Magnetite in a Highly Magnesian Gangue, Originally Chlorite and Actinolite but Now Largely Altered to Talc
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Durham E-Theses The iron ore deposits of Ulu Rompin, Malaya Bean, J. H. How to cite: Bean, J. H. (1975) The iron ore deposits of Ulu Rompin, Malaya, Durham theses, Durham University. Available at Durham E-Theses Online: http://etheses.dur.ac.uk/8144/ Use policy The full-text may be used and/or reproduced, and given to third parties in any format or medium, without prior permission or charge, for personal research or study, educational, or not-for-prot purposes provided that: • a full bibliographic reference is made to the original source • a link is made to the metadata record in Durham E-Theses • the full-text is not changed in any way The full-text must not be sold in any format or medium without the formal permission of the copyright holders. Please consult the full Durham E-Theses policy for further details. Academic Support Oce, Durham University, University Oce, Old Elvet, Durham DH1 3HP e-mail: [email protected] Tel: +44 0191 334 6107 http://etheses.dur.ac.uk THE IRON ORE DEPOSITS OP ULU ROMPIN, MALAYA J.H. BEAN The copyright of this thesis rests with the author. No quotation from it should be published without his prior written consent and information derived from it should be acknowledged. being a Thesis submitted to the Faculty of Science, University of Durham for the fulfilment of.the Ph.D. degree. DURHAM, EMGLAND NOVEMBER, 1975. SCI£»C ABSTRACT The Ulu Rompin iron deposits axe located in an area of . ' rugged topography in the State of Pahang, Malaya. There are several high grade primary ore bodies and superficial sheets of lateritic ore. The area is underlain by sheared alkalio rhyolite lavas and tuffs in which there are small lenses of sedimentary rocks, carbonates being the most important. There are several small stocks of hornblende granodiorite which probably merge into one larger parental mass at depth. The Bt. Ibam ore body, which is the largest, is a tabular mass of magnetite in a highly magnesian gangue, originally chlorite and actinolite but now largely altered to talc. Underneath the ore there is a thin intermittent layer of calcic skarn, while massive chlorite appears along parts of the hangingwall. A short distance below the footwall there is granodiorite. The Bt. Batu Puteh deposit is magnetite associated with calcite marble, and at Bt, Hitaiii magnetite is found just above granodiorite. At Bt, Pesagi and Bt. Sanlong the primary ore is haematite with very little magnetite. These bodies are located in shear zones in the volcanic rocks, and are not associated with calcic or magnesian minerals. All the ore bodies and country rocks have been pyritized, and other sulphides and sulphosalts have impregnated the Bt. Ibam body. These have produced zones, contaminated by copper and zinc, and to a lesser degree bismuth and lead, Hypogene and supergene alteration have extensively affected the iron ores and rocks and caused some redistribution of the impurity elements. The iron ores probably originated in the cooling granodiorite magma and were transported as chlorides or chloride complexes. The control over the loci of mineralization was partly lithological - magnetite bodies in calcic and magnesian rocks, and partly structural - haematite bodies in shear zones. 11 ACKNOWLEDGEMENTS The writer is indebted to many people for assistance dtiring different stages of this study. To the directors of Rompin Mining Company for permission to study the deposits and the provision of accomodation at Bt. Ibam, and to the Mine Superintendent, Mr. D. Newiok, for help at the mine. The writer has held discussions with many of the company geologists over a period of several years, but is especially indebted to Mr. B.Mellor, Mr. D. Taylor, Mr. M. Muthu- ppalianappan and Mr. P. Muthuveerappan, Professor K.C. Dunham kindly siccepted the writer as a research student, and his successor. Professor G.M.Brown, continued this support. To Mr. R. Phillips, for help and guidance throughout the laboratory studies, the writer is especially grateful. Many colleagues at the University of Durham helped with various aspects of the work, but of particular assistance were Dr. E.H. Emelaus, Mr. G. Rowbotham, Dr. J.G. Holland, Dr. J. Aucott, Dr. Tarik Tugal aJid Mr. M, George. The laboratory technical staff had to cope with a large quantity of material which was highly decomposed and very difficult 'to prepare, and to all of them the writer expresses his gratitude. iii TABLE OF CONTENTS Page. ABSTRACT i ACKNOWLEDGEMMTS ii LIST OP FIGURES ix LIST OP TABLES xiii I INTRODUCTION Location of Area and Access 1 Physiography 3 History of the Ore Deposits 5 Purpose of Present Study 7 GEOLOGY OF ULU ROMPIN II REGIONAL GEOLOGY AND STRATIGRAPHY Regional Geological Environment 9 Previous Geological Studies .. .. .. 13 Stratigraphy of the Mineralized Zone 14 III ACID VOLCANIC ROCKS Introduction .. .. .. .. I7 Classification I9 Petrography .. .. 21 Quartz 22 Feldspars 26 Mica and Chlorite 26 Clay 27 Accessory Minerals 27 Groundmass 28 Lithic Fragments 28 Veins 28 Diffraction Studies 30 Chemical Analyses 30 Metamorphism of Volcanic Rocks 40 IV SEDIMENTARY ROCKS AND SKARNS Introduction 41 Arenaceous Rocks 41 Marble 43 SKARNS Introduction 44 IV Petrography 44 Epidote 46 Garnet 48 Amphibole ^0 Mica 50 Pyroxene ^^ Quartz and Carbonate 51 Chlorite 5I Chemical Composition and Origin 5I INTRUSIVE IGl^TEOUS ROCKS Introduction 54 Petrography 56 Plagioclase 57 Potash Feldspar 58 Quartz 60 Biotite 60 Chlorite 61 Hornblende 61 Accessory Minerals 62 Minor Intrusion .. 62 Chemical Composition 63 Stocks and Aeromagnetic Maps 63 VI STRUCTURAL GEOLOGY Introduction . 66 Primary Bedding 66 Foliation 67 Folding 69 Jointing 70 Faulting 72 IRON ORE DEPOSITS VII GENERAL DESCRIPTION Distribution of the Deposits 77 Regional Pattern of Mineralization 80 VIII BUKIT IBAM ORE BODY Surface Features . .. 82 Prospecting 84 Shape of the Ore Body 85 Dimensions of the Mineralized Body 85 Types of Iron Ore and their Distribution 88 IX MINERALOGY OF BUKIT IBAM. (l) IRON MINERALS Introduction 96 Magnetite 96 Macroscopic Features 96 Microscopic Features 101 Polish 101 Parting 101 Colour 103 Crystal Shape 103 Zoning 107 Texture 109 Age 111 Magnetite After Haematite , .111 Diffraction Pattern of Magnetite 114 Oxidation and Hydration of Magnetite 114 Haematite 123 Veinlets and Replaxsements .. .. 124 Martite 127 Haematite with Colloform Goethite 128 Micaceous Haematite .. 129 Diffraction Patterns for Haematite 131 Maghemite 131 Goethite 139 X MINERALOGY OF BUKIT IBAM. (2) PYRITE AND CUPRIFEROUS MINERALS Pyrite 144 Microscopic Properties 144 Pyrite in Massive Iron Ore 147 Pyrite in Gangue and Low Grade Ore 147 Pyrite in Skarn ; 149 Pyrite in Wall Rock 15° Alteration of Pyrite 150 Diffraction Pattern of Pyrite 151 Chalcopyrite 154 Bornite 158 Chaloocite-Neodigenite-Djurleite 158 VI Covellite 166 Cuprite 166 Cuprite-Native Copper I67 Cuprite-Pyrite-Secondary Copper Sulphides .. .. I67 Copper 169 Malachite and Azurite ..' I7I Chalcanthite 171 XI MINERALOGY OF BUKIT IBAM. (3) MINERALS OP ZINC, BISMUTH & LEAD Sphalerite 173 Bismuthinite .. .. I76 Tetradymite 179 Bismutoferrite 179 Galena I85 XII MINERALOGY OF BUKIT lEAM. (4) OTHER ORE MINERALS Tennantite I87 Molybdenite I87 Arsenopyrite I89 Pyrrhotite I89 Gold-Electrum I89 Mixed Manganese Oxides I89 Manganese Oxides in Veins .. .. 191 Chalcophanite 192 Strontiobarytes 192 Siderite .. 194 Chemical Composition 197 Diffraction Pattern I98 XIII MINERALOGY OP BUKIT IBAM. (5) GANGUE MINERALS Introduction 202 Contacts 202 Act indite 205 Chlorite 206 Talc 208 Antigorite 210 Hontronite 211 Kaolinite 211 VI1 Quartz 212 Calcite 213 Blue Mineral Along Footwall .. 213 XIV GEOCHEMISTRY OF THE HJKIT IBAM DEPOSIT Introduction 218 Bulk Composition of the Iron Ore .. .. 219 Minor Elements in Ores and Rocks Magnetite 223 Goethite 228 Pyrite 230 Acid Volcanic Rocks 234 Skarn Rocks 238 Plutonic Rocks 239 Gangue Minerals 240 Distribution of Iron and Trace Elements Iron 240 Copper and Zinc 247 Bismuth 259 Lead 260 Arsenic .. • . • . • 261 Miscellaneous Metallic Elements* 262 Non-Metallic Elements 263 XV THE DEPOSITS AT BUKIT PESAGI AND BUKIT SANLONG Introduction 266 Country Rocks .. .. .. 266 Ore Deposits General Description 267 Primary Ore Bodies 267 Mineralogy 27I Secondary Ore Bodies 280 Geochemistry (I) Iron Ores 281 Geochemistry (2) Coimtry Rocks .. .. 285 XVI THE BUKIT HITAM DEPOSIT The Bukit Hitam Deposit .. 289 Geochemistry • 293 Vlll XVII THE BUKIT BATU PUTEH DEPOSIT The Bukit Batu Puteh Deposit 297 Geochemistry 299 XVIII BUKIT SANAM AND OTHER MINOR DEPOSITS Bukit Sanam 301 Other Minor Deposits 301 XIX GENESIS OP THE ULU ROMPIN ORE DEPOSITS Introduction .. .. .. .. .. ., .. 303 Geological Environment Before Mineralization .. .. 303 The Bukit Ibam Ore Body Previous Interpretations 304 Background Details 308 Source of the Magnesia 310 Formation of the Skarns and Magnesian Rocks and Facies of Metamorphism . .. 313 Iron Oxide Mineralization 318 SixLphide Mineralization 326 Transfer of Materials 327 Physical Conditions During Metamorphism and Metasomatism 329 Late-Stage Mineralization .. 336 Hydrothermal Alteration .. .. 337 Supergene Alteration 339 The Bukit Pesagi and Bukit Sanlong Ore Bodies . .. 344 The Bukit Hitam Ore Body ..... .. 347 The Bukit Batu Put eh Ore Body 348 The Bukit Sanara and Other Minor Deposits 348 XX ORIGIN AND TRANSPORT OF THE IRON Source of the Iron 350 Transport of the Iron 352 XXI MINING METHODS AND QUALITY CONTROL Mining Methods 355 Treatment Plant 356 Transportation 356 Quality Control 356 REFERENCES 358 IX LIST OP FIGURES Figure. 1. Location Map 2 2, Topography of Ulu Rompin Area 4 3, Geological Sketch Map of Southeast Pahang lO/ll 4. Part of the Bt. Ibam Ore Body 18 5- An Example of "Pseudo Agglomerate" 18 6. Phenocryst of ^Q\iartz 23 7. Corroded Quartz Phenocryst .. .. .. 23 8. Rhombohedral Parting in Quartz .. .. 24 9. Recrystaliized Quartz Phenocryst ,. .. .. .. .. 24 10. Reaction Zone Between Quartz and Groundmass ,, ., 25 11. Detail of Pig, 10 25 12. Crystallo-Lithic Tuff 29 13. Normative Feldspar in the Volcanic Rocks 35 14. Triangular Diagram for the Volcanic Rocks 39 15.