All M.A. Ford Cutting Tools Safety Data Sheet According to Federal Register / Vol
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All M.A. Ford Cutting Tools Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Revision Date: 04/28/2015 Date of issue: 04/28/2015 Version: 1.0 SECTION 1: IDENTIFICATION Product Identifier Product Name: All M.A. Ford Cutting Tools Article Exemption: This product meets the definition of an article under 29 CFR 1910.1200(c), which states: Article means a manufactured item other than a fluid or particle: (i) which is formed to a specific shape or design during manufacture; (ii) which has end use function(s) dependent in whole or in part upon its shape or design during end use; and (iii) which under normal conditions of use does not release more than very small quantities, e.g., minute or trace amounts of a hazardous chemical (as determined under paragraph (d) of this section), and does not pose a physical hazard or health risk to employees. Intended Use of the Product Industrial drilling and milling Name, Address, and Telephone of the Responsible Party Company M.A. Ford Manufacturing Co. Inc. 7737 Northwest Blvd Davenport, IA 52806 563.391.6220 www.maford.com Emergency Telephone Number Emergency Number : 800.553.8024 SECTION 2: HAZARDS IDENTIFICATION Classification of the Substance or Mixture Classification (GHS-US) Not classified Label Elements GHS-US Labeling No labeling applicable Other Hazards In this product's final form, it does not pose any hazard to health. However, when subject to sawing, brazing, grinding, etc., the following applies: Dust of the product, if generated, is very toxic to aquatic life with long lasting effects. When machined or physically altered material may produce dusts or ribbons that may be irritating or harmful. Inhalation of dusts and fumes can cause metal fume fever. Symptoms can include a metallic or sweet taste in the mouth, sweating, shivering, headache, throat irritation, fever, chills, thirstiness, muscle aches, nausea, vomiting, weakness, fatigue, and shortness of breath. Metallic dusts may ignite or explode. May cause allergic skin reactions in some individuals. Ingestion may cause metallic taste, abdominal pain, vomiting and diarrhea. May also cause hemolytic anemia, liver and kidney damage, and discoloration of the hair and skin. Wilson’s Disease, a genetic condition, may cause abnormally high absorption, retention and storage of copper by the body. This disease is progressive and fatal if untreated. Warning! Contains lead. Exposure to respirable dusts, fumes, or ingestion of powdered material may produce signs of polyneuritis, diminished vision, and peripheral neuropathy, such as tingling or loss of feeling in the fingers, arms and legs. May also cause anemia, irregular heart rhythm, and renal, brain and immune system damage. May cause adverse reproductive effects. Damages genetic material in mammalian test systems. Unknown Acute Toxicity (GHS-US) Not available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Mixture Name Product Identifier % (w/w) Classification (GHS-US) Tungsten carbide (CAS No) 12070-12-1 0 - 100 Not classified Iron (CAS No) 7439-89-6 0 - 99 Comb. Dust Flam. Sol. 1, H228 Self-heat. 1, H251 Titanium boride (TiB2) (CAS No) 12045-63-5 0 - 80 Comb. Dust Titanium carbide (TiC) (CAS No) 12070-08-5 0 - 70 Not classified Copper (CAS No) 7440-50-8 0 - 70 Aquatic Acute 1, H400 SDS NA 04/28/2015 EN (English US) 1/23 All M.A. Ford Cutting Tools Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Aquatic Chronic 2, H411 Silver (CAS No) 7440-22-4 0 - 70 Comb. Dust STOT SE 3, H335 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Tantalum carbide (TaC) (CAS No) 12070-06-3 0 - 52 Not classified Nickel (CAS No) 7440-02-0 0 - 37 Skin Sens. 1, H317 Carc. 2, H351 STOT RE 1, H372 Aquatic Acute 1, H400 Aquatic Chronic 3, H412 Niobium carbide (NbC) (CAS No) 12069-94-2 0 - 30 Flam. Sol. 1, H228 Cobalt (CAS No) 7440-48-4 0 - 30 Acute Tox. 4 (Oral), H302 Acute Tox. 1 (Inhalation:dust,mist), H330 Resp. Sens. 1B, H334 Skin Sens. 1, H317 Carc. 2, H351 Repr. 2, H361 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Titanium nitride (CAS No) 25583-20-4 0 - 30 Not classified Zinc (CAS No) 7440-66-6 0 - 30 Comb. Dust Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Chromium (CAS No) 7440-47-3 0 - 27 Comb. Dust Tungsten (CAS No) 7440-33-7 0 - 19 Flam. Sol. 1, H228 Self-heat. 2, H252 Vanadium (CAS No) 7440-62-2 0 - 18 Not classified Manganese (CAS No) 7439-96-5 0 - 13 Comb. Dust Molybdenum (CAS No) 7439-98-7 0 - 11 Comb. Dust Chromium carbide (Cr3C2) (CAS No) 12012-35-0 0 - 10 Not classified Hafnium carbide (HfC) (CAS No) 12069-85-1 0 - 10 Flam. Sol. 2, H228 Molybdenum carbide (Mo2C) (CAS No) 12069-89-5 0 - 10 Not classified Vanadium carbide (VC) (CAS No) 12070-10-9 0 - 10 Not classified Silicon (CAS No) 7440-21-3 0 - 5 Comb. Dust Aluminum nitride (AlN) (CAS No) 24304-00-5 0 - 5 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 STOT SE 3, H335 Carbon (CAS No) 7440-44-0 0 - 3.5 Comb. Dust Aluminum (CAS No) 7429-90-5 0 - 3 Comb. Dust Flam. Sol. 1, H228 Water-react. 2, H261 Niobium (CAS No) 7440-03-1 0 - 2.5 Flam. Sol. 1, H228 Selenium (CAS No) 7782-49-2 0 - 2 Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Inhalation:dust,mist), H331 STOT RE 2, H373 Aquatic Chronic 4, H413 Titanium (CAS No) 7440-32-6 0 - 1 Flam. Sol. 1, H228 Lead (CAS No) 7439-92-1 0 - 0.35 Carc. 1B, H350 Repr. 1A, H360 STOT RE 1, H372 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 04/28/2015 EN (English US) 2/23 All M.A. Ford Cutting Tools Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Sulfur (CAS No) 7704-34-9 0 - 0.35 Comb. Dust Skin Irrit. 2, H315 Aquatic Acute 3, H402 Phosphorus elemental (CAS No) 7723-14-0 0 - 0.15 Not classified Zinc oxide (CAS No) 1314-13-2 0 - 0.1 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Full text of H-phrases: see section 16 SECTION 4: FIRST AID MEASURES Description of First Aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). Inhalation: Using proper respiratory protection, move the exposed person to fresh air at once. Encourage exposed person to cough, spit out, and blow nose to remove dust. Immediately call a poison center, physician, or emergency medical service. Skin Contact: Remove contaminated clothing. Gently wash with plenty of soap and water. Obtain medical attention if irritation persists. Eye Contact: Rinse cautiously with water for at least 5 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if redness, pain, or irritation occurs. Ingestion: Rinse mouth. Do not induce vomiting. Call a physician or poison control center immediately. Most Important Symptoms and Effects Both Acute and Delayed General: Attention! - Contains lead. Inhalation of dusts and fumes can cause metal fume fever. Symptoms can include a metallic or sweet taste in the mouth, sweating, shivering, headache, throat irritation, fever, chills, thirstiness, muscle aches, nausea, vomiting, weakness, fatigue, and shortness of breath. Inhalation: Not expected to present a significant inhalation hazard under anticipated conditions of normal use. Inhalation of dusts and fumes can cause metal fume fever. Symptoms can include a metallic or sweet taste in the mouth, sweating, shivering, headache, throat irritation, fever, chills, thirstiness, muscle aches, nausea, vomiting, weakness, fatigue, and shortness of breath. Skin Contact: None expected under normal conditions of use. Eye Contact: None expected under normal conditions of use. Dusts caused from milling and physical alteration will likely cause eye irritation. Fumes from thermal decomposition or molten material will likely be irritating to the eyes. Ingestion: Ingestion is likely to be harmful or have adverse effects. Chronic Symptoms: Attention! - Contains lead. In massive form, no hazard exists. If physically altered to present slivers, ribbons, dusts or fumes from molten material: May cause cancer by inhalation. May damage fertility or the unborn child. Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned, get medical advice and attention. SECTION 5: FIRE-FIGHTING MEASURES Extinguishing Media Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire. Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire. Special Hazards Arising From the Substance or Mixture Fire Hazard: Not flammable. The following applies to the product if it is cut, sanded or altered in such a way that excessive and/or significant particulates and/or dusts may be generated: Metallic dusts may ignite or explode. Explosion Hazard: Product itself is not explosive but if dust is generated, dust clouds suspended in air can be explosive. Reactivity: Product is stable. Contact with concentrated acid or alkali can result in evolution of hydrogen gas. Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Firefighting Instructions: Use water spray or fog for cooling exposed containers. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Hazardous Combustion Products : Burning material releases heavy metal oxide fumes. Reference to Other Sections Refer to section 9 for flammability properties. 04/28/2015 EN (English US) 3/23 All M.A.