<<

i TERRITORY OF ALASKA !I 1 DEPARTMENT OF MINES [ B. D. STEWART ~omrnissionerof Mines

s$@ 'i Industrial as a Field for t4 Prospeding in Alaska including I a . A Glossary of Elemenis and 1E Minerals $1

JUNEAU, ALASKA March, 1946 CONTENTS PREFACE Page Foreseeing that Alaska must develop industrial enterprise in ...... preface ...... 3 order to support further population increases, it is the hope of the ...... author that the information presented here will awaken an Introduction ...... 5 i~~terestin many metallic and non-metailic minerals that can ilI- ...... ldentlflcadoll ...... 6 afford .to be overlooked if there is to be an orderly development ...... Assaying ...... : ...... --:...... 5 of Alaska. Industrial growth and substantial population gains mglrserlngservi,ys md exrminal\o~u...... 6 must *go hand in hand. One cannot exist in Alaska without the other. Lapidary ~IVIC(J...... The success and even the existence of new industries may well Ol,,errervi ...... 7 depend up011 local develupment of minerals previously deemed ...... 9 The elemen& ...... -.,,...... valueless. As an illustration; should the paper and pulp industry in Territory, there would immediately ~h~ rnlnerals ...... 30 become established the exist an interest in paper clays, , sulphur, and. other raw materials. Markets may indeed be small at first, but advance knowledge of the existence and location of certain minerals may be the deciding factor in influencing the establishment of small industry which, we may trust, will thrive. The average person fails to realize the extremely important part that minerals play in the everyday existence of modem civilization. To produce this . sheet of paper required the use, in some way or another, of , sulphur, , salt, gypsum, talc, and even the lowly sand- stone and clay. No attempt has been made in this report to restrict it to those - minerals of immediate value in Alaska. Some of those listed will remain more or less valueless ,until such time as the development of the Territory makes possible their local 'utilization. The ex- ploitation of some may be hastened by industrial expansion along the coast of Washington, Oregon and California. (This is a strong possibility due to the development and availability of cheap hydroelectric power and, if that occurs, it would seem likely that some minerd raw materials, produced in Alaska and shipped by boat, could compete favorably with transcontinental rail deliv- eries.) Some, as will be readily seen, are in good demand, at high prices and warrant the fuIlest attention of the prospector. Still others, producible in small quantity, yet having high unit value, are of special importance to the average prospector as a means of ' financing himself for further prospecting. Of particular impart- 4 INDUSTRIAL MINERALS AS A FlEtD ance in this class is the collecting and sale of specimen material and gem'stones, both semi-precious and precious. Great detail is not possible in a report of this nature. It is hoped that the reader will supplement and amplify the informa- fion presented by co~lsultingup to date standard texts, especially INTRODUCTION those on mineralogy. Xt should be mentioned, however, that accurate identification of most of these minerals had best be done The information presented in these pages is based upon avail- in a wellequipped laboratory, and it is suggested that the pros- able information up to recent date, but during the present world pector avail himself of the free services offered by the Territorial collfIict there have been many outstanding technical developments Department of Mines, and send in all samples for identification taking place, so far unpublicized. When peace has been won we or for confirmation of his findings. The Department would also will learn of these new developments ; of new uses for both metals welcome the opportunity to be of service in suggesting or locating and minerals, many of them finding use in quantity for the first market outlets for any new mineral production. time. Others, the majority in fact, have long ago proven indispens- able tp the degree of civilization rve know today. To acquaint the prospector with these minerals; to assist him to realize the greatest benefits from his efforts, even though he map be primarily search- ing for gold, is the purpose of this report. Further development of the Territory largely depends upon his discoveries. Conversely, much of the ultimate value of his discoveries depends upon devel- opment of and by the Territory. To stimulate and encourage development of mining in the Territory is one primary purpose of the Territorial Department of Mines. No single project can accomplish more in that direction than the offering of the fullest support and assistance to the prospector and, of course, receiving his cooperation. The foll~ing services are available, free of charge.

Mineral ldentif ication Mineral identification service .is provided at the Juneau office and at the Assay Offices at Ketchikan, Anchorage and College (Fairbanks). Specimens sent for identification are elassif ied, and if ally commercially important mineral or metal is present, a brief. doscripti.on of its use and value is included in the report. If, in the opinion of the mineralogist, the specimen warrants an assay for any particular element, such assay is made and reported without the necessity of a specific request therefor.

Assaying Fully equipped assay offices are maintained at Xekhikan, Anchorage and College (Fairbanks). Prospectors are encouraged to submit samples to the most convenient office. When possible to do so, carefully taken channel samples should be submitted EN FOR PROSPECTING ALASKA 7

rather than band samples. Often samples are received with a rock or mineral suspected of being useful as an ornamental stone be sent be request for certain assays entailing much work, when a proper or gem may to this office where a polished surface will along knowledge of the rock, or possibly qualitative tests, would show prepared and returned to the sender with a report of its such work to be unnecessary and unwarranted. It is, therefore, possible usefulness and value- often necessary for the assayer to exercise his best judgment in determining how much labor is actually warranted in such cases. Other Services Although such informa'tion is not required, a brief description All offices of the Territorial Department of Mines welcome visits and inquiries. Files are kept that may be helpful in locating of the approximate location of the source of the sample would be appreciated by the Department. This information is most helpful purchasers for various minerals or in suggesting local utilization.. S. in maintaining files on the mineral resources of the Territory. All A library of U. Geological Survey bulletins, other Alaskan reports, and available for by anyone such information is kept strictly confidential. maps are study interested. Display collections of minerals also are accessible for study. It has been observed that some persons, fearing. thai they may become "bothersome", hesitate about submitting,samples. When- ever the prospector has any question as to the identity or content of any rock or mineral, the Department of Mines hopes that a - specimen wiH be submitted for examination. Many important minerals occur in inconspicuous and common appearing rocks.

Engineering Services and Examinations Field engineers in the employ of the Department of Mines are available for examining prospects, the owners of which are unable to afford the services of a private engineer. Requests for such examinations should be ltddressed to the Commissioner of Mines, Juneau, Alaska. Services available include sampling and mapping of mineral showings if a preliminary examination indi- cates that type of work is justified. The information obhined is

made available to the owner of the prospect in a form suitable for, , presenting to companies or individuals who might be interested in financing development and mining operations. Advice of the . engineer may also be obtained if desired on development and mining problems that are met in the course of bringing a newly discovered mineral deposit to the productive stage. Requests for engineering service should be accompanied by information that would be useful to an examining engineer, including location, nature and extent of the deposit so far as known, transportation available, season of the year most favorable for an examination, etc. Lapidary Services Equipment for the sawing and polishing of sheis a part of the facilities of the department office at College (Fairbanks). Any THE ELEMENTS

Although some 86 elements are known to exist, 21 of them are of no present practical value. The remaining 65, from the familiar aluminum, copper or gold, to the less well known zirconium, are all more or less important to industry and civilization as we know it today. Inclusion of this section, briefly discussing. these 65 elements, is intended to give a more com- prehensive understanding of the value and impoxtance attached to the less familiar elements.

ALUMINUM Aluminum will undoubtedly continue to play an i.mpurtant role in all types of industry. New uses and new alloys have bee11 developed and are constai~tly being improved upon. Increased production and 1;echnological advances d recent years will likely lower its price. As a result aluminum ores, to be of comm.ercial importance, must be favorably located, of good grade, and' exist in almost unlimited quantity. Commercial extrxction of aluminum from other more abundant sources, portends little hope for ores of alumiuum in Alaska. Alumillurn minerals, used for purposes other thau extraction of the metal, may hold promise, however. Aluminum is the most abundant metal, constituting about eight per cent of the earth's crust. It is a constituent of nearly all rocks but never occurs native. It is found chiefly in silicates such as , clays, micas, etc., but also as the oxide, CORUNDUM; the hydroxide, BAUXITE; as fluoride in CRYOLITE; and in various sulphates and . The gem stones ,GAR NET, , , , and TQURBlALINE are all aluminum minerals. The chief commercial sources of alumillurn are BAUXITE, and CLAY. Aluminum metal and its alloys are chiefly used as structural. material in aircraft and other articles of commerce. As an elec- trical conductor it competes with copper and there are many other -varied uses. LO INDUSTRIAL mLSAS A FImD I FOR PROSPECTING TN ALASKA 11 At present the metal in ingot form has a value of fifteen cents Very little use is made of metallic , most industrial per pound. usage depen@ng upon the oxide, which is used in insecticides, weed killers, and various chemicals. The metal is valued at about fifty cents a pound, Prior to the war most of the antimony used in the United I States was produced as a by-product of . Imported Chinese ore made up most of the balance. Pressure of war needs The dement barium never occurs native and has very little encouraged production of ores in the proper and in use in its metallic form. The chief minerals of barium are Alaska. However, normal demands are not particularly great. EAR- and WnHERITE, both of which are utilized for their own Profitable production of antimony ore in Alaska, therefore, is .. ITE particular properties for their barium content. Minor questionable. Antimony minerals are comnlonly associated with rather than amounts of the metal find some use in radio tubes and, when ores of gold and other metals. alloyed, in ignition systems. To be of commercia1 importance in Metallic antimony is rarely found native. Usually ,it occurs Alaska a deposit of barite would have to be large, high-grade, and as the sulphide, STIBNITE; also in various antirnonides, and easily accessible to transportation as it is low in price. Witherite * sulphantimonides of the heavy metals, and as secondary oxides. (barium carbonate) brings a higher price and might be of economic value under less favorable conditions. Metallic antimony is used in various alloys for the manu- facture of storage battery plates, type metals, bearing and anti- BERYLLIUM friction metals and chemicals. It has a value of fifteen cents a I pound. The beryllium industry is one of the most promising infant industries. Even before the present war the advantages of - ARGON lium and its alloys were deemed of great importance and the future of the metal seems assured. Any important source of beryllium A gaseous element of limited use, argon is commercially ore in the Territory would command attention, The price of recovered from the atmosphere. It constitutes about 0.94 per. BERYL, the mineral from which the metaI is recovered, is suf- cent by volume of the air and is also found in volcanic and other ficiently high to warrant Alaskan interest even at the present natural gases, and in a few minerals. No compounds of argon time. are known. It is used for filling of incandescent light bulbs and fluorescent tubing. This element is chemically related to aluminum and mag- . nesium. Like them, its importance lies in its application to the light; metals industry. Seldom used alone it is generally alloyed ARSENIC with copper, aluminum, , or silver. With copper it is -As in the case of antimony, most of the arsenic produced used in manufacturing special springs and similar small parts in comes as a by-pruduct of dornestjc smelters. Ores of arsenic offer scientific. instruments and business machines;. also in making little encouragement in Alaska for any realization on the arsenic "non-sparking" safety tools. Alloying with aluminum produces a content. Attention should, however, be paid to ores containing metal, lighter than aluminum, having the tensile strength of good arsenic minerals, especially ARSENOPYRITE, as they are fre- . steel, and comparatively non-corrosive. quently asociated with gold and other metals. 'Many factors govern the present price of beryllium metal, Arsenic is occasionally found native in limited amounts. and very likely the price will be substantially reduced as greater UsualIy i,t is 'combined with the heavy metals in the form of supplies of ore are discovered. Most of the metal is produced as arsenides .and sulpharsenides. Many such minerals are known. a four per cent aIloy with copper, selling for fifteen dollars per FOR PROSPECTmG lN ALASKA 13

12 INDUSTRIAL MINERALS AS A FIELD calcium is more widely used in modern in- pound of contained beryllium. Beryllium metal itself costs pbout Metallic being $46.00 per pound. dustry, yet the greatest attention will continue to be focused upon the important calcium minerals which are used in enormous quan- tities due to their own properties and uses. (see LIMESTONE and GYPSUM). Like antimony and arsenic, is commercially produced Recent advances in the metals industries have developed uses as a by-product of smelters and refineries. Demand for the metal for calcium metal in various of the Iight weight alloys. is good but there is little Ukelihood of profitable exploitation of ores for their bismuth content alone since by-product recovery will probably continue to supply all demands. The association with other metals of value is, however, important. Carbon is a non-metallic element occurring as a constituent 01 coal, petroleum, asphalt, carbonate minerals and all organic. Bismuth is frequently found in the native state in placer matter. Native carbon occurs as the minerals DIAMOHD and operations, but mare frequently it occurs as a sulphide. and oc- GRAPfiITE. casionally as a telluride, with gold, silver, copper, lead and zinc. It also is found with ores of tin, tungsten and molybdenum. CERIUM (see Rare Earth Elements)

Bismutl~is priiieipally used, ~IIalloys, for bearing and anti- frictioil metals, also in easily fusible alloys such as safety plugs CESIUM (Caesium) for boilers, fire-sprinkler systems and other special uses. The limited supply of ,cesium minerals has retarded commer- cial development of the metal. The unusual properties of this Market value of the metal, in ton lots, is $1.25 per pound. element and its compounds would very likely find more extensive application if adequate supplies were available. BORON The metal and its alloys are highly prized in photo-electric While the demand for certain minerals of boron is appreciable, celis, finding appjieation in sound movies, television, and else- thc ncn-metallic element itself is difficultly prepared and finds where. Considerable is used in the preparation of radio tubes. little, if any, use. Existing deposits are capable of supplying, at low cost, all world demands for the boron minerals. The minerals and are possible commercial sources of cesium. Little information is available regarding present prices; several years ago the metal solcl for $10.00 per gram. Bromine is important in modern industry but of little interest in this discussion since commercial recovery is largely obtained from sea water. Xt is used in the production of tetra-ethyl lead for the gasoline industry, also in chemicals and medicinals. Many and varied uses exist for this gaseous element but commercial production is derived from various industrial pro- cesses.. No mineral is mined expressly for the recovery of chlorine. A I-elativdy rare metal found almost entirely in associatioil It is ordinarily compressed from a gaseous to a liquid state with zinc ores from which it is recovered as-a by-product, cadmium and marketed in steel cylinders for use in (I) -water purification, is chiefly used in corrosion-resisting plating of iron ; also in alloys for bearings, etc., and in chemicals and pi.gments. 14 INDUSTRIAL MINERALS AS A FIELD FOR PROSPECTING IN ALASKA 15

(2) disinfectants, (3) preparation of chemicals, (4) bleaching COPPER agent. Most of the important copper minerals are readily recognized by most prospectors and, as a result. considerable attention has ,CHROMIUM been devoted to copper prospects in the Territory. Many favorable Extensive use in modem industry is found both for the metal occurrences are known and undoubtedly more will be discovered. and for the ore. Known Alaskan deposits have been developed With further development of the Territory bringing a reduction under the impetus of wartime requirements and continued or at in operational costs, copper mining should again play an important least future production may be possible if development of the role in Alaska. west coast steel industry continues- Important copper minerals are CHALCOCITE, CHALCO- CHROMITE is the ore from which the metal is recovered. , EORMZTE, TETRAHEDRITE, , and The metal is one of the principal elements used in the manufacture . Native copper is rather common and several areas in . of alloy steel, especialIy stainless steels.. The metal is valued at 80 Alaska offer in this regard. Copper ores commonly to 90 cents per pound. ,contain values in gold, silver, lead, nickel, eke.

Copper is widely used in construction and apparatus where COBALT workability and resistance to corrosion are important factors. Cobalt is another metal whose uses are constantly expanding. .Electrical uses are many as are the uses in alloys of various types, Any Alaskan occurrences of cobalt-bearing ores should command .particularly brass and bronze. Many other uses also exist. attention, not only for the cobalt content, but also for the nickel, copper, silver, gold and other values with which if may be asso- During recent years, prior to the war, the price of copper ciated. LINNAEITE, SMALTXTE and COBALTTTE are the uaual ranged from eight to twelve cents per pound. . ore minetals of importance. FLUORINE Alloys of steel and cobalt are used for cutting tmls, drills, welding rods and other special purposes. Electroplating and This element, a gas, is of little importance, yet its mineral ceramic coloring utilize minor amounts. The metal has a value -compounds~reof considerable commercial value. and of $1.50 to $2.00 per pound. ,CRYOLITEare particularly important because of their industrial .appbcations. COLUMBIUM

, GALLIUM The element columbium is a high priced metal, which because of price and probable increased demand, warrants special atten- . The rare metallic elenlent gallium has very limited use due tion. Present demands are based, to a great extent, upon military to the extreme scarcity of supply and the resultant high price. needs, but recent developments indicate substantial increase in What production there is comes as a by-product of zinc smelters peacetime consumption. It is recovered chiefly from the mineral as it occurs in zinc ores, iron ores and some alunlinous minerals. COLUMBITE which occurs in veins and dikes. Because of its unusual properties it finds use in high ternpera- The manufacture of special purpose steels and electronic tubes ture thermometers, optical mirrors, electron tubes and as a less are commercial uses. Present market price of columbium metal is poisonous substitute in filling teeth. Its value is approximately $225.00 to $260.00 per pound. $3.00 per gram. I6 INDUSTRIAL MINERALS AS A FIELD

FOR PROSPECITNG IN A~ASU 17 GOLD - Placer gold prospecting has been quite thorough in certain INDIUM areas of Alaska; some prospecting for placers having been under- This mekl now has several important applications and new taken almost everywhere. While there may yet be new discoveries, uses will likely be found but amounts used will be small. Most of it is felt that the future of gold mining in the Territory lies pre- that produced comes as a by-product of zinc refining, a source dominately in the lode mines. Particular attention should be given expected to supply normal demands. to complex ores containing little or no "free gold," and to large low grade deposits. The former have commonly been found and It occurs in minor amount in several metallic ores mainly passed by because identifiable gold was not seen, or the extraction those of zinc and iron. Uses include plating of bearings for appeared too cornpiicated. The latter have been neglected because internal combustion engines, plating of silverware, and jewelry economic conditions prohibited profitable recovery of the gold. and dental uses. Its value is $12.50 an ounce (Troy). Gold mining should increase markedly as the Territory is developed and operating costs decline. Gold is usually easily recognized when it occurs "free" or The world supply of this nonmetallic element comes mainly native, in placers and rich . Less easily detected is its from Chile where it is produced as a by-product of the nitrate presence in SULPHIDES, TELLURIDES,and other complex ores. industry. United States production is derived from treatment of sea-water, an unlimited source of iodine. About two-thirds of the gold produced is used as a monetary medium. The remaining one-third is largely used in the arts. It is used in various chemicals, medicine and photography, and is worth about $1.00 a pound. HELIUM . Inasmuch as available reserves in the States, largely govern- IRIDIUM ment owned, will be able to supply the demand, helium is not Although new uses are being found for iridium, they will particularly of interest in Alaska. ShouId natural gas be dis- . consume relatively small amounts of the metal. However, it will covered in any quantity. however, the possibie helium content continue.to be a valuable by-product of platinum mining. (See should be ascertained. Nalural gas is the chief source of helium. It is used in inflating dirigibles, observation and meteor- PLATINUM). ological balloons. Industrially it is used in diving equipment In spite of the price of 6120.00 per troy ounce, it is used and caisson work. Electric lamp manufacture, medicine and re in surgical tools scientific apparatus, pen points, electrical equip search are other users. mint, jewelry, etc.

HYDROGEN IRON This' is a common gaseous element widely used in industry. Iron deposits in Alaska, especially thwe located on or near It is produced by electrolysis of water, and other means, all usually tide water are of possible commercial importance if West Coast connected with some other industrial function. It is rather out- steel operations continue to expand. Cheapness of production is a side the scope of this report, but is included becauae it is an critical factor as the value of iron ore is very low. Only very large important element. deposits will warrant operation but seemingly small occurrences Uses include (I) welding, cutting, and melting of metals, (2) should receive sufficient attention to prove their extent. fixation of , (3) hydrogenation of oils, coal tar, coal, etc., Possible constituents of iron ores such as copper, nickel, vana- (4) formation of methyl alcohoI, and countless others. dium, manganese, and others shoutid be investigated. The pos- sibility that the iron ore is a gossan occurrence (a superficial FOR PROSPECTING IN ALASKA 19 covering over sulphide ore bodies or veins) should likewise be . industry in the States resulted in unprecedented production from investigated. Such a gossm may cover important copper or gold both. Future production may eventually come largely from sea depusita. (See GOSSAN) water, but other possible mineral sources are also being inves- tigated: Magnesium minerals in Alaska are not likely to be used Important iron ore minerals are , for extraction of the metal, but several may become useful for and MAGNETITE. Others, useful for other reasons than extrac- properties of their own. BRUCITE, DOLOMITE, and TALC, as tioil of the metal, are PYRITE, and PYRRHOTITE. well as MAGNESITE, are a few that may find commercial outlets. The uses of iron are numerous and well-known. CommereiaI Magnesium metal has gained in importance until it now ranks pig iron is valued, roughly, at $16.00 to $18.00 per ton. along with aluminum and copper. A very light metal, like alum- inum, it also is of paramount importance in light metal industry. In addition, it; finds use in pyrotechnics, chemicals, etc. It is Numerous prospects containing lead are known in Alaska, worth about twenty to thirty cents per pound. most of them in areas where profitable exploitation is questionable or impossible at the present time. Some of these areas should receive further attention to determine their probable value, MANGANESE special attention being paid to other values possibly contained in 1. , The steel industry relies heavily on the use of manganese, yet, the ore. very little is normally produced from domestic sources, the bulk The principal ore of lead is usually containing some, of requirements being imported. Substantial quantities of hlgh often large, amounts of silver. Copper and zinc are often present grade manganese ore, if found in a favorable location in Alaska, might possibly b6 of value. and in some instances rich gold ore is found with the galena. I I Numerous other lead minerals of minor importance are rather The minerds of importance are PYROLUSITE, PSILOME- common. LAME, , and RHODOCBROSITE. Lead is utilized in (1) construction work where corrosion- Manganese is used h various steel and copper alloys. It is resistant and pliable metal is needed, (2) alloys, particularly solder, ,worth about thirty-seven cents a pound. type metal, pewter, fusible alloys, (3) storage battery plates, (4) shot and bullets, (5) chemicals, etc. Prices before the war were from four to six cents per pound. Mercury is the.only metal in liquid form at ordinary tern- . peratures. It is an important element obtained from the mineral Recel~ttechnological develdpments indicate a wider applica- CINNABAR, which occurs in several districts within the Terri- tion of this metal and increased demand. It is the lightest metal tory, notably along the Kuskokwim River. Substantial quantities known. a fact which .is of great importance in the trend to light of mercury have been produced from this area in spite of high metals and alloys. -costa and isolated location- Under more favorable conditions, Lithium metal is recovered from the minerals LEPIDOLITE, , resulting from development of the Territory, there is little reason ,and others. At present the price of metallic lithium f ,todoubt that production could be greatly expanded. is $15.00 per pound. Mercury is used in (1) barometers, thermometers, pyro-

; - meters, etc., (2) mercury arc lamps; (3) mirrors, paints, drugs, R.1 A GN ESIUM ' chemicals, (4) boilers and electric transformers, (5) amalgamation The production of magnesium utilizes two main raw materials, .of gold. Normally its market price ranges from $1.00 to $1.30 MAGNESITE and sea water. Wartime development of this : :per pound. FOB PROSPECTING IN ALASKA 22 OSMIUM MOLYBDENUM . One of the little used members of the platinum group of This is another metal demanded by the steel industry in elements, osmium is produced as a by-product of platinum mining. appreciable amounts. Existing sources apparently are capable of (See PLA'..INUM). supplying most of the demand, but if a large deposit of MOLYBDE Very minor amounts are utjlized in alloys for the manufacture NITE ore could be developed in Alaska, it might be of value. of pen points and fine instrument bearings. Its value is $60.00 Molybdenum metal finds use in special steel slloys for cutting per ounce (Troy). tools, transportation vehicle construction, bearings, ete. It has a value of. $2.50 to $3.00 per pound. As an element 'oxygen is a gas occurring in a free state in NEON the atmosphere. Combined chiefly in silicates, it is a constituent A rare gaseous element obtained commercially from the of all important rocks and many minerals. Oxygen gas is com- atmosphere, neon is the basis for the establishment of the gaseous mercially produced, rather &imply, from the atmosphere and tube lighting industry. It is especially adapted to use in beacon, marketed for a number of uses. Large quantities are used, with airway and display lighting. or acetylene, for welding and cutting of metals. It is also employed to compensate for oxygen deficiency in high level air travel, medical purposes, etc. NICKEL The United States is almost entirely dependent upon imports for its supply of ore. In view of the numerous industrial nickel Next to platinum, palladium is the most extensively used uses of this element and the quantities consumed, nickel-bearing as ores, wherever found in Alaska, should receive careful investiga- element of the platinum group (see PLATINUM). About half common as platinum but Iess costly, most palladium is derived tion. The nickel content of various iron minerals is too frequently from platinum mining. However, an important in overlooked. source Alaska is a copper, gold, silver, palladium ore on Prince of WaIes Island. Minerals known to contain nickel in ambunts sufficient to It is also known to cccur 'in other copper or nickel bearing ores constitute ore are PYRRIIOTITE, PENTLANDITE, GARNIER- associated with basic rocks. XTE, NICCOLITE, and several others which usually occur finely It is widely used, chiefly as an alloy in (1) dentistry, (2) disseminated in some ores of copper, platinum, cobalt or iron. rnanvf~cture of watch and instrumetlt parts, (3) jewelry, (4) Nickel is used in many and various alloys, coinage, magnets, electricai equipment. Its present value is $24.00 per ounce (Troy). electrical equipment, etc. Its value is thirty-five cents per pound. NITROGEN Elemental phosphorus has few uses, yet its compounds have many. Phosphorus is prepared commercially from certain of its This gas is the predominate element in the atmosphere. It minerals, but the same minerals are more important for the . also is a constituent of organic matter and the nitrate minerals, but commercially it is largely derived from the atmosphere. Ni- .. preparation of other compounds and chemicals used largely in . . fertilizers. trate minerals are valuable in a sense somewhat apart from the consideration of elemental nitrogen, and play a vital role in the Phosphorus is used in relatively small amount in pyrotechnics, chemical industry. Commercial deposits are found only In arid . . smoke screens, poisons, match manufacture and gas analysis. , regions, however. +r, .. - FOR PROSPECTING W ALASKA a5 SODIUM

Elemental is little used and of no particular value. Metallic sodiim is obtained by electrolysis. and occurs in However, its numerous natural compounds include a great number nature only in the form of compounds with other elements. .As of economically important minerals, some of which will eventually such it is a constituent of many minerals which are utilized for be developed in the Territory. Such minerals are commonly re- their own properties. It is largely used by the chemical industry ferred to as silicates, varieties of QUARTZ or SILICA. for the manufacture of numerous sodium compounds. It is worth fifteen cents a pound.

STRONTIUM Many and varied uses are now common for metallic selenium, Strontium metal is little used, although its mineral compounds but special interest is attacked to the importance of one char- are rather widely employed. The minerals used are CELESTlTE acteristic physical property, that of its change in conductivity and STRONTPANITE. whe11 brought from darkness into light. Many uses are now based on this property and continued attempts are being made to develop SULPHUR oth~rs. It is quite probable that the demand for selenium will increase. However, because of the comparatively large quantities Crude suIphur and PYRITE are the two sources of contrnercial recoverable as a by-product from smejting and refining of sulphide sulphur. Both occur in Alaska and although no development has ores, that source will likely continue to supply the demand. ever advanced beyond the initial stages, further exploitation of the crude sulphur deposits may yet be warranted. Where sulphur Selenium is a metallic element somewhat akin to sulphur with deposits are unavailable or remote, sulphur is sometimes obtained which it is commonly associated. Many SULPHZDE ores, mined by the-roasting of PYRITE or other sulpfiide ores. for values in copper, lead, silver, merculy and other metals, con- tain some selenium, but it is never mined for that content alone. Further industrial expansion along the Pacific Coast of the States, and establishment of the paper pulp industry in Alaska, It is chiefly used in (1) photo-electric cells, photometry, (2) would be two important factors affecting future exploitation of glass manufacture, (3) vulcanizing rubber, (4) insecticides, (5) Alaskan sulphur deposits. All the sulphur now used by industries . fire-proofing electric cables, etc. It has a value of $1.75 per poul~d. along the coast is shipped from TexasAby boat, necessitating a - much longer voyage than that from Alaska. Low price and limited markets prevent active interest at present. SILVER Sulphuric acid, a very important industrial item, is made from Much of the discussion under "GOLD" also applies 'to silver - sulphur. It is also used in paper making processes, fertilizer, inaslnuch as the bulk of that metal produced in Alaska occurs as a natural alloy with the gold. Development of lode mines producing plastics, insecticides, vu!canizing rubber, etc. Sulphur is sold for $16.00 per ton. copper and lead! as well as gold, will result in a substantid increase in the silver production. Attention to the SULPHIDE ores may also result in rich sjlver ore being identified. ARGEN- TANTALUM TITE, and PYRARGYRITE are high grade silver minerals. Tantalum is a rnetaIIic element closely related to columbium with which it occurs. As is also true of columbium, new develop Silver is employed in- coinage, silverware, silver plating and menis indicate material expansion in the useful applieatiolls of in the preparation of many chemical compounds, as well as in a j : tantalum. It .is a high priced metal and the production of even number of industrial metal parts. ; small quanties of the ore mineral TANTALITE would be most Silver is valued at 71 cents per ounce (Troy). ' profitable. 26 INDUSTRIAL MLNEALS AS A FIELD FOR PROSPECTING IN ALASKA 27

The metal, extracted commercidly from TAWTALITE, is used TERITE. in ( I) the manufacture of acid-resistant laboratory utensils, sur- Tin is used in tin plate, solder, foil and numerous alloys. IB gical tools and equipment, (2) vacuum tubes and electrodes, (3) value is f Sty-two cents a pound. special alloys, both ferrous and non-fel~ous. It is valued at about $70.00 a pound. TITANIUM TELLURIUM The metallic element titanium. and its compounds, are widely Because of the meager industrial use of the element and the used in many different industries with promise of becoming even fact that ample production can be maintained from the treatment more important. Titanium minerals are numerous and quite com- of residues of copper, lead and gold smelting and refining. tel- mon but must be found in considerable quantity to permit profit- lurium is of minor interest. Of greater interest is the possible able mining. association of tellurium with other ores, particularly those of gold It occurs only in combination, the chief minerals being and silver. (see TELLURIDES). ZLMENITE and RUTILE. Some iron ores have a high titanium he metal is used in alloys of lead for the fabrication of pipes, content. coils, tanks, etc. Other alloys, with copper and various steels are In alloys, titanium is prepared and used as ferro-titanium, employed. Minor amounts are employed in the staining of glass cupro-titanium, etc. In the steel making process it is also em- and china. Its value is about $1.76 a pound. ployed as a scavenger. Titanium compounds find a wider usage, being used in large quantities in the manufacture of enamels, THALLIUM, rubber, plastics, welding rods and in the textile and dying indus- A rare element, of which only minor qua~ltitiesare consumed, try; also as a in paint manufacture. Titanium metal is thallium is produced as a by-product of smelters and sulphuric worth about $6.00 per pound. acid plants. No minerals are mined expressly for thallium, but, as a minor impurity, it occurs in pyrite, rnarcasite and other. TUNGSTEN sulphides. Tungsten metal, recovered from the ore minerals SCKEEL- It finds use in the preparation of artificial stones, optical 1TE, WOLFRAMITE, HUBNERTTE, and FERBERITE, is vitaIly glass, rat poison and in col-rosion-resistant lead alloys. It sells for important to the steel industry and there are other applications $12.00 a pound. as weU. THORIUM (see Rare Earth dements) .It is added in comparatively large quantities in the making of speck1 steel alloys for high speed tools, metal cutting tools and TIN dies, etc. The metal is also employed in the manufacture of elec- tric lamp and radjo tube filaments, contact points, and various Small quantities of till ore (CASSITERITE) will continue to chemicals. Tungsten is valued at $2.50 to $2.75 a pound., be produced in Alaska chifely as a by-product of placer gold opera- tions in a few loealitiss, but the future of Alaskan till mining appears to depend largely on new discoveries. Special attention to URANIUM finding and prospecting PEGMATITE veins and dlkes is warranted The main interest in uranium today centers about the scien- for besides CASSITERITE, other important minerals and metals tific investigations of its possible use as a source of power. Several are likely to be found. laboratories engaged in these studies have definitely established Although other tin minerals are known, metallic tin is com- that one pound of uranium can be made to yield as much power as mercially derived almost entirely from the smelting of CASSI- five million pounds of coal or three million gallons of gasoline. 28 INDUSTRIAL MINERALS AS A FTELD FOR PROSPECTING IN ALASKA 29 Whether there will be any commercial applicatioi~ of this is extremely problematical to say the least. for ZIRCON, the ore mineral of greatest importance, should include examination of beach sands and other alluvial deposits. What little metallic uranium there is produced today is de- The manufacture of radio tubes, welding electrodes and both rived cl?iefiy from the ore minerals and PITCH- ferrous and non-ferrous alloys all employ metallic zircon and new BLENDE and is used in the making of chemicals and for scientific applications are being found. Present price of zirconium metal is investigations. $7.00 per pound.

Vanadium is an important industrial metal but because of apparent ample supplies elsewhere, any Alaskan occurrence would probably have to be extensive or associated .with other profitably extractable metals befoxe it could be of economic value. Two ores are KOSCOELLTE and VANADINITE. ATost all ura~~iumminerals contain vanadium and there are many othexs. Vanadium is used as an alloy to produce steels requiring toughness quch as axles, pistons, etc.

ZINC Much of what has been said under the headings of copper and Iead applies likewise to zinc. Nearly a11 known zinc prospects in Alaska early some values in other metals, usually gold, silver, lead or copper. Zinc mining alone would command little ahtion in Alaska unless the deposits were very large and favorably situated, but some production Srom deposits where the ore is mined chiefly for gold, silver, lead or copper may be profitable. The principal ore of zinc is SPHALERITE, although SMLTH- SONITE;, ZlNCITE and WILLEMlTE sometimes occur in quantity sufficient to constitute valuable ores. Uses for zinc include galvanizing, manufacture of utensils, zinc salts and numerous alloys; also in batteries, castings, printing plates, etc. In normal times the price of zinc ranges from five to seven cents a pound.

ZIRCON WM

The last few years have witnessed a greatly improved demand for zirconium and even more interest is indicated. Prospecting FOR PROSPECTING IN ALASKA 31 .- .- AGATIZED WOOD Agatized wood is composed essentially of . THE MINERALS Unlike true agate the color is usually some shade of brown. Some of the original wood structure may be visible, particularly on The minerals, both metallic and non-metal- outer surfaces. Prices and demand may be slightly greater than lie, considered in this section, constitute the those for agate. raw materials required to furnish practically all of the necessities and luxuries of our daily ALABASTER existence. How many of these can be developed Alabaster is a compact, fine grPtined translucent GYPSUM in the Territory, for both local use and export, used in minor amount for sculpture and decorative objects, vases, will be a deciding factor in the growth of Alaska. etc. Good quality material may be worth from ten to twenty-five Even though the prospector may be chiefly cents per pound. interested in gold, he will be wise to pay careful attention to these other minerals.

The slums are soluble, crystallized; double sulphates of potas- s.i.um, sc6ium, iron, or other elements. No deposits of importance are likely in Alaska since they occur in quantity only in arid Actinolite is a type of AMPIJIBOLE usually occurring as light; green bladed in irregular fibrous aggregates or in com- regions. pact granular masses. It is a rather common mineral used to a ALUNZTE minor extent, with tar, as a roofing material. and A particular variety known as actinolite asbestos has the Alunite is a hydrous sulphate of potassium aluminum, often with some sodium. It closely resembles KAOLINITE characteristic white, silky, asbestos appearance ad, i£ of good in water quality, may qualify for one or more of the uses of ASBESTOS appearance. Generally it results from the action of acid on -minerals. (See ASBESTOS). feldspathic rocks. It is a source of potassium for use principally as a fertilizer. As a possible commercial ore of aluminum it is AGATE i-eceiving some present attention. Agate is a chdcedonic or cryptocrystalline variety of quartz AMAZONSTONE in which the color may be in bands, clouds or in distinct groups. It is considered a semi-precious stone and is found chiefly in Ama'zonstone is a green microline sometimes stream gravels but sometimes in loose soil resulting from weather- used as a - Found in PEGMATITE veins and dikes, in ing of the rocks. Often an unattractive, dull exterior will cause good crystals, its color strongly resembles that of JADE. one to overlook a beautiful specimen. Breaking of a specimen will 'likely destroy its value, but one soon leal-ns to recognize their appearance and can save them unbroken. Amber is a brittle, translucent fossil resin of a yellowish or Agate of good quality finds ready market with jewelers, lapi- brownish color. It is usually found in or near lignite-bearing daries and collectors. Like most gem materials the value of any 'sandstones and, in some areas, upon sea beaches. It will float in specimen depends upon the attractiveness or desirability of that salt water. Rubbing with a soft cloth easily electrifies amber -particular piece. In general prices range from a few cents for allowing it to attract small bits of paper. From it are made average stones up to several dollars for choice polished pieces. objects such as beads, earrings, pipe stems, etc. By nature of its FOR PROSPECTING IN ALASKA 3s -- -....-- Used in ceramic work, 1nain1y in the manufacture of spark mcde of occurrence amber sometimes contains trapped liquids, plugs, it is valued according to grade, from $20.00 to $40.00 per insects, e'ic., and these examples are highly prized by collectors ton. and museums. Clear crystals, and a variety containing black, cross shaped inclusions, are used as gem stones. This latter variety is known AMBLYGONITE as "Chiastolite." Amblygonite is a of lithium and aluminum with some fluorine. Its usual occurrence is as coarse white masses or aggregates; sometimes in large distinct crystals. It is found in associated with other lithium minerals. Ambly- , lead sulphate, is a secondary mineral formed in gonite is an important source of lithium as it contains about through oxidation of GALENA, and occurring white or pale nine per cent (Li'O). Market quotatioas list a value colored crystals or masses. Ordinarily it is not an important ore be of $40.00 to $50.00 per ton for material assaying eight to nine of lead, but wherever found GALENA shou!d sought. per cent. ANTHOPRYLLITE Anthophyllite is a type af AMPHIEOLE which occurs in the Amethyst is a purple or violet transparent variety of quartz form commonly known as ASBESTOS..Anthophyllite asbestos has which owes its color to a minor amount of manganese impurity. considerable value in iiisutating materials, piasters, wall board Otherwise it is the same as common crystalline quartz. Good and paint manufacture; also used with cement or asphalt in quality material is always in fair demand for use in jewelry. road building. (See ASBESTOS)

AMOSITE . (Phosphate Rbck) Amosite is an amphibole ASBESTOS useful chiefly in the Apatite is calcium phosphate. Commercial deposits are oftell manufacture of heat insulating materials. (See ASBESTOS) of an impure massive type varying widely in both color and tex- ture, thus they are often mistaken for limestone, volcanic ash or a number of other minerals. Chief use for apatite or rock phosphate is-as a fertilizer, consequently it has a low unit value. Amphibole is a name applied to a cedain group of minerds, some of which wilt be discussed under separate headings or under AQUAMARINE ASBESTOS. Aquamarine is the name given the pale greenish blue, trans- See : parent variety of BERYL. It is highly prized as a gemstone. (See Actinolite Crocidolite BERYL) Anthophyllite (Jade) Amosite TI-emolite ARGENTITE (Silver Glance) AND ALUSITE Argentite is a black silver sulphide containing 87 per cent silver. It is usually found in veins in small masses, or as an earthy ' Andalusite is aluminum silicate and occurs as Iarge coarse, coating, associated with other silver rnineraIs; also galena. Jt is nearly square, prismatic crystals; also massive. It is found in the most 'common and important silver mineral. (See SUE metamorphic rocks such as weisses and schists, especially near PHTDES) or pegmatites. - 34 INDUSTRIAL MINERALS AS A FELD FOR PROSPE-ING IN ALASKA 35

ARSENOPY RITE (Mispickel) ASPHALT Arsenopyrite is a common sulphide mineral somewhat re- Asphalt is a black to brownish black, brittle, skmi-solid sembling pyrite except for its silver white color. Because of its mixture of hydrocarbons which will melt and burn in a match usual associatio~~sit is a good indicator of possible values in gold flame. It is often confused with a number of other similar hydro- and other metah. Any deposit containing arsenopy rite should carbon minerals which, like asphalt, are found in petroleum and have a sample submitted for assay. coal bearing areas. "Asphalt rock" is a limestone or sandstone Arsenopyrite is the chief source of arsenic but is seldom impregnated with asphalt and, from which asphalt can be ex- tracted. , mjnecl for that purpose nlo~~e(see ARSENIC). Except for the other values commonly found with it, it is of no value. Principal local uses for asphalt would include surfacing rnater- ial Tor roads and airports although many other uses also exist. ASBESTOS Asbestos is the popular name for several fibrous forms of AZURITE serpentine and amphibole, hence the. asbestos of commerce is Azurite is a blue, hydrous copper carbonate found in the usually typed under these two general heads. Many varieties of oxidized zone of copper deposits, often with MALACHITE. Good each exist, the irnpurti~ntasbestos minerals being listed below. quality material is in demand by collectom, lapidaries and jewelers, Each is elsewhere mentioned under its separate heading. although AZURMALACHITE and MALACHITE bring better prices. A dollar or so a pourrd, however, is not uncommon for AMPHIBOLE TYPE SERPENTINE TWE ' AZURITE suitable for polishing. Actinoli te C;hrysotile An thophyllite Amosi te AZURMALACHITE Crocidolite Tremolite Azurrnalachite is an intimate mixture of AZURITE (blue) aid MALACHITE (green). It is readily purchased by jewelers, Fibers may be separated fronz an,y asbestos by rubbj~~gbe- lapidaries and collectors at a price of several dollars a pound. tween the fingers. Characteristics and properties of this fiber . give some rough idea of the grade. BALL CLAY All foxms of asbestos are impohnt industrial minerals, the Ball Clay is a high grade, white burning, plastic clay used various types often having distinct applications and Alaskan uses. as an ingredient in making high grade tile and whiteware. (see occurrences should be fully explored as any sizeable deposit con- CLAY). taining good i1o~lit.ymaterial should find a ready market. Because of the exeeptio~~alAlaskan need for insulating materials, and the adaptability of some of the poorer grades of asbestos for this BARITE purpose, there would appear to be ar! opportunity for profitable Barite, barium sulphate, is also known as '%heavy spar" and exploitation should such deposits be developed. "." It resembles or limestone but is much heavier and may vary in color. It has a wide variety of uses, both in its High quality asbestos minerals have a value in the neighbor- natural state (ground or crushed) and in prepared products, but hood of six or seven. hundred dollars per ton. Poorer grades, the price is relatively low. For that reason only those uses, which including waste from production of high grade material, range in may have some possible future application locally, are listed here. value from fifteen to seventy-five dollars per ton. 1. As a welldrilling mud it is used in large amounts in oil ASH, VOLCANIC {see PUMICE and FUMICITE) well drilf ng operations. FOR PROSPECTMG IN ALASKA 37 -- .. -. . .-

2. As a filler and surfacing material in paper manufacture. As the commek-cia1 source of the metal Beryllium, which is Mention should be made however of the possibilities of developing fast becoming very important in the light nletals industry, its deposits having particuIarly favorable location with regard to value is about $40.00 to $50.90 per ton. shipments to the Pacific Coast States. Most barite is produced Besides Beryl in the sense above described, there are several in the East, thus an opening for some Alaskan production may varieties highly valued as gem stoneeone, the , rank- develop. ing with the most precious of all gems. This, and the other gem Barite price varies according to grade and manufacturers' varieties AQUAMARINE, MORG ANITE and GOLDEN BERYL specifications but may be in the neighborhood of $7.00 to $9.00 are discussed separately. per long ton (2240 lbs.) BLACKJACK (see Sphalerite) BAUXITE BLACK-SAND Bauxite js an earthy mineral having a high aluminum and low silica content. It often occurs in a clay-like mass showing The term "black-sand", as considered here, includes any con- rounded, concretionary grains; also in structureless, amorphous centrate, natural or otherwise, resulting from the washing of , masses. Both types are generally of a brownish color. alluvial material. It mag or may not actually be black. Generally, Bauxite is an important source of aluminum but is also uged it consists of magnetite, chromi te, ilmenite, and many other min- in the manufacture of abrasives and "alumina cement." It also is erals including the gold, platinum, or cassiterite for which it is Many employed as a slag-correcting additive in the smelting of iron. 1t: worked. such "black-sands" also contain the sulphide thc is worth about: $7.00 to $8.00 per ton. minerals in varying amount; in fact they will contain all of heavy minerals that were originally present in the alluvial material, with the exception of a few easily decomposed or altered BENTONITE minerals. Bentonite is a bedded, plastic, clay-like mineral, usually gray In treating "black-sands" from placer operations two things or white, derived from alteration of volcanic ash (Pumicite). are important. One, to realize maximum recovery of the metals may Most vat-ieties be distinguished from clay by their property of or minerals sought. Two, to make certain that the sands contain absorbing large amounts of water and swelling. Some exhibit no other important values when they are discarded. - little swelling. ~ssumingthat the usual interest in "black-sand" lies in its The chief use of bentonite is in oil refining. Quantities are gold content, the recovery is largely a matter of proper equipment also used in foui~drywork, laundries, paper mills and ceramics. and understanding how it should be used. That being a subject is $10.00 Its value from $7.00 to per ton. outside the scope of this paper, it cannot be gone into here, but attention may be called to the advisability of having all such BERYL sands assayed before they are discarded. Too frequently all the Beryl is n silicate of beryllium and aluminum usually found "free-gold" is efficiently removed and the rest ,assumed to be in long, green crystals, although sometimes it may be yellow, pink. vaiueless. Yet assays will show appreciable gold remaining. This or white. Because of the similarity to quartz, light colored beryl is especially true of "black-sand" containing pyrite or other sul- may easily be overlooked. phide minerals. Assays on some discarded concentrates have shown a gold content as high as $4,000.00 per ton. It is obvious It occurs in pegmatite veins or dikes or in nearby schists and that even though facilities at hand may not be able to recover this gneisses. Occasionally large crystals weighing hundreds of pounds , gold, it may be advantageous to save the sands for shipment to are produced. a smelter. 38 INDUSTRIAL MINERALS AS A FIELD FOR PROSPECTING IN ALASKA 39

In any placer operation k representative sample of the sand burning clays are usually preferable but not required. (also see should be submitted for examination and identification of the CLAY) constituent minerals. Quite often the totally unsuspected presence of other valuable minerals has been discovered after years of BRU CITE working the ground. Identification of the minerds contained in Erucite is magnesium hydroxide, a soft, ensity carved, waxy, the concentrate, while it may not reveal profitably recoverable translucent mineral, usually green but sometimes white or bluish. amounts of other could conceivably clues which, minerals, furnish It somewhat resembles TALC and occurs in serpeliti~leor lirne- if properly followed, might lead to the finding of lode deposits. stone with magn$site. Eelow are listed minerals which may occur,in placer sands Good massive material finds some use in the carvitlg of and gravels in sufficient quantity to permit profitable recovery: decorative and ornamental objects. It is also used in the making Platinum al~drelated metals llmeni te of I-efractories. Gold Jade Silver Magnetite Recently a fibrous, asbestifom variety of brucite was found Copper Monazite in Alaska which may possess qualities that will permit its use as . Cinnabar Quartz Gems (agate, arne- an ASBESTOS. Cassiterite thy.&, etc.) Chromite Rare Earth nlinerals . Chrysobely 1 Ruby BUILDING-STONE Columbite Rutile to Sapphire BuiIding-stone is a term appiied all stone used in masonry Ferberite Tantali te constquction, ornamentation, E~C. The subject would require a Wolf rarnite separate report to fully discuss it. Briefly, however, the common Hubnerite Zircon stones so used are , SAKDSTONE, LIMESTONE: MARBLE and serpentine. Many factors have important bear- BLOODSTONE (Heliotrope) ing on the value and usefufness of a building-stone, chief among these being 11) cost of preparing for market, (2) attractiveness Bloodstone is a variety of , usually dark green with of the finished stone, (3) durability and strength, (4) availability scattered spots of red. Good quality material finds limited use as of a market. a minor gemstone. Some building-stone is suited only to more or less local BORNITE cansumption. Stone possessing unusual beauty, or other desirous qualities, may benefit by a price sufficiently high to justify ship- Bomite is a sulphide of copper and iron containil~gabout 60 meht to distant markets. per cent copper. Exposed surfaces tarnish to a purple or blue color while on a fresh the mineral is nonnaIlg brownish CALCITE bronze. Tt occurs with other copper minerals and is an important ore of copper. Calcite is cdcium carbonate occurring most commonly in massive form as LIMESTONE and MARBLE, but also in trans- BORT (see DIAMOND) parent to translucent or opaque crystals. Although ordinarily white, 'it may be variously tinted. BRICK CLAY Discussed separately under individual headings are the mas- Brick clay is any clay that can be used to make bricks. Its sive varieties LIMESTONE, MARBLE, CHALK and TRAVER- value is largely determined by the grade of brick produced. Red TINE. The form is mentioned under ICELAND SPAR. 40 INDUSTRIAL MLmRAIS AS A FTmD

CAREONADO (see DIAMOND) i.t is found massive, resembling limestone, but heavier. Tabular or prismatic crjwC,als are more common. It may occur dessemin- CARBONATED SPRINGS :I ated through sandstone or limestone, or in cavities in such rocks, usually associated with gypsum, calcite, sulphur, etc. Carbonated springs are not entirely out of place in this report inasmuch as they constitute a source of carbon dioxide. Carbon- Celestite is used principally in the manufacture of clzemicals. ated waters, occurring in natural springs, are identified by the Crude ore is marketed at about $15.00 to $20.00 per to11; the higl2- evolution of carbon dioxide gas and the similarity to familiar grade, finely powdered mineral at $35.00.to $45.00 per ton. bottled "carbonated drinks." Frequently a deposit of accumulated "lime" is found around such springs. CEMENT ROCK Natural sources of .arbon dioxide gas may be carnmercislly Cement rock is any limestone, or mixture of limestone with .,,I rock clay, etc.) for of exploited and the purified gas marketed in both solid and liquid : other (shale, suitabie the manufacture form. cement. A separate report would be required to fully disci~ssthe subject of cement and its raw materials. Although ilecessarily CARNELIAN limited, it is hoped that this brief discussion will stimulate interest in a search for deposits capable of supplying the needs of a cement given to a reddish to reddish-brown Carnelian is a name plant within the Territoly. , CVALCEDONY or AGATE. At the present time only those limestone deposits favorably CAHNQTITE '4 located with regard to transportation are of great interest. Far the cheapest operation the deposit must be at or near the plant Carnotite is a uranium-vanadium mineral containing a small site. Lf a mix with clay or other rock is necessary, one raw quantity of radium. It is canary yellow colored and usually occurs material or the other may have to be transported to the pla~~t. ih powdery or earthy form disseminated in sandstone. A number GYPSUM is employed in considerable quantity by cement plants, of other minerals resemble carnotite and its iden tif icatiori should thus the finding of suitablelimestone is not the only factor involved. be left to a mineralogist. An important ore of uranium, vanadium These problems, +s well as those of proximity to the ultimate and radium, its value depends upon the average content of those market and sources of fuel, must dl be considered. elements. . . Returns to the prospector for his efforts in finding useful deposits will probably come from the ,sale of his interests to large CASSITERITE (Stream Tin) concerns rather than from individual operation. Only large deposits Cassiterite, an oxide of tin, is commercially recovered chiefly warrant attention, yet it must. be borne in mind that apparently from placer deposits where it occurs in heavy, black to light brown, small deposits may prove lnrge upon development. Chemical occasionally gray, pebbles, grains or crystals. Placer cassiterite. analyses are necessary to determine the usefulness of any cement

derived from veins in or near such . is tin-bearing pegmatites and . . raw material. should receive careful rocks attention. Consumption of cement in Alaska being definitely on the As ordinarily produced placer cassiteribe contains from 60 .,.? increase, there is no apparent reason why the needs of the Terri- to 70 per cent metallic tin. Purchase is made, 011 the basis of , - .,..:: 7.:; tory could not support a cement plant, 'I.. -- contained tin, at 52 cents a pound. (see BLACK-SAND) r ; ,$ ., &- I-. . 8: , -Cerrusite, lead carbonate, is a secondary lead mineral similar Celestite, strontium sulpbak, is a heavy, white to bluish to ANGLESITE and the remarks under that heading also apply transparent to translucent mineral resembling barite. Occasionall to cerrusite. I 42 INDUSTRIAL MINERAS AS A FImD FOR PROSPECTING IN ALASKA 43

CHALCEDONY fragments in alluvial deposits derived from such rocks. The mineral is very hard and usually colored various shades of green, ' Chalcedony is a transparent or translucent, cryptocrystalline although yellow to brown tints also occur. Good stones are of Some of variety of quartz of which there are many variations. considerable value as gems: (see BLACK-SANDS) . these are listed below and will be separately discussed under those headings. Agate Flint Chrysotile is fibrous serpentine or serpentine ASBESTOS, Bloodstone Jasper Carnelian although the fiber is ordinarily from inch to an inch or so in length, longer fiber up to a foot or more is occasional1y found. CMALCOCITE Chrysotile brings the highest market price of all asbestos Chalcocite contains 80 per cent copper and is a dark, lead-gray minerals, ranging from several hundred dollars per ton downward mineral tarnishing black or green. Found in the enriched sulphide to about $20.00 per ton as the quality and length of fiber de- zone of copper deposits, with other copper minerals, it is an creases. Following are listed some of its uses. important ore of copper. 1. Asbestos cloth, yarn, etc. 2. Brake linings, clutch facings CHAl,K (Whiting) 3. Insulating and building materials 4. Pipe covering and special cements ~hxlkis a soft, white, fine-grained limestone, composed of the calcflreous remains of minute marine organisms and shells. A CINNABAR variety of uses exist, the largest quantities being used by the foI- , lowing industries. Cinnabar, mercury sulphide, is the commercial ore of mercury and is found in a wide variety of rocks: h he color will rarely vary 1. Abrasive (fine polishing) from a characteristic crimson or reddish-brown, particularly if a 2. Rubber (used as filier) 3. Paint (calcimine and cold water paint) crushed particle is examined. Although sometimes confused with 4. Paper (coating glazed paper) iron ocher, red jasper, and other minerals, cinnabar may be panned 5. Ceramics and enamel-ware like gold, when the distinctive color will be apparent. It is some- 6. Others times found in placer deposits indicating proximity to the lode source. CHROMITE (Chrome-iron ore) Cinnabar is not ordinarily shipped but is treated, and the Chromite is the only eornrnercia~ore of chromium. It is hard, mercury recovered, at the mine. Mercury is generally worth from black and heavy and occurs in serpentine or peridotite, usually with $1.00 to $1.30 per pound. Pure cinnabar contains 86 per cent magnetite. It is frequently mistaken for any of several iron metal. minerals. Areas in which chromite occurs are favorable areas to , prospect for nickel ores, platinum and asbestos. CITRXNE Chromitc is used in large quantity in the metallurgical, re- Citrine is yellow transparetit quartz valuable as a gem stone fractory and chemical industries and has a value of $26.00 to when obtainable in crystals or pieces suitable for cutting. $40.00 per ton depending on the grade.

CHRYSOBERYL CLAY is a beryllium and aluminum mineral found in The subject of clays is too large to cover satisfactorily in a crystals in pegmatite or mica schist, or as crysbls and crystal report of this nature. A list of the various types of clays foUows FOR PROSPECTING LN ALASKA 45 ---..-

.and some idea of the uses may be obtained from the nnmes. A few tity associated with pyrite, arsenopyrite, and other sulphide min- will be separately mentioned elsewhere. erals, in meblliferous veins, notably those containing silver. copper or nickel. Surface exposures of cobalt-bearing veins often show 1. BALL CLAY 7. Pottery Clay an earthy incrustation of "cobalt-bloom," light cl.imson to pink 2. BRICK CLAY 3.. Paving Brick Clay 3. FIRE CLAY 9. Sewer Pipe Clay in color. 4. Fuller's Easth 10. Stoneware Clay Cobaltite is an important source of cobalt metal. Value of the 5. 11. Paint Clay TerracottaClay - ore is about $1.00 to $1.25 per pound of cobalt coi~hined. 6. PAPERCLAY Clays vary widely in their chemical and physical properties as COLUMBITE and TANTAEITE well as in their applications 'Lo industry. Generally they are of value Columbib and tantalite are two distinct minerals containing only when they occur very near the market which is to utilize the Since usually vary in find product. This is particularly true of those employed in the the met& colurnhium and tantalum. they composition, one grading into the other, they are discussed to- manufacture of low unit value commodities which cannot profit- to that ably be transported long distances. Building brick and paving gether here. It will suffice, therefore, assume columbite contains more columbium than tantalum while, in hntalite, the brick nre examples. Certain high quaIity clays. usualIy white tantalum predominates. Ciring, which are found by some industries to be jndispensabIe and ' difficfilt to obtain, ase sometimes shipped considerable distances. Both miaerals occur in some pegmatites artd may be found in Ai~alysesand manufacturers' specifications determine the placer sands df the area. Both are heavy, hard, black minerals usefulness and value of any clay. easily confused with wolframite and severa.1 other minerals with which they may occur. Areas known to contain pegmatite dikes and veins should be carefully prospected for the possible oceur- rence of columbite and tantalite as well as for other valuable The abundant coal deposits of Alaska are destined to become minerals known to occur in such rocks. Any heavy, black concen- the subject uf greater interest. The major coal-bearing areas, the trate, not rekponding to a magnet, should be submitted for existence of which have long been known, incIude lignite, bitumin- identification. ous and anthracite types. Apparently most abundant is the lignite Calumbite and tantalite .are the chief sources of the melaIs which is considered, by American standards, to be a poor grade of columbium and tantalum for which there is an increasing demarid. coaI for most industr!al uses. Alaskan reserves of high grade ' especially by the steel and metals industries. Tantalite is partic- coals, including coking coal which is indispensable to the iron and lariy in demand, a concentrate-assaying60 per cent tantalum oxide steel industry, are among the largest on the West Coast. All are (Talus) bringing $2,000.000 to $3,000.00 per ton depending upon being capnblc of put to good use. impurities. The price of columbite concentrate is about half of that. The common uses of coal are for household heating and as a source of power in'generating electricity. On a larger scale certain CORUNDUM and EMERY high grade coals are burned in "coking ovens" to produce coke far Corundum is an oxide of sl uminum. The transparent crystal- metallurgical use . By-products of these plants include gas, am- Iine varieties are the precious RUBY and SAPPHIRE: ~OIIIB,tar, creosote, and l~urnerousother products which in turn while the opaque granular corundum, accompanied by impurities are used in the preparation of hundreds of essential commodities. of hematite or magnetite, is known as "EMERY". .

Corundum ranks next to diamond in hardness and is found ill COBA LTITE (see SULPHIPES) barrel-shaped crystals and compact masses in a rather wide assort- Cobaltite contains .cobalt, arsenic, and sulphur and is similar ment of rocks; also in placer deposits in the form of crystals al~d to a'rsenopyrite in appearance, Ordinarily it occurs in small quan- grains. FOR PROSPECTING IN ALASKA 47 .------

Clean corundum and the impure mixture, "EMERY'' are both translucent to opaque, poorly crystallized and found in crystals or important abrasives. The folmer is worth from 8 to 70 cents a fragments, is known as "bort" or "bortz". pound according to grade size acquired by milling treatment. The various forms are ordinarily first found in placer deposits "Crude emery" is worth about $10.00 a ton but dter proper from which search is usually made for the parent rock. Diamond milling avd classification the resuitant "grain emery" brings 5 tp origiilates in certain peridotite rocks where it occurs sparsely 7 cents a pound. disseminated. GornrnerciaI recovery is most favorabIe in stream sands and gravels and in the clay and soil derived from alteration COVELLITE of tlle diamond-bearing peridotite. Covellite is a sulphide of copper containing 66 per cent copper. Finding of gem'diarnond may be no more spectacular or in- Found in the enriched sulphide zone of copper deposits it usually teresting than finding a small well worn piece of glass, conse- occ'urs massive, with other copper minerals. It is indigo-blue in quently attention should be paid to any find of this nature. color, turning purple when moistened. There is, of course, no need to explain the value or uses of Bern diamond. The other varieties, carbonado and bort, are highly important industrial abrasives in great demand for diamond-drill Crocidolite is a fibrous amphibole, commonly of bluish color, bits, diamond saws, and various machine tools. from whence it derives its other name "blue asbestos." It is not widely found but because of the high tensile strength of its fibers Prices of both of these materials are high. They are sold by the (140,carats equal 1 ounce). and its resistance to chernicsI action, it is a valuable type of carat ASBESTOS. Depending upon the length of fiber and other factors, the value of crociddife is from $100.00 to $400.00 per ton. DIATOhiITE (Diatomaceous Earth) (see ASBESTOS) Diatomite is composed of the siliceous remains of microscopic water organisms known as diatoms. It is about 90 per cent silica CRYOLITE but strongly resembles chalk in that it is white, earthy, fine- Cryolite, composed of sodium, aluminum and fluorine, is found gri~inedand very light. Dry pieces will float on water until they in cornpast masses, rarely crystalline. Xt is colorless or white and become saturated and sink. may be mistaken for quartz or a number of similar appearing Deposits of diatomite occur in beds, varying in thickness up minerah. Although it is somewhat heavier than quartz the dif- to hundreds of feet. f erence may not be suff ieient to attract attention. Its uses are many and the important ones are listed here. Cryolite is found associated with fluorite, pyrite, galena, I. Insulation (sound and heat) sphalerite and the pegmatite minerah. Its chief use is in alum- 2. Abrasive (fine polishing) inum production but there are various other uses including the 3. Filter or absorbent manufacture of enamels, glass, abrasives, etc. Clean ccyolite is 4. Filler (in manufacture of numerous products) worth from $70.00 to $80.00 per ton. VaIue of diatomite varies from $7.00 per ton fzr the crude material, to $40.00 per ton for the highest grade product after milling. Specially prepared diatomite for special purposes may bring substantially higher prices. Diamond is a pure form of carbon and is the hardest mineral known. When clear and colorless, or only slightly tinted, it is highly valued as a gemstone. An opaque, black or brown variety of diamond,'occurring in small, irregular, rounded nodules is term- Dolomite is the carbonate of magnesium and calcium, and ed "carbonado" or "black diamond.'' Another form, dark colored, except for the magnesium content is essentially the same as lirne- FOR PROSFECTIEIG IN ALASKA -49 stone. Its manner of occurence is like that 03 limestone, in fact FELDSPAR most such deposits contain both. Deposits of commercial import- Feldspar is the name applied to a group of minerals cornpris- ance are large and must be favorably situated ivith regard to plant ing (1) potassium aluminum silicates and (2) calcium and sodium location, market and transportation, since aU rnanufactu~edprod- aluminum silicates. These are referred to respectively as orthoclase ucts are relatively Iow priced commodities. and plagioclase feldspars. Feldspars are familiar to all as the Dolomite is often used interchangeably, depending upon the predominate light colored mineral (other than quartz) in granite particular purpose, with limestone. Following are the important rocks. They may vary in color from white to brownish to pink and applications of dolomite. (see LIMESTONE also) sometimes light shades of green, yellow or blue. They are about as heavy .as quartz but may be distinguished from that mineral by 1. Lime manufacture properties, crystal form, and by other means. 2. Agricultural limestone 3. Building and ornamental stone Emphasizing again the importance of pegmatites as a prolific 4. Road building source of. minerals, commercial feldspar deposits are found only in 5. Metallurgical fIux and refractory rocks, occurring 6. Source of rnitmesium metal such the feldspar minerals in large crystals. Some paper mills utilize dolomite in preparing bisulphite acid. The ceramic industry, making whiteware bodies, glazes and enamels, utilizes the greatest portion of all feldspar produced. Other uses include roofing and cement surfacing, scouring soaps, abrasives, etc. Electrum is a natural alloy af gold and silver containing 25 to 40 per cent silver. It may be distinguished from the ordinary gold Milled, grouhd feldspar is valued at $10.00 to $20.00 per ton ilugget by its pale yellowish white color. Its occurrence is the according to type and fineness of grind. same as for ordinary gold. Only the orthoclaskfe~ds~arsare of industrial importance. However, various of the feldspar minerals if of good quality, find EMERALD use as minor gemstones. Emerald is a bright, emerald green variety of BERYL. Yet, unlike the other varieties of BERYL, it is not exclusively found in the pegrnatites. Most emerald has been found disseminated ' is through Ferbedte, composed of iron and tungsten, a black to brown- a dark metamorphosed limestone, or in schist. Good ish-black, heavy, metallic looking mineral, easily mistaken for a quality emerald is rare, consequently it, about equals the diamond number of other minerals. ft is an important tungsten ore related in value. to WOLFRAMITE and HUBNERITE. Like these, it is found in Emerald may he found in gravel deposits but since its weight granite and pegmatite rocks. is about that of quartz, it cannot be separated by gravity concen- tration- FIRECLAY Fireclays are those clays capable of withstanding high tem- ERYTHRITE (cobalt bloom) peratures without material change. Sufficient plasticity for shap- ing must be obtained, but since many fireclays are non-plastic, this Erythrite is a hydrous of cobalt, a rare secondary . mineral, which is only of importance as an indicator of cobalt is often accomplished by additions of suitable, more plastic clays. mineralization. It is an earthy, incrustii~gmineral, of a pinkish Fireclays are transported clays {deposiked in water) as distinguish- eoldr and may be found on surface exposures of cobalt bearing ed from residual clays (from rock decomposition in place). They veins. are often found in coal measures. 50 XNDUSTRLAL MINERALS A$ A FIELD FOR PROSPECTING IN ALASKA 51. _. _ -- - .- -.. -, ---- . ---- Fir.eclays are used in the manufacture of heat resisting ware GALENA and such as firebrick, funlace linings and crucibles, may also be Galena, lead sulphide, is readily recognized bj7 all prospectors used for tile, paving bricks, etc. Like most other clays, commercial as a bright, fead-gray, britt1e;xnetallic mineral, breaking into cubes deposits should be clos~to the plant and transportation. (see ,or sharp, right angles. it may'occur massive and very fine grained, CLAY) however, this type commonly containing high silver values. Galena is accompanied by other minerals, notably silver, gold, zinc and copper. Alone it constitutes the most important lead ore.

Flint is a cryptocrystalline variety of quartz which is dense. GARNET fi~egrained, very toughaandbreaks with conchoidal fracture. It is' foulid as ncdbles or concretions, often with a white challc coating. Garnet is the name applied to a group of related siIicate minerals incrud irig some commercial1 y useful species. Considered ~IIlinlestone or chalk, beds., Colors are gray to brown to black- as n grQup, are usually found as characteristic crystals in Flint pebbles are used in grinding mills, bringing ~oughly, rock, or as somewhat worn, rounded crystals in strean1 gravels. $10.00 per tun. Ground flint is much used as an abrasive and.other They are very hard and brittle and may he found in most any minor uses exist. The United States is dege~~dtntupon import for color, although the deep red, pink, brown and black colors are n~ost its supply of flint pebbles. cornman. Garnets are found in a wide variety of the metamorphic ~oeks,notably gneiss, schist and crystalline lirnestojre. FLUORITE (Fltiorspar) Most of the garnet produced is used as an abrasive, mainly in . the manufacture of abrasive paper and cloth for the wood-working Fluorite is con~pcsedof calcium fluoride and is a I,urple, green industry. Another possible application would be'for surfacing and or white glassy mineral, found in Icad, zil-rc, and tin deposits, polishing of marble and other building and orname~ltalstones. comino~~Iyassociated with limestone. It occurs crystalline in the $35.00 $100.00 form of cubes, or massive somewhat resembling. a colored quartz, Abrasive garnet is worth from to per to11 de- although it is softer. It often constitutes a large portion of,the pending upon grade and grain size. gangue in mineralized veins . Certain attractively colored garnet is of some value as a gem- stone, especially if found in large, flawless crystals. F1uori.t~is a very important i.ndustrial mineral finding its greatest use in the steel, acid making, glass and enanlel industries. GARNIERITE It is ~alued,according to grade, from $20.00 to $35.00 per ton. Garnierite is a hydrous nickel-magnesium silicate, greenish Eeczuse of the ease with which it may be worked and the in color, often appearing to be merely a green stain. It is asso- beaut)- of the finished article, good material is often in demand by ciated, as a rule, with serpentine and chrornite. Although it is an 1apid;lri~sand co~lectors.- it is too 'sof lfor gem use but is formed important nickel mineral, the nickel content is rather lour akd into objects of decorative value. treatment expensive, so only large deposits are of great value.

GEMS FRANKLIMITE The possibilities of precious and semi-precious gem stones in Franklinite contains zinc, iron, and manganese. A black Alaska have received little or no attention. As a result practicalIy mineral resembling magnetite, it is invariably associated with two no occurrences are kndwn, yet they unquestionably do exist. By other zinc millerale, WILLEMITE and ZINCZTE. These ore bodies discussing them in this report, it is hoped that interest will be are usually in limestone. created and the value of searching for them recognized. The IN ALASKA 52 INDUSTRIAL MXNERALS AS A FIELD FOB PROSPECTING 53 prospector, who is wise enough to pause in his search for gold and GLAUCONITE (Greensand) spend time uncovering agatized wood or picking colored eryskIs Glauconite is a hydrous silicate of iron and potassium, oc- from an outcrop, may be rewarded with a deposit upon which he curring in deposits, derived from marine sediments, and associated can depend for a grubstake at any time. A ready market exists, with sands and clays. It is a soft, green rock. with good prices, for huridreds of different stones, crystals and mineral specimens. It finds two chief uses (1) a fertilizer (2) a water softener. The marketable product, after washing and screening sells for Prices ranging from a few cents to many dollars, depending about $25.00 per ton. on the individual specimens, are paid by collectors, jewelers, lapidaries and dealers for good display specimens of any mineral. GOLDEN BERYL Crystal aggregates, and other unusual forms encountered in lode mining, contain only a few cents worth of the metal for which the Golden beryl is a form of BERYL occurring in beautifuI ore is mined, yet the value as a specimen may be several dollars. golden or yellow crystals. It is highly prized as a gem stone. Various of the gem minerals are found in placer deposits, a fact which shodd not be overlooked by operators. A substantial percenhge of the profits of some gold dredges, and smaller op- Gossan is not a mineral but it will be discussed here briefly erators, is derived from the by-product recovery .of gem stones. for it bears an important relation to certain niineral occurrences, particularly those of copper and gold. Gossan, a term applied to deposits of LIMONITE, with other iron oxides, is derived from the GEODE oxidaJion and leaching of ore bodies containing heavy sulphide show values A geode is a nodule or spherical mass, of variable size, usually mineralization.. Often this capping will no other than such possessing a dull or unattractive exterior and an interior lined iron, but whenever an occurrence is discovered it should be with agate or crystals. Only by breaking these open can any idea thoroughly prospected to determine the nature and value of the body. is gossan be had of the nature of the interior, and to do so invariably ruins underlying ore If it a true there will be found it a the specimen. Once identified, others in the vicinity should be beneath sulphide ore body possibly containing gold or copper collected unbroken thus presewing their intrinsic value until they or both. If appreciable gold is present in the vein it is probable can be sawed in half. that free gold can be panned from the gossan capping. Copper, however, may be entirely lacking at the surface, even though the Rhyolites, light colored lava rocks, and the surface soils and vein is rich. A gossan capping may be any: depth up to a hundred stream gravels nearby, are the usual source of agate filled geodes. or rno18e feet. Large deposits would be of potential importance as iron ore. Values vary from a few cents for common specimens to as much as a hundred dollars or more for choice polished pieces. GRANITE Granite is a common rock, considered here for its possible GLLSONITE i.mportance as a building stone. (Attention may also be called to Gilsonite is a natural hydrocarbon resembling asphalt or cod the fact that areas containing granite rocks are favorable districts found filling veins in sedimentary rocks near coal and oil bearing in which to prospect for gold and other minerals.) To be of eom- formations. The manufacture of varnishes and inks are the prin- merciaP value as a building stone, a granite must possess good cipal uses although there are many minor demands. color and be capable of taking a high polish. Just as important, it must possess certain physical properties which pemit cheap Gilsonite is marketed at $20.00 to $30.00 per ton. quarrying and shaping and give durability to the stone. INDUSTRIAL MINERALS AS A WEm PROSPECTING IN ALASKA. . 55 54 . , .. . . . --A -- .- FOR --.--

The term, as used here, includes other granite type rocks such is sometimes used as a pign~e~itin paints, etc. The value of hema- as diori te, monxonite, etc. (see BUILDING STONE) tite as an iron ore is about $2.00 to $3.00 per ton. . Black hematite in good crystals or hard, compact masses, is GRAPHXTE always in demand by jewelers and dealers in gem materials. is a form of carbon easily recognized as a soft, black, greasy f eeliag mineral. MOLYBDENITE and graphite are quite similar in appearance but a person familiar with both should have no difficulty in distinguishing between them. Graphite is a 1 - Hiddenite is n yellow-green to emevald green, transpnrent common mineral found widely in non-commercial amounts. Com- variety of SPODUMENE,iiluable as a -(see SPODU- mercial deposits contain massive graphite in veins, or flakes dis- MENE) seminated throughout tlie schist, gneiss or other country rock. Many industrial uses are known for graphite. The mosl im- BONESTONE (Whetstone, Oilstone) portant include the making of pencils, crucibles, lubricants, paint, Hone'st0ne.i~a term applied to certain natural stones or rocks, commutator brushes, ek. Two commercial forms of graphite are whose propel-ties adapt them to use as specialized abrasives. Such mined asd there are several grades of each. Depending upon the stones ordinarily are made from a fine to medium grained sand- form and grade, prices per ton range from $10.00 to $200.00. stone, or an exceptionally fine-grained crystalline quartzose rock. Samples should be taken from any substantial occurrence and sub- Other types of rocks'also may yield satisfactory results. mitted for determination of its type and possibilities.

. fiubnerite is composed of manganese and tungsten and re- Gypsum, hydrous calcium sulphate, is a white to slightly sembles both WOLFRAMITE and FERBERITE except that its bl uish-white, soft, miueral resembling calcite or limestone. Com- )color is dark reddish brown. All three are found in or near ,mercial deposits occur in massive form, interbedded with sedi- granites or pegmatites a'nd are ores of tungsten. mentary rocks, commonly with or near limestone. 'Large quantities are used by the paper and cement industries, ICELAND SPAR and in the manufacture of plasters, wall board, insulatil~gboard, and other building materials. From these uses it should be appar- lcelaod Spar is pure crystallized calcium carbonate, calcite. ' calcite in ent that gypsum deposits, favorably situated, will be important Ordinary is common and well-known, bnt Iceland Spar factors in establishing local industry and reducing building clear crystab, free of flaws, is relatively scarce. Accordingly it is material costs in Alaska. in fair demand at high prices. Good quality crystals are marketed by the pound, bringing I4 I3 M ATITE from $2.00 to $30.00 per pound. They are used to rnannfacture ,' prisms for optical instruments. Hematite, an iron oxide, contains about 70 per cent iron. It' . . is a common mineral of no value unless it occul.s in enormous quan- I Should such crystals' be discovered in AIaska, representative tity. Large deposits constitute the most important source of crystals or crystal groups, should be carefully packed and submit- iron ore. . . ted for examination to determine if they quaiify as optical grade Xn these deposits the mineral may be of two descrij?tions (1) material. Since they lose their value if flawed or broken, it is soft, earthy and reddish-brown (2) hard, heavy, bluish to brownish recommended that they be extracted and handled wit11 as nltich b!ack, or reddish brown. The earthy variety, also called red ocher, care as possible. 56 INDUSTRIAL BIEINERAJX AS A FIELD FOR PROSPECTING IN ALASKA 57

ILMENITE . Ilrnenite, an oxide of iron and titanium is rather common, Jet is a dense, black, lignite coal capable of taking a high especially as an accessory mineral in placer concentrates. It is polish, and therefore fittied for use in certain forms of jewelry. found as iron-black, shiny, metallic-appearing grains or masses; KAOLIN (China Clay) often in thin platy crystals. The rocks in which it occurs are Kaolin is a high grade? white firing clay, suitable for use in igneous. chiefly metamorphic and the manufacture of porcelain, whiteware, etc. Residual kaolins It is of no value uniess recoverable in large quantities and ' possess tow plasticity while secondary kaolins are somewhat more then it must contain a high percentage of titanium. The con- plastic. Both types are used in large amounts, the former being centrate is then worth about $25.00 per ton. especially desired for highest quality wares. Its chief use is as a source of titanium In addition to the above mentioned uses, large quantities are utilized in the manufacture of paper and there are numerous other JADE and JADEffE industrial uses. Jade, as generally considered, includes two minerals, nephrite Careful attention to suitable clay deposits situated near and , which are enough alike to defy making any distinction transportation routes appears especially warranted. Good china between them outside of the laboratory. Both are used only as clay has a value of from $7.00 to $9.00 per ton. Washed and pro- gem material so will be discussed here as one mineral. cessed material, suited to special uses, may bring as high as $15.00 $20.00 Jade is a tough, compact, hard, translucent to opaque mineral. to per ton. Ordinarily it is soine shade of green and it is this material that Because of the impossibility of properly grading a clay outside is most used in jewelry, and ol-namental figures. Occasionally of the laboratory, samples should be sent to one of the Department white or pale colored jade is found. This is not usually regarded laboratories for a report on the type and possible uses. as highly as the green. Areas of serpentine rocks are the most usual source of jade and the best material is often found in the form of large and small Kunzite is a delicate pink to lilac colored, transparent variety boulders in the nearby stream gravels. Only by actual cutting of spodumene, valuable as a gemstone. (see SPODUMENE) and polishing of sections of the rough material can its true'beauty

I ' and value be determined. KYANlTE (CYANZTE) Selected quality jade may be sold for several dollars per Ryanite, an alumnium silicate, is a brittle, translucent to pound to jewelers, lapidaries, collectors and dealers. transparent mineral usually some shade of blue, but occasionally white, grayish, or greenish. It is found in ci-ystals, or in masses JASPER of long, bladed, intergrown crystals. Characteristically the hard- Jasper is an impure cryptocryshlline quartz, usually red but ness varies with the orientation of the crystal ; a knife point will occasionally yellow, brown, dark green or grayish blue. The color scratch along the length of the bladed mineral but will not scratch . is due to impurities of iron, more or less associated hematite, across it. comrnonIy being visible in the surrounding rocks. Kyanite occurs in mehmoi-phic rocks such as schists and Common jasper is widespread and consequently less in de- gneisses, and is mined for use as a refractory material in the mand, but with it may occur material of excellent quality suitable manufacture of spark plugs, enamel ware, glass, etc. Crude kyanite for use in jewelry or specimen polishing. Such material may bring is worth $15.00 to $20.00 per ton while ground, special grade from a few cents to a dollar or more per pound. material brings up to $40.00 per ton. iZ INDUSTRLAL MINERAM AS A FIELD FOR PROSPECTING IN ALASKA . 59 -.- -. -. -- ____ .- ---

L-4PIS-LAZULI and LAZURITE 1. Manufacture of building-Iime, mortar. stucco, e6c. 2. Manufacture of cement and cen~entproducts. Lapis-lazuli is a rock containing several minei'als among which 3. Manufacture of n~ineral(rock) \-vool insi~lation. LAZURITE predominates, giving the stone its value. LAZURITE 4. Manufacture of paper. is a hard, opaque to translucent mineral, with deep blue or blue- , 5. Building stone grceii color. Its conlposition is complex, its only value being as a 6. Agricultural lime decorative or ornamental semi-precious stone. I't is found in crys- 7. Coal mine dusting 8. Numerous metallurgical and chemical processes talline limestone, resulting from contact . (see CEMENT ROCK and MARBLE) Depending on its quality it may bring up to several dollars per pound. LIMONITE Lazuli te, an entirely different mineral, strongly res~rnbles Limoilite is a hydrous iron oxide, a very common mineral. As Lazurite. li~asrnuchas the uses and values of both are the same, ordinarily encountered it is of no value, but \\?hell found in large no iurther distinction between them is necessary here. quantity it may have irn.I;c)rtanceas an iron ore. Massive limonite is heavy, rather hard, and yellowish to bxown to black iiz color. A . IJEPIDOLITE (Lithia Mica) powdery form may occur with the massive ore. Lepidolite is readily recognized as a mica, the particular type is $2.00 toll. king identified by the pink to lilac color. Containing 4 to 6 per As an iron ore, limonite worth tu $2.50 per The powdery form, know11 as yellow ocher, is used as a pigment in cent lithium oxide (LizO), it is mined as an ore of lithium bringing paints, etc. (see GOSSAN). $20.00 to $25.00 per ton. Some lepidolite may also contain suf- ficient CESIUM to constitute an ore of that element. MAGNESITE Pegmatite veins and dikes are the main source of lepidolite. Afagnesite, magnesium carbonate, exists in commercial de- posits in massive or compact form. The mineral is usually white LIMESTONE but may occur variously colored. Limestone and dolomite are Limestone is a sedimenbl-y rock, ehieflj; calcium carbonate often confused with magnesite. (CALCITE), but containing variable amounts of rnag~esjum carbo~ate. It occurs commercially in nlassive deposits which vary It occurs, (1) in areas of serpentine rocks where it is fornled rather widely in the nature and amount of impurities contained. as a result of alteration, (2) associated with linlestone and dolomite Thus for whatever use the rock is jntended, its suitability must as replacement deposits. first bc yiqoveuby :\naIyses al!d other examinations. Magnesite is important as a refractory to the steel industry Uses for limestone are too numerous to mention in fult. Were 1 it not for the availabilty, at low cost, of limestone, many of our ancl as a raw material to the magnesium industry. 0th~uses exist preparation of certain insulating major cheni ieal and metallurgical i~ldustries ~r~ouldbe greatly chiefly in the bititding and handicapped or nonexistent. In many respects it ranks even materials. Foremost among the building material is Sorrel (oxy- used wall stucco higher than coal or iron as a mainstay of our present civilization. chloride) cement, in plaster, and special floors. Future industrial exploitatiol~of Alaska will be dependent upon, .Mixed with asbestos, large amounts of rnagnesite are used for and the location of some plant sites will be decided by, the boiler and pipe covering. The pulp and paper mills use appreciable availabitjty of suitable limestone. Deposits near coal may be of quantities in the bisulphite process.

particular interest. , Calcined mamesite ranges in value from $25.00 to $50.00 per Following are listed a few of the uses for limestone: ton. FOR PROSPECTING M ALASKA . 61

MAGNETITE The peculiar properties of meerschauin make .it admirably Magnetite, iron oxide, contains 72 per cent iron. A common suited to the carving of pipes and cigar holders. Other uses would mineral, it is readily recognized since it is strongly attracted to a be developed if commercial deposits could furnish the material. magnet. In addition to its presence in placer sands it is commonly Turkish deposits now supply nearly the entire world. Meerschaum found, in non-commercial amounts, in the majority of roeks. Large is worth about $1.00 to $1.50 a pound. deposits of'rnagnetite sand, low in titanium content, and mineable masses in metamorphic rocks, constitute possible cornmercjaI sources of iron are. The price of magnetite iron ore is about $2.75 Mica is a term covering a certain group of silicate minerals to $3.75 per ton. occurring in transparent sheets or flakes. Varieties of commercial importance are , LEPiDOLITE, PETLOGOY ZTE and

MALACHITE VERMICULITE. They are discussed under separate headings; ' Malachite is a green copper carbonate, a secondary mineral found in the oxidized zone of copper deposits. It is associated with MOLYBDENLTE AZURITE and other copper minerals. Large and small rounded Molybdenite is a molybdenum sulpkide, a lead-gray, greasy masses present a very attractive appearance when cat and polished. feeling mineral resembling graphite. It may be distinguished from Consequently it is much in demand for fashioning ornamental graphite, however, by the faint bluish tinge to its color, whereas objects ntld jewelry. Raw material, of good quality, wiH bring graphite has a brownish to black tinge. up to $3.00 a pound from dealers and lapidaries. Molybdenite is found in granite rocks and is the principal ore of molybdenum. The mineral is concentrated by flotation and the MARBLE resulting shipping concentrate contains about 90 per cent molybde- Commercially "marble" is any LlMESTONE or DOLOMITE nite. On the basis of the normal price of 45 cents per pound of capable of taking a polish. The main use is in the production of molybdenum sulphide contained, this concentrate would be worth ornamental building stones and monuments. For such uses it is about $810.00 per ton. ore assaying 2 per cent molybdenum sul- chosen primarily for itk appearance, the value being influenced to phide would produce $18.00 worth per ton if it were entirely a great extent by exceptional color characteristics. Consequently recovered. it commands higher prices than ordinary structural stone and may be economically shipped over greater distances. MONAZITE . Finished marble has a vaIue somewhere in the neighborhood Monazite is a containing varying amounts of $5.00 to $7.00 per cubic foot, about three times the price for of the Rare Earth elements, THORIUM, CERIUM, lanthanum, the rough, unfinished stone. yttrium, etc. It is generally found as yellow to brown, ~anslucent to opaque grains, in sands which, being heavy, are amenable to When not used as a "marble" it becomes merely a LIME- concentration by panning. Monazite sands are derived from STONE or DOLOMITE and thus may have any of the uses common granites and pegmatites. to those rocks. in general the price for monazite sand concentrate is about MEERSCHAUM (Sepiolite) $60.00 per ton; however, an analysis of such sands must be made Meerschaum is a hydrous magnesium silicate occurring in before prospective purchasers wiII quote a price. The purchaser may be intereskd only in the amount of one or two of the con- compact, nodular, soft, earkhy, or dayey masses in serpentine or stituent elements, thus the price is set aceardingly. other high magnesium rocks. It is white colored and, when pure and dry, will float on water. When dry it is rather hard and tough. Monazite is used as a source of the rare elements. .62 INDUSTRIAL MINERALS AS A ;FTELD FOR PROSPECTING IN ALASKA 63

MORGANXTE shoultl, . however, recognize the value of new discoveries of oil bearing areas and be able to recognize surface indications. Morganite is a pink to rose-red variety of BERYL used as a gem stone (see BERYL). Oil exists in areas of sedimentary rocks, and under favorable col!dit:ons, it nay find its way to the surface, the amount at the MOSS AGATE surface having no relatioil to the.quantity of oil underlying the Muss agate is a variety OK AGATE containing dendrilic in- area. Even the most meager indications in new districts are - J. . Srnpui-tant-discoveries. Seepages of oil may exude fl-om'thesand, clusions of brown or black calor Which,, when polished, add ',.. ..;:!'.. . : .. I attractiveness to the stone. There is a good demand for moss muti cr. clay, or from along the joints and bedding planes of the agate nt prices rangillg from a few cents for inferior specimens ~andztones,slates, shales, etc. to a dollar or so a pound for good material. Choice polished pieces The presence of inflammable gas, detected arising from bodies bring considerably higher prices. (see AGATE) -. oi water, or otherwise, may or may not be related to oil structures. Such gas occurrence should be heeded, however, and the area MUSCOVITE . . csl.eTuliy stu&%d for further cifidencc favorable or unfavorable to Musco\~it;e,the most jmyurtant of the mica minerals, occurs the exiztenco of petroIeum. Sv.iface showings do not always have in thin, transparent. more or. less colorless flakes or sheets it1 the appca,n?;

,,-.._. ' curls as it is cut, the amqunt of curling being greatest in the . , richest shales: - Niccolite contains arsenic and nickel and' resembles pyrite : and several of the sulphide minerals. The characteristic pinkish 2. Attempt to burn a sliver or shaving of the shale. High tone to its color usually distinguishes it from the others. prsde' material burns, giving off a characteristic petroleum odor. Niecolite is found in silver ores (except silver-lead ores) . usually with several. copper and cobalt and silver minerals. It is a , a trans- minor, yet important, nickel ore. (see SULPHIDES) Olivine, a silicate 'of iron and magnesium, is green parent to translucent mineral found in basic igneous rocks, OIL (;Petroleum) . especIzlly pejidotite. It is recognized by its granular form.

It is doubtful that any prospector in Alaska is searching - Demand for olivine is not particularly great at the present particularly for oil. Those engaged in the search' for minerals time, but its possibilities have been recognized and are the subject ,, 64 IJQUSTRIAL MIPw A FIm I FOR PROSPECTING IN ALAS= 66 of present investigations. It is likely to become more widely used PEGMATPI'ES in a variety of industrial,applications,chief among which are the The pegmakites are coarse grained, granite type rocks, whose manufacture of refractories and magnesium compounds. impo~tmceis so great that the prospector should constantly watch Its increased use depends, however, on its low price. At for them. So many valuable minerals, both rare and common, are present crude olivine is worth $5.00 to $7.00 per ton. found in or near pegmatite veins and dikes that care should be taken to -recognize the rock and carefully prospect the area, In certain localities large, dear crystds of olivine suitable for including the placers. gem cutting may be found. This gem variety is known as "peridat" . which commands a fair price: By the nature of its formation, a pegmatite contains char- acteristically large, well-formed, interpenetrating crystals of quartz, feldspar'and mica. These are essentially the same minerals comprising ordinary granite, the apparent difference being in the Opal is a hydrous non-crystalline variety of silica occurring in much coarser texture of the pegmatite. numerous forms, many of which are known commercially under other names. Only the more valuable gem varieties are considered Following are listed some of the minerals likely to be found . here. in areas of pegmatite mineralization : Precious Opal is translucent, with a noticeable play of colors, AMBLYGONITE MOLYBDENITE often displaying vivid flashes. Ordinary fire opal is usually white BERYL MONAZITE . may BISMUTH MUSCOVITE or milky, but be variously colored, even black, which is an CASSITERITE POLLUCITE especially valuable type. Thus precious opal may possess various COLUMBTTE QUARTZ and QUARTZ GEMS base colors, yet all display the flashes or fiery play of color. Prec- CRYOLITE RARE EARTH MINERALS ious opal is found deposited in cracks and crevices of rocks, a EMERALD SAPPHIRE particularly favorable occurrence being in andesitic lava rocks. mLDSPAR SPODUMENE , Detached nodules are not uncommon. FLUORITE TAMTALITE ' GARNET TOPAZ - Wood Opal, also called opalized wood, is petrified'woorl in GOLD which the original structure has been replaced by siliceous LEPIDOLITE WOLFRAMXTE solutions, forming opal. Colors are usually black and white. Wood As ja true of the constituent minerals quartz, feldspai and opal will only be found in areas producing petrified wood. mica, the accessory minerals are also often present in large well formed crystals. This accounts for the exceptional production of relatively ,rare gem and specimen from OZOKERITE (Ozocerite, Native parraff in) minerah stones, material, the pegmatites. Recognition of the possibilities presented may b'e Ozokerite is a wax-Iike hydrocarbon, yellowish-brown to green of great value to the prospector. in color. It is found filling veins or fissures in sandstone, shale, or limestone, in areas containing oil. The above discussion, in its entirety, deals with the acid pegmatites. A basic quartzdeficient pegmatite exists but is not Uses inciude the manufacture of high quality candles, floor common and cannot compare with the acid type as a prolific wax and electric wire insulation, source of valuable minerals.

PAPER CLAY Paper clay is a white, grit-free, high grade clay used as a Pentlandite is an important iron-nickel sulphide and has a filler to give weight and body to various kinds of paper. (see , yellow-bronze color. It looh like pyrrhotite and drnost always KAOLIN and CLAY) occurs as very fine grains in pyrrhotite, but that does not mean IN A- 66 . INDUSTRLAE MINERALS AS A FIELD FOR PROSPECTING 67 ' ' ." that pyrrhotik contains nickel as most of it does not carry any. , PUMICE , pyrrhotite that, does contain pen tlandite is sometimes called Pumice is a light colored, light weight, cellular, vo1-i~ ]ava, nickeliferous pyrrhotjte. (see PYRRHOTITEI- fwnd in bedded deposits containing material of si~s,from sand to large b16cks. It is found in the vicinity of volcanoes. PHLOGOPlTE (Amber Mia) Some of the most important uses are listed below : Ph]ogopite is a miaceous mineral resembling MUSGOVITE- - 1. As an abraai*e in cleansing and scouring compounds, and Unlike that however, it occurs in serpentine, e~ystalline. :':..:., - .. .I .,' .. L hard soaps. dolomite, or dolomitic limestone...... -., ,. Uses and prices are much the same as for MUSCOVITE- . .i ,= 2: 'ASan abrasive in polishing metal; glass, wood, atone, etc. . .-. a I I. , .., ,>I I A8 a in .: i;,': ,y. 3.. light concrete work, lowering the ,. .? . . .- 9,. amount of PITCHBLENDE (Uraninits) :It cement required. . ~i..;...+b .?2*.r.'+!. Pitchblende contains uranium, lead, radium, and several rare , 4. AS an insulathg material. elements. rtisfound as ablack, hard, heavy,and brittleminerd '::., :! .. ., ., $0 in metalliferous deposits containing silver; gold, copper, or lead ,-':* :', According the physical properties of the pumice and the use $0 is a ores. Pif,&bIende is a rare mineral but when found! in substantial which it to be put, the price range ~arie8.f~~~few - dollars to $100.00 per ton. quantity, it is valuabie as an ore of both radium and uranium-

, ,. PUMICITE PSILOMELANE . .' ..::< ,. ' Pumicih is very simG to PUDdICE in all respeete except that Psilomelane is a hard, black to brownish-Hack oxide of man- .",.. :'r " . ,:+ it is entirely composed of sharp aNar mains Or fine powder. g&,ese. Other manganese oxides, soft, black and earthy may also -.i.::":?':'.; Y . . -:Pumicite is more apt t6 be found at greater dismce from its be upsent. commercial dep-osits are of secondar~origin, being -?- .'2:. Y'.$ .:- :: b . . , volcanic sourie, sometimes hundreda of miles. bmerdalde- .. ,I.. found in residual clay or bog concentrations. I ... . ' posits, in the form of beds of variable thickness, are oft= overjab A high manganese ore, psilomelane is used in m with overburden of day, sand, etc, . chemicals and dry batteries; in the metdl~rgi~dindustry;'' Usm and values of p~miciteare much the same as those The manufacture of iron and steel requires great quantities mo~t, tion& above under pmc~. of this industry in the western Sbtes, greater attention possibilities of Alaskan ores appears warranted. 'is a silver minerd ~nhiagsilver, antimony, psilomelane ore, depending on the manganese content is bkk to deep-red in color and found in the impurities, is worth from $10.00 to $60-00per bn- f silver veins usudly accompanied by galena, . . and other silver minerals. (see SILVER

POLLUCZTE I Pollucitc is a rare mineral, a silicate of aluminum and cesium, : fortnd in =vities in granites and pegmatites. It is a hard, CO~O~~~SS,: sdphide, contain^, 47 per iron and 53 per cent not particularly heavy minel-al, occurring. massive and in cube-like .: cent found in quantity, pyrite is generdly recognized crysta1s: , its cubit C~YS~~S,metaIlie luster, and brassy b silvery ye]^^^ pr>llucitecontains, &out 80 per cent cesium and is ther .color- .At tiines, if tarnished, or if it occurs finely disseminated,

.I. ,.. .: an important source of that metal. (see CESIUM) .... . , it may have the appearance of other sulphide minerals. , I, ... FOR PROSPECTING IN ALASKA 69 68 INDUSTRIAL MlNmAtS AS A PDLD names. The composition of all is essentially silicon and oxygen, Whenever pyrite, or any other sulphide mineral, is found or SILICA. The association of quartz with some mineral deposits, suspected, it is recommended that a sample be taken and submitted and form occurring in veins, is well recognized. Less for examination and assay. Pyrite is an indication of the possible that massive famijiar, however, are the commercial varieties and uses. Bi-icfly, presence of gold. If gold were presat. ail or majority of it the some are described here. others are described under SILICA. would not be detected by panning, yet such ores may be very rich. Many other ore minerals are commonly associated with pyrite. QUARTZ CRYSTAL,,also known as Larockrrysta~;~ is in exceptionally valuable industrial mineral when found in clear, In addition to being an indicator mineral, pyrite is also a transparent, possible source of SULPHUR ; and after removal of the SULPHUR, flawless crystals. This quality, however, may be by a so to as an iron ore. Considerable pyrite is used in the production of masked surface coating the prospector should learn sulphuric acid and, in the Scandinavian countries, recovery of the identity them by their characteristic form. Crystals exceeding two inches in sizi that may be utiIized in radio and related indus- SULPHUR in the elemental form, or as solid or liquid sulphur. dioxide gas, supplies the pulp and paper industries with their re- tries bring $2.00 to $20.00 or more per pound. Some crystals . weighing many pounds are found and it is not always necessary quirements. (also see PYRRHOTITE, SULPHIDES, SULPHUR, for a specimen to have more than two or three crystal faces intact. and GOSSAN) The prospector should submit any specimen found for examination PYROLUSJTE and determination of the value. Pyrolusite is a soft, black, earthy oxide of manganese found Crystal found unsuitable for such use, yet suitable for fusing in secondary deposits with PSILOMELANE. Their uses and values to manufacture special purpose quartz glass, is worth from $100.00 are the same. to $150.00 per ton. QUARTZ GEMS are separately mentioned under individual headings. IAGATE, AGATXZED WOOD, AMETHYST, BLOOD- Pyromorpbite is a secondary lead mineral, essentially lead STONE, ' CARNELIAN, CHALCEDONY, CITRINE, FLINT, phosphate. Usually greenish to yellow to brown it is rather soft GEODE, JASPER, MOSS AGATE, OPAL, ROSE QUARTZ, and quite heavy, Although considered a minor ore of lead, it is of RUTILATEB QUARTZ, SMOKY QUARTZ). , chief importance to the prospector as an indicator of lead deposits. (see SILICA) It may be found in the upper portions of lead veins or in placer concentrates nearby. Galena and other lead minerals usually RARE EARTH MINERALS accompany . The "rare earth minerals," while numerous, are rare'ely found PYRRHOTITE in commercially important amounts except in placer sands. They Pyrrhotite is a sulphide of iron usually occurring massive. It contain the elements THORIUM, CERIUM, Lan thanurn, Yttrium, etc. and are derived from coarse grained granite or pegmatite has a metallic luster and a reddish-brown bronzy color. It is found rocks. Being heavy and resistant to decomposition they are most associated with or near basic rocks and may contain copper and likeiy to be found with other heavy minerals in streams and beach nickel in substantial amounts. Nickeliferous pyrrhotite is the sands. chief ore of ,nickel. (see PENTLANDITE) . Comments under Pyrite concerning sulphide minerals, iron MONAZITE, a yellow to brown, translucent to opaque mineral and sulphur, are also applicable to pyrrhotik. is the most common of the group, but others possibly present are of ail colors, thus accurate identification in the fjeld is difficult or QUARTZ impossible. It is a,wise policy, therefore, to submit a sample of any heavy, non-magnetic concentrate to the assay office for crust, Quartz, the most common mineral in the earth's has a identification of the constituent minerals. great many forms and colors, many of whicli are given different 70 INDUSTRIAL NZINmAm AS A FIELD FOR PROSPECTING IN ALAsKA ?1

/ The "rare earth minerals" are utfiized as a source of the rare elements. Zn general, the price is about $60.00 per ton, however, Rubellite, a rose-red to pink variety of TOURMALINE is a - an analysis of the concentrate must be made before prospective valuable gem mineral when in clear, transparent crystals. Gem purchasers will quote a price. The purchaser may be interested . -. , qudity material is derived principally from pegmatite dikes and only in one or two of the constituent elements, thus the price , veins. . -, . , depends on the analysis. - RUBY RHO DOCROSlTE . , Ruby, a cle&, red variety of corundum, is one of the most Rhodocrosite is a carbonate of manganese, occurring in g.raz-. ' ,' valuable of all gem stones. Occurrences are not restricted to any ular or compact masses, .colored pink or reddish. It is found in -; particular kind of rock, although metamorphosed and veins with ores of silver, lead, and copper, and may also be asso- ,. .': certah basic igneous dike rocks are the origind source rocks of ciated with the black manganese oxides. To the prospector it is .. , --. - ',:I . most of the ruby produced. Recovery from the rock is practical in . - .. :: ,.. an indicator mineral particularly for silver-lead deposits. ' -:.: to . .. special instances, but most commercial operations are confined 4, . either working the placer sands and gravels, or the soil and clay Pacific Coast activity of the metall~r~icatindustry would- ",,... . .; ", derived from the decomposition of the host rock. stimulate the search for Alaskan manganese ore. Where rhodo- - .).,. d crosite occurs ss a gangue mineral with silver-lead ores, the prac- -2 .. ruby , -. The most valuable is the "pigeon's blood", a purplish as -. I. ticability of recovery a by-product should be considered. :, L ,:,; red colored stone. Those af lighter shades of red are less valuable, , :.< :. .5 yet individual stones of clear flawless character may be worth RHDDONITE . . several hundred dollars per carat (1 ounce equals 140 carats). One Rhodonite is manganese siIicate, pink in color like rhodo- -.' .' exceptionally good "pigeon's blood" may bring one or two thousand crosite but harder. It is little used except as an ornamental stone dollars per carat. or gem material. Deposits of rhadonite may weather tome black ::-,. . Ruby mining operations market most of their produetion for manganese oxides which are important ores of manganese...... use as "jewels" for bearings of watches and scientific instruments. a .:. . .' ,.. ' I' '_ This is an inferior grade unfit for gem use. SAPPHIRE also con- I . .. stitutes a percentage of the same deposits.

Roscoelite is a mica containing vanadium, recognized by its ' . :. !- micaceous foh, minute scales and green to greenish brown color. .:.'-:;j,., When found in sandstones, its most frequent occurrence, it may ..:%:l;:.. . .:. Butile is an oxide of titanium ,commonly ,encountered in placer exist in lenses or in very small flakes disseminated through the,..,;,.,' . concentrates as a heavy, reddish-brown to black mineral, somewhat sandstone giving it a greenish appearance. It has also been found .' : resembling cassiterite. It may be found in a wide variety of rocks . . with quartz as a gangue mineral in gold lodes. >. _ from whence it finds its way into stream sands and gravels. Cer- tain placer deposits may contain enough rutile to permit recovery Roscoelite may contain as much as 29 per cent vanadium oxide . :;?. : as a by-product. Most commercial deposits, however, occur in and is therefore an impoitant vanadium ore. Xt is sold for about ., . , dikes of ultrabasic igneous rocks or granitoid rocks deficient in twenty-five cents per pound of vanadium oxide contained. . . siIicsl.

.. 3 ROSE QUARTZ as .. ': Rutile is marketed chiefly an ore of titanium. Concentrates containing 88 to 90 per cent rutile sell for $60.00 to $75.00 per ton. Rose quartz is similar to ordinary massive quartz in every: ;, :, , way except color. As the name implies it is colored rose red to ,,,: Ninety-four per cent concentrates bring about ten cents per pound. pink, and is seldom, if ever, found in any other form than massivk' :;. ,:<$, : Occasionally clear red crystals may be found which are readily . . . y>; ~t'isof minor use as an ornamental stone and for jewelry. " . -z'u-.;-..:, . >. . . salable for use as gem stones. . -" < RUTILATED QUARTZ colors exist but the greatest value is in the blue stones. Occurrence of sapphire is the same as that given for RUBY. Rutilated quartz is quartz containing long, fine hair-like in- clusions of rutile. Good material, suitable for cutting and polishing, Material for gem use brings from $6.00 to $125.00 per carat or crystals and crystal masses, are in good demand at fair prices (I ounce equals I40 carats). As is also true for RUBY, inferior by dealers, lapidaries and collectors. stones are marketed for use in 'the manufacture of watches and precision instruments. SALT SCIIEELJTE The commercial term "saIt" refers' to the familiar chemical, is , which occurs in solid masses, in natural brines, Scheelite, calcium tungstate, a white, or light colored, heavy, and in salt lakes and sea water. So far as is known, no deposits brittle mineral, containing 80 per cent tungstic oxide. It occurs have been identified in Alaska. Salt, being sotuble in water, only near contacts of granite rocks and limestone ; in quartz veins, or arid country is favorable to the existence of surface deposits or replacement deposits in the metamorphosed limestone. ScheeIite may concentrations; therefore if salt exists in the Territory, it is be found in placer concentrates and whenever whitish concen- probably at some depth below the effect of surface waters. One trates or heavy white pebblcs are found they should be tested for or two such areas, geologicaIly favorable, are known and others tungsten. The location of lode deposits may readily be traced by may well exist. panning, More frequently tharl not, the appearance of even high grade ore will fail to attract attention unless it is ground and Because of the relatively large amount of salt now used in panned. Alaska, and the probability of a larger consumption, any possibility .- of local production should be considered. Scheelite is one of the chief minerals from which the metal tungsten is extracted. Presznt prices are a]-tificially high and post in and In addition to its household use, salt is used packing war prices are most uncertain. Concentrates assaying 60 per cent curing fish and meat, manu-facturing dairy products, curing hides, tungstic oxide are now worth about $1,500.00 per tor^ but this price ice many rejuvenating water softeners, thawing of on streets, and will certainly decline. While a drastic reduction would adversely others. By far the greatest quantities are used by the chemical affect production, it is felt that scheeIite will coljtinue to warrant industry in producing a long list of chemicals which are in turn the prospeetor's attention. used by practically all industries. SANDSTONE Scorodite is a hydrcus arsenate of iron which may be en- Sandstone is a composed of grains of quarl;z countered in surface exposures sf mineralized veins. In some sand plus a natural cementing material. The physical, as welJ as areas it is an important indicator of gold-bearing lodes associated the chemical properties of the rock determine to a great extent with arsenopyrite. Usually it is found as an earthy material, or whether a given sandstone qualifies for any of the many possible possibly only a stain, of pale green to brownish color. Other than uses. as an indicator it has little or no value. Quarried and trimmed sandstone is a most useful BUILDING S~ONE-Probably the next in importance is its use its an abrasive - SILICA in the form of grindstones, BONESTONES and whetstones. Large Silica is an oxide of siticon occurring in many forms and under blocks, shaped in to wheels, are employed to grind wood pulp for the many names. In addition to those already discussed under pulp and paper mills. QUARTZ, other foms have numerous industrial and commercial applications. Other than FLINT, DIATOMITE, SANDSTONE, SAPPHIRE and TRIPOLI, which are discussed separately, a few may be men- Sapphire is a clear blue variety of CORUNDUM, ranking tioned briefly here. The principal ones are chert, , and among the highest valued of all gem stones. Other, more pale silica sand, all possessing qualities adapting them to abrasive 74 INDUSTRIAL MINERALS AS A-Fm I ' FOR PROSPECTING IN ALASKA 76 - - ' use. In addition, however, certain and sands having a ,compounds. As a raw material it is extensively used in the manu- high degree of purity are employed in the manufacture of glass. , . facture of 'enamel and glass. For such uses it is valued at $30.00

High quality glass sands are not particularly abundant and are ' : .... , to $36.00 per ton. . . thus much sought, although the price seldom pennits shipping -,. , :.' HIDDENITE and KUNZITE are two clear, transparent . great distances...... +...... Varieties valuable as gem stones .

SMALTITE ...... ,:I= . STIBNITE Smaltite is an arsenide of cobalt probably containing varying . ..- - Stibnite, antimony sulphide, is a lead-gray, soft mineral oc- amounts of nickel. It occurs massive rather than crystalline; is% :. . .:2 'curring in bladed crystal masses in various rocks, often with gold steel gray in color, often possessing a pinkish tone. Surface -. .*.., ' ' or mercury ores. The chief ore of antimony, it'is also used as a . . exposures may be rather bbck due to the presence of certain raw material in the preparation of safety matches, fireworks, and silver minerals or to effects of weathering. The gangue is likely ' ':. -. - . ... I. rubber manufactures. ", . to be calcite rsther.than quartz and association with silver minerds - 7:. I ..,_: ,A: . : High No .:: wartime prices for antimony ore will not continue. is ores , . common. If such are panned they will reveal a black, non- .. prediction, at,this time, of what the peacetime price may be is ., .' .:, magnetic concentrate, ii which case, they should be submitted possible, but considering the by-product antimony normally pro- for assay. . .:. .' . ' . :, Iittle '.,.. . ..' duced by the smelters, encouragement for Alaskan production . - ,...... :. ,.-:* . is indicated. SMITHSONITE . 1 .x !a .,: .<.:- Smithsonite is a carbonate of zinc, containing over 50 per cent , \ :,!.?;;.., STROMTIANrrE . of that metal. .,.. . . . :.. Found near the surface of zinc deposits, it appears ;r, :::;';:;. x-. , a carbonate of strontium, is similar in appear- as a porous 'material or as an incrustation. The color ,may be : .: y. , " !' an& to barite and calcite, with which it is frequently found. The to Srnithsonite occurrences should be 'i, 1 brown to greenish gray. : preparation of chemicals and compounds of strontium consumes carefully prospected for besides being a minor ore of zinc itself,. . .'. 8 . . . the .greater part of the strontianite produced. It is valued at about its presence indicates an underlying ore body of SPHALERITE. . ':\!:;',";._., ,,; , i! . ' , , , -:. ' ,,,:, q , ' $56.00 per ton. '- :. . : -.% . , ,;., .. I .. . . '.T< SMOKY QUARm , . -. .L. Smoky quartz is ordinary quartz, usualIy crystalline, contain- . :.. .. -,- , ,:. ,:. The relationship of the sulphides and related minerals to ing impurities which give it a light smoky to dark color. Areas of ., , '-. . ,- . co~erciallyimportant mineral deposits is exceedingly importapt, pegmalit. and granite rocks, plrtiedarly pockets in the weathered . '.. , ....- 1.. _, .:i.r . and for this reason the subject is inserted here. By "related ,. . ,. ..,. rock, are a likely source of amoky quartz of gem quality. ... .-. . . > is meant akin . 1 ,q.: ; :..-. &nerale" those minerals somewhat to the sulphjdes, , , com- SPfIALERITE . . ,. =.P- ,-. _ _ : n'mely the arsenides, antimonides, tellurides and various binations, which, when encountered by the prospectof, are usually Sphaksite is the 11phide if zinc, us~al~ylight to dark brown ' . , . considered "sulphide" ores. They may consist of only one or a in color. having the appearance of resin. A wide variety of ores, . '.:--;;:,,,. L:. _I, , . .1. ,, <. is common mixture of several such minerals. Pyrite the most contain sphalerite, particularly those of gold, silver, lead and cop- :,,::, .:'. - . . . . 2. . sulphide ,mineral and it is recognized as such by most prospectors. A. per, in or near limestone. . ,':, , and . < The others are more difficult to accurately identify for our .. . , SPODUMENE purpose here, it suffices to say that any vein or deposit containing Spodumene is lithium aluminum silicate found only in peg- .', :' . "sulphide" minerals should be sampled and the sample submitted - for eximination and assay. matites where it sometimes foms immense'crystds. mite, or : ::: jl.$. ..; . , of green, re- -. tinted some light shade pink, yellow or it strongly .7~ . .. ,:? On fresh fractures most of these minerals have a metallic . , sernbles milky quartz except 'in crystal form and cleavage. , luster and, when fineIy ground, most are black in color. All are Ordinary spodurnene is a source of metallic LITHIUM aind its relatively heavy and thus may be concentrated by panning. Gold

h. :C' 76 INDUSTRIAL MINERAL$ AS A FIELD FOR PIZOSPECTTNG LN mKA may be present in appreciable amount in such ores and yet not be being chiefly of interest as ores of gold and.silver. As such they visible in the pan. Other than gold, the following may also bd may constitute extremely rich ore, yet since no free gold is visible, present, in one form or another, not readily identifiable to the their importance is easily overlooked. ~rosgector: The appearance of gold-silver tellurides may vary from steel- 1. Antimony 8. Nickel gray to bronzy to black. Although they contain from 20 to 60 2. Bismuth 9. Platinum group metals per cent of gold or silver, they yay be brittle and strongly resemble 10. 3. Cadmjum Silver some comparatively worthless iron sulphide mineral. (see SUL 4. Cobalt 11. Tin 5.. Copper 12. Zinc PHIDES) 6. Lead 13. Others 7. Molybdenum TETRAHEDRlTE (Gray copper) The following opinion expressed elsewhere in this report bears , Tetrahedrite contains copper, antimony and sulphur and is repeating. The majority of the prospecting done in Alaska has gray to black in color, with a metallic luster. It is commonly found been for free gold and therefore deposit of the so-called "sulphide" massive, or crystalline, in copper deposits with other copper min- ores offer special promise lo the wise prospector. erals. Requently it carries silver, and at times such content is so high as to constitute the chief value of the ore. TALC (Soapstone, Steatite) Talc is a magnesium recognized by its char- THOMSONITE acteristic smooth or soapy feel. Another mineral which responds Thomsonite is hydrated c~kiurn,sodium, and aluminum sili- in the same manner is pyrophyuite, which since it is marketed cate, which occurs in cavities in basic igneous rocks, particularly under the classification of talc, and has more or less the same basalt. Its only use is as a gem stone, the best material, in the appearance and uses, will be included here. While "saapstone" form of pebbles eroded from the rock, being found in streams and is more properly a massive rock containing a high proportion of residual soils. Thomsonite is gray or white but the best gem talc, it, too, is considered under this heading. material is mottled with rings or layers of red, green or yellow. Uses are many and varied. The chemical and physical prop- erties determine the usefulness of any particular talc, and Lo some TOPAZ extent, the price. Topaz, aluminum fluosilicate, is a hard, transparent to trans- Crude talc commands a tow price, and for various reasons, lucent mineral, usually some shade of yellow, but sometimes pink- prcbably could 11ot be profitably exported from the Territory ish, bluish or greenish prismatic crystals and crystalline masses unless it. w~sn particularly desirable type. are found in pegmatite dikes, in cavities in rhyolite and granite Groulld talc finds use in the manufacture of paper, paints, and also in other rocks. Rounded or worn crysta!s may be found ceramics, roofing, rubber and various minor fieIds. According to in placer sands and gravels. Clear, transparent crystals, whether grade and range,prices may range from $6.00 to $12.00 per ton. rounded or not, bring good prices from the gem cutting trade. Sawed and manufactured talc offers the best oppoltunity ;this is usually soapstone, or the massive quarried stone, from which ' TOURMALINE articles such as table tops, laundry tubs, structural stones, switch Tourmaline is a complex borosilicate of aluminum with a boards, etc. are made at the plant. number of minor and variable constituents. It is ordinariIy found in well developed prismatic or columnar crystals having char- TANTALTTF, (see COLUMBITE) acteristic ~oundedtriangular cross section. Valueless, or of minor value, are the black, opaque varieties. Those of considerable value TELLURIDES as gem stones ar,e transparent and colored green, blue, red, pink, Telluride rni.nera.1~are compounds of tellurium with other ele- or yellow. Due to unusual zonal coloring, individual crystals may ments. They are seldom if ever mined for the tellurium content, display beautiful arrangements of several colors, a frequent occur- 78 INDUSTRIAL MINERALS AS A PlXLIl NRPROSPECTING IN AUSICA 79 , rence being a gradation from green at one end to pink or red at masses. or veins in igneous rocks. Also usually. present i~ an the other. Another type has a core of one color and an outer abundance of kaolinized feldspar, limonite, and other products of portion of a different color. OccasionaIly colorless stones are alteration. ' found. A pink variety, RUBELLITE, is briefly mentioned under Turquoise is cut and used in jewelry. There appears to be a its separate heading. special demand for turquoise matrix (turquoise in the associated The gem are most commonly found in pegmatites. rock)'. Gmd quality rough material may bring several dollars They are a very popular semi-precious stone and also much in per pound. demand by collectors and dealers. . . ' VANADLNPTE

TRAVERTINE '12 ,.,.,,I Vanadinite is a vanadium and lead mineral occurring as crys- . , .... .* . talline or globular incrustations in the upper portion of lead veins. Travertine 'is calcium carbonate (limestone), deposited by .,. . , ' ; ,. , quite small, are deep red (infrequent- mineral springs. It may be of a cellular, porous type or solid and ',,., .I:, ::; . The crystals, usually in color ' ly yellow or green) and have a resinous luster. Pure vanadinite banded. The former type is admirably suited for use as a soil '1:. '-.>:.,A d:',;.:'-.+- . conditioner and is marketed as "agricultural lime." The solid form contains about 19 per cent vanadium oxide and is sold for about 27 :,.:,. -.,, :.!;. ' has, generally, the uses of LIMESTONE, and when it takes a high :. -,:, .ev.- , . .. , cents per pound of contained vanadium oxide. -- I. polish, of MARBLE. 1. ';. ,-'.. . , " VERMICULITE . . , , . ,! !Is TREMOLITE !I ,; ,.. , ,..:$:: ,,.- ,. ,pL :, . . * Vermiculite is a name applied to certain mica minerals that

,. =.'- ,.5.; , ""-"? Tremolite, calcium magnesium silicate is ah amphibole mineral - , . ' are derived from alterations of other micas and have the property - , of greatly expanding when moderately heated. Whenever mica- of no particular value except in one fom, that of the fibrous or ;',' ; ' - :,. . '. - ashstiform variety. Tremolite asbestos, as this iis called, is a . ;;'.., . - ..,, ' -, ceous. minerals are recognized in quantity, it-is well to test a .' . ,,, . and minor ASBESTOS mineral, yet it may be of some importance. Only . 7 '-:. .. '. selective sample of the flakes with a match flame or camp fire . ,. ,". . " by laboratory investigation can fibrous tremolite be definitely, , . .' ' note if it expands and becom~s''fluffy." distinguished from the more valuable ASBESTOS minerals and , . Vermiculite is extremely well suited for building insulation

'. , ' ' such investigation is also requb'ed to determine its possible use- ' , ' . and is chiefly so used. Production to supply the Alaskan demands , . f ulness. (see ASBESTOS). . -...... alone would be a most profitable enterprise . Commercially it is : -. . . valued at $8.00 to $12.00 per ton, but local retail sales by the sack TRIPOLI , , would realize considerably more. nipoli is a form of silica, white, fine granular, porous, and , " . ' usually soft and easily crumbled, although it may occur firm and , , , WUILEMITE , -1 , , rather hard. It occurs in bedded deposits in sedimaw xocks, . -., .. - . WiIlemite, zinc silicate, is found generally in massive to granu- . I notably chert and limestone. , . , lar'form, near igneous intrusions in limestone. Its color varies ' Tripoli is used for an abrasive in many trades, pdieularly, , .. from white to yelIow to bluish, and with impurities, it may appear . however, in polishing metals. It is also used in foundry work, . .. ,-, ;. . . greehish to brown. Other zinc minerals, especially ZINCITE, are ,, y.' ,. - : - ,. associated with the ore, but sulphide minerals are rarely present, paint and rubber manufacture, and numerous other fields. The .:. *, , .': - value is low, somewhere around $10.00 per ton, but sgmidly pre- -. .. -. hence SPHALERITE is absent. Such desposits are few in number,

' ' yet pared tripoli for special uses may bring $20.00 to $30.00 per ton ".. , . . .. . they are major producers of high-grade zinc ore. or higher. . . TURQUOISE . Witherite, barium carbonate, is found in veins in sedimentary Turquoise is a hydrated aluminum copper phosphate, rardy. ' rocks, usually with barite; sometimes with galena or fluorite. It found-crystalline. It is found as waxy to dull blue or green, opaque is a rather heavy, white or gray, translucent mineral: commonly

. , occurring finely crystalline or granular. Used in the preparation of barium compounds and chemjcals, the ground, 90 per cent pure material has a value of about $40.00 per ton. WOLFRAMPI'E I Wolframite, a tungstate of iron and nlanganese, is black to brownish black in color and very heavy. It occurs in granite and pegmatite veins either massive or in bladed or columnar crystal form. It may be found in placer concentrates and is easily mis- taken for some worthless oxide mineral of iron. Wolframite is also important as an indicator mineral because of its frequent association with CASSITERITE, TANTALITE, and many others. It is a major ore of tungsten. Prices are about the same as those for SCHEEXJTE. (Comments pertaining to future economic considerations made there also apply to wolf rami te.) ZINCITE I Zincite is an oxide of zinc and occurs in same manner as 1 the I . WILLEMITE with which it is associated. A red mineral, somewhat resmbling cinnabar, it has a platy or granular structure and is usually found massive rather than as recognizable crystals.

Zircon, a silicate of zirconium, is usually found in opaque to transparent crystals or crystal fragments of some shade of brown, although they may also be colorless to greenish to red. Originally derived from igneous and metamorphic rocks, the mineral is pro- duced commercially from alluvial sands where it has naturally accumulated. In such deposits the zircon crystals acquire a worn and rou.nded appearance. Although transparent stones are sold for use as gems, this is not the only use of zircon. It has important and increasing industrial applications in the manufacture of enamels, porcelain and glass. Zil-conium metal and certain compounds prepared from zircon, are of major importance to the steel and metals industry, electrical manufactures and others. . Concentrates assaying 55 per cent zirconium oxide are worth $65.00 to $75.00 per ton. . . I