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SAFETY DATA SHEET Santa Cruz Biotechnology, Inc SAFETY DATA SHEET Santa Cruz Biotechnology, Inc. Revision date 05-Apr-2018 Version 1 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING _____________________________________________________________________________________________________________________ Product identifier Product Name Methyl-d3-magnesium iodide solution Product Code SC-235856 Recommended use of the chemical and restrictions on use For research use only. Not intended for diagnostic or therapeutic use. Details of the supplier of the safety data sheet Emergency telephone number Chemtrec Santa Cruz Biotechnology, Inc. 1.800.424.9300 (Within USA) 10410 Finnell Street +1.703.527.3887 (Outside USA) Dallas, TX 75220 831.457.3800 800.457.3801 [email protected] 2. HAZARDS IDENTIFICATION _____________________________________________________________________________________________________________________ This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification Acute toxicity - Oral Category 4 Specific target organ toxicity (single exposure) Category 3 Substances or mixtures which, in contact with water, emit Category 1 flammable gases Flammable liquids Label elements Signal word Danger Hazard statements Harmful if swallowed May cause drowsiness or dizziness Extremely flammable liquid and vapor In contact with water releases flammable gases which may ignite spontaneously Symbols/Pictograms Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. — No smoking Keep container tightly closed Ground/bond container and receiving equipment Use only non-sparking tools Take precautionary measures against static discharge Wear protective gloves/protective clothing/eye protection/face protection Handle under inert gas. Protect from moisture Santa Cruz Biotechnology, Inc. www.scbt.com 1 / 7 SC-235856 - Methyl-d3-magnesium iodide solution Revision date 05-Apr-2018 _____________________________________________________________________________________________________________________ Keep away from any possible contact with water, because of violent reaction and possible flash fire Keep cool Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth In case of fire: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store in a well-ventilated place. Keep container tightly closed Store locked up Store in a dry place. Store in a closed container Store in a dry place Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Hazards not otherwise classified (HNOC) Not applicable Other Information Unknown acute toxicity 23.726% of the mixture consists of ingredient(s) of unknown toxicity. NFPA Health hazards 2 HMIS Health hazards 2 Flammability 4 Flammability 4 Stability 2 Physical hazards 2 Physical and chemical W Personal protection - properties 3. COMPOSITION/INFORMATION ON INGREDIENTS _____________________________________________________________________________________________________________________ CAS No 41251-37-0 Molecular Weight 169.26 Formula CD3MgI Chemical name CAS No Weight % Oral LD50 Dermal LD50 Inhalation LC50 Diethyl Ether 60-29-7 70 - 90 = 1215 mg/kg ( Rat ) = 20 mL/kg ( Rabbit ) > 20 = 32000 ppm ( Rat ) 4 h mL/kg ( Rabbit ) Methyl-d3-magnesium iodide 41251-37-0 10 - 30 - - - 4. FIRST AID MEASURES _____________________________________________________________________________________________________________________ First Aid Measures General advice Consult a physician if necessary. Remove to fresh air. Eye contact Wash with plenty of water. Skin Contact Wash skin with soap and water. Inhalation Remove to fresh air If breathing is difficult, give oxygen If not breathing, give artificial respiration Ingestion Never give anything by mouth to an unconscious person. Clean mouth with water. Most important symptoms and effects, both acute and delayed Symptoms No information available. Santa Cruz Biotechnology, Inc. www.scbt.com 2 / 7 SC-235856 - Methyl-d3-magnesium iodide solution Revision date 05-Apr-2018 _____________________________________________________________________________________________________________________ Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES _____________________________________________________________________________________________________________________ Suitable Extinguishing Media Suitable Extinguishing Media Use CO2, dry chemical, or foam. Unsuitable Extinguishing Media Water. Specific hazards arising from the chemical Specific hazards arising from the Highly flammable. chemical Hazardous combustion products Carbon oxides. Explosion data Sensitivity to Mechanical Impact No information available. Sensitivity to Static Discharge No information available. Protective equipment and precautions for firefighters Protective equipment and precautions As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH for firefighters (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES _____________________________________________________________________________________________________________________ Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. 7. HANDLING AND STORAGE _____________________________________________________________________________________________________________________ Precautions for safe handling Advice on safe handling Contact with water liberates toxic, highly flammable gas. Conditions for safe storage, including any incompatibilities Storage Conditions Protect from moisture. Store at room temperature. Incompatible materials Strong oxidizing agents. Water. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION _____________________________________________________________________________________________________________________ Control parameters Exposure Guidelines . Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 Santa Cruz Biotechnology, Inc. www.scbt.com 3 / 7 SC-235856 - Methyl-d3-magnesium iodide solution Revision date 05-Apr-2018 _____________________________________________________________________________________________________________________ (11th Cir., 1992). Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Diethyl Ether STEL: 500 ppm TWA: 400 ppm IDLH: 1900 ppm 60-29-7 TWA: 400 ppm TWA: 1200 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 1200 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1500 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and Body Protection Wear protective gloves and protective clothing. Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES _____________________________________________________________________________________________________________________ Physical State liquid Appearance No information available Odor No information available Property Values pH No information available Melting point/freezing point No information available Boiling point 35 °C Flash point -40 °C Density 0.871 g/mL Evaporation rate No information available Upper flammability limits No information available Lower flammability limit No information available Vapor pressure No information available Vapor density No information available Specific gravity No information available Water solubility No information available Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Explosive properties No information available Oxidizing properties No information available 10. STABILITY AND REACTIVITY _____________________________________________________________________________________________________________________
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