Early History of Fourier Transform Spectroscopy
Total Page:16
File Type:pdf, Size:1020Kb
Infrared Phys. Vol. 24, No. 2/3. pp. 69-93, 1984 0020-0891/84 $3.00 + 0.00 Printed in Great Britain. All rights reserved Copyright !c 1984 Pergamon Press Ltd EARLY HISTORY OF FOURIER TRANSFORM SPECTROSCOPY PIERRE CONNES Service d’Akonomie du CNRS, B.P. No. 3, 91370 Verrieres-le-Buisson, France (Received 31 October 1983) Abstract-This is an attempt to explain how and why the stage was set for the appearance on the scene of Fourier transform spectroscopy (FTS) in the 1950s and not a whit before. The play begins 100 years earlier with Fizeau and Foucault who first produced high path-difference interference phenomena and used them for measuring solar spectrum wavelengths in the near IR. Next, the story unfolds with Michelson’s contribution, which led to important discoveries around 1890: the hyperfine structures and widths of atomic lines. Somewhat less well known is the Rubens interferometric technique, presented in 1910, because no such striking results were ever collected; still, it represented a distinct advance over the Michelson one. What is the reason why Michelson, Rubens and Lord Rayleigh (who made no experiments himself but understood all about them) never managed to get together and propose the modern form of FTS? Part of the responsibility we must ascribe to chance; however, sufficient motivation could not be felt as long as basic noise limitations had not been understood and closely approached. INTRODUCTION The Durham Conference has just demonstrated that Fourier transform spectroscopy (FTS) is now one of the most versatile and widely useful tools in the paraphernalia of modern optics. Will it become one of the permanent features of the landscape, just like-let us say-the Cathedral? Such a prediction would be risky of course; but any participant who briefly stole away from one of the less thrilling sessions and trespassed across the Close, surely discovered that all the great surviving medieval cathedrals are first of all things of the mind: destroyed, rebuilt, enlarged or mutilated, plastered all over and then joyfully restored and rediscovered. What truly endures is oft more the spirit than the stones. At the dissipation rate of all things modern, our present interferometers (some of them anyhow) will be museum pieces before the turn of the century-millenium, and likewise most of our analysis or recording techniques. But the basic principles involved might well exhibit far greater staying power, and earn a permanent niche on the shelves of scientific methodology (see Note l).* Where do they come from? All involved in FTS realize that the independent work of Fellgett and Jacquinot about 30 years ago is unquestionably at the origin of the whole development (see Note 2). They also know of the classical results of Michelson, a trace of which is still found in textbooks, but only vaguely. Few are even aware of the work of Rubens in the field, or realize that the modern form of FTS was almost discovered around 1910; if it had been, much of the development of twentieth century spectroscopy would have been different, particularly of course in the IR. Why was it not discovered in actual fact? Was the prime reason insufficient mathematical understanding, immature technology, absence of motivation, or just the lack of the right people (the last being of course no valid historical explanation)? How much of the basic advantage of FTS (as we understand it today) was already seen? How close to the modern devices were the turn of the century interferometers? And what is the essential change of scene that made possible-and practical-the technique that had failed 40 years before? The following brief (and amateurish) historical study will attempt to answer these questions. It will not start with Fourier, whose contribution is of course essential but had originally nothing to do with optics. For the purpose of our demonstration, the story begins by experimental advances around the middle of the last century. *Notes 1-7 can be found at the end of the article. 69 70 PIERRECONNES I. HIPPOLYTE FIZEAU (1819-1896) AND LEON FOUCAULT (1819.-1868) Born within a few days of each other, Fizeau and Foucault at first tackled several fundamental problems of experimental optics together; after they split, in 1849, they went on in competition. and produced equally brilliant results, We are concerned here with a minor part of that work: their contribution to interference spectroscopy. Fizeau and Foucault initiated two distinct lines of research which were much later to converge and make present-day FTS possible: the production of interferences at high path d@erence, and the recording of IR int~~fi~renceJringes, leading to the first measurement of IR wavelengths. Prior to 1845, no interference phenomena seem to have been observed, or at least understood and properly analysed, for path differences greater than a few wavelengths. Then Fizeau and Foucault published together two brief Notes”’ “ Sur le phinomene des interferences entre deux rayons de lumiere dans le case des grandes differences de marche”. The authors introduce a new technique: the observation of channelled spectra (thanks to a much improved prism spectroscope) and its systematic use for the measurement of path differences. The source was the sun, and bright and dark bands were counted in between the Fraunhofer lines. Three different interference devices were used (Fig. 1): “With Fresnel mirrors, we have observed interference when the path difference for blue rays near line F was 1737 waves. Through reflexion upon both surfaces of a thin plate, interference was noticed when the path difference went up to 3406 waves. With crystalline plates the phenomenon has been followed for remarkably high thick- nesses . ‘* In the second Note, the not-so-thin isotropic plate thickness went up to 1 mm and path difference to “seven or eight thousand times the fundamental interval A”, thanks to the use of up to five prisms in series. (See Note 3.) Fourteen years later, Fizeau (by then no longer paired with Foucault), was to take up again the question of large path differences, but with a different source. His paper,“’ “Note sur la lumiere du sodium brulant dans lair”, was about a popular subject at the time; indeed, he refers to the “many and important results present in the work of M. M. Kirchhoff and Bunsen”. Fizeau is here mostly concerned with his own discovery of an inuerteci pair of D lines from a piece of burning sodium; but he mentions almost incidentally that from an ordinary sodium flame he has obtained: i‘ . the phenomenon of Newton rings, observed with that very simple light, by normal reflexion on the two surfaces of plates that are relatively very thick for such phenomena, since the thickness went up to 10.058 mm, corresponding to a ring of order 52193.” A detailed account is promised “in my next work”. Thanks to the fat pile of scribbled laboratory notes preserved at the Academic, we can follow Fizeau’s progress: he was building the first variable-path interferometer for wavelength measurement by fringe counting (Fig. 2) surely the ancestor of all present so-called “Fourier interferometers” (a particularly absurd contraction). The results were presented a few months later, somewhat hidden away within a paper on interference measurement of refractive index thermal variation for various solids. lh) The small instrument built by Duboscq is described, together with the now familiar sight of Newton’s rings (here observed as “Fizeau fringes” between a plane and spherical glass surface) expanding or contracting when the separation is changed. Fizeau notices and explains correctly the successive coincidences between the fringes from the two D lines, up to the 52nd period of the phenomenon, i.e. 50,000 fringes and a plate separation of 15 mm. The red line of lithium is also observed. and the wavelength given from the coincidences with the D lines. There is no attempt yet to deduce wavelengths from the known pitch of the screw. However, in,fine, the remarkable stability of fringes seen on a thick glass plate (at constant temperature) is ncticed; it is estimated that with the path difference being about 50,000 fringes and a 1/2&h of a fringe motion being easy to detect, the stability must be better than 10. ‘. Fizeau concludes by expressing the hope of important applications. From this remark. all of modern length metrology was to arise. fi PIERRE CONNES Fig. 2. Laboratory note of Fizeau, dated 3 February 1862, illustrating the mechanical design of the first variable-path interferometer for wavelength measurement by fringe counting: “I have made an agreement with Mr Duboscq for constructing a small instrument suitable for measuring the wavelengths of light. .” The device shown is a differential screw with two nuts, one fixed (pitch 0.5 mm) and one mobile (pitch 0.5 x 20/21 mm). For sodium light Fizeau computes a count of 85 fringes/revolution. Also preserved is the draft of a letter to Duboscq (a well remembered instrument maker), discussing some points and ending with the plea: “. I rely on your promise of actively pushing the work on this small instrument which 1 find quite indispensable at present. .“. Results were to be given soon after. in Ref. (6). (Reproduced courtesy of Archives de 1’Acadimie des Sciences. Paris.) As soon as Fizeau and Foucault had perfected their technique they applied it to the detection of IR radiation, and to measuring IR wavelengths. In the first paper,(‘) “Recherches sur les interfkrences des rayons calorifiques”, the source was the sun again, and the detector an alcohol thermometer with a 1 mm dia spherical bulb; a 1” temperature change induced 8 mm of column expansion, which was followed with a microscope; one micrometer division corresponded to l/400-.