<<

J. Gmehling U. Onken

VAPOR-LIQUID EQUILIBRIUM DATA COLLECTION

Carboxylic , Anhydrides Supplement 1

Chemistry Data Series

Vol. I, Part Sa

Published by DECHEMA Gesellschaft fur Chemische Technik und Biotechnologie e. V.

Executive Editor: Gerhard Kreysa Bibliographic information published by Die Deutsche Bibliothek

Die Deutsche Bibliothek lists this publication in the Deutsche Nationalbibliographie; detailed bibliographic data is available on the Internet at http://dnb.ddb.de

ISBN: 3-89746-040-8

© DECHEMA Gesellschaft fOr Chemische Technik und Biotechnologie e. V. Postfach 15 01 04, D-60061 Frankfurt am Main, Germany, 2002

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Technical Production: Mitterweger & Partner, Plankstadt Vapor-Liquid Equilibrium Data Collection

Sa

Carboxylic Acids, Anhydrides

Supplement 1

Tables and diagrams of data for binary and multicomponent mixtures up to moderate pressures. Constants of correlation equations for computer use.

J. Gmehling, U. Onken

Technische Chemie Universitat Oldenburg Sa

Carboxylic Acids, Anhydrides

Systems with: Aliphatic and aromatic carboxylic acids

Acetic Acid Lauric Acid Acrylic Acid Benzoic Acid Z-9-0ctadecenoic Acid 3-Pentenoic Acid ( not specified) Chloroacetic Acid Propionic Acid Formic Acid Trifluoroacetic Acid Hexanoic Acid Valeric Acid Isobutyric Acid

Anhydrides

Acetic Anhydride Maleic Anhydride vii

AUTHORS' PREFACE

With this volume we have pleasure in publishing a new supplement of the Vapor­ Liquid Equilibrium Data Collection for carboxylic acids and anhydrides as DECHEMA Chemistry Data Series Volume I Part 5a.

The data in this book are taken from the Dortmund Data Bank and are available in electronic form. The Dortmund Data Bank covers a wide range of properties in E addition to the VLE, h , yoo, for example: data bases of the vapor-liquid equilibria of low boiling substances (HPV), azeotropic data (AZD), (GLE), solid-liquid equilibria (SLE) and a pure component property data base (PCP). Data in electronic form can be obtained from DDBST GmbH, Oldenburg, Germany or DECHEMA e.V., Frankfurt am Main. Data collections for inhouse use are available from DDBST GmbH; DECHEMA e.V.; FIZ Chemie GmbH, Berlin, Germany and Aspen Technology, Inc., Cambridge, Massachusetts, USA. DDBST GmbH can also supply a large program system well suited to handling the data in the data banks. Online versions of the database are hosted by STN International (Columbus, Ohio, USA; Karlsruhe, Germany and Tokyo, Japan) and DECHEMA e.V. (via the Internet).

We would like to thank J. Krafczyk and J. Menke for computer programming assistance in order to allow publication of data determined under non-isotherm and non-isobaric conditions. In addition we would like to sincerely thank all those colleagues who have both supported and continue to support the endeavours of the thermodynamic group at the University of Oldenburg by delivering VLE data from their research. At this juncture we would like to request other colleagues in this field to send us unpublished data and reprints of their publications on thermophysical properties.

Oldenburg, November 2002

J. Gmehling U. Onken viii

EXECUTIVE EDITOR'S PREFACE

The aim of DECHEMA e.V., The Society for Chemical Technology and Biotechnology when it was founded in 1926 was to improve cooperation between chemist and engineer. As the importance of mathematical modelling, computer simulation and optimisation became apparent in the mid-nineteen-seventies, this ideal resulted in the production and publication of collections of basic thermophysical data in both electronic and book form. This is not data that could have easily found a publisher outside the engineering societies, because of its sheer volume and limited circle of interest. By its sponsoring and publication of the DECHEMA Chemistry Data Series DECHEMA e.V. has been associated with these endevours for over a quarter of a century. Much of the original work to determine the values obtained was financed by the German Ministry of Research.

lt is to be hoped that publication of this data collection by DECHEMA e.V. in the DECHEMA Chemistry Data Series will inspire other authors to consider publishing their collections of thermophysical data. DECHEMA e.V. is always pleased to assist colleagues from the thermophysical data community in preparing their results, their studies, their collections and their assessments for publication. DECHEMA e.V. is always prepared to enlarge the scope of the DECHEMA Chemistry Data Series and is thus pleased to hear from readers, designers, scientists and engineers of areas where thermophysical data is not available or scarce. We hope that the end user finds the data of utility and of interest.

Frankfurt am Main, November 2002 Gerhard Kreysa ix

CONTENTS6- Vol. I, Part/a

Subjects of Volume I ...... VI

Author's Preface ...... VII

Executive Editor's Preface ...... VIII

Contents Volume I, Part Sa ...... IX

Guide to Tables ...... XI

List of Symbols ...... XXI

References ...... XXIII

Data Tables

Carboxylic Acids

Binary Systems

Formic Acid ......

Trichloroacetic Acid ...... 21

Trifluoroacetic Acid ...... 27

Dichloroacetic Acid ...... 28

Chloroacetic Acid ...... 30

Acetic Acid ...... 36

Acrylic Acid ...... 155

Propionic Acid ...... 166

Methacrylic Acid ...... 219

Butyric Acid ...... 236

Isobutyric Acid ...... 250

3-Pentenoic Acid (isomer not specified) ...... 260

Valeric Acid ...... 263

Hexanoic Acid ...... 267

Benzoic Acid ...... 270

Lauric Acid ...... 280

Z-9-0ctadecenoic Acid ...... 283

Ternary Systems ...... 284

Quaternary Systems ...... 305

Anhydrides ......

Maleic Anhydride ...... 306

Acetic Anhydride ...... 312 X

Appendix A: Pure Component Parameters ...... 329

Appendix B: Dimerization Constants of Carboxlic Acids 347

Formula Index of Binary Systems ...... 349

Formula Index of Ternary Systems ...... 362

Formula Index of Quaternary Systems ...... 364

Alphabetical Index of Binary Systems ...... 365

Alphabetical Index of Ternary Systems ...... 378

Alphabetical Index of Quaternary Systems ...... 380 028 Sulfur Dioxide C2H•02 Acetic Acid 36

C•Hs03 Acetic Anhydride 312

HN03 Nitric Acid C2HCI302 Trichloroacetic Acid 21-24

C2H3CI02 Chloroacetic Acid 30

C2H•02 Acetic Acid 37

H20•S C2H3CI02 Chloroacetic Acid 31

CCI4 Tetrachloromethane C2H402 Acetic Acid 38-42R

C3Hs02 Propionic Acid 166-172

C.Hs03 Acetic Anhydride 313-319R cs2 Carbon Disulfide C.H603 Acetic Anhydride 322

C.Ha02 Butyric Acid 236

C,aH3.o2 Z-9-0ctadecenoic Acid 283 11 0 CHCI3 C2HCI302 Trichloroacetic Acid 25 """''

C2H2CI202 Dichloroacetic Acid 28 3 c C2H3CI02 Chloroacetic Acid 32 Ill

C2H•02 Acetic Acid 43 ::J a. C•Hs02 Methacrylic Acid 219 CD >< CH202 Formic Acid C2H3N Acetonitrile 1 0 C2H•02 Acetic Acid 2-7 -

Methyl Formate 8-11 OJ ::J C3H5CI 3-Chloro-1- 12 Ill """'' C3Hs02 Methyl Acetate 13 '<

Propionic Acid 14-16 (/) '< C3H1NO N,N-Dimethylformamide (DMF) 17 CIJ ro+ CsHsN Pyridine 18-19 CD U) CsH,002 Valeric Acid 20 3 � CIJ <0 "'T1 Ul CH3CI Methyl Chloride C.Hs03 Acetic Anhydride 320 c.n 0 0 """' CH31 Methyl Iodide C H402 Acetic Acid 44 2 3 C•Hs03 Acetic Anhydride 321 c

CH3N02 c.H2o3 Maleic Anhydride 306 Ill

C2HCI302 Trichloroacetic Acid HN03 Nitric Acid 21-24 ::::::1 a. CHCI3 Chloroform 25 CD X C2HF302 Trifluoroacetic Acid C2H•02 Acetic Acid 27 0 C2H2CI202 Dichloroacetic Acid CHCI3 Chloroform 28 ...... llJ CsHs 29 ::::::1 C2H3CI02 Chloroacetic Acid HN03 Nitric Acid 30 Ill

H2o.s Sulfuric Acid 31 � (J) CHCI3 Chloroform 32 '< H 02 N-Pentanoic Acid 33-35 (/J Cs 1o ro+ CD CsHs Benzene 26 3 C2H3N Acetonitrile CH202 Formic Acid 1 (/J

C2H402 Acetic Acid 45-47

C3Hs02 Propionic Acid 173-174

C•Hs02 Isobutyric Acid 250-251

C2H4CI2 1,2-Dichloroethane C4H602 Methacrylic Acid 220

C2H•02 Acetic Acid 028 Sulfur Dioxide 36

HN03 Nitric Acid 37

CCI4 Tetrachloromethane 38-42R

CHCI3 Chloroform 43

CH202 Formic Acid 2-7

CH31 Methyl Iodide 44

C2HF302 Trifluoroacetic Acid 27 C2H3N Acetonitrile 45-47

C2H51 Ethyl Iodide 48-49

C2H5NO Acetamide 50-51

C3H5CI 3-Chloro-1-Propene 52-53

C3Ha02 Methyl Acetate 54-57

Propionic Acid 58--64R

C3H7Br Propyl Bromide 65--69R

C3H7NO N,N-Dimethylformamide (DMF) 70-71

C4H5CI302 Ethyl Trichloroacetate 72

C4H60 Methacrolein 73

C4Hs02 Methacrylic Acid 74

Vinyl Acetate 75 'T1 0 C.Ha03 Acetic Anhydride 76-79 �

C•Hs02 Butyric Acid 80-82 3 c: Ethyl Acetate 83-95 Ill

C.HgNO N,N-Dimethylacetamide 96 ::J a. C5H5N Pyridine 97-100 CD >< C5Hs02 Vinyl Propionate 101-102 0 C5H,o02 Propyl Acetate 103 ......

C6H4CI2 a-Dichlorobenzene 104 ro ::J C6H5CI Chlorobenzene 105-106 Ill CaHs Benzene 107-112R � C6H1o02 Vinyl Butyrate 113-114 (f) '< CaH,oO• Acetaldehyde Diacetate 115-117 C/) - Ethylene Glycol Diacetate 118 CD (.,) C6H NO 6-Caprolactam 119 3 c.n 11 C/) ..... "'T1 � C H 2 Cyclohexane 12Q-123 0'1 s 1 0 1\) """�: 124 1-Hexene 3 c.H,2o2 Butyl Acetate 125-126 c Ol Isobutyl Acetate 127-129R :::J CsH 4 Hexane 130 1 Q. CsH15N Triethylamine 131-138 CD X C H 139 1 a 0 - C7H,20• 140 OJ C H,402 Pentyl Acetate 141-143 1 :::J C1H1s Heptane 144-145 Ol

CaH,sN Caprylonitrile 146 � (/) CaH,a Octane 147-148 '< CIJ C9H,o02 Benzyl Acetate 149 - CD 15Q-151 CsH12 lsopropylbenzene 3 CsH2o Nonane 152 CIJ

C10H1s Camphene 153

C,2H2o02 Isobornyl Acetate 154

Methyl Formate CH202 Formic Acid 8-11

C2Hsl Ethyl Iodide C2H402 Acetic Acid 48-49

C2HsNO Acetamide C2H402 Acetic Acid 50-51 155-158 CsH•02 Acrylic Acid C4Hs02 Methyl Acrylate

CsHa02 Ethyl Acrylate 159

C7H1202 sec-Butylacrylate 160

C1H1s Heptane 161

CaH,s 1-0ctene 162

CsH1a Octane 163 CsH2o Nonane 164

C10H22 Decane 165

C3H5CI 3-Chloro-1-Propene CH202 Formic Acid 12

C2H•02 Acetic Acid 52-53

CsHs02 Methyl Acetate CH202 Formic Acid 13

C2H•02 Acetic Acid 54-57

C.H802 Butyric Acid 237

Propionic Acid CCI4 Tetrachloromethane 166-172

CH202 Formic Acid 14-16

C2HsN Acetonitrile 173--174

C2H•02 Acetic Acid 58-MR

C3H7Br Propyl Bromide 175-179 "'T1 0 C.HsOs Acetic Anhydride 180--183 ...,.

C•Hs Butyric Acid 184-186 3 02 c:: Ethyl Acetate 187 Ql

Isobutyric Acid 188 :::J c. CsH5N Pyridine 189--190 CD >< C5H,o02 Ethyl Propionate 191-198R 0 CsHs Benzene 199-200R ......

CsH7N Aniline 201-202 OJ :::J CsH,oOs Propionic Acid, Anhydride 203-204 Ql ...,. CsH12 Cyclohexane 205--208R '<

1-Hexene 209 en '< CsH1202 Butyl Acetate 210 en ...... CD CaH14 Hexane 211 c.u C7H Toluene 212-213 3 ()1 a en c.u .., (,) C1H1s Heptane 214-218R 01 0 ""' � C3H Br Propyl Bromide H•02 Acetic Acid 65-69R 1 C2 3 C3Hs02 Propionic Acid 175-179 c ll> C3H1NO N,N-Dimethylformamide (DMF) CH202 Formic Acid 17

C2H402 Acetic Acid 70--71 ::J a. C4H203 Maleic Anhydride CH3N02 Nitromethane 306 CD X C•Hs02 Methyl Acrylate 307 0 C•Hs02 Ethyl Acetate 308 ...... OJ CsHs Benzene 309 ::J CaH,o Xylene (isomer not specified) 311 ll>

o-Xylene 310 -< (/) C4H5CI302 Ethyl Trichloroacetate C2H•02 Acetic Acid 72 '< Methacrolein Acetic Acid 73 (J) C4H60 C2H•02 - CD C•Hs02 Methacrylic Acid 221 3 C4Hs02 Methacrylic Acid CHCI3 Chloroform 219 (J)

C2H.CI2 1,2-Dichloroethane 220

C2H402 Acetic Acid 74

C4H60 Methacrolein 221

CsH5CI Chlorobenzene 222

CsH,. Hexane 223

C1H1s Heptane 224

CaH,o Ethylbenzene 225

m-Xylene 226

C8H1402 Butyl Methacrylate 227-228

CaH,s Octane 229

CsH12 Isopropyl benzene 230 CsH2o Nonane 231

C,oH22 Decane 232-233

c,,H24 N-Undecane 234

c,2H2a Dodecane 235

Methyl Acrylate C3H402 Acrylic Acid 155-158

C4H203 Maleic Anhydride 307

Vinyl Acetate C2H402 Acetic Acid 75

C4Ha03 Acetic Anhydride 02S Sulfur Dioxide 312

CC14 Tetrachloromethane 313-319R

cs2 Carbon Disulfide 322

CH3CI Methyl Chloride 320

CH31 Methyl Iodide 321 .., 0 C2H402 Acetic Acid 76-79 """"

C3Hs02 Propionic Acid 18Q-183 3 c C4Hs02 Butyric Acid 238 Ill

Ethyl Acetate 323 :::J a. Isobutyric Acid 252 CD >< CsH1o02 Isopropyl Acetate 324-325 0 CsH,o04 Acetaldehyde Diacetate 326-328 -

C7Hs Toluene 329--330 OJ :::J C7H1s Heptane 331 Ill CsH1o a-Xylene 332 -< CsH,s 1-0ctene 333-335 (f) '< CsH,s Octane 336-337 rJJ .-+ C4Hs02 Butyric Acid cs2 Carbon Disulfide 236 CD w C2H402 Acetic Acid 80-82 3 ()1 rJJ ()1 , VJ C3Hs02 Methyl Acetate 237 01 0 m """'' 184-186 Propionic Acid 3 C.Hs03 Acetic Anhydride 238 s:: Ill CsHsN Pyridine 239-240 :::J CsHs Benzene 241 a. CsH7N Aniline 242-243 CD >< C7Hs Toluene 244 0 -+1 C7H,•02 Pentyl Acetate 245 lJJ Propyl Butyrate 246 :::J CaH,s02 Butyl Butyrate 247 Ill

C9H2o Nonane 248 -< (f) c,,H2• N-Undecane 249 '< 83-95 (JJ Ethyl Acetate C2H402 Acetic Acid r-+ CD 187 C3Hs02 Propionic Acid 3 c.H2o3 Maleic Anhydride 308 (JJ

C.Hs03 Acetic Anhydride 323

Isobutyric Acid C2H3N Acetonitrile 250--251

C3Hs02 Propionic Acid 188

c.H603 Acetic Anhydride 252

C.H,o02 tert-Butylhydroperoxide 253

CsH12 Cyclohexane 254-255

C7Hs Toluene 256

C7H,. Methylcyclohexane 257

C7H,s Heptane 258-259 c.HgNO N ,N-Dimethylacetamide C2H•02 Acetic Acid 96

C.H,002 tert-Butylhydroperoxide C•Hs02 Isobutyric Acid 253 CsHsN Pyridine CH202 Formic Acid 18-19

C2H•02 Acetic Acid 97-100

C3Hs02 Propionic Acid 189-190

C•Ha02 Butyric Acid 239-240

CsHa02 Ethyl Acrylate C3H402 Acrylic Acid 159

3-Pentenoic Acid (isomer not CsH,o02 3-Pentenoic Acid Methyl (isomer not 260-262 specified) specified)

Vinyl Propionate C2H402 Acetic Acid 101-102

CsH1002 Ethyl Propionate C3Hs02 Propionic Acid 191-198R

Isopropyl Acetate C.H603 Acetic Anhydride 324-325

N-Pentanoic Acid C2H3CI02 Chloroacetic Acid 33-35

Propyl Acetate C2H•02 Acetic Acid 103 , Valeric Acid CH202 Formic Acid 20 0 ...... C,oH22 Decane 263 3 C,H2• N-Undecane 264 c D) c,2H2s Dodecane 265 ::J c,3H2a Tridecane 266 a. C6H.CI2 a-Dichlorobenzene C2H•02 Acetic Acid 104 CD X C6H Chlorobenzene C2H•02 Acetic Acid 105-106 sCI 0 - C•Hs02 Methacrylic Acid 222 CD CsHs Benzene C2H2CI202 Dichloroacetic Acid 29 ::J C2H3CI02 Chloroacetic Acid 26 D)

C2H402 Acetic Acid 107-112R -< 199-200R (/) C3Hs02 Propionic Acid '< c.H2o3 Maleic Anhydride 309 CJ) - CD C•Ha02 Butyric Acid 241 (.:1 Benzoic Acid 270 3 0'1 C1Hs02 CJ) -...J "'T1 c.u C6H7N Aniline CsHs02 Propionic Acid 201-202 ()1 0 (X) """'l C4H Butyric Acid 242-243 a02 3 CsH,o02 3-Pentenoic Acid Methyl Ester C5H802 3-Pentenoic Acid (isomer not specified) 26Q-262 c (isomer not specified) m

Vinyl Butyrate C2H402 Acetic Acid 113-114 :::J CsH,oOs Propionic Acid, Anhydride C3H602 Propionic Acid 203-204 a. CD C6H,o04 Acetaldehyde Diacetate C2H402 Acetic Acid 115-117 X

C4H 0 Acetic Anhydride 326-328 0 s s ...... Ethylene Glycol Diacetate C2H402 Acetic Acid 118 OJ

C6H,,NO 6-Caprolactam C2H402 Acetic Acid 119 :::J m CsH12 Cyclohexane C2H402 Acetic Acid 12Q-123 � CsHs02 Propionic Acid 205-208R (j) '< C4Ha02 Isobutyric Acid 254-255 CJ) ...... 1-Hexene C2H402 Acetic Acid 124 CD

C H 02 Propionic Acid 209 s s CJ)3 C6H,202 Butyl Acetate C2H402 Acetic Acid 125-126

CsHs02 Propionic Acid 210

Hexanoic Acid c,,H24 N-Undecane 267

c,2H2s Dodecane 268

C,4Hso Tetradecane 269

Isobutyl Acetate C2H402 Acetic Acid 127-129R

CsH,4 Hexane C2H402 Acetic Acid 130

CsHs02 Propionic Acid 211

C4Hs02 Methacrylic Acid 223

CsH,sN Triethylamine C2H402 Acetic Acid 131-138

C7H5N Benzonitrile C7H602 Benzoic Acid 271-272 C1Hs02 Benzoic Acid CsHs Benzene 270

C1HsN Benzonitrile 271-272

C1Ha Toluene 273-278

c,.H,2o2 Benzyl Benzoate 279

C1Ha Toluene C2H402 Acetic Acid 139

CaHs02 Propionic Acid 212-213

C.HsOa Acetic Anhydride 329-330

C•Ha02 Butyric Acid 244

Isobutyric Acid 256

C1Hs02 Benzoic Acid 273-278

C7H1202 sec-Butylacrylate CaH•02 Acrylic Acid 160

C7H120• Diethyl Malonate C2H•02 Acetic Acid 140 "'T1 C1H,. Methylcyclohexane C.Ha02 Isobutyric Acid 257 0 ...... C1H,.02 Pentyl Acetate C2H•02 Acetic Acid 141-143 3 C.H802 Butyric Acid 245 c Q,) Propyl Butyrate C•Ha02 Butyric Acid 246

144-145 :::l C1H1s Heptane C2H•02 Acetic Acid a. CaH•D2 Acrylic Acid 161 CD >< Propionic Acid 214-218R CaHs02 0 -+. C4H602 Methacrylic Acid 224 CO C4Ha03 Acetic Anhydride 331 :::l C•Ha02 Isobutyric Acid 258-259 Q,) ...... CsH1o Ethylbenzene C•Hs02 Methacrylic Acid 225 '<

Maleic Anhydride 311 (/) Xylene (isomer not specified) c.H2o3 '< m-Xylene C•HsD2 Methacrylic Acid 226 en r-+ CD a-Xylene c.H2o3 Maleic Anhydride 310 U) C.Hs03 Acetic Anhydride 332 3 c.n en <0 "'T1 c.;! CaH,.o2 Butyl Methacrylate C•Hs02 Methacrylic Acid 227-228 0> 0 0 � 5N Caprylonitrile C Acetic Acid 146 C8H1 2H•02 3 CaH1a 1-0ctene C3H•02 Acrylic Acid 162 c Ill C.Ha03 Acetic Anhydride 333-335

CaH,s02 Butyl Butyrate C.Ha02 Butyric Acid 247 ::::J a. CaH1a Octane C2H402 Acetic Acid 147-148 CD >< C3H402 Acrylic Acid 163 0 C•Hs02 Methacrylic Acid 229 .... OJ C.Ha03 Acetic Anhydride 336-337 ::::J CsH1o02 Benzyl Acetate C2H402 Acetic Acid 149 Ill

CsH12 lsopropylbenzene C2H402 Acetic Acid 15G-151 -< CJ) C•Hs02 Methacrylic Acid 230 '< Acetic Acid 152 (J) CsH2o Nonane C2H402 r-+ CD C3H402 Acrylic Acid 164 3 C4H602 Methacrylic Acid 231 (J)

C•Hs02 Butyric Acid 248

C,oH,s Camphene C2H•02 Acetic Acid 153

C,oH22 Decane C3H•02 Acrylic Acid 165

C.H602 Methacrylic Acid 232-233

CsH1o02 Valeric Acid 263

C11H2• N-Undecane C.Ha02 Methacrylic Acid 234

C.H802 Butyric Acid 249

CsH1o02 Valeric Acid 264

CsH1202 Hexanoic Acid 267

C,2H2o02 Isobornyl Acetate C2H•02 Acetic Acid 154

c,2H2402 Lauric Acid c,.H2a02 Myristic Acid 28G-282 Methacrylic Acid 235 c,2H2s Dodecane C4Hs02 265 C5H,o02 Valeric Acid 268 CsH1202 Hexanoic Acid

Valeric Acid 266 C,3H2a Tridecane C5H,o02 Benzoic Acid 279 c,4H,2o2 Benzyl Benzoate C7Hs02 Lauric Acid 28Q-282 C,4H2a02 Myristic Acid c,2H2402 Hexanoic Acid 269 C,4H3o Tetradecane CsH1202 Carbon Disulfide 283 C,aH3402 Z -9-0ctadecenoic Acid cs2

""Tl 0 ..... 3 c::: Ill

::::::1 a. CD >< 0 - � ::::::1 Ill ..... '< en '< CIJ - CD � 3 m CIJ ...... c,.) 0> CCI4 Tetrachloromethane C2H•02 Acetic Acid C3Hs02 Propionic Acid 289 �

CsHs Benzene 290-291

C3H402 Acrylic Acid C2H•02 Acetic Acid 288

CH202 Formic Acid C2H402 Acetic Acid C3Hs02 Methyl Acetate 284

Propionic Acid 285-286

C5H1002 Butyl Formate CsHsN Pyridine 287

C2H•02 Acetic Acid CCI4 Tetrachloromethane C3H402 Acrylic Acid 288

C3Hs02 Methyl Acetate CH202 Formic Acid 284

Propionic Acid CCI4 Tetrachloromethane 289

CH202 Formic Acid 285-286

293-294 C3H1Br Propyl Bromide , 0 C.H802 Butyric Acid 295 '""'( Ethyl Acetate 296 3 c CsH12 Cyclohexane 298-299 s:u C4H802 Butyric Acid CsH1o02 Pentanoic Acid 300 ::I Ethyl Acetate C6H,4 Hexane 301 c. CD CsHs Benzene CCI4 Tetrachloromethane 290-291 >< C3Hs02 Propionic Acid 297 0 ...... C1H1s Heptane C3H402 Acrylic Acid 292

CsH1o Ethyl benzene CaHs Styrene 302 �'""'( ::I C3H402 Acrylic Acid C2H•02 Acetic Acid CCI4 Tetrachloromethane 288 s:u C1H1s Heptane 292 -< C3H 02 Methyl Acetate CH202 Formic Acid C2H402 Acetic Acid 284 CJ) s '< (J) Propionic Acid CCI4 Tetrachloromethane C2H402 Acetic Acid 289 ...... CD CH202 Formic Acid C2H402 Acetic Acid 285-286 3 C2H402 Acetic Acid CsHs Benzene 297 (J) '"Tl CsH7Br Propyl Bromide C2H•02 Acetic Acid 293-294 0 ....,. C•Ha02 Butyric Acid C2H402 Acetic Acid 295 3 Ethyl Acetate C2H402 Acetic Acid 296 c: Ill CsH12 Cyclohexane C2H402 Acetic Acid 298-299 ::J Propionic Acid 293-294 CsH1Br Propyl Bromide C2H402 Acetic Acid CsHs02 a. C4H Butyric Acid C2H•02 Acetic Acid CsHs02 Propionic Acid 295 CD a02 >< 300 CsH1o02 Pentanoic Acid C2H•02 Acetic Acid 0 ...... Ethyl Acetate C2H•02 Acetic Acid CsHs02 Propionic Acid 296

CsH1• Hexane C2H402 Acetic Acid 301 roi ....,. ::J Formic Acid C H 02 Butyl Formate 287 CsHsN Pyridine CH202 s 1o Ill ....,. C5H1002 Butyl Formate C5H5N Pyridine CH202 Formic Acid 287 '< Pentanoic Acid C2H•02 Acetic Acid C4H802 Butyric Acid 300 (/) '< CsHs Benzene CCI4 Tetrachloromethane C2H402 Acetic Acid 29Q-291 (J) ..... CsHs02 Propionic Acid C2H402 Acetic Acid 297 CD

298-299 CsH12 Cyclohexane C2H•02 Acetic Acid CsHs02 Propionic Acid 3(J) CsH1• Hexane C2H•02 Acetic Acid C.H802 Ethyl Acetate 301

C1Ha02 Benzoic Acid c12H10 Biphenyl C1Ha Toluene 303-304

C1Ha Toluene C7Hs02 Benzoic Acid C12H1o Biphenyl 303-304

C1H1s Heptane CsH•02 Acrylic Acid C2H402 Acetic Acid 292

CaHa Styrene C2H•02 Acetic Acid CaH1o Ethylbenzene 302

CsH10 Ethyl benzene CaHa Styrene C2H•02 Acetic Acid 302

C12H1o Biphenyl C1Ha Toluene C1Hs02 Benzoic Acid 303-304

C.:l 0> C.:l .,c.u N-Pentanoic Acid C H 202 lsocaproic Acid 305 C2H402 Acetic Acid C•Ha02 Butyric Acid CsH1o02 s 1 0 0> (4-Methylpentanoic """'' � Acid) 3 c:: C4H802 Butyric Acid CsH,o02 N-Pentanoic Acid CsH1202 lsocaproic Acid C2H•02 Acetic Acid 305 (4-Methylpentanoic Dl Acid) :::::s Q. CsH1o02 N-Pentanoic Acid CsH1202 lsocaproic Acid C2H•02 Acetic Acid C.Ha02 Butyric Acid 305 (4-Methylpentanoic Acid) CD >< CsH1202 lsocaproic Acid (4- C2H•02 Acetic Acid C•Ha02 Butyric Acid CsH1o02 N-Pentanoic Acid 305 0 Methylpentanoic Acid) ...... 0 c:: Dl .-+ CD"""'' :::::s Dl '<"""'' (J) '< CIJ .-+ CD

CIJ3 Acetaldehyde Diacetate CsH,o04 Acetic Acid C2H402 115-117

Acetic Anhydride C4Hs03 326-328

Acetamide C2H5NO Acetic Acid C2H402 50-51

Acetic Acid C2H402 Acetaldehyde Diacetate CsH,o04 115-117

Acetamide C2H5NO 5Q--51

Acetic Anhydride C4Hs03 76-79

Acetonitrile C2H3N 45-47

Benzene CsHs 107-112R

Benzyl Acetate CsH1o02 149 Butyl Acetate CsH1202 125-126 )> Butyric Acid C4Hs02 80-82 "C :::r Camphene C,oH,s 153 Dl 0" 6-Caprolactam C6H11NO 119 CD .-+ Caprylonitrile CsH,sN 146 (') Dl 3-Chloro-1-Propene C3HsCI 52-53

Chlorobenzene C6H5CI 105-106 ::::::1 0. Chloroform CHCI3 43 CD >< Cyclohexane CsH12 12Q--123 0 o-Dichlorobenzene C6H4CI2 104 ......

Diethyl Malonate C7H1204 140 Ill ::::::1 N ,N-Dimethylacetamide C4H9NO 96 Dl """'' N,N-Dimethylformamide (DMF) C3H7NO 70-71 '<

Ethyl Acetate C4Hs02 83-95 (j) '< Ethyl Iodide C2Hsl 48-49 C/J .-+ Ethyl Trichloroacetate C4HsCI302 72 CD Ul Ethylene Glycol Diacetate CsH,o04 118 3 0> C/) 01 (,) Formic Acid CH202 2-7 )> 0'> "0 0'> 144-145 Heptane C1H1s ::::r D) Hexane CaH,4 130 o- 1-Hexene C H 124 CD s 12 !:!': Isobornyl Acetate C,2H2o02 154 (') D) Isobutyl Acetate 2oH1202 127-129R lsopropylbenzene C9H 2 150-151 ::::::l 1 0. Methacrolein C4H60 73 CD >< 74 Methacrylic Acid C4Hs02 0 ...... Methyl Acetate CsHa02 54-57 OJ Methyl Iodide CH31 44 ::::::l Nitric Acid HNOs 37 D)

Nonane C9H2o 152 -< (J) Octane CaH,e 147-148 '< en Pentyl Acetate C1H,402 141-143 - CD Propionic Acid CsHa02 58-{)4R 3 Propyl Acetate CsH1002 103 en

Propyl Bromide CsH1Br 65-{)9R

Pyridine CsHsN 97-100

Sulfur Dioxide 02S 36

Tetrachloromethane CC14 38-42R

Toluene C1Ha 139

Triethylamine CaH,sN 131-138

Trifluoroacetic Acid C2HFs02 27

Vinyl Acetate C4Hs02 75

Vinyl Butyrate CaH,o02 113-114 Vinyl Propionate CsHa02 101-102

Acetic Anhydride C.HsOs Acetaldehyde Diacetate CsH,oO• 326-328

Acetic Acid C2H402 76-79

Butyric Acid C4H802 238

Carbon Disulfide cs2 322

Ethyl Acetate C•Ha02 323

Heptane C7H1s 331

Isobutyric Acid C•Ha02 252

Isopropyl Acetate CsH1o02 324-325 Methyl Chloride CH3CI 320 )> Methyl Iodide CH31 321 "'C :::J"' Octane CaH1a 336-337 Ill C" 1-0ctene CaH1s 333-335 CD .-+ Propionic Acid CsHs02 180-183 () Ill Sulfur Dioxide 028 312

Tetrachloromethane CCI4 313-319R ::J a. Toluene C7Ha 329-330 CD >< o-Xylene CsH1o 332 0 Acetonitrile C2HsN Acetic Acid C2H•02 45-47 -

Formic Acid CH202 1 OJ ::J Isobutyric Acid C.H802 25D-251 Ill Propionic Acid CsHs02 173-174 -< Acrylic Acid C3H402 sec-Butylacrylate C7H1202 160 (j) '< Decane C,oH22 165 CJ) .-+ Ethyl Acrylate CsHa02 159 CD Ul Heptane C7H1s 161 3 0) CJ) -....! (,) Methyl Acrylate c.H6o2 155-158 )> 0> "0 (X) Nonane CsH2o 164 ::::r � Octane CaH1a 163 0"' 162 CD 1-0ctene CaH,6 � Butyric Acid C.H802 242-243 (") Aniline C6H7N � Propionic Acid C3H602 201-202 ::J 107-112R Benzene C6H6 Acetic Acid C2H•02 a. Benzoic Acid C7H502 270 CD >< Butyric Acid C•Ha02 241 0 ...... Chloroacetic Acid C2H3CI02 26 OJ 29 Dichloroacetic Acid C2H2CI202 ::J Maleic Anhydride c.H2o3 309 �

Propionic Acid C3H602 199-200R � (J) Benzoic Acid C7H602 Benzene C6H6 270 '< C/) Benzonitrile C7H5N 271-272 ..... CD Benzyl Benzoate c,.H,2o2 279 C/)3 Toluene C7Ha 273-278

Benzonitrile C7H5N Benzoic Acid C7H602 271-272

Benzyl Acetate CsH1o02 Acetic Acid C2H•02 149

Benzyl Benzoate c,.H,2o2 Benzoic Acid C7H602 279

Butyl Acetate C6H,202 Acetic Acid C2H402 125-126

Propionic Acid C3H602 210

Butyl Butyrate CaH,602 Butyric Acid C•Ha02 247

Butyl Methacrylate CaH,.o2 Methacrylic Acid c.H6o2 227-228

sec-Butylacrylate C7H1202 Acrylic Acid C3H402 160

tert-Butylhydroperoxide c.H1002 Isobutyric Acid C.H802 253 Butyric Acid C•Ha02 Acetic Acid C2H402 80-82

Acetic Anhydride C•Hs03 238

Aniline C6H7N 242-243

Benzene CsHs 241

Butyl Butyrate CaH1s02 247

Carbon Disulfide cs2 236

Methyl Acetate C3Hs02 237

Nonane CsH2o 248

Pentyl Acetate C1H,.02 245

Propionic Acid C3Hs02 184-186 )> Propyl Butyrate C1H,.02 246 lJ Pyridine C5H5N 239-240 ::::r Q) Toluene C1Ha 244 0" CD N-Undecane C,H2• 249 r-+ (") Camphene C,oH,s Acetic Acid C2H402 153 Q)- 6-Caprolactam C6H,NO Acetic Acid C2H•02 119 - :::J 146 Caprylonitrile CaH,sN Acetic Acid C2H•02 a. Carbon Disulfide cs2 Acetic Anhydride C4H603 322 CD >< Butyric Acid C•H 236 a02 0 - Z -9-0ctadecenoic Acid C,aH3402 283 OJ 3-Chloro-1-Propene C3H5CI Acetic Acid C2H402 52-53 :::J Formic Acid CH202 12 Q) """�: Chloroacetic Acid C2H3CI02 Benzene CsHs 26 '<

Chloroform CHCI3 32 en '< Nitric Acid HN03 30 C/J r-+ CD N-Pentanoic Acid CsH1o02 33-35 U) Sulfuric Acid H20•S 31 3 Ol C/J CO (,) Chlorobenzene CsHsCI Acetic Acid C2H402 105-106 )> -...j "0 0 Methacrylic Acid C4H 222 s02 ::r Q,) Chloroform CHCI3 Acetic Acid C2H402 43 0" Chloroacetic Acid C2H3CI02 32 CD -

Dichloroacetic Acid CzHzCizOz 28 () Q,) Methacrylic Acid C4Hs0z 219 ::J Trichloroacetic Acid C HCI302 25 2 0. Cyclohexane CsH12 Acetic Acid C2H402 120-123 CD >< 254-255 Isobutyric Acid C4Ha02 0 -+. Propionic Acid C3Hs0z 205-208R OJ Acrylic Acid C3H402 165 Decane C,oH22 ::J Methacrylic Acid C4Hs0z 232-233 Q,) � '< Valeric Acid CsH,oOz 263 (/) Dichloroacetic Acid CzHzCI202 Benzene CsHs 29 '< en Chloroform CHCI3 28 - CD a-Dichlorobenzene C6H4CI2 Acetic Acid CzH402 104 3 1,2-Dichloroethane C2H4Ciz Methacrylic Acid C4Hs02 220 en

Diethyl Malonate C7H1204 Acetic Acid C2H402 140

N,N-Dimethylacetamide C4H9NO Acetic Acid C2H402 96

N,N-Dimethylformamide (DMF) C3H7NO Acetic Acid C2H402 70-71

Formic Acid CH202 17

Dodecane C,zHzs Hexanoic Acid CsH,zOz 268

Methacrylic Acid C4Hs02 235

Valeric Acid CsH,o02 265

Ethyl Acetate C4Ha02 Acetic Acid CzH40z 83-95

Acetic Anhydride C4Hs03 323 Maleic Anhydride C4H203 308

Propionic Acid C3Ha02 187

Ethyl Acrylate CsHa02 Acrylic Acid C3H402 159

Ethyl Iodide C2H51 Acetic Acid C2H402 48-49

Ethyl Propionate CsH1o02 Propionic Acid C3Ha02 191-198R

Ethyl Trichloroacetate C4HsCI302 Acetic Acid C2H402 72

Ethylbenzene CaH1o Methacrylic Acid C4H602 225

Ethylene Glycol Diacetate C6H,o04 Acetic Acid C2H402 118

Formic Acid CH202 Acetic Acid C2H402 2-7 Acetonitrile C2H3N 1 )> 3-Chloro-1-Propene C3H5CI 12 "'0 :::J"' N,N-Dimethylformamide (DMF) C3H7NO 17 Ill 0" Methyl Acetate C3Ha02 13 CD - Methyl Formate C2H402 8-11 (') Ill Propionic Acid C3Ha02 14-16

Pyridine C5H5N 18-19 ::J a. Valeric Acid CsH1o02 20 CD X Heptane C7H1a Acetic Acid C2H402 144-145 0 Acetic Anhydride C4Ha03 331 .....,

Acrylic Acid C3H402 161 OJ ::J Isobutyric Acid C4Hs02 258-259 Ill Methacrylic Acid C4Ha02 224 -< Propionic Acid C3Ha02 214-218R (J) '< Hexane CaH,4 Acetic Acid C2H402 130 (/J - Methacrylic Acid C4Ha02 223 CD (.:> Propionic Acid C3Ha02 211 3 "'-I (/J ..... C.:l Hexanoic Acid CsH1202 Dodecane c,2H2s 268 )> ""-.I "'0 1\) 269 Tetradecane C,.Hso :::J'" Q) N-Undecane C,H2• 267 0" 124 CD 1-Hexene CsH12 Acetic Acid C2H402 .-+ Propionic Acid CsHs02 209 (') Q)- Isobornyl Acetate C,2H2o02 Acetic Acid C2H402 154 :::J Acetic Acid C 402 127-129R Isobutyl Acetate CsH1202 2H a. Isobutyric Acid C•Hs02 Acetic Anhydride C4H60s 252 CD X Acetonitrile C2HsN 250-251 0 ....., tert-Butylhydroperoxide C.H,o02 253 Ill 254-255 Cyclohexane CsH12 :::J Heptane C7H1s 258-259 Q) ""'I '< Methylcyclohexane C7H,. 257 (J) Propionic Acid CsHs02 188 '< C/J Toluene C7Ha 256 .-+ CD Isopropyl Acetate CsH1o02 Acetic Anhydride C.HsOs 324-325 3C/J Isopropyl benzene CsH12 Acetic Acid C2H402 150-151

Methacrylic Acid C•Hs02 230

Lauric Acid c,2H2.o2 Myristic Acid c,.H2s02 280-282

Maleic Anhydride c.H20a Benzene CsHs 309

Ethyl Acetate C•Hs02 308

Methyl Acrylate C•Hs02 307

Nitromethane CH3N02 306

Xylene (isomer not specified) CaH,o 311

a-Xylene CsH1o 310 Methacrolein C4H60 Acetic Acid C2H•02 73

Methacrylic Acid C•Hs02 221

Methacrylic Acid C4H602 Acetic Acid C2H402 74

Butyl Methacrylate CaH1402 227-228

Chlorobenzene CsHsCI 222

Chloroform CHCI3 219

Decane C1oH22 232-233

1 ,2-Dichloroethane C2H•CI2 220

Dodecane c12H2s 235

Ethylbenzene CaH1o 225 )> Heptane C7H1s 224 ""0 Hexane CsH1• 223 ::::r Ill lsopropylbenzene C9H12 230 0'" CD Methacrolein C4H60 221 ..... (') Nonane C9H2 231 o Ill Octane CaH1a 229 ::::::1 N-Undecane • 234 C11H2 c. m-Xylene CaH1o 226 CD X Methyl Acetate C3H 02 Acetic Acid C2H402 54-57 s 0 Butyric Acid C4H802 237 ...... CD Formic Acid CH202 13 ::::::1 Methyl Acrylate C•Hs02 Acrylic Acid C3H402 155-158 Ill ., Maleic Anhydride c.H2o3 307 '<

Methyl Chloride CH3CI Acetic Anhydride C.H 03 320 (j) s '< Methyl Formate C2H402 Formic Acid CH202 8-11 en ..... Methyl Iodide CH31 Acetic Acid C2H402 44 CD Vl Acetic Anhydride C.Hs03 321 3 -....! en Vl (,) Methylcyclohexane C7H,. Isobutyric Acid C•Ha02 257 )> -..,J "'0 .j:>. 28D-282 Myristic Acid c,.H2a02 Lauric Acid c,2H2402 :::J"' Ill Nitric Acid HN03 Acetic Acid C2H402 37 0" 30 CD Chloroacetic Acid C2H3CI02 .-+ Trichloroacetic Acid C2HCI302 21-24 (") Ill Nitromethane CH3N02 Maleic Anhydride c.H2o3 306 ::l Acetic Acid C2H•02 152 Nonane CsH2o a. Acrylic Acid C3H.02 164 CD X Butyric Acid C.H802 248 0 ...... Methacrylic Acid C•Hs02 231 CD 283 Z -9-0ctadecenoic Acid C,aH3.02 Carbon Disulfide cs2 ::l Octane CaH,a Acetic Acid C2H•02 147-148 Ill """' '< Acetic Anhydride C.H603 336-337 en Acrylic Acid C3H402 163 '< (/) Methacrylic Acid C.H602 229 .-+ CD 1-0ctene CaH,s Acetic Anhydride C4H603 333-335 3 Acrylic Acid C3H402 162 en

N-Pentanoic Acid CsH1o02 Chloroacetic Acid C2H3CI02 33-35

3-Pentenoic Acid (isomer not CsHa02 3-Pentenoic Acid Methyl Ester CsH,a02 26Q-262 specified) (isomer not specified)

3-Pentenoic Acid Methyl Ester C6H1002 3-Pentenoic Acid (isomer not CsHa02 26Q-262 (isomer not specified) specified)

Pentyl Acetate C1H,.o2 Acetic Acid C2H•02 141-143

Butyric Acid C•Ha02 245

Propionic Acid C3Hs02 Acetic Acid C2H•02 5!Hl4R

Acetic Anhydride C.Hs03 180-183

Acetonitrile C2H3N 173-174 Aniline C6H7N 201-202

Benzene CaHa 199-200R

Butyl Acetate CaH1202 210

Butyric Acid C.Ha02 184-186

Cyclohexane CaH12 205-208R

Ethyl Acetate C•Ha02 187

Ethyl Propionate CsH1o02 191-198R

Formic Acid CH202 14-16

Heptane C1H1a 214-218R Hexane CaH,. 211 )> 1-Hexene CaH12 209 "'0 ::r Isobutyric Acid C•Ha02 188 Ill 0" Propionic Acid, Anhydride CaH,oOs 203-204 CD r-+ Propyl Bromide C3H7Br 175-179 (") Ill Pyridine C5H5N 189-190

Tetrachloromethane CCI4 166-172 ::J 0. Toluene C1Ha 212-213 CD >< Propionic Acid, Anhydride CaH,oOs Propionic Acid CsHa02 203-204 0 Propyl Acetate CsH1o02 Acetic Acid C2H402 103 -

Propyl Bromide C3H7Br Acetic Acid C2H402 65-69R (JJ ::J Propionic Acid CsHa02 175-179 Ill """': Propyl Butyrate C1H,.o2 Butyric Acid C•Ha02 246 '<

Pyridine CsHsN Acetic Acid C2H402 97-100 (J) '< Butyric Acid C•Hs02 239-240 en r-+ Formic Acid CH202 18-19 CD c.> Propionic Acid C H 02 189-190 3 -....J s a en ()1 c.u Sulfur Dioxide 028 Acetic Acid C2H•02 36 )> -....J "'C O'l C•HeOa 312 Acetic Anhydride :::r Ill Chloroacetic Acid C2HaCI02 31 Sulfuric Acid H2o.s o- Tetrachloromethane CCI4 Acetic Acid C2H402 38-42R CD r-+ Acetic Anhydride C•HeOa 313-319R ("') Ill Propionic Acid CaHe02 166-172

Tetradecane C,.H30 Hexanoic Acid CeH,202 269 ::::J a. Toluene C1Hs Acetic Acid C2H•02 139 CD X Acetic Anhydride C4H603 329-330 0 Benzoic Acid C1H602 273-278 -

Butyric Acid C•Hs02 244 CD ::::J 256 Isobutyric Acid C•Ha02 Ill Propionic Acid CaHe02 212-213 -< Trichloroacetic Acid C2HCia02 Chloroform CHCI3 25 (/) '< Nitric Acid HN03 21-24 (JJ r-+ Tridecane C,aH2s Valeric Acid CsH,o02 266 CD

C6H,5N Acetic Acid C2H402 131-138 Triethylamine (JJ3 Trifluoroacetic Acid C2HF302 Acetic Acid C2H402 27

N-Undecane c,,H2• Butyric Acid C•Ha02 249

Hexanoic Acid CeH,202 267

Methacrylic Acid C•He02 234

Valeric Acid CsH,o02 264

Valeric Acid CsH1002 Decane C,oH22 263

Dodecane c,2H2e 265

Formic Acid CH202 20

Tridecane C,3H2s 266

N-Undecane c,,H2• 264 Vinyl Acetate C•Hs02 Acetic Acid C2H402 75

Vinyl Butyrate CsH1002 Acetic Acid C2H402 113-114

Vinyl Propionate CsHa02 Acetic Acid C2H402 101-102

Xylene (isomer not specified) CaH,o Maleic Anhydride C4H203 311

m-Xylene CaH,o Methacrylic Acid C4H602 226

o-Xylene CsH10 Acetic Anhydride C.Hs03 332

Maleic Anhydride C4H203 310

� "'0 ::::r DJ rr CD z (') DJ

:::J a. CD X 0 - � :::J DJ ..... '< (/) '< en ...... CD (1.) 3 -...J en -...J c.> Acetic Acid C2H•02 Benzene CaHs Propionic Acid C3Ha02 297 )> --..1 "'C (X) Tetrachloromethane CCI4 29D-291 ::::,- Ill Pentanoic Acid C H 02 300 Butyric Acid C•Hs02 s ,o 0" Ethyl Acetate C•H 02 Hexane C H14 301 CD s 6 .-+ Ethylbenzene CsH1o Styrene CaHs 302 (') Ill Heptane C7H1s Acrylic Acid C3H402 292 ::s Methyl Acetate C3H 02 Formic Acid CH202 284 s c.. Propionic Acid C3Hs02 Butyric Acid C.H802 295 CD >< Cyclohexane C H 2 298-299 s 1 0 - Ethyl Acetate C•Hs02 296

Formic Acid CH202 285-286 roi ""'' Propyl Bromide C3H7Br 293-294 ::s Ill Tetrachloromethane CCI4 289 -< Tetrachloromethane CCI4 Acrylic Acid C3H402 288 CJ) '< Acrylic Acid C3H402 Acetic Acid C2H•02 Heptane C7H1s 292 CJJ .-+ Tetrachloromethane CCI4 288 CD

Benzene CaHs Propionic Acid C3Hs02 Acetic Acid C2H402 297 CJJ3 Tetrachloromethane CCI4 Acetic Acid C2H•02 29D-291

Benzoic Acid C7Hs02 Biphenyl C,2H1o Toluene C7Ha 303-304

Biphenyl C,2H1o Toluene C7Ha Benzoic Acid C7Hs02 303-304

Butyl Formate CsH,o02 Pyridine CsH5N Formic Acid CH202 287

Butyric Acid C•Ha02 Acetic Acid C2H•02 Propionic Acid C3Hs02 295

Pentanoic Acid CsH1002 Acetic Acid C2H•02 300

Cyclohexane CsH12 Acetic Acid C2H•02 Propionic Acid C3Hs02 298-299

Ethyl Acetate C.H802 Acetic Acid C2H•02 Propionic Acid C3Hs02 296

Hexane C6H14 Acetic Acid C2H•02 301 Ethylbenzene CsH1o Styrene CsHs Acetic Acid C2H402 302

Formic Acid CH202 Acetic Acid C2H402 Methyl Acetate CaHs02 284

Propionic Acid CaHs02 285-286

Butyl Formate C5H1o02 Pyridine C5H5N 287

Heptane C1H1s Acrylic Acid CaH402 Acetic Acid C2H•02 292

Hexane CsH1• Acetic Acid C2H•02 Ethyl Acetate C.Ha02 301

Methyl Acetate CaHs02 Formic Acid CH202 Acetic Acid C2H402 284

Pentanoic Acid C5H1o02 Acetic Acid C2H402 Butyric Acid C•Hs02 300

Propionic Acid CaHs02 Acetic Acid C2H402 Benzene CsHs 297

Butyric Acid C4H802 Acetic Acid C2H402 295 )> ""0 Cyclohexane CsH12 Acetic Acid C2H402 298-299 ::r Pl Ethyl Acetate C.H802 Acetic Acid C2H•02 296 0'" CD Formic Acid CH202 Acetic Acid C2H402 285-286 .-+ (') C3H7Br Acetic Acid C2H402 293-294 Propyl Bromide Pl Tetrachloromethane CCI4 Acetic Acid C2H402 289 :::J Propyl Bromide C3H7Br Acetic Acid C2H402 Propionic Acid C3Hs02 293-294 a. Butyl Formate C5H 02 287 CD Pyridine C5H5N Formic Acid CH202 1o >< Styrene CsHs Acetic Acid C2H402 Ethylbenzene CsH1o 302 0 - Tetrachloromethane CCI4 Acetic Acid C2H402 Benzene CsHs 290-291

Propionic Acid C3H 02 289 coi s """'l :::J Acrylic Acid C3H402 Acetic Acid C2H402 288 Pl Toluene C7H8 Benzoic Acid C1Hs02 Biphenyl C12H1o 303-304 -< (J) '< (JJ .-+ CD cu 3 -...j (JJ CO ::J Acetic Acid C2H•02 Butyric Acid C.Ha02 N-Pentanoic Acid CsH,o02 lsocaproic Acid (4-C6H,202 305 a_o� Methylpentanoic Acid) CD Butyric Acid C•Ha02 N-Pentanoic Acid CsH10 02 lsocaproic Acid (4-C6H,202 Acetic Acid C2H402 305 >< Methylpentanoic Acid) 0 - lsocaproic Acid (4-CsH, 202 Acetic Acid C2H•02 Butyric Acid C•Ha02 N-Pentanoic Acid CsH,o02 305 Methylpentanoic Acid) 0 c N-Pentanoic Acid C5H,o02 lsocaproic Acid (4-CsH,202 Acetic Acid C2H•02 Butyric Acid C.Ha02 305 Methylpentanoic Acid) et CD .....,; ::J QJ -< (/) '< (/) r-+ CD

3(/)