The Summer Assignment Will Receive a GRADE on the First Day of Class – August 9
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MDA Scientific SPM
MDA Scientific SPM Fast response monitor for the detection of a target gas SPM Advantages • Fast response monitor specific to target gas only • Gas sensitivity to ppb levels with physical evidence • Minimum maintenance and no dynamic calibration • Customized for harsh industrial environments • More than 50 gas calibrations available Applications • Outdoor locations • Corrosive areas • Remote sampling areas • Gas storage areas • Survey work • Perimeter/fencelines • Ventilation and exhaust systems Options • Z-purge system • Duty cycle • ChemKey™ • RS422 • Remote reset • Portable • Extended sample • Heater option (operate from -20°C to ±40°C) Technical Specification Specifications Detection Technique Chemcassette® Detection System Alarm Point Dual level alarms typically set at 1/2 TLV and TLV Response Time As fast as 10 seconds Alarm Indication Local audio/visual alarms; remote capability optional Signal Outputs SPDT concentration alarm relays; SPDT fault relay; 4-20 mA; digital display Relay Rating 120VAC@10amps; 240VAC@5amps; 48VDC@5amps Operating Temperature Range 32° to 104°F; 0° to 40°C (basic unit); heating/cooling optional Power Requirements 115/230 VAC 50/60 Hz, battery operation optional Enclosure NEMA 4X fiberglass (basic unit) Dimensions 12"(H) x 12"(W) x 7”(D) (30.5 x 30.5 x 17.8 cm) (basic unit) Weight Up to 25 pounds, depending on option installed Note: options may vary the specifications Detectable Gases Range Amines Ammonia (NH3) 2.6-75.0 ppm Ammonia (NH3)-II 2.6-75.0 ppm Dimethylamine (DMA) 0.1-6 ppm n-Butylamine (n-BA) 0.4-12 -
Vibrationally Excited Hydrogen Halides : a Bibliography On
VI NBS SPECIAL PUBLICATION 392 J U.S. DEPARTMENT OF COMMERCE / National Bureau of Standards National Bureau of Standards Bldg. Library, _ E-01 Admin. OCT 1 1981 191023 / oO Vibrationally Excited Hydrogen Halides: A Bibliography on Chemical Kinetics of Chemiexcitation and Energy Transfer Processes (1958 through 1973) QC 100 • 1X57 no. 2te c l !14 c '- — | NATIONAL BUREAU OF STANDARDS The National Bureau of Standards' was established by an act of Congress March 3, 1901. The Bureau's overall goal is to strengthen and advance the Nation's science and technology and facilitate their effective application for public benefit. To this end, the Bureau conducts research and provides: (1) a basis for the Nation's physical measurement system, (2) scientific and technological services for industry and government, (3) a technical basis for equity in trade, and (4) technical services to promote public safety. The Bureau consists of the Institute for Basic Standards, the Institute for Materials Research, the Institute for Applied Technology, the Institute for Computer Sciences and Technology, and the Office for Information Programs. THE INSTITUTE FOR BASIC STANDARDS provides the central basis within the United States of a complete and consistent system of physical measurement; coordinates that system with measurement systems of other nations; and furnishes essential services leading to accurate and uniform physical measurements throughout the Nation's scientific community, industry, and commerce. The Institute consists of a Center for Radiation Research, an Office of Meas- urement Services and the following divisions: Applied Mathematics — Electricity — Mechanics — Heat — Optical Physics — Nuclear Sciences" — Applied Radiation 2 — Quantum Electronics 1 — Electromagnetics 3 — Time 3 1 1 and Frequency — Laboratory Astrophysics — Cryogenics . -
Cyanide Poisoning and How to Treat It Using CYANOKIT (Hydroxocobalamin for Injection) 5G
Cyanide Poisoning and How to Treat It Using CYANOKIT (hydroxocobalamin for injection) 5g 1. CYANOKIT (single 5-g vial) [package insert]. Columbia, MD: Meridian Medical Technologies, Inc.; 2011. Please see Important Safety Information on slides 3-4 and full Prescribing Information for CYANOKIT starting on slide 33. CYANOKIT is a registered trademark of SERB Sarl, licensed by Meridian Medical Technologies, Inc., a Pfizer company. Copyright © 2015 Meridian Medical Technologies, Inc., a Pfizer company. All rights reserved. CYK783109-01 November/2015. Indication and Important Safety Information……………………………………………………………………………….………..…..3 . Identifying Cyanide Poisoning……………………………………………………………………………………………………………….…………….….5 . How CYANOKIT (hydroxocobalamin for injection) Works……………………………………………………………….12 . The Specifics of CYANOKIT…………………………………………………………………………………………………………………………….………17 . Administering CYANOKIT………………………………………………………………………………………………………………………………..……….21 . Storage and Disposal of CYANOKIT…................................................................................................................................26 . Grant Information for CYANOKIT……………………………………………………………………………………………………………………....30 . Full Prescribing Information………………………………………………………………………………………………….………………………………33 Please see Important Safety Information on slides 3-4 and full Prescribing Information for CYANOKIT starting on slide 33. CYANOKIT (hydroxocobalamin for injection) 5 g for intravenous infusion is indicated for the treatment of known or suspected cyanide poisoning. -
2-‐Bromobutane
Practice Questions 1. What is true about the reaction between (R)-2-bromobutane and potassium cyanide as shown below? Br KCN a) The product is a racemic mixture. b) The product is (S)-2-cyanobutane. c) The mechanism proceeds through a stable intermediate. d) The mechanism proceeds through a single transition state step. e) Answers a and c. f) Answers b and d. 2. The following reaction goes through an SN2 mechanism. - - CH3CH2CH2Br + OH à CH3CH2CH2OH + Br At constant temperature, what is the effect on the rate of the reaction by simultaneously doubling the concentration of propyl bromide and OH- ion? a) It would increase the rate by six. b) It would double the rate. c) It would triple the rate. d) It would increase the rate by four. e) It would have no effect on the rate. 3. Which is the minor substitution product in the following reaction? a) I b) II c) III d) Equal amounts of I and II e) None of these products 4. What is the major product of the following reaction? a) I b) II c) III d) IV e) Equal amount of I and III 5. Consider the reaction between 2-bromo-2,4-dimethylpentane and sodium iodide, NaI, in acetone. Br NaI I acetone At constant temperature, what is the effect on the reaction rate if one simultaneously double the concentration of 2-bromo-2,4-dimethylpentane and sodium iodide? a) It would double the reaction rate. b) It would triple the reaction rate. c) It would quadruple the reaction rate. d) It would increase the reaction rate by 5. -
Sodium Iodide Spotlight 352 Compiled by Vinícius Rangel Campos Vinícius Rangel Campos Was Born in Niterói/RJ, Brazil in 1986
1186 SPOTLIGHT SYNLETT Sodium Iodide Spotlight 352 Compiled by Vinícius Rangel Campos Vinícius Rangel Campos was born in Niterói/RJ, Brazil in 1986. He This feature focuses on a re- received his Chemistry degree from the Universidade Federal Fluminense (UFF), Niterói/RJ, Brazil in 2009. He is currently in the agent chosen by a postgradu- final stages of his MSc. studies under the supervision of Professors ate, highlighting the uses and Anna Claudia Cunha and Vitor Francisco Ferreira in Organic preparation of the reagent in Chemistry at the Universidade Federal Fluminense. His research in- current research terest is focused on the design and synthesis of new bioactive com- pounds, such as quinone and 1,2,3-triazole derivatives. Instituto de Química, Universidade Federal Fluminense, UFF, CEP: 24020-141 Niterói, Rio de Janeiro, Brazil E-mail: [email protected] Introduction NaI R–I NaX + R–X acetone Sodium iodide (NaI) occurs as colorless, odorless or as a X = Cl or Br white crystalline solid; it is slightly hygroscopic, and a commercially available reagent. It is soluble in water, Scheme 1 alcohols, acetone, and other organic solvents and stable This reaction has been expanded to include the conversion under normal temperature and pressure (mp: 651 °C, of alcohols into alkyl halides by first converting the alco- d = 3.67 g/cm3).1 On a laboratory scale, sodium iodide hol into a sulfonate ester (tosylates or mesylates are usu- may be prepared by neutralizing a solution of sodium hy- ally used), and then performing the substitution.6 Other droxide or sodium carbonate with hydriodic acid.2 Sodi- applications using sodium iodide as reagent in organic um iodide is a very useful and versatile reagent for the synthesis have been reported. -
Revision of KS4 the Periodic Table for KS5 Chemistry - Worksheet
Revision of KS4 The Periodic Table for KS5 Chemistry - Worksheet 1. On the copy of the periodic table (next page) label the following: a. metals and non metals b. groups (with numbers) c. periods (with numbers) d. transition elements 2. How are elements in the periodic table ordered? 3. Find two examples where the mass number does not increase. 4. How many electrons does Magnesium have in its highest energy level? 5. How many electrons does Oxygen have in its highest energy level? 6. What do elements in the same group have in common? 7. What happens to reactivity in group 1 as you go down the group? 8. What happens to reactivity in group 7 as you go down the group? 9. Name 1 similarity and 1 difference between group 1&2 metals and the transition elements. 10. Write a word and symbol equation to show how sodium reacts with water. 11. If identical pieces of lithium and potassium were dropped into a bowl of water at the same time describe how their reactions would differ. 12. Complete the table with ticks to show which reaction will happen. Fluorine Chlorine Bromine Iodine Sodium fluoride Sodium chloride Sodium bromide Sodium iodide Extension Question Research the appearance and state of group 7 elements, use this knowledge to predict observation for the reaction in question 12. Revision of KS4 The Periodic Table for KS5 Chemistry Image credit to LeVanHan https://commons.wikimedia.org/wiki/File:Periodic-table.jpg Revision of KS4 The Periodic Table for KS5 Chemistry Revision of KS4 The Periodic Table for KS5 Chemistry - Worksheet (Answers) 1. -
Thursday 10 January 2019
Please check the examination details below before entering your candidate information Candidate surname Other names Pearson Edexcel Centre Number Candidate Number International Advanced Level Thursday 10 January 2019 Afternoon (Time: 1 hour 40 minutes) Paper Reference WCH04/01 Chemistry Advanced Unit 4: General Principles of Chemistry I – Rates, Equilibria and Further Organic Chemistry (including synoptic assessment) Candidates must have: Scientific calculator Total Marks Data Booklet Instructions • Use black ink or black ball-point pen. • Fill in the boxes at the top of this page with your name, centre number and candidate number. • Answer all questions. • Answer the questions in the spaces provided – there may be more space than you need. Information • The total mark for this paper is 90. • The marks for each question are shown in brackets – use this as a guide as to how much time to spend on each question. • Questions labelled with an asterisk (*) are ones where the quality of your written communication will be assessed – you should take particular care with your spelling, punctuation and grammar, as well as the clarity of expression, on these questions. • A Periodic Table is printed on the back cover of this paper. Advice • Read each question carefully before you start to answer it. • Show all your working in calculations and include units where appropriate. • Check your answers if you have time at the end. Turn over P54560A ©2019 Pearson Education Ltd. *P54560A0128* 2/1/1/1/1/1/ SECTION A Answer ALL the questions in this section. You should aim to spend no more than 20 minutes on THIS AREA WRITE IN DO NOT this section. -
POTASSIUM CYANIDE -- Chemical Fact Sheet What Is It? 1 Potassium Cyanide Is a White Granular Solid with a Bitter Almond Odor
POTASSIUM CYANIDE -- Chemical Fact Sheet What is it? 1 Potassium Cyanide is a white granular solid with a bitter almond odor. It is similar in appearance to sugar. Potassium Cyanide has been used to extract metals from ore and as a rat poison. Where does it Potassium Cyanide is the product of reacting potassium with hydrogen cyanide. come from? What are the Rat Poison common uses for Metal Plating it? Semiconductor Manufacturing How is it Potassium Cyanide is shipped by truck transported in CCC? How is it stored Potassium Cyanide is stored in tightly closed containers. in CCC? Health Hazards from Exposure Exposure Route Symptoms First Aid Inhalation Irritates nose, throat and lungs Remove to fresh air. Seek (low concentrations) Headache or Dizziness medical attention. DO NOT Nausea ATTEMPT CPR. Inhalation Burning sensation Remove to fresh air. Get (high concentrations & prolonged exposure) Unconsciousness medical attention Convulsions immediately. DO NOT Coma ATTEMPT CPR. Death Ingestion Digestive tract burn DO NOT INDUCE Abdominal pain VOMITING. Seek medical Vomiting attention. Large doses can cause death Eyes Severe eye irritant Rinse eyes with water for at Blurred Vision least 15 minutes. Seek Redness, swelling, eye burns medical attention. Skin Skin irritant Wash skin with water for 15 Burning/discomfort minutes. Remove Ulcers contaminated clothing and Skin burns shoes. Seek medical attention . Contra Costa RMP/CalARP Companies that Use, Store or Manufacture this Chemical 2 Electroforming Company Web Sites on the Internet US Environmental -
IODINE Its Properties and Technical Applications
IODINE Its Properties and Technical Applications CHILEAN IODINE EDUCATIONAL BUREAU, INC. 120 Broadway, New York 5, New York IODINE Its Properties and Technical Applications ¡¡iiHiüíiüüiütitittüHiiUitítHiiiittiíU CHILEAN IODINE EDUCATIONAL BUREAU, INC. 120 Broadway, New York 5, New York 1951 Copyright, 1951, by Chilean Iodine Educational Bureau, Inc. Printed in U.S.A. Contents Page Foreword v I—Chemistry of Iodine and Its Compounds 1 A Short History of Iodine 1 The Occurrence and Production of Iodine ....... 3 The Properties of Iodine 4 Solid Iodine 4 Liquid Iodine 5 Iodine Vapor and Gas 6 Chemical Properties 6 Inorganic Compounds of Iodine 8 Compounds of Electropositive Iodine 8 Compounds with Other Halogens 8 The Polyhalides 9 Hydrogen Iodide 1,0 Inorganic Iodides 10 Physical Properties 10 Chemical Properties 12 Complex Iodides .13 The Oxides of Iodine . 14 Iodic Acid and the Iodates 15 Periodic Acid and the Periodates 15 Reactions of Iodine and Its Inorganic Compounds With Organic Compounds 17 Iodine . 17 Iodine Halides 18 Hydrogen Iodide 19 Inorganic Iodides 19 Periodic and Iodic Acids 21 The Organic Iodo Compounds 22 Organic Compounds of Polyvalent Iodine 25 The lodoso Compounds 25 The Iodoxy Compounds 26 The Iodyl Compounds 26 The Iodonium Salts 27 Heterocyclic Iodine Compounds 30 Bibliography 31 II—Applications of Iodine and Its Compounds 35 Iodine in Organic Chemistry 35 Iodine and Its Compounds at Catalysts 35 Exchange Catalysis 35 Halogenation 38 Isomerization 38 Dehydration 39 III Page Acylation 41 Carbón Monoxide (and Nitric Oxide) Additions ... 42 Reactions with Oxygen 42 Homogeneous Pyrolysis 43 Iodine as an Inhibitor 44 Other Applications 44 Iodine and Its Compounds as Process Reagents ... -
Gas Phase Chemistry and Removal of CH3I During a Severe Accident
DK0100070 Nordisk kernesikkerhedsforskning Norraenar kjarnoryggisrannsoknir Pohjoismainenydinturvallisuustutkimus Nordiskkjernesikkerhetsforskning Nordisk karnsakerhetsforskning Nordic nuclear safety research NKS-25 ISBN 87-7893-076-6 Gas Phase Chemistry and Removal of CH I during a Severe Accident Anna Karhu VTT Energy, Finland 2/42 January 2001 Abstract The purpose of this literature review was to gather valuable information on the behavior of methyl iodide on the gas phase during a severe accident. The po- tential of transition metals, especially silver and copper, to remove organic io- dides from the gas streams was also studied. Transition metals are one of the most interesting groups in the contex of iodine mitigation. For example silver is known to react intensively with iodine compounds. Silver is also relatively inert material and it is thermally stable. Copper is known to react with some radioio- dine species. However, it is not reactive toward methyl iodide. In addition, it is oxidized to copper oxide under atmospheric conditions. This may limit the in- dustrial use of copper. Key words Methyl iodide, gas phase, severe accident mitigation NKS-25 ISBN 87-7893-076-6 Danka Services International, DSI, 2001 The report can be obtained from NKS Secretariat P.O. Box 30 DK-4000RoskiIde Denmark Phone +45 4677 4045 Fax +45 4677 4046 http://www.nks.org e-mail: [email protected] Gas Phase Chemistry and Removal of CH3I during a Severe Accident VTT Energy, Finland Anna Karhu Abstract The purpose of this literature review was to gather valuable information on the behavior of methyl iodide on the gas phase during a severe accident. -
Kinetics of the Self-Decomposition of Ozone and the Ozonation of Cyanide Ion and Dyes in Aqueous Solutions
KINETICS OF THE SELF-DECOMPOSITION OF OZONE AND THE OZONATION OF CYANIDE ION AND DYES IN AQUEOUS SOLUTIONS Masaaki TERAMOTO,Seiichiro IMAMURA,Naoyuki YATAGAI, Yoshio NISHIKAWA and Hiroshi TERANISHI Department of Industrial Chemistry, Kyoto Institute of Technology, Matsugasaki, Kyoto 606 Kinetic studies on the self-decomposition of ozone in water, the decomposition of CN~and CNO~,and the decolorization of several dyes by ozone were performed over a wide range of pHusing a stopped-flow apparatus under homogeneousconditions at 298 K. The rate of self- decomposition of ozone was measured in the pH range from 1 to 13.5, and it was found that in the pH range above 8 the rate was expressed by -dlOs]/dt=374 [O3] [OH-]0-88 while in the acidic region the concentration dependence of the rate was complicated, and a simple rate expression could not be obtained. The rate of decomposition of CN~by ozone was expressed by -d[CN-]/dt=310 [O3]° 8 [CN-]° 55 (9.4<pH<11.6) and the rate of decomposition of CNO~was found to be much slower than that of CN~. The decolorization rates of naphthol yellow and methylene blue followed second-order kinetics. Rate constants are presented. The purpose of this paper is to obtain the intrinsic Intr oduction reaction kinetics of the ozonation of several typical Ozone is a powerful oxidizing agent, and it has contaminants such as cyanide and cyanate ions and been recognized as very effective for disinfection, dyes in water using a stopped-flow technique under decolorization, deodorization and the decomposition homogeneous conditions. -
WO 2016/074683 Al 19 May 2016 (19.05.2016) W P O P C T
(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2016/074683 Al 19 May 2016 (19.05.2016) W P O P C T (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every C12N 15/10 (2006.01) kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, (21) International Application Number: BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, PCT/DK20 15/050343 DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, (22) International Filing Date: HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, 11 November 2015 ( 11. 1 1.2015) KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, (25) Filing Language: English PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, (26) Publication Language: English SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (30) Priority Data: PA 2014 00655 11 November 2014 ( 11. 1 1.2014) DK (84) Designated States (unless otherwise indicated, for every 62/077,933 11 November 2014 ( 11. 11.2014) US kind of regional protection available): ARIPO (BW, GH, 62/202,3 18 7 August 2015 (07.08.2015) US GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, (71) Applicant: LUNDORF PEDERSEN MATERIALS APS TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, [DK/DK]; Nordvej 16 B, Himmelev, DK-4000 Roskilde DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, (DK).