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VAPOR-LIQUID EQUILIBRIUM DATA COLLECTION Chemistry Data Series J. Gmehling U. Onken VAPOR-LIQUID EQUILIBRIUM DATA COLLECTION Carboxylic Acids, Anhydrides Supplement 1 Chemistry Data Series Vol. I, Part Sa Published by DECHEMA Gesellschaft fur Chemische Technik und Biotechnologie e. V. Executive Editor: Gerhard Kreysa Bibliographic information published by Die Deutsche Bibliothek Die Deutsche Bibliothek lists this publication in the Deutsche Nationalbibliographie; detailed bibliographic data is available on the Internet at http://dnb.ddb.de ISBN: 3-89746-040-8 © DECHEMA Gesellschaft fOr Chemische Technik und Biotechnologie e. V. Postfach 15 01 04, D-60061 Frankfurt am Main, Germany, 2002 Dieses Werk ist urheberrechtlich geschOtzt. Alle Rechte, auch die der Obersetzung, des Nachdrucks und der Vervielfaltigung des Buches oder Teilen daraus sind vorbehalten. Kein Teil des Werkes dart ohne schriftliche Genehmigung der DECHEMA in irgendeiner Form (Fotokopie, Mikrofilm oder einem anderen Verfahren), auch nicht fOr Zwecke der Un­ terrichtsgestaltung, reproduziert oder unter Verwendung elektronischer Systeme verarbei­ tet, vervielfaltigt oder verbreitet werden. Die Herausgeber Obernehmen fOr die Richtigkeit und Vollstandigkeit der publizierten Oaten keinerlei Gewahrleistung. This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, including those of translation, reprinting, reproduction by photo­ copying machine or similar means. No part of this work may be reproduced, processed or distributed in any form, not even for teaching purposes - by photocopying, microfilm or other processes, or implemented in electronic information storage and retrieval systems -without the written permission of the publishers. The publishers accept no liability for the accuracy and completeness of the published data. This volume of the Chemistry Data Series was printed using acid-free paper. Technical Production: Mitterweger & Partner, Plankstadt Vapor-Liquid Equilibrium Data Collection Sa Carboxylic Acids, Anhydrides Supplement 1 Tables and diagrams of data for binary and multicomponent mixtures up to moderate pressures. Constants of correlation equations for computer use. J. Gmehling, U. Onken Technische Chemie Universitat Oldenburg Sa Carboxylic Acids, Anhydrides Systems with: Aliphatic and aromatic carboxylic acids Acetic Acid Lauric Acid Acrylic Acid Methacrylic Acid Benzoic Acid Z-9-0ctadecenoic Acid Butyric Acid 3-Pentenoic Acid (isomer not specified) Chloroacetic Acid Propionic Acid Dichloroacetic Acid Trichloroacetic Acid Formic Acid Trifluoroacetic Acid Hexanoic Acid Valeric Acid Isobutyric Acid Anhydrides Acetic Anhydride Maleic Anhydride vii AUTHORS' PREFACE With this volume we have pleasure in publishing a new supplement of the Vapor­ Liquid Equilibrium Data Collection for carboxylic acids and anhydrides as DECHEMA Chemistry Data Series Volume I Part 5a. The data in this book are taken from the Dortmund Data Bank and are available in electronic form. The Dortmund Data Bank covers a wide range of properties in E addition to the VLE, h , yoo, for example: data bases of the vapor-liquid equilibria of low boiling substances (HPV), azeotropic data (AZD), gas solubilities (GLE), solid-liquid equilibria (SLE) and a pure component property data base (PCP). Data in electronic form can be obtained from DDBST GmbH, Oldenburg, Germany or DECHEMA e.V., Frankfurt am Main. Data collections for inhouse use are available from DDBST GmbH; DECHEMA e.V.; FIZ Chemie GmbH, Berlin, Germany and Aspen Technology, Inc., Cambridge, Massachusetts, USA. DDBST GmbH can also supply a large program system well suited to handling the data in the data banks. Online versions of the database are hosted by STN International (Columbus, Ohio, USA; Karlsruhe, Germany and Tokyo, Japan) and DECHEMA e.V. (via the Internet). We would like to thank J. Krafczyk and J. Menke for computer programming assistance in order to allow publication of data determined under non-isotherm and non-isobaric conditions. In addition we would like to sincerely thank all those colleagues who have both supported and continue to support the endeavours of the thermodynamic group at the University of Oldenburg by delivering VLE data from their research. At this juncture we would like to request other colleagues in this field to send us unpublished data and reprints of their publications on thermophysical properties. Oldenburg, November 2002 J. Gmehling U. Onken viii EXECUTIVE EDITOR'S PREFACE The aim of DECHEMA e.V., The Society for Chemical Technology and Biotechnology when it was founded in 1926 was to improve cooperation between chemist and engineer. As the importance of mathematical modelling, computer simulation and optimisation became apparent in the mid-nineteen-seventies, this ideal resulted in the production and publication of collections of basic thermophysical data in both electronic and book form. This is not data that could have easily found a publisher outside the engineering societies, because of its sheer volume and limited circle of interest. By its sponsoring and publication of the DECHEMA Chemistry Data Series DECHEMA e.V. has been associated with these endevours for over a quarter of a century. Much of the original work to determine the values obtained was financed by the German Ministry of Research. lt is to be hoped that publication of this data collection by DECHEMA e.V. in the DECHEMA Chemistry Data Series will inspire other authors to consider publishing their collections of thermophysical data. DECHEMA e.V. is always pleased to assist colleagues from the thermophysical data community in preparing their results, their studies, their collections and their assessments for publication. DECHEMA e.V. is always prepared to enlarge the scope of the DECHEMA Chemistry Data Series and is thus pleased to hear from readers, designers, scientists and engineers of areas where thermophysical data is not available or scarce. We hope that the end user finds the data of utility and of interest. Frankfurt am Main, November 2002 Gerhard Kreysa ix CONTENTS6- Vol. I, Part/a Subjects of Volume I . .. .. .. .. .. .. .. .. .. .. .. .. VI Author's Preface .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. VII Executive Editor's Preface .. .. .. .. .. .. .. .. .. .. .. .. .. VIII Contents Volume I, Part Sa .................................. IX Guide to Tables . .. .. .. .. .. .. .. .. .. .. .. .. .. XI List of Symbols . .. .. .. .. .. .. .. .. .. .. .. .. XXI References ............................................ XXIII Data Tables Carboxylic Acids Binary Systems Formic Acid .............................................. Trichloroacetic Acid ........................................ 21 Trifluoroacetic Acid .. .. .. .. .. .. .. .. .. .. .. .. 27 Dichloroacetic Acid . .. .. .. .. .. .. .. .. .. .. .. 28 Chloroacetic Acid . .. .. .. .. .. .. .. .. .. .. .. .. .. 30 Acetic Acid . .. .. .. .. .. .. .. .. .. .. .. .. .. .. 36 Acrylic Acid .. .. .. .. .. .. .. .. .. .. .. .. .. 155 Propionic Acid .. .. .. .. .. .. .. .. .. .. .. .. .. 166 Methacrylic Acid . .. .. .. .. .. .. .. .. .. .. .. .. 219 Butyric Acid . .. .. .. .. .. .. .. .. .. 236 Isobutyric Acid . .. .. .. .. .. .. .. .. .. .. 250 3-Pentenoic Acid (isomer not specified) .. .. .. .. .. .. .. 260 Valeric Acid . .. .. .. .. .. .. .. .. .. .. .. .. .. .. 263 Hexanoic Acid ........................................... 267 Benzoic Acid .. .. .. .. .. .. .. .. .. .. .. .. .. 270 Lauric Acid .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. 280 Z-9-0ctadecenoic Acid .................................... 283 Ternary Systems ............................................ 284 Quaternary Systems . .. .. .. .. .. .. .. .. .. .. .. .. .. .. 305 Anhydrides ...................................................... Maleic Anhydride . .. .. .. .. .. .. .. .. .. .. .. .. 306 Acetic Anhydride ......................................... 312 X Appendix A: Pure Component Parameters . .. .. .. .. 329 Appendix B: Dimerization Constants of Carboxlic Acids 347 Formula Index of Binary Systems . .. .. .. .. .. .. 349 Formula Index of Ternary Systems .. .. .. .. .. 362 Formula Index of Quaternary Systems . .. .. 364 Alphabetical Index of Binary Systems . .. .. .. .. .. 365 Alphabetical Index of Ternary Systems ... .. ..... .. ...... ...... 378 Alphabetical Index of Quaternary Systems . .. .. .. .. .. 380 028 Sulfur Dioxide C2H•02 Acetic Acid 36 C•Hs03 Acetic Anhydride 312 HN03 Nitric Acid C2HCI302 Trichloroacetic Acid 21-24 C2H3CI02 Chloroacetic Acid 30 C2H•02 Acetic Acid 37 H20•S Sulfuric Acid C2H3CI02 Chloroacetic Acid 31 CCI4 Tetrachloromethane C2H402 Acetic Acid 38-42R C3Hs02 Propionic Acid 166-172 C.Hs03 Acetic Anhydride 313-319R cs2 Carbon Disulfide C.H603 Acetic Anhydride 322 C.Ha02 Butyric Acid 236 C,aH3.o2 Z-9-0ctadecenoic Acid 283 11 0 CHCI3 Chloroform C2HCI302 Trichloroacetic Acid 25 """'' C2H2CI202 Dichloroacetic Acid 28 3 c C2H3CI02 Chloroacetic Acid 32 Ill C2H•02 Acetic Acid 43 ::J a. C•Hs02 Methacrylic Acid 219 CD >< CH202 Formic Acid C2H3N Acetonitrile 1 0 C2H•02 Acetic Acid 2-7 - Methyl Formate 8-11 OJ ::J C3H5CI 3-Chloro-1-Propene 12 Ill """'' C3Hs02 Methyl Acetate 13 '< Propionic Acid 14-16 (/) '< C3H1NO N,N-Dimethylformamide (DMF) 17 CIJ ro+ CsHsN Pyridine 18-19 CD U) CsH,002 Valeric Acid 20 3 � CIJ <0 "'T1 Ul CH3CI Methyl Chloride C.Hs03 Acetic Anhydride 320 c.n 0 0 """' CH31 Methyl Iodide C H402 Acetic Acid 44 2 3 C•Hs03 Acetic Anhydride 321 c CH3N02 Nitromethane c.H2o3 Maleic Anhydride 306 Ill C2HCI302 Trichloroacetic Acid HN03 Nitric Acid 21-24 ::::::1 a. CHCI3 Chloroform 25
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