Accepted Manuscript Title: Pyrolysis of hydrazine derivatives and related compounds with N-N single bonds Author: Abd-El Aal M. Gaber Curt Wentrup PII: S0165-2370(17)30020-7 DOI: http://dx.doi.org/doi:10.1016/j.jaap.2017.03.016 Reference: JAAP 4003 To appear in: J. Anal. Appl. Pyrolysis Received date: 7-1-2017 Revised date: 10-3-2017 Accepted date: 15-3-2017 Please cite this article as: A.-E.A.M. Gaber, C. Wentrup, Pyrolysis of hydrazine derivatives and related compounds with N-N single bonds, Journal of Analytical and Applied Pyrolysis (2017), http://dx.doi.org/10.1016/j.jaap.2017.03.016 This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain. 1 Pyrolysis of hydrazine derivatives and related compounds with N-N single 2 bonds 3 4 Abd-El Aal M. Gabera,* and Curt Wentrupb,* 5 6 a Chemistry Department, Faculty of Science, Assiut University, Assiut 71516, Egypt 7 b School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane, 8 Queensland 4072, Australia 9 10 ∗Corresponding authors, E-mail addresses:
[email protected] (Gaber),
[email protected] (Wentrup). 11 12 Highlights 13 Pyrolysis of all types of hydrazine derivatives are reviewed 14 N-aminoheterocycles, N-aminoisocyanides, and N-aminoisocyanates are included 15 Aminimides, azimines, and tri-, tetra-, penta- and hexazenes are covered 16 Pyrolyses in solution, in the solid state, and under flash vacuum pyrolysis conditions 17 18 ABSTRACT 19 Pyrolysis of hydrazines and their derivatives often results in homolytic cleavage of the N-N 20 bonds, but molecular rearrangements and eliminations are also observed in many cases.