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Trace Element Analysis of Obsidian Artifacts from the Andes: New Perspectives on Pre- Hispanic Economic Interaction in Peru and Bolivia

Trace Element Analysis of Obsidian Artifacts from the Andes: New Perspectives on Pre- Hispanic Economic Interaction in Peru and Bolivia

UC Berkeley Archaeological X-ray Fluorescence Reports

Title Trace Element Analysis of Artifacts from the : New Perspectives on Pre- Hispanic Economic Interaction in and Bolivia

Permalink https://escholarship.org/uc/item/2kr0k9c1

Authors Burger, Richard L. Asaro, Frank

Publication Date 1977-06-01

eScholarship.org Powered by the California Digital Library University of California n

Trace Element Analysis Of Obsidian Artifacts From The Andes: New Perspectives On Pre­ Hispanic Economic Interaction In Peru And Bolivia

Richard Burger and Frank Asaro

June 1977

it f Ie U. S IEnergy Research and Development Administration under Contract No. W-7405-IENG-48 he tn 'Revista del Museo Peru SIS on in

LE

I on 0

lysis 2

Neu Acti vat ion is 6

X-Ray Fluorescence (Rapid Scan XRF, U.C. Berkeley) 9

X-Ray Fluorescence (LBL) .. 10

Obsidian Use ..... 0' •• 13

Quispisisa Source 18

Ayacucho Type Obsidian 30

Acari e Obsidian 30

Type Obsidian. 31

as A Type i di an 32

Andahuaylas B Type Obsidian 33

CUlCO Type Obsidian 33 Titicaca Basin Type Obsidian. 37

Rare Unique Types of Obsidian 39

Models of Distribution Mechanisms 40

Discussion .... 43

...... r''''''''''' edgments. 49

50

les 0 • 54

x

Bibl;

i Li Fires

Fi 10 i si ic in is

Fi 2. c on of at the Department of Geol iversi of California, Berkel This initial study usi on Sr, Rb and was unable distinguish between of the principal types of obsidian. The graph demonstrates the way in which the Pampas Type and Andahuaylas B Type were lumped in cluster A ile the Quispisisa Source, CUICO Type, the Andahuaylas A Type, and the rare Tum.Jku

were all incl in clu B. This confusion

made it necessary to seek the more isticated techniques loyed at the Lawrence Ber ley Laboratory,

the res ts of ich are seen in Tables 1 and 2~ and in

the Append i x. L st les

le tions iations neu ion at t or le it ions

neu ion t Lawrence L rare

Table 2. Selected trace el ition of dean obs i dian: x-ray uorescence anal is made Lawrence keley

(i n p i 11 i on) .

3. i dian ana 1 x fluorescence

iorL le 4. excavations ical P

Table 5. i di an excavat ions at site ka

i nce,

Table 6. i di an ions two sis in in.

v TRACE ELEMENT SIS ARTIFACTS FROM New Perspectives on spanic Economic In ion in Peru and Bolivia Ric L. Burger Frank aro

INTRODUCTION This article is an introduction to the study of the distribution by trade of obsidian artifacts in ancient Peru and Bolivia. Obsidian tools were used as early as Preceramic times and continued to be popular through the Middle Horizon. The techniques of neutron activation analysis (NAA) and x-ray fluorescence (XRF) were used to identify eight main types of obsidian and to infer the locations of the natural obsidian sources. These data~ in conjunction with the findings of the archaeological research, have been used to make observations on the changing patterns of regional and pan-regional economic interaction. The data are discussed in context of the role of obsidian in ancient Andean society and the social mechanisms by which this rare material was distributed. Obsidian, a natural glass, has a hardness of 5.5 on the Moh scale (slightly harder than window glass) and is similar in chemical (but not structural) composition to granite. It is formed during volcanic activity by the cooling of viscuous lava rich in silica (over 65%) at a rate slow enough to allow volatiles to escape, but rapid enough to prevent crystallization. Because crystallization does not occur, obsidian a vitreous luster and the abili to produce conchoidal fractures struck. is fracturi characteristic is one its most i ortant qualities, p s all stone artifacts idian amen le to precision chi idian sui le on of ifac mu come

ions 9 usual iary or ~ because it is e tr fies over time~ los; qualities

is val ver, even some recent obsidian f 1o~"s suitable ippi ause tors s as the presence phenocrysts, spherical aggregates~ or hydration

groundwater. ~ although obsidian has great potential for use in tools, it occurs rarely~ if at all, in most areas. 1 In the

s, obs i dian de its exist in the highlands of Ecuador9 2 tra 1 sou Peru, 1i a.

SIS re1 ive scarci obsidian suit le tools resul in obsidian over long distances. Archaeologists interested in anc i trade communication have ac ter is t 'i c s idian useful in reconstructing these movements. Obsidian from ical sites can matched th natural obsidian sources use ical fi ; nt i methods. visual qualities of obsidian are rarely of use in distin d; idian sources. Bl , gray, c ear, sidian can all occur in a single is misl arc is co ir idian collections us; sua lities. 3

on can, h and ld ; dian

s at t most tive met d i in sh d 2 sources is ana el el is one

1i c t on is t idian comi one source trace e 1 ition as fingerpri le source must be 'small in ison di sources. These as ions been ri

Asaro 9 and (1 9 a & b). Their i di an sources can is is case ( as n the single i dian source in lifornia)~ vari ion is extraord nari removes icul in ifi vari ion in source's el composition. itional

ven i ence ana is less d of or ceramics. ies of quartzite statues n t i a 1 tional variation in a s gle qu source izer et al., contra th i dian, on al source i 1 as sources. sources. ience

q s ld le measure d el tech-·

niques u wi some success. are activation

ana is x fluorescence ical 4 in arc ies sidian ven ience s varied consi is has imes resulted in mistaken identifications and inability to distingui between sources. The accurate measurements published thus far have been made by Perlman, Asaro, and others using NAA. Ideally, provenience studies of obsidian should begin with analysis of several samples taken from all possible sources which might have been used in iqui unate ,in the Central Andes the st little ion. sidian

use was n time ish is tor' i c

gives no clues for the location of idian sources. Therefore~ ne geologists nor archaeologists have a useful to location of obsidian sources. Because of is, it has been necessary work in the os i te d i rec t ion.

is study, obsidian at 94 archaeol cal sites

in Bolivia was analyzed to determine its trace element com-

itions. These determinations were used to identi the di

i dian u i di an s a di inctive geochemi ! ich corresponds to an ivi al source raw i dian. the exact source ions are ssi

in one case~ it t each i di an was

thin circumscri ical a~"ea . is 1y 3

ies Old ld ans s most i ve use

4 an idian occu rs near source. di ons idian a i ic ion

ion i cases is iques u in were on ana is x-ray uorescence. ion was consi an essential technique because hi ision measurement of a large el It was relied on dis tinguish between different types of obsidian found in archaeological contexts. is was done determini absolute amounts various trace elements. The results of these nations served as a guide for this st 11 ~ no t, The neutron activation ique u Lawrence is time cons 1i t s les which can be run. all, les were run is The ndings of the neutron acti i on an ali s were develop an x fluorescence techni specifical desi distinguish the different of obsidian. se whi used a more 1 ited of , were less cost An additional advantage is that it is ive. lese ini s le ible ici b e some

ca are summari applied NAA to obsidian from three sites in the Departments of Cuzco

Puna, Peru 1973) . XRF 32 pieces Bolivian i di an was 1i shed recent ly ila Salinas, ) . There are disturbing differences between our results and those of ila, 0.1 the samples analyzed from Tiahuanaco and Sora Sora were taken from the same obsidian fragments used in the study of Avila. "

NEUTRON ACTIVATION ANALYSIS

This section describes the NAA procedure used at the Lawrence Berkeley Laboratory for this study.5 To begin, the obsidian sample is cleaned of surface dirt, usually by scrubbing with water. The fragment is then pulverized by hand using a mortar and pestle of . One hundred milligrams of obsidian powder is measured with a Mettler balance to an accuracy of 0.1 mg. The powder is thoroughly mixed with 50. mg of cellulose binder. (Previous studies have shown that cellulose does not contain disturbing levels of impurities.) The obsidian and cellulose mixture is made into a pill (1 cm x 0.12 cm) with a hand-operated press. The .pi·lls must be standard in size in order to maintain a reproducible geometric arrangement between pill and detector during the counting of the gamma-ray radioactivity. The pills are first encapsulated ;n 0.0025 cm polyethylene foil, and then placed on edge in a radial array inside a heavy-duty polyethylene capsule. Within the capsule is an B-position jig which holds 5 unknown pills and three standards. One II standard pottery pillil ;s included in each er, placed in diametrically opposed itions. The 11s are irradi ice th neu in a reac . The first i i at ion 1as 6 nu a ux 1. x 6 ion 1e is is wi ills, insures pi 1 s are same 11 is ion, pills cool nutes are transported , The effect the neu ardment is to certain isotopes of the elements in the pills i radioactive species emi~ gamma rays. These gamma rays have energies whi are characteristic of and can be used to identify the different elements. When a pill is analyzed for its gamma rays after an irradiation, a fraction of the gamma rays strikes a solid-state Germanium detector. The detector absorbs the energy it i electrical lses pro- portional to the energy absorbed. A lse hei ana then sorts out the electrical pulses, making it possible to relate them to different elements in the pills. This information is stored on magnetic tape. The accumulated information on the number of lses of each energy level coming from an obsidian sample can then be converted into absolute abundances of the elements being measured in each pill. The calculations needed to do is are so time consuming that a computer is a necessary aid.

Foll ng the s on pill s are repackaged in high num foil, placed in an num capsule and i iated again. is t are arded maximum ux reactor 2 x 3 neu a 1 num ins ers s er nu a i reso ution i

wi 1i i um 0 The p 11 inue cool

2 weeks are 3 a 7 cc Ge(Li) detector. Then n on hi resol ion detector. Thus each pill is counted al 5 times. the counts provides measurements for various trace and major elements depend; on half-l fe, backg and factors.

This NAA procedure is able to measure a large number of trace elements in the parts-per-million (ppm) ran ~ some with a precision of measurement less one error. is h precision for many elements eli nates amb i in z on of id an sources.

A large number of elements are c ear iC 9 ruling out lumping sources wi some cal si larities. The high precision of techn ue is partial due the use of standards made an art; ieial enri ne c1 i is careful analyzed for uniformity. the best trace elements~ a reproducibility of or better been ach i the calibrated pottery standard. This is sign icant since the accu of ana is for each element cannot than accuracy measurement the corresponding e arrive at sol quantification, the gamma sities for each element are compared its counterpart in the cali The n sources error remaining in is procedure errors ica errors i i s resul es i an s es

i dian 1 i z were on s 1i

XRF results. Sampling different geographical areas t augmented this strategy. After the techn ue was on the basis of NAA res lts, was used to analyze those samp es which appeared in XRF tests as aberrant, ambiguous, or surprisi from an archaeological perspective. A summary of the mean compositions of the best measured trace elements for each type of obsidian is presented in Table 1. The results for all runs have been included in the ix.

X-RAY ESCENCE (Rapid Scan XRF, U.C. Berkeley)

the Spri and Fall in 1973, R. Burger i d scan x-ray fluorescence tests on 380 pieces of Andean obsidian. An idian sample was excited by irradiation with energetic x rays. The el in the obsidian sample then emitted a spectrum of x rays which were passed through a crystal and sorted so that they could be detec electronically. The relative intensities of each element were in graph form as peaks of different heights. these tes spectrum between ni ium and rubidium was analyzed usi a Norelco iversal Vacuum X-Ray Spectrograph with a t Li analyzi crystal, sci ill ion detec th discr nation~ and an air p anni at per nute. i di an were is irconi on tri

9 is ue s u R0 izer

in soamerica 1 ) 9

1i id an 2 is technique successful s les three it was not clear whether these s si le idian sources.

is 1ack of discrete groups was resol a larger of trace elements with ision showed that two of the three groups establis id scan did represent material from dis obsidian sources. One of the groupings was actua 1 composed of from different sources.

X A cross section an sian ifac used in is work was analyzed high precision establish a number of chemical groups ich were easi di in ishable from each other. From these udies it was elements could be used to distinguish Peruvi an sources they were precise measured. The expense of is precluded its use for large numbers of was deduced t measurements of the abundance barium (Sa even th rel ision (-10%), would disti a derance ified ies remaini could resol wi a is ion

source 60 keV of 24 was used to exc Ba atoms in the obsidian and produce Ba K-x rays. The K-x rays and other radiations from obsidian were detec a silicon solid state detector, whose pulses were amplified collected and displayed as a spectrum with a 512-channel pulse height analyzer. There was a peak of In K-x rays in the spectrum caused by excitation of In in the detector system. This peak, which appeared in all Sa spectra, served as a reference point for defining the position of the Ba peak and its back­ ground region. The 60 keV gamma rays from the 241Am source, besides exciting Ba (and other elements), also scattered from the obsidian and appeared in the spectrum as a broad peak (backscatter peak) somewhat lower than 60 keV. is peak was used as an efficiency monitor into which all Sa peak totals were dividedo Cerium (Ce) was also measured in the Ba determination but because of its relatively poor precision of measurement (~10%), was not as useful as the Ba. However, it was treated in the same way as the Ba and its abundance determined in every run. Both abundances were determined by comparison with a standard of Guatemalan obsidian from El Chayal. The Ba and Ce abundances of the standard were 943 and 48.4 ppm respectively. In the Sr measurement the radiation from the 241Am was screened with a Cu absorber to reduce the intensi of the L-x rays. The 26.5 and 60 keV gamma rays of 241Am struck a Ag target which then emitted Ag x rays~exciting Sr and other elements in the obsidian. The radiation from the obsidian was stored and displayed in the same manner as in the Ba meas '''''!"limA'''"\''" There were prominent peaks of backscatter radiation (the scattered radiation) whi same ener es a.s K

K=OL in was u

itions t ions.

wa.s so a i at i on (t inc ly K=x lower energy than the K-OL peak ~ and was u sed as an ici mon; The Sr peak

atl was d ided is backscatter peak total abundance determi ion. dances were determi comparing these

i as the i di an if ac th those a of El idian. rconium r idium If,fere measured in the same , Zr", wey'e usec! ianj) were tively.

was b ion t t s le in place on orescence in and run~:) ,

was se spectrum. In runs ~ ratio

b ter a given osition i di an varied th s ness; is var i ion an error. The variation cau if the le thi ness were known, th'j s mea ness was ious if acts of

size s t is re 1 to ness, an irical ea 1 i on was is re 1 onship. A correction was only necess er if acts, and is never ions were necess runs.

ian 1es "Jere on em i 1s an

ld i 1ar ils turn~ were moun ina s le it ions. tions ld one one ition w on a il, one a pl ic pl sidian artifac

a run on les lI result; s les were a Sr run (or vice versa). The standard was anal several times, and the artifacts were sometimes anal more than once as the sample changer would recycle ri its normal operation. tra were dumped from the lse height analyzer onto magnetic tape after each sample was analyzed. The magnetic tape was subsequently processed

by the LBL central computer facilities. Sample changing~ radiation counting and data transfer were all handled automatically. In compari the average abundance for eight of Peruvian obsidian as measured by and the methods described above, the average difference was 3.8%. For Ce the average difference was 2.0%. is suggests that calibration procedures for Ba and Ce in the XRF measurements were essentially correct. The root-mean-square deviations for Ba abundances as determi ned by the XRF measurements were usua 11y better 7%, which was more than sufficient to make the desired assignments of proven i ence . The results the XRF measurements appear in le 2.

OBSI

assess meani Hi an i p of obsidian

in u livia~ it is necess role wi in ancient an is ro e most

1i k mul t vari to oea 1 ec c

13 i ona 1 cu 1 it ions II di icul ini

it is sible some

ive i s role i di an us i

i di an seems u exclusive production

1s. such too1s~ points are far the most common. Obsidian points are obsidian was used, at sites obsidian seems have used exclusively for poi (e.g.!) ia a) .

some si s, i di an was secondarily used for other types of too'S s as un ac i a1 scrapers (e. g. , San Ni co 1as, Pucara, Taraco, Casavilca),

rins (e.g., ) , gravers (e.g.~ 1970, p. i di an it is also were liz (e g., a; communi ion) .

great in size, and qua 1i these served as on ected by s In at i a, an obsi di an int was found in association wi (Engel, , p. ), suggesting is use of i di an ints dates c times.

e, in graves i ;zon,

wi in one case, fores were connec

F. d an ion an i dian the ropolis

le izon aco icts arrows ti poi

14 ian~ since small idian are at Ti anaco

o XXa; ) 0 so ser as bl ives tips of s

use obs i di an ives in late Ear izon and Intermediate Period mes is documented in late Paracas and Nasca iconogra

ng and fracture patterns on points from Media Luna in the Cal~ango

Basin, lca confirm is (Burger 9 unpublished data). From Ocucaje 8 to Nasca 6, the pottery styles of Nasca and lca show representations of black tipped darts and knives. The more naturalistic of these depictions can be linked to archaeological finds of obsidian weapons at local contemporary sites. This has led Lawrence Dawson to hypothesize many of these are representations of obsidian objects (personal communication). Beginning in Ocucaje 8 the hypothesized obsidian knives are associated with the taking of trophy heads in the iconography. These representations are extended to the textile medium in Epoch 1 of the Early Intermediate Period (O'Harcourt, 1962, pp. 110 and 112). ical beings such as the late Being or the Killer le are often shown holding an obsidian knife in one hand, a tro head in the After Nasca 3, representation of obsidian

ives became uncommon~ obsidian often are s A Nasca 5 vesse 1 in the e logy~ Berkeley~ shows warriors wi idian darts and spear throwers; each the warriors

at scene s a raid in ion.

insi into id

iles in arc i

15 id case was an i di an in a c ave ca Ravines

s i di an i 1e

, caus i

A si 1 ar f was a. is instance t obsidian-tipped arm viet so y t the side of the arm bone ge 19 1966~ F go 59, po 212) .

Obsidian were also used to ld game. A Nasca 5 vessel in seum shows a nting scene in ich obsidian ti sa i 1 h air towards several wild camelids ( anacos .

di an pl an role in ily s s ities ancient dean e especial n ing an s

shear i domestic camelids. lmore speculated igin sheari must have ired speci lements, perhaps obsidian ves. lists are

0 to use broken glass for s alpacas (Gilmore, ~ p. 446)

i 1i tar i an use of becomes evi on in 1ate is ic t I Peri and zon) p ease id an one s s s. i di an so a ot

e, 10 Co 1 0 a ical kit at Paracas inc an s

b 11 110 \} i dian 1s are d sizes s rel

'« ra e 10, , p. J

1i tar i an sis on among anc ient an on logic ancient soci i es, obsidian was used extensively ritual ects. Some examples of this are the ritual caches of eccentrically shaped symbols in obsidian which have been found throughout during the Classic Period. In the Near East after 4000 BC, obsidian was traded almost exclusively for the production of objects such as bowls, statuettes, and tables (Dixon et al., 1968,pp. 38 and 46).

in Peru, i dian is not lized. In fact, the only verified case of modern use is in the folk medicine of the Tuqsa area, is ince~ (Percy personal communication) where is believed to have curative Such medicinal uses of obsidian occurred also in ear Colonial times and perhaps much earlier (Cabo, 1956, p. 135). In antiquity, obsidian undoubtedly had some ritual uses in the

Central Andes. An ear Nasca ritual knife has been illustrated by

Dissel (1972, p. 277). is knife has an obsidian blade hafted in a licate pai dol in's palate; the knife is reminiscent of ives he 1d ities in Nasca iconography. Besides this

ece, id an obsidian mirror fr in a

le ilon (1 , po Fina 11 ~ in areas ou i sid ian ~ s as

rare i di an nts were va more as as 1so

17 I ~ obsidian was di in the anc i to serve as 1s necess sis iv ties

in idian was a raw i i a 1

existence of common le, one sense, di i t i di an have more in common th the exchange of ricultural

commodities or salt, than did wi ei long di ance trade in

prestige goods such as lapiz lazuli~ , or exotic pottery,

or wi commodities traded ong distances for ritual purposes, such as spondylus and strombus shells. Thus, one should expect the patterns of obsidian exchange to differ from exchange patterns of these other trade goods to reflect different kinds social and economic interactions. Moreover, the mec isms ich idian was procured

also have dis t inc t from e at rare raw s. QUISPISISA SOURCE The dely distributed Peruvian idi an came from an obs i d an flow Qu s pis i s a i n the hi s near San Genaro, Castrovirreyna Province, Department of Huancavelica. s located hear the headwaters

Pisco River~ whose shores lead down into the Department of lca. This river ley provided a n route

hi good s, inc 1ud i dian, nto the Sou Coast. is isisa Source is also convenient loc for access to rver systems, coul hi ic in to ars Hisp

commun i es in 1 an 1 s exclus ve

+- u ispisis d an. i.,. an

18 idian sources are ise it is 1 1y t

isisa is c source of hi sidian in u. is th its strategic lac ion, i ally distri tion.

time~ the ispisisa is the on verified source archaeological obsidian. Rogger Ravines visited the flow and identified a quarry area (Petersen, 1970, p. L as we 11 as a rock shelter (Ha3-2l) below the quarry ich was inhabited in antiquity. Obsidian samples collected by Ravines from the quarry and the shelter were analyzed by neutron activation and x-ray fluorescence at the Lawrence Berkeley Laboratory. Trace element analysis by NAA revealed cal composition of the obsidian from the source area the idian artifacts collected on archaeological sites Huamachuco to Cuzco and from i 110 to Acari. Three samples have been tested from the quarry itself. ive samples archaeological contexts were identified by NAA as coming from the is pis i s a Sou rce . additional 321 archaeological samples have been found~ on the basis of XRF9 to have come the Quispisisa Source. The obsidian Quispisisa displays great variety in i appearance; it is black, gray~ streaked~ near colorless,

h red~ or red led. There is also vari ion in its terms trace el ition, the source (or source i qu i is (see ix

(" is s isa me was exp 0 in "'9

10l1g dis movemel1t its i d -j an consti some t earliest ev i al i ana 1 ex excava ons of e Archaeological anical Project revealed a long Preceramic sequence. is is of special interest for the purposes of is article because it shows that obsidian tools were used in the Ayacucho area duri these early times. Because only the preliminary findings of the Project are published, it is necessary to exercise caution in interpretation. Sixty-five samples from seven of the early Ayacucho sites were analyzed (see Table 4). These samples came from sites in several micro-environmental zones: the tundra, the humid scrub forest, the desert, and the dry thorn forest. Samples from zones Nand K of Jaywamachay are the oldest. According to MacNeish et al (1970), C14 determinations suggest that both samples predate 9000 BC. tests find that the obsidian for those flakes came from the Quispisisa Source. Thirty-seven samples come from levels associated with pre- Piki Phase materials. These obsidian tools and flakes were the products or by-products of a pre-agr cultural society. Over 94% of the obsidian tested from these levels came from the Quispisisa Source. This mine continued to be the main source of obsidian during early agricultural times (Chihua and Cachi complexes) through the end of our sampling from the Ayacucho sequence, at around 800 BC. Obsidian was found by Browman in materials from of his Preceramic units: the Jurpac the nyari (2800 Be 1500/1000 BC). Trian lar i di an i nts

were i ass h i s

~ p. . a so~ al communication . 20 in 11 1as ~ ions c site of

i ncu less t a an fl

II it can i dian use here was more rare in anc or i ncu was J rig i n ,:i 1 1Y occupi about 7000 BC and was finally abandoned s the i ion of ceramics (Ly , 1970, p. ); no precise provenience is provid~d for the obsidian akes. Considering is known of obsidian use during the Preceramic of Ayacucho and of later periods in ayo the northern highlands~ it is likely that this untested obsidian from Huancayo and Quichqui Puncu also comes from Quispisisa. The site of San Nicolas, Nasca ince, Department of lca is a 1 ic shel ~ invest; fi ncan

9 freder i c [nge 1 and 1i us (1963). Vescelius noted that obsidian is 1ent at si Strong recovered several hundred pieces of obsidian debitage, and Vescelius obsidian points and an obsidian scraper (1963, plate VI I, 1a, b, c). The San Nicolas is still problematic, but the discovery cotton in excavations there suggests that it belongs the Preceramic (Bonavia ines. 1972, p. 39). Forty=nine fl from Nicolas were tes all were

ispisisa i dian. Nico'las was not on ic si on the use i dian. i di an art if acts are a

avilca in lca 11 near ia

i a in 11

L idi an 5i 5C have in sites i di an 1 in two graves Lanni p.

I s si so Q s si i d i

A nal piece use i di an comes from in ) . near eces wor is site\)

on ly one was i d an 0 was a leal distinct

other artifacts site s a~ commun i ion) .

; nt was is i dian. The

ing of is unclear t other

s t c as as 11

evi some i cations

transport isisa

imes. Since 11 ama obsid an must have sli less t trip s ed economic en vi V"" ...... nr~n

1 i d an di si s as

tri rous ivi als s ld not ruled out. iliz ispisisa idian in ie times and probably extended least as h as the Cotton Preceramic, Quispisisa obsidian was being used by the people of the Suuth Coast, as elear seen the site of San Nicolas. is is definitely an instance of ear contact between the sierra and coast. The obsidian being transported from the Quispisisa Source, in these early times, seems to have been unworked or simp roughed­ out, as evidenced by the considerable amount of debitage at the site. The use of the Quispisisa obsidian source conti itial Period. The scarei data on idian ( on most ot s ec during the Initial Period in Peru makes large di icult to discern. The authors had access information on Initial Period sites on the South Coast: Erizo in the Department lea in the Department of Arequipa (Rowe, 1963, . 5-6; and pp. 26 and 30). The inhabitants of both sites used obsidian artifacts. The three samples tested from izo were made of ispisisa obsidian.

Fifty-three pieces of obsidian from Haeha were tes ; two- i of these came from the ispisisa Source.

rough same t ~ the res i a as

Pro nce~ Department were related to those H izo 8

excav i di an

s t a ion ian comes is is sa rce, ka, low ties u s is sa an seems

In i a 1 inc se i

see le 5

A second id an was h a Hacha. t di communic ion between the s erra nitial incl a ex exotic ncludi i dian. ispisisa exceeds 475 kil trip from ki 1 less. was an un n cul

was uence s a so ev a fi ansion in ures s to a re igious cu t, centered in in, Huari ash.

s lars ul a ar 1it i ca un t on ide

s the commerc al k ich incor=

h an

k to c times.

antit es di an are n zon n t area s

s es were tes Q an site b

na e 0, es so s t in o 5

le area. s have is sisa kil distant (one-way). It

is si ific t t on obsidian disco at

Expedition had h in i ad assoc i at ions

. 124 and 151; and ~ 1972,

nearby site of Shillacoto~ ich 1acked

Chavin style material~ the Japanese found no obsidian.

her sou old network of obsidian exchange seems to continue. Obsidian was tested from three Early Horizon sites in the Huancayo area

801-B~ 685). These sites belong to the Pirwapuquio Phase, ieh is rough contemporary to the important developments at in). 1 e i the s 1e s we reis pis ; sa. is obsidian was also used during Chavin pre-Chavin phases at

Ataura, a nearby site in the Central Highl s (see le 6), Obsidian was the common chipping stone material found at the Ear Horizon site Chuncuimarca (15 north Huaneavelica)

(Ravines, 1969/70). ght llace obsidian points at a

ake associated th aje Phase 3 materials ;110s, lea (1962; personal communic on). obsidian excavated C. Patterson in levels in k site, on , were be

is

t ispisisa i di an t conti in 1 s in

i 1uence in ilon. f an increase i dian ins i is les isisa. same me in si were i

si of uana ~ are no especi al large

ia Luna came is sisa; ali se s the nance of isisa obsidian. s es taken Ear izon sites in refl same pattern

idian utiliz ion. These iti s es came from Cerro Prieto

e 9L a ia ' .." ... UI,,",U~ e 9, ear

i so u

i di an s is a. site was idi an le was i isisa

i di an f ac ts assoc i th 1ate

Ear izon lorado in Pisco 11

38- ). lliam Isbell recent ocated a late Ear Horizon or Intermediate hi 1 site several kilometers south

the Cabana i nce,

is site or )~ over idian tested came spisisa.

in ispisisa di an i I

s areas as ate izon 9

on a esser scale 1i le i dian wi

I ate associ ions was avai le is

f

vi nee, s i less

h f came isis 0 It is ri le s sa s was sea evel a ung in cross re

I 11 recovere excav ions on s si communi were ana is .

ui an were even s a L itu ) . ic since s 1 si incl s.

In Hi 1 s ~ i di an was least as as is isisa s es ons were ana were assoc wi from

le izon si

d an f isisa ci i ana 1 ir were p sis a i dian. que are

s 1ar t a

e in his s s sin t area came al communi ion.

Obsidian was di ted le i zan s i in the Highlands between anc area, Browman notes an increased of dian in Intermediate Period, carries the first

Middle Horizon. Samples from sites is time peri (J u~1 616 and JuM 618) proved to be from the Quispisisa nee Bennett un- covered four obsidian points associated with early Middle Horizon ceramics in a deep stone-lined tomb at the site of lkawain aras Province, Department of Ancash) (Bennett, -31). No Middle Horizon obsidian was analyzed from the Coast and the authors are unaware of any Middle Horizon examples of idian found there. However, this could s ly reflect current state of archae logical research in this area. On the h Coast, one of two obsidian fragments recovered by the --Moche 11 ey Proj ect in the extensive surveys and excavations came from a Moche V graveyard. The obsidian point was found on the surface and thus has no direct associations. However, material from a near grave included a face- necked jar and a IITiahuanacoid ll sherd U,1osely, personal communication). the poi nt did indeed come a Moche V grave, it from one in servi as a nt is idian. decline re seems di rs H

Quis isa i i ve in area~ is is sa di u es. idian is not Coast in post Middle Horizon times.

101

source is obsidian is not if made it are known on Preceramic occup ons sites in

the Ayacucho area. It occurs at Iomachay (Ac 102), Ac 500 9 and Puente (Ac 158) (see Table 4). The sample tested from these sites is small, but it established that it was used as early as zone 13 at Puente (approximately 7100 BC) and as late as zone 0 of Ac 500 (approximately 3000 BC). In the sample tested, it was only common at sites in lower micro-environmental zones. The apparent absence of Ayacucho Type obsidian from all sites outside of Ayacucho suggests that it is probably local; however, Quispisisa Source obsidian seems to be quite common in the sites where Ayacucho Type obsidian was used. It is worth noting that obsidian from this source was not found among the 52 samples tested from Huari, which is located near the sites where Ayacucho Type obsidian was used n Preceramic times. Presumably, the Huari Empire controlled the area where this obsidian comes from, but those responsible for the procurement of obsidian either chose not to exploit it or no longer had knowledge of its existence. Another possibility is that the obsidian deposit was small a was exhausted by its early exploitation.

ACARI OBSI source ience is idian is un

The on archaeo ic site ed ich oi idian

is source is in i i idian pi eces s s n t ~, i te .

s ld in t s s i I.e

uvi an cali s s his source may

1ar u dcent hi s.

I

of i di an comes a d si i r~ southern Peru. Recent lorations Kat Schrei icate that t may come near' in anas Province, Oepart-

is i dian is common at archae-

01 sites area sou Ayacucho

(sur i 11 i I id an was at several

s is area: i ) , 5-5 (Coracorral or 5 (Ki iucu).

i di an s1 is

5 ive as 1ate or EIP

5 is an ear Mil e izon si Isbell, communi ion .

i di an was also i 1i 1as area

sites a ia a vi t

) , A it continued

n 1atev" ti rox

i nts is ian were

11 use i dian, as we 11 as isp s isa idianj) in h evi an niti tionj) so ref1 ected in ceramic styles. is t the areas where Type i di an has been detected a rough t per i cu 1ar to the coast, running the Acari and Pampamarca Rivers.

The ~ingle sample of Pampas type obsidian identified from outside is transect was from Wimpilla in the Department of Cuzco. The long and complex occ ation of Wimpilla makes it difficult to interpret the significance of is surface find.

DAHUAVLAS A TYPE 1D The source aylas A obsidian is not known. sites s ed, it is heavily represented at sites in the Andahuaylas area. site of Waywaka, Andahuaylas A Type obsidian i ded more t 40% of the material tested. It was the most important type of obsidian used there during Initial Period and Early Intermediate Period times. Andahuaylas A Type is also the source of the four obsidian flakes found at the site of Qasawirka (Ap 2 )~ a nearby site roughly contemporary with the Qasawirka phase (Ear I i ate Per i od ) at Waywakao At Huar i , probable center of Middle izon expansion, one of the 52 pieces from the surface collection sampled was the as

A 1y, sole piece of 1as A obsidian was ta, e

ocal ve le izon 1as A id an was also si 5 and n nee so

i sec on, sites in a

anas sid ian in common were ly

interac ion some time. a, 3 a ece as A dian was ami le Horizon 2 refuse in the uppermost dist 1eve 1 .

LAS B TYPE OBSI01 Andahuay'f as B obsidian is known only three archaeological sites, in the aylas region: a, Santa Elena, and Its use a is in occupations si It is scarce or al ant ear ion site. Andahuaylas

B obsidian is ei fou associ wi a Phase occupation (early L i ate ), in i a 1, or on the s ace wi i a . source this type of obsidian is

PE 101

lCO i dian at near all ar aeological si co. It ified at

ical sites in t inces co, is,

co ian rare y occurs si s I source remains o z ic ion).

re 1at

h ast

it i ona 1 lem evaluat our restll i obsidian les an come from s ace co lections at multi-

So

source was u c. The cave si i, near Sieuani a, Caochi')

i nee i ali an flakes a late ic in; associations s a rel ive is 1 cOO11lun; on;

ion) 0

ion on i an Highlands is ly se s 11 more ful in a is COO11lon associated

le in exc ons P.

si 11 e. is was so le e

cs in t re ist at Pikicall near

Sicuani. cs s \l are COO11lon associ es i id an

) 0

s el ia a 11 e ~ levels at Pikicall a containi s a contin reliance on

i di an s collections at si a so revea utilization

14, Cz 2=10). Marcavalle and Chanapata styles are thought to be successive styles used in the Cuzco area during most of the Early

Horizon .(Rowe and Menzel, 1967, Chronological Tables). The following style, Derived Chanapata or Pakallamoqo, is currently considered to have been used in the beginning of the Ear Intermediate Period. Derived Chanapata and CUlCO Inca style ceramics, along with an abundance of obsidian artifacts, have been found on the twice-occupied IUrqo (Cz ) site. Since obsidian is rare on Inca sites

in lCO area and ly common Chan a e sites, most of obsidian debi nd at IUrqo probably is related to the Derived Chanapata occupation. Twelve of the thirteen samples tested from ·Urqo were CUlCO Type obsidian. The inter between Derived Chanapata style and Early Inca or Kilke style is not yet well understood. The sites of Qotakalli and Tarawi (CUlCO ince) were occupied during this interim period

in later times communication). A small sample of obsidian tested these sites proved to from the CUlCO source.

i di an use ri I nc a tim e sin co was ly rare. is is evidenced scarc i dian on co si Inca origin

is same conclusion was re

les his stu Inca lith cs CUlCO al communi ion) . occasional use id

I s fi

i di an fl at a. e s es rom se s were

zco e i di an.

As noted~ outside of the co, co Type i di an is rarely found. two fragments CUlCO obsidian were identifi from a (Andahuaylas nee), one wi Qasawirka style as so- ci ions and the other in a xed Muyu Moqo context; is constitutes less t 2.5% of the s les tested from W a.

The appearance of small qua ties CUlCO Type obsi an in some

lower levels Qaluyu, reci 1 occurrence

Ti caca Basin an at 11 e Pi calle ta ~ tes to communica on between these two areas ng Ea y i zon meso er samples of CUlCO Type obsidian surface mul -component sites in no leave open the possibility of er contact b e two areas in later times. In other areas of the distri on obsidi an seems to have been linked to the new lines movement and communication established reo A si le ece i di an was identified ve s es t Jinc ari center n e wi s

a i di an from come source. e a nite

i ence a eces in was sian i area.

I idi Titicaca in occurs cal si s

. i n southern u and nort Bo 1i v i a. The source is of idian is an of is was by Burger near of all i , Melgar nee, . attempts to locate a source in this vicinity have failed. eight archaeological sites in the Department of Puna from ich obsidian samples were taken used Titicaca Basin Type obsidian. 93. of s les sted were is Qal Titicaca Basin Type idi an i ded materi sixteen of the

1es ana lyz ed ). Accardi to Kidder i di an debitage also is pl at the sites of Pucara (p. )~ Ayrampuni

(p. 20), and Incat iri (p. 15). the site of (Chucuito Province, Department of Puna), obsidian points and debitage were found on the surface along th

1i ics of other i a 1s . At 1east of the obsidian from this

the Preceramic (Felix Palacios~ 1 ). , in to sites s led, the Titicaca Basin Type was on source of idian used.

idi an ana exc ic

ticaca n was loi in area izon lence Titicaca in

ian 5i

S i clian i ear c soc i a 1 i on on rrence Titicaca in n area Sicuani t is area

Pik c a~ T ticaca id an more s e. twas even more s les en the nei sites

In Cuzco area~ Titicaca Basin i di an about material analyzed from the Ear zon site of Marcavalle. In the area, Cuzco Type obsidian made about 6% of obsidian s Qaluyu and is a so found in Early Horizon levels at Taraco. si ticaca in obsidian was more common than

n smal s le ear site i s nce, zco) . It is

sible t use these two obsidian in C is goes k to Preceramic times. In Puna area the use of the Titicaca Basin source was arent 9 li and is obsidian is present in q even at the late site Sil1ustani uro iz Estrada, son communication; garet person communication). ticaca in Type obs dian was also u on 1i v ian s i . of the obsidian tested from ahuanaco came

s source. s les i di an 11 a (K a site 1ve k ahuanaco, also came is source. These s les d in excavat ons associ with

le ceram c i a 1 ( . u ion . D E eig idi cr al re at i 'l:/e ar si s these were cases samples were ana 1 re samples came in sample upon ich is stu is based. will remain anomalous. Two of three pieces s from (Dep of Puna) were made a rare i di an 1e is is ial source

e i dian y an one. Three s les a trace el ition disti from t ed. of is occurred wi associations; in ixed Moqo refuse. The was on s ace.

Si le unique s have (CUlCO i nce, Department of Cuzco)

artment of ) . The s came a s ion s les ana le some s arit es as A

an cal re ons w

1m" qu were source in was 1 logical~ was consi source in it ipa sources idi an ana arc

ELS STRI BUTI MEC ISMS The provenience and distribution data on obsidian, or on any other material, do not in themselves provide adequate data for inferences on the mechanisms of distribution and the kinds of social interaction associated with it. The absence of both a complex market sytem and a large merchant class in Peru at the time of the Conquest should act to caution the projection of models of trade developed in Mesoamerica or the East. se of the distinct character of the Central Andes, may be ile to present some models of pre-Hispanic obsidian distribution drawn from ethnographic and ethnohistoric research. Travel and trade are basic components of adaptation to the vertical zonation of the Central Andes. Some occupants of the lower and upper zones traditional spend at least part of the dry season in other lower ecological zones exchanging pr'oducts for foods, especially corn, grown in lower elevations. Study of the energy flow in Nunoa has s it is is exchange, favorable in terms energy use to the puna dwe 11 ers, that a 11 ows the current human adaptat i on to cont i nue

successful (Thomas, 1 , p. 137; stred, 1974, p. 280) 0 also seems 1 ion leave in season

ir in on erl'wi 9 S

1 ve season. are usual y male ani a son Flores Custred, 1974, po 257). These are known exceed kil tr p) in (Flores 1 s are a1 to ac i ional and

ts, s as s t or wi 11 even more favorable (Custred, . 278 ; Flores 131). In some cases, products are still exchanged b trading partners may be acquaintances ot zones, re ated fictive kinship (compadrazco), or blood relatives. In some ethnohistoric cases, members of communities settled in other zones to insure exchange (Diez de San Miguel, 1964). The distribution of obsidian could have been integrated into this basic Andean economic pattern of zone inter- dependence wit difficu Obsidian occurs in geological recent volcanic ions common found in the upper puna (usual above 12,500 ft). spots ItJOU 1d have been more accessible to ancient a dwellers and their camelid herds than to the agricultural people of the lower zones. rther9 the possession of llamas as pack would have given the puna dwellers an added advantage in Qbsidian trade. The actual mini obsidian could have been done traveler-merchants or by permanent resi at the mine. Such m ners could have been in dent or led as co on sts ot communit es.

"i n cases a community controls al basic zones of on ~ a is rs si le

s is cases 9 t s s e se

secure rare ia s s 9 ) 0 s can serve as an

ts i area

is did a ro in s in s. did exi in ic as ev lizarraga1s

I gourds

as as ) 0 The work

ki were both numerous hi currently

i non local communi i es (Webster \'

in p to is out.

i di an sources,

a 1 i di it Q In Inca t

s i 1ver , . ) was

I I I ) . 1s in local

. ) .

tri ou ons s ) . rel ionsh would have ser as an exce 1ent sm d sian on ic cul

ivi s d areas viewed from a regional or s ra tive~ can 11y inferred from material remains (s as obsidian) arc ist. The identification, through provenience anal is idian, of such interaction spheres in the prehistoric record has more than re economic lications. The hypothetical mechanisms of procurement and di ion outlined here are all mutually exclusive. t is ible several coexisted n different areas or were used in nction. In addition, earance ic obsidian a site is necess ar i ly due exchange or distri ion; it a of people travelli at rposes leavi ir personal tool kit. is could occur th sol ers sent to a foreign province carryi obsidian tipped arms produced in t area where they were original stationed. Large-sc e of troops civilian lations under Inca resu ted in is kind of A second case would be that a

11 er on a long ip breaks his e i e in dist commun ei or disc it.

D1

A ana is s s

01 s v e s i di an

s 1 i

i several i to economi soc al are t idi 1f. t s ion are

on cal trace el ana 1 i dian ~ their

i ical interpre-

ions on ana is ifac

u as a on ki i It can also unction economic lon ion i wi

In is s i sa i di an is i i seems ive1y in core area and

ex; is i di an

c i nues intact unt i 1

area as"

i is sis ~ ir access to or sources

cUl i 1 nort is core use ian s ate

i OWu i

c c on our i di an ana i s ~ 5, inter-

ion can the H s: one thE: Titicaca

in CUlCO. t Sicuani area s ts

lements t were on t sout edge of the CUlCO s dati as far back as the Preceramic. The obsidian data are high compatible wi earlier views on Andean culture history. The absence of Titicaca Basin Type and Cuzco Type in other

parts of Peru suggests cultural and economic isolation, which is 3150 reflected in ceramic styles. Rowe, for example, has noted the difficulty

of cross dating the sequence of CUlCO and Puno to the lca Dimaster sequence ll using ceramic style or traded ceramics (1966, p. 17). Obsidian analysis also provides evidence of trade between inhabitants of CUlCO and Puno in the Ear ilon. It is also notable that major changes in patterns of obsidian distri tion occur during the spread of Chavin i uence and the expansion of the ari reo Both of these phenomena had been recognized earlier using ceramics, architecture, and other material. During Chavin times, obsidian from ispisisa was brought to Chavin in quantity, indicating a mod ication in the economic structure of the Central Andes. Indeed it is reasonable economic as well as religious forces have been responsible the cultural homogenei which came into existence in much Peru at that time.

A di idian distri tion occu ri

on was i di an

did not it i ona 11 access to i dian (i. e .

hi ~ eastern s opes of t , etc.)" also ieces ic i di an are in areas u isisa as idians are in izon

) .

In cases\) at t and im; obsidian sources must pl a Perhaps this difference is icative movements tr'oops, administrators, and/or popul ions. hesis is that is distribution reflects idi ies in toad Huari of storage and redistri ion. It is i of obsidian trade seems izon ier cuani area, is cul ec in an d i t

i di an h s ive in R personal communication ~ i 11 on 11 (Tom Dill , personal commlHtli cat i on ) , 11 1d lx~ al communication), ru communic communi ion . reasons c is

ion h

isisa 11 rou is is 1 i n ure and 11 1 serve 1ate ure in- st arc ica obs i dian s ure di tion pre-Hi ic t orities re research is the locat ion of the idi ows served as sources in anci times. When an obsidian source is located, it would be desirable to take samples from different parts of 'the flow, making note of the spot from which each sample is taken~ in order to detect chemical heterogeneity within a single deposit. Care should be taken to distin­ guish quarry areas from workshops where 'large quantities of obsidian debris accumulated.

Another priority s ld be securi samp es sites in areas not covered is st gap is coastal and hi land areas of Arequipa, Moquegua, a. It is known that obsidian was used in Arequipa beginni in Preceramic times (Eloy ares Malaga, personal communication; Neira, 1969~ . 45,64; Bonavia and Ravines, 1972, pp. 40-41). It is anticipated that new types of obs dian may be encountered in further sampling. In the study of obsidian from extensively excavated sites, quantification of obsidian artifacts is an important step in evalu ing the intensi of obsidian trade a given time. intersite variation in the types of obsidian use would also be tive. st a more so underst idian s uses d soci

Inves ons s ld uc at idian sources 1yes to ga i ible

Ul ; an thin ali anc; goods ishable and resilient, scarce and common) which were traded both locally and for long distances. Few these other trade goods have received the attention they deserve.

Interest among Andean archaeologists is increasing (e.g.~ Paulsen, 1974) and th improved scientific techniques at their disposal we can look forward to much additional information on other ancient trade goods. studies of obsidian artifacts and other trade goods are integrated, the changing patterns of trade and social interaction in ancient should be great clarified. nowl is icle s ble on ause ion colleagues ks are is Barreda

M. \I id o and Karen lawrence

Dawson, Ned and Jane Dwyer, Jose z es, Joel Grossman~ Joach Hempel, Gary Ho, Peggy Hoyt, William Isbell, Lowie Museum of Anthropology

(Berkeley), Patricia lyon, Thomas , Richard S. MacNeish 9 Ramiro Matos Mendieta, Clement Meighan, Dorothy Menzel, Helen Michel, chael Moseley, Antoinette Nelken-Terner, Paul Ossa, Felix Palacios, Thomas C. Patterson, Percy Paz, Carlos Ponce Sangines, Maks Portugal, Vianne

Ramirez, Rogger Ravines, Scott Raymond~ John H. Rowe, Alfredo Sandoval Millones, Kathy Schreiber, Helaine Silverman Mayer, ivers of California Archaeological Research Facility, Gary Vescelius, Robert Vierra.

Work performed under the auspices of the U. s. Energy Research and Development ~'~IU~A~~ o o

o

Fi g. 1. ical si an Key Fi re 1,

1. illo (Uhle ~ v

2. La 3. a 4. Chavin de Huantar (Castillo, Pueblo, Qaucho 5. Uchcumachay 6. Ancon 7. Ataura B. PJuM616 9. PJu61B (Calpish) 10. PJuM704 (Pirwapuquio) 11. 12. lestina 13. Ac100 (), Ac102 (Iomachay 14. Huari, Ac300, Camino Antiguo 15. Ac15B (Puente) 16. Ac500, Ac351 (Tukumachay) . Ac335 (Jaywamachay) lB. PHa3-21 ( igo), Mina de Quispisisa

19. Chi a, Si 0 0

20. A1 de 1as as jl Pis co

21. Cerro i (PV62-27), San Jose de Cordero (PV62-70) 220 ahuana

23. izo~ (PV62- 3 Ocucaj e Ocucaje B

24. i a . San Nicolas

51 a ena

l~ =5 ( o ana) ,

30. Cz2=26 (K 1pi t u) \) 2= ,Bandoj a, Baja 11 a apata, ava11e, Qotakal1i,

i, i11a~ 32. naspata,

33. Satan IUrqo all

i 0 \l uro

37 • i i

Yanamancha, Suyu~ Pikica11epata 39. II 1i .' Pucara, 41. Taraco

1 i ac a , Sill us iri 1;

11 a c:

A .. :· . . tI • ,,0·... ·0 GDf. ..o . •.

Zr .

Fig. 2. Graphic presentation Geology, University of using only Sr, of the inc;

as is lawrence

~ul$pisi~a Source 1~1l .: 1 -+ = !\yacl.i1cho Typte: 232 + 19 ! 0.05 Type 2.31 -+ Type 4.51 + 0.13 791 + 1.90 !. 0015 Andahuaylas A Type 2.50 + O. 374 0.29 + 0.08

Andahl.laylas B Type 2.20 -I- 0.10 0.01 + 26 0.26 .! 0.06

ClJlCO Type 2.06 -I- 0.10 416 3.23 -+ 0.05 1040 -+ 23 0.17 + 0005

TUkaca Basi n ~.05 .::. 0.11 120 + 14 7.25 -+ 0.01 144 + 13 0.88 ! 0.11

lEu Ce Ta

Quispisisa Source 20.69 -+ 0.48 51.9 + 0.9 3.29 + 0.8 .1 + 0.02 1.15 ! 0.03 Ayacucho Type -+ 24 0.292 -+ 0.006 40.7-+ 3.76 + 0.07 1. 78 + 0.01 0.84 + 0.03

Atad Type 17 .70 -+ 14 0.366 -+ 2.99 -I- 0.7 1.36 -+ 0.01 1.34 .:!: 0.03

Pampas Type 13.83 -+ 00 1.031 + 80.6 -I- 2.6 5.01 + 0.18 1.56 + 0.03 2.78 + 0.05

Andahuaylas A Type 18.37 -I- 0.21 + 0.011 + 0.8 3.32 + 1.22 + 0.01 1.22 + 0.02 Andahuaylas Type 19.60 5.29 -+ 1.04 0.01 1.04 + 0.05

CU.lCO 14.76 + 12 + 0.010 58.5 + 1.4 3.56 + 14 0.90 + 1. -+

11ticaca Basin Type 25.03 -+ 0.26 0.288 -I- 43.0 + 1.1 3.85 + 11 1.69 + 0.04 1.67 + O.M

La Cs

Quispisisa Source 2.49 + 0.05 27 + 1 0.04 577 + 0.018 11.38 + 0.24

Aw.~c~lcho Type + 0.02 22.6 + 0.7 1012 + 0.05 0.491 + 0.015 3.99 + 0.12

Acari 2.62 + 20.3 + 2.03 + 0.02 ·0.467 + 0.010 7.09 + 0.17

Pampas Type 5.16 .... 2.58 + 0.03 0.928 + (L020 12.73 + 0.29

Andahuaylas A Type 3.46 + 0.04 19.7 .... 1.84 + OJJ3 0.473 + 0.015 5.49 + 0.14

Andahuaylas B Type 4.82 + 0.05 + 0.894 -+ 4.29 -+ 0.15

3.30 0.03 1.95 + 0.565 +"0.015 2.90 + 0.13 liticaca Basin Type 3.66 1~L2 -+ 0.8 .... 0.03 0.506 + 0.07 10.21 + 0.37

Notes: I. Abundance values are in for ali elements except Fe. which is in

root-mean-square deviation or the stand~rd

54 Notes to Table lA.

~uh~1shfj Source: hued on 4Bsamples, including 3 from the obsidian mine. The archaeolo91cll1 sites at ~hich the samples \lIere Dun and the number analyzed in this work by neutron activation were: Pampa Media Luna (1), San Nicolas (3). Erizo (1). Huar1 (3). Waywaka (4). Marca HUdmachuco (2). Trujillo (1). Hacha (2). Jaywamachay (7). La Banda, 01st. Chavin (3), Uchcumachay (6), Jlncamoqo (2), Ataura (2), Jalpacocha (1). lomachay (1), Ancon (2), Ac300 (2), Cebolla WaiQo (1). The average standard deviation for the best 22 elements tested is 4.12~.

Ayacucho Type: based on 3 samples from the archaeological site of lomachay and one from Ac500. The average standard dewiatl~n for the best 22 elements tested is 5.83~. Acari T{pe: based on 2 samples from the archaeological site of Hacha. The avefage standard deviation for the best 20 elements ts 3.19 . Pampas Type: based on 7 samples from the archaeological sites of Jincamoqo (1), Jalpacocha (1), Canlcht (1), dnd WaY\llaka (4). Th~ average standard deviation for the best 22 elements tested is 3.77%.

Andahuaylas A Tape: based on 12 samples from the archaeological sites Qf Waywaka (8). Qasa~lrka (3), and Santa E'ena (1). average standar deviation for the 22 best elements tested is 6.38%.

Andahuaylas B T~pe:. based on 5 samples from the archaeological sites of Waywa!u (2). and Knunka Taka (3). The I)\{erage sUndard dev1ation for t e 20 best elements tested is 4.59%.

CUlCO T,pe: based on 24 samples from the archaeological sites of Huyu 'Urqo (3). Minaspata (1). Marcavalle (2). Suyu (3). Qolakal i (1). TClrllCO (4), JincamoQo (2), Coricancha (1), Pakallallloqo (1). AQawlhy (1). lncatunuhuiri (1), Huarl (1). Waywaka (1), Yanamancha (1), Huamachuco (1). The average standard deviation for the 20 best elements tested is 6.64~. Titicaca Basin Type: based on 21 samples from the archaeological sites of Qaluyu (1), Pucara (1), Juli (I), Sfllustanl (1). Julldca (1), Incatunuhuir1 (1). Tumuku (1). Sora Sora (3), Marcavalle (2). Llalll (5). Tiahuanaco (2), Pukupata (I), Suyu (1). The ~verage st@ndard deviation for the best 10 best elements tested is 3.25%. Elements not listed in Table 1:

As: The precision gf the measurements for As is low but results suggest that it may eventually be useful to distinguish types iT obstdian. Arsenic is found in small quantities in most cases but is somewhat larger in the Acari typeD larger still in the Titicac& Basin ~nd largest in the Pampas type (see Appendi~ ).

Co: Desp1t~ low in the mf8surement of Co. it is clear that Co occurs in much ~~11er quantities in the Andahuaylas A tipea CUlt@ tYP~0 A'l1~~cLllcoo typeD \}nd Acari type thaln 1ft the other .ajar types.

55 Table lB. Mean compositions and standard deviations determined neutron activation at the Lawrence Berkeley Laboratory: Rare types.

Sb Til Eu

1.47 .;. 0.10 493 .;. 10 .;. 0.05 567 .;. 19 + 05 13.57 .;. O.H 0.433 0.008 52.4 0.9

Rare Type 2 : 1. 59 + 0.10 508.+ .;. 0.05 0.344 -I- 0.006 42.9 + 0.8 Jay\'Jamachay*

Rare Type 3: 1.58 0.10 630 -I- 13 6.82 .;. 0.05 +13 + 0.06 30.31 + 0.30 0.101 + 0.004 51 r~uyu 'Urqo*

4: 2.14 .;. 0.11 486 + 10 4.75 0.07 961 + 24 0.40 .;. 0.07 19.80 .;. 0.-17 0.773 + 0.010 82.B + 1.1 (3)

Rare Type 5: 1.30 .;. 0.08 '340 .;. 7 9.77 + 0.08 946 + 12 1.61 .: O.lS, 20.61 + 0.17 0.286 + 0.006 33.3 + 0.1 Uchcumachay*

Rare Type 6: 2.18 + 0.10 451 + 9 4.49 + 0.05 816 + 24 0.42 + 0.06 17.S1 + 0.13 0.544 + 0.009 66.6 + 0.9 Taraco and Chinchiramoqo (1 sample each)

Rare 7: 7.68 + 0.11 311 .p 6 3.08 + 0.04 1194 + 28 0.S2 + 0.08 7.66 -I- 0.07 0.547 + O.OlD 52.8 .: 0.7 1 ai<

Rare 8: 2.36 + 0.08 412 + 8 8.33 + 0.06 574 19 0.06 .;. 0.04 3S.08 + 0.22 0.S28 + 0.009 85.5 + 0.9 la*

Hf Ta Sc Fe% Cs Rb

Rare Type 1: 3.63 + 0.08 0.97 + 1.06 0.03 2. + 0.02 29.7 1. 71 + 0.02 0.550 -I- 0.020 3.39 + 143 "7 Tumuku (2)

Rare Type 2: 3.86 + 0.09 1.94 0.01 0.95 + 0.03 2.34 -I- 0.02 21. 7 0.6 1.87 + 0.02 0.540 + 0.020 3.80 + 0.11 124 ,:I: 9 Jaywamachyay*

Rare Type 3: 4.77 + 0.10 1.40 + 0.01 .50 0.04 -I- 0.01 28.9 + 0.7 1. 74 + 0.02 0.510 + 0.02 4.40 + 0.11 229 9 Muyu 'Urqo*

Rare Type 4: 4.45 -I- 0.09 0.83 + 0.01 09 + 0.03 4.22 + 0.02 44.2 + 1.0 1. 72 + 0.02 0.707 4- 0.020 5.95 -I- 0.15 156 + 1 Waywaka (3)

Rare 5: 2.51 + 0.07 1.12 + 0,01 0.93 + 0.03 + 17.9 -I- 0.7 1.38 -I- 0.02 0,380 + 0.010 11.22 -I- 0.24 173 {> 6

Rare Type 6: 3.13 .;. 0.08 1.00 + 0.01 1.28 + 0.03 3.20 + 0.01 34.8 2.04 -+ 0.02 0.570 -I- 0.01 5.80 + 0.16 176 ,:I: 5 Taraco and Ch inch i ramoqo (1 sample each)

4.07 + 0.08 0.80 + 0.01 5.67 -I- 0.06 5.88 + 0.02 .5 + 0.8 4.1 + 2.51 -+ 0.13 ii\.are Type 8: 4.68 -+ 0.08 1.48 + 0.01 1. 74 .,. 0.03 3.44 + 0.01 .1 + 2.34 + 0.02 0.69 0.02 6.32 .;. 241 ,:I: 5

'ates: Abundance values 1 elements which is in w When only a si the standard in counting e 2. Selected trace element of Andean obsidian: fluorescence ana 11 i on)

i di an le Sa Ce Rb Zr Size

t i cacao Basin 60 126 41.1 331 54 101 Ayacucho 8 220 42.8 154 89 90

Andahuaylas A 26 396 44.3 211 99 77

Acari 10 626 43.2 156 89 86 Quispisisa 60 735 52.0 233 155 93 Pampas 36 799 78.6 212 346 196

CUlCO 52 1019 58.4 165 106 104

as B 9 1128 100.0 179 359 193

57 Table 3. Summary of obsidian .analyzed by x-ray fluorescence and neu acti

(J) ~ ~ (J) CI) 0.. VI ..0 ..0 (J) 0- 0.. ~ (J) u ~ ~ I-- 0- -0 -0 s- I-- I-- >, (j) (j) ::::> !>::: I-- N N 0 ()) c::::( co 'r- >, ~ V') 0- VI -0 ...- >, Q) VI VI t"'O Q) rd t"'O (I'j I-- (J) 0.. I'd (I'j CI) 00 VI C C VI 0- >, ...- ...- n. CI) 4- I'd rd 'r- 0 I-- >, >, rO 0.. U'l J::. ~ rO rd ~ U VI I,/) If) u I,/) ::::> ::i rd ~ 'I,/) Q) CI) 0... ::i rd J::. J::. 0 U (I'j ...- I,/) u s- o.. rd (I'j U CI) ...- 0- 0... (I'j (I'j E -0 -0 N +J s- u E E ::s u I'd s:: s:: ::i 'r- i'tl !>::: I1j I1j C1' ~ c::::( CL. c::::( c:C U I-- ~ ::::> V') V')

Mina de Quispisisa 3 3 4 Ha 3-21, Abrigo 4 4 Ha 4-8 1 1 San Ni co 1as 49 46 Erizo 3 2 Media Luna 31 30 Taj ahuana 4 5 Ocucaje A 1 1 Ocucaje B 2 2 San Jose de Cordero 2 2 Santa Luc i a 1 1 La Venta 1 1 Cerro ieto 1 62-128 1 1 Paroma 3 3 62-141A 1 1 62 1 1 to de 1as Brujas, Pisco 1 1 i ncha 0 1 1 Hacha 35 10 6 2 4 53 Ac 355 (Jaywamachay) 30 1 8 23 Ac 158 (Puente) 9 3 2 10 Ac 102 (Iomachay) 3 3 4 6 Ac 351 (Tukumachay) 3 3 II4.C 4 2 1 6 Ac 300 10 2 Ac (Pi k imachay) 1 1 50 1 3 via an gua 2 2 1 1 6 1 7 3 3 2 1 3 2 2 1

58 le 3. Conti

0::::( 0::::( z Q) >, >, Q) Q) c.. Vl D ...0 0- c.. >, QJ >, >, I-- 0- "'C -0 l- I-- >, Q) QJ c .- N I"d Q) 0::::( 00 or- >; >, c.. Vl u >, Q) 1.1'1 Vl fIj Q) fIj ,.;j f!j I-- Q) 0.. Rj ro w co If) c: c: 1.1'1 0. >, ,...- ,...- c. Q; 4- rtS ({j 0 >, I-- >., >, co 0.. 1.1'1 -'= I- f!j f!j ~ u >, 1.1'1 Vl 1.1'1 .,... U 1.1'1 ::;:, ::s rtS 1-- Vl (JJ Q) 0.. ::;:, fIj -'= -'= 0 u fIj !.II U t- o. fIj fIj u (1J c.. 0- fIj Rj E -0 -0 N +J $-. u E E ::s u to C c: ::s res c: (\j (\j 0' ~ 0::::( 0- 0::::( c:::( U I- 0::::: ::::> (/') (/')

Town of Chavin 1 1 '~ Temple of Chavin 3 J Qaucho 13 3 12 Uchcumachay 9 7 10 Marca Huamachuco 3 1 3 3 Huamachuco (Uhle) 9 5 14 La Cumbre 1 1 Cementerio Moche V 1 1 Trujillo (Uhle) 3 1... Ancon 2 5-1 1 3 1 1 ::> PAy 5-5 (Coraeorral Pata) 6 4 1 11 PAy 5-6 24 22 5 8 50 PAy 5-7 2 1 3 Qasawirka 4 3 1 Waywaka 15 16 33 11 2 3 22 71 Kunka Taka 1 1 1 1 Santa Elena 1 1 Marcava lle 26 3 2 3 28 nas Pata 9 2 7 1 1 Muyu ·Urqo 12 .I. v 10 Qotaka 11 i 3 1 1 4 Tarawi 1 1 PCz 13-14 1 1 1 Pikillaqta 1 1 ill a 1 1 2 4 Kal pitu 1 1 Corieaneha 1 1 z 2=10 2 1 2 1 1 a 1 1 2 1 1 1 1 1 3 3 ') a 1 L ') 1 c Table 3. i nued.

OJ (l) 0- U ~ >- I- =:i C 0 ClJ c::( 00 or- <./) 0.. I.fJ >, ClJ I.fJ Vl fCi I'd m I'd I- OJ 0. I'd fCi <1J ro Vl C C I.fJ 0- >, 0.. ClJ 4- I'd rd 0 I- >, ~ >, fCi 0.. I.fJ ..c ~ m ro I- U >, I.fJ Ul I.fJ 'r- U I.fJ ::5 =:i ro I- I.fJ Q) OJ 0.. :::J or- fCi ..c ..c 0 u m r-- r-- I.fJ U s- o. ro ro u OJ r-- 0. 0.. !"Ij ro E u '"0 N -!-l s- u E E ::5 U ro c c ::5 or- m c.: rei I'd 0" ~ .::::c 0- <:( V")

Qhataqasallaqta 1 1 Pukupata 1 1 1 1 Choque Puquio 1 1 2 Paka11amoqo 1 1 Chinchiramoqo 1 1 1 Yanamancha 3 2 2 3 Suyu 4 2 4 2 Pi k i k all e pat a 11 3 i Wasi 2 3 1 6 Taraco 10 143 4 153 Qa1 1 1 1. 1° 2 1 1 Incatununuiri 1 9 2 8 Aqawa 11 ay 2 1 1 1 1 Sill ustan i 1 1 Pucara 1 1 Tumuku 1 2 3 Ka 11amarka 2 2 Ti ahuanaco 16 2 14 Llal1i 7 6 1 Sora Sora 3 3 Table 4, ica Sites Ac

Ac Ac Ac 351 Ac 500 forest

Site Zone ispisisa Ayacucho Source Type

Ac 100 f-2 1 Ac 102 8 7300 1 7 2 6 3 Ac 158 XIII 1 I 1 XI 2

III Piki 1 V I Pik 2 1 I Piki 1 Piki I 1 Ac 300 C 6 sou 4 Ac 335 1 K 3 J-2 3 I 2 H 2 G 2 F 5 E 1 0 5 4 Ac 1 F E

a on Table 5. Analysis of obsidian from excavations at the site of Waywayka, Andahuaylas Province, Department of Apurimac.*

as Andahuaylas ispisisa Pampas CUICO Rare A Type B Type Source Type From

A 10 2 4

2 5

B 2 3

3 2 1 1 1 1 1

C=D 7 3 1 1

qo 2 1 2 5 2 1 rk Horizon 1~2 1 1 Surface Plow Zone nlv Dost-MH2) 1 7 1 1 1

xed 1 4 3

oms Joel Grossman (1972). ions si in.

Rare ive

Uchcumach , Yau 1i vince Pit 1, strata 4BW 1 Late Preceramic

Pit 2, strata 4CE 1 Late Preceramic

Pit 2, strata 2 1 Early I nte'rmed i ate Period Pit 4, strata 4 1 Ear ly Intermediate Period

Pit 5, strata 5 1 JaywajPiki

Profile A, 18-20 m 1 (Probab ly, Late Preceramic)

Profile A, 24-26 m 4 (Probably Late Preceramic) ra, Jauja ince

Quadrant C- 11 9 strata 5 1 Pre-Chavi

Quadrant C-l~ a 1 1 Chavinoid

Surface 4

*Excavations directed by Rami ro Matos Mendieta. Relative dates were

ded R ra i eta and Peter Kau 1i cke 0 APPENDIX ABUNDI\MCES BY NEUTRON PER MXllIO~ OR PERCENT !F INDICATeD RUN SAMPLE 011 0/0

I" BURG-2 .ll 3.04" +1- .D2'? "3 .87 ~/- .29 022 G 8U'IG-3 .26 622 PUil.G-6 .;H '" 822 M BURG-a 5 822 p RU'lG-H (, il22 U I3U'IG-H, 7 822 w 8URG-18 132 ;'1- B B22 X .36 ll1 <-1- 9 822 V -IJo/- 138 ;'1- 1.:1 H .23 202 '>/- !l g "1- • 23 194 +1- 12 826 W AURG-39 ~/- .22 4Ll +/- 69 13 828 flURG-41 &1- .21 270 79 14 845 [lURG-4l 193 +/- 65 15 845 BURG-i):! 129 l\.U7 16 861 H !jURG-M ClS "1- 61 11 d61 J <-1- 69 18 86~" 4.01 ~/- .23 ./- 70 19 66~ R 8LJRG-7~, 3.88 +1- .23 130 ... 1- 62 20 A~t S BURG-15 3.87 1- .23 43 "1- 63 21 861 BU~G-19 .22 141 "1- 12 22 B f BURG-89 .22 86 <-1- 63 23 G RURG-9u .22 24 "1- 64 20, an J .22 149 "1- 68 25 871 Q :;.92 .. /- .22 2 63 26 871 1 BU,\-liJll 3.55 .22 142 68 27 871 X 8UR-10i; 3.63 .. 1- .22 154 .. ,- 69 28 l 140 <>1- 12 29 E 56 63 30 890 G 3.64 ,,/- .22 110 66 H 890 H '1.76 <-1- .22 201 69 32 890 M 4022 "1- .23 215 1l. 33 B 2.344 <-1- .(115 S.u6 .. 1- .22 237 <-1- 72 41 693 F AUI<-lOI3 360 2 2.709 +/- 4.0ll. .. 1- .22 96 "I­ 68 42 893 G BUR-109 364 3 3.011 .vl- 4.00 ... 1- .22 II 0 {o/- 71 43 893 H "Iu~-110 :3 2.90S "1- .018 3.67 .. 1- .:n. 239 +1- 74 44 893 0 365 :3 "1- .QUI 3.71 "1- .22 95 .. 1- 72 45 893 366 "1- .029 +1- .QUI 3.87 +/- .22 53 "1- 73 46 91.1;, 5 ANCO-2 ,110 .. /- "3 3.020 "1- .018 3.69 '>1- .23 114 1tl 0,7 914 T ANCO-'! 369 "1- .018 3.34 "1- .23 154 .. 1- 72 48 890 T flUR-13<\. .018 3.19'>1- .22 218 12

49 822 BURG-l 501 .. 1- 3. +1- .030 4.71 +/- .32 324 +1- 136 5fJl 1\1 BU'lG-9 3.044 +1- .032 4.44 +1- .34 261 +1- 126 Cl BURG-R~ .34 +1- 119 52 an T .3~ 15), 90 53 10 .34 148 105 ,'" 0 165 '>1- 86 55 821lJ g flURG-,1] 15 .. 1- sO 56 828 6U'lC.-3~ 121 "1- 86 51 132 B RU~G-42 .22 81 '!-/- 82 58 "i45 4.0B .. 1- .,24- 68 ;.1- 76 '59 8 .. 5 4.26 +1- .24 91 .. /- 112 1;.0 dn 4.27 ~/- .2', 43 67

61 B22 H f3U~G-4 .10 460 -r /- 3.323 1- 3.272 -IJo1- 3.1>1 "1- .24 123 <-/- 14 13 845 0 BURG-51 3.214 "1- 3.39 ">/- .24 1:~6 "1- n 1'" 1345 BUPG-52 .93 ,,1- .25 100 76 15 845 Q BURG-5:;! .. /- .24 157 +/- 82 10 1171 0 B~Qr,-95 .. /- .26 33 <-1- 82 71 893 T 3.51 .. 1- .23 78 .. /- 68 76 890 >( 3.59 <>/- .24 61 .. /- 75 19 890 N flUi'l-126 3.11 to/- .24 211 H- 81 80 890 S '1UR-~33 3.B5 .. 1- .24 17 <-/- 75 8], 914 0 BUoJ.-14:1! 3.90 "1- 98 91'" P BUR-~"'4 3.93 "1- .. 1- 96 83 914 0 SUR-145 3.6l v/- 40 +1- 126 84 '114 R BUil.-l l,6 l.79 96 '>/- 76

TITICAC~ BASIN TYPE 65 823 P BU'lG-22 3.213 "1- .033 4.04- to/- 91 '>/- H8 8!> 828 F BLJRG-24 3.86 2b +1- 85 131 828 BU~G-26 4.35 .29 lU +/- 88 BB 828 M BLJ~G-29 .28 161 .. 1- 92 89 82B I3U·'1G-31 .26 -4 "1- 98 90 845 H flUo.G-46 .26 -11 .. 1- 85 91 1345 K :lURG-4B .27 0:; .. 1- 71 92 84'5 M flU RG-49 .21 43 .. 1- 61 93 8 /., fWilG-5') .26 98 +/- 83 94 845 R BU~G-54 .26 +1- 94 ~I:>l 8URG-63 80 'II:> flUi'lG-M 50 .. /- 61 91 BUR G-b'j 9 "1- 8<\. 9El 861 au"- G-69 .25 79 .. /- 85 99 S61 III ?,URG-70 202 92 100 8&1 0 RURG-l1 48 <>/- 93 101 86J. <>1- 94 lu2 -8 81 103 U -12 <-1- 89 104 861" '>1- 85 861 93 SI\MPl[

PANI"AS TYPE 106 HO I'URG-El4 1.72 .. /- .13 4.66 .. /- S6e. +/- 3.48lJ <;>/- .Oll ::I.U "1- .25 447 .. /- 89 1\17 87,) BURG-85 7.68 .. /- .14 10.70 +/- • 592 +/- 3."'98 +/- .Oll 3.78 .. /- .25 293 ./- 86 lQ8 B n H ~U"G-91 1.71 .. /- .11 .. 1- .1~ 567 .. /- .. /- .020 3.62 .. /- 305 .. /- 80 10<;1 an ill flURG-93 7.81 .. /- .1$ <;>/- .u 57'6 +/- 3. ../-. OZl 3.62 +/- 227 +/- 87 110 !In ~ SU61G-~4 S.OO <>/- .18 ~o$O +1- alA 513 '1;1= .. /- .021 3.7e. ./- .2e 266 .. /- 8'il III Hi U ®u~·HIl!. 8.()1' <>1- .2~ "'.3a. +1- 51l>9 <>1- +1- .02') 3.41 .25 281 +/- 84 III 971 II RUR-102 7.66 i?I- .U It ... ~ "./- 56'1 +1- 3.445 .. /- .ll2-') 3.34 .. /- .24 283 "/- 8(l

IINOAHUAYLAS EI TYPE 113 !i2l I RURr.-21 7.57 .. /- .18 2.24 0/1- 5 ./- .033 5.04 .. /- .40 219 "/- 112 114 dze P 6UQG-32 7.52 .. /­ .;!<;l 2.10 .. /- 6 3. +/-. /- 99 115 S7I) Q RUf:.G-83 T.37 .11 2.13 +/- .09 :3 3.216 .. /- 3.B4 .. /- .24 333 .. /- 18 U6 8'il0 I' BU~-12!. 7.14 "1- 2.35 .. /- .09 3 3.2119 .. /- 4.U .. /- .24 333 .. /- 74 117 890 W flUR-131 7.37 .. /- 2:.17 .09 3 3.088 +/- • '>.66 .. /- .24 313 +/- 79 AUCUCHO US 893 J BU"-lU 7.20 +/- .37 1.108 .10 449 <;>1- 2.981) .. /- .018 4.22 .. /- .23 153 .. /- 79 119 893 K FlULl,-112 6.81 +/- .08 1.31 ~/- .08 4'>3 "1- 2.878 ./- .018 '>.51 .. /- .23 U1 +/- 7Cl 120 893 M BUR-ll3 6.82 .. /- .10 1.51 +/- .1)9 452 <;>1- 3.033 .. 1- .018 4.19 ./- .23 109 "/- 73 121 893 f\I [lUR-U,> 6.97 .. /- .12 1.34 .1- .U'IJ '>53 "1- 3.4110 .. /- .(21) 3.78 +/- .23 38 .,./- 76

122 893 AULl,-HI7 6.65 .. /- .12 1.52 '>/- .09 509 .. /- 3.294, +/- .020 196 .. /- 77 ACARI TYPE 123 893 8ULl,-UB 6.76 ./- .10 2.35 ./- .~9 3.196 .. /- .019 3.94 .. /- .24 124 +1- 67 12'" 893 BUR-H9 e. .61 .'-.11 2.26 <;>/- .10 3.177 +/- .019 3.41 .. /- .23 -63 '>1- 68

OTHER CHEMICAL COMPOSITIONS OF OEISIDIAN ARTIFACTS FOUND AT TLJMUKU 125 826 N ElURC;"30 7.18 .. /- .18 1.46 +/- .10 6 2.640 .. /- .021 5.31 t/- .26 31 +/- 78 126 861 Of BURG-tn 6.78 +1-.14 1.48 H- .10 ;I 2.923 +/- .01a 4.61 +1- .24 74 .. /- 81} FOUND AT JAVWAMIICHAV 127 828 V AURG-39 7.10 +/-.13 1.59 .. /- .1L! 508 +/- 3.109 "1- .023 3.64 +/- .23 a .. /- 75 FOUND AT MUYU URCO 128 828 S BURG-35 6.88 +/- .16 1.58 "1- .10 630 +/- 3.296 .. /- .025 3.59 .. /- .26 105 +/- 91 FOUND AT WAYWAKA 129 871 P BULl,G-96 7.67 +1- .29 2.13 +/- .11 483 +1- 3 3.629 ./- .022 3.40 +/- .25 176 +1- 69 130 8n v BULl.-105 7.2S +/- .17 2.12 .. /- .10 480 ./- 3 3.645 +/- .021 3.91> .. /- .24 260 .. /- 82 131 914 N RuR-!42 7.'>1 +/- .17 2.17 .. /- .11 494 ./- 3.6{'8 +/- .025 3.73 "/- .27 229 .. /- 94

fOUND AT UOlCUWlOlAV 132 fl7l II f\WR-103 6.79 +/- .11 1.30 +/- .08 3100 .. 1- 2.991 .. /- .OUI 3.63 +/- .22 -22 "1- 65 FOUND AT TARACO 18URG-1251 AND CHINCHIRAMOQO IBURG-1411 133 690 J 7.12 +/- .26 2.19 +/- .09 450 +/- 3 2.960 v/- .016 3.96 .. /- .23 237 91'> M 7.02 +/- .14 2.16 .. /- .10 451 .. /- 3 2.956 +/- .021 3.92 .. /- .26 121 ""/- 84 FOUND AT CUZCO 135 890 V BUR-139 6.65 +/- .14 7.68 .. /- .11 3U +/- 3.257 +/- .lll9 3.70 +1- .22 64 .. /- 72

136 893 0 BUQ-U 1 6.73 .. /- .08 412 .. /- 3.057 .. /- .018 3.90 +/- .23 70 .. /- 60

GEOLOGICAL SAMPLES FROM PERU IIYilCUCHO SOURCe 137 1%5 III 6.(1) "/-.U 1.21 <>1- .10 156 .. /- 95

SaCHACA. IIR~OUIPA 3.71 +/- .la;) 259 74 13& 861 Q ~U"G-n 1.44 +/- .17 2.83 .. /- .!O YURI, AREQUIPA 10.97 "/- .25 174 .. /- 84 139 661 x BURG-Btl 7.29 +/- .12 2.53 +/- .10 672 +/- 2.397 +/- .015

HIGH SILICA GLASS ARTIFACTS FOUND IN THE MANTARO VALLEV SAMPLES JUM625 AND JUM616 HO 871 R .02 +/- .02 .05 .. /- .02 ;:) +/- .019 'It/- .001

25 .. /- 10 141 Hi S 10 +/- .019 .. /- .001 .10 +/- .03 RUN SAMPLE AS u

.009 .O/- .06 41 893 F BUR-l DB zt 2.479 .. /- .lllCl .70 .66 .. 1- .05 42 ·393 G BUR-109 .. 1- 21 2.485 f!>/- .011 +1- .12 .65 .. 1- .OS 43 893 H 21 2.471 +/- .01 +/- .11 .54 .. 1- .05 44 fl93 0 2() 2.41:14 ~/- .011 +1- .71 .50 <>f- .05 45 89 '3 f'U~.-1l6 20 532 .. /- .011 +/- .71 .5A .. 1- .05 "6 914 MICD-Z +1- 25 2.436 +/- .009 .. 1- .66 .50 .. /- .06 41 914 tlNcn-l 25 .. /- .010 .. /- .68 .55 .. /- .06 48 eSlu BUR-13<, 2:1. 420 "1- .012 .. /- .19 .49 .. /- .06

49 B22 E 3.8 "1- 1.') <>1- 21 19.26 +/- .59 .26 .. 1- .04 50 822 IIJ 6.3 1.0 .. /- ! l' 19.'53 +1- .51 .16 .. /- .04 51 822 0 BUKG-it) 3.5 1.0 11 18.32 "/- .51 .le. ~/- .04 52 '122 T 3.8 "/- 1.0 16 20.66 .. /- .56 .15 .. /- .Cl4 SOl [J 20.26 .. /- .5O "'1- .03 .Hi! 1;01- .03 8UI .•n :;I!> flURG-3@ .(}:!) 51' 82 B RURG-t,;;; '" 03 ,8 El45 f\'NG-~1' 59 845 'lU'IG-61 .. /- .03 60 'In flU%-llei ,,/- .03

61 822 H flURG-4 3.1 3.249 .. /- .009 28.65 .. /- .65 .24 .. /- .04 62 822 J flllRG-5 1. l' 3.245 .009 29.58 <1-1- .64 .20 "1- .04 63 822 Q !3:.JRG-!2 2.1 3.266 .. /- • llJ9 3u. ../- .65 .2'l +/- .04 64 622 AUQG-U 3.3 328 ,,/- .009 29.49 .. f- .6'5 .35 .. /- .04 65 822 flU.l.G-14 24 3.298 .. /- .009 30.44 .. /- .65 .. 1- .04 66 822 \I AUPG-l1' 3.261 ,,1- • Ji.l9 28.82 .. /- .64 .. /- .04 67 828 E BUR G-23 Z 2'> 3.311 "/- .010 29.48 .. 1- .69 .21 .. /- .03 68 82B G filURG-25 1.5 24 3.291 .010 29.23 .69 .26 .. 1- .03 69 B 26 J BUPG-21 2.6 24 3.304 .. /- .01J 29.4ll .. 1- .69 .31.l +/- .04 7t) 828 )( BUR G-40 2.7 'l91 .. /- 22 .. /- • all 30.02 .. /- .70 .26 +1- .03 71 a45 F flU'1G-44 1.0 .. 1- 3 .. /- .010 29.B6 +/- .69 .24 .. 1- .04 72 845 G RU;J,G-45 l.CI +1- 23 3.360 30.46 .. 1- .69 .23 .. /- .04 13 845 o BU:tG-51 ~/­ 1039 25 28.82 .69 .37. +/- .04 14 845 p &/­ +/- .69 .26 .. /- .04 75 845 o .. 1- "1- .67 .25 .. 1- .04 .24 .. /- .04 76 n RU~r.-95 ,,/­ 1025 .. 1- 22 3.286 ./- .013 30.04 ./- .82 77 T BUR-l22 .. /­ 1014 3.334 .011 29.38 "1- .72 .29 .. 1- .04 18 1l'l0 K flUP-126 .. /- 1.5 ".322 .. /- lLl35 "'/- 3.368 "1- 30.06 .. /- .85 .21 <;1- .04 79 .043 21> 3. 28.96 .84 .25 ~/- .04 80 .041 26 30.14 "/- .82 .1 q ,,/- .04 01 .039 1038 ,,/- 29 29.38 "1- .17 .23 '>/- .05 82 .036 1010 .. 1- 28 29.55 .. 1- .72 .2'l +/- .04 83 .. 1)36 1015 29 .n .25 .. /- .05 84 914 R .036 1027 29 .10 .29 .. /- .J4

85 823 P flURC-22 12 31.682 .. /- .011 19.96 .. 1- .43 .. 1- .05 a6 F 8U"G-24 +1- .36 .. /- .05 81 82 fI K BURG-2E1 .. /- .48 .. /- .05 88 828 M AURG-29 18.'59 '>1- .34 .. /- .04 89 B26 U BU~G-37 19.65 "1- .29 .. /- .04 'ill! 845 RUPG-46 .33 .. /- .05 91 845 K AUgG-4fl .33 .05 92 845 8URG-4'l .4() .05 93 845 flU'5 .33 .. 1- .06 98 86 .40 +1- .06 99 861 N .47 .. 1- .0& 100 a61 a BURG-I! .30 +/- .06 flb1 P flURG-72 lJ2 Cl6))' ElU".G-16 .06 103 BURG-1'7 .06 1Ll4 861 BURG-7B .06 RUN SAMPLE

PAMPAS TVPE 1:>6 870 S BUflG-8lo 16.6 +/- 1.9 6.542 <-!- 830 +1- 23 5.140 +1- .011 .59 +/­ .06 101 S7c) T. BURG-8S 15.5 .. /- 1.6 6.56" .. /- 9112 .. 1- 22 5.152 .. 1- .uli .56 ./­ .1l6 108 d 11 Ii BUQG-91 10.0 +/- 6.566 +/- 788 +/- 20 5.128 .. /- .011 42.44 +/-1.01) .70 <-I­ .06 109 en M eU'IG-<;)3 12. B +/­ 6.616 .. /­ 769 +1- 20 5.0911 +/- .011 4Z.41 +/-1.00· .5<;) .. /­ • 06 110 Hi N BUilG-94 lZ.D .. /- 1.8 e> .545 "1- 764 .. 1- 2tJ 5.14'> .. /- • u17 43.66 +/-1.0l. .75 <-/­ .ll6 Hi dn u BUR-lot B.2 .. /- Z.O 6.435 189 ~/- 20 ~.157 .011 ':'0.19 +/- .91! .56 .. /­ .06 H.:; .. /- 2.0 e..loST +1- 112 811 Ii BUR-102 1'!14 "'- 20 S.2en .011' ""'.2'11 +'-1.02 .:57 'I-!- .06 ANOAHUAYLAS B TYPE 113 822 BURG-21 2.2 +/- 1.1 .. /- .035 1111 +/- 4.811 .. 1- .012 58.82 .. /- .as .6'9 +/- .05 114 828 F\u<'G-32 2.1 l>/- 1. 2 .. /- .036 4.19(J ./- .013 57.15 <>1- .92 .65 .. /- .(J5 115 :110 BU'IG-!l3 4.6 <>/- .6 3.'>24 -/- .J44 4.789 .. /- .016 60.0..1 "/-1.16 .68 .. /- .1l5 116 391.1 BUiI-l21 2.2 .. /- ",.2 3.484 '>/- .069 4. 82 2 .. /- • 021 51.85 .. /-1.9" .54 .. /- .06 HI il90 I3UR-l] 1 3.2 H- 1.8 3.574 .. /- .U5Y 1093 +1- 4.881 .. /- • ell 1 58.88 "1-1.24 ."'!) +/- .06 AYACUCI10 TYPE li6 ~93 J BUR-ill 4.1 H- 4.604 .. /- .042 231 +/- 1. CJ7:; .. /- .009 Z 1.5 a +/- .64 .20 .. /- .04 119 893 K 'lUil-UZ 3.0 +/- 4.663 .. ,- .0"'2 259 +/- l.CJ56 +/- .009 22.54 .. /- .64 .43 <-/- .04 120 1393 14 AUR-l U 3.1 .. /- .1..1 4.105 H- .042 221 +/- 1.CJ1CJ ./- .009 23.16 .. /- .66 .28 .. /- .04 121 893 1\1 AUfl-U<\, 3.0 +/- 1.2 ... 120 .. !- .043 2U "'1- ~.99e. .. /- .009 23.01 .. /- .68 .26 "1- .04

12'< 893 BUR-lOT 11 2.217 +/- .009 18.82 .. /- .6'> .48 +/- .05

ACARI TYPE 123 8'n s." .. !- 1.2 6.22!5 +/- .050 61e, +/- 19 2.60a .. /- .010 19.69 +/- .63 .25 +/- .04 124 6<;)3 6.2 ~/- 1.2 6.2"1 "'- .050 649 .. !- 19 2.622 .. !- .(no 20.85 "/- .63 .36 +/- .04

OTHER CHEMICAL COMPOSITIONS OF OBSIDIAN ARTIFACTS

FOliNO AT TUMUKU 125 eZ8 III BUfl.G-30 1.0 +/- 1.0 3.385 +/- • 033 511 +!- 17 2.121 .. 1- .009 30.04 +/- .66 .29 .. /­ .03 126 86\ Y BUClG-.U. • '> ... !- 1.1 3.407 .. /- .068 556 ;;,/- 20 2.148 +,- .014 29.44 .. /- .99 .21 +/- • Olo

fOUNO AT JAVWAMACHAV 121 828 V BURG-38 3.2 +/- 1.1 4.537 +/- .039 2.341 .. /- .009 21.69 +/- .63 .19 .. /- .03

FOUND AT MUYU URCO 1Z8 828 AURG-35 6.8ZU "/- .05;) 9 .. /- 1.523 +/- .009 28.89 +/- .69 .03

FOUND AT WAVWAKA 129 811 P AUilG-96 1.6 +/- 1.6 4.846 +/- .050 960 .. /- 22 4.249 +/- .015 43.15 +/-1.01 .23 .. /­ • 04 130 8n y RUR-I05 6.0 +/- 1.9 4.166 +/- .1l46 979 .. /- Z2 4.245 H- .015 46.53 +/-1.03 .1 CJ +/- .04 131 914 1\1 1IUR-!'>2 5.5 ./- 1.2 4.628 "/- .043 930 +/- Z8 4.132 .. /- .011 41. ... 8 .. /- .84 1.09 .. /- .01

fOUND ,AT UCHCUMACHAY 132 871 W BUR-LOl 9.712 .. /- .(115 21 1.765 +/- .012 17.90 ."./- .69 .18 + /- .04

FOUNO liT TARACO IBURG-l251 ANO CH!NCHIRAMOQO (flURG-1411 133 S9() J '1UR-125 4.7 +/- 1.5 4.531 +/- .049 alB +/- 23 3.193 +/- .013 35.05 +/- .B8 .33 +/- • 05 134 914!'4 AUfl-1H 5.1 .. /- 1.ol 4.443 <;-1- .0 ... 1 813 .. /- 25 3.202 +/- .010 34.54 +/- .15 .54 +/- .05

FOUND AT CUZCO 135 S90 Y ElUR-139 2.6 +/- 1.5 3.016 +/- .042 119'> +/- 28 5.879 +/- .017 Z4.45 +/- .78 .28 +/- .05

13l> 8<;)) Q 2.3 .. /- 1.2 e.325 +/- .061 574 +/- 19 3.'>42 .. /- .1l12 47.09 .. /- .90 .54 +/- .05

GEOLOGICAL SAMPLES FilO~ PERU

AYACUCHO SOURCE 137 845 II FlURG-60 3.1 +/- 1.1l 4.500 +/- .038 288 .. /- 14 .16 "/- .03 $ACliACA. AREQUIPA 4.2 +/- 1.8 1.518 .. ,- .063 11~S +/- 31 .50 +!- .06

YUR!o AREOUIPA 139 661 x BUCIG-SO 1i.2 +/- l.!! 1.5fJlo H- .059 .15 +/- .04

HIGH SILICA GLASS ARTIFACTS FOUND IN TH~ MANTARO VALLEY SAMPLES JUM625 AND JUM616 14<> a 71 R BU~G-98 .4 "/-.3 .6!i2 +/- .01'. 4 +/- .016 +/- .003 .28 .. /- .10 .10 .. /- .02

141 071 S l.6c)7 .. /- .023 1 ... '> .. /- .211 .. /- .005 2.12 +/- .3D .24 +/- .03

6 RUN SAMPLE

f\IJ~G-Z "lU"IC-3 :I 6UliG-6 It BURG-E! ::> BU I

6 ') BU;l.G-ZO 10 Ii BU,(G-26 .434 "I- f( BU'\G-34 12 W BU'lG-39 13 'f ElU~G-41 1" e '3u,(G-"'!i 15 8,,5 I t'lURG-62 16 B6l. BU '0 il90 1. BU"--140 "1- •• l09 .. /- .025 "1 893 F '3U"'-108 .. !- .u2" "2 613 G 13'Jfl-1Ll9 .156 "1- .02" 43 8<;3 Ii flU'l-t 10 <-1- 1.14() .. /- .024 41> cl93 0 flUQ-115 1.16J .024 45 8<)3 P flUR-ll~ ~/- 1.130 <-1-.006 .182 +/- .025 46 914 S ANcn-2 .llJ8 +/-.<11)6 1.136 "1- .027 41 914 .l.NCO-l ~/-.\hj6 1.161 ,,1- .u27 4<'1 a'll) E1UR-l34 1.075 +/-.001 1.125 +/- .025

49 822 BU"-C;-l 1.2lJ9 +/- .021 SO 822 N flUQG-<) 1 +/- .021 51 822 0 RU'lG-IIJI "'/- .)J8 1.213 +/- • ()21 52 822 r 53 82:3 0 5'> 828 (J RURG-31 55 e2@ I'iIJQG-H .5M .. /- 5(, ®2@ "'i' BU'IG-3& 51 a28 l 56 845 J 59 845 '( , RUDG-61 60 ~11 E IVJ D c.-88

CUZco TYPE 61 Ii flU~ G-4 .001 .J7 .019 62 I3U~G-5 .007 .06 .019 63 822 Q BURG-It!. .Ll'17 1.09 B .019 6" 822 I< flUc(G-13 .. 1- .019 65 il22 S '1U~G-14 ?I- .019 66 en v BU~G-~ .., "/- .019 67 828 ,,1- .u3') 68 828 G "1- .030 69 828 J flURG-21 1.093 "'/- • 030 70 El28 )( FlU'1- .U22 74 845 ? BUQG-52 .476 "/- "/-.005 .022 75 845 Q BU~",-53 .4<)5 0021 76 a7l () 8:.)'\ G-9S .483 ",1- .OOB .08 +/-.006 .OZB 17 993 T BUR-Ill .491 "'1- .006 .07 .023 78 B90 K QUfl-1Zo .0<.19 .,)13 .023 79 S9(l I'll "1- .009 ~ 00 .023 8\1 891.1 S .08 .024 81 914 0 BU'<-ll,l .uB .028 82 ell 4- RU'I-L44 '" 08 .O2~ 83 914 flU'I-145 .Oll .025 84 III 4 BUR-14;6 .02B

THICACi\ 95 323 r> 8URG-22 .021 Bb .039 !J,1 1\ .039 88 82;; M BUPG-29 .03') 89 828 U BU"'G-31 .1)42 90 845 H tlU'lr,-46 <-1- .02B 'ill 845 K flUf.\G-4B .,,1- 0028 gz 845 BUrl. G-49 <-1- .028 93 6 t,5 BU 'l.G-5 0 .028 94 845 8')'(G-54 0027 95 dbl 8U'l.G-69 9'1 ab 1 N flU ~G-70 10') 961 0 BU" G- n 101 061 P '''PG-I2 102 86 r RU ~G-76 [l'JRG-17

d6 fl'AMi>b.§ TVP\!: BUIllG-fJ4 IU.6,., '>1-1.11" Iv .9e. "'1- >1- .o'}" 16<1> >1- .046 6U9G-IIS @4.l& .. 1-l.U !i.Oil <>1- >I-.(Ju'ii +1- .0'" BURG-'H 60.31 +1-1.01' "'1- .10 1.5!>5 .I-.OOS 2.®H "1- .045 BUQr,-'n 7~. Ell +1-1.04 +/- .10 1.507 "'1-.OllS 2.696 +1- .040 U.Ji [lU"IG-I-.oorn 2. 8 ~ll .. /- • 045 111 BUR-lot 1'l1 ;!.n3 ",- ,0'0'" ANDAHUAYLAS 6 TYPE AU 822 .969 '>/­ lCl1.41 +/- .95 .o@ 1.J.Hl ./-.00':1 .030 "1- .02e;) 1129 ~ .941- 1·111.68 ./-1."'':1 .11 1.J59 ./- .u,)7 1. ./- • .:132 ~ 1'0 III .IlB .O~l 1011."'9 "I-l.l~ 1.J3'l1 ,,1-. 0/- .G31 ®9;} I' .94S ./­ 10!:l.60 .1-1.10 .031 +/-.007 ./- .02" IHQI ttl .'illvliil <>/~ l\lS.2l <>1-1.11.1 "1- .1l.:!1' 01- .02'9

n&CUCNO TVI''' J ~u~-lI.l .2111 <>1- ./- .ClI' 1. 7rnO "'-.OOI!! .Gle ./- .1.122 12». til'":!} ~ BUIl.-114> .26$ '>1- .006 40.10 +1- .~'ll 3.7& &/- .01 1.lGjl <-I-.ooa .S15 "1- .023

!!lUIl-107

ACARI TVpe .il63 <>/- 4A.6~ +/- .e.u ).01 &/- .1)7 1.151 <>1- .0lH 1.3,,1 ./- .025 .il&Gj <>/- 42.316 -/- .61 2."'@ ~/- .01' 1.3&~ "/-.001' 1.310 +/- .025

orNeR CHe~ICAl CCMpaSITIONS O~ 06SIDIA~ ARTIFACTS

FOUI1dD AT TUMUKU ••21 ./- .~u1' 51 •• 9 .,- .96 3.67 ./- .08 .931 +/-.00& 1.0"10 +/- .029 ••• , ./- .00lii 53.31 +/- .62 3.,e .1- .06 .99'5 ./-.007 1.072 +/- .IlZS FOUIilD AT JAYWAMACHAY .3 ••• /- .~u6 4l."'2 .,- .e2 3.6& ./- .Ylil .951 ./- .032

FOUND AT MUVU uRca .10)1 +/- .~O. 51.0. <-1- .92

fOUI1dD AT ~AVWAKA 12"", tin I" AUPC-9& .lB5 +1- .010 52.20 >1-1.07 to.39 .. /- .09 .640 .1-.006 1.0S3 +/- .029 Ut) £in v FlUI'I-l,J~ .764 +/- .010 e2.70 +'-1.07 4.21) +1- .09 .014 "/-.005 1.0510 0/- .026 lH '11&4> III I!IUFiI-1Io2 .177 "1- .ulo 63 •• 1l .1-1.07 "'.6m +/- .1l9 .Blb +1-.<11.1<1> 1.119 .. /- .029

~ AT IIOICUMACHIIV .2S6 ./- .~06 31.29 ./- .66 2.~1 .. /- .01'

FOUND AT TARaCO IGU~G-1251 AND CHINCH!RAMOQO ISURG-l"ll .,.l,3 .. /- .010 b5.SS >/- .82 3.05 .. /- .07 .989 &/-.007 1.149 ./- .025 .544 "1- .JOS 67.)EI +/- .92 l.21 .. /- .OS 1.003 <>1-.OOb 1.304 ./- .029

FOUND AT CUiCO .!l41' ,,/- .010 52.82 "/- .72 .800 ./-.006 5.67Z ./- .05B

1.476 >/-.001

GeOLOGical SAMPLES FRO~ PERU

AVACUCMO SOURCE .l07 .. /- .OO~ 46.25 ./- .bO 3.11 +/- .or 1.b.1 0/-.001 .74'> .. /- .020 SACHACA. AREQUIPA .845 ./- .0Al 92.&~ .I-l.l~

YIJ!U. UI!QUIP& .la! ~/- .~l~ ~S.~1 ./- .,&

HIGH SiliCA CLASS ARTIFACTS FOUlIIO IN THE MANT4RO VAll:';' SAMPLES JU~625 A~O JUMb16 .004 &1- .1l0! .29 >/- .10 .02 +/- .01 .O~ "1-.001 .OU +/- .005

.11 .. /- .Ol

+1- ., +1- ., +1-.. ,- ,7 14& ~/­ , H!5 +1- ., HZ US! .. /- .,

15'11 '>1- '" "/- HI +1- 6 4 0/- &,

lIU 6!U J 119 1'$'il3 I( UO ~"'l 14 lU 1l'iJ~ N

166 +1- . &, .1n +1- 4

orM~R CH~~IC~t eO~~O$~i(aNS O~ O~SKO!~ &~r~F~CT$

fOUN@ I!;Tf "!'UMlmU 1.Tl .02 .55 ~/- .O~ 3l.H +/- ell!) .1e;, ~/- .05 lel~ +/- .~Z .55 ~/- .O~ ?l03~ '"'1- .1.4 .10 +1= .05

fOUI\lO &1' l.Il' ~/- .5~ +/~ .OZ +/= .11

FOUNO Ai MU~U URea 1.1~ +/- .GZ .$1 +1= .02 ~.~O +/- .11

(;>/- .Oll u.{,!&

FWIII>:! ill"!' UlCl .0:12 134" 'n4 00:!!

FOUMO lilT CUlCCl .~3 .51 .~l

BlftI!!QIJYIil'i\ +/~ .02 l.n +1- .U .,

FOUf'lO IN THE MANUIHl VAI!.lE'" ANO .U <>/- 001 <>/- oO:!) #

822 F ia 822 G San Nicolas, . lca

822 K izo, lca 822 M San Nicolas, Dept. lca

822 P i~ Dept. Ayacucho 822 U Dept.

828 H ill 0, Dept. 828 R ui

Li 828 Y Hacha, . Arequi

845 E a, r

845 Z Huari, Dept. Ayacucho 861 H iss i sane, Huancavelica

861 J Qui isisa mine, Dept. ancavelica

861 K Quispisisa ne, Dept. 1 i ca

R . Ayacucho 861 S in

1

1 a # I

1 T Q n) ash x Q ash 871 Z achay, . Junin 890 E Uchcumachay, Dept. in 890 G Uchcumachay, Dept. Junin

890 H Ataura, Dept. Junin 890 M Jalpacocha, Dept. Ayacucho 890 0 Jaywamachay, Dept. Ayacucho 890 P Jaywamachay, Dept. Ayacucho 890 Q Iomachay, Dept. Ayacucho 890 R Puente, Dept. Ayacucho

890 U Uchcumachay, Dept. Junin 890 V Ataura, Dept. Junin

890 X Ac 300, Dept. Ayacucho 890 Z Ac 300, Dept. Ayacucho 893 F Jaywamachay, Dept. Ayacucho·

893 G Jaywamachay, Dept. Ayacucho 893 H Jaywamachay, Dept. Ayacucho 893 0 Uchcumachay, Dept. in 893 P Jincamoqo, Dept. Ayacucho 914 S , Dept. Lima 914 T Ancon, De . Lima

890 T Cebolla Waiqo, Dept. CUlCO

E a, imac #

822 N a~

822 0 a!) rimae

822 T Waywaka~ Dept. imae 823 0 W ka, Dept. rimae 828 0 Qasawirka, Dept. Apurimae

828 Q S~nta Elena, Dept. Apurimae 828 T Waywaka, Dept. Apurimae 828 Z Pikillaqta, Dept. CUleo

845 J Qasawirka, Dept. Apurimae

845 Y Qasawirka, Dept. Apurimae

871 E Waywaka, De . Apurimae CUleo 822 H Urqo, Dept. CUleo

822 J Minaspata, De . CUleo 822 Q Muyu 'Urqo, Dept. CUleo 822 R Minaspata, Dept. CUleo

822 S Mareavalle, Dept. CUleo 822 V Mareavalle, Dept. CUleo 828 E , Dept. CUleo 828 G , Dept. CUleo

828 J Inc unuhuiri, Puno

828 1i . CUleo

845 F co

G Y amancha 9 co o e co N # NI

845 P , Dept. CUlCO

871 0 r 893 T ,De . La Libertad

890 K Jincamoqo, Dept. Ayacucho 890 N Jincamoqo, Dept. Ayacucho

890 S Hu~ri, Dept. Cuzco 914 0 Taraco, Dept. Puno 914 P Taraco, Dept. Puno 914 Q Taraco, Dept. Puno

914 R Taraco~ Dept. Puno ticaca Basin 823 P liaca, Dept. 828 F , Dept. Cuzco ! 828 K Incatunuhuiri, Dept. Puno

828 M Tumuku, Dept. Puno

828 U Marcavalle, Dept. Cuzco 845 H , Dept. Puno 845 K Pucara, Dept. Puno

845 M Qa 1 , Dept. Puno 845 N Ju i, Dept. Puno

845 R Pukupata, Dept. Cuzco

861 E livia 861 F Sora, Bolivia 1 G livia

1 Llalli9 # NI

N Llall ~ 861 0 Lla 1;,

861 P Llalli~ Dept. Puna 861 T Tiahuanaco, Bolivia

861 U Tiahuanaeo~ Bolivia 861 V Llalli, Dept. Puno

861 Z L1 all i ~ Dept. Puno Pampas Type 870 S Waywaka, Dept. Apurimae 870 T Waywaka, rimae

871 H Jalpaeoeha 9 o Ayaeueho 871 M Waywaka, Dept. Apurimac 871 N Waywaka, De . Apurimac 871 U Jineamoqo, Dept. Ayacueho 871 V Caniehi, Dept. Ayaeucho Andahu

822 Z Waywaka, Dept. Apurimae

828 P Kunka Taka, Dept. Apurimac 870 R a, Dept. imac

890 F Waywaka~ Dept. Apurimac 890 W a, Dept. imac

J I

K N E

893 R Hacha, Dept. 893 S Hacha, Dept. Arequi FOOTNOTES

lIn Near East Central Asia, for example~ there are no obs i dian de et a 1 . ~ 1 ) . 2Archaeo 1 i c sites in northern Chile has not encountered obsidian artifacts or chipping waste (Meighan, personal communication). Obsidian is abundant at many archaeological sites in . Five samples in this study were analyzed by NAA from Chobshi Cave~ an early site in the southern central highlands of Ecuador. Of the five samples tested, three different sources were represented. These three Ecuadorian types were chemically distinct from the obsidian analyzed from Peru and Bolivia. However, no obsidian was analyzed from sites north of

Huamachuco and Truji 10. Whether or not Ecuadorian obsidian was traded northern Peru remains an interesti question. 3There may be occasional exceptions to this, as for example, with the pearly gray obsidian of Melos or the green obsidian from Pachuca in central Mexico. Visual characteristics do not seem to be helpful in identifying the obsidian types analyzed in this study except in the case of red obsidian, which thus far seems to have come exclusively from the Quispisisa source. 40 ptical spectroscopy has been used in several fascinating studies of obsidian in the Near East, the Aegean and the Mediterranean

(Renfrew et a 1 . ~ 1965 9 1966; Dixon et a 1 . , 1968; Cann et a 1 . , 1970) . X-ray fluorescence st ies been used with interesting results in North ica ( son a 1 . , 1) in Mesoamerica (Jack and i zer, et a . , 1 st et a 1. is especial le or its intensive of a si e si usi exc~vated material. In addition to the work done at the Lawrence

Berkeley ora Berkeley~ Cali ana 1 sis obsidian

h s been con 1abo

t iversi Michigan ( n et a 1 " 1 Wri 1969) . 5Those interested in a more detailed description of the more technical aspects of the neutron activation analysis used in this study and an element-by-element evaluation of its precision should consult earlier publications on NAA work done at the Lawrence Berkeley Laboratory (Perlman and Asaro, 1969). Since 1969, changes have been introduced to increase the accuracy of measurement for certain elements and to permit analysis of new elements (Bowman et al., 1973a and b). 6These fi ings come cucaje Phase 9 obsidian artifacts from Pampa Media Luna, Peru!!, an unpublished study by R. Burger. 7The distance figures presented in this article are in rough air mileage and as such underestimate the actual distance travelled along the paths of the sierra. 8Grossman has revised his original correlations with Hacha due to further study and new C14 results. He now correlates Muyu Moqo C-D with Hacha. This revision will be published in the Actas del ndo greso del re y ltura uana, Trujillo. BI I

ila nas 9 , 1 as de Al nas i anas

1i i anas . aciones P licacion 4 Serie, La Paz.

Bennett, Wendell C., 1934. "Excavations at ahuanaco. II ical American Natural Hi Vol. XXXIV, part III, pp. 359 -"494, New k. Bennett, Wendell C., 1944. liThe North Highlands of Peru: Excavations in the Callejon de Huaylas and at Chavin de Huantar," Anthropological Vol. 39, . 1, American Museum of Natural History, New York.

av i a, io Rogger Ravines, "El Preceramico i no:

Evaluacion lema. iI ional, I I I,

. 23 ~ L Bowman, H. R., F. Asaro, and I. Per an, 1973a. IIComposition Variations in -Obsidian Sources and Archaeological Implications.!! ------=-Arch Vol. 15, No.1, pp. 123-127, Great Britain. Bowman, H. R., F. Asaro, and I. Per ,1973b. the ty of Compositions in Obsidians idence for Magmatic xing." The 1 of Geol 1. 81, 3, pp. 312-317, icago.

i d L 0 , of a Central H lands Vall published doctoral thesis. iversi Cambri

B. en e 1 is ino,1i ------" 2, L E. a ue de Ali entos. e 1ema 12, it

i os s , 1 , L ao

Cann 9 J. R. , J. E. Dixon, 19 sidian a1ysis

and the Obs di an Trade. II Don hwe 11 and Eric Higgs, editors, Praeger, New York. Cobean, Robert H., Michael D. Coe, Edward A. Perry, Karl K. Turekian,

and Dinkar P. Kharkar, 1971. "Obsidian Trade at San Lorenzo,

Tenochti t lan, Mexico. II Science, Vo"l. 1749 pp. 666 1, Washington, D.C.

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Rowe, and, 1 in uo ll a

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Sancho la So 10

en la vincis la tilla y la

ana, serie, 2 is 0

1i am T. , 1 5i i 11

i a S 9 R. F. izer~ 1 . a 1Udt ion

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Flow II 79

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Vescelius~ F i s at Nicolas." a 1. 1, ley.

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