ARTICLE https://doi.org/10.1038/s41467-019-13349-1 OPEN Colloidal quantum dot molecules manifesting quantum coupling at room temperature Jiabin Cui 1,2,3, Yossef E. Panfil1,2,3, Somnath Koley1,2,3, Doaa Shamalia1,2, Nir Waiskopf1,2, Sergei Remennik2, Inna Popov2, Meirav Oded1,2 & Uri Banin 1,2* Coupling of atoms is the basis of chemistry, yielding the beauty and richness of molecules. We utilize semiconductor nanocrystals as artificial atoms to form nanocrystal molecules that 1234567890():,; are structurally and electronically coupled. CdSe/CdS core/shell nanocrystals are linked to form dimers which are then fused via constrained oriented attachment. The possible nano- crystal facets in which such fusion takes place are analyzed with atomic resolution revealing the distribution of possible crystal fusion scenarios. Coherent coupling and wave-function hybridization are manifested by a redshift of the band gap, in agreement with quantum mechanical simulations. Single nanoparticle spectroscopy unravels the attributes of coupled nanocrystal dimers related to the unique combination of quantum mechanical tunneling and energy transfer mechanisms. This sets the stage for nanocrystal chemistry to yield a diverse selection of coupled nanocrystal molecules constructed from controlled core/shell nano- crystal building blocks. These are of direct relevance for numerous applications in displays, sensing, biological tagging and emerging quantum technologies. 1 Institute of Chemistry, The Hebrew University of Jerusalem, Jerusalem 91904, Israel. 2 The Center for Nanoscience and Nanotechnology, The Hebrew University of Jerusalem, Jerusalem 91904, Israel. 3These authors contributed equally: Jiabin Cui, Yossef E. Panfil, Somnath Koley. *email:
[email protected] NATURE COMMUNICATIONS | (2019) 10:5401 | https://doi.org/10.1038/s41467-019-13349-1 | www.nature.com/naturecommunications 1 ARTICLE NATURE COMMUNICATIONS | https://doi.org/10.1038/s41467-019-13349-1 olloidal semiconductor quantum dots (CQDs) that con- hetero-plane-attachment in the fusion process.