NYS00484B-00-BD01 Identified: 11/5/2015 Admitted: 11/5/2015 Withdrawn: Rejected: Stricken: Other
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United States Nuclear Regulatory Commission Official Hearing Exhibit In the Matter of: Entergy Nuclear Operations, Inc. (Indian Point Nuclear Generating Units 2 and 3) ASLBP #: 07-858-03-LR-BD01 Docket #: 05000247 | 05000286 Exhibit #: NYS00484B-00-BD01 Identified: 11/5/2015 Admitted: 11/5/2015 Withdrawn: Rejected: Stricken: Other: 5. CARBON AND LOW ALLOY STEELS Peter Ford General Electric Global Research, Niskayuna, New York – Retired 5.1 OVERALL INTRODUCTION AND CURRENT CONCERNS Carbon and low alloys steels serve in a variety of locations within the nuclear power generating fleet. These ductile structural materials are used as pressure boundary materials in pressure vessels and piping in the RCS, ECCS, secondary water and service water systems of LWRs. These alloys are attractive for this use due to their relatively low cost, good mechanical properties in thick sections and good weldability. In reactor coolant system components, such as the pressure vessel, pressurizer and some piping, the carbon and low alloy steels are clad on the inside wetted surface with corrosion resistant materials such as austenitic stainless steels or nickel-base alloys. This background paper covers stress corrosion cracking (SCC) of ductile carbon and low alloy steel components and their associated weldments, with a special focus on extended operation degradation. Stress corrosion cracking, corrosion fatigue cracking, and flow-accelerated corrosion (FAC) are the primary modes of degradation discussed and presented. Specific areas of concern for extended service are identified. Irradiation effects and thermal aging for these alloys are also covered in considerably more detail in Volume III of this EMDA report (i.e., NUREG/CR-7153). 5.1.1 Steel Compositions and Applications Carbon and low alloy steels (Table 5.1) are used for pressure-retaining components in the primary, secondary, and tertiary systems of both BWRs and PWRs. These steels are used in the reactor in a variety of forms, including seamless piping, forgings, castings, plate, and bolting. The specific carbon or low alloy steel/component combinations that are used in a particular reactor vary between reactor designs and manufacturers, but in general, the reactor components include the following: • Reactor pressure vessel vertical sections in both PWRs and BWRs are manufactured from rolled low alloy steel A533 Gr. B Class 1 plates, which are then welded to form a cylinder. The cylinder is clad on the internal surface with a 5 mm layer of Type 308 SS, and then tempered during a post weld heat treatment (PWHT) at 595 °C (1,103 °F) to 620 °C (1,148 °F) for one hour per 25 mm thickness of steel. The composition of this C-Mn-Mo low alloy steel has more severe limitations on the Cu, S, P, and V contents for plates in the high-flux beltline region since these elements increase the extent of irradiation embrittlement. • The top and bottom heads of the pressure vessel in BWRs and PWRs are generally clad* low alloy steel A508 Gr. 2 Class 1 forgings using the same cladding/heat treatment conditions as for the vertical sections. After the vertical sections and the top and bottom * Note that in some BWR designs the top head may be unclad. heads are fabricated, all three subassemblies are welded together to form the primary pressure vessel and are then given a further PWHT. • Steam generator shells of PWRs are low alloy steel A533 Gr. A Class 1 or Class 2 plates, which, like the pressure vessel, are heat-treated after subassembly. The secondary side of the steam generator is not usually clad. • Steam generator tube sheets in PWRs are generally A508 Gr. 2 Class 1 or A508 Gr. 2 Class 2, with cladding on the primary side of the bottom head. • Steam generator channel heads in PWRs are generally A216 Gr. • The pressurizer shells in PWRs are generally low alloy steel A516 Gr.70 or A533 Gr. B plate with internal stainless steel cladding. Table 5.1. ASTM compositional specifications for ferritic and bainitic carbon and low alloy steel concentrations given as weight percentages. Balance is Fe. ASME/ASTM C max Mn P max S max Si Cu max Ni Cr Mo V max Ferritic Steels A105 0.035 0.6–1.05 0.035 0.04 0.1–0.35 0.4(1) 0.4 maxa 0.3 0.12 0.05 maxa maxa A106 GrB 0.3 0.29– 0.035 0.035 0.1 min 0.4 (2) 0.4 maxb 0.4 0.15 0.08b 1.06 maxb maxb A216 Gr WCB 0.3 1.0 max 0.04 0.045 0.6 max 0.3(3) 0.5 maxc 0.5 0.2 maxc 0.03c maxc A302 GrB 0.25 1.15– 0.035 0.035 0.15–0.4 0.45–0.6 1.50 A333 Gr6 0.3 0.29– 0.035 0.035 0.1 max 1.06 A508 Gr3 0.25 1.2–1.5 0.025 0.025 0.15–0.4 0.4–1.0 0.25 0.45–0.6 0.05 max A516 Gr70 d 0.85–1.2 0.035 0.035 0.15–0.4 A533 Type A 0.25 1.15–1.5 0.035e 0.035 0.15–0.4 0.45–0.6 A533 Type B 0.25 1.15–1.5 0.035 0.035 0.15–0.4 0.4–0.7 0.45–0.6 Bainitic Steels 1Cr1Mo0.25V 0.33 0.85 0.25 1.0 1.25 0.25 2Cr1Mo Gr22 0.026 0.49 0.012 0.009 0.28 0.05 2.42 0.98 NiCrMoV 0.28 0.6 0.015 0.018 0.15–0.3 3.25–4.0 1.25– 0.3–0.6 0.15 (A469 Cl8) 2.0 NiCrMoV 0.35 1.0 0.015 0.018 0.15– 0.75 0.9–1.5 1.0–1.5 0.3 (A470 Cl8) 0.35 NiCrMoV 0.28 0.7 0.015 0.015 0.15– 2.0–4.0 0.7–2.0 0.2–0.7 0.05 (A471 Cl8) 0.35 a Sum of Cu, Ni, Cr, and Mo shall be <1.00%; sum of Cr and Mo shall not exceed 0.32%. b Limits for V and Nb may be increased to 0.1% and 0.05%, respectively. c Sum of Cr and Ni shall not exceed 0.32%. d Carbon max. varies with thickness of plate; 0.5–2 in., 0.28% max; 2–4 in., 0.30% max; 4–8 in., 0.31% max. e For reactor beltline: Cu < 0.1% max, P < 0.012% max, S < 0.015% max, and V < 0.05% max. 100 • Reactor coolant piping for PWR primary circuits may be seamless carbon steel with, in some designs, austenitic stainless steel cladding. Alternatively, a higher-cost option of using cast stainless steel (CF8M) has been used for the main coolant piping. The recirculation piping in BWRs is usually stainless steel (Types 304 SS, 316 SS, 304L SS, 316L SS), although unclad A333 Gr. 6 carbon steel piping may be used in the main steam and the feedwater lines. The piping in the lower-temperature emergency core cooling and auxiliary/support systems is usually seamless A105 or A106 Gr. B carbon steel. 5.1.2 Initial Concerns It was recognized initially by the reactor designers that two problems could occur if carbon steels and low alloy steels were used in water-cooled nuclear reactors. First, irradiation embrittlement of the pressure vessel steel would occur in high-neutron-flux regions over time, and, second, corrosion products could be irradiated during passage through the core region and would create radioactive “crud” that could hamper maintenance operations. The first problem was addressed by monitoring the extent of irradiation embrittlement in low alloy steel surveillance samples placed adjacent to a reactor pressure vessel (RPV) wall in the high neutron flux “beltline” region. This embrittlement is, along with fatigue usage calculations, an input to the regulatory “time limited aging analyses” (TLAA) required for license renewal (sometimes referred to more commonly as “life extension”) for up to 60 years. The crud/radioactivity issue was addressed by cladding the inside of the RPV with stainless steel (e.g., Type 308 SS), thereby reducing the inventory of corrosion product that could become irradiated. 5.1.3 Subsequent Concerns Unfortunately, environmentally assisted degradation has been observed [1–8] in carbon and low alloy steel components of LWRs by degradation modes that were not assessed at the early design stage. The degradation modes were: • “High-cycle” (i.e., low strain amplitude/high frequency) fatigue due to flow-induced vibration or thermal stress cycles (e.g., in dead legs and in feedwater nozzles). • “Low-cycle” (i.e., high strain amplitude/low frequency) fatigue (e.g., due to start-up and shutdown cycles). • Pitting of carbon steel components, usually under oxidizing conditions at temperatures <150 °C (302 °F). Such degradation often acts as a precursor to stress corrosion cracking (SCC) and corrosion fatigue (CF) during subsequent operation at higher temperatures. • Corrosion of carbon steel tube support plates in the secondary side of PWR steam generators due to complex concentrated environments occurring at heat transfer surfaces in the tube/support plate crevice. • Transgranular stress corrosion cracking (TGSCC) of BWR carbon steel piping and low alloy steel PWR steam generator shells in situations involving dynamic loading, oxidizing environments, and high service stress. 101 • Intergranular stress corrosion cracking (IGSCC) at elevated temperatures of components such as Canada Deuterium Uranium (CANDU) PWR steam generator inlet piping that had been cold formed. • IGSCC of welded carbon steel piping in low-temperature [<90 °C (194 °F)], closed-coolant water (CCW) systems containing inhibitors.