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From Molecular Architecture and Electrostatic Interactions to Underwater Adherence of Hydrogels Francisco Javier Cedano Serrano

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From Molecular Architecture and Electrostatic Interactions to Underwater Adherence of Hydrogels Francisco Javier Cedano Serrano From molecular architecture and electrostatic interactions to underwater adherence of hydrogels Francisco Javier Cedano Serrano To cite this version: Francisco Javier Cedano Serrano. From molecular architecture and electrostatic interactions to underwater adherence of hydrogels. Polymers. Sorbonne Université, 2019. English. NNT : 2019SORUS056. tel-02968194 HAL Id: tel-02968194 https://tel.archives-ouvertes.fr/tel-02968194 Submitted on 15 Oct 2020 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Sorbonne Université ED 397 : Physique et Chimie des Matériaux Laboratoire Sciences et Ingénierie de la Matière Molle (SIMM) – ESPCI Paris From molecular architecture and electrostatic interactions to underwater adherence of hydrogels Par Francisco J. CEDANO-SERRANO Thèse de doctorat de Chimie et Physico-chimie des Polymères Dirigée par Yvette TRAN, Dominique HOURDET et Costantino CRETON Présentée et soutenue publiquement le 13/05/2019 Devant un jury composé de : RESTAGNO, Frédéric Chargé de recherche CNRS. Université Paris-Saclay. Rapporteurs GEOGHEGAN, Mark Professeur. University of Sheffield. DEL CAMPO BÉCARES, Aránzazu Professeur. Saarland University. Examinatrices LINDNER, Anke Professeur. Université Paris Diderot. CRETON, Costantino Directeur de recherche CNRS. ESPCI Paris. Directeur de thèse HOURDET, Dominique Professeur. Sorbonne Université. ESPCI Paris. Co-directeurs de thèse TRAN, Yvette Maître de Conférences. ESPCI Paris. From molecular architecture and electrostatic interactions to underwater adherence of hydrogels Francisco J. CEDANO-SERRANO Yvette TRAN, Dominique HOURDET and Costantino CRETON May 13th, 2019 Acknowledgments At the end of this doctoral thesis. I would like to express my gratitude to all the different people who have encouraged and supported me during these years. I would like to start by acknowledging my principal supervisor Costantino. First, for gave me his confidence and his guidance during my PhD, but also his friendship during these years. I am also very grateful to Dominique and Yvette. I admire them very much and I greatly appreciate the discussions and all their academic and non-academic advices during these 3 years. I believe the three of them form an excellent team of supervisors that can guide several PhD students in different areas of research in the SIMM lab at ESPCI. During my dissertation, it was an honour for me to have professor Mark Geoghegan, Frederic Restagno, Anke Linder and Arancha del Campo as members of the jury in the dissertation of my doctoral thesis. Thank you very much for accepting to review my thesis and for the valuable discussion during this. In particular, thanks to professors Frédéric and Mark for accepting to write the respective report of the manuscript and for Anke to be president of the jury committee. I would like to thank all the members of the BioSmartTrainee network. This innovative training network led by Alla Synytska in Dresden, gave me the opportunity to pursue a PhD in a unique environment of fantastic collaboration and outstanding scientific and soft skills training in the field of adhesion science. As a fellow researcher in this network, I was able to collaborate with remarkable researchers and to share memorable experiences during these years. I would like to thank professors Marleen Kamperman and Alla Synytska, since the conclusions of this doctorate would not be the same if it were not for our collaborations. I want to highlight the ESRs Marco Dompé, Ugo Sidoli and Mehdi Vahdati with who I had the honour of working together and shared treasured moments. I also want to thank the long and valuable discussions with Victor Kang, Justine Tavera, Dimitris Mintis and Maria Villou, and also the rest of the ESRs, Aurelie Feat, Vaishali Chopra and Maciej Chudak. During the preparation of this manuscript and my PhD, I have been help by many. I am particularly grateful to my friends in the lab; Robert Gurney, Pierre Millereau, Jingwen Zhao, Helen Minsky and Gabriel Sanoja who made valuable comments for improving my scientific writing and oral presentations skills. I want to thank all of them as well for their friendship and for making my life easier and more enjoyable inside and outside ESPCI. I would like to thank all the permanents in SIMM Lab and all the students and postdocs for their friendship, discussions, help, encouragements, and more important, for all the football and tennis games. Especially, I want to thank, Bruno, Valentine, Paul E., Paul F., Cécile M, Cécile C, Antoine F., Giorgia, Cyprian, Pascal, Anne-Charlotte, Juliette, Nassim, Xavier, Melanie, Milena, Julien, Louis, Yinjun, Josh, Ekkchai… I want to thank my friends outside the lab. The Parisian group; Madda, Pekka, Connie and Sibell, and also my Colombian friends; Susana, Diana, Coloso, Juan, Manu, Juli, and Harry. Thank you for enriching my life with unforgettable moments during these years. I want to thank my parents and my family for their loving and continuous support during my PhD. Above all I want to thank Leonie for all the hours she dedicated to listen to all my excited stories of underwater glues and for her loving and constant support during our time together, especially during the days of writing the manuscript. Muchas gracias, Francisco CEDANO – 20/05/2019 ii Table of Contents CONTENTS ...................................................................................................... III 1. UNDERWATER ADHESION: CONTEXT AND OBJECTIVES. ......... 7 1.1. INTRODUCTION ............................................................................................................... 9 1.2. UNDERWATER ADHESION IN NATURE ........................................................................... 10 1.3. BIO-INSPIRED ADHESIVE SYSTEMS ............................................................................... 13 1.4. MOLECULAR INTERACTIONS INVOLVED IN UNDERWATER ADHESION ........................ 16 1.5. MEASUREMENT OF ADHESION UNDERWATER .............................................................. 19 1.6. OBJECTIVES OF THE THESIS.......................................................................................... 32 1.7. OUTLINE OF THIS MANUSCRIPT .................................................................................... 38 REFERENCES ........................................................................................................................ 39 PART I 2. FROM MOLECULAR ELECTROSTATIC INTERACTIONS TO MACROSCOPIC UNDERWATER ADHERENCE. .................................... 51 2.1. INTRODUCTION ............................................................................................................. 54 2.2. THEORY ......................................................................................................................... 56 2.3. EXPERIMENTAL ............................................................................................................. 63 2.4. RESULTS ........................................................................................................................ 74 2.5. DISCUSSION ................................................................................................................... 83 2.6. CONCLUSIONS ............................................................................................................... 92 REFERENCES ........................................................................................................................ 93 3. UNDERWATER ADHERENCE SCREENED BY SALT. A PROBE- TACK TEST AND AFM COLLOIDAL PROBE STUDY. .......................... 97 3.1. INTRODUCTION ........................................................................................................... 100 3.2. THEORY ....................................................................................................................... 109 3.3. EXPERIMENTAL ........................................................................................................... 116 iii 3.4. RESULTS ...................................................................................................................... 122 3.5. DISCUSSION ................................................................................................................. 133 3.6. CONCLUSIONS ............................................................................................................. 137 REFERENCES ...................................................................................................................... 138 PART II 4. UNDERWATER ADHESION BETWEEN OPPOSITELY CHARGED GELATIN-BASED HYDROGELS. .............................................................. 145 4.1. INTRODUCTION ........................................................................................................... 148 4.2. THEORY ....................................................................................................................... 158 4.3. EXPERIMENTAL ........................................................................................................... 159 4.4.
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