Safety Instruction for Hazardous Maerials (Appendix 3-4) Structures and Generation of Explosives "Safety Guidance for Chemical Experiments 4th Edition" ed. by The Chemical Society of Japan, Maruzen (1999) Bond Explosive compounds Chemical structures Generation reaction O-O High concentrated H2O2 hydrogen peroxide Organic peroxides R-O-O-R' Alcohols + H2O2 Halides + H2O2 Aldehydes + H2O2 Ketones + H2O2 Carboxylic acids + H2O2 Ethers + H2O2 O Ozonides Unsaturated hydrocarbon + O O O 3 Alcohols + HNO N-O Nitric acid esters C ONO2 3 Carbohydrates + HNO3 Nitrous acid esters C ONO Alcohols + HNO2 Halides + MNO2 Halides + M'NO2 Nitro compounds C NO2 Hydrocarbons, others + HNO3 Amine salts of nitric acid N HNO3 Amines + HNO3 Ammonium nitrate NH4NO3 NH3 + HNO3 Dehydration of amino nitrates Nitramines C N NO2 Amines + HNO3 Nitroso compounds C NO Phenols + HNO2 Ketone oximes O C C NOH R1 Hydroxyamine N OH derivatives R2 Fulminates M' O N C Metal nitrates + HNO3 + Alcohls X-O Dichlorine Heptoxide Cl2O7 Amine salts of perchloric acid N HClO4 Perchloric acid esters C OClO3 Alcohols + HClO4 Perchloryl compounds C ClO3 C H + FClO3 Chloric acid HClO3 M'ClO3 + Acids Chlorine dioxide ClO2 M'ClO2 + Acids Heavy metal salts of KClO + Heavy metal salts, M'ClO 3 chloric acid 3 Hg, Ag, Pb Ammonium chlorate NH ClO M'ClO3 + NH3 or 4 3 Ammonium salts Amine salts of chloric N HClO3 M'ClO + Amine salts acid 3 Chloric acid esters C OClO2 Chlorous acid HClO2 Hypochlorous acid HClO Chlorine monooxide Cl2O Salts of hypochlorous acid M'ClO Hypochlorous acid esters C OCl Amine salts of boromic N HBrO acid 3 Ammonium bromate NH4BrO3 Amine salts of iodic acid N HIO3 Ammonium iodate NH4IO3 Permanganic acid HMnO4 M'MnO4 + H2SO4 Manganese(VII) oxide Mn O (Dimanganese heptoxide) 2 7 M'MnO4 + H2SO4 Ammonium Permanganate NH4MnO4 M'MnO4 + Ammonium salts Amine salts of N HMnO permanganic acid 4 Ammonium dichromate (NH4)2Cr2O7 M'2Cr2O7 + Ammonium salts Amine salts of dichromic acid N H2Cr2O7 2 N-N Amine salts of nitrous N HNO Amines + HNO acid 2 2 Ammonium nitrite NH4NO2 M'NO2 + NH4X Nitrosoamines C N NO C N + HNO2 H + C N N Diazonium salts Amines + HNO2 + HX X– Diazo oxides H2N C C OH N2 C C O + HNO2 + HX Hydrazine derivatives N N Hydrogen azide HN3 Metal azides + acids Heavy metal azides M'N3 NaNH3 N2H4 + + N2O NaNO2 + RONO NaN3 + Heavy meal salts Halogen azides XN3 NaN3 + Halogen or hypohalogenous acid salts Halides + NaN Organic azides C N3 3 Isotetracene derivatives Nitrogen long chain compounds N-M Nirides M'3N Imides M'2NH Amides M'NH2 Amine metal complexes MX + nNH3 N-X X or M'XO + NH Nitrogen halides NX 2 3 3 or Ammonium salts N S Nitrogen sulfide 4 4 SCl2 or S2Cl2 + NH3 C-C Acetylene HC CH CaC2 + H2O Heavy metal acetylide M'C CM' Heavy metal salts + C2H2 Acetylene halides X C C X Polyacetylenes, acetylene derivatives etc. and their halogen or heavy metal derivatives Heavy metal salts of COOM' COOH + Heavy metal salts oxalic acid COOM' COOH CH2 Ethylene oxide O CH2 Compounds with a N-O bond: Compounds with a N-N bond: Nitric acid esters C ONO2 Diazo compounds N N C Hydrogen azide HN3 Nitro compounds C NO 2 Metal azides M'N3 Compounds with an O-O bond: Nitramines C N NO2 Organic peroxides O O Amine salts of nitric acid N HNO 3 O O Ozonides O Nitrous acid esters C ONO Compounds with an O-halogen bond: Amine salts and esters of chloric acid: Nitroso compounds C NO HClO3, perchloric acid: HClO4, etc. Others: Nitrosoamines C N NO Acetylenes and their heavy metal salts and halogen derivatives Amine salts of nitrous acid N HNO Heavy metal salts of oxalic acid etc. 2 .