Sodium Chromate 10 Percent Section 1
Total Page:16
File Type:pdf, Size:1020Kb
Conforms to US OSHA Hazard Communication 29CFR1910.1200 SAFETY DATA SHEET Sodium Chromate 10 percent Section 1. Identification 1.1 Product identifier Product name : Sodium Chromate 10 percent Part no. : AR176, AR376 Validation date : 6/24/2020 1.2 Relevant identified uses of the substance or mixture and uses advised against Material uses : Laboratory use Container type: Dispenser Pack AR176 // Sodium Chromate 10 percent // Artisan Grocott's Methenamine Silver Stain Kit // 65 mL and 115 mL AR376 // Sodium Chromate 10 percent // Artisan Grocott's Methenamine Silver Eosin Stain Kit // 65 mL and 115 mL Reference number: SDS056 1.3 Details of the supplier of the safety data sheet Supplier/Manufacturer : Agilent Technologies, Inc. 5301 Stevens Creek Blvd Santa Clara, CA 95051, USA Tel: +1 800 227 9770 Agilent Technologies Singapore (International) Pte Ltd. No. 1 Yishun Avenue 7 Singapore, 768923 Tel. (65) 6276 2622 Agilent Technologies Denmark ApS Produktionsvej 42 2600 Glostrup, Denmark Tel. +45 44 85 95 00 www.Agilent.com e-mail address of person : [email protected] responsible for this SDS 1.4 Emergency telephone number In case of emergency : CHEMTREC®: 1-800-424-9300 Section 2. Hazards identification 2.1 Classification of the substance or mixture OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the substance or mixture Date of issue : 06/24/2020 1/15 Sodium Chromate 10 percent Section 2. Hazards identification H302 ACUTE TOXICITY (oral) - Category 4 H311 ACUTE TOXICITY (dermal) - Category 3 H331 ACUTE TOXICITY (inhalation) - Category 3 H314 SKIN CORROSION - Category 1B H318 SERIOUS EYE DAMAGE - Category 1 H334 RESPIRATORY SENSITIZATION - Category 1 H317 SKIN SENSITIZATION - Category 1 H340 GERM CELL MUTAGENICITY - Category 1 H350 CARCINOGENICITY - Category 1B H360 TOXIC TO REPRODUCTION - Category 1B H372 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 H411 AQUATIC HAZARD (LONG-TERM) - Category 2 2.2 GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : H302 - Harmful if swallowed. H311 + H331 - Toxic in contact with skin or if inhaled. H314 - Causes severe skin burns and eye damage. H317 - May cause an allergic skin reaction. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H340 - May cause genetic defects. H350 - May cause cancer. H360 - May damage fertility or the unborn child. H372 - Causes damage to organs through prolonged or repeated exposure. (blood, kidneys, liver, lungs) H411 - Toxic to aquatic life with long lasting effects. Precautionary statements Prevention : P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P280 - Wear protective gloves. Wear eye or face protection. Wear protective clothing. P284 - Wear respiratory protection. P271 - Use only outdoors or in a well-ventilated area. P273 - Avoid release to the environment. P260 - Do not breathe vapor. P270 - Do not eat, drink or smoke when using this product. P264 - Wash hands thoroughly after handling. P272 (OSHA) - Contaminated work clothing must not be allowed out of the workplace. Response : P391 - Collect spillage. P314 - Get medical attention if you feel unwell. P308 + P313 - IF exposed or concerned: Get medical attention. P304 + P341 (OSHA) + P310 - IF INHALED: If breathing is difficult, remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or physician. P342 + P311 - If experiencing respiratory symptoms: Call a POISON CENTER or physician. P301 + P310 + P330 + P331 - IF SWALLOWED: Immediately call a POISON CENTER or physician. Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 + P363 + P310 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER or physician. P302 + P361 + P364 + P352 + P312 + P363 - IF ON SKIN: Take off immediately all contaminated clothing and wash it before reuse. Wash with plenty of soap and water. Date of issue : 06/24/2020 2/15 Sodium Chromate 10 percent Section 2. Hazards identification Call a POISON CENTER or physician if you feel unwell. Wash contaminated clothing before reuse. P333 + P313 - If skin irritation or rash occurs: Get medical attention. P305 + P351 + P338 + P310 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or physician. Storage : P405 - Store locked up. Disposal : P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations. Supplemental label : Do not taste or swallow. Wash thoroughly after handling. elements 2.3 Other hazards Hazards not otherwise : Causes digestive tract burns. classified Section 3. Composition/information on ingredients Substance/mixture : Mixture Ingredient name % CAS number Chromic acid (H2CrO4), disodium salt, tetrahydrate ≥10 - <25 10034-82-9 Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures 4.1 Description of necessary first aid measures Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Inhalation : Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In the event of any complaints or symptoms, avoid further exposure. Skin contact : Get medical attention immediately. Call a poison center or physician. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Date of issue : 06/24/2020 3/15 Sodium Chromate 10 percent Section 4. First aid measures Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. 4.2 Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Causes serious eye damage. Inhalation : Toxic if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin contact : Causes severe burns. Toxic in contact with skin. May cause an allergic skin reaction. Ingestion : Harmful if swallowed. Corrosive to the digestive tract. Causes burns. Over-exposure signs/symptoms Eye contact : Adverse symptoms may include the following: pain watering redness Inhalation : Adverse symptoms may include the following: wheezing and breathing difficulties asthma reduced fetal weight increase in fetal deaths skeletal malformations Skin contact : Adverse symptoms may include the following: pain or irritation redness blistering may occur reduced fetal weight increase in fetal deaths skeletal malformations Ingestion : Adverse symptoms may include the following: stomach pains reduced fetal weight increase in fetal deaths skeletal malformations 4.3 Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained