History of Science As a Facilitator for the Study of Physics
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Biochemical Thermodynamics
Biochemical Thermodynamics Biochemical Thermodynamics By Juan S. Jiménez Biochemical Thermodynamics By Juan S. Jiménez This book first published 2020 Cambridge Scholars Publishing Lady Stephenson Library, Newcastle upon Tyne, NE6 2PA, UK British Library Cataloguing in Publication Data A catalogue record for this book is available from the British Library Copyright © 2020 by Juan S. Jiménez All rights for this book reserved. No part of this book may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, electronic, mechanical, photocopying, recording or otherwise, without the prior permission of the copyright owner. ISBN (10): 1-5275-5359-0 ISBN (13): 978-1-5275-5359-0 To the memory of Brígida and Francisco Jiménez CONTENTS PREFACE ..................................................................................................... x CHAPTER 1 .................................................................................................. 1 INTRODUCTION 1.1 The Atomic Theory of John Dalton and the Hypothesis of Amedeo Avogadro 1.2 The Mole and Avogadro’s Number 1.3 The ideal gas model 1.4 The Periodic Table and Initial Atomic Theories 1.5 The Hydrogen Atom and the Schrödinger Equation 1.6 Atomic Structure 1.7 Molecules CHAPTER 2 ................................................................................................ 35 ENTROPY 2.1 Systems, Properties and States 2.2 The First Law of Thermodynamics 2.3 Enthalpy 2.4 Reversible changes 2.5 The Second Law of Thermodynamics 2.6 A Particle in a One-dimensional Box 2.7 Quantum States 2.8 The Boltzmann Equation CHAPTER 3 ................................................................................................ 63 THE CHEMICAL EQUILIBRIUM 3.1 The Gibbs Function 3.2 The Chemical Potential 3.3 Chemical Equilibrium 3.4 Model Systems 3.5 The Equilibrium Constant for Chemical Reactions between Gases. -
Introduction
Introduction The following two papers of Planck represent only a very small part of the historical development of our knowledge about the spectral energy distribution of electromagnetic radiation. They are the result of a long series of investigations undertaken not only by Planck (in his work on irreversible processes since 1878, and—stimulated by Maxwell's theory as developed especially by H. Hertz—on the application of thermodynamics to electromagnetic processes, from about 1891) but also by many other scientists who contributed to these experimentally and theoretically in the 19th century or earlier. Planck did not work in a vacuum. On the theoretical side, his formulations were most directly preceded by the theoretical research of Wilhelm Wien, who not only introduced the entropy of (resonator-free) radiation in 1894, but also in 1893 and 1894 discovered several regularities governing the form of the black-body radiation function introduced in 1860 by Gustav Robert Kirchhoff; in 1896 Wien found, simultaneously and independently with Friedrich Paschen, what is now called Wien's distribution law. But Planck also drew on J. H. Poynting's theorem on energy flux, as well as on the law for total radiation obtained by Josef Stefan in 1879 from measure ments of earlier authors and derived theoretically in 1884 by L. Boltzmann. Indeed, Planck may have retained as "youthful memories" his intense preoccupation, in his 19th year, with John Tyndall's works on heat radiation. On the other hand the results, as they become evident in these two papers, are only the initial steps in the direction of the quantum theory to be developed later. -
Amedeo Avogadro
Amedeo Avogadro ALSO LISTED IN Physicists FAMOUS AS Chemist and Physicist NATIONALITY Italian Famous Italian Men RELIGION Roman Catholic BORN ON 09 August 1776 AD Famous 9th August Birthdays ZODIAC SIGN Leo Leo Men BORN IN Turin, Italy DIED ON 09 July 1856 AD PLACE OF DEATH Turin, Italy FATHER Filippo Avogadro MOTHER Anna Maria Vercellone SPOUSE: Felicita Mazzé Lorenzo Romano Amedeo Carlo Avogadro de Quaregna e di Cerreto, more popularly known as Amedeo Avogadro was born on August 9, 1776, in Turin, Italy. He was a gifted physicist and chemist who proposed the molecular theory, which is more popularly known as ‘Avogadro’s Law’. Although he earned a doctorate in ecclesiastical law, he developed a passion for studying mathematics and physics. He then gave up his career in law and pursued a career teaching natural physics at the Royal College of Vercelli. Years later, he was offered the chair of mathematical physics at the University of Turin. Avogadro conducted experiments in both physics and chemistry using mathematics as a basis for his findings. His hypothesis, known as the ‘Avogadro’s Law’ is recognized all over the world. He also published many works during his lifetime. The number 6.02214199 x 10^23 is named as Avogadro’s number to honor him for his contribution in molecular theory. Read on to know more about this great physicist and chemist. Read more at http://www.thefamouspeople.com/profiles/amadeo-avogadro- 532.php#09s5lE6QjEOdfSro.99 Career After studying philosophy in 1789, Amedeo Avogadro graduated in jurisprudence in 1792 and earned his doctorate in ecclesiastical law in 1796. -
Richard Phillips Feynman Physicist and Teacher Extraordinary
ARTICLE-IN-A-BOX Richard Phillips Feynman Physicist and Teacher Extraordinary The first three decades of the twentieth century have been among the most momentous in the history of physics. The first saw the appearance of special relativity and the birth of quantum theory; the second the creation of general relativity. And in the third, quantum mechanics proper was discovered. These developments shaped the progress of fundamental physics for the rest of the century and beyond. While the two relativity theories were largely the creation of Albert Einstein, the quantum revolution took much more time and involved about a dozen of the most creative minds of a couple of generations. Of all those who contributed to the consolidation and extension of the quantum ideas in later decades – now from the USA as much as from Europe and elsewhere – it is generally agreed that Richard Phillips Feynman was the most gifted, brilliant and intuitive genius out of many extremely gifted physicists. Here are descriptions of him by leading physicists of his own, and older as well as younger generations: “He is a second Dirac, only this time more human.” – Eugene Wigner …Feynman was not an ordinary genius but a magician, that is one “who does things that nobody else could ever do and that seem completely unexpected.” – Hans Bethe “… an honest man, the outstanding intuitionist of our age and a prime example of what may lie in store for anyone who dares to follow the beat of a different drum..” – Julian Schwinger “… the most original mind of his generation.” – Freeman Dyson Richard Feynman was born on 11 May 1918 in Far Rockaway near New York to Jewish parents Lucille Phillips and Melville Feynman. -
Chemistry in Italy During Late 18Th and 19Th Centuries
CHEMISTRY IN ITALY DURING LATE 18TH AND 19TH CENTURIES Ignazio Renato Bellobono, CSci, CChem, FRSC LASA, Department of Physics, University of Milan. e-mail add ress : i.bell obon o@ti scali.it LASA, Dept.Dept. ofPhysics, Physics, University of Milan The birth of Electrochemistry Luigi Galvani, Alessandro Volta, and Luigi Valentino Brugnatelli From Chemistry to Radiochemistry The birth of Chemistry and Periodic Table Amedeo Avogadro and Stanislao Cannizzaro Contributions to Organic Chemistry LASA, Dept.Dept. ofPhysics, Physics, University of Milan 1737 At the Faculty of Medicine of the Bologna University, the first chair of Chemistry is establishedestablished,,andandassigned to Jacopo Bartolomeo BECCARI (1692-1766). He studied phosphorescence and the action of light on silver halides 1776 In some marshes of the Lago Maggiore, near AngeraAngera,, Alessandro VOLTA ((17451745--18271827),),hi gh school teacher of physics in Como, individuates a flammable gas, which he calls aria infiammabile. Methane is thus discovereddiscovered.. Two years laterlater,,heheis assignedassigned,,asas professor of experimental phihysicscs,,toto the UiUniversi ty of PiPavia LASA, DtDept. of PhPhys icscs,, University of Milan 1778 In aletter a letter to Horace Bénédict de Saussure, aaSwissSwiss naturalist, VOLTA introduces, beneath that of electrical capacitycapacity,, the fundamental concept of tensione elettrica (electrical tension), exactly the name that CITCE recommended for the difference of potential in an electrochemical cell. 17901790--17911791 VOLTA anticipatesanticipates,,bybyabout 10 yearsyears,,thethe GAYGAY--LUSSACLUSSAC linear de ppyendency of gas volume on tem pp,erature, at constant pressurepressure,,andandafew a fewyears later ((17951795)) anticipatesanticipates,,byby about 6years 6 years,,thethe soso--calledcalled John Dalton’s rules ((18011801))ononvapour pressure LASA, Dept.Dept. -
Einstein and Hilbert: the Creation of General Relativity
EINSTEIN AND HILBERT: THE CREATION OF GENERAL RELATIVITY ∗ Ivan T. Todorov Institut f¨ur Theoretische Physik, Universit¨at G¨ottingen, Friedrich-Hund-Platz 1 D-37077 G¨ottingen, Germany; e-mail: [email protected] and Institute for Nuclear Research and Nuclear Energy, Bulgarian Academy of Sciences Tsarigradsko Chaussee 72, BG-1784 Sofia, Bulgaria;∗∗e-mail: [email protected] ABSTRACT It took eight years after Einstein announced the basic physical ideas behind the relativistic gravity theory before the proper mathematical formulation of general relativity was mastered. The efforts of the greatest physicist and of the greatest mathematician of the time were involved and reached a breathtaking concentration during the last month of the work. Recent controversy, raised by a much publicized 1997 reading of Hilbert’s proof- sheets of his article of November 1915, is also discussed. arXiv:physics/0504179v1 [physics.hist-ph] 25 Apr 2005 ∗ Expanded version of a Colloquium lecture held at the International Centre for Theoretical Physics, Trieste, 9 December 1992 and (updated) at the International University Bremen, 15 March 2005. ∗∗ Permanent address. Introduction Since the supergravity fashion and especially since the birth of superstrings a new science emerged which may be called “high energy mathematical physics”. One fad changes the other each going further away from accessible experiments and into mathe- matical models, ending up, at best, with the solution of an interesting problem in pure mathematics. The realization of the grand original design seems to be, decades later, nowhere in sight. For quite some time, though, the temptation for mathematical physi- cists (including leading mathematicians) was hard to resist. -
Richard P. Feynman Author
Title: The Making of a Genius: Richard P. Feynman Author: Christian Forstner Ernst-Haeckel-Haus Friedrich-Schiller-Universität Jena Berggasse 7 D-07743 Jena Germany Fax: +49 3641 949 502 Email: [email protected] Abstract: In 1965 the Nobel Foundation honored Sin-Itiro Tomonaga, Julian Schwinger, and Richard Feynman for their fundamental work in quantum electrodynamics and the consequences for the physics of elementary particles. In contrast to both of his colleagues only Richard Feynman appeared as a genius before the public. In his autobiographies he managed to connect his behavior, which contradicted several social and scientific norms, with the American myth of the “practical man”. This connection led to the image of a common American with extraordinary scientific abilities and contributed extensively to enhance the image of Feynman as genius in the public opinion. Is this image resulting from Feynman’s autobiographies in accordance with historical facts? This question is the starting point for a deeper historical analysis that tries to put Feynman and his actions back into historical context. The image of a “genius” appears then as a construct resulting from the public reception of brilliant scientific research. Introduction Richard Feynman is “half genius and half buffoon”, his colleague Freeman Dyson wrote in a letter to his parents in 1947 shortly after having met Feynman for the first time.1 It was precisely this combination of outstanding scientist of great talent and seeming clown that was conducive to allowing Feynman to appear as a genius amongst the American public. Between Feynman’s image as a genius, which was created significantly through the representation of Feynman in his autobiographical writings, and the historical perspective on his earlier career as a young aspiring physicist, a discrepancy exists that has not been observed in prior biographical literature. -
High-Energy Physics from 1945 to 1952/ 53
CHS-17 March 1985 STUDIES IN CERN HISTORY High-energy physics from 1945 to 1952/ 53 Ulrike Mersits GENEVA 1985 The Study of CERN History is a project financed by Institutions in several CERN Member Countries. This report presents preliminary findings, and is intended for incorporation into a more comprehensive study of CERN's history. It is distributed primarily to historians and scientists to provoke discussion, and no part of it should be cited or reproduced without written permission from the Team Leader. Comments are welcome and should be sent to: Study Team for CERN History c/oCERN CH-1211 GENEVE23 Switzerland © Copyright Study Team for CERN History, Geneva 1985 CERN-Service d'information scientifique - 300- mars 1985 HIGH-ENERGY PHYSICS from 1945 to 1952/53 I. The scientific situation in 'elementary particle physics' around 1945/46 I.1. Cosmic-ray physics I.2 Nuclear physics II. Institutional changes in nuclear physics due to the war III. The post-war accelerator programmes III.1. The principle of phase stability III.2. The United States III.3. Great Britain - the leading country in Europe III.4. Continental western Europe III.5. AG focusing - another step into higher energy regions IV. Experimental particle physics: developments from 1946 to 1953 IV.1. The leptonic nature of the mesotron and the detection of the pi meson (1946/47) IV.2. The artificial production of charged and uncharged pi-mesons (1948/49) IV.3. The complexity of the mass spectrum (1947-1953) IV.3.1.The V-particles IV.3.2.The heavy mesons IV.3.3.The Bagneres-de-Bigorre Conference (1953) V. -
7.12 Comm Mx
commentary The quantum centennial One hundred years ago, a simple concept changed our world view forever. spectrum, but did not agree with experi- tion of this experimentally successful radia- Anton Zeilinger ments for all wavelengths. Planck had the tion law from other known laws of physics, When Max Planck announced his quantum advantage of close access to the most recent but he slowly had to accept that he had found assumption in his talk at the German Physical experimental results obtained by Otto Lum- something fundamentally new. Society in Berlin on 14 December 1900, mer and Ernst Pringsheim and by Ferdinand The next important step in the early days nobody, including himself, realized that he Kurlbaum and Heinrich Rubens, also work- of quantum mechanics came in 1905, when was opening the door to a completely new ing in Berlin, on the spectral distribution of Albert Einstein introduced his radical theoretical description of nature. Quantum black-body heat radiation emerging from a hypothesis of quanta of light to explain the physics has had unsurpassed success in hole in a box kept at a certain temperature. photoelectric effect. For a while, this explaining many phenomena — from the Planck eventually found a full explana- remained the only significant instance of the structure of elementary particles, through tion, but only after forcing himself “to an act quantum being taken seriously. Einstein’s the essence of chemical bonds or the nature of of despair” by assuming that energy can only hypothesis met with strong objections from many solid-state phenomena, all the way to be exchanged between the light field inside the his contemporaries, including Planck him- the physics of the early Universe. -
Julian Schwinger (1918-1994)
Julian Schwinger (1918-1994) K. A. Milton Homer L. Dodge Department of Physics and Astronomy, University of Oklahoma, Norman, OK 73019 June 15, 2006 Julian Schwinger’s influence on Twentieth Century science is profound and pervasive. Of course, he is most famous for his renormalization theory of quantum electrodynamics, for which he shared the Nobel Prize with Richard Feynman and Sin-itiro Tomonaga. But although this triumph was undoubt- edly his most heroic accomplishment, his legacy lives on chiefly through sub- tle and elegant work in classical electrodynamics, quantum variational princi- ples, proper-time methods, quantum anomalies, dynamical mass generation, partial symmetry, and more. Starting as just a boy, he rapidly became the pre-eminent nuclear physicist in the late 1930s, led the theoretical develop- ment of radar technology at MIT during World War II, and then, soon after the war, conquered quantum electrodynamics, and became the leading quan- tum field theorist for two decades, before taking a more iconoclastic route during his last quarter century. Given his commanding stature in theoretical physics for decades it may seem puzzling why he is relatively unknown now to the educated public, even to many younger physicists, while Feynman is a cult figure with his photograph needing no more introduction than Einstein’s. This relative ob- scurity is even more remarkable, in view of the enormous number of eminent physicists, as well as other leaders in science and industry, who received their Ph.D.’s under Schwinger’s direction, while Feynman had but few. In part, the answer lies in Schwinger’s retiring nature and reserved demeanor. -
Avogadro's Constant
Avogadro's Constant Nancy Eisenmenger Question Artem, 8th grade How \Avogadro constant" was invented and how scientists calculated it for the first time? Answer What is Avogadro's Constant? • Avogadros constant, NA: the number of particles in a mole • mole: The number of Carbon-12 atoms in 0.012 kg of Carbon-12 23 −1 • NA = 6:02214129(27) × 10 mol How was Avogadro's Constant Invented? Avogadro's constant was invented because scientists were learning about measuring matter and wanted a way to relate the microscopic to the macroscopic (e.g. how many particles (atoms, molecules, etc.) were in a sample of matter). The first scientists to see a need for Avogadro's constant were studying gases and how they behave under different temperatures and pressures. Amedeo Avogadro did not invent the constant, but he did state that all gases with the same volume, pressure, and temperature contained the same number of gas particles, which turned out to be very important to the development of our understanding of the principles of chemistry and physics. The constant was first calculated by Johann Josef Loschmidt, a German scientist, in 1865. He actually calculated the Loschmidt number, a constant that measures the same thing as Avogadro's number, but in different units (ideal gas particles per cubic meter at 0◦C and 1 atm). When converted to the same units, his number was off by about a factor of 10 from Avogadro's number. That may sound like a lot, but given the tools he had to work with for both theory and experiment and the magnitude of the number (∼ 1023), that is an impressively close estimate. -
Something Is Rotten in the State of QED
February 2020 Something is rotten in the state of QED Oliver Consa Independent Researcher, Barcelona, Spain Email: [email protected] Quantum electrodynamics (QED) is considered the most accurate theory in the his- tory of science. However, this precision is based on a single experimental value: the anomalous magnetic moment of the electron (g-factor). An examination of QED history reveals that this value was obtained using illegitimate mathematical traps, manipula- tions and tricks. These traps included the fraud of Kroll & Karplus, who acknowledged that they lied in their presentation of the most relevant calculation in QED history. As we will demonstrate in this paper, the Kroll & Karplus scandal was not a unique event. Instead, the scandal represented the fraudulent manner in which physics has been conducted from the creation of QED through today. 1 Introduction truth the hypotheses of the former members of the Manhat- tan Project were rewarded with positions of responsibility in After the end of World War II, American physicists organized research centers, while those who criticized their work were a series of three transcendent conferences for the separated and ostracized. The devil’s seed had been planted development of modern physics: Shelter Island (1947), in the scientific community, and its inevitable consequences Pocono (1948) and Oldstone (1949). These conferences were would soon grow and flourish. intended to be a continuation of the mythical Solvay confer- ences. But, after World War II, the world had changed. 2 Shelter Island (1947) The launch of the atomic bombs in Hiroshima and 2.1 The problem of infinities Nagasaki (1945), followed by the immediate surrender of Japan, made the Manhattan Project scientists true war heroes.