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Potential Defined List of Toxic Air Contaminants Based on the Draft Air Toxics Workgroup Methodology May 13, 2013 Future TAC Basis Reason for HAP ITSL CAS No

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Potential Defined List of Toxic Air Contaminants Based on the Draft Air Toxics Workgroup Methodology May 13, 2013 Future TAC Basis Reason for HAP ITSL CAS No. Chemical Name Ex.#1 for Yes No, etc. ? (ug/m3) AvgT epoxy resin solution YES ITSL no 6 annual amyl acetate (mixture) NO > 75%tile no 1100 24hr cyclopentyldichlorosilane NO default no 0.1 annual dicyclopentyldichlorosilane NO default no 0.1 annual disiloxane NO default no 0.1 annual n-butylglucamine YES ITSL no 6.4 annual purafect 4000g YES ITSL no 0.02 1hr biosam tp-1.5 YES ITSL no 0.02 1hr 2-(1-ethoxyethoxy)-6-(trifluoromethyl)-benzenethiol NO default no 0.1 annual 2-mercapto-3-(trifluoromethyl)-phenol NO default no 0.1 annual 4-chloro-2-ethyoxy-6-fluoropyrimidine NO default no 0.1 annual n-chloro-2,6-difluorobenzamide NO default no 0.1 annual cyclic (phme)2(me)2, d4 NO default no 0.1 annual 100 sxl NO default unknown 0.1 annual atlox 848 NO default no 0.1 annual ethomeen t/30 NO default no 0.1 annual sponto 11 NO default no 0.1 annual sponto 723 NO default no 0.1 annual t-det c-40 NO default no 0.1 annual witconol al 69-66 NO default no 0.1 annual heptamethyl-1-vinyl-1,7-dichlorotetrasilazane NO default no 0.1 annual fyre-zyme YES ITSL no 0.15 annual 1,1,2,4-tetramethyl-1-1-1-sila-2-aza-cyclopentane YES ITSL no 0.7 annual polyglycol 26-3 YES ITSL no 16 annual ad acid YES ITSL no 17 annual triethylammonium suleptanate YES ITSL no 17 annual see spec. polycyclic aromatic hydrocarbons (pahs) NO HAP comps. yes POM o-(1-ethoxyethyl)-2-(propylthio)-3- (trifluoromethyl)phenol NO default no 0.1 annual 50-00-0 formaldehyde YES Carc yes this chemical 9 8hr 50-03-3 hydrocortisone acetate YES ITSL no 15 annual 50-21-5 lactic acid YES ITSL no 7 annual 50-28-2 estradiol NO default no 0.1 annual 50-29-3 ddt YES Carc yes POM 50-32-8 benzo(a)pyrene YES Carc7 yes POM 51-28-5 2,4-dinitrophenol YES ITSL yes this chemical 7 24hr 51-79-6 Ethyl carbamate (Urethane) YES HAP YES 53-36-1 methyl predisolone acetate YES ITSL no 43 annual 53-70-3 dibenz(a,h)anthracene YES Carc7 yes POM 56-23-5 carbon tetrachloride YES Carc yes this chemical 100 24hr 56-49-5 3-methyl cholanthrene YES Cal Carc yes POM 56-55-3 benz(a)anthracene YES Carc7 yes POM 56-81-5 glycerol YES ITSL no 100 8hr 57-11-4 stearic acid YES ITSL no 100 8hr Page 1 of 29 Potential Defined List of Toxic Air Contaminants Based on the Draft Air Toxics Workgroup Methodology May 13, 2013 Future TAC Basis Reason for HAP ITSL CAS No. Chemical Name Ex.#1 for Yes No, etc. ? (ug/m3) AvgT 57-12-5 cyanide YES HAP yes cyanides 50 1hr 57-15-8 chlorobutanol NO default no 0.1 annual 57-41-0 phenytoin YES Carc yes POM 57-55-6 propylene glycol NO > 75%tile no 6000 annual 57-74-9 Chlordane YES HAP YES 57-83-0 progesterone NO default no 0.1 annual 57-97-9 7,12-dimethyl benzanthracene YES Cal Carc yes POM 58-36-6 10,10'-oxybisphenoxarsine oxide YES ITSL no 0.2 annual 60-29-7 ethyl ether NO > 75%tile no 12000 8hr 60-34-4 methyl hydrazine YES ITSL yes this chemical 0.03 24hr 60-57-1 dieldrin YES Carc no 62-53-3 aniline YES Carc yes this chemical 1 annual 62-73-7 dichlorvos YES ITSL yes this chemical 0.5 24hr 62-75-9 n-nitrosodimethylamine YES Carc yes this chemical 63-05-8 androstenedione YES ITSL no 17 annual 64-02-8 ethylenediamine tetra-acetic acid, tetrasodium salt NO default no 0.1 annual 64-04-0 beta phenylethylamine NO default no 0.1 annual 64-17-5 ethyl alcohol NO > 75%tile no 19000 8hr 64-18-6 formic acid YES ITSL no 2 24hr 64-19-7 acetic acid YES ITSL no 250 8hr 64-67-5 diethyl sulfate YES ITSL yes this chemical 1 annual 65-85-0 benzoic acid NO PM Low Tox no 66-25-1 hexanaldehyde YES ITSL no 2 annual 67-56-1 methanol NO HAP > 75%tile yes this chemical 3250 1hr 67-63-0 isopropyl alcohol YES ITSL no 220 24hr 67-64-1 acetone NO > 75%tile no 5900 8hr 67-66-3 chloroform YES Carc yes this chemical 67-68-5 dimethylsulfoxide YES ITSL no 20 annual 67-72-1 hexachloroethane YES Carc yes this chemical 30 annual 68-12-2 N,N-dimethylformamide YES ITSL yes this chemical 30 24hr 71-23-8 n-propyl alcohol NO > 75%tile no 730 annual 71-36-3 n-butanol YES ITSL no 350 24hr 71-41-0 amyl alcohol NO > 75%tile no 120 annual 71-43-2 benzene YES Carc yes this chemical 30 annual 71-55-6 methyl chloroform NO HAP > 75%tile yes this chemical 6000 24hr 72-54-8 DDD (TDE) YES Carc no 72-55-9 DDE (p,p'-DDE) - CAS# 3547044 in original list YES HAP YES 74-83-9 methyl bromide YES ITSL yes this chemical 5 24hr 74-85-1 ethylene NO > 75%tile no 6240 24hr 74-87-3 methyl chloride YES Carc yes this chemical 90 24hr 74-88-4 Methyl iodide (Iodomethane) YES HAP YES 74-89-5 methylamine YES ITSL no 64 8hr 74-90-8 hydrogen cyanide YES ITSL yes cyanides 0.8 annual 74-93-1 methyl mercaptan YES ITSL no 10 1hr Page 2 of 29 Potential Defined List of Toxic Air Contaminants Based on the Draft Air Toxics Workgroup Methodology May 13, 2013 Future TAC Basis Reason for HAP ITSL CAS No. Chemical Name Ex.#1 for Yes No, etc. ? (ug/m3) AvgT 74-97-5 chlorobromomethane NO > 75%tile no 10600 8hr 74-99-7 methyl acetylene NO > 75%tile no 16500 8hr 75-00-3 ethyl chloride NO HAP > 75%tile yes this chemical 10000 24hr 75-01-4 vinyl chloride YES Carc yes this chemical 100 24hr 75-04-7 ethylamine YES ITSL no 92 8hr 75-05-8 acetonitrile YES ITSL yes this chemical 60 24hr 75-07-0 acetaldehyde YES Carc yes this chemical 9 24hr 75-09-2 methylene chloride YES Carc yes this chemical 2000 annual 75-12-7 formamide YES Carc no 600 24hr 75-15-0 carbon disulfide YES HAP yes this chemical 700 24hr 75-18-3 dimethylsulfide YES ITSL no 7 annual 75-21-8 ethylene oxide YES Carc yes this chemical 75-25-2 bromoform YES Carc yes this chemical 75-27-4 bromodichloromethane YES Carc no 75-28-5 isobutane NO > 75%tile no 23800 8hr 75-29-6 2-chloropropane YES ITSL no 100 24hr 75-31-0 isopropylamine YES ITSL no 120 8hr 75-34-3 1,1-dichloroethane YES HAP yes this chemical 500 24hr 75-35-4 vinylidene chloride (1,1-dichloroethylene) YES ITSL yes this chemical 200 24hr 75-36-5 acetyl chloride NO default no 0.1 annual 75-37-6 1,1-difluoroethane NO > 75%tile no 40000 24hr 75-38-7 vinylidene fluoride YES ITSL no 30 24hr 75-44-5 phosgene YES ITSL yes this chemical 0.3 24hr 75-45-6 chlorodifluoromethane NO > 75%tile no 50000 24hr 75-50-3 trimethylamine YES ITSL no 120 8hr 75-52-5 nitromethane YES Carc no 70 24hr 75-54-7 methyldichlorosilane YES ITSL no 4 annual 75-55-8 1,2-propylenimine YES HAP yes this chemical 5 8hr 75-56-9 propylene oxide YES Carc yes this chemical 30 24hr 75-64-9 t-butylamine NO > 75%tile no 60 annual 75-65-0 t-butanol NO > 75%tile no 1890 24hr 75-68-3 1-chloro-1,1-difluoroethane NO > 75%tile no 50000 24hr 75-69-4 trichlorofluoromethane NO > 75%tile no 56200 1hr 75-71-8 dichlorodifluoromethane NO > 75%tile no 49500 8hr 75-75-2 methane sulfonic acid YES ITSL no 1.4 annual 75-76-3 tetramethylsilane NO > 75%tile no 1300 annual 75-77-4 trimethylchlorosilane YES ITSL no 6 annual 75-78-5 dimethyldichlorosilane YES ITSL no 6.2 annual 75-79-6 methyltrichlorosilane NO > 75%tile no 109 annual 75-94-5 vinyltrichlorosilane YES ITSL no 7 annual 76-05-1 trifluoroacetic acid YES ITSL no 8 annual 76-13-1 1,1,2-trichloro-1,2,2-trifluoroethane NO > 75%tile no 19140 24hr 76-14-2 dichlorotetrafluoroethan NO > 75%tile no 69000 8hr 76-44-8 heptachlor YES Carc yes this chemical Page 3 of 29 Potential Defined List of Toxic Air Contaminants Based on the Draft Air Toxics Workgroup Methodology May 13, 2013 Future TAC Basis Reason for HAP ITSL CAS No. Chemical Name Ex.#1 for Yes No, etc. ? (ug/m3) AvgT 76-83-5 triphenyl methyl chloride YES ITSL yes POM 17 annual 77-47-4 hexachlorocyclopentadiene YES ITSL yes this chemical 0.2 24hr 77-48-5 1,3-dibromo-5,5-dimethylhydantoin YES ITSL no 2 8hr 77-58-7 dibutyl tin dilaurate YES ITSL no 5 8hr 77-73-6 dicyclopentadiene YES ITSL no 1 24hr 77-76-9 2,2-dimethoxypropane NO default no 0.1 annual 77-78-1 dimethyl sulfate YES HAP yes this chemical 0.5 8hr 77-93-0 triethyl citrate NO > 75%tile no 290 annual 78-07-9 ethyltriethoxysilane NO > 75%tile no 44 annual 78-10-4 ethyl silicate YES ITSL no 850 8hr 78-59-1 isophorone YES Carc yes this chemical 280 1hr 78-78-4 2-methyl butane NO > 75%tile no 17700 8hr 78-79-5 isoprene YES Carc no 78-83-1 isobutyl alcohol YES ITSL no 1500 8hr 78-84-2 isobutyraldehyde YES ITSL no 160 24hr 78-87-5 propylene dichloride YES ITSL yes this chemical 4 24hr 78-92-2 sec-butanol NO > 75%tile no 3000 8hr 78-93-3 methyl ethyl ketone NO > 75%tile delisted HAP 5000 24hr 78-96-6 monoisopropanolamine YES ITSL no 15 annual 79-00-5 1,1,2-trichloroethane YES Carc yes this chemical 79-01-6 trichloroethylene YES Carc yes this chemical 2 annual 79-06-1 acrylamide YES Carc yes this chemical 6 24hr 79-09-4 propionic acid YES ITSL no 300 8hr 79-10-7 acrylic acid YES ITSL yes this chemical 1 24hr 79-11-8 Chloroacetic acid YES HAP YES 79-14-1 hydroxyacetic acid/ glycolic acid YES ITSL no 4 annual 79-20-9 methyl acetate NO > 75%tile no 6100 8hr 79-24-3 nitroethane YES ITSL no 60 24hr 79-29-8 2,3-dimethylbutane NO > 75%tile no 3500 8hr 79-31-2 isobutyric acid YES ITSL no 0.9 annual 79-34-5 1,1,2,2-tetrachloroethane YES Carc yes this chemical 79-41-4 methacrylic acid YES ITSL no 30 24hr 79-46-9 2-nitropropane YES Carc yes this chemical 20 24hr 79-92-5 camphene NO > 75%tile no 80 annual 80-15-9 cumene hydroperoxide YES ITSL no 6 24hr 80-43-3 dicumyl peroxide NO default no 0.1 annual 80-56-8 pinene, alpha YES ITSL no 1120 8hr 80-62-6 methyl methacrylate NO HAP > 75%tile yes this chemical 700 24hr 80-73-9 n,n'-dimethylethyleneurea NO default no 0.1 annual 82-68-8 pentachloronitrobenzene YES ITSL yes this chemical 11 24hr 83-32-9 acenaphthene YES ITSL yes POM 210 24hr 84-66-2 diethyl phthalate YES ITSL no 50 8hr 84-74-2 dibutyl phthalate YES HAP yes this chemical 50 8hr 85-01-8 phenanthrene NO default yes POM 0.1 annual Page 4 of 29 Potential Defined List of Toxic Air Contaminants Based on the Draft Air Toxics Workgroup Methodology May 13, 2013 Future TAC Basis Reason for HAP ITSL CAS No.
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    Version: 1.0 Revision Date: 03/14/2018 SAFETY DATA SHEET 1. Identification Material name: TREMPLY TPO BONDING ADHESIVE 5 GL Material: 423300 805 Recommended use and restriction on use Recommended use : Adhesive Restrictions on use: Not known. Manufacturer/Importer/Supplier/Distributor Information Tremco U.S. Roofing 3735 Green Road Beachwood OH 44122 US Contact person : EH&S Department Telephone : 216-292-5000 Emergency telephone number : 1-800-424-9300 (US); 1-613-996-6666 (Canada) 2. Hazard(s) identification Hazard Classification Physical Hazards Flammable liquids Category 2 Health Hazards Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 2A Germ Cell Mutagenicity Category 1B Carcinogenicity Category 1B Toxic to reproduction Category 2 Specific Target Organ Toxicity - Category 1 Repeated Exposure Unknown toxicity - Health Acute toxicity, oral 22.57 % Acute toxicity, dermal 22.72 % Acute toxicity, inhalation, vapor 37.75 % Acute toxicity, inhalation, dust 100 % or mist Environmental Hazards Acute hazards to the aquatic Category 3 environment Unknown toxicity - Environment 1/20 000000026448 Version: 1.0 Revision Date: 03/14/2018 Acute hazards to the aquatic 24.15 % environment Chronic hazards to the aquatic 100 % environment Label Elements Hazard Symbol : Signal Word: Danger Hazard Statement: Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness. Suspected of damaging fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure if inhaled. Harmful to aquatic life. Precautionary Statements Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container tightly closed. Ground and bond container and receiving equipment.
  • CAS 84-69-5 Diisobutyl Phthalate (DIBP)

    CAS 84-69-5 Diisobutyl Phthalate (DIBP)

    CAS 84-69-5 Diisobutyl phthalate (DIBP) Toxicity The European Union classified DIBP as a reproductive Substance of Very High Concern (SVHC).1 A 2011 study observed decreased testicular testosterone in male rats fed DIBP for 4 days.2 Borch et al. 2006 found male offspring of female rats exposed to DIBP from gestation day 7 to gestation day 20 or 21 had significantly reduced anogenital distance.3 The Chronic Hazard Advisory Panel (CHAP) determined, due to toxicological profile similarities to Dibutyl phthalate (DBP), exposure to DIBP contributes to a cumulative antiandrogenic effect with other phthalates and should be permanently banned in children’s toys and child care articles at levels greater than 0.1 percent.4 In 2017 the CPSC permanently banned DIBP in children’s toys and childcare articles at levels greater than 0.1 percent.5 Exposure The 2015 National Health and Nutrition Examination Survey (NHANES) monitored a metabolite of DIBP in human urine, and the levels appear to be increasing.6 Metabolites of DIBP were detected in the urine of pregnant Danish women in a 2010-2012 study.7 A significant correlation was found between DIBP metabolite concentrations in the urine of Danish children and increased levels of DIBP in bedroom dust and day care centers.8 Other DIBP is used as a substitute ingredient to di-n-butyl phthalate (DBP) due to structural similarities, therefore, its’ presence in products may increase.3 References 1. European Commission, Endocrine disruptor priority list. Retrieved from: http://ec.europa.eu/environment/chemicals/endocrine/strategy/substances_en.htm 2. Hannas, B.R., Lambright, C.S., Furr, J., Howdeshell, K.L., Wilson, V.S., Gray, L.E., Jr.
  • Chemical Resistance of Plastics

    Chemical Resistance of Plastics

    (c) Bürkle GmbH 2010 Important Important information The tables “Chemical resistance of plastics”, “Plastics and their properties” and “Viscosity of liquids" as well as the information about chemical resistance given in the particular product descriptions have been drawn up based on information provided by various raw material manufacturers. These values are based solely on laboratory tests with raw materials. Plastic components produced from these raw materials are frequently subject to influences that cannot be recognized in laboratory tests (temperature, pressure, material stress, effects of chemicals, construction features, etc.). For this reason the values given are only to be regarded as being guidelines. In critical cases it is essential that a test is carried out first. No legal claims can be derived from this information; nor do we accept any liability for it. A knowledge of the chemical and mechanical Copyright This table has been published and updated by Bürkle GmbH, D-79415 Bad Bellingen as a work of reference. This Copyright clause must not be removed. The table may be freely passed on and copied, provided that Extensions, additions and translations If your own experiences with materials and media could be used to extend this table then we would be pleased to receive any additional information. Please send an E-Mail to [email protected]. We would also like to receive translations into other languages. Please visit our website at http://www.buerkle.de from time to Thanks Our special thanks to Franz Kass ([email protected]), who has completed and extended these lists with great enthusiasm and his excellent specialist knowledge.
  • Appendix B Reproductive and Other Toxicology

    Appendix B Reproductive and Other Toxicology

    Report to the U.S. Consumer Product Safety Commission by the CHRONIC HAZARD ADVISORY PANEL ON PHTHALATES AND PHTHALATE ALTERNATIVES July 2014 APPENDIX B REPRODUCTIVE AND OTHER TOXICOLOGY TABLE OF CONTENTS 1 Introduction ............................................................................................................................. 1 1.1 Nonreproductive Toxicity ................................................................................................ 2 2 Permanently Banned Phthalates .............................................................................................. 3 2.1 Di-n-Butyl Phthalate (DBP) ............................................................................................. 3 2.1.1 Human Data .............................................................................................................. 3 2.1.2 Animal Data .............................................................................................................. 4 2.1.3 Studies Reported Since the NTP-CERHR Report in 2000 ....................................... 4 2.2 Butylbenzyl Phthalate (BBP) ........................................................................................... 6 2.2.1 Human Data .............................................................................................................. 6 2.2.2 Animal Data .............................................................................................................. 6 2.2.3 Studies Reported Since the NTP-CERHR Report in 2003 ......................................