Safety Instruction for Hazardous Maerials (Appendix 3-4) Structures and Generation of Explosives "Safety Guidance for Chemical Experiments 4th Edition" ed. by The Chemical Society of Japan, Maruzen (1999)
Bond Explosive compounds Chemical structures Generation reaction
O-O High concentrated H2O2 hydrogen peroxide
Organic peroxides R-O-O-R' Alcohols + H2O2 Halides + H2O2 Aldehydes + H2O2 Ketones + H2O2 Carboxylic acids + H2O2 Ethers + H2O2
O Ozonides Unsaturated hydrocarbon + O O O 3
Alcohols + HNO N-O Nitric acid esters C ONO2 3 Carbohydrates + HNO3
Nitrous acid esters C ONO Alcohols + HNO2 Halides + MNO2
Halides + M'NO2 Nitro compounds C NO2 Hydrocarbons, others + HNO3
Amine salts of nitric acid N HNO3 Amines + HNO3
Ammonium nitrate NH4NO3 NH3 + HNO3
Dehydration of amino nitrates Nitramines C N NO2 Amines + HNO3
Nitroso compounds C NO Phenols + HNO2
Ketone oximes O C C NOH
R1 Hydroxyamine N OH derivatives R2
Fulminates M' O N C Metal nitrates + HNO3 + Alcohls
X-O Dichlorine Heptoxide Cl2O7 Amine salts of perchloric acid N HClO4
Perchloric acid esters C OClO3 Alcohols + HClO4
Perchloryl compounds C ClO3 C H + FClO3
Chloric acid HClO3 M'ClO3 + Acids
Chlorine dioxide ClO2 M'ClO2 + Acids Heavy metal salts of KClO + Heavy metal salts, M'ClO 3 chloric acid 3 Hg, Ag, Pb
Ammonium chlorate NH ClO M'ClO3 + NH3 or 4 3 Ammonium salts Amine salts of chloric HClO acid N 3 M'ClO3 + Amine salts
Chloric acid esters C OClO2
Chlorous acid HClO2 Hypochlorous acid HClO
Chlorine monooxide Cl2O Salts of hypochlorous acid M'ClO
Hypochlorous acid esters C OCl
Amine salts of boromic N HBrO acid 3
Ammonium bromate NH4BrO3
Amine salts of iodic acid N HIO3
Ammonium iodate NH4IO3
Permanganic acid HMnO4 M'MnO4 + H2SO4 Manganese(VII) oxide Mn O (Dimanganese heptoxide) 2 7 M'MnO4 + H2SO4
Ammonium Permanganate NH4MnO4 M'MnO4 + Ammonium salts Amine salts of N HMnO permanganic acid 4
Ammonium dichromate (NH4)2Cr2O7 M'2Cr2O7 + Ammonium salts Amine salts of dichromic acid N H2Cr2O7 2 N-N Amine salts of nitrous N HNO Amines + HNO acid 2 2
Ammonium nitrite NH4NO2 M'NO2 + NH4X
Nitrosoamines C N NO C N + HNO2 H
+ C N N Diazonium salts Amines + HNO2 + HX X–
Diazo oxides H2N C C OH N2 C C O
+ HNO2 + HX
Hydrazine derivatives N N
Hydrogen azide HN3 Metal azides + acids
Heavy metal azides M'N3 NaNH3 N2H4 + + N2O NaNO2 + RONO
NaN3 + Heavy meal salts
Halogen azides XN3 NaN3 + Halogen or hypohalogenous acid salts
Halides + NaN Organic azides C N3 3
Isotetracene derivatives
Nitrogen long chain compounds
N-M Nirides M'3N
Imides M'2NH
Amides M'NH2
Amine metal complexes MX + nNH3
N-X X or M'XO + NH Nitrogen halides NX 2 3 3 or Ammonium salts
N S Nitrogen sulfide 4 4 SCl2 or S2Cl2 + NH3
C-C Acetylene HC CH CaC2 + H2O
Heavy metal acetylide M'C CM' Heavy metal salts + C2H2
Acetylene halides X C C X
Polyacetylenes, acetylene derivatives etc. and their halogen or heavy metal derivatives
Heavy metal salts of COOM' COOH + Heavy metal salts oxalic acid COOM' COOH
CH2 Ethylene oxide O CH2
Compounds with a N-O bond: Compounds with a N-N bond:
Nitric acid esters C ONO2 Diazo compounds N N C
Hydrogen azide HN3 Nitro compounds C NO 2 Metal azides M'N3
Compounds with an O-O bond: Nitramines C N NO2
Organic peroxides O O
Amine salts of nitric acid N HNO 3 O O Ozonides O Nitrous acid esters C ONO Compounds with an O-halogen bond:
Amine salts and esters of chloric acid: Nitroso compounds C NO HClO3, perchloric acid: HClO4, etc.
Others: Nitrosoamines C N NO Acetylenes and their heavy metal salts and halogen derivatives
Amine salts of nitrous acid N HNO Heavy metal salts of oxalic acid etc. 2