DOCSLIB.ORG

Reconnaissance Data for Glyphosate, Other Selected Herbicides, Their Degradation Products, and Antibiotics in 51 Streams in Nine Midwestern States, 2002

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Reconnaissance Data for Glyphosate, Other Selected Herbicides, Their Degradation Products, and Antibiotics in 51 Streams in Nine Midwestern States, 2002 science for a changing world Prepared as part of the U.S. GEOLOGICAL SURVEY TOXIC SUBSTANCES HYDROLOGY PROGRAM Reconnaissance Data for Glyphosate, Other Selected Herbicides, Their Degradation Products, and Antibiotics in 51 Streams in Nine Midwestern States, 2002 Open-File Report 03-217 ) MINNESOTA \ r- WISCONSIN. V «V \\%- o/'s*-' \_\ \ \.\sV ^ IUVV3 34\10 ,..^T 7 ^V. V:f U.S. Department of the Interior U.S. Geological Survey U.S. Department of the Interior U.S. Geological Survey Reconnaissance Data for Glyphosate, Other Selected Herbicides, Their Degradation Products, and Antibiotics in 51 Streams in Nine Midwestern States, 2002 By ELISABETH A. SCRIBNER, WILLIAM A. BATTAGLIN, JULIE E. DIETZE, and E.M. THURMAN Open-File Report 03-217 Prepared in cooperation with the U.S. GEOLOGICAL SURVEY TOXIC SUBSTANCES HYDROLOGY PROGRAM Lawrence, Kansas 2003 CONTENTS Abstract.....................................................................................................................................................^ 1 Introduction .................................................................................................................................................................^ 1 Previous Studies........................................................................................................................................................... 1 Changes in Herbicide Use Since 1989 ........................................................................................................................ 3 Herbicide Degradation Products.................................................................................................................................. 4 Antibiotics ................................................................................................................................................................. 5 Purpose and Scope of Report....................................................................................................................................... 6 Methods ....................................................................................................................................^ 6 Selection of Sampling Sites......................................................................................................................................... 6 Sample Collection..........................................................................................................................................^ 6 Sample Processing....................................................................................................................................................... 6 Laboratory Methods .................................................................................................................................................. 8 Gas Chromatography/Mass Spectrometry......................................................................................................... 8 Liquid Chromatography/Mass Spectrometry .................................................................................................... 12 Analytical Results....................................................^ 13 Streamflow and Physical Properties............................................................................................................................ 13 Results of Laboratory Method Analysis Code GCS.................................................................................................... 13 Results of Laboratory Method Analysis Code LCAA................................................................................................. 14 Results of Laboratory Method Analysis Code LCEA................................................................................................. 15 Results of Laboratory Method Analysis Code LCGY................................................................................................. 15 Results of Laboratory Method Analysis Code LCAN................................................................................................. 16 Quality-Control Samples............................................................................................................................................. 17 Duplicate Analysis of Selected Herbicides ................................................................................................................. 18 References Cited.................................................................. 18 Supplemental Information............................................................................................................................... 21 FIGURES 1. Map showing location of study area, stream sampling sites, and associated drainage areas sampled during 2002 2 2. Graph showing herbicide use in Midwestern United States, 1990-2001 ............................................................... 4 3. Chemical structure diagrams showing pathways for degradation of atrazine, cyanazine, propazine, and simazine todeethylatrazineanddeisopropylatrazine............................................................................................................. 5 4-7. Graphs showing: 4. Number of detections for selected herbicides and degradation products determined by laboratory method analysis code GCS for pre-emergence, post-emergence, and harvest-season runoff samples collected from 51 streams in nine Midwestern States, 2002 ..................................................................................................... 14 5. Number of detections for selected acetamide degradation products determined by laboratory method analysis code LCAA for pre-emergence, post-emergence, and harvest-season runoff samples collected from 51 streams in nine Midwestern States, 2002 ..................................................................................................... 15 6. Number of detections for selected triazine and phenylurea herbicides and their degradation products determined by laboratory method analysis code LCEA for pre-emergence, post-emergence, and harvest- season runoff samples collected from 51 streams in nine Midwestern States, 2002......................................... 16 7. Number of detections for glyphosate, its degradation product, AMPA, and glufosinate determined by laboratory method analysis code LCGY for pre-emergence, post-emergence, and harvest-season runoff samples collected from 51 streams in nine Midwestern States, 2002............................................................... 17 Contents III TABLES 1. Names, locations, and drainage areas for 51 stream sampling sites in nine Midwestern States, 2002.................. 7 2. Chemical compounds, laboratory method analysis codes, USGS parameter codes, approved USGS method numbers, and reporting limits determined for water samples collected from 51 streams in nine Midwestern States, 2002................................................................................................................................................ 9 3. Streamflow and physical properties determined for water samples collected from 51 streams in nine Midwestern States, 2002......................................................................................................................................... 22 4. Statistical summary of Streamflow and physical properties determined for water samples collected from 51 streams in nine Midwestern States, 2002 .......................................................................................................... 29 5. Concentrations of selected herbicides and degradation products determined by laboratory method analysis code GCS for water samples collected from 51 streams in nine Midwestern States, 2002 .................................. 30 6. Statistical summary of concentrations of selected herbicides and degradation products determined by laboratory method analysis code GCS for water samples collected from 51 streams in nine Midwestern States, 2002........ 47 7. Concentrations of selected acetamide degradation products determined by laboratory method analysis code LCAA for water samples collected from 51 streams in nine Midwestern States, 2002 ................................ 49 8. Statistical summary of concentrations of selected acetamide degradation products determined by laboratory method analysis code LCAA for water samples collected from 51 streams in nine Midwestern States, 2002 ..... 67 9. Concentrations of selected triazine and phenylurea herbicides and their degradation products determined by laboratory method analysis code LCEA for water samples collected from 51 streams in nine Midwestern States, 2()02..............................................................._ 69 10. Statistical summary of concentrations of selected triazine and phenylurea herbicides and their degradation products determined by laboratory method analysis code LCEA for water samples collected from 51 streams in nine Midwestern States, 2002............................................................................................................................. 93 11. Concentrations of glyphosate, its degradation product, AMPA, and glufosinate determined by laboratory method analysis code LCGY for water samples collected from 51 streams in nine Midwestern States, 2002 ..... 95 12. Statistical summary of concentrations of glyphosate, its degradation product, AMPA, and glufosinate determined by laboratory method analysis code LCGY for water samples collected from 51 streams
Load more

Recommended publications
  • MN2000 FSAC 006 Revised1978.Pdf
    -i .., ,,, (I-,~-- -' d ~-- C:::- ,, AG RIC UL TURAL EXTENSION SERVICE Afr{ ,<"·<,'>· , -> ',' "\, '. '' ~'¥) AGRICULTURAL CHEMICALS FACT SHEET No. 6-1978 Chemicals for'Weed Cop: GERALD R. MILLER . \~:::sr" This fact sheet is intended only as a summary of suggested Herbicide names and formulations alternative chemicals for weed control in corn. Label informa­ Common Trade Concentration and tion should be read and followed exactly. For further informa­ name name commercial formulation 1 tion, see Extension Bulletin 400, Cultural and Chemical Weed Control in Field Crops. Alachlor Lasso 4 lb/gal L Lasso 11 15% G Selection of an effective chemical or combination of chemicals Atrazine AAtrex, 80% WP, 4 lb/gal L should be based on consideration of the following factors: others 80%WP -Clearance status of the chemical Atrazine and propachlor AAtram 20% G -Use of the crop Bentazon Basagran 4 lb/gal L -Potential for soil residues that may affect following crops Butylate and protectant Sutan+ 6.7 lb/gal L -Kinds of weeds Cyanazine Bladex 80% WP, 15% G, 4 lb/gal L -Soil texture Dicamba Banvel 4 lb/gal L -pH of soil Dicamba and 2,4-D Banvel-K 1.25 lb/gal dicamba -Amount of organic matter in the soil 2.50 lb/gal 2,4-D -Formulation of the chemical EPTC and protectant Eradicane 6.7 lb/gal L -Application equipment available Linuron Lorox 50%WP -Potential for drift problems Metolachlor Dual 6 lb/gal L Propachlor Bexton, 65% WP, 20% G, 4 lb/gal L Ramrod 2,4-D Several Various 1 G = granular, L = liquid, WP= wettable powder Effectiveness of herbicides on
    [Show full text]
  • 2,4-Dichlorophenoxyacetic Acid
    2,4-Dichlorophenoxyacetic acid 2,4-Dichlorophenoxyacetic acid IUPAC (2,4-dichlorophenoxy)acetic acid name 2,4-D Other hedonal names trinoxol Identifiers CAS [94-75-7] number SMILES OC(COC1=CC=C(Cl)C=C1Cl)=O ChemSpider 1441 ID Properties Molecular C H Cl O formula 8 6 2 3 Molar mass 221.04 g mol−1 Appearance white to yellow powder Melting point 140.5 °C (413.5 K) Boiling 160 °C (0.4 mm Hg) point Solubility in 900 mg/L (25 °C) water Related compounds Related 2,4,5-T, Dichlorprop compounds Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) 2,4-Dichlorophenoxyacetic acid (2,4-D) is a common systemic herbicide used in the control of broadleaf weeds. It is the most widely used herbicide in the world, and the third most commonly used in North America.[1] 2,4-D is also an important synthetic auxin, often used in laboratories for plant research and as a supplement in plant cell culture media such as MS medium. History 2,4-D was developed during World War II by a British team at Rothamsted Experimental Station, under the leadership of Judah Hirsch Quastel, aiming to increase crop yields for a nation at war.[citation needed] When it was commercially released in 1946, it became the first successful selective herbicide and allowed for greatly enhanced weed control in wheat, maize (corn), rice, and similar cereal grass crop, because it only kills dicots, leaving behind monocots. Mechanism of herbicide action 2,4-D is a synthetic auxin, which is a class of plant growth regulators.
    [Show full text]
  • Herbicide Mode of Action Table High Resistance Risk
    Herbicide Mode of Action Table High resistance risk Chemical family Active constituent (first registered trade name) GROUP 1 Inhibition of acetyl co-enzyme A carboxylase (ACC’ase inhibitors) clodinafop (Topik®), cyhalofop (Agixa®*, Barnstorm®), diclofop (Cheetah® Gold* Decision®*, Hoegrass®), Aryloxyphenoxy- fenoxaprop (Cheetah®, Gold*, Wildcat®), fluazifop propionates (FOPs) (Fusilade®), haloxyfop (Verdict®), propaquizafop (Shogun®), quizalofop (Targa®) Cyclohexanediones (DIMs) butroxydim (Factor®*), clethodim (Select®), profoxydim (Aura®), sethoxydim (Cheetah® Gold*, Decision®*), tralkoxydim (Achieve®) Phenylpyrazoles (DENs) pinoxaden (Axial®) GROUP 2 Inhibition of acetolactate synthase (ALS inhibitors), acetohydroxyacid synthase (AHAS) Imidazolinones (IMIs) imazamox (Intervix®*, Raptor®), imazapic (Bobcat I-Maxx®*, Flame®, Midas®*, OnDuty®*), imazapyr (Arsenal Xpress®*, Intervix®*, Lightning®*, Midas®* OnDuty®*), imazethapyr (Lightning®*, Spinnaker®) Pyrimidinyl–thio- bispyribac (Nominee®), pyrithiobac (Staple®) benzoates Sulfonylureas (SUs) azimsulfuron (Gulliver®), bensulfuron (Londax®), chlorsulfuron (Glean®), ethoxysulfuron (Hero®), foramsulfuron (Tribute®), halosulfuron (Sempra®), iodosulfuron (Hussar®), mesosulfuron (Atlantis®), metsulfuron (Ally®, Harmony®* M, Stinger®*, Trounce®*, Ultimate Brushweed®* Herbicide), prosulfuron (Casper®*), rimsulfuron (Titus®), sulfometuron (Oust®, Eucmix Pre Plant®*, Trimac Plus®*), sulfosulfuron (Monza®), thifensulfuron (Harmony®* M), triasulfuron (Logran®, Logran® B-Power®*), tribenuron (Express®),
    [Show full text]
  • Special Report 354 April 1972 Agricultural Experiment Station
    ORTMAL DO ;10T REMOVE 7.9 m FILE Special Report 354 April 1972 Agricultural Experiment Station Oregon State University, Corvallis I FIELD APPLICATION OF HERBICIDES--AVOIDING DANGER TO FISH Erland T. Juntunen Department of Fisheries and Wildlife Oregon State University Corvallis, Oregon and Logan A. Norris Pacific Northwest Forestry Sciences Laboratory and Range Experiment Station Forest Service, U. S. Department of Agriculture Corvallis, Oregon April, 1972 Trade names are used in this publication solely to provide specific information. No endorsement of products is intended nor is criticism implieLl to products mentioned or omitted. Recommendations are not made concerning safe use of products nor is any guarantee or warranty of results or effects of the products intended or implied. ii Chemical weed and brush control with herbicides is an important land management practice in modern agriculture and forestry. In some cases, herbicides are applied directly to bodies of water for aquatic weed control. More commonly, herbicides are applied to lands adjacent to waterways for general weed and brush control. The responsible applicator will avoid damage to fishery resources by being fully aware of a particular herbicides potential hazard to fish. Herbicide applications should be considered hazardous to fish when there is the probability fish will be exposed to herbicide concen- trations which are harmful. This bulletin offers information that will aid in selecting the particular herbicides and formulations of least hazard to fish considering the toxicity of the herbicide and the poten- tial for its entry into streams, lakes, or ponds. Entry of Herbicides into the Aquatic Environment In aquatic weed control, the effective concentration of herbicide in the water depends on the rate of application, the rate of the spread of the chemical, the size and chemical composition of the body of water, the rate of degradation or adsorption of the chemical on sediments, and the rate of mixing of treated water with untreated water.
    [Show full text]
  • INDEX to PESTICIDE TYPES and FAMILIES and PART 180 TOLERANCE INFORMATION of PESTICIDE CHEMICALS in FOOD and FEED COMMODITIES
    US Environmental Protection Agency Office of Pesticide Programs INDEX to PESTICIDE TYPES and FAMILIES and PART 180 TOLERANCE INFORMATION of PESTICIDE CHEMICALS in FOOD and FEED COMMODITIES Note: Pesticide tolerance information is updated in the Code of Federal Regulations on a weekly basis. EPA plans to update these indexes biannually. These indexes are current as of the date indicated in the pdf file. For the latest information on pesticide tolerances, please check the electronic Code of Federal Regulations (eCFR) at http://www.access.gpo.gov/nara/cfr/waisidx_07/40cfrv23_07.html 1 40 CFR Type Family Common name CAS Number PC code 180.163 Acaricide bridged diphenyl Dicofol (1,1-Bis(chlorophenyl)-2,2,2-trichloroethanol) 115-32-2 10501 180.198 Acaricide phosphonate Trichlorfon 52-68-6 57901 180.259 Acaricide sulfite ester Propargite 2312-35-8 97601 180.446 Acaricide tetrazine Clofentezine 74115-24-5 125501 180.448 Acaricide thiazolidine Hexythiazox 78587-05-0 128849 180.517 Acaricide phenylpyrazole Fipronil 120068-37-3 129121 180.566 Acaricide pyrazole Fenpyroximate 134098-61-6 129131 180.572 Acaricide carbazate Bifenazate 149877-41-8 586 180.593 Acaricide unclassified Etoxazole 153233-91-1 107091 180.599 Acaricide unclassified Acequinocyl 57960-19-7 6329 180.341 Acaricide, fungicide dinitrophenol Dinocap (2, 4-Dinitro-6-octylphenyl crotonate and 2,6-dinitro-4- 39300-45-3 36001 octylphenyl crotonate} 180.111 Acaricide, insecticide organophosphorus Malathion 121-75-5 57701 180.182 Acaricide, insecticide cyclodiene Endosulfan 115-29-7 79401
    [Show full text]
  • Weed Control in Corn Tjay 11 1932 Gerald R
    MN d-ooo E-f- b'-f/ EXTENSION FOLDER 641-1982 Weed Control in Corn tJAY 11 1932 Gerald R. Miller, Extension Agronomist Richard Behrens, Professor, Agronomy and Plant Genetics Weed control in corn should be based on an optimum com­ or preemergence herbicides have been applied, unless a prop­ bination of cultural, mechanical, and chemical practices. The erly timed postemergence herbicide treatment is planned. ideal combination for each field will depend on several factors Set cultivators for shallow operation to avoid pruning the including crop being grown, kinds of weeds, severity of the corn roots and to reduce the number of weed seeds brought weed infestation, soil characteristics, tillage practices, cropping to the surface. Throw enough soil into the row to cover small systems, and availability of time and labor. weeds, but avoid excessive ridging that may encourage erosion or interfere with harvesting. Shallow cultivation should be re­ Cultural Practices peated as necessary to control newly germinated weeds. Cultural practices for weed control in corn include seedbed preparation, establishing an optimum stand, adequate fertility, Herbicides and timely cultivations. Weeds that germinate before planting When selecting an appropriate herbicide or combination of can be destroyed with tillage operations or herbicides. Killing herbicide treatments, consider carefully the following factors: weeds just before planting gives the young crop seedlings a -Label approval for use competitive advantage and often improves performance of -Use of the crop preplanting or preemergence herbicides. -Corn tolerance to the herbicide Early cultivations are most effective for killing weeds and -Potential for chemical residues that may affect later crops for preventing crop yield reduction due to weed competition -Kinds of weeds or corn root damage.
    [Show full text]
  • AP-42, CH 9.2.2: Pesticide Application
    9.2.2PesticideApplication 9.2.2.1General1-2 Pesticidesaresubstancesormixturesusedtocontrolplantandanimallifeforthepurposesof increasingandimprovingagriculturalproduction,protectingpublichealthfrompest-bornediseaseand discomfort,reducingpropertydamagecausedbypests,andimprovingtheaestheticqualityofoutdoor orindoorsurroundings.Pesticidesareusedwidelyinagriculture,byhomeowners,byindustry,andby governmentagencies.Thelargestusageofchemicalswithpesticidalactivity,byweightof"active ingredient"(AI),isinagriculture.Agriculturalpesticidesareusedforcost-effectivecontrolofweeds, insects,mites,fungi,nematodes,andotherthreatstotheyield,quality,orsafetyoffood.Theannual U.S.usageofpesticideAIs(i.e.,insecticides,herbicides,andfungicides)isover800millionpounds. AiremissionsfrompesticideusearisebecauseofthevolatilenatureofmanyAIs,solvents, andotheradditivesusedinformulations,andofthedustynatureofsomeformulations.Mostmodern pesticidesareorganiccompounds.EmissionscanresultdirectlyduringapplicationorastheAIor solventvolatilizesovertimefromsoilandvegetation.Thisdiscussionwillfocusonemissionfactors forvolatilization.Thereareinsufficientdataavailableonparticulateemissionstopermitemission factordevelopment. 9.2.2.2ProcessDescription3-6 ApplicationMethods- Pesticideapplicationmethodsvaryaccordingtothetargetpestandtothecroporothervalue tobeprotected.Insomecases,thepesticideisapplieddirectlytothepest,andinotherstothehost plant.Instillothers,itisusedonthesoilorinanenclosedairspace.Pesticidemanufacturershave developedvariousformulationsofAIstomeetboththepestcontrolneedsandthepreferred
    [Show full text]
  • Chemic~L$,·!9R~:W,Eed Control in Corn GERALD R
    n:N J 600 AGRICUL TUJ:lAL EXTENSION SERVICE UNIVERSITY OF MINNESOTA \ \ .. _., .-·· .. -.~1~-.-~~rr-:1 AGRICULTURAL CHEMICALS \ -· _.;-,< ,. •-- . FACT SHEET No. 6-Revised 1979 Chemic~l$,·!9r~:w,eed Control in Corn GERALD R. MILLER \,_,.,, .... This fact sheet is intended only as a summary of suggested alter­ Herbicide -names and formulations native chemicals for weed control in corn. Label information Common Trade Concentration and should be read and followed exactly. For further information, name name commercial formulation 1 see Extension Bulletin 400, Cultural and Chemical Weed Control in Field Crops. Alachlor Lasso 4 lb/gal L Lasso II 15%G Selection of an effective chemical or combination of chemicals Atrazine Mtrex, 80% WP, 4 lb/gal L should be based on consideration of the following factors: others 90% WDG -Clearance status of the chemical Atrazine and propachlor Mtram 20%G -Use of the crop Bentazon Basagran 4 lb/gal L -Potential for soil residues that may affect following crops Butylate and protectant Sutan+ 6.7 lb/gal L -Kinds of weeds Cyanazine Bladex 80%WP, 15%G, 4 lb/gal L -Soil texture Dicamba Banvel 4 lb/gal L -pH of soil Dicamba and 2, 4-D Banvel-K 1.25 lb/gal dicamba -Amount of organic matter in the soil 2.50 lb/gal 2,4-D -Formulation of the chemical EPTC and protectant Eradicane 6.7 lb/gal L -Application equipment available Linuron Lorox 50%WP -Potential for drift problems Metolachlor Dual 6 or 8 lb/gal L Pendimethalin Prowl 4 lb/gal L Propachlor Sexton, 65% WP, 20% G, 4 lb/gal L Ramrod 2,4-D several various ·t G = Granular, L = Liquid, WP=Wettable Powder, WDG =Water Dispers­ Effectiveness of herbicides on weeds in corn 1 sible Granule Preplanting Preemergence C Postemergence -;;;..
    [Show full text]
  • List of Herbicide Groups
    List of herbicides Group Scientific name Trade name clodinafop (Topik®), cyhalofop (Barnstorm®), diclofop (Cheetah® Gold*, Decision®*, Hoegrass®), fenoxaprop (Cheetah® Gold* , Wildcat®), A Aryloxyphenoxypropionates fluazifop (Fusilade®, Fusion®*), haloxyfop (Verdict®), propaquizafop (Shogun®), quizalofop (Targa®) butroxydim (Falcon®, Fusion®*), clethodim (Select®), profoxydim A Cyclohexanediones (Aura®), sethoxydim (Cheetah® Gold*, Decision®*), tralkoxydim (Achieve®) A Phenylpyrazoles pinoxaden (Axial®) azimsulfuron (Gulliver®), bensulfuron (Londax®), chlorsulfuron (Glean®), ethoxysulfuron (Hero®), foramsulfuron (Tribute®), halosulfuron (Sempra®), iodosulfuron (Hussar®), mesosulfuron (Atlantis®), metsulfuron (Ally®, Harmony®* M, Stinger®*, Trounce®*, B Sulfonylureas Ultimate Brushweed®* Herbicide), prosulfuron (Casper®*), rimsulfuron (Titus®), sulfometuron (Oust®, Eucmix Pre Plant®*), sulfosulfuron (Monza®), thifensulfuron (Harmony®* M), triasulfuron, (Logran®, Logran® B Power®*), tribenuron (Express®), trifloxysulfuron (Envoke®, Krismat®*) florasulam (Paradigm®*, Vortex®*, X-Pand®*), flumetsulam B Triazolopyrimidines (Broadstrike®), metosulam (Eclipse®), pyroxsulam (Crusader®Rexade®*) imazamox (Intervix®*, Raptor®,), imazapic (Bobcat I-Maxx®*, Flame®, Midas®*, OnDuty®*), imazapyr (Arsenal Xpress®*, Intervix®*, B Imidazolinones Lightning®*, Midas®*, OnDuty®*), imazethapyr (Lightning®*, Spinnaker®) B Pyrimidinylthiobenzoates bispyribac (Nominee®), pyrithiobac (Staple®) C Amides: propanil (Stam®) C Benzothiadiazinones: bentazone (Basagran®,
    [Show full text]
  • Pesticides in Iowa's Water Resources: Historical Trends and New Issues
    PesticidesPesticides inin IowaIowa’’ss WaterWater Resources:Resources: HistoricalHistorical TrendsTrends andand NewNew IssuesIssues MaryMary P.P. SkopecSkopec andand KatieKatie ForemanForeman WatershedWatershed MonitoringMonitoring andand AssessmentAssessment IowaIowa DepartmentDepartment ofof NaturalNatural ResourcesResources OutlineOutline PesticidePesticide UseUse inin IowaIowa CurrentCurrent StatusStatus andand HistoricalHistorical TrendsTrends NewNew ApproachesApproaches forfor UnderstandingUnderstanding Occurrence of Pesticides in Water Resources Function of: 1. Use 2. Soil Characteristics 3. Rainfall Timing and Amount 4. Pesticide Properties Land Use in Iowa (2002) Percent of Iowa Acres Treated Herbicides Insecticides Yes No Source: Pesticide Movement: What Farmers Need to Know, Iowa State Extension, PAT-36 2000, Non-City Stream Sites 2001, Non-City Stream Sites 2002, Non-City Stream Sites 2,4-D* 2,4,5-T* Acetochlor Acifluoren* Alachlor Ametryn Atrazine Atrazine, Deethyl Atrazine, Deisopropyl Bentazon* Bromacil* Some Bromoxynil* Butylate Very Chloramben* Cyanazine Dalapon* Common; Herbicides Dicamba* Dichloprop* Others Dimethenamid EPTC Less so Metolachlor Metribuzin Pendimethalin* Picloram* Prometon Propachlor Propazine Simazine Triclopyr* Trifluralin Carbaryl* Carbofuran* Chlordane* Chlorpyrifos* es DDD* DDE* id DDT* Few ic Diazinon* ct Dieldrin* Detects Fonofos* Lindane (gamma-BHC)* Inse Malathion* Parathion* Phorate* 0 204060801000 204060801000 20406080100 Detection Rate, in Percent Detection Rate, in Percent Detection Rate,
    [Show full text]
  • 2019 Minnesota Chemicals of High Concern List
    Minnesota Department of Health, Chemicals of High Concern List, 2019 Persistent, Bioaccumulative, Toxic (PBT) or very Persistent, very High Production CAS Bioaccumulative Use Example(s) and/or Volume (HPV) Number Chemical Name Health Endpoint(s) (vPvB) Source(s) Chemical Class Chemical1 Maine (CA Prop 65; IARC; IRIS; NTP Wood and textiles finishes, Cancer, Respiratory 11th ROC); WA Appen1; WA CHCC; disinfection, tissue 50-00-0 Formaldehyde x system, Eye irritant Minnesota HRV; Minnesota RAA preservative Gastrointestinal Minnesota HRL Contaminant 50-00-0 Formaldehyde (in water) system EU Category 1 Endocrine disruptor pesticide 50-29-3 DDT, technical, p,p'DDT Endocrine system Maine (CA Prop 65; IARC; IRIS; NTP PAH (chem-class) 11th ROC; OSPAR Chemicals of Concern; EuC Endocrine Disruptor Cancer, Endocrine Priority List; EPA Final PBT Rule for 50-32-8 Benzo(a)pyrene x x system TRI; EPA Priority PBT); Oregon P3 List; WA Appen1; Minnesota HRV WA Appen1; Minnesota HRL Dyes and diaminophenol mfg, wood preservation, 51-28-5 2,4-Dinitrophenol Eyes pesticide, pharmaceutical Maine (CA Prop 65; IARC; NTP 11th Preparation of amino resins, 51-79-6 Urethane (Ethyl carbamate) Cancer, Development ROC); WA Appen1 solubilizer, chemical intermediate Maine (CA Prop 65; IARC; IRIS; NTP Research; PAH (chem-class) 11th ROC; EPA Final PBT Rule for 53-70-3 Dibenzo(a,h)anthracene Cancer x TRI; WA PBT List; OSPAR Chemicals of Concern); WA Appen1; Oregon P3 List Maine (CA Prop 65; NTP 11th ROC); Research 53-96-3 2-Acetylaminofluorene Cancer WA Appen1 Maine (CA Prop 65; IARC; IRIS; NTP Lubricant, antioxidant, 55-18-5 N-Nitrosodiethylamine Cancer 11th ROC); WA Appen1 plastics stabilizer Maine (CA Prop 65; IRIS; NTP 11th Pesticide (EPA reg.
    [Show full text]
  • Recommended Classification of Pesticides by Hazard and Guidelines to Classification 2019 Theinternational Programme on Chemical Safety (IPCS) Was Established in 1980
    The WHO Recommended Classi cation of Pesticides by Hazard and Guidelines to Classi cation 2019 cation Hazard of Pesticides by and Guidelines to Classi The WHO Recommended Classi The WHO Recommended Classi cation of Pesticides by Hazard and Guidelines to Classi cation 2019 The WHO Recommended Classification of Pesticides by Hazard and Guidelines to Classification 2019 TheInternational Programme on Chemical Safety (IPCS) was established in 1980. The overall objectives of the IPCS are to establish the scientific basis for assessment of the risk to human health and the environment from exposure to chemicals, through international peer review processes, as a prerequisite for the promotion of chemical safety, and to provide technical assistance in strengthening national capacities for the sound management of chemicals. This publication was developed in the IOMC context. The contents do not necessarily reflect the views or stated policies of individual IOMC Participating Organizations. The Inter-Organization Programme for the Sound Management of Chemicals (IOMC) was established in 1995 following recommendations made by the 1992 UN Conference on Environment and Development to strengthen cooperation and increase international coordination in the field of chemical safety. The Participating Organizations are: FAO, ILO, UNDP, UNEP, UNIDO, UNITAR, WHO, World Bank and OECD. The purpose of the IOMC is to promote coordination of the policies and activities pursued by the Participating Organizations, jointly or separately, to achieve the sound management of chemicals in relation to human health and the environment. WHO recommended classification of pesticides by hazard and guidelines to classification, 2019 edition ISBN 978-92-4-000566-2 (electronic version) ISBN 978-92-4-000567-9 (print version) ISSN 1684-1042 © World Health Organization 2020 Some rights reserved.
    [Show full text]