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US and Canadian Version: 1.0 Revision Date: 03/14/2018 SAFETY DATA SHEET 1. Identification Material name: TREMPLY TPO BONDING ADHESIVE 5 GL Material: 423300 805 Recommended use and restriction on use Recommended use : Adhesive Restrictions on use: Not known. Manufacturer/Importer/Supplier/Distributor Information Tremco U.S. Roofing 3735 Green Road Beachwood OH 44122 US Contact person : EH&S Department Telephone : 216-292-5000 Emergency telephone number : 1-800-424-9300 (US); 1-613-996-6666 (Canada) 2. Hazard(s) identification Hazard Classification Physical Hazards Flammable liquids Category 2 Health Hazards Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 2A Germ Cell Mutagenicity Category 1B Carcinogenicity Category 1B Toxic to reproduction Category 2 Specific Target Organ Toxicity - Category 1 Repeated Exposure Unknown toxicity - Health Acute toxicity, oral 22.57 % Acute toxicity, dermal 22.72 % Acute toxicity, inhalation, vapor 37.75 % Acute toxicity, inhalation, dust 100 % or mist Environmental Hazards Acute hazards to the aquatic Category 3 environment Unknown toxicity - Environment 1/20 000000026448 Version: 1.0 Revision Date: 03/14/2018 Acute hazards to the aquatic 24.15 % environment Chronic hazards to the aquatic 100 % environment Label Elements Hazard Symbol : Signal Word: Danger Hazard Statement: Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness. Suspected of damaging fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure if inhaled. Harmful to aquatic life. Precautionary Statements Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container tightly closed. Ground and bond container and receiving equipment. Use explosion-proof [electrical/ventilating/lighting/EF equipment. -se non3spar)ing tools. Ta)e action to prevent static discharges. Gear protective gloves/protective clothing/eye protection/.ace protection. Gash thoroughly a.ter handling. Obtain special instructions be.ore use. Do not handle until all sa.ety precautions have been read and understood. -se personal protective equipment as required. Avoid release to the environment. Response : I9 I EYES: Rinse cautiously with water .or several minutes. Remove contact lenses, i. present and easy to do. Continue rinsing. I. eye irritation persists: Get medical advice/attention. I9 O SCI 5or hair6: Ta)e o.. immediately all contaminated clothing. Rinse s)in with water Dor showerF. I. s)in irritation occurs: Get medical advice/attention. I9 exposed or concerned: Get medical advice/attention. Speci.ic treatment 5see on this label6. Ta)e o.. contaminated clothing. In case o. .ire: -seE to extinguish. Storage : Store in a well3ventilated place. Ceep cool. Store loc)ed up. Disposal : Dispose o. contents/container to an appropriate treatment and disposal .acility in accordance with applicable laws and regulations, and product characteristics at time o. disposal. 2/20 000000026448 Version: 1.0 Revision Date: 03/14/2018 Hazard(s) not otherwise Static accumulating .lammable liquid can become electrostatically charged classified (HNOC): even in bonded and grounded equipment. Spar)s may ignite liquid and vapor. May cause .lash .ire or explosion. 3. Composition/information on ingredients Mixtures Chemical Identity CAS number Content in percent (%) H Toluene 10838833 25 3 I50A Acetone 6036431 20 3 I50A Hexane 11035433 10 3 I20A Aliphatic aphtha 5Light 6404238438 1 3 I5A aliphatic naphtha6 Methylcyclopentane 4633030 1 3 I5A EthylbenBene 10034134 0.1 3 I1A H All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First -aid measures Ingestion : Call a POISO CE TRE/doctor i. you .eel unwell. Rinse mouth. Inhalation : Move to .resh air. Skin Contact : Ta)e o.. immediately all contaminated clothing. Immediately .lush with plenty o. water .or at least 15 minutes while removing contaminated clothing and shoes. Gash contaminated clothing be.ore reuse. Get medical attention. Eye contact : Immediately .lush with plenty o. water .or at least 15 minutes. I. easy to do, remove contact lenses. Get medical attention. Most important symptoms/effects , acute and delayed Symptoms : Respiratory tract irritation. Prolonged or repeated contact with s)in may cause redness, itching, irritation and ecBema/chapping. Indication of immediate medical attention and special treatment needed Treatment : Symptoms may be delayed. 5. Fire -fighting measures General Fire Hazards : -se water spray to )eep .ire3exposed containers cool. Gater may be ine..ective in .ighting the .ire. 9ight .ire .rom a protected location. Move containers .rom .ire area i. you can do so without ris). 3/20 000000026448 Version: 1.0 Revision Date: 03/14/2018 Suitable (and unsuitable) extinguishing media Suita ble extinguishing -se .ire3extinguishing media appropriate .or surrounding materials. media: Unsuitable extinguishing Avoid water in straight hose stream7 will scatter and spread .ire. media: Specific hazards arising from Vapors may travel considerable distance to a source o. ignition and .lash the chemical: bac). Vapors may cause a .lash .ire or ignite explosively. Prevent buildup o. vapors or gases to explosive concentrations. Special protective equipment and precautions for firefighters Special fire fighting o data available. procedures: Special protective equipment 9ire.ighters must use standard protective equipment including .lame for fire-fighters: retardant coat, helmet with .ace shield, gloves, rubber boots, and in enclosed spaces, SCBA. 6. Accidental release measures Personal precautions, Ventilate closed spaces be.ore entering them. ELIMI ATE all ignition protective equipment and sources 5no smo)ing, .lares, spar)s or .lames in immediate area6. Ceep emergency procedures: upwind. See Section 8 o. the SDS .or Personal Protective Equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ceep unauthoriBed personnel away. Methods and material for Dam and absorb spillages with sand, earth or other non3combustible containment and cleaning material. Collect spillage in containers, seal securely and deliver .or up: disposal according to local regulations. Notification Procedures : In the event o. a spill or accidental release, noti.y relevant authorities in accordance with all applicable regulations. Environmental Precautions : Avoid release to the environment. Prevent .urther lea)age or spillage i. sa.e to do so. Do not contaminate water sources or sewer. 7. Handling and storage Precautions for safe handling : Do not handle until all sa.ety precautions have been read and understood. Obtain special instructions be.ore use. -se personal protective equipment as required. Avoid contact with eyes. Gash hands thoroughly a.ter handling. Ceep away .rom heat, hot sur.aces, spar)s, open .lames and other ignition sources. o smo)ing. Ground and bond container and receiving equipment. Ta)e precautionary measures against static discharges. Avoid contact with s)in. Provide adequate ventilation. Gear appropriate personal protective equipment. Observe good industrial hygiene practices. 4/20 000000026448 Version: 1.0 Revision Date: 03/14/2018 Conditions for safe storage, Store loc)ed up. Store in a well3ventilated place. Store in a cool place. including any incompatibilities: 8. Exposure controls/personal protection Control Parameters Occupational Exposure Limits Chemical Identity Type Exposure Limit Values Source Toluene TGA 20 ppm -S. ACGIH Threshold Limit Values 520116 TGA 200 ppm -S. OSHA Table J32 524 C9R 1410.10006 502 20066 Ceiling 300 ppm -S. OSHA Table J32 524 C9R 1410.10006 502 20066 MAX. 500 ppm -S. OSHA Table J32 524 C9R 1410.10006 502 CO C 20066 Acetone TGA 250 ppm -S. ACGIH Threshold Limit Values 503 20156 STEL 500 ppm -S. ACGIH Threshold Limit Values 503 20156 PEL 1,000 ppm 2,400 mg/m3 -S. OSHA Table J31 Limits .or Air Contaminants 524 C9R 1410.10006 502 20066 Hexane TGA 50 ppm -S. ACGIH Threshold Limit Values 520116 PEL 500 ppm 1,800 mg/m3 -S. OSHA Table J31 Limits .or Air Contaminants 524 C9R 1410.10006 502 20066 Aliphatic aphtha 5Light PEL 100 ppm 400 mg/m3 -S. OSHA Table J31 Limits .or Air aliphatic naphtha6 Contaminants 524 C9R 1410.10006 503 20166 EthylbenBene TGA 20 ppm -S. ACGIH Threshold Limit Values 520116 PEL 100 ppm 435 mg/m3 -S. OSHA Table J31 Limits .or Air Contaminants 524 C9R 1410.10006 502 20066 Chemical name Type Exposure Limit Values Source Toluene TGA 20 ppm Canada. British Columbia OELs. 5Occupational Exposure Limits .or Chemical Substances, Occupational Health and Sa.ety Regulation 246/40, as amended6 500 20006 Toluene TGA 20 ppm Canada. Ontario OELs. 5Control o. Exposure to Biological or Chemical Agents6 511 20106 Toluene TGA 50 ppm 188 mg/m3 Canada. Luebec OELs. 5Ministry o. Labor 3 Regulation Respecting the Luality o. the Gor) Environment6 512 20086 Acetone STEL 500 ppm Canada. British Columbia OELs. 5Occupational Exposure Limits .or Chemical Substances, Occupational Health and Sa.ety Regulation 246/40, as amended6 500 20006 TGA 250 ppm Canada. British Columbia OELs. 5Occupational Exposure Limits .or Chemical Substances, Occupational Health and Sa.ety Regulation 246/40, as amended6 500 20006 Acetone TGA 500 ppm Canada. Ontario OELs. 5Control o. Exposure to Biological or Chemical Agents6 511 20106 STEL 050 ppm Canada. Ontario OELs. 5Control o. Exposure to Biological or Chemical Agents6 511 20106 Acetone
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