Using Countless Tons of Arsenic As a Non-Selective Contact and Soil Sterilant
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2,4-Dichlorophenoxyacetic Acid
2,4-Dichlorophenoxyacetic acid 2,4-Dichlorophenoxyacetic acid IUPAC (2,4-dichlorophenoxy)acetic acid name 2,4-D Other hedonal names trinoxol Identifiers CAS [94-75-7] number SMILES OC(COC1=CC=C(Cl)C=C1Cl)=O ChemSpider 1441 ID Properties Molecular C H Cl O formula 8 6 2 3 Molar mass 221.04 g mol−1 Appearance white to yellow powder Melting point 140.5 °C (413.5 K) Boiling 160 °C (0.4 mm Hg) point Solubility in 900 mg/L (25 °C) water Related compounds Related 2,4,5-T, Dichlorprop compounds Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) 2,4-Dichlorophenoxyacetic acid (2,4-D) is a common systemic herbicide used in the control of broadleaf weeds. It is the most widely used herbicide in the world, and the third most commonly used in North America.[1] 2,4-D is also an important synthetic auxin, often used in laboratories for plant research and as a supplement in plant cell culture media such as MS medium. History 2,4-D was developed during World War II by a British team at Rothamsted Experimental Station, under the leadership of Judah Hirsch Quastel, aiming to increase crop yields for a nation at war.[citation needed] When it was commercially released in 1946, it became the first successful selective herbicide and allowed for greatly enhanced weed control in wheat, maize (corn), rice, and similar cereal grass crop, because it only kills dicots, leaving behind monocots. Mechanism of herbicide action 2,4-D is a synthetic auxin, which is a class of plant growth regulators. -
U.S. EPA, Pesticide Product Label, DICAMBAZINE, 09/25/2003
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON. D.C. 20460 OFFICE OF PREVENTION, PESTICIDES AND TOXIC SUBSTANCES SEP 2 5 2003 Albaugh, Inc. clo Pyxis Regulatory Consulting, Inc. ATTN: Michael Kellogg 11324 1']'1' Ave. Ct. NW Gig Harbor, W A 98332 Dear Mr. Kellogg: Subject: Fast Track Amendment for Atrazine Product Product: Dicambaiine EPA Registration Number: 42750-41 Submission Date: 04/24/03 The labeling referred to above, submitted in connection with registration under the Federal Insecticide, Fungicide and Rodenticide Act, as amended is acceptable, provided you make the followmg changes before you release the product for shipment. 1. Change the PPE section to the following: • "Some materials that are chemical-resistant to this product are barrier laminate> 14 mils, neoprene rubber> 14 mils, polyvinyl chloride (PVC) > 14 mils, butyl rubber> 14 mils, orviton >14 mils. Ifyou want more options, follow the instructions for category A on an EPA chemical-resistance category selection chart. " • "Mixers, loaders, applicators and other handlers not using Engineering Controls must wear: Coveralls over long sleeved ~hirt and long pants Chemical resistant gloves Chemical resistant footwear plus socks Chemical resistant headgear (if overhead exposure) A NlOSH approved dust mist filtering respirator with any N, R, P or HE filter A chemical resistant apron (if exposed to undiluted product)" • "Mixers, loaders, applicators and other handlers using Engineering Controls must wear: Long-sleeved shirt and long pants Chemical resistant gloves and apron for mixers and loaders Shoes plus socks See Engineering Controls for additional requirements" Note to registrant: You must drop the N type filter from the respirator statement if the product contains or is used with oil. -
Exposure to Herbicides in House Dust and Risk of Childhood Acute Lymphoblastic Leukemia
Journal of Exposure Science and Environmental Epidemiology (2013) 23, 363–370 & 2013 Nature America, Inc. All rights reserved 1559-0631/13 www.nature.com/jes ORIGINAL ARTICLE Exposure to herbicides in house dust and risk of childhood acute lymphoblastic leukemia Catherine Metayer1, Joanne S. Colt2, Patricia A. Buffler1, Helen D. Reed3, Steve Selvin1, Vonda Crouse4 and Mary H. Ward2 We examine the association between exposure to herbicides and childhood acute lymphoblastic leukemia (ALL). Dust samples were collected from homes of 269 ALL cases and 333 healthy controls (o8 years of age at diagnosis/reference date and residing in same home since diagnosis/reference date) in California, using a high-volume surface sampler or household vacuum bags. Amounts of agricultural or professional herbicides (alachlor, metolachlor, bromoxynil, bromoxynil octanoate, pebulate, butylate, prometryn, simazine, ethalfluralin, and pendimethalin) and residential herbicides (cyanazine, trifluralin, 2-methyl-4- chlorophenoxyacetic acid (MCPA), mecoprop, 2,4-dichlorophenoxyacetic acid (2,4-D), chlorthal, and dicamba) were measured. Odds ratios (OR) and 95% confidence intervals (CI) were estimated by logistic regression. Models included the herbicide of interest, age, sex, race/ethnicity, household income, year and season of dust sampling, neighborhood type, and residence type. The risk of childhood ALL was associated with dust levels of chlorthal; compared to homes with no detections, ORs for the first, second, and third tertiles were 1.49 (95% CI: 0.82–2.72), 1.49 (95% CI: 0.83–2.67), and 1.57 (95% CI: 0.90–2.73), respectively (P-value for linear trend ¼ 0.05). The magnitude of this association appeared to be higher in the presence of alachlor. -
INDEX to PESTICIDE TYPES and FAMILIES and PART 180 TOLERANCE INFORMATION of PESTICIDE CHEMICALS in FOOD and FEED COMMODITIES
US Environmental Protection Agency Office of Pesticide Programs INDEX to PESTICIDE TYPES and FAMILIES and PART 180 TOLERANCE INFORMATION of PESTICIDE CHEMICALS in FOOD and FEED COMMODITIES Note: Pesticide tolerance information is updated in the Code of Federal Regulations on a weekly basis. EPA plans to update these indexes biannually. These indexes are current as of the date indicated in the pdf file. For the latest information on pesticide tolerances, please check the electronic Code of Federal Regulations (eCFR) at http://www.access.gpo.gov/nara/cfr/waisidx_07/40cfrv23_07.html 1 40 CFR Type Family Common name CAS Number PC code 180.163 Acaricide bridged diphenyl Dicofol (1,1-Bis(chlorophenyl)-2,2,2-trichloroethanol) 115-32-2 10501 180.198 Acaricide phosphonate Trichlorfon 52-68-6 57901 180.259 Acaricide sulfite ester Propargite 2312-35-8 97601 180.446 Acaricide tetrazine Clofentezine 74115-24-5 125501 180.448 Acaricide thiazolidine Hexythiazox 78587-05-0 128849 180.517 Acaricide phenylpyrazole Fipronil 120068-37-3 129121 180.566 Acaricide pyrazole Fenpyroximate 134098-61-6 129131 180.572 Acaricide carbazate Bifenazate 149877-41-8 586 180.593 Acaricide unclassified Etoxazole 153233-91-1 107091 180.599 Acaricide unclassified Acequinocyl 57960-19-7 6329 180.341 Acaricide, fungicide dinitrophenol Dinocap (2, 4-Dinitro-6-octylphenyl crotonate and 2,6-dinitro-4- 39300-45-3 36001 octylphenyl crotonate} 180.111 Acaricide, insecticide organophosphorus Malathion 121-75-5 57701 180.182 Acaricide, insecticide cyclodiene Endosulfan 115-29-7 79401 -
Delayed Fluorescence Imaging of Photosynthesis Inhibitor and Heavy Metal Induced Stress in Potato
Cent. Eur. J. Biol. • 7(3) • 2012 • 531-541 DOI: 10.2478/s11535-012-0038-z Central European Journal of Biology Delayed fluorescence imaging of photosynthesis inhibitor and heavy metal induced stress in potato Research Article Jaka Razinger1,*, Luka Drinovec2, Maja Berden-Zrimec3 1Agricultural Institute of Slovenia, 1000 Ljubljana, Slovenia 2Aerosol d.o.o., 1000 Ljubljana, Slovenia 3Institute of Physical Biology, 1000 Ljubljana, Slovenia Received 09 November 2011; Accepted 13 March 2012 Abstract: Early chemical-induced stress in Solanum tuberosum leaves was visualized using delayed fluorescence (DF) imaging. The ability to detect spatially heterogeneous responses of plant leaves exposed to several toxicants using delayed fluorescence was compared to prompt fluorescence (PF) imaging and the standard maximum fluorescence yield of PSII measurements (Fv/Fm). The toxicants used in the study were two photosynthesis inhibitors (herbicides), 100 μM methyl viologen (MV) and 140 μM diuron (DCMU), and two heavy metals, 100 μM cadmium and 100 μM copper. The exposure times were 5 and 72 h. Significant photosynthesis-inhibitor effects were already visualized after 5 h. In addition, a significant reduction in the DF/PF index was measured in DCMU- and MV-treated leaves after 5 h. In contrast, only DCMU-treated leaves exhibited a significant decrease in Fv/Fm after 5 h. All treatments resulted in a significant decrease in the DF/PF parameter after 72 h of exposure, when only MV and Cd treatment resulted in visible symptoms. Our study highlights the power of delayed fluorescence imaging. Abundant quantifiable spatial information was obtained with the instrumental setup. Delayed fluorescence imaging has been confirmed as a very responsive and useful technique for detecting stress induced by photosynthesis inhibitors or heavy metals. -
Sorption of Atrazine, Alachlor and Trifluralin from Water Onto Different Geosorbents
RSC Advances Sorption of atrazine, alachlor and trifluralin from water onto different geosorbents Journal: RSC Advances Manuscript ID: RA-ART-04-2014-003886.R1 Article Type: Paper Date Submitted by the Author: 04-Dec-2014 Complete List of Authors: Leovac, Anita; University of Novi Sad Faculty of Sciences, Department for Chemistry, Biochemistry and Environmental Protection Vasyukova, Ekaterina; Technische Universität Dresden, Faculty of Environmental Sciences, Institute of Urban Water Management Ivančev-Tumbas, Ivana; University of Novi Sad Faculty of Sciences, Department for Chemistry, Biochemistry and Environmental Protection Uhl, Wolfgang; Technische Universität Dresden, Faculty of Environmental Sciences, Institute of Urban Water Management Kragulj, Marijana; University of Novi Sad Faculty of Sciences, Department for Chemistry, Biochemistry and Environmental Protection Trickovic, Jelena; University of Novi Sad Faculty of Sciences, Department for Chemistry, Biochemistry and Environmental Protection Kerkez, Đurña; University of Novi Sad Faculty of Sciences, Department for Chemistry, Biochemistry and Environmental Protection Dalmacija, Bozo; University of Novi Sad Faculty of Sciences, Department for Chemistry, Biochemistry and Environmental Protection Page 1 of 21 RSC Advances 1 Sorption of atrazine, alachlor and trifluralin from water onto different geosorbents 2 Anita S. Leovac 1, Ekaterina Vasyukova 2, Ivana I. Ivan čev-Tumbas 1, Wolfgang Uhl 2, 3 Marijana M. Kragulj 1, Jelena S. Tri čkovi ć1, Đur đa V. Kerkez 1, Božo D. Dalmacija 1 -
Trifluralin Human Health and Ecological Risk Assessment FINAL REPORT
SERA TR-052-26-03a Trifluralin Human Health and Ecological Risk Assessment FINAL REPORT Submitted to: Paul Mistretta, COR USDA/Forest Service, Southern Region 1720 Peachtree RD, NW Atlanta, Georgia 30309 USDA Forest Service Contract: AG-3187-C-06-0010 USDA Forest Order Number: AG-43ZP-D-10-0010 SERA Internal Task No. 52-26 Submitted by: Patrick R. Durkin Syracuse Environmental Research Associates, Inc. 8125 Solomon Seal Manlius, New York 13104 E-Mail: [email protected] Home Page: www.sera-inc.com September 20, 2011 Table of Contents LIST OF FIGURES ...................................................................................................................... vii LIST OF TABLES ........................................................................................................................ vii LIST OF APPENDICES .............................................................................................................. viii LIST OF ATTACHEMENTS ...................................................................................................... viii ACRONYMS, ABBREVIATIONS, AND SYMBOLS ................................................................ ix COMMON UNIT CONVERSIONS AND ABBREVIATIONS .................................................. xii CONVERSION OF SCIENTIFIC NOTATION ......................................................................... xiii EXECUTIVE SUMMARY ......................................................................................................... xiv 1. INTRODUCTION ..................................................................................................................... -
Environmental Health Criteria 39 PARAQUAT and DIQUAT
Environmental Health Criteria 39 PARAQUAT AND DIQUAT Please note that the layout and pagination of this web version are not identical with the printed version. Paraquat and diquat (EHC 39, 1984) INTERNATIONAL PROGRAMME ON CHEMICAL SAFETY ENVIRONMENTAL HEALTH CRITERIA 39 PARAQUAT AND DIQUAT This report contains the collective views of an international group of experts and does not necessarily represent the decisions or the stated policy of the United Nations Environment Programme, the International Labour Organisation, or the World Health Organization. Published under the joint sponsorship of the United Nations Environment Programme, the International Labour Organisation, and the World Health Organization World Health Orgnization Geneva, 1984 The International Programme on Chemical Safety (IPCS) is a joint venture of the United Nations Environment Programme, the International Labour Organisation, and the World Health Organization. The main objective of the IPCS is to carry out and disseminate evaluations of the effects of chemicals on human health and the quality of the environment. Supporting activities include the development of epidemiological, experimental laboratory, and risk-assessment methods that could produce internationally comparable results, and the development of manpower in the field of toxicology. Other activities carried out by the IPCS include the development of know-how for coping with chemical accidents, coordination of laboratory testing and epidemiological studies, and promotion of research on the mechanisms of the biological action of chemicals. ISBN 92 4 154099 4 The World Health Organization welcomes requests for permission to reproduce or translate its publications, in part or in full. Applications and enquiries should be addressed to the Office of Publications, World Health Organization, Geneva, Switzerland, which will be glad to provide the latest information on any changes made to the text, plans for new editions, and reprints and translations already available. -
Diquat Ecological Risk Assessment, Final Report
Utah State University DigitalCommons@USU All U.S. Government Documents (Utah Regional U.S. Government Documents (Utah Regional Depository) Depository) 11-2005 Diquat Ecological Risk Assessment, Final Report Bureau of Land Management Follow this and additional works at: https://digitalcommons.usu.edu/govdocs Part of the Life Sciences Commons, and the Physical Sciences and Mathematics Commons Recommended Citation Bureau of Land Management, "Diquat Ecological Risk Assessment, Final Report" (2005). All U.S. Government Documents (Utah Regional Depository). Paper 107. https://digitalcommons.usu.edu/govdocs/107 This Report is brought to you for free and open access by the U.S. Government Documents (Utah Regional Depository) at DigitalCommons@USU. It has been accepted for inclusion in All U.S. Government Documents (Utah Regional Depository) by an authorized administrator of DigitalCommons@USU. For more information, please contact [email protected]. Bureau of Land Management Reno, Nevada Diquat Ecological Risk Assessment Final Report November 2005 Bureau of Land Management Contract No. NAD010156 ENSR Document Number 09090-020-650 Executive Summary The United States Department of the Interior (USDI) Bureau of Land Management (BLM) is proposing a program to treat vegetation on up to six million acres of public lands annually in 17 western states in the continental United States (US) and Alaska. As part of this program, the BLM is proposing the use of ten herbicide active ingredients (a.i.) to control invasive plants and noxious weeds on approximately one million of the 6 million acres proposed for treatment. The BLM and its contractor, ENSR, are preparing a Vegetation Treatments Programmatic Environmental Impact Statement (EIS) to evaluate this and other proposed vegetation treatment methods and alternatives on lands managed by the BLM in the western continental US and Alaska. -
List of Herbicide Groups
List of herbicides Group Scientific name Trade name clodinafop (Topik®), cyhalofop (Barnstorm®), diclofop (Cheetah® Gold*, Decision®*, Hoegrass®), fenoxaprop (Cheetah® Gold* , Wildcat®), A Aryloxyphenoxypropionates fluazifop (Fusilade®, Fusion®*), haloxyfop (Verdict®), propaquizafop (Shogun®), quizalofop (Targa®) butroxydim (Falcon®, Fusion®*), clethodim (Select®), profoxydim A Cyclohexanediones (Aura®), sethoxydim (Cheetah® Gold*, Decision®*), tralkoxydim (Achieve®) A Phenylpyrazoles pinoxaden (Axial®) azimsulfuron (Gulliver®), bensulfuron (Londax®), chlorsulfuron (Glean®), ethoxysulfuron (Hero®), foramsulfuron (Tribute®), halosulfuron (Sempra®), iodosulfuron (Hussar®), mesosulfuron (Atlantis®), metsulfuron (Ally®, Harmony®* M, Stinger®*, Trounce®*, B Sulfonylureas Ultimate Brushweed®* Herbicide), prosulfuron (Casper®*), rimsulfuron (Titus®), sulfometuron (Oust®, Eucmix Pre Plant®*), sulfosulfuron (Monza®), thifensulfuron (Harmony®* M), triasulfuron, (Logran®, Logran® B Power®*), tribenuron (Express®), trifloxysulfuron (Envoke®, Krismat®*) florasulam (Paradigm®*, Vortex®*, X-Pand®*), flumetsulam B Triazolopyrimidines (Broadstrike®), metosulam (Eclipse®), pyroxsulam (Crusader®Rexade®*) imazamox (Intervix®*, Raptor®,), imazapic (Bobcat I-Maxx®*, Flame®, Midas®*, OnDuty®*), imazapyr (Arsenal Xpress®*, Intervix®*, B Imidazolinones Lightning®*, Midas®*, OnDuty®*), imazethapyr (Lightning®*, Spinnaker®) B Pyrimidinylthiobenzoates bispyribac (Nominee®), pyrithiobac (Staple®) C Amides: propanil (Stam®) C Benzothiadiazinones: bentazone (Basagran®, -
Classification of Herbicides
Title of the course : Weed Management Credit: 3(2+1) Class : 3rd Year IInd Semester Title of the topic : Principles of weed management College : Krishi vigyan Kendra,College of Agriculture, Rewa, JNKVV, Jabalpur Name of Teacher : Dr. (Mrs.) Smita Singh Classification of Herbicides Herbicides: Chemical method of weed control is very effective in certain cases and have great scope provided the herbicides are cheap, efficient and easily available. The chemicals used for killing the weeds or inhibiting growth of weeds are called herbicides (Weedicides). Classification of Herbicides: Herbicides are classified in different ways: A) First Group Chemical Herbicides: I) Classification of herbicides according to chemical composition. II) Classification of herbicides according to their use. III) Classification of herbicides based on time of application. IV) Classification of herbicides according to Formulation. V) Classification of herbicides according to residual effect. B) Second Group – Bio herbicides C) Third Group herbicidal mixtures. Classification of herbicide I) Classification of Herbicide Based on Chemical Nature or Composition Compounds having chemical affinities are grouped together. This is useful in liting and characterising herbicides. i) Inorganic Herbicides:Contain no carbon actions in their molecules. These were the first chemicals used for weed control before the introduction of the organic compounds, example are: a) Acids:Arsenic acid, arsenious acid, arsenic trioxide sulphuric acid. b) Salts:Borax, copper sulphate, ammonium sulphate, Na chlorate , Na arsenite , copper nitrate. ii) Organic Herbicides:Oils and non oils contain carbon and hydrogen in their molecules. a) Oils: Diesel oil, standard solvent, xylene-type, aromatic oils, polycyclic , aromatic oils etc. b) Aliphatics:Dalapon, TCA, Acrolein, Glyphosphate methyl bromide. -
Chemical Weed Control
2014 North Carolina Agricultural Chemicals Manual The 2014 North Carolina Agricultural Chemicals Manual is published by the North Carolina Cooperative Extension Service, College of Agriculture and Life Sciences, N.C. State University, Raleigh, N.C. These recommendations apply only to North Carolina. They may not be appropriate for conditions in other states and may not comply with laws and regulations outside North Carolina. These recommendations are current as of November 2013. Individuals who use agricultural chemicals are responsible for ensuring that the intended use complies with current regulations and conforms to the product label. Be sure to obtain current information about usage regulations and examine a current product label before applying any chemical. For assistance, contact your county Cooperative Extension agent. The use of brand names and any mention or listing of commercial products or services in this document does not imply endorsement by the North Carolina Cooperative Extension Service nor discrimination against similar products or services not mentioned. VII — CHEMICAL WEED CONTROL 2014 North Carolina Agricultural Chemicals Manual VII — CHEMICAL WEED CONTROL Chemical Weed Control in Field Corn ...................................................................................................... 224 Weed Response to Preemergence Herbicides — Corn ........................................................................... 231 Weed Response to Postemergence Herbicides — Corn ........................................................................