide, N- acetoacetamide R acetoacetanilide R acetoacetic acid, lithium salt R acetobromoglucose -α-D- NB acetohydroxamic acid R acetoin R acetol (hydroxyacetone) R acetonaphthalide (α)R acetone M (solv) acetone ,A.R. M (solv) acetone-d6 RM acetone cyanohydrin R acetonedicarboxylic acid ,dimethyl ester R acetonedicarboxylic acid -1,3- R acetone dimethyl acetal see dimethoxypropane 2,2- acetonitrile M (solv) acetonitrile-d3 RM acetonylacetone see hexanedione 2,5- acetonylbenzylhydroxycoumarin (3-(α- -4- R acetophenone M (LC) acetophenone oxime R acetophenone trimethylsilyl enol ether see phenyltrimethylsilyl... acetoxyacetone (oxopropyl acetate 2-) R acetoxybenzoic acid 4- DS acetoxynaphthoic acid 6- -2- R 2 acetylacetaldehyde dimethylacetal R acetylacetone (pentanedione -2,4-) M (C) acetylbenzonitrile p- R acetylbiphenyl 4- see phenylacetophenone, p- acetyl bromide M (FC) acetylbromothiophene 2- -5- -
Chemical Trends in Solid Alkali Pertechnetates † ‡ ‡ ‡ ‡ ‡ Jamie Weaver, , Chuck Z
This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes. Article pubs.acs.org/IC Chemical Trends in Solid Alkali Pertechnetates † ‡ ‡ ‡ ‡ ‡ Jamie Weaver, , Chuck Z. Soderquist, Nancy M. Washton, Andrew S. Lipton, Paul L. Gassman, § ∥ † † ‡ ⊥ Wayne W. Lukens, Albert A. Kruger, Nathalie A. Wall, and John S. McCloy*, , , † Department of Chemistry, Washington State University, Pullman, Washington 99164, United States ‡ Pacific Northwest National Laboratory, Richland, Washington 99352, United States § Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States ∥ U.S. Department of Energy (DOE), Office of River Protection, Richland, Washington 99352, United States ⊥ Materials Science and Engineering Program and School of Mechanical & Materials Engineering, Washington State University, Pullman, Washington 99164, United States *S Supporting Information ABSTRACT: Insight into the solid-state chemistry of pure technetium-99 (99Tc) oxides is required in the development of a robust immobilization and disposal system for nuclear waste stemming from the radiopharmaceutical industry, from the production of nuclear weapons, and from spent nuclear fuel. However, because of its radiotoxicity and the subsequent requirement of special facilities and handling procedures for research, only a few studies have been completed, many of which are over 20 years old. In this study, we report the synthesis of pure alkali pertechnetates (sodium, potassium, rubidium, and cesium) and analysis of these compounds by Raman spectroscopy, X-ray absorption spectroscopy (XANES and EXAFS), solid-state nuclear magnetic resonance (static and magic angle spinning), and neutron diffraction. The structures and spectral signatures of these compounds will aid in refining the understanding of 99Tc incorporation into and release from nuclear waste glasses. -
Harmonized Tariff Schedule of the United States (2020) Revision 14 Annotated for Statistical Reporting Purposes
Harmonized Tariff Schedule of the United States (2020) Revision 14 Annotated for Statistical Reporting Purposes SECTION VI PRODUCTS OF THE CHEMICAL OR ALLIED INDUSTRIES VI-1 Notes 1. (a) Goods (other than radioactive ores) answering to a description in heading 2844 or 2845 are to be classified in those headings and in no other heading of the tariff schedule. (b) Subject to paragraph (a) above, goods answering to a description in heading 2843, 2846 or 2852 are to be classified in those headings and in no other heading of this section. 2. Subject to note 1 above, goods classifiable in heading 3004, 3005, 3006, 3212, 3303, 3304, 3305, 3306, 3307, 3506, 3707 or 3808 by reason of being put up in measured doses or for retail sale are to be classified in those headings and in no other heading of the tariff schedule. 3. Goods put up in sets consisting of two or more separate constituents, some or all of which fall in this section and are intended to be mixed together to obtain a product of section VI or VII, are to be classified in the heading appropriate to that product, provided that the constituents are: (a) Having regard to the manner in which they are put up, clearly identifiable as being intended to be used together without first being repacked; (b) Entered together; and (c) Identifiable, whether by their nature or by the relative proportions in which they are present, as being complementary one to another. Additional U.S. Notes 1. In determining the amount of duty applicable to a solution of a single compound in water subject to duty in this section at a specific rate, an allowance in weight or volume, as the case may be, shall be made for the water in excess of any water of crystallization which may be present in the undissolved compound. -
P'aturan Harga Satuan Standar BATAN-2009
BADAN TENAGA NUKLIR NASIONAL PERATURAN KEPALA BADAN TENAGA NUKLIR NASIONAL NOMOR: 110/KA/VI/2008 VIII/2007 TENTANG HARGA SATUAN STANDAR BATAN TAHUN ANGGARAN 2009 DENGAN RAHMAT TUHAN YANG MAHA ESA KEPALA BADAN TENAGA NUKLIR NASIONAL, Menimbang : a. bahwa dengan Peraturan Kepala BATAN Nomor 122/KA/VIII/2007 telah ditetapkan Harga Satuan Standar BATAN Tahun Anggaran 2008; b. bahwa mengingat banyaknya perubahan jumlah maupun struktur biaya yang terjadi, akan berdampak terhadap pelaksanaan kegiatan Tahun Anggaran 2009; c. bahwa berdasarkan pertimbangan sebagaimana dimaksud dalam huruf a dan huruf b, perlu menetapkan Peraturan Kepala BATAN tentang Harga Satuan Standar BATAN Tahun Anggaran 2009; Mengingat : 1. Undang-Undang Nomor 17 Tahun 2003 tentang Keuangan Negara (Lembaran Negara Republik Indonesia Tahun 2003 Nomor 47, Tambahan Lembaran Negara Republik Indonesia Nomor 4286); 2. Undang-Undang Nomor 1 Tahun 2004 tentang Perbendaharaan Negara (Lembaran Negara Republik Indonesia Tahun 2004 Nomor 5, Tambahan Lembaran Negara Republik Indonesia Nomor 4355); 3. Undang-Undang Nomor 25 Tahun 2004 tentang Sistem Perencanaan Pembangunan Nasional (Lembaran Negara Republik Indonesia Tahun 2004 Nomor 104, Tambahan Lembaran Negara Republik Indonesia Nomor 4421); 4. Peraturan Pemerintah Nomor 21 Tahun 2004 tentang Penyusunan Rencana Kerja dan Anggaran Kementerian Negara/Lembaga (Lembaran Negara Republik Indonesia Tahun 2004 Nomor 75, Tambahan Lembaran Negara Republik Indonesia Nomor 4406); BADAN TENAGA NUKLIR NASIONAL -2- 5. Peraturan Pemerintah Nomor 77 Tahun 2005 tentang Jenis dan Tarif Atas Jenis Penerimaan Negara Bukan Pajak Yang Berlaku Pada Badan Tenaga Nuklir Nasional (Lembaran Negara Republik Indonesia Tahun 2005 Nomor 163, Tambahan Lembaran Negara Republik Indonesia Nomor 4591); 6. Keputusan Presiden Nomor 103 Tahun 2001 tentang Kedudukan, Tugas, Fungsi, Kewenangan, Susunan Organisasi, dan Tata Kerja Lembaga Pemerintah Non Departemen sebagaimana telah beberapa kali diubah, terakhir dengan Peraturan Presiden Nomor 64 Tahun 2005; 7. -
Tungstovanadate Heteropoly Complexes. 11. Products of Acidification of V2w&Lg4
TUNGSTOVANADATEHETEROPOLY COMPLEXES Inorganic Chemistry, Vol. 10, No. 12, 1971 2745 Then, assuming that the difference is also reflected in line widths were somewhat broader than those of the Tze,much broader epr lines are expected for the mono- VO(H20)42+spectrum. That observation is compatible chloro species, which would be difficult to detect in the with a decreased re relative to that of the aquo complex, presence of the sharper spectrum of VO(H20)2C12. but a much more detailed investigation of the relaxa- The liquid solution epr spectra for a number of tion processes would be necessary for quantitative HC1 concentrations were also observed in this labora- comparison. tory. The intensity of the spectrum attributed to VO (H~0)4~+appeared to follow qualitatively the rela- Acknowledgments.-We are indebted to Dr. W. tive concentrations indicated in Tables I1 and I11 and Burton Lewis and others for helpful comments during Figure 4. However, no attempt was made to do an discussions of the work reported here. We also wish absolute spin count. In 12 M HC1 solution the (g) to thank Dr. B. B. McInteer and Mr. R. M. Potter of and (A) values obtained corresponded well with the Los Alamos Scientific Laboratory for supplying those reported by Kon and Sharpless and the observed the enriched "'0. CONTRIBUTIONFROM THE DEPARTMENTOF CHEMISTRY, GEORGETOWNUNIVERSITY, WASHINGTON, D. C. 20007 Tungstovanadate Heteropoly Complexes. 11. Products of Acidification of v2w&lg4- BY C. M. FLY", JR., AND M. T. POPE* Receiz'ed April 30, 1971 Acidification of solutions of VzW40104- is an efficient means of preparing the red complex V~WQO~O~-,isolated as K, "4, Na, N(CH3)4, C(NHZ)~,and C~H~(NH~)Zsalts. -
Tungsten-Based Nanocomposites by Chemical Methods
Tungsten-Based Nanocomposites by Chemical Methods Sverker Wahlberg Doctoral Thesis in Materials Chemistry Stockholm 2014 KTH Royal Institute of Technology SE-100 44 Stockholm, Sweden TRITA-ICT/MAP AVH Report 2014:20 KTH School of Information and ISSN 1653-7610 Communication Technology ISRN KTH/ICT-MAP/AVH-2014:20-SE SE-164 40, Kista, Sweden ISBN 978-91-7595-368-7 Akademisk avhandling som med tillstånd av KTH i Stockholm framlägges till offentlig granskning för avläggande av teknisk doktorsexamen torsdagen den 11 december kl 10.00 i sal 205, Electrum, KTH, Isafjordsgatan 22, Kista. © Sverker Wahlberg, 2014 Universitetsservice US-AB, Stockholm 2014 2 Abstract Tungsten based-materials find use in many different fields of engineering, particularly in applications where good temperature and/or erosion resistance is important. Nanostructuring of tungsten composites is expected to dramatically improve the materials’ properties and enhancing the performance in present applications but also enabling totally new possibilities. Nanostructured WC-Co materials have been the focus of researchers and engineers for over two decades. New fabrication methods have been developed. But, the fabrication of true nanograined WC-Co composites is still a challenge. Nanostructured tungsten-based materials for applications as plasma facing materials in fusion reactors have attracted a growing interest. This Thesis summarizes work on the development of chemical methods for the fabrication of two different types of nanostructured tungsten-based materials; WC-Co composites mainly for cutting tools applications and W-ODS materials with yttria particles, intended as plasma facing materials in fusion reactors. The approach has been to prepare powders in two steps: a) synthesis of uniform powder precursors containing ions of tungsten and cobalt or yttrium by precipitation from aqueous solutions and b) processing of the precursors into WC- or W-based nano-composite powders. -
RSC Advances
RSC Advances REVIEW View Article Online View Journal | View Issue Glymes as versatile solvents for chemical reactions and processes: from the laboratory to industry Cite this: RSC Adv.,2014,4,11251 Shaokun Tanga and Hua Zhao*b Glymes, also known as glycol diethers, are saturated non-cyclic polyethers containing no other functional groups. Most glymes are usually less volatile and less toxic than common laboratory organic solvents; in this context, they are more environmentally benign solvents. However, it is also important to point out that some glymes could cause long-term reproductive and developmental damage despite their low acute toxicities. Glymes have both hydrophilic and hydrophobic characteristics that common organic solvents lack. In addition, they are usually thermally and chemically stable, and can even form complexes with ions. Therefore, glymes are found in a broad range of laboratory applications including organic synthesis, electrochemistry, biocatalysis, materials, Chemical Vapor Deposition (CVD), etc. In addition, glymes are used in numerous industrial applications, such as cleaning products, inks, adhesives and coatings, Received 6th October 2013 batteries and electronics, absorption refrigeration and heat pumps, as well as pharmaceutical Accepted 9th December 2013 formulations, etc. However, there is a lack of a comprehensive and critical review on this attractive DOI: 10.1039/c3ra47191h subject. This review aims to accomplish this task by providing an in-depth understanding of glymes' www.rsc.org/advances physicochemical properties, toxicity and major applications. 1. Introduction based). The general structure of PEG-based glymes and their common names are illustrated in Scheme 1. Glymes, i.e. glycol diethers, are saturated polyethers containing Most glymes are completely miscible with both water and no other functional groups. -
Provides a Process of Hydrogenating 3-Hydroxypropionalde
USOO7335800B2 (12) United States Patent (10) Patent No.: US 7,335,800 B2 Komplin et al. (45) Date of Patent: Feb. 26, 2008 (54) HYDROGENATION CATALYST AND 5,945,570 A 8/1999 Arhancet et al. ........... 568,862 HYDROGENATION METHOD 5,958,825 A 9/1999 Wulff-Doring et al. ..... 502,300 5,977,013 A 1 1/1999 Elliott et al. ................ 5O2,337 (75) Inventors: Glenn Charles Komplin, Katy, TX 6,152.975 A 1 1/2000 Elliott et al. .............. 48.197 R (US); John Anthony Smegal, Houston, 6,232,511 B1 5/2001 Haas et al. ................. 568,862 TX (US) 6,342.464 B1 1/2002 Arhancet et al. ........... 5O2/257 6,376,720 B1 4/2002 Han ........................... 568,483 (73) Assignee: Shell Oil Company, Houston, TX (US) 6,399,538 B1 6/2002 Hucul ........................ 5O2,325 ( c ) Notice: Subject tO any disclaimer, the term of this 6,429,167 B1 8/2002 Maeno et al. ............... 5O2,325 patent is extended or adjusted under 35 6,670,300 B2 12/2003 Werpy et al. ............... 502f182 U.S.C. 154(b) by 168 days. 6,911,566 B2 6/2005 Tsunoda et al. ............ 568,862 2002/0087.036 A1 7/2002 Haas et al. ................. 568/885 (21) Appl. No.: 11/409,433 2004/0097764 A1 5/2004 Tsunoda et al. ............ 568.860 2004/0225 161 Al 11/2004 Sunkara et al. ............. 568,852 (22) Filed: Apr. 21, 2006 2004/0260125 Al 12/2004 Seapan et al. .............. 568,868 O O 2005/0033099 A1 2/2005 Ryu et al. ................... 585,259 (65) Prior Publication Data 2005/0080300 A1 4/2005 Komplin et al. -
Analysis of Alternatives
ANALYSIS OF ALTERNATIVES Legal name of applicant(s): Acton Technologies Ltd Submitted by: Acton Technologies Ltd (jointly developed with Maflon Spa) Substance: bis(2-methoxyethyl) ether (diglyme): EC 203-924-4: CAS 111-96-6 Use title: Use of bis(2-methoxyethyl) ether (diglyme) as a carrier solvent in the formulation and use of sodium naphthalide etchant for fluoropolymer surface modification whilst preserving article structural integrity (in-house processes). Use of bis(2-methoxyethyl) ether (diglyme) as a carrier solvent in the application of sodium naphthalide etchant for fluoropolymer surface modification whilst preserving article structural integrity (downstream user processes). Use number: 1 and 2 ANALYSIS OF ALTERNATIVES CONTENTS LIST OF ABBREVIATIONS ....................................................................................................................................... 5 DECLARATION .......................................................................................................................................................... 6 1. SUMMARY ............................................................................................................................................................ 7 2. ANALYSIS OF SUBSTANCE FUNCTION.......................................................................................................... 10 2.1. The requirement to modify the surface of fluoropolymers ............................................................................. 10 2.1.1 Fluoropolymers .................................................................................................................................. -
In Accurately Assessing the Development Of
28 . 5 . 84 Official Journal of the European Communities No L 141 / 1 I (Acts whose publication is obligatory) COUNCIL REGULATION (EEC) No 1410/84 of 15 May 1984 temporarily suspending the autonomous Common Customs Tariff duties on a number of industrial products THE COUNCIL OF THE EUROPEAN taken only temporarily with their term of validity COMMUNITIES, fixed to coincide with the interests of Community production , Having regard to the Treaty establishing the Euro pean Economic Community, and in particular HAS ADOPTED THIS REGULATION : Article 28 thereof, Having regard to the draft Regulation submitted by Article 1 the Commission, The autonomous Common Customs Tariff duties Whereas production of the products referred to in for the products listed in the tables annexed to this this Regulation is at present inadequate or non Regulation shall be suspended as the level indicated existent within the Community and producers are in respect of each of them . thus unable to meet the needs of user industries in the Community ; These suspensions shall be valid : Whereas it is in the Community's interest to sus — from 1 July to 31 December 1984 for the prod pend the autonomous Common Customs Tariff ucts listed in Table I , duties only partially in certain cases , due particu — from 1 July 1984 to 30 June 1985 for the prod larly to the existence of Community production , and ucts listed in Table II . to suspend them completely in other cases ; Whereas , taking account of the difficulties involved Article 2 in accurately assessing the development of the economic situation in the sectors concerned in the This Regulation shall enter into force on 1 July near future, these suspension measures should be 1984 . -
Perylene Diimide: a Versatile Building Block for Complex Molecular Architectures and a Stable Charge Storage Material
Perylene Diimide: A Versatile Building Block for Complex Molecular Architectures and a Stable Charge Storage Material Margarita Milton Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy in the Graduate School of Arts and Sciences COLUMBIA UNIVERSITY 2018 © 2018 Margarita Milton All rights reserved ABSTRACT Perylene Diimide: A Versatile Building Block for Complex Molecular Architectures and a Stable Charge Storage Material Margarita Milton Properties such as chemical robustness, potential for synthetic tunability, and superior electron-accepting character describe the chromophore perylene-3,4,9,10-tetracarboxylic diimide (PDI) and have enabled its penetration into organic photovoltaics. The ability to extend what is already a large aromatic core allows for synthesis of graphene ribbon PDI oligomers. Functionalization with polar and ionic groups leads to liquid crystalline phases or immense supramolecular architectures. Significantly, PDI dianions can survive in water for two months with no decomposition, an important property for charge storage materials. We realized the potential of PDI as an efficient negative-side material for Redox Flow Batteries (RFBs). The synthetic tunability of PDI allowed for screening of several derivatives with side chains that enhanced solubility in polar solvents. The optimized molecule, PDI[TFSI]2, dissolved in acetonitrile up to 0.5 M. For the positive-side, we synthesized the ferrocene oil [Fc4] in high yield. The large hydrodynamic radii of PDI[TFSI]2 and [Fc4] preclude their ability to cross a size exclusion membrane, which is a cheap alternative to the typical RFB membranes. We show that this cellulose-based membrane can support high voltages in excess of 3 V and extreme temperatures (−20 to 110 °C).