The Quantum Leap
MILESTONES MILESTONE 3 described by his formula, partially guided by the work of Ludwig Boltzmann on entropy. However, The quantum leap there was one revolutionary assump- tion that he had to make: that light aimed at constructing a standard for was emitted and absorbed in discrete the measurement of illumination packets of energy — quanta. These intensities, directed him towards were not a feature of heat radiation heat radiation. He revisited Gustav alone, but, as Albert Einstein showed Kirchhoff’s theoretical studies of in 1905, also of light. Einstein used black-body radiation, which implied the term Lichtquant, or quantum that when a substance capable of of light. Only in 1926 was the word absorbing and emitting radiation is ‘photon’ introduced, by the chemist enclosed in a cavity with perfectly Gilbert Lewis. His theory of a “hypo- reflecting walls, the spectral distribu- thetical new atom that is not light tion of the observed radiation at but plays an essential part in every equilibrium is a function only of process of radiation” did not hold up, temperature and is independent of but the name ‘photon’ stuck. the substance involved. Intrigued by Without setting out to do so, such an ‘absolute’ law, Plank devoted Planck had rocked the edifice of himself, from 1896, to finding an physics to its very foundations. “His explanation for it. was, by nature, a conservative mind,” Parallel works on black-body wrote Max Born in an obituary radiation produced confusing results. of Planck, “he had nothing of the Lord Rayleigh had found a law revolutionary and was thoroughly (which, with James Jeans, he later sceptical about speculations.
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