| 509 Index a BIP (2,6-bis(1-methyl-1H-benzo[d]imidazol- 40-[4-(2-acryloyloxyethoxy)phenyl]-2,20:60,200- 2-yl)pyridine) 205 terpyridine 243 – 4-ethynyl functionalized 52 actin filament (F-actin) 451 – ditopic 52, 205, 268 AgI complex – metallopolymer 224 – dinuclear 467 – polydisperse 224 alcohol cross-coupling 470 2,20-bipyrazine (bpz) ligand 491 aldol-type condensation 468ff. 2,20-bipyridine (bpy) 2, 282, 475 2þ allylation reaction 460ff. – cis-[(bpy)2(py)Ru(H2O)] 476 2þ allylic substitution reaction 463 – cis-[(bpy)2(py)RuO] 477 amidation bipyridine-cyclodextrin 186 – intramolecular 466 2,20-bipyrimidine (bpm) 491 aminolysis 6,600-bis(aminomethyl)-40-phenyl-2,20:60,200- – asymmetric 472 terpyridine chelating unit 387 40-(4-aminophenyl)-2,20:60,200-terpyridine 410 2,6-bis(benzimidazol-2-yl)pyridine antitumor agent 341ff. (bzimpy) 366 40-aryl-2,20:60,200-terpyridine 38ff. 1,4-bis[2,6-bis(1-butyl-1H-1,2,3-triazol-4-yl) atom-transfer radical polymerization pyridin-4-yl]benzene (BTP-type) 219 (ATRP) 244ff., 282 bis-cyclometalating tridentate ligand 113 –CuI-catalyzed 475 1,4-bis[2,6-di(1H-pyrazol-1-yl)pyridin-4-yl] Au nanoparticle 421f. benzene (BPP-type) 219 – terpyridine ligand 422 2,6-bis(5,6-dihydro-4H-1,3-oxazin-2-yl) Au surface 402ff. pyridine 463 – terpyridine-modified 408f. 2,6-bis(4,5-dihydrooxazol-2-yl)pyridine 463 AuIII mono(terpyridine) complex 333, 5,500-bis(hydroxymethyl)-2,20:60,200- 349, 386 terpyridine 256 40-azido-2,20:60,200-terpyridine 25f. bis-intercalator 334 aziridination 466f. 2,6-bis(1-methyl-1H-benzo[d]imidazol-2-yl) azurin 380 pyridin-4-ol (BIP-OH) 51 2,6-bis(1-methyl-1H-benzo[d]imidazol-2-yl) b pyridine, see BIP para-benzoquinone 477 bis(phenanthroline) 150ff. BINOL (1,10-binaphth-2-ol) 107 3,6-bis(pyridin-2-yl)pyridazine ligand – BINOL-type bis(terpyridine) 220 158 biolabeling 376 2,6-bis(pyridin-2-yl)-4-pyridone 284 biomolecule 1,5-bis(pyridin-2-yl)triazine 83 – covalent binding to small-molecule 338 bis-rotaxane 179 – labeling 388 1,2-bis(2,20:60,200-terpyridin-40-yl)acetylene 32 biotin moiety 381 bis(2,20:60,200-terpyridin-4-yl)amine 25 Terpyridine-based Materials: For Catalytic, Optoelectronic and Life Science Applications, First Edition. Ulrich S. Schubert, Andreas Winter, and George R. Newkome. r 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Published 2011 by WILEY-VCH Verlag GmbH & Co. KGaA BINDEX 27 J l 2011 9 29 9 510 | Index 1,4-bis(2,20:60,200-terpyridin-40-yl)benzene block copolymer 42 – A-[M]-(B-[M]-)nB-[M]-A type 308 (E)-1,2-bis(terpyridin-4-yl)diazene 25 – dinuclear A-[M]-B-[M]-A 309 1,4-bis[(2,20:60,200-terpyridin-5-yl) – oligonuclear metallo-supramolecular 308 methylsulfanyl]butane 130 blue dimer 489ff. 1,3-bis[(2,20:60,200-terpyridin-5-yl) BODIPY (boron-dipyrromethene) 209 methylsulfanyl]propane 130 boron neutron capture therapy (BNCT) 330 bis(terpyridine) 42ff., 149f., 182, 289 Borromean links (Borromean rings) 157, – alkene-functionalized angular 141 181ff. – amine-bridged 25 bpy, see 2,20-bipyridine – angular 136ff. 40-(4-bromomethylphenyl)-2,20:60,200- – BINOL-type 220 terpyridine 450 – boron-dipyrromethane (BODIPY)- 40-(4-bromophenyl)-2,20:60,200-terpyridine 233 bridged 48f. BTB (bipyridine–terpyridine–bipyridine) 173 – dithiol-bridged 130 – BTP-based ligand 52 – electron-acceptor-type p-conjugated – BTB-type ligand 219 spacer 48 n-butyl acrylate (nBA) 283f. – motif 206 1-butyl-3-methylimidazolium – oligophenylene-bridged 212 hexafluorophosphate (bmim-PF6) 423 – oligoyne-bridged 33 – photophysical property 35, 47 c p – -conjugated 47, 204, 309 C60tpy@Pd 426 – piperazine-functionalized 412 C^N^N (mono-cyclometalating tridentate – soluble 34 ligand) 445 þ – step-wise self-assembly 404 [(C^N^N)Ru(N^N^N)] 445 – trans-stilbene-bridged 44 cadmium 174 – telechelic 270 –CdII 292, 365 – thieno[3,4-b]pyrazine-bridged 47 –CdII coordination polymer 208 – viologen-type 133, 220 –CdII mono(terpyridine) complex 425 – X-shaped 37 – [Cd(tpy)F2] 467f. bis(terpyridine) complex cage-like structure 172 – dinuclear 89 calix[4]arene – heteroleptic 185 – derivative 186 – self-assembly 147 – functionalized with four terpyridine bis(terpyridine) ligand 32 ligands 188 – angular 137 e-caprolactone 279 – heteroleptic 68 2-(N-carbazolyl)ethyl methacrylate – homoleptic 68 (CzMA) 256 – multifunctional 131 carbene-insertion 467 – telechelic 224 catalyst in organic reaction – thiophene-containing 98 – asymmetric 460 1,1000-bis(2,20:60,200-terpyridin-4-yl)-1,10- catenane 177, 181 biferrocene 100 – reversible molecular motion 181 3,6-bis(2,20:60,200-terpyridin-40-yl)-9-alkyl- CCAAC (CuI-catalyzed alkyne-azide [2þ3]- carbazole 136 cycloaddition) reaction (“click” 1,4-bis(2,20:60,200-terpyridin-40-yl)benzene reaction) 25, 52f., 406, 472 309 chain-transfer agent (CTA) 283 4,40-bis(2,20:60,200-terpyridin-40-yl) – telechelic 284 triphenylamine 136 chemotherapeutic agent 342 2,6-bis(1H-1,2,3-triazol-4-yl)pyridine 40-chloro-2,20:60,200-terpyridine 264ff. (BTP-type) 52 chromium bis(U-terpyridine) 50f. –CrIII bis(terpyridine) complex 375 black dye 66, 432ff. circular dichroism (CD) effect 320 bleomycin co-dimerization – iron-containing glycopeptide 372 – linear 471 BINDEX 27 J l 2011 9 29 9 Index | 511 cobaloxime complex 486 d cobalt dendrimer –CoII bis(terpyridine) complex 71, – first-generation 105 185, 374, 412ff. dendritic terpyridine architecture 24 –CoIII bis(terpyridine) complex 374 deoxycholic acid (DCA) 436 –CoII ion 244, 267, 292, 374, 403 deoxycytidinyl-(30,50)-deoxyguanosine –CoIII ion 374 (deoxy-CpG) 328 –CoII mono(terpyridine) complex 413 dextran 0 0 – [Co(btp)3](ClO4)2 (btp: 4,4 -di(tert-butyl)-2,2 - – terpyridine-functionalized 450 bipyridine) 234 di(hexadecyl)phosphate (DHP) 216 2þ – [Co(tpy)2] 479 2,6-di(quinolin-8-yl)pyridine 54 2þ 0 0 00 0 – [Co(tpy-vinyl)2] 479 dialkyl 2,2 :6 ,2 -terpyridine-4 - –CoII-containing grid 159 phosphonate 27 – grid 163ff. diazo-bis(terpyridine) 104 – homoleptic (alkyl)thiol-functionalized CoII diblock copolymer 286f., 303 bis(terpyridine) complex 415 – A-[M]-A 294 – infinite 2D grid-like – A-[M]-B 272, 294ff. structure 164 –B-b-A-tpy 286 – thiol-functionalized CoII bis(terpyridine) – B-[M]-B 294 complex 412 – PEG-[Ru]-PS 297 competitive fluorescence spectroscopy dihydride mechanism 468f. (CFS) 324 1,4-dihydropyridine (DHP) 487 container transportation system 451 6,600-dimethyl-2,20:60,200-terpyridine coordination polymer 203 15, 28 – terpyridine-based 215 5,500-dinitro-2,20:60,200-terpyridine 16 copper 174f. dinuclear complex 94ff. – CCAAC 25, 52f., 406, 472 – bicyclo[2.2.2]octane bridge 97 –CuII bis(terpyridine) complex 367ff. – N-heteroaromatic groups in the spacer 99 –CuII complex 366 – heterometallic 91 –CuI ion 178ff. – strapped biphenyl 97 –CuII ion 177ff., 244, 292, 366ff., 380 dinuclear rack 157 –CuII mono(terpyridine) 367ff. 2,9-diphenyl-1,10-phenanthroline (dpp) 379 2þ – [Cu(bpy)(H2O)] 369 1,1-diphenylethylene 463 þ – [Cu(bpy)(tpy)]2 172 2,9-diphenylphenanthroline 177 þ – [Cu(BTB)Fe(BTB)Cu]4 173 40-(diphenylphosphino)-2,20:60,200- þ – [Cu(bzimpy)] 367 terpyridine 27 þ – [Cu(bzimpy)Cl] 367 dipyrido[3,2-a:20,30-c]phenazine (dppz) 335 – [Cu(pty)Cl]Cl 367 40-(2,3-disubstituted 2H-azirin-2-yl)-2,20:60,200- 2þ – [Cu(tpy)(H2O)] 369 terpyridine 25 – polymer-bound CuI mono(terpyridine) dithienylethene (DTE) 43 complex 472 – photochromic 43 cross-coupling procedures 18ff DNA CRP (controlled radical polymerization) – A-[Fe]-B0 (A/A0, and B/B0 represent 244, 281 complementary strands) 378 current imaging tunnelling spectroscopy – A-[Ru]-A 378 (CITS) 168 – B-[Fe]-C0 (B/B0, and C/C0 represent cyclodextrin 182ff. complementary strands) 378 cyclodextrin-complex – B-[Ru]-B 378 – homoleptic 182 – C-[Fe]-A0 (A/A0, and C/C0 represent cyclometalation 113 complementary strands) 378 cyclopropanation – damage 350f. – asymmetric 461 – double helix 327ff. cyclosexipyridine 143 – double-strand break (DSB) 350 cytochrome c protein 384 – G-quadruplex 331f. cytotoxicity 341f., 361, 373 – ODN Â DNA duplex 377 BINDEX 27 J l 2011 9 29 9 512 | Index DNA (continued) –FeII bis(terpyridine) complex 180f., 380, – oxidative cleavage 350f., 375 423, 464f. – single-strand break (SSB) 350 –FeII bis(terpyridine) unit 278 – topology 327 –FeII bis(terpyridine)-PEtOx complex 278 DNA binding 350ff. –FeII mono(terpyridine) complex 468 DNA diblock copolymer 378 –FeIII mono(terpyridine) complex 472ff. DNA intercalation 320ff. –FeII tris(bipyridine) complex –PtII mono(terpyridine) complex 244, 279 321ff. – [Fe(tpy)2](FeCl4)2 475 DNA intercalator 320ff. –Fe3O4@Au-tpy nanoparticle 425 dodecahydro-19,20,21,22,23,24- – grid 163ff. hexaazakekulene 144 – homoleptic FeII bis(terpyridine) donor–[Ir(tpy)2]–acceptor array 112 complex 464 double-cross-shaped structure 170 – metallopolymer 222, 265 dye-sensitized solar cell (DSSC) 233f., – polymer-bound FeIII mono(terpyridine) 431ff., 497 complex 472 dysprosium ferrocene –DyIII ion 252 – functionalized 370 ferrocenium cation 370 e ferrocifen 369 electron hopping mechanism 409 flanking region (FL) 353 electron/proton-transfer (EPT) 488 Fremy’s salt (FS, potassium electroreduction 480 nitrosodisulfonate) 212ff. –CO2 480 FTO (fluorine-doped tin oxide) 443, 497 – oxygen 480 40-(furan-2-yl)- 2,20:60,200-terpyridine 40 energy and charge transfer 143 fused terpyridines 155 epoxidation 464f. – asymmetric epoxidation of styrene g derivative 465 gel (metallo-supramolecular) 248 meso-epoxide 472 giant amphiphiles 381 ethidium bromide (EthBr) 324 b-1,3-glucan 451 40-ethynyl-2,20:60,200-terpyridine 31f., 135 glutathione (GSH, Glu-Cys-Gly europium tripeptide) 339ff.