AP Chemistry Summer Assignment 2021
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Cool Reaction the Endothermic Reaction Between SCIENTIFIC Barium Hydroxide and Ammonium Thiocyanate
Cool Reaction The Endothermic Reaction Between SCIENTIFIC Barium Hydroxide and Ammonium Thiocyanate Introduction Many reactions produce heat, in fact when people think of chemical reactions, heat production is often expected. However, endothermic reactions, reactions which consume heat, can be just as exciting. One of the most striking examples of this is when the solids barium hydroxide and ammonium thiocyanate are mixed together in a beaker. Materials Ammonium thiocyanate, NH4SCN, 10 g Stirring rod Barium hydroxide octahydrate, Ba(OH)28H2O, 20 g Thermometer graduated to at least –30 °C Erlenmeyer flask, small, with stopper, or a 50-mL beaker Safety Precautions Barium salts are toxic by ingestion. Ammonium thiocyanate is also toxic by ingestion. Use caution when handling the beaker or flask. Use tongs if available. The temperatures involved are cold enough to freeze skin. Ammonia vapor is very irritating to eyes and the respiratory tract. Do not allow students to inhale this gas. Wear chemical splash goggles, chemical-resistant gloves, and a chemical-resistant apron. Please review current Material Safety Data Sheets for additional safety, handling, and disposal information. Procedure 1. Transfer 20 g of barium hydroxide and 10 g of ammonium thiocyanate to a flask and mix with a glass or plastic stirring rod. 2. In less than two minutes the solids become liquid. A thermometer placed in the mixture shows the temperature falling far below freezing. An ammonia odor is evident to all who are near the flask. 3. Place the flask in a small puddle of water and your students will clearly see just how cool this reaction is; the water will freeze the flask to the counter top. -
Writing Total and Net Ionic Equations
WRITING TOTAL AND NET IONIC EQUATIONS http://www.csun.edu/~hcchm001/FreshChemHandouts.html 1. Write the overall equation including the correct designations for the physical state of the substances (s, l, g, aq). Balance this equation. Most of these kinds of equations are double displacement reactions: AX + BY 6 AY + BX 2. For the total ionic equations, write strong electrolytes in solution in the form of aqueous ions. (a) Strong acids. The common strong acids and their aqueous ions are: HI Hydroiodic acid H+-(aq) + I (aq) HBr Hydrobromic acid H+-(aq) + Br (aq) HCl Hydrochloric acid H+-(aq) + Cl (aq) +- HNO33Nitric acid H (aq) + NO (aq) +- HClO44Perchloric acid H (aq) + ClO (aq) +-2 H24SO Sulfuric acid 2 H (aq) + SO4(aq) (b) Strong bases. Strong bases are the hydroxides of the alkali (Group IA) and alkaline earth (Group IIA) metals ions which are sufficiently soluble. The common strong bases and their aqueous ions are: LiOH Lithium hydroxide Li+-(aq) + OH (aq) NaOH Sodium hydroxide Na+-(aq) + OH (aq) KOH Potassium hydroxide K+-(aq) + OH (aq) +2 - Sr(OH)2Strontium hydroxide Sr (aq) + 2 OH (aq) +2 - Ba(OH)2 Barium hydroxide Ba (aq) + 2 OH (aq) (c) Soluble salts. Determinations of the solubility of a salt may be made by reference to SOLUBILITIES OF IONIC COMPOUNDS. Soluble salts are written as their aqueous ions: NaCl(aq) Sodium chloride Na+-(aq) + Cl (aq) +-2 K24SO (aq) Potassium sulfate 2 K (aq) + SO4(aq) +-2 Li23CO (aq) Lithium carbonate 2 Li (aq) + CO3(aq) +-3 Na34PO (aq) Sodium phosphate 3 Na (aq) + PO4(aq) +-2 (NH42) SO4(aq) Ammonium sulfate 2 NH4(aq) + SO4 (aq) 3. -
Acetal (POM) Chemical Compatibility Chart From
ver 31-Mar-2020 Acetal (POM) Chemical Compatibility Chart Chemical Chemical Acetaldehyde A Ammonium Acetate C Acetamide A Ammonium Bifluoride D Acetate Solvents A Ammonium Carbonate D Acetic Acid D Ammonium Caseinate D Acetic Acid, 20% C Ammonium Chloride, 10% B Acetic Acid, 80% D Ammonium Hydroxide D Acetic Acid, Glacial D Ammonium Nitrate, 10% A Acetic Anhydride D Ammonium Oxalate B Acetone A Ammonium Persulfate D Acetyl Chloride, dry D Ammonium Phosphate, Dibasic B Acetylene A Ammonium Phosphate, Monobasic B Alcohols: Amyl A Ammonium Phosphate, Tribasic B Alcohols: Benzyl A Ammonium Sulfate B Alcohols: Butyl A Ammonium Sulfite D Alcohols: Diacetone A Ammonium Thiosulfate B Alcohols: Ethyl A Amyl Acetate B Alcohols: Hexyl A Amyl Alcohol A Alcohols: Isobutyl A Amyl Chloride A Alcohols: Isopropyl A Aniline A Alcohols: Methyl A Aniline Oil D Alcohols: Octyl A Anise Oil D Alcohols: Propyl (1-Propanol) A Antifreeze D Aluminum chloride, 20% C Aqua Regia (80% HCl, 20% HNO3) D Aluminum Fluoride C Aromatic Hydrocarbons A Aluminum Hydroxide A Arsenic Acid D Aluminum Nitrate B Asphalt B Aluminum Potassium Sulfate, 10% C Barium Carbonate A Aluminum Potassium Sulfate, 100% C Barium Chloride A Aluminum Sulfate, 10% B Barium Cyanide B Alums C Barium Hydroxide D Amines D Barium Nitrate B Ammonia, 10% (Ammonium Hydroxide) C Barium Sulfate B Ammonia, 10% D Barium Sulfide A Ammonia, anhydrous D Bay Oil D Ammonia, liquid D Beer A Ammonia Nitrate C Beet Sugar Liquids B Key to General Chemical Resistance – All data is based on ambient or room temperature conditions, about 64°F (18°C) to 73°F (23°C) A = Excellent C = Fair - Moderate Effect, not recommended B= Good - Minor Effect, slight corrosion or discoloration D = Severe Effect, not recommended for ANY use It is the sole responsibility of the system designer and user to select products suitable for their specific application requirements and to ensure proper installation, operation, and maintenance of these products. -
Introduetion
THE CONCENTFL4TION OF RADIUM AND MESO- THORIUM BY FRACTIONAL CRYSTALLIZATION* BY JOHN I,. NIERMAN Introduetion MarkwaldlO and Soddyl' have shown independently that mesothorium is absolutely identical in chemical nature with radium and cannot be separated therefrom.** In consequence all radium separated from uranium minerals containing thorium, contains also the mesothorium in the mineral, and all preparations of mesothorium contain the radium that is present in the mineral from which the thorium is derived. In the extraction and recovery of the minute quantities of mesothorium and radium present in radioactive minerals, these elements become associated with barium and follow the barium throughout the process. The refining of mesothorium and radium then consists in separating these elements from barium, the method generally followed being fractional crystallization of the barium solution, first as chloride, and later as bromide. The mesothorium and radium continue to be enriched in the crystal fractions, and reduced in the succes- sive mother liquors. t In practice, l2 a fair concentration of acid is maintained throughout the chloride and bromide systems, for the reason ' that the factor of enrichment of mesothorium radium chloride from barium chloride and also of mesothorium radium bromide from barium bromide is regarded as more favorable in acid than in neutral solutions. While it has been shown3 that the crystallization factor is higher for bromides than for chlorides, the effect of the acidity of the solutions on the progress of * Abstract of a thesis submitted in partial fulfilment of the requirements for the degree of Master of Arts in the Graduate, School of the University of Missouri, August, 1919. -
Mccord (Pmccord) – HW6 Acids, Bases and Salts – Mccord – (51520) 1 This Print-Out Should Have 45 Questions
mccord (pmccord) – HW6 Acids, Bases and Salts – mccord – (51520) 1 This print-out should have 45 questions. 6. The term is misleading, because the am- Multiple-choice questions may continue on monium ion is not an acid. the next column or page – find all choices Explanation: before answering. 003 10.0 points 001 10.0 points −9 If the value of Kb for pyridine is 1.8 × 10 , Assume that five weak acids, identified only calculate the equilibrium constant for by numbers (1, 2, 3, 4, and 5), have the + C5H5NH (aq)+ H2O(ℓ) → following ionization constants. + C5H5N(aq) + H3O (aq) . − Ionization 1. 5.6 × 10 6 correct Acid Constant − Ka value 2. 1.8 × 10 9 − 1 1.0 × 10 3 − × −16 2 3.0 × 10 5 3. 1.8 10 − 3 2.6 × 10 7 − × 8 4 4.0 × 10 9 4. 5.6 10 −11 5 7.3 × 10 − 5. −1.8 × 10 9 The anion of which acid is the strongest Explanation: base? 004 10.0 points 1. 4 Which of the following is true in pure water at any temperature? 2. 5 correct 1. Kw decreases with increasing tempera- 3. 2 ture. + − −14 4. 3 2. [H3O ][OH ] = 1.0 × 10 + − 5. 1 3. [H3O ] = [OH ] correct Explanation: 4. pH = 7.0 or greater than 7.0 002 10.0 points 5. pH = 7.0 The term “Ka for the ammonium ion” de- scribes the equilibrium constant for which of Explanation: the following reactions? Kw is shown to INCREASE with increas- ing temperature. pH = 7 is only true when + ⇀ + ◦ + − 1. -
Effects of Intravenous Injections of Radium Bromide. by R
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by PubMed Central EFFECTS OF INTRAVENOUS INJECTIONS OF RADIUM BROMIDE. BY R. BURTON-OPITZ AND GUSTAVE M. MEYER. (From the Laboratories of Physiology and Physiological Chemistry of Colum- bia University, at the College of Physicians and Surgeons, New York.) PLATE XVI. The present study was undertaken with a view of determining in a general way the effects of intravenous administration of ra- dium upon the circulation and respiration. The problem was sug- gested to us by Dr. William J. Gies, under whose guidance a number of researches, dealing with the more extensive question of the action of radium upon animal and vegetable cells, have re- cently been carried on in the laboratories of Columbia University.1 For the radium used in these experiments we are greatly in- debted to Mr. Hugo Lieber. It was supplied to us in the form of the bromide, in preparations of 240 , iooo, and io,ooo activities. The strength of the solution used was the same in all cases. It contained 45 rag. of the dry substance in 25 c. c. of the solvent; each cubic centimeter of the solution, therefore, contained 1.8 rag. of the radium preparation. The amount of the radium present varies directly with the ra- dio-activity. Preparations of ~,5oo,ooo activity are said to repre- sent pure radium bromide3 Taking this figure as the standard of purity, ~ .8 rag. of the radium preparation of io,ooo activity contained approximately only o.o~ 26 mg., the same quantity of the preparation of ~ooo activity contained o.ooi26 rag. -
Hemoglobin, Myoglobin and Neuroglobin in Endogenous Thiosulfate Production Processes
International Journal of Molecular Sciences Review The Role of Hemoproteins: Hemoglobin, Myoglobin and Neuroglobin in Endogenous Thiosulfate Production Processes Anna Bilska-Wilkosz *, Małgorzata Iciek, Magdalena Górny and Danuta Kowalczyk-Pachel Chair of Medical Biochemistry, Jagiellonian University Collegium Medicum ,7 Kopernika Street, Kraków 31-034, Poland; [email protected] (M.I.); [email protected] (M.G.); [email protected] (D.K.-P.) * Correspondence: [email protected]; Tel.: +48-12-4227-400; Fax: +48-12-4223-272 Received: 5 May 2017; Accepted: 16 June 2017; Published: 20 June 2017 Abstract: Thiosulfate formation and biodegradation processes link aerobic and anaerobic metabolism of cysteine. In these reactions, sulfite formed from thiosulfate is oxidized to sulfate while hydrogen sulfide is transformed into thiosulfate. These processes occurring mostly in mitochondria are described as a canonical hydrogen sulfide oxidation pathway. In this review, we discuss the current state of knowledge on the interactions between hydrogen sulfide and hemoglobin, myoglobin and neuroglobin and postulate that thiosulfate is a metabolically important product of this processes. Hydrogen sulfide oxidation by ferric hemoglobin, myoglobin and neuroglobin has been defined as a non-canonical hydrogen sulfide oxidation pathway. Until recently, it appeared that the goal of thiosulfate production was to delay irreversible oxidation of hydrogen sulfide to sulfate excreted in urine; while thiosulfate itself was only an intermediate, transient metabolite on the hydrogen sulfide oxidation pathway. In the light of data presented in this paper, it seems that thiosulfate is a molecule that plays a prominent role in the human body. Thus, we hope that all these findings will encourage further studies on the role of hemoproteins in the formation of this undoubtedly fascinating molecule and on the mechanisms responsible for its biological activity in the human body. -
APPENDIX G Acid Dissociation Constants
harxxxxx_App-G.qxd 3/8/10 1:34 PM Page AP11 APPENDIX G Acid Dissociation Constants § ϭ 0.1 M 0 ؍ (Ionic strength ( † ‡ † Name Structure* pKa Ka pKa ϫ Ϫ5 Acetic acid CH3CO2H 4.756 1.75 10 4.56 (ethanoic acid) N ϩ H3 ϫ Ϫ3 Alanine CHCH3 2.344 (CO2H) 4.53 10 2.33 ϫ Ϫ10 9.868 (NH3) 1.36 10 9.71 CO2H ϩ Ϫ5 Aminobenzene NH3 4.601 2.51 ϫ 10 4.64 (aniline) ϪO SNϩ Ϫ4 4-Aminobenzenesulfonic acid 3 H3 3.232 5.86 ϫ 10 3.01 (sulfanilic acid) ϩ NH3 ϫ Ϫ3 2-Aminobenzoic acid 2.08 (CO2H) 8.3 10 2.01 ϫ Ϫ5 (anthranilic acid) 4.96 (NH3) 1.10 10 4.78 CO2H ϩ 2-Aminoethanethiol HSCH2CH2NH3 —— 8.21 (SH) (2-mercaptoethylamine) —— 10.73 (NH3) ϩ ϫ Ϫ10 2-Aminoethanol HOCH2CH2NH3 9.498 3.18 10 9.52 (ethanolamine) O H ϫ Ϫ5 4.70 (NH3) (20°) 2.0 10 4.74 2-Aminophenol Ϫ 9.97 (OH) (20°) 1.05 ϫ 10 10 9.87 ϩ NH3 ϩ ϫ Ϫ10 Ammonia NH4 9.245 5.69 10 9.26 N ϩ H3 N ϩ H2 ϫ Ϫ2 1.823 (CO2H) 1.50 10 2.03 CHCH CH CH NHC ϫ Ϫ9 Arginine 2 2 2 8.991 (NH3) 1.02 10 9.00 NH —— (NH2) —— (12.1) CO2H 2 O Ϫ 2.24 5.8 ϫ 10 3 2.15 Ϫ Arsenic acid HO As OH 6.96 1.10 ϫ 10 7 6.65 Ϫ (hydrogen arsenate) (11.50) 3.2 ϫ 10 12 (11.18) OH ϫ Ϫ10 Arsenious acid As(OH)3 9.29 5.1 10 9.14 (hydrogen arsenite) N ϩ O H3 Asparagine CHCH2CNH2 —— —— 2.16 (CO2H) —— —— 8.73 (NH3) CO2H *Each acid is written in its protonated form. -
United States Patent (19) 11) 4,078,045 Nakayama Et Al
United States Patent (19) 11) 4,078,045 Nakayama et al. 45) Mar. 7, 1978 (54) PROCESS FOR PRODUCING CARBONYL (56) References Cited SULFIDE U.S. PATENT DOCUMENTS (75) Inventors: Yoshiki Nakayama, Shimizu; Hironobu Sano, Fuji; Sataro 2,992,897 7/1961 Applegathet al................... 423/416 Okamura; Kazunari Hirao, both of 3,764,661 10/1973 Kanazawa et al. .................. 423/416 Shizuoka, all of Japan Primary Examiner-Earl C. Thomas (73) Assignee: Ihara Chemical Industry Co., Ltd., Attorney, Agent, or Firm-Oblon, Fisher, Spivak, Tokyo, Japan McClelland & Maier 21) Appl. No.: 736,334 57 ABSTRACT 22) Filed: Oct. 28, 1976 Carbonyl sulfide is produced by reacting carbon mon (30) Foreign Application Priority Data oxide with sulfur in the presence of an alkaline earth metal compound selected from the group consisting of Apr. 28, 1976 Japan .................................. 51-48944 calcium, strontium or barium sulfides sulfates and ha (51) Int. C.’.............................................. C01B31/26 lides. 52) U.S. Cl. .................................................... 423/416 (58) Field of Search ................................. 423/414-416 6 Claims, 1 Drawing Figure U.S. Patent March 7, 1978 4,078,045 -a COS 4,078,045 1 2 However, when the conversion is low, carbon mon PROCESS FOR PRODUCING CARBONYL oxide of the unreacted material contained in the reac SULFIDE tion mixture gas at high ratio should be separated and recovered from carbonyl sulfide. Accordingly, the pro BACKGROUND OF THE INVENTION cess is not satisfactory for the industrial operation. The present invention relates to an improved process On the other hand, in the process for reacting carbon for producing carbonyl sulfide which is useful as the monoxide with sulfur in the presence of the alkali metal intermediate for agriculture chemicals, medicines and sulfide such as sodium or potassium sulfide, the catalytic other chemical compounds. -
Step-By-Step Guide to Better Laboratory Management Practices
Step-by-Step Guide to Better Laboratory Management Practices Prepared by The Washington State Department of Ecology Hazardous Waste and Toxics Reduction Program Publication No. 97- 431 Revised January 2003 Printed on recycled paper For additional copies of this document, contact: Department of Ecology Publications Distribution Center PO Box 47600 Olympia, WA 98504-7600 (360) 407-7472 or 1 (800) 633-7585 or contact your regional office: Department of Ecology’s Regional Offices (425) 649-7000 (509) 575-2490 (509) 329-3400 (360) 407-6300 The Department of Ecology is an equal opportunity agency and does not discriminate on the basis of race, creed, color, disability, age, religion, national origin, sex, marital status, disabled veteran’s status, Vietnam Era veteran’s status or sexual orientation. If you have special accommodation needs, or require this document in an alternate format, contact the Hazardous Waste and Toxics Reduction Program at (360)407-6700 (voice) or 711 or (800) 833-6388 (TTY). Table of Contents Introduction ....................................................................................................................................iii Section 1 Laboratory Hazardous Waste Management ...........................................................1 Designating Dangerous Waste................................................................................................1 Counting Wastes .......................................................................................................................8 Treatment by Generator...........................................................................................................12 -
CHEM 301 Assignment #2 Provide Solutions to the Following Questions in a Neat and Well-Organized Manner
CHEM 301 Assignment #2 Provide solutions to the following questions in a neat and well-organized manner. Reference data sources for any constants and state assumptions, if any. Due date: Thursday, Oct 20th, 2016 Attempt all questions. Only even numbers will be assessed. 1. A pond in an area affected by acid mine drainage is observed to have freshly precipitated Fe(OH)3(s) at pH 4. What is the minimum value of pe in this water? Use the appropriate pe-pH speciation diagram to predict the dominant chemical speciation of carbon, sulfur and copper under these conditions. 2. The solubility of FeS(s) in marine sediments is expected to be affected by the pH and the [H2S(aq)] in the surrounding pore water? Calculate the equilibrium concentration of Fe2+ (ppb) at pH 5 and pH 8, -3 assuming the H2S is 1.0 x 10 M. pKsp(FeS) = 16.84. + 2+ FeS(s) + 2 H (aq) ==== Fe (aq) + H2S 3. Boric acid is a triprotic acid (H3BO3); pKa1 = 9.24, pKa2 = 12.74 and pKa3 = 13.80. a) Derive an expression for the fractional abundance of H3BO3 as a function of pH b) Construct a fully labeled pH speciation diagram for boric acid over the pH range of 0 to 14 using Excel spreadsheet at a 0.2 pH unit interval. 4. At pCl- = 2.0, Cd2+ and CdCl+ are the only dominant cadmium chloride species with a 50% fractional abundance of each. + a) Calculate the equilibrium constant for the formation of CdCl (1). + - b) Derive an expression for the fractional abundance of CdCl as a function of [Cl ] and 1 – 4 for cadmium chloro species. -
Download Author Version (PDF)
Analytical Methods Accepted Manuscript This is an Accepted Manuscript, which has been through the Royal Society of Chemistry peer review process and has been accepted for publication. Accepted Manuscripts are published online shortly after acceptance, before technical editing, formatting and proof reading. Using this free service, authors can make their results available to the community, in citable form, before we publish the edited article. We will replace this Accepted Manuscript with the edited and formatted Advance Article as soon as it is available. You can find more information about Accepted Manuscripts in the Information for Authors. Please note that technical editing may introduce minor changes to the text and/or graphics, which may alter content. The journal’s standard Terms & Conditions and the Ethical guidelines still apply. In no event shall the Royal Society of Chemistry be held responsible for any errors or omissions in this Accepted Manuscript or any consequences arising from the use of any information it contains. www.rsc.org/methods Page 1 of 21 Analytical Methods 1 2 3 4 Multi-element analysis of sulfuric acid by oaTOF-ICP-MS after matrix 5 6 modification with barium bromide 7 8 9 10 11 Lenka Husáková*, Iva Urbanová, Tereza Šídová, Tomáš Mikysek 12 13 14 Department of Analytical Chemistry, Faculty of Chemical Technology, University of Pardubice, 15 16 Pardubice, Studentska 573 HB/D, CZ-532 10, Czech Republic 17 18 19 20 21 * Corresponding author: Tel. +420 466 037 029 fax: +420 466 037 068 Manuscript 22 23 E-mail address: [email protected] 24 25 26 27 28 29 30 31 Accepted 32 33 34 35 36 37 38 39 40 Methods 41 42 43 44 45 46 47 48 49 50 51 Analytical 52 53 54 55 56 57 58 59 60 1 Analytical Methods Page 2 of 21 1 2 3 Abstract 4 5 6 In this work a novel method for simultaneous multi-element analysis of sulfuric acid by 7 8 inductively coupled plasma orthogonal acceleration time-of-flight mass spectrometry (oaTOF- 9 10 ICP-MS) after matrix modification with barium bromide was introduced.