Tracing Silicate Weathering Processes in the Permafrost-Dominated Lena River Watershed Using Lithium Isotopes
Available online at www.sciencedirect.com ScienceDirect Geochimica et Cosmochimica Acta 245 (2019) 154–171 www.elsevier.com/locate/gca Tracing silicate weathering processes in the permafrost-dominated Lena River watershed using lithium isotopes Melissa J. Murphy a,⇑, Don Porcelli a, Philip A.E. Pogge von Strandmann b, Catherine A. Hirst c,d, Liselott Kutscher c,e, Joachim A. Katchinoff f, Carl-Magnus Mo¨rth e, Trofim Maximov g, Per S. Andersson c a Department of Earth Sciences, University of Oxford, South Parks Road, Oxford OX1 3AN, UK b London Geochemistry and Isotope Centre (LOGIC), Institute of Earth and Planetary Sciences, University College London and Birkbeck College, Gower Street, London WC1E 6BT, UK c Department of Geosciences, Swedish Museum of Natural History, Box 50007, SE-104 05 Stockholm, Sweden d Earth and Life Institute, Universite´ catholique de Louvain, Croix du Sud, L7.05.10, B-1348 Louvain-la-Neuve, Belgium e Department of Geological Sciences, Stockholm University, SE-10691 Stockholm, Sweden f Department of Geology & Geophysics, Yale University, USA g Institute for Biological Problems of the Cryolithozone, Siberian Branch, Russian Academy of Science, Russia Received 25 March 2018; accepted in revised form 19 October 2018; Available online 31 October 2018 Abstract Increasing global temperatures are causing widespread changes in the Arctic, including permafrost thawing and altered freshwater inputs and trace metal and carbon fluxes into the ocean and atmosphere. Changes in the permafrost active layer thickness can affect subsurface water flow-paths and water-rock interaction times, and hence weathering processes. Riverine lithium isotope ratios (reported as d7Li) are tracers of silicate weathering that are unaffected by biological uptake, redox, car- bonate weathering and primary lithology.
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