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2,4-Dichlorophenoxyacetic Acid
2,4-Dichlorophenoxyacetic acid 2,4-Dichlorophenoxyacetic acid IUPAC (2,4-dichlorophenoxy)acetic acid name 2,4-D Other hedonal names trinoxol Identifiers CAS [94-75-7] number SMILES OC(COC1=CC=C(Cl)C=C1Cl)=O ChemSpider 1441 ID Properties Molecular C H Cl O formula 8 6 2 3 Molar mass 221.04 g mol−1 Appearance white to yellow powder Melting point 140.5 °C (413.5 K) Boiling 160 °C (0.4 mm Hg) point Solubility in 900 mg/L (25 °C) water Related compounds Related 2,4,5-T, Dichlorprop compounds Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) 2,4-Dichlorophenoxyacetic acid (2,4-D) is a common systemic herbicide used in the control of broadleaf weeds. It is the most widely used herbicide in the world, and the third most commonly used in North America.[1] 2,4-D is also an important synthetic auxin, often used in laboratories for plant research and as a supplement in plant cell culture media such as MS medium. History 2,4-D was developed during World War II by a British team at Rothamsted Experimental Station, under the leadership of Judah Hirsch Quastel, aiming to increase crop yields for a nation at war.[citation needed] When it was commercially released in 1946, it became the first successful selective herbicide and allowed for greatly enhanced weed control in wheat, maize (corn), rice, and similar cereal grass crop, because it only kills dicots, leaving behind monocots. Mechanism of herbicide action 2,4-D is a synthetic auxin, which is a class of plant growth regulators. -
INDEX to PESTICIDE TYPES and FAMILIES and PART 180 TOLERANCE INFORMATION of PESTICIDE CHEMICALS in FOOD and FEED COMMODITIES
US Environmental Protection Agency Office of Pesticide Programs INDEX to PESTICIDE TYPES and FAMILIES and PART 180 TOLERANCE INFORMATION of PESTICIDE CHEMICALS in FOOD and FEED COMMODITIES Note: Pesticide tolerance information is updated in the Code of Federal Regulations on a weekly basis. EPA plans to update these indexes biannually. These indexes are current as of the date indicated in the pdf file. For the latest information on pesticide tolerances, please check the electronic Code of Federal Regulations (eCFR) at http://www.access.gpo.gov/nara/cfr/waisidx_07/40cfrv23_07.html 1 40 CFR Type Family Common name CAS Number PC code 180.163 Acaricide bridged diphenyl Dicofol (1,1-Bis(chlorophenyl)-2,2,2-trichloroethanol) 115-32-2 10501 180.198 Acaricide phosphonate Trichlorfon 52-68-6 57901 180.259 Acaricide sulfite ester Propargite 2312-35-8 97601 180.446 Acaricide tetrazine Clofentezine 74115-24-5 125501 180.448 Acaricide thiazolidine Hexythiazox 78587-05-0 128849 180.517 Acaricide phenylpyrazole Fipronil 120068-37-3 129121 180.566 Acaricide pyrazole Fenpyroximate 134098-61-6 129131 180.572 Acaricide carbazate Bifenazate 149877-41-8 586 180.593 Acaricide unclassified Etoxazole 153233-91-1 107091 180.599 Acaricide unclassified Acequinocyl 57960-19-7 6329 180.341 Acaricide, fungicide dinitrophenol Dinocap (2, 4-Dinitro-6-octylphenyl crotonate and 2,6-dinitro-4- 39300-45-3 36001 octylphenyl crotonate} 180.111 Acaricide, insecticide organophosphorus Malathion 121-75-5 57701 180.182 Acaricide, insecticide cyclodiene Endosulfan 115-29-7 79401 -
Environmental Health Criteria 39 PARAQUAT and DIQUAT
Environmental Health Criteria 39 PARAQUAT AND DIQUAT Please note that the layout and pagination of this web version are not identical with the printed version. Paraquat and diquat (EHC 39, 1984) INTERNATIONAL PROGRAMME ON CHEMICAL SAFETY ENVIRONMENTAL HEALTH CRITERIA 39 PARAQUAT AND DIQUAT This report contains the collective views of an international group of experts and does not necessarily represent the decisions or the stated policy of the United Nations Environment Programme, the International Labour Organisation, or the World Health Organization. Published under the joint sponsorship of the United Nations Environment Programme, the International Labour Organisation, and the World Health Organization World Health Orgnization Geneva, 1984 The International Programme on Chemical Safety (IPCS) is a joint venture of the United Nations Environment Programme, the International Labour Organisation, and the World Health Organization. The main objective of the IPCS is to carry out and disseminate evaluations of the effects of chemicals on human health and the quality of the environment. Supporting activities include the development of epidemiological, experimental laboratory, and risk-assessment methods that could produce internationally comparable results, and the development of manpower in the field of toxicology. Other activities carried out by the IPCS include the development of know-how for coping with chemical accidents, coordination of laboratory testing and epidemiological studies, and promotion of research on the mechanisms of the biological action of chemicals. ISBN 92 4 154099 4 The World Health Organization welcomes requests for permission to reproduce or translate its publications, in part or in full. Applications and enquiries should be addressed to the Office of Publications, World Health Organization, Geneva, Switzerland, which will be glad to provide the latest information on any changes made to the text, plans for new editions, and reprints and translations already available. -
Diquat Ecological Risk Assessment, Final Report
Utah State University DigitalCommons@USU All U.S. Government Documents (Utah Regional U.S. Government Documents (Utah Regional Depository) Depository) 11-2005 Diquat Ecological Risk Assessment, Final Report Bureau of Land Management Follow this and additional works at: https://digitalcommons.usu.edu/govdocs Part of the Life Sciences Commons, and the Physical Sciences and Mathematics Commons Recommended Citation Bureau of Land Management, "Diquat Ecological Risk Assessment, Final Report" (2005). All U.S. Government Documents (Utah Regional Depository). Paper 107. https://digitalcommons.usu.edu/govdocs/107 This Report is brought to you for free and open access by the U.S. Government Documents (Utah Regional Depository) at DigitalCommons@USU. It has been accepted for inclusion in All U.S. Government Documents (Utah Regional Depository) by an authorized administrator of DigitalCommons@USU. For more information, please contact [email protected]. Bureau of Land Management Reno, Nevada Diquat Ecological Risk Assessment Final Report November 2005 Bureau of Land Management Contract No. NAD010156 ENSR Document Number 09090-020-650 Executive Summary The United States Department of the Interior (USDI) Bureau of Land Management (BLM) is proposing a program to treat vegetation on up to six million acres of public lands annually in 17 western states in the continental United States (US) and Alaska. As part of this program, the BLM is proposing the use of ten herbicide active ingredients (a.i.) to control invasive plants and noxious weeds on approximately one million of the 6 million acres proposed for treatment. The BLM and its contractor, ENSR, are preparing a Vegetation Treatments Programmatic Environmental Impact Statement (EIS) to evaluate this and other proposed vegetation treatment methods and alternatives on lands managed by the BLM in the western continental US and Alaska. -
Weed Control Guide for Ohio, Indiana and Illinois
Pub# WS16 / Bulletin 789 / IL15 OHIO STATE UNIVERSITY EXTENSION Tables Table 1. Weed Response to “Burndown” Herbicides .............................................................................................19 Table 2. Application Intervals for Early Preplant Herbicides ............................................................................... 20 Table 3. Weed Response to Preplant/Preemergence Herbicides in Corn—Grasses ....................................30 WEED Table 4. Weed Response to Preplant/Preemergence Herbicides in Corn—Broadleaf Weeds ....................31 Table 5. Weed Response to Postemergence Herbicides in Corn—Grasses ...................................................32 Table 6. Weed Response to Postemergence Herbicides in Corn—Broadleaf Weeds ..................................33 2015 CONTROL Table 7. Grazing and Forage (Silage, Hay, etc.) Intervals for Herbicide-Treated Corn ................................. 66 OHIO, INDIANA Table 8. Rainfast Intervals, Spray Additives, and Maximum Crop Size for Postemergence Corn Herbicides .........................................................................................................................................................68 AND ILLINOIS Table 9. Herbicides Labeled for Use on Field Corn, Seed Corn, Popcorn, and Sweet Corn ..................... 69 GUIDE Table 10. Herbicide and Soil Insecticide Use Precautions ......................................................................................71 Table 11. Weed Response to Herbicides in Popcorn and Sweet Corn—Grasses -
List of Herbicide Groups
List of herbicides Group Scientific name Trade name clodinafop (Topik®), cyhalofop (Barnstorm®), diclofop (Cheetah® Gold*, Decision®*, Hoegrass®), fenoxaprop (Cheetah® Gold* , Wildcat®), A Aryloxyphenoxypropionates fluazifop (Fusilade®, Fusion®*), haloxyfop (Verdict®), propaquizafop (Shogun®), quizalofop (Targa®) butroxydim (Falcon®, Fusion®*), clethodim (Select®), profoxydim A Cyclohexanediones (Aura®), sethoxydim (Cheetah® Gold*, Decision®*), tralkoxydim (Achieve®) A Phenylpyrazoles pinoxaden (Axial®) azimsulfuron (Gulliver®), bensulfuron (Londax®), chlorsulfuron (Glean®), ethoxysulfuron (Hero®), foramsulfuron (Tribute®), halosulfuron (Sempra®), iodosulfuron (Hussar®), mesosulfuron (Atlantis®), metsulfuron (Ally®, Harmony®* M, Stinger®*, Trounce®*, B Sulfonylureas Ultimate Brushweed®* Herbicide), prosulfuron (Casper®*), rimsulfuron (Titus®), sulfometuron (Oust®, Eucmix Pre Plant®*), sulfosulfuron (Monza®), thifensulfuron (Harmony®* M), triasulfuron, (Logran®, Logran® B Power®*), tribenuron (Express®), trifloxysulfuron (Envoke®, Krismat®*) florasulam (Paradigm®*, Vortex®*, X-Pand®*), flumetsulam B Triazolopyrimidines (Broadstrike®), metosulam (Eclipse®), pyroxsulam (Crusader®Rexade®*) imazamox (Intervix®*, Raptor®,), imazapic (Bobcat I-Maxx®*, Flame®, Midas®*, OnDuty®*), imazapyr (Arsenal Xpress®*, Intervix®*, B Imidazolinones Lightning®*, Midas®*, OnDuty®*), imazethapyr (Lightning®*, Spinnaker®) B Pyrimidinylthiobenzoates bispyribac (Nominee®), pyrithiobac (Staple®) C Amides: propanil (Stam®) C Benzothiadiazinones: bentazone (Basagran®, -
Chemical Weed Control
2014 North Carolina Agricultural Chemicals Manual The 2014 North Carolina Agricultural Chemicals Manual is published by the North Carolina Cooperative Extension Service, College of Agriculture and Life Sciences, N.C. State University, Raleigh, N.C. These recommendations apply only to North Carolina. They may not be appropriate for conditions in other states and may not comply with laws and regulations outside North Carolina. These recommendations are current as of November 2013. Individuals who use agricultural chemicals are responsible for ensuring that the intended use complies with current regulations and conforms to the product label. Be sure to obtain current information about usage regulations and examine a current product label before applying any chemical. For assistance, contact your county Cooperative Extension agent. The use of brand names and any mention or listing of commercial products or services in this document does not imply endorsement by the North Carolina Cooperative Extension Service nor discrimination against similar products or services not mentioned. VII — CHEMICAL WEED CONTROL 2014 North Carolina Agricultural Chemicals Manual VII — CHEMICAL WEED CONTROL Chemical Weed Control in Field Corn ...................................................................................................... 224 Weed Response to Preemergence Herbicides — Corn ........................................................................... 231 Weed Response to Postemergence Herbicides — Corn ........................................................................ -
Factors Affecting Differential Sensitivity of Sweet Corn to HPPD-Inhibiting Herbicides Martin M
Weed Science 2010 58:289–294 Factors Affecting Differential Sensitivity of Sweet Corn to HPPD-Inhibiting Herbicides Martin M. Williams II and Jerald K. Pataky* Mutation of a cytochrome P450 (CYP) allele on the short arm of chromosome 5 affects sensitivity in sweet corn to mesotrione and to tembotrione plus isoxadifen applied POST. Hybrids that are homozygous for the functional allele (i.e., CYPCYP) are rarely injured at registered use rates, hybrids that are homozygous for mutant alleles (i.e., cypcyp) are frequently injured, and hybrids that are heterozygous for a functional and mutant allele (i.e., CYPcyp) have more variable responses over trials. The objectives of this work were (1) to conduct side-by-side comparisons of sweet corn hybrid responses to mesotrione, tembotrione plus isoxadifen, and topramezone under field conditions; and (2) to compare dose– response relationships among CYPCYP, CYPcyp, and cypcyp hybrids. Among 4-hydroxyphenylpyruvate dioxygenase (HPPD) inhibitors used POST in sweet corn, topramezone was safe on the 746 hybrids tested. When environmental conditions favored crop growth, mesotrione injured the largest number of hybrids, and these hybrids were almost exclusively cypcyp or CYPcyp. The safener isoxadifen added to the tembotrione product greatly reduced occurrence of injury to the CYPcyp genotypic class but not to the cypcyp hybrids. Despite a common genetic basis for herbicide metabolism, genotypic classes of sweet corn hybrids did not have identical field responses to mesotrione, tembotrione plus isoxadifen, and topramezone. Nomenclature: Isoxadifen, ethyl-5, 5-diphenyl-2-isoxazoline-3-3-carboxylate; mesotrione; tembotrione; topramezone; sweet corn, Zea mays L. Key words: Cross-sensitivity, cytochrome P450, dose–response, herbicide tolerance, nsf1 gene. -
North Dakota Herbicide Chart
This chart lists premix herbicides alphabetically by their trade names so you can identify the premix's component herbicides and their respective site of action groups. Refer to the Mode of Action chart on the left for more information. North Dakota ------------------------------- Component -------------------------------------------------------- Premix Site of Action Trade Name ® Trade Name ® Active Ingredient Group Affinity BroadSpec Harmony :1 thifensulfuron 2 Express :1 tribenuron 2 Herbicide Chart Repeated use of herbicides with the same site of action alone can Affinity TankMix Harmony :4 thifensulfuron 2 Express :1 tribenuron 2 result in the development of herbicide-resistant weed populations. Anthem * Zidua* pyroxasulfone 15 Cadet fluthiacet-ethyl 14 By Mode of Action (effect on plant growth) Audit Harmony :3 thifensulfuron 2 This chart groups herbicides by their modes of action to assist you in selecting 1) to maintain Express :1 tribenuron 2 greater diversity in herbicide use and 2) to rotate among herbicides with different sites of action to delay the development of herbcide resistance. Authority Assist Spartan sulfentrazone 14 Pursuit imazethapyr 2 The Site of Action Group is a classification system developed by the Weed Science Society of America. Authority First Spartan sulfentrazone 14 Number of resistant - or Sonic FirstRate cloransulam 2 weed species in U.S. Site of Authority MTZ Spartan sulfentrazone 14 Action Product Examples Metribuzin metribuzin 5 Group Site of Action Chemical Family Active Ingredient Trade Name ® -
Combinations of Penoxsulam and Diquat As Foliar Applications for Control of Waterhyacinth and Common Salvinia: Evidence of Herbicide Antagonism
J. Aquat. Plant Manage. 48: 21-25 Combinations of Penoxsulam and Diquat as Foliar Applications for Control of Waterhyacinth and Common Salvinia: Evidence of Herbicide Antagonism RYAN M. WERSAL1 AND J. D. MADSEN1,2 ABSTRACT INTRODUCTION Waterhyacinth (Eichhornia crassipes [Mart.] Solms) and Waterhyacinth (Eichhornia crassipes [Mart.] Solms) and common salvinia (Salvinia minima Baker) are two floating common salvinia (Salvinia minima Baker) are widespread aquatic plants that can cause wide-spread problems in the problems in waterways throughout the southern United southern United States. These species can cause reductions States. Waterhyacinth is an invasive free-floating aquatic in ecosystem function as well as the abundance of native plant from the tropical and subtropical regions of South plant species. Herbicides are often used in an attempt to America (Holm et al. 1991). Waterhyacinth effectively dou- control both species; however, few recommendations exist bles the number of plants within 12.5 d (Penfound and Ear- for common salvinia. Penoxsulam (2-(2,2-difluoroethoxy)-N- le 1948), increases dry biomass at a rate of 1.2% d-1, and (5,8 dimethoxy [1,2,4] triazolo [1,5-c] pyrimidin-2-yl)-6 (trif- peak biomass can reach a maximum of 2.5 kg m-2 under op- luoromethyl) benzenesulfonamide) is newly registered for timal conditions (Center and Spencer 1981). Waterhya- use in aquatic environments and is efficacious on floating cinth impedes the recreational use of rivers and lakes plants as a submersed application; however, foliar applica- (fishing, swimming, and boat traffic) and the generation of tion rates are largely undefined. The objectives of these stud- hydroelectric power. -
Diquat Dibromide: Reregistration Eligibility Decision (RED)
United States Prevention, Pesticides EPA 738-R-95-016 Environmental Protection And Toxic Substances July 1995 Agency (7508W) Reregistration Eligibility Decision (RED) Diquat Dibromide UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, D.C. 20460 OFFICE OF PREVENTION, PESTICIDES AND TOXIC SUBSTANCES CERTIFIED MAIL Dear Registrant: I am pleased to announce that the Environmental Protection Agency has completed its reregistration eligibility review and decisions on the pesticide chemical case diquat dibromide which icludes the active ingredient 6, 7-dihydrodipyrido(1,2-a:2',1,-c)pyrazinediium dibromide. The enclosed Reregistration Eligibility Decision (RED) contains the Agency's evaluation of the data base of these chemicals, its conclusions of the potential human health and environmental risks of the current product uses, and its decisions and conditions under which these uses and products will be eligible for reregistration. The RED includes the data and labeling requirements for products for reregistration. It may also include requirements for additional data (generic) on the active ingredients to confirm the risk assessments. To assist you with a proper response, read the enclosed document entitled "Summary of Instructions for Responding to the RED". This summary also refers to other enclosed documents which include further instructions. You must follow all instructions and submit complete and timely responses. The first set of required responses are due 90 days from the date of this letter. The second set of required responses are due 8 months from the date of this letter. Complete and timely responses will avoid the Agency taking the enforcement action of suspension against your products. If you have questions on the product specific data requirements or wish to meet with the Agency, please contact the Special Review and Reregistration Division representative Franklin Rubis at (703) 308-8184. -
A Corn and Soybean Herbicide Chart
By Premix This chart lists premix herbicides alphabetically by their trade names Corn and Soybean so you can identify the premix’s component herbicides and their respective site of action groups. Refer to the Mode of Action chart on the left for more information. Herbicide Chart Component Premix Site of Action Trade Name ® Trade Name ® Active Ingredient Group Repeated use of herbicides with the same Anthem Zidua pyroxasulfone 15 Cadet fluthiacet-ethyl 14 site of action can result in the development of Autority Assist Spartan sulfentrazone 14 Pursuit imazethapyr 2 herbicide-resistant weed populations. Authority First Spartan sulfentrazone 14 FirstRate cloransulam 2 Autority MTZ Spartan sulfentrazone 14 Sencor metribuzin 5 By Mode of Action (effect on plant growth) Authority XL Spartan sulfentrazone 14 Classic chlorimuron 2 This chart groups herbicides by their modes of action to assist you in Autumn Super Autumn iodosulfuron 2 selecting herbicides 1) to maintain greater diversity in herbicide use and ------- thiencarbazone 2 Basis Blend Resolve rimsulfuron 2 2) to rotate among herbicides with different sites of action to delay the Harmony thifensulfuron 2 development of herbicide resistance. Bicep II Magnum Dual II Magnum s-metolachlor 15 (Bicep Lite II Mag) AAtrex atrazine 5 The Site of Action Group is a classification system developed by the Weed Science Society of America. Boundary Dual Magnum s-metolachlor 15 Sencor metribuzin 5 Breakfree ATZ Breakfree acetochlor 15 (Breakfree ATZ Lite) AAtrex atrazine 5 Number of resistant Bullet