| 509

Index

a BIP (2,6-bis(1-methyl-1H-benzo[d]imidazol- 40-[4-(2-acryloyloxyethoxy)phenyl]-2,20:60,200- 2-yl)) 205 terpyridine 243 – 4-ethynyl functionalized 52 actin filament (F-actin) 451 – ditopic 52, 205, 268 AgI complex – metallopolymer 224 – dinuclear 467 – polydisperse 224 alcohol cross-coupling 470 2,20-bipyrazine (bpz) 491 aldol-type condensation 468ff. 2,20-bipyridine (bpy) 2, 282, 475 2þ allylation reaction 460ff. – cis-[(bpy)2(py)Ru(H2O)] 476 2þ allylic substitution reaction 463 – cis-[(bpy)2(py)RuO] 477 amidation bipyridine-cyclodextrin 186 – intramolecular 466 2,20-bipyrimidine (bpm) 491 aminolysis 6,600-bis(aminomethyl)-40-phenyl-2,20:60,200- – asymmetric 472 terpyridine chelating unit 387 40-(4-aminophenyl)-2,20:60,200-terpyridine 410 2,6-bis(benzimidazol-2-yl)pyridine antitumor agent 341ff. (bzimpy) 366 40-aryl-2,20:60,200-terpyridine 38ff. 1,4-bis[2,6-bis(1-butyl-1H-1,2,3-triazol-4-yl) atom-transfer radical polymerization pyridin-4-yl]benzene (BTP-type) 219 (ATRP) 244ff., 282 bis-cyclometalating tridentate ligand 113 –CuI-catalyzed 475 1,4-bis[2,6-di(1H-pyrazol-1-yl)pyridin-4-yl] Au nanoparticle 421f. benzene (BPP-type) 219 – terpyridine ligand 422 2,6-bis(5,6-dihydro-4H-1,3-oxazin-2-yl) Au surface 402ff. pyridine 463 – terpyridine-modified 408f. 2,6-bis(4,5-dihydrooxazol-2-yl)pyridine 463 AuIII mono(terpyridine) complex 333, 5,500-bis(hydroxymethyl)-2,20:60,200- 349, 386 terpyridine 256 40-azido-2,20:60,200-terpyridine 25f. bis-intercalator 334 aziridination 466f. 2,6-bis(1-methyl-1H-benzo[d]imidazol-2-yl) azurin 380 pyridin-4-ol (BIP-OH) 51 2,6-bis(1-methyl-1H-benzo[d]imidazol-2-yl) b pyridine, see BIP para-benzoquinone 477 bis() 150ff. BINOL (1,10-binaphth-2-ol) 107 3,6-bis(pyridin-2-yl)pyridazine ligand – BINOL-type bis(terpyridine) 220 158 biolabeling 376 2,6-bis(pyridin-2-yl)-4-pyridone 284 biomolecule 1,5-bis(pyridin-2-yl)triazine 83 – covalent binding to small-molecule 338 bis-rotaxane 179 – labeling 388 1,2-bis(2,20:60,200-terpyridin-40-yl)acetylene 32 biotin moiety 381 bis(2,20:60,200-terpyridin-4-yl)amine 25

Terpyridine-based Materials: For Catalytic, Optoelectronic and Life Science Applications, First Edition. Ulrich S. Schubert, Andreas Winter, and George R. Newkome. r 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Published 2011 by WILEY-VCH Verlag GmbH & Co. KGaA

BINDEX 27 J l 2011 9 29 9 510 | Index 1,4-bis(2,20:60,200-terpyridin-40-yl)benzene block copolymer 42 – A-[M]-(B-[M]-)nB-[M]-A type 308 (E)-1,2-bis(terpyridin-4-yl)diazene 25 – dinuclear A-[M]-B-[M]-A 309 1,4-bis[(2,20:60,200-terpyridin-5-yl) – oligonuclear metallo-supramolecular 308 methylsulfanyl]butane 130 blue dimer 489ff. 1,3-bis[(2,20:60,200-terpyridin-5-yl) BODIPY (boron-dipyrromethene) 209 methylsulfanyl]propane 130 boron neutron capture therapy (BNCT) 330 bis(terpyridine) 42ff., 149f., 182, 289 Borromean links (Borromean rings) 157, – alkene-functionalized angular 141 181ff. – amine-bridged 25 bpy, see 2,20-bipyridine – angular 136ff. 40-(4-bromomethylphenyl)-2,20:60,200- – BINOL-type 220 terpyridine 450 – boron-dipyrromethane (BODIPY)- 40-(4-bromophenyl)-2,20:60,200-terpyridine 233 bridged 48f. BTB (bipyridine–terpyridine–bipyridine) 173 – dithiol-bridged 130 – BTP-based ligand 52 – electron-acceptor-type p-conjugated – BTB-type ligand 219 spacer 48 n-butyl acrylate (nBA) 283f. – motif 206 1-butyl-3-methylimidazolium – oligophenylene-bridged 212 hexafluorophosphate (bmim-PF6) 423 – oligoyne-bridged 33 – photophysical property 35, 47 c p – -conjugated 47, 204, 309 C60tpy@Pd 426 – piperazine-functionalized 412 C^N^N (mono-cyclometalating tridentate – soluble 34 ligand) 445 þ – step-wise self-assembly 404 [(C^N^N)Ru(N^N^N)] 445 – trans-stilbene-bridged 44 cadmium 174 – telechelic 270 –CdII 292, 365 – thieno[3,4-b]pyrazine-bridged 47 –CdII coordination polymer 208 – viologen-type 133, 220 –CdII mono(terpyridine) complex 425 – X-shaped 37 – [Cd(tpy)F2] 467f. bis(terpyridine) complex cage-like structure 172 – dinuclear 89 calix[4]arene – heteroleptic 185 – derivative 186 – self-assembly 147 – functionalized with four terpyridine bis(terpyridine) ligand 32 188 – angular 137 e-caprolactone 279 – heteroleptic 68 2-(N-carbazolyl)ethyl methacrylate – homoleptic 68 (CzMA) 256 – multifunctional 131 carbene-insertion 467 – telechelic 224 catalyst in organic reaction – thiophene-containing 98 – asymmetric 460 1,1000-bis(2,20:60,200-terpyridin-4-yl)-1,10- catenane 177, 181 biferrocene 100 – reversible molecular motion 181 3,6-bis(2,20:60,200-terpyridin-40-yl)-9-alkyl- CCAAC (CuI-catalyzed alkyne-azide [2þ3]- carbazole 136 cycloaddition) reaction (“click” 1,4-bis(2,20:60,200-terpyridin-40-yl)benzene reaction) 25, 52f., 406, 472 309 chain-transfer agent (CTA) 283 4,40-bis(2,20:60,200-terpyridin-40-yl) – telechelic 284 triphenylamine 136 chemotherapeutic agent 342 2,6-bis(1H-1,2,3-triazol-4-yl)pyridine 40-chloro-2,20:60,200-terpyridine 264ff. (BTP-type) 52 chromium bis(U-terpyridine) 50f. –CrIII bis(terpyridine) complex 375 black dye 66, 432ff. circular dichroism (CD) effect 320 bleomycin co-dimerization – iron-containing glycopeptide 372 – linear 471

BINDEX 27 J l 2011 9 29 9 Index | 511 cobaloxime complex 486 d cobalt dendrimer –CoII bis(terpyridine) complex 71, – first-generation 105 185, 374, 412ff. dendritic terpyridine architecture 24 –CoIII bis(terpyridine) complex 374 deoxycholic acid (DCA) 436 –CoII ion 244, 267, 292, 374, 403 deoxycytidinyl-(30,50)-deoxyguanosine –CoIII ion 374 (deoxy-CpG) 328 –CoII mono(terpyridine) complex 413 dextran 0 0 – [Co(btp)3](ClO4)2 (btp: 4,4 -di(tert-butyl)-2,2 - – terpyridine-functionalized 450 bipyridine) 234 di(hexadecyl)phosphate (DHP) 216 2þ – [Co(tpy)2] 479 2,6-di(quinolin-8-yl)pyridine 54 2þ 0 0 00 0 – [Co(tpy-vinyl)2] 479 dialkyl 2,2 :6 ,2 -terpyridine-4 - –CoII-containing grid 159 phosphonate 27 – grid 163ff. diazo-bis(terpyridine) 104 – homoleptic (alkyl)thiol-functionalized CoII diblock copolymer 286f., 303 bis(terpyridine) complex 415 – A-[M]-A 294 – infinite 2D grid-like – A-[M]-B 272, 294ff. structure 164 –B-b-A-tpy 286 – thiol-functionalized CoII bis(terpyridine) – B-[M]-B 294 complex 412 – PEG-[Ru]-PS 297 competitive fluorescence spectroscopy dihydride mechanism 468f. (CFS) 324 1,4-dihydropyridine (DHP) 487 container transportation system 451 6,600-dimethyl-2,20:60,200-terpyridine coordination polymer 203 15, 28 – terpyridine-based 215 5,500-dinitro-2,20:60,200-terpyridine 16 copper 174f. dinuclear complex 94ff. – CCAAC 25, 52f., 406, 472 – bicyclo[2.2.2]octane bridge 97 –CuII bis(terpyridine) complex 367ff. – N-heteroaromatic groups in the spacer 99 –CuII complex 366 – heterometallic 91 –CuI ion 178ff. – strapped biphenyl 97 –CuII ion 177ff., 244, 292, 366ff., 380 dinuclear rack 157 –CuII mono(terpyridine) 367ff. 2,9-diphenyl-1,10-phenanthroline (dpp) 379 2þ – [Cu(bpy)(H2O)] 369 1,1-diphenylethylene 463 þ – [Cu(bpy)(tpy)]2 172 2,9-diphenylphenanthroline 177 þ – [Cu(BTB)Fe(BTB)Cu]4 173 40-(diphenylphosphino)-2,20:60,200- þ – [Cu(bzimpy)] 367 terpyridine 27 þ – [Cu(bzimpy)Cl] 367 dipyrido[3,2-a:20,30-c]phenazine (dppz) 335 – [Cu(pty)Cl]Cl 367 40-(2,3-disubstituted 2H-azirin-2-yl)-2,20:60,200- 2þ – [Cu(tpy)(H2O)] 369 terpyridine 25 – polymer-bound CuI mono(terpyridine) dithienylethene (DTE) 43 complex 472 – photochromic 43 cross-coupling procedures 18ff DNA CRP (controlled radical polymerization) – A-[Fe]-B0 (A/A0, and B/B0 represent 244, 281 complementary strands) 378 current imaging tunnelling spectroscopy – A-[Ru]-A 378 (CITS) 168 – B-[Fe]-C0 (B/B0, and C/C0 represent cyclodextrin 182ff. complementary strands) 378 cyclodextrin-complex – B-[Ru]-B 378 – homoleptic 182 – C-[Fe]-A0 (A/A0, and C/C0 represent cyclometalation 113 complementary strands) 378 cyclopropanation – damage 350f. – asymmetric 461 – double helix 327ff. cyclosexipyridine 143 – double-strand break (DSB) 350 cytochrome c protein 384 – G-quadruplex 331f. cytotoxicity 341f., 361, 373 – ODN DNA duplex 377

BINDEX 27 J l 2011 9 29 9 512 | Index DNA (continued) –FeII bis(terpyridine) complex 180f., 380, – oxidative cleavage 350f., 375 423, 464f. – single-strand break (SSB) 350 –FeII bis(terpyridine) unit 278 – topology 327 –FeII bis(terpyridine)-PEtOx complex 278 DNA binding 350ff. –FeII mono(terpyridine) complex 468 DNA diblock copolymer 378 –FeIII mono(terpyridine) complex 472ff. DNA intercalation 320ff. –FeII tris(bipyridine) complex –PtII mono(terpyridine) complex 244, 279 321ff. – [Fe(tpy)2](FeCl4)2 475 DNA intercalator 320ff. –Fe3O4@Au-tpy nanoparticle 425 dodecahydro-19,20,21,22,23,24- – grid 163ff. hexaazakekulene 144 – homoleptic FeII bis(terpyridine) donor–[Ir(tpy)2]–acceptor array 112 complex 464 double-cross-shaped structure 170 – metallopolymer 222, 265 dye-sensitized solar cell (DSSC) 233f., – polymer-bound FeIII mono(terpyridine) 431ff., 497 complex 472 dysprosium ferrocene –DyIII ion 252 – functionalized 370 ferrocenium cation 370 e ferrocifen 369 electron hopping mechanism 409 flanking region (FL) 353 electron/proton-transfer (EPT) 488 Fremy’s salt (FS, potassium electroreduction 480 nitrosodisulfonate) 212ff. –CO2 480 FTO (fluorine-doped tin oxide) 443, 497 – oxygen 480 40-(furan-2-yl)- 2,20:60,200-terpyridine 40 energy and charge transfer 143 fused terpyridines 155 epoxidation 464f. – asymmetric epoxidation of styrene g derivative 465 gel (metallo-supramolecular) 248 meso-epoxide 472 giant amphiphiles 381 ethidium bromide (EthBr) 324 b-1,3-glucan 451 40-ethynyl-2,20:60,200-terpyridine 31f., 135 glutathione (GSH, Glu-Cys-Gly europium tripeptide) 339ff. –EuIII 269 gold, see Au –EuIII chelate 387f. graft copolymer 255, 289 –EuIII ion 182, 251f. graft-on-graft architecture 291 excited-state energy relaxation grid 154ff. diagram 143 – grid of grids arrangement 164 – grid-like architecture 156 f – grid-like array 155 Fe [2 2] grid 158ff. – A-[Fe]-B0 (A/A0, and B/B0 represent – chiral heterobimetallic 162 complementary DNA strands) 378 – double-T shaped 170f. – B-[Fe]-C0 (B/B0, and C/C0 represent – with periphal H-acceptor groups 164 complementary DNA strands) 378 – with periphal H-donor groups 164 – bio-inspired [FeFe]-hydrogenase [4 4] grid 170f. moiety 484 guanine-cytosine (G-C) DNA base pair 329 – C-[Fe]-A0 (A/A0, and C/C0 represent complementary DNA strands) 378 h – dinuclear FeII complex 464 halfgrid 156 –FeII catalyst 469 head-to-head helicate 173 –FeII complex 373, 464 Heck cross-coupling reaction 44 –FeII ion 181f., 220, 244, 267ff., 292, HEEDTA (sodium salt of N-(hydroxyethyl) 378, 403 ethylenediamine triacetic acid) 292

BINDEX 27 J l 2011 9 29 9 Index | 513 helicate 171 iron regulatory element (IRE) 352 – dinuclear double helicate 181 IRP (iron regulatory protein) 353f. – heteroduplex 175 isoprene 475 40-heteroaryl-2,20:60,200-terpyridine 38ff. Irving-Williams series 67 heteroditopic ligand 50 heterometallo-macrocycle 137f. j HETPHEN (heteroleptic phenanthroline) Jameson’s protocol 14 complexation approach 148 HETTAP (heteroleptic terpyridine and k phenanthroline) complexation concept 148 Kro¨hnke condensation 14f., 40 hexaazakekulene 143 – variant 17 hexakis(terpyridine) 152 Kro¨hnke-motif 4 – star-shaped 38 Kro¨hnke-type mono(terpyridine) 39 HgII ion 365 Kro¨hnke-type 2,20:60,200-terpyridine 38, 82 highly ordered pyrolytic graphite – non-planar 41, 82 (HOPG) 416ff. – planar (pyrimidin-2-yl)-substituted 82 homopolymer – A-[M]-A 272, 291ff. l – metallo-supramolecular 294 L-lactide 279 – supramolecular 291 lactoferrin (LF) 405 – tpy-TIPNO 285 labeling Horner–Wadsworth–Emmons (HWE) – biomolecule 388 condensation 41ff. lanthanide(III) hydrosilylation –LnIII chelate 388 – metal-catalyzed 463 –LnIII mono(terpyridine) complex 387 40-(4-hydroxyphenyl)-2,20:60,200- –LnIII-PtII mixed-metal trinuclear terpyridine 448, 472 complex 337 – metal ion 336 i layer-by-layer (LBL) self-assembly 429f. ibuprofen Leishmania parasite 346f. – regioselective oxidation 474 LiI cation 436 initiation ligand-to-ligand charge-transfer (LLCT) 113 – ionic polymerization reaction 277 light absorption sensitizer (LAS) 482 initiator light-driven hydrogen formation 483 – functional terpyridine-containing 277 light-induced excited-state spin-trapping intercalation 320ff. (LIESST) 143 –PtII mono(terpyridine) complex 321ff. lower critical solution temperature interfacial electron transfer (IET) 446 (LCST) 293f. intra-ligand charge-transfer (3ILCT) state 85 ionic liquid 423 m 2þ ionochromism 258 [M(tpy)2] 292f. IrIII bis-complex macrocycle 181 – mono-cyclometalated 114 – shape-persistent metal-free hexagonal 143 IrIII bis(terpyridine) complex 107ff., 185, 383 [2þ2]-macrocycle 133 – metallopolymer 252 – heterometallic 132 IrIII complex [3þ3]-macrocycle – bis-cyclometalated 484 – homo- and heterometallic triangular 136 – terpyridine ligand 107 macroligand 281 IrIII mono(terpyridine) complex 364, 470ff. – ditopic 272 IrIII-PtII mixed–metal dinuclear complex 337 – monotopic 272ff. IrIII-RuII complex 100f., 111 – monotopic terpyridine-functionalized 274 3þ [Ir(tpy-mes)2] (mes: 2,4,6- manganese, see Mn trimethylphenyl) 108 maximum coordination site occupancy iron, see Fe – deviation 169

BINDEX 27 J l 2011 9 29 9 514 | Index melamine formaldehyde (MF) particle 215 – type 201 metal-to-ligand coordination 1 –ZnII ion 208ff. metallo-dendritic architecture 24 methoxy-poly(tetrahydrofuran) metallo-intercalator 324ff. (MPTHF) 273 – mono(terpyridine) d8 metal complex 320 methyl methacrylate (MMA) 247 metallo-macrocycle – RAFT polymerization 247 – hexameric 141 9-methylanthracene (9-MA) 146 – hexameric dodecanuclear 146 micellar gel 308 – mononuclear 131 micelle 297ff. – oxidized single-wall carbon nanotube – core–shell–corona 305 t (oxi-SWNT) 140ff. –PS47-b-P BA55-[Fe]-PEO125 307 t – terpyridine-containing 130 –PS47-b-P BA55-tpy 307 t – trinuclear hexagonal metallo-macrocycle –PS80-b-P BA200-tpy 307 containing FeII ions 143 microbead 449 [6þ6]-metallo-macrocycle 136 – terpyridine-functionalized 3D metallo-network 219 TentaGelTM 449 metallo-semiconducting material 282 3MLCT (metal-to-ligand charge-transfer) metallo-supramolecular architecture 272 excited-state 76ff., 481 – helical 171 – lifetime 76f. – self-assembly 166 3MMLCT 485 – terpyridine complex 129ff. MMLCT absorption 117 metallo-supramolecular assembly Mn – bicyclic 184 – complex 492 m III IV metallo-supramolecular brush – dinuclear -(O)2-bridged Mn /Mn mono – amphiphilic 302 (terpyridine) catalyst 473 metallo-supramolecular homopolymer 294 –Mn4 161 metallo-supramolecular material –Mn12 161 III IV – self-assembly of bis(terpyridine) 266 –Mn (O)2Mn 500 IV IV metallo-supramolecular micelle 298 –Mn (O)2Mn 500 III m IV metallo-supramolecular polyelectrolyte – [(ptpy)(H2O)Mn ( -O)2Mn (H2O) þ (MEPE) 212 (ptpy)]3 473 m 3þ metallo-supramolecular polymer 22 – [(tpy)(H2O)Mn( -O)2Mn(H2O)(tpy)] – mononuclear 291 492 metallo-supramolecular polymerization 200 MnII complex metallo-supramolecular triblock – dinuclear 470 copolymer 267 – dioxygen-bridged dinuclear 464 metallo-supramolecular zipper 187 – mononuclear 499 metallomonomer 221 MnII mono(terpyridine) complex 445ff., metallopolymer 201ff., 219ff. 464ff., 499 – amido- and imido-linkages 226 modified methylalumoxane (MMAO) –CdII ion 208 475 – chiral 219ff. molecular monolayer memory (MMM) – color 224, 251 device 413f. –FeII ion 222 molecular monolayer non-volatile memory –IrIII bis(terpyridine) complexes in the device (MMNVM) 413f. side-chain 252 molecular motion – non-classical 220 – oxidation-induced 178 – p-conjugated bis(terpyridine) 204 molecular switch 178 – polydisperse BIP-type ligand 224 molecular wire-type behavior 157 –RuII ion 206 mono(terpyridine) – self-assembly 212 – aldehyde-functionalized 45f. – synthesis 202, 213ff., 225f., 264 – amine-bridged 25 – terpyridine-functionalized p-conjugated – ethynyl-functionalized 33 polymer 229 – nonlinear optical behavior 46

BINDEX 27 J l 2011 9 29 9 Index | 515 mono-terpyridine complex 66 – middle-(RuII-complex)-ODN 377 – metallo-intercalator based on mono – ODN DNA duplex 377 (terpyridine) d8 metal complex 320 –30-(RuII-complex)-ODN 377 mono[tris(pyridin-2-yl)triazine] (tptz) –50-(RuII-complex)-ODN 377 complex 356 –RuII-labeled ODN-conjugate 377 monocyclometalated species 113 organic light-emitting diode (OLED) monocyclometalating tridentate ligand 113 140ff., 200, 257 monohydride mechanism 468f. organic solar cell (OSC) 257 multi-ion pair association 142 organopolymeric resin 447 multi-walled carbon nanotube (MWNT) 428f. OsII myosin 451 – grid 163 OsII bis-complex n – thiophene-substituted 229 N^C^N ligand 445 OsII bis(terpyridine) complex 81ff., 411 þ [(N^C^N)Ir(N^N^C)] 115 – anthracene-substituted 86 N^N^N-ligand (tridentate ligand) 339, 445 – heteroleptic 75, 183 þ [(N^N^N)Ir(C^N^C)] 115 – homoleptic 75ff. NafionTM 493f. – synthesis 68ff. þ þ nanocluster –TP -functionalized (TP : 2,4,6- – bis(4-iodophenyl)silane-modified triarylpyridinium) 80 7 II [PW11O37] 431 Os bis(terpyridine) unit nanomaterial – oligonuclear complex 89 – inorganic 420 OsII complex 228, 491 nanoprism 149ff. – monocyclometalated 88 – self-assembly 152 – photophysical property 88 nanostructure 399ff. OsIII mono(terpyridine) complex 68 nBA (n-butyl acrylate) 283f. oxidation neighbor exclusion model 328 – alkene 495 nickel – electrocatalytic 476 – grid 163ff. – molecular terpyridine-based catalysts for –NiII ion 244, 267, 292 water oxidation 488 –NiII mono(terpyridine) complex 472 – photocatalytic 487 2þ – [Ni(tpy)2] connectivity 292 – regioselective oxidation of ibuprofen 474 – [(tpy)Ni(Me)] 471f. oxidation potential 482 NIPAM (N-isopropylacrylamide) 283 oxime nitroxide-mediated polymerization – photocleavage 496 (NMP) 244ff., 285 oxygen norbornene derivative 244 – electroreduction 480 nucleoside 342 – singlet 375, 495f. nucleotide 342 p o palladium oligo(ethylene oxide) methacrylate –PdII mono(terpyridine) complex 340f., 470

(OEGMA475) 291 – [(tpy)Pd(NCMe)](BF4)2 468 oligo(hexylthiophene) (OHT) 231 PCBM ([6,6]-phenyl-C61-methyl butyrate) 206 oligo(phenylene-ethylene) (OPE) PDIm (perylene diimide) 402, 417 – thiol-functionalized 410 PEG (poly(ethylene glycol)) 255, 265ff., 464 oligo(phenylenevinylidene) (OPV) – amino-functionalized PEG75 289 trimer 231 – PDMS-[Ru]-PEG 303 – terpyridine-functionalized 231 – PEB-[Ru]-PEG 303 oligonuclear complex – PEB70-[Ru]-PEG70 303 – V-shaped 106 – PEG-b-PPG-b-PEG 271 – X-shaped 106 – PEG-PDIm terpyridine 417 oligodeoxynucleotide (ODN) 377 – (PEG44-[Ru]-)3 310f.

BINDEX 27 J l 2011 9 29 9 516 | Index 3þ palladium (continued) – [PCD-tpy)Fe(H2O)3] 472 – (PEG44-[Ru]-)4 310f. – terpyridine-functionalized PCD resin 448 – PEG-[Ru]-PS 297 poly(dialkoxyphenylene-thiophene) 260 – PFDS12-[Ru]-PEG70 303f. poly(dialkylfluorene-thiophene) 260 – PPG-b-PEG-b-PPG 271 poly(dimethylsiloxane) (PDMS) 274 –PS22-b-PEG70 298 – PDMS-[Ru]-PEG 303 –PS76-b-PTFMS42-[Ru]-PEG70 306 poly(ethylene glycol), see PEG –PS32-b-P2VP13-[Ru]-PEG70 303 poly(ethylene imine) (PEI) 214, 436 –PS20-[Ru]-PEG70 297ff. – metallo-supramolecular 278 –PSx-[Ru]-PEGy 298ff. poly(ethylene oxide) monomethyl ether t – PTFMS20-b-P BA25-b-PS35-[Ru]-PEG70 306 (MPEG) 272 penta-amine macrocycle poly(ethylene-co-butylene) (PEB) 273 – terpyridine-containing 133 – PEB-[Ru]-PEG 303

pentadentate ligand – PEB70-[Ru]-PEG70 303 – terpyridine-based 30 poly(3,4-ethylenedioxythiophene)–poly 40-(pentafluorophenyl)-2,20:60,200- (styrenesulfonate) (PEDOT:PSS) terpyridine 40 layer 414

PEO125-tpy 307 poly(2-ethyloxazoline) (PEtOx) 3-(phenanthrolin-2-yl)-1,2,4-triazine – hydroxyl-functionalized 274 ligand 358 poly(2-ethyloxazoline)-block-poly 1,10-phenanthroline (phen) 319 (2-phenyloxazoline) 278 phenanthroline-based ligand 177 poly(ferrocenyldimethylsilane) (PFDS) 275 phenanthroline–terpyridine rotaxane 178 – PFDS12-[Ru]-PEG70 303f. 2-phenyl-4,6-bis[6-(pyridin-2-yl)-4-(pyridin-4-yl) poly(N-isopropylacrylamide) pyridin-2-yl]pyrimidine (2,40-BTP) 417 (PNIPAM) 275, 294 40-phenyl-2,20:60,200-terpyridine (ptpy) 39, 473 poly(L-lactide)-macroligand 280 m – [(ptpy)2Mn2( -O)2(H2O)2](ClO4)3 470 poly(methyl methacrylate) (PMMA) 247 40-(4-phenylmethanethiol)-2,20:60,200- poly(n-octylthiophene) 442 terpyridine 421 poly(2-oxazoline)-macroligand 277 photocatalytic process 480 poly(oxytetramethylene) photochemical open–close cycle – a-carboxy-o-terpyridin-40-yl- – reversible 43 functionalized 269 photochromic dithienylethene (DTE) 43 poly(p-phenylenevinylene) (PPV) 261 photocleavage poly(p-phenylenevinylidene)-type (PPV) – oxime 496 polymer 231 photoelectrochemical cell (PEC) 234 – tpy-functionalized 233 – water-splitting 492 poly(propylene glycol) (PPG) 271 photoinduced electron-transfer (PET) 487 poly(styrene sulfonate) (PSS) 214 photosensitized electron transfer process 483 poly(styrene-alt-diphenylethylene) copolymer photovoltaic application 431 – terpyridine-terminated 276 photovoltaic (PV) cell poly(tetrahydrofuran) (PTHF) 271 – bulk-heterojunction 260 poly(p-trifluoromethylstyrene) (PTFMS) 288 photovoltaic device 232 –PS76-b-PTFMS42-[Ru]-PEG70 306 t photovoltaic quantum yield 439ff. – PTFMS20-b-P BA25-b-PS35-[Ru]-PEG70 306 platinum, see Pt poly(vinyl chloride) (PVC) 256 platinyne-bis(terpyridine) 132 – terpyridine-functionalized 256 PMDETA (N,N,N,N00,N00- poly(2-vinylpyridine) 286 pentamethyldiethylenetriamine) 246, 282, polybutadiene 428, 475 – terpyridine-modified 275 poly(acrylic acid) (PAA) 287, 436 polybutadiene-block-poly(ethylene glycol) 273 –PS120-[Ru]-PAA135 303ff. polyelectrolyte-amphiphile complex poly(e-caprolactone)-macroligand 280ff. (PAC) 216 poly(chloromethylstyrene-codivinylbenzene) polyelectrolyte-surfactant-like complex 253 (PCD) 448, 472 polyimide 227

BINDEX 27 J l 2011 9 29 10 Index | 517 polyisoprene (PI) –IrIII-PtII mixed–metal dinuclear – terpyridine-modified 275, 286 complex 337 polymer –LnIII-PtII mixed-metal trinuclear – a,o-dihydroxy-functionalized 270 complex 337 þ – block copolymer 254 – [Pt(tpy)]2 384 þ – chain-extended polymers from polymeric – [Pt(tpy)(Cl)] 384 2þ building blocks 269 – [(tpy)Pt(H2O)] 385 þ – functional polymers incorporating – [(tpy)Pt(His)]2 complex 384 terpyridine-metal complexes 241ff. PtII mono(terpyridine) complex 66, 115ff., – metal ions/complexes 201 321ff., 333ff., 348, 383ff., 486ff. – p-conjugated 199ff., 257ff. – antitumor agent 343 – terpyridine metal complex 199ff. – azido-functionalized dinuclear 385 – terpyridine units in the side-chain 242 – carborane-containing 346 – terpyridine within the polymer – dinuclear 119, 334ff. backbone 262 – DNA intercalation 321ff. – terpyridine-functionalized 259 – dyad 120 polymer light-emitting diode – estrogen-modified 386 (PLED) 199, 257 – glycosylated 330, 349 polymer light-emitting device (PLED) – labeling 385 – supramolecular 206 – luminescent 116 polymer solar cell (PSC) 206 – mononuclear 345f. polymerization 243ff. – pH-responsive 118 – anionic 276 – polymer-bound 496 – complex first method 224 – silica-bound 496 – ionic 277 – styrene functionalized 496 – radical 281 – triad 120 þ – RAFT (reversible addition-fragmentation [Pt(tpy)Cl] 484f. þ chain-transfer) 244ff. [Pt(ttpy)Cl] 487 – transition metal ion coordination 204 40-(pyridin-4-yl)- 2,20:60,200-terpyridine 133 polyoxometalate (POM) 430 60-(200-pyridyl)dipyrido[3,2-a:20,30-c]phenazine polystyrene (PS) (dppzp) 360 – latex particle 215 40-(pyrimidin-2-yl)-2,20:60,200-terpyridine 81 – PEG-[Ru]-PS 297 – planar 41 – polystyrene-block-poly(2-vinylpyridine) 10-(1H-pyrrol-1-yl)decane-1-thiol 421 273 t –PS47-b-P BA55-[Fe]-PEO125 307 q t –PS47-b-P BA55-tpy 307 quenching 481 t –PS80-b-P BA200-tpy 307f. quinquepyridine 187ff. 0 0 00 00 000 000 0000 –PS22-b-PEG70 298 2,2 :6 ,2 :6 ,2 :6 ,2 -quinquepyridine 172 –PS76-b-PTFMS42-[Ru]-PEG70 306 – ligand 373 0 0 00 00 000 –PS32-b-P2VP13-[Ru]-PEG70 303 – 2,2 :6 ,2 :6 ,2 -quaterpyridine 172, 176 –PS120-[Ru]-PAA135 303ff. –PS20-[Ru]-PEG70 297ff. r –PSx-[Ru]-PEGy 298ff. rack 154 t – PTFMS20-b-P BA25-b-PS35-[Ru]-PEG70 306 – anthracene-containing 157 post-polymerization functionalization – rack-type architecture 156 250ff., 288 radiotherapeutic agent 350 Potts’ methodology 14f. RAFT (reversible addition-fragmentation protecting group approach 406 chain-transfer) polymerization 247 proton-coupled electron-transfer (PCET) 488 – methyl methacrylate (MMA) 247 PtII complex – NIPAM 283 þ – cyclometalated [Pt(pbpy)] (pbpy: 6-phenyl- – styrene 283 0 I 2,2 -bipyridine) 410 Re (CO)3 mono(terpyridine) complex 463 – hexanuclear 147 [Re(CO)5]Br 147

BINDEX 27 J l 2011 9 29 10 518 | Index redox system 476, 489 RuII complex reduction – A-[Ru]-A (A, B are complementary DNA

–CO2 479 strands) 378 – electrocatalytic 476 – B-[Ru]-B (A, B are complementary DNA – ketone 469 strands) 378 – water 484 – bis-triazole-pyridine ligand 87 reduction potential 482 – carbene-type ligand 87 resorc[4]arene – diiodo-functionalized 227 – terpyridine-functionalized 187 – dinuclear 363, 493 rhodium – heteroleptic 188, 221, 256, 464 –RhIII complex 364 – monocyclometalated 88, 221, 445f. –RhIII mono(terpyridine) complex – mononuclear 363 462, 479 – neutral 473

– [Rh(COD)Cl]2 (COD: cycloocta-1,5- – photophysical property 88 diene) 463 – pyrrole-functionalized dimeric 498 3þ 0 II – [Rh(phen)2(phi)] (phen: 1,10- –3-(Ru -complex)-ODN 377 phenanthroline; phi: 9,10- –50-(RuII-complex)-ODN 377 þ phenanthrenequinone diimine) 353 – [Ru(tpy)(bpy)]2 410 þ ring-assembly strategy 14 – [(tpy)Ru(L)]2 (L: bpy or phen) 380 k ring-opening metathesis polymerization – trans-[(tpy)Ru( N-NC5H4O)2(H2O)] 469 (ROMP) RuII coordination polymer 207 –RuII-catalyzed 244 RuII ion 182, 269 ring-opening polymerization (ROP) – metallopolymer 206, 212ff., 244 – cationic 278 RuII mono(terpyridine) complex 157, 357, – coordinative 279 444, 462ff. Risch’s methodology 17 RuIII mono(terpyridine) complex 68, 439 rotaxane 177f. RuII mono(tptz) complex 357 Ru () complex RuII oligopyridinyl complex 372 4þ II – {O[Ru(H2O)2(tpy-PO(OH)2)]2} [tpy-PO Ru polyimide 227 0 0 00 0 II (OH)2: 2,2 :6 ,2 -terpyridin-4 -yl- Ru tris(bipyridine) complex 184, 279, 484 phosphonic acid] 497 RuII tris-thiocyanato complex 261 3þ III – [(tpy)(H2O)Ru(dpp)Ru(H2O)(tpy)] 499 Ru tris-thiocyanato complex 438 RuII 292 RuII ZnII-porphyrin complex – grid 163 – tetranuclear 444 RuII bis(terpyridine) complex 36, 78ff., 137, RuII-IrIII array 186 180ff., 254, 371ff., 411ff., 428, RuII-OsII array 186 440ff., 484f. RuII-OsII dyad 185 – anthracene-substituted 86 RuIII/RuII coordination chemistry – dendritic, oligonuclear 445 – selective 255 – dinuclear 95ff. RuII/RuIII redox system 476, 478, 489 – dithiol-functionalized 420 RuIII/RuIV redox system 476, 489 – DNA intercalation 335 RuIV/RuIII redox system 478 – heteroleptic 73, 420, 438 RuVI/RuIV redox system 478 – homoleptic 74ff., 357ff., 438 RuIII-terpyridine monocomplex 244 – monomeric 428 RuIIIORuIII 489 – mononuclear 76 RuIVORuIII 489 – photophysical property 75ff. RuIVORuIV 489f. V V – synthesis 73f. Ru ORu 490Ru(acetone)6](BF4)3 219 þ þ 2þ –TP -functionalized (TP : 2,4,6- [Ru(bpy)3] 424, 483f. 2þ triarylpyridinium) 80 cis-[Ru(bpy)2(py)(H2O)] 488 II 2þ Ru bis(terpyridine) unit [Ru(bpy)2(py)(O)] 488 1.5 0 – dendritic system 102 [Ru2(btpyan) (qu ¯)(O2¯)] [btpyan: 1,8-bis – oligonuclear complex 89 (2,20:60,200-terpyridin-4-yl)anthracene; qu: – star-shaped system 102 quinoline] 492

BINDEX 27 J l 2011 9 29 10 Index | 519

[Ru(p-cymene)Cl2]2 473 – supramolecular polymer 253 Ru(dmso)4Cl2 177 – terpyridine functionalized Au 0 0 cis-RuL2(NCS)2 (L: 2,2 -bipyridyl-4,4 - nanoparticle 423 dicarboxylic acid) 432 – terpyridine-functionalized PMMA 249 0 0 00 [RuL(NCS)3](n-Bu4N)3 (L: 2,2 :6 ,2 - self-healing material 288 terpyridyl-4,40400-tricarboxylate) 432 semi-self-assembly approach 137 [RuO]IV complex 351ff. sensitizer 445 [RuO]IV mono(terpyridine) complex 351 –RuII-based 433ff. [Ru(OH)]III complex 354 –RuIII-containing 441 [Ru(tptz)Cl2(PPh3)] 357 septipyridine 2þ [Ru(tpy)2] 181, 227, 255, 292ff. – disubstituted 173 [Ru(tpy)2](BPh4)2 unit 298 – redox-switching of the self-assembly [Ru(tpy)Cl3] 471 process 174 [Ru(tpy)(dmbpy)Cl] (dmbpy: 4,40-dimethyl- 2,20:60,200:600,2000:6000,20000:60000,200000- 2,20-bipyridine) 256 sexipyridine 172 [Ru2(tpy)2](PF6)4 157 Sierpin´ski hexagonal gasket 138f. [Ru3(tpy)3](PF6)6 157 silver, see Ag ruthenium polymer 206 single-molecule magnet (SMM) 161 – A-[Ru]-B 296 single-walled carbon nanotube – A-[Ru]-B-[Ru]-A triblock copolymer 309 (SWNT) 427f., 451 – PDMS-[Ru]-PEG 303 SnO2 – PEB-[Ru]-PEG 303 – nanocrystalline 442 – PEB70-[Ru]-PEG70 303 Sonogashira cross-coupling approach 35f. – (PEG44-[Ru]-)3 310f. – iterative 34 – (PEG44-[Ru]-)4 310f. spiro-metallodendrimer 133f. – PEG-[Ru]-PS 297 spoke set with rim elements 152ff. – PFDS12-[Ru]-PEG70 303f. spoked wheel-type architecture 152ff. –PS76-b-PTFMS42-[Ru]-PEG70 306 steroid a –PS120-[Ru]-PAA135 303ff. – -unsaturated 465 –PS20-[Ru]-PEG70 297ff. structure-within-structure morphology 253 –PSx-[Ru]-PEGy 298ff. styrene 283f. t – PTFMS20-b-P BA25-b-PS35-[Ru]-PEG70 306 – asymmetric epoxidation of styrene derivative 465 s – aziridination 466 Sauer methodology 16 – fluorinated derivative 286 scandium – para-substituted 466 – chiral ScIII mono(terpyridine) complex 472 40-(4-styryl)-2,20:60,200-terpyridine 243 schizophyllan 451 sulfanylbenzene 402 – terpyridine-modified (tpy-SPG) 451 40-(4-sulfanylphenyl)-2,20:60,200- scorpionate-complex 189 terpyridine 402 self-assembled monolayer (SAM) 401ff., 419 11-sulfanylundecan-1-ol matrix 405 self-assembly 152ff. superoxide radical 367 – bis(terpyridine) 266 superpolystyrene 276 – chiral heterobimetallic [2 2] grid 162 supramolecular gel 260 – directional 173 – reversible self-assembly of terpyridine- –FeII ion 378 functionalized PMMA 249 – hierarchical 215, 253 supramolecular protecting group – metallo-supramolecular architecture 166 chemistry 406 – metallo-supramolecular material 266 Suzuki–Miyaura cross-coupling – metallopolymer 212ff. reaction 42ff. – reversible redox-state-dependent switching of sexipyridine 175 t – redox-switching of septipyridine 174 tamoxifen – step-wise 296, 404 – ferrocene-substituted 369

BINDEX 27 J l 2011 9 29 10 520 | Index 3þ TBT (terpyridine–bipyridine– – [(tpy)(H2O)Ru(dpp)Ru(H2O)(tpy)] 497 þ terpyridine) 173 – [(tpy)Ir(C^N^C)] 113ff. þ terbium – [(tpy)Ir(N^C^N)]2 113 þ –TbIII ion 251f. – [(tpy)Ir(N^N^C)]2 113 þ terpolymer – [(tpy)Ir(tpy-R)]3 (R:biphenyl) 110 þ – random 250 – [tpy-M-tpy0]2 complex 262 2,20:60,200-terpyridin-40-yl triflate 135 – tpy-nBA-b-PS-b-nBA-tpy (nBA: n-butyl 2,20:60,200-terpyridin-40-yl-carboxylic acid 40 acrylate) 283 2þ terpyridine 2ff., 426 – [(tpy)(phen)Ru(H2O)] 478 – acrylate-functionalized monomer 20 – tpy-PNIPAM 294 – alkoxy-substituted 416 – tpy-PPFS30-g-AP7-b-PS73-TIPNO 291 0 –4-alkyl-functionalized 27 – tpy-PPFS30-g-AP[(OEGMA475)10]7-b-PS73- – amino-functionalized 410 TIPNO 291

– anchoring 407 – tpy-PPFS30-g-AP(PLA11)9-TIPNO 291 – biotin-modified 383 – tpy-PPFS30-g-AP9-TIPNO 291 – catalytic application 459ff. – tpy-PPFS30-g-(PEG75)10-TIPNO 289 – chiral 460 – tpy-PS-b-nBA-b-PS-tpy 283

– dialkenyl-functionalized 183 – tpy-PS35-b-PMA54-b-PPFS97-TIPNO 288 – disulfide-functionalized 425 – tpy-PS35-b-PMA54-PTFMS20-TIPNO 288 – dithienylethene-bridged 43 – tpy-PS50-b-PPFS80-TIPNO 286 – ferrocene-functionalized 419 – tpy-PS50-b-PTFMS34-TIPNO 286 – fullerene-functionalized 21 – tpy-PS160-TIPNO 287 –40-functionalized 4, 27 – tpy-PS-TIPNO 288 – fused 155 – tpy-PSn-TIPNO-UPy 288 2þ 2þ – [(H2O3P-tpy)Ru(O)2(H2O)] 478 – [(tpy)Pt(H2O)] 385 þ – inorganic nanomaterial 420 – [(tpy)Pt(His)]2 complex 384 – liquid crystalline (LC) behaviour 29f. – tpy-PTFMS42-TIPNO 287 – macrocyclic terpyridine 135 – tpy-PTFMS42-b-PS76-TIPNO 287 2þ 0 – methacrylate-functionalized monomer 20 – [(tpy)Ru(bpy)(H2O)] (bpy: 2,2 - – molecular terpyridine-based catalyst for bipyridine) 351 þ water oxidation 488 – [(tpy)Ru(bpy)(L)]2 complex (L: labile – nano-structured TiO2 431 ligand) 355 0 –4-nitro-functionalized 25 – [(tpy)Ru(bpy)(L)](PF6)2 355 2- 2þ – {O[Ru(C2O4)(tpy)]2(H2O)8}(C2O4 : – [(tpy)Ru(bpy)(O)] 353f. þ oxalate) 489 – [(tpy)Ru(bpy)(OH)]2 354 t 2þ –PS47-b-P BA55-tpy 307 – [(tpy)Ru(bpy)] –protein adduct 355 t –PS80-b-P BA200-tpy 307f. – mer-(tpy)RuCl3 361 þ – rigid U-shaped 4, 49 – [(tpy)Ru(dppene)Cl] (dppene: cis-l,2-bis þ – [(40-R-tpy)PtCl] 116 (diphenylphosphino)ethylene) 479 þ – S-shaped 49 – [(tpy)Ru(dppz-COOH)(MeCN)]2 376 2þ – serino-functionalized 378 – [(tpy)Ru(dppz)(H2O)] 351 2þ – star-shaped 104 – [(tpy)Ru(dppz–ODN)(H2O)] 377 þ – terthiophene-functionalized 23 – [(tpy)Ru(L)]2 (L: bpy or phen) 380

– tetraacid-functionalized 29 – [(tpy)Ru(PPh3)Cl2] 470 – thioalkyl-functionalized 420 – [(tpy)Ru(pydic)] (pydic: pyridine-2,6- – thiol-functionalized 424 dicarboxylate) 463ff. – TIPNO-functionalized (tpy-TIPNO, TIPNO: – 4,40,400-tri(tert-butyl)-substituted 475 2,2,5-trimethyl-4-phenyl-3-azahexane –(1H-1,2,3-triazol-1-yl)-substituted 25 nitroxide) 22f., 284 2,20:60,20-terpyridine 2þ 0 – [(tpy)(bpy)Ru(H2O)] 477 –4-(hetero)aryl-substituted 364 2þ 0 0 00 – [(tpy)(bpy)Ru(H2O)] /[(tpy)(bpy) 2,2 :6 ,2 -terpyridine (tpy) 2, 216, 358 þ RuO]2 476 – five-membered N-heterocycles replacing the þ – [(tpy)(bpy)RuO]2 477 outer pyridine rings 51 3þ 0 – [(tpy)(H2O)Mn(O)2Mn(H2O)(tpy)] 492 –4-functionalized 27

BINDEX 27 J l 2011 9 29 10 Index | 521 – synthesis 13ff. TIPNO (2,2,5-trimethyl-4-phenyl-3-azahexane – symmetrically substituted on the outer nitroxide) 284, 296

pyridine rings 28 – TIPNO-PS240-[M(dmf)3Cl2] 295 – vinyl-functionalized 243 – TIPNO-PS240-[M]-PEG230 295 2,20:60,300-terpyridine 364 TMPO (2,2,6,6-tetramethlypiperidine 2,20:60,400-terpyridine 364 N-oxide) 494 terpyridine complex 411 40-tolyl-2,20:60,200-terpyridine (ttpy) 8 –d late transition metal ion 320 – [(ttpy)Mn(H2O)O]2 464 þ – heavy d6 transition metal ion 350 – [(ttpy)Ru(tppz)IrCl]2 91 2þ – transition metal ion 364, 459ff. – [(ttpy)Ru(tpy-Phn-typ)] 91 4þ terpyridine derivative 19ff. – [(ttpy)Ru(tpy-Phn-tpy)Os(ttpy)] 91 5þ – fullerene-substituted 427 – [(ttpy)Ru(tpy-Phn-tpy)Rh(ttpy)] 91 – hydroxyl-functionalized 279 tpy, see terpyridine – liquid crystalline (LC) behaviour 29f. trefoil knot 182 –40-substituted 24 4,40,400-tri(tert-butyl)-2,20:60,200- – symmetrical and unsymmetrical ditopic 51 terpyridine 466 terpyridine ligand tri-N-oxide 460 –40-(boronate ester)-substituted 27 triad – chiral 460 – porphyrin-containing 92 – star-shaped 105 1,3,4-triaryldihydropyrrole 487 – tri- and tetratopic 169 triblock copolymer 283, 303 terpyridine macroligand – A-[M]-B-[M]-A 272 – monotopic 272 – A-[Ru]-B-[Ru]-A 309 terpyridine metal complex 319ff. – coil-rod-coil 309f. – biological activity 320 – metallo-supramolecular 267 – functional polymer 241ff. tridentate ligand – p-conjugated polymer 199ff. – bis-cyclometalating 113 terpyridine rotaxane 180 –C^N^N (mono-cyclometalating tridentate terpyridine transition metal ion ligand) 445 complex 65ff. – expanded bite angle 53 – catalytic application 459ff. – monocyclometalating 113 – basic synthetic strategy 66ff. – multitopic hydrazone-based 158 – binding enthalpy 67 –N^N^N-ligand 339, 445 – characterization tool 66ff. – phenanthroline-based ditopic 159 – stability constant 67 trinuclear complex 94ff. terpyridine-calixarenes 186 – heterometallic 92 terpyridine-cyclodextrin 185 – mixed-metal RuII–IrIII 100f. terpyridinophane macroligand 134 – strapped biphenyl 97 s tetrabutylammonium Oxone 464 tris(phenanthroline) 149 tetrakis(2,20:60,200-terpyridin-40-oxymethyl) tris(pyridine) 151 methane 105 2,4,6-tris(pyrimidin-2-yl)-1,3,5-triazine 171 tetrakis(terpyridine) 46, 310 1,3,5-tris(2,20:60,200-terpyridin-40-yl) – amine-bridged 25 benzene 39 tetrakis(terpyridine)-porphyrin 445 1,4,7-tris[(2,20:60,200-terpyridin-5-yl)methyl]- thermochromism 251 1,4,7-triazanonane 131 thieno[3,4-b]pyrazine-bridged bis tris(terpyridine) 46, 104, 151, 310, 409 (terpyridine) 47 – amine-bridged 25 40-(thiophen-5-yl-2-phosphonic acid) 442 – star-shaped 38 Thummel’s methodology 17 trithiocyanato RuII terpyridine complex 260 tin, see Sn tritopic ligand 169 TiO2 431ff., 447 – star-shaped 172 – dye-sensitized nanoparticle 443 ttpy, see 40-tolyl-2,20:60,200-terpyridine – nano-structured 431 Typanosoma parasite 346f.

BINDEX 27 J l 2011 9 29 10 522 | Index u z ureido-pyrimidinone (UPy) moiety 280 Ziessel-type bis(terpyridine) – dithieno[3,2-b:20,30-d]phosphole- v containing 35 vanadium – fluorene-containing 35 V – [VO(O2)2] complex 375 Ziessel-type mono(terpyridine) 37 V – [VO(O2)2] mono(terpyridine) complex Ziessel-type terpyridine 4 375 Ziessel-type 2,20:60,200-terpyridine 31 þ – [VO(O2)2(tpy)] complex 375 zinc þ p II – [VO(O2)2(tpy)(H2O)] 375 – -conjugated Zn coordination polymer 209 40-vinyl-2,20:60,200-terpyridine 242 –ZnIIion 248, 292 vinylbenzamide monomer –ZnII bis(terpyridine) complex 366, 406 – polymerization 246 –ZnII coordination polymer 207 viologen-like structure 219 –ZnII copolymer 209 vitamin H 381 –ZnII metallopolymer 210 Volmer–Weber growth mode 419 –ZnII mono(terpyridine) complex 366, 422 –ZnII-bis(terpyridine) coordination w polymer 208 water – {[Zn(bis(terpyridine))](PF6)2n} 208 – oxidation 488 –ZnII-porphyrin-bis(terpyridine) 151 – reduction 484 zirconium white light-emitting diode (WOLED) 252 – anchoring of terpyridine to a ZrIV Wittig condensation 41ff. phosphate monolayer 407

BINDEX 27 J l 2011 9 29 10