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PURATREM™ - High Purity Inorganics The Strem Product Line OUR LINE OF RESEARCH CHEMICALS Custom Synthesis Biocatalysts & Organocatalysts Electronic Grade Chemicals FDA Inspected Fullerenes High Purity Inorganics & Alkali Metals cGMP Facilities Ionic Liquids Ligands & Chiral Ligands Drug Master Files Metal Acetates & Carbonates Metal Alkoxides & beta-Diketonates Complete Documentation Metal Alkyls & Alkylamides Metal Carbonyls & Derivatives Metal Catalysts & Chiral Catalysts Metal Foils, Wires, Powders & Elements Metal Halides, Hydrides & Deuterides Metal Oxides, Nitrates, Chalcogenides Metal Scavengers Metallocenes Nanomaterials Organofluorines Organometallics Organophosphines & Arsines Porphines & Phthalocyanines Precious Metal & Rare Earth Chemicals Volatile Precursors for MOCVD, CVD & ALD Strem Chemicals, Inc. Strem Chemicals, Inc. 7 Mulliken Way 15, rue de l’Atome Dexter Industrial Park Zone Industrielle Newburyport, MA 01950-4098 67800 BISCHHEIM (France) U.S.A. Tel.: (33) 03 88 62 52 60 Fax: (33) 03 88 62 26 81 Office Tel: (978) 499-1600 Email: [email protected] Office Fax: (978) 465-3104 Toll-free Orders Tel.: (800) 647-8736 Strem Chemicals, Inc. Fax: (800) 517-8736 Postfach 1215 (U.S. & Canada only) D-77672 KEHL, Germany Tel.: +49 (0) 7851 75879 Email: [email protected] Fax: +33 (0) 3 88 62 26 81 www.strem.com Email: [email protected] Strem Chemicals UK Ltd. An Independent Distributor of Strem Chemicals products Newton Hall, Town Street Newton, Cambridge, CB22 7ZE, UK Tel.: 0845 643 7263 Fax: 0845 643 7362 Email: [email protected] PURA © 2014 Strem Chemicals, Inc. PURATREM™ - High Purity Inorganics For 50 years, Strem Chemicals, Inc. has been providing fine chemicals for research as well as for commercial production. For many years we have offered high purity inorganics and in 1988 officially launched the “PURATREM” line. These products have a minimum purity of 99.99% (metals basis) and are presented in this booklet. They also appear in our catalog and on our web site. Please also see some of our other booklets: Metal Catalysts for Organic Synthesis, including Organocatalysts: Strem stocks a broad range of homogeneous catalysts. These are featured with technical notes and up-to-date references. Many provide pathways to chiral products and are available in multi-kg quantities. Heterogeneous Catalysts: Strem offers a variety of heterogeneous catalysts, many manufactured at commercial scale. Phosphorus Ligands and Compounds: Strem carries an extensive line. Other Ligands: Strem also offers Carbon, Nitrogen, Oxygen, Arsenic and Sulfur ligands. MOCVD, CVD and ALD Precursors: Strem has a wide range of precursors for MOCVD, CVD and ALD as well as a line of electropolished stainless steel bubblers and NEW ALD cylinders. Kits: This booklet lists a variety of products grouped into kits. New Products: Products introduced after our last printed catalog appear in this booklet as well as on our web site. Nanomaterials: Metal-based nanoproducts, carbon nanotubes, cones, fibers and arrays, magnetic fluids and more are listed. Materials for Energy Applications: Many products for Photovoltaics, Fuel Cells, LED/Quantum Dots, Energy Storage, Hydrogen Storage, Metal Organic Frameworks. Buchwald Ligands and Precatalysts: Strem has provided the widest range of Buchwald ligands and precatalysts available for over 15 years. Custom Synthesis: We provide custom synthesis services to academic and government institutions, as well as some of the world’s leading corporations under the strictest confidence. cGMP: Our FDA inspected current Good Manufacturing Practices facilities are also available for pharmaceutical applications. We have regulatory filings in over 20 countries. • FDA Inspected • Drug Master Files • cGMP Facilities • Complete Documentation strem.com: Visit our web site for product availability, technical notes, (M)SDS sheets and certificates of analysis. Pura10/14 Ephraim S. Honig, Ph.D., M.B.A. ©2014 Strem Chemicals, Inc. Chief Operating Officer PURATREM™ - ALUMINUM (Compounds) 13-0050 Aluminum chloride, anhydrous (99.99+%-Al) PURATREM 50g HAZ [7446-70-0] 250g AlCl3; FW: 133.34; -20 mesh white to yellow pwdr.; m.p. 190°; b.p. 180° subl.; d. 2.44 moisture sensitive 13-1309 Aluminum chloride hexahydrate (99.999%-Al) PURATREM 25g HAZ [7784-13-6] 100g AlCl3·6H2O; FW: 133.34 (241.43); white xtl.; m.p. 100° dec.; d. 2.398 hygroscopic 13-1310 Aluminum chloride hexahydrate (99.9995%-Al) PURATREM 25g HAZ [7784-13-6] 100g AlCl3·6H2O; FW: 133.34 (241.43); white xtl.; m.p. 100° dec.; d. 2.398 hygroscopic 13-1300 Aluminum oxide (99.999%-Al) PURATREM [1344-28-1] 10g Al2O3; FW: 101.96; white pwdr.; b.p. 2980°; d. 3.97 50g 97-0139 Aluminum i-propoxide (99.99+%-Al) PURATREM [555-31-7] 25g HAZ Al[(OCH(CH3)2]3; FW: 204.25; white pwdr.; m.p. 118.5°; 100g b.p. 140.5°/8 mm; d. 1.0346 moisture sensitive 13-1600 Dimethylaluminum i-propoxide, 98% (99.99+%-Al) PURATREM 1g HAZ [6063-89-4] 5g (CH3)2Al(OC3H7); FW: 116.14; colorless liq.; d. 0.824 air sensitive, moisture sensitive Technical Note: 1. Useful starting material for the atomic layer deposition of Al2O3 films. Reference: 1. J. Vac. Sci. Tech. A., 2003, 21, 1366. 98-1855 Triethylaluminum, elec. gr. (99.999+%-Al) PURATREM [97-93-8] 100g HAZ (C2H5)3Al; FW: 114.17; colorless liq.; m.p. -52.5°; b.p. 186°; f.p. -1°F; d. 0.835 moisture sensitive, pyrophoric S. Steel bubbler extra 98-1955 Trimethylaluminum, elec. gr. (99.999+%-Al) PURATREM [75-24-1] 25g HAZ (CH3)3Al; FW: 72.09; colorless liq.; m.p. 15.4°; b.p. 20°/8 mm; 100g f.p. 1.4°F; d. 0.752 (20°) 200g moisture sensitive, pyrophoric S. Steel bubbler extra 98-4008 Trimethylaluminum, elec. gr. (99.999+%-Al) PURATREM, 98-1955, 25g HAZ contained in 50 ml Swagelok® cylinder (96-1070) for CVD/ALD [75-24-1] (CH3)3Al; FW: 72.09; colorless liq.; m.p. 15.4°; b.p. 20°/8 mm; f.p. 1.4°F; d. 0.752 (20°) moisture sensitive, pyrophoric 98-4007 Trimethylaluminum, elec. gr. (99.999+%-Al) PURATREM, 98-1955, 25g HAZ contained in 50 ml electropolished Swagelok® cylinder (96-1077) for CVD/ALD [75-24-1] (CH3)3Al; FW: 72.09; colorless liq.; m.p. 15.4°; b.p. 20°/8mm; f.p. 1.4°F; d. 0.752 (20°) moisture sensitive, pyrophoric PURATREM™ - AMMONIUM (Compounds) 93-0242 Ammonium chloride (99.999%) PURATREM [12125-02-9] 25g NH4Cl; FW: 53.49; white xtl.; m.p. 340° subl.; b.p. 520°; d. 1.527 100g 02-0500 Ammonium dihydrogen phosphate (99.998%) PURATREM 10g [7722-76-1] 50g NH4H2PO4; FW: 115.03; white xtl.; m.p. 190°; d. 1.803 02-0590 Ammonium hexachlororhodate(III) monohydrate (99.995%-Rh) 1g PURATREM [15336-18-2] 5g (NH4)3RhCl6·H2O; FW: 369.74 (387.76); red xtl. hygroscopic 93-0214 Ammonium iodide (99.999%) PURATREM [12027-06-4] 5g NH4I; FW: 144.94; white xtl.; m.p. 551° subl.; d. 2.514 25g 02-0700 Ammonium metavanadate (99.995%-V) PURATREM [7803-55-6] 5g HAZ NH4VO3; FW: 116.98; white pwdr.; m.p. 200° dec.; d. 2.33 [email protected] · [email protected] · [email protected] · [email protected] 1 PURATREM™ - AMMONIUM (Compounds) 02-0750 Ammonium molybdate tetrahydrate (99.999%-Mo) PURATREM 5g [12027-67-7] 25g (NH4)6Mo7O24·4H2O; FW: 1163.80 (1235.86); white xtl.; d. 2.498 02-0900 Ammonium perrhenate (99.999%-Re) PURATREM [13598-65-7] 1g HAZ NH4ReO4; FW: 268.24; white pwdr.; m.p. dec.; d. 3.97 5g 02-1000 Ammonium tetrachloroaurate(III) hydrate (99.9985%-Au) 1g PURATREM [13874-04-9] 5g NH4AuCl4·XH2O; FW: 356.82; yellow xtl. 02-1275 Ammonium tetrachloropalladate(II) (99.998%-Pd) PURATREM 1g [13820-40-1] 5g (NH4)2PdCl4; FW: 284.29; red to brown pwdr.; m.p. dec.; d. 2.17 42-1000 Ammonium tetrathiomolybdate(VI), 99% (99.99%-Mo) PURATREM 5g [15060-55-6] 25g (NH4)2MoS4; FW: 260.27; red-green xtl. 93-0250 Ammonium tungstate pentahydrate (99.996%-W) PURATREM 10g [1311-93-9] 50g (NH4)10W12O41·5H2O; FW: 3042.56 (3132.63); white xtl. PURATREM™ - ANTIMONY (Compounds) 97-0373 Antimony(III) chloride, elec. gr. (99.999%-Sb) PURATREM 5g amp [10025-91-9] 25g HAZ SbCl3; FW: 228.11; off-white xtl.; m.p. 73.4°; b.p. 283°; d. 3.140 moisture sensitive 51-2200 Antimony(V) chloride, (99.999%-Sb) PURATREM [7647-18-9] 5g amp SbCl5; FW: 299.02; yellow liq.; m.p. 2.8°; b.p. 79°/22mm; d. 2.336 25g HAZ moisture sensitive 97-0380 Antimony(III) oxide, elec. gr. (99.999%-Sb) PURATREM 25g HAZ [1309-64-4] 100g Sb2O3; FW: 291.50; white pwdr.; m.p. 656°; b.p. 1550° subl.; d. 5.67 51-5110 Antimony(IV) oxide (99.99%-Sb) PURATREM [1332-81-6] 5g HAZ Sb2O4; FW: 307.50; white to off-white pwdr.; d. 5.82 25g 97-0382 Antimony(V) oxide, elec. gr. (99.998%-Sb) PURATREM 5g HAZ [1314-60-9] 25g Sb2O5; FW: 323.50; white to light yellow pwdr.; d. 3.80 100g 93-5120 Antimony(III) sulfide (99.999%-Sb) PURATREM [1345-04-6] 10g HAZ Sb2S3; FW: 339.68; black pwdr.; m.p. 550°; b.p. ~1150°; d. 4.12 50g 51-5000 Tris(dimethylamino)antimony (99.99%-Sb) PURATREM 1g HAZ [7289-92-1] 5g ((CH3)2N)3Sb; FW: 253.99; colorless liq.; b.p. 32-34°/0.45mm; d. 1.325 25g air sensitive, moisture sensitive PURATREM™ - ARSENIC (Compounds) 93-3309 Arsenic(III) chloride (99.999%-As) PURATREM [7784-34-1] 5g amp AsCl3; FW: 181.27; colorless liq.; m.p. -8.5°; b.p. 130.2°; d. 2.163 25g HAZ moisture sensitive 100g 97-0425 Arsenic(III) oxide, elec. gr. (99.999%-As) PURATREM [1327-53-3] 5g HAZ As2O3; FW: 197.84; white pwdr.; m.p.
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