A Review of Some Recent Concepts of the Bushveld
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Mineral Profile
Platinum September 2009 Definition, mineralogy and Pt Pd Rh Ir Ru Os Au nt Atomic 195.08 106.42 102.91 192.22 101.07 190.23 196.97 deposits weight opme vel Atomic Definition and characteristics 78 46 45 77 44 76 79 de number l Platinum (Pt) is one of a group of six chemical elements ra UK collectively referred to as the platinum-group elements Density ne 21.45 12.02 12.41 22.65 12.45 22.61 19.3 (gcm-3) mi (PGE). The other PGE are palladium (Pd), iridium (Ir), osmium e Melting bl (Os), rhodium (Rh) and ruthenium (Ru). Reference is also 1769 1554 1960 2443 2310 3050 1064 na point (ºC) ai commonly made to platinum-group metals and to platinum- Electrical st group minerals, both often abbreviated to PGM. In this su resistivity r document we use PGM to refer to platinum-group minerals. 9.85 9.93 4.33 4.71 6.8 8.12 2.15 f o (micro-ohm re cm at 0º C) nt Chemically the PGE are all very similar, but their physical Hardness Ce Minerals 4-4.5 4.75 5.5 6.5 6.5 7 2.5-3 properties vary considerably (Table 1). Platinum, iridium (Mohs) and osmium are the densest known metals, being significantly denser than gold. Platinum and palladium are Table 1 Selected properties of the six platinum-group highly resistant to heat and to corrosion, and are soft and elements (PGE) compared with gold (Au). ductile. Rhodium and iridium are more difficult to work, while ruthenium and osmium are hard, brittle and almost pentlandite, or in PGE-bearing accessory minerals (PGM). -
New Mineral Names*,†
American Mineralogist, Volume 104, pages 625–629, 2019 New Mineral Names*,† DMITRIY I. BELAKOVSKIY1 AND FERNANDO CÁMARA2 1Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18 korp. 2, Moscow 119071, Russia 2Dipartimento di Scienze della Terra “Ardito Desio”, Universitá di degli Studi di Milano, Via Mangiagalli, 34, 20133 Milano, Italy IN THIS ISSUE This New Mineral Names has entries for 8 new minerals, including fengchengite, ferriperbøeite-(Ce), genplesite, heyerdahlite, millsite, saranchinaite, siudaite, vymazalováite and new data on lavinskyite-1M. FENGCHENGITE* X-ray diffraction pattern [d Å (I%; hkl)] are: 7.186 (55; 110), 5.761 (44; 113), 4.187 (53; 123), 3.201 (47; 028), 2.978 (61; 135). 2.857 (100; 044), G. Shen, J. Xu, P. Yao, and G. Li (2017) Fengchengite: A new species with 2.146 (30; 336), 1.771 (36; 24.11). Single-crystal X-ray diffraction data the Na-poor but vacancy-dominante N(5) site in the eudialyte group. shows the mineral is trigonal, space group R3m, a = 14.2467 (6), c = Acta Mineralogica Sinica, 37 (1/2), 140–151. 30.033(2) Å, V = 5279.08 Å3, Z = 3. The structure was solved by direct methods and refined to R = 0.043 for all unique I > 2σ(I) reflections. Fengchengite (IMA 2007-018a), Na Ca (Fe3+,) Zr Si (Si O ) 12 3 6 3 3 25 73 Fenchengite is the Fe3+ analog of eudialyte with a structural difference (H O) (OH) , trigonal, is a new eudialyte-group mineral discovered in 2 3 2 in vacancy dominant N5 site and splitting its Na site N1 into N1a and the agpaitic nepheline syenites and its pegmatite facies near the Saima N1b sites. -
STRATIFORM and ALLUVIAL Plafl NUM MINERALIZATION in THE
LU3 The Canadian M iner alog is t Vol. 33,pp. 1023-lM5(1995) STRATIFORMAND ALLUVIALPLAfl NUM MINERALIZATION IN THENEW CALEDONIA OPHIOLITE COMPLEX THIERRY AUGE lNI PIERREMATIRZOT BRGM'Metallogeny and Geotynarnics", B.P. 6009, 45060 Orldans Cedex 2, France ABSTRA T An unusualtype offt mineralizationhas beenfound in the New Caledoniaophiolite complex, associatedwitl stratiform chromite-bearingrocks at the baseof the cumulateseries (close to the transition zone betweendunite and pyroxene-bearing rocks) and with cbromite-richpyroxenite dykes from the samezone. Two placer deposis, both enrichedin Fl also have been recognized one derived from the chromite-rich horizons and the other a cbromitiferous beach sand of unknown origin. Chromite-bearingrocks aremarked by a very strongenrichment in Pt relative to fhe other platinum-groupelements (PGE), $'ith a rrardmunconcentration of 11.5ppm (average3.9 ppm). The Pt enrichmenttakes the form of platinum-groupminerals (PGM) included in chromite crystals and is interpretedas being pdlrar'/. The following minerals have been identified: ft-Fe{u alloys (isoferroplatinum,tulame€nite, tetraferroplatinum and undeterminedphases), cooperite, laurite, bowieite, malanite, cuprorhodsite,unnamed PGE oxides, and base-metalsulfides with PGE in solid solution. The associatedplacers show a slightly different mineral association,with isoferroplatinum,tulameenite, and rare cooperite,sperrylite, Os-k-Ru alloys and PGE oxides. A more complex paragenesishas been identified in the beach san4 with isoferroplatinum,cooperite, laurite, erlichmanite, Os-Ir-Ru alloys, bowieite, ba$ite, hollingworthire, sperrylite, stibiopalladinite, and unnamed Rh sulfide, Pt-Ru-Rh alloy and PGE oxides. This type of mineralization, which differs markedly from the Os-Ru-h mineralization previously recognized in podiform cbromitite in New Caledonia, shows several analogies with Alaskan-type PGE mineralization.The host chromitite,with typical cumulustextwes, is markedby Ti and Feh emichmentdue to derivationfrom an evolved liquid. -
ECONOMIC GEOLOGY RESEARCH INSTITUTE HUGH ALLSOPP LABORATORY University of the Witwatersrand Johannesburg
ECONOMIC GEOLOGY RESEARCH INSTITUTE HUGH ALLSOPP LABORATORY University of the Witwatersrand Johannesburg CHROMITITES OF THE BUSHVELD COMPLEX- PROCESS OF FORMATION AND PGE ENRICHMENT J.A. KINNAIRD, F.J. KRUGER, P.A.M. NEX and R.G. CAWTHORN INFORMATION CIRCULAR No. 369 UNIVERSITY OF THE WITWATERSRAND JOHANNESBURG CHROMITITES OF THE BUSHVELD COMPLEX – PROCESSES OF FORMATION AND PGE ENRICHMENT by J. A. KINNAIRD, F. J. KRUGER, P.A. M. NEX AND R.G. CAWTHORN (Department of Geology, School of Geosciences, University of the Witwatersrand, Private Bag 3, P.O. WITS 2050, Johannesburg, South Africa) ECONOMIC GEOLOGY RESEARCH INSTITUTE INFORMATION CIRCULAR No. 369 December, 2002 CHROMITITES OF THE BUSHVELD COMPLEX – PROCESSES OF FORMATION AND PGE ENRICHMENT ABSTRACT The mafic layered suite of the 2.05 Ga old Bushveld Complex hosts a number of substantial PGE-bearing chromitite layers, including the UG2, within the Critical Zone, together with thin chromitite stringers of the platinum-bearing Merensky Reef. Until 1982, only the Merensky Reef was mined for platinum although it has long been known that chromitites also host platinum group minerals. Three groups of chromitites occur: a Lower Group of up to seven major layers hosted in feldspathic pyroxenite; a Middle Group with four layers hosted by feldspathic pyroxenite or norite; and an Upper Group usually of two chromitite packages, hosted in pyroxenite, norite or anorthosite. There is a systematic chemical variation from bottom to top chromitite layers, in terms of Cr : Fe ratios and the abundance and proportion of PGE’s. Although all the chromitites are enriched in PGE’s relative to the host rocks, the Upper Group 2 layer (UG2) shows the highest concentration. -
List of New Mineral Names: with an Index of Authors
415 A (fifth) list of new mineral names: with an index of authors. 1 By L. J. S~v.scs~, M.A., F.G.S. Assistant in the ~Iineral Department of the,Brltish Museum. [Communicated June 7, 1910.] Aglaurito. R. Handmann, 1907. Zeita. Min. Geol. Stuttgart, col. i, p. 78. Orthoc]ase-felspar with a fine blue reflection forming a constituent of quartz-porphyry (Aglauritporphyr) from Teplitz, Bohemia. Named from ~,Xavpo~ ---- ~Xa&, bright. Alaito. K. A. ~Yenadkevi~, 1909. BuU. Acad. Sci. Saint-P6tersbourg, ser. 6, col. iii, p. 185 (A~am~s). Hydrate~l vanadic oxide, V205. H~O, forming blood=red, mossy growths with silky lustre. Founi] with turanite (q. v.) in thct neighbourhood of the Alai Mountains, Russian Central Asia. Alamosite. C. Palaehe and H. E. Merwin, 1909. Amer. Journ. Sci., ser. 4, col. xxvii, p. 899; Zeits. Kryst. Min., col. xlvi, p. 518. Lead recta-silicate, PbSiOs, occurring as snow-white, radially fibrous masses. Crystals are monoclinic, though apparently not isom0rphous with wol]astonite. From Alamos, Sonora, Mexico. Prepared artificially by S. Hilpert and P. Weiller, Ber. Deutsch. Chem. Ges., 1909, col. xlii, p. 2969. Aloisiite. L. Colomba, 1908. Rend. B. Accad. Lincei, Roma, set. 5, col. xvii, sere. 2, p. 233. A hydrated sub-silicate of calcium, ferrous iron, magnesium, sodium, and hydrogen, (R pp, R',), SiO,, occurring in an amorphous condition, intimately mixed with oalcinm carbonate, in a palagonite-tuff at Fort Portal, Uganda. Named in honour of H.R.H. Prince Luigi Amedeo of Savoy, Duke of Abruzzi. Aloisius or Aloysius is a Latin form of Luigi or I~ewis. -
Mineral Collecting Sites in North Carolina by W
.'.' .., Mineral Collecting Sites in North Carolina By W. F. Wilson and B. J. McKenzie RUTILE GUMMITE IN GARNET RUBY CORUNDUM GOLD TORBERNITE GARNET IN MICA ANATASE RUTILE AJTUNITE AND TORBERNITE THULITE AND PYRITE MONAZITE EMERALD CUPRITE SMOKY QUARTZ ZIRCON TORBERNITE ~/ UBRAR'l USE ONLV ,~O NOT REMOVE. fROM LIBRARY N. C. GEOLOGICAL SUHVEY Information Circular 24 Mineral Collecting Sites in North Carolina By W. F. Wilson and B. J. McKenzie Raleigh 1978 Second Printing 1980. Additional copies of this publication may be obtained from: North CarOlina Department of Natural Resources and Community Development Geological Survey Section P. O. Box 27687 ~ Raleigh. N. C. 27611 1823 --~- GEOLOGICAL SURVEY SECTION The Geological Survey Section shall, by law"...make such exami nation, survey, and mapping of the geology, mineralogy, and topo graphy of the state, including their industrial and economic utilization as it may consider necessary." In carrying out its duties under this law, the section promotes the wise conservation and use of mineral resources by industry, commerce, agriculture, and other governmental agencies for the general welfare of the citizens of North Carolina. The Section conducts a number of basic and applied research projects in environmental resource planning, mineral resource explora tion, mineral statistics, and systematic geologic mapping. Services constitute a major portion ofthe Sections's activities and include identi fying rock and mineral samples submitted by the citizens of the state and providing consulting services and specially prepared reports to other agencies that require geological information. The Geological Survey Section publishes results of research in a series of Bulletins, Economic Papers, Information Circulars, Educa tional Series, Geologic Maps, and Special Publications. -
Thirty-Fourth List of New Mineral Names
MINERALOGICAL MAGAZINE, DECEMBER 1986, VOL. 50, PP. 741-61 Thirty-fourth list of new mineral names E. E. FEJER Department of Mineralogy, British Museum (Natural History), Cromwell Road, London SW7 5BD THE present list contains 181 entries. Of these 148 are Alacranite. V. I. Popova, V. A. Popov, A. Clark, valid species, most of which have been approved by the V. O. Polyakov, and S. E. Borisovskii, 1986. Zap. IMA Commission on New Minerals and Mineral Names, 115, 360. First found at Alacran, Pampa Larga, 17 are misspellings or erroneous transliterations, 9 are Chile by A. H. Clark in 1970 (rejected by IMA names published without IMA approval, 4 are variety because of insufficient data), then in 1980 at the names, 2 are spelling corrections, and one is a name applied to gem material. As in previous lists, contractions caldera of Uzon volcano, Kamchatka, USSR, as are used for the names of frequently cited journals and yellowish orange equant crystals up to 0.5 ram, other publications are abbreviated in italic. sometimes flattened on {100} with {100}, {111}, {ill}, and {110} faces, adamantine to greasy Abhurite. J. J. Matzko, H. T. Evans Jr., M. E. Mrose, lustre, poor {100} cleavage, brittle, H 1 Mono- and P. Aruscavage, 1985. C.M. 23, 233. At a clinic, P2/c, a 9.89(2), b 9.73(2), c 9.13(1) A, depth c.35 m, in an arm of the Red Sea, known as fl 101.84(5) ~ Z = 2; Dobs. 3.43(5), D~alr 3.43; Sharm Abhur, c.30 km north of Jiddah, Saudi reflectances and microhardness given. -
The Original Lithologies and Their Metamorphism
BASIC PLUTONIC INTRUSIONS OF THE RISÖR SÖNDELED AREA, SOUTH NORWAY: THE ORIGINAL LITHOLOGIES AND THEIR METAMORPHISM IAN C. STARMER Department of Geology, University of Nottingham, England Present address: Dept. of Geo/ogy, Queen Mary College, London, E. l STARMER, I. C.: Basic plutonic intrusions of the Risör-Sändeled area South Norway: The original Jithologies and their metamorphism Norsk Geologisk Tidsskri/1, Vol. 49, pp. 403-431. Oslo 1969. The emplacement of Pre-Cambrian basic intrusions is shown to have been a polyphase process and to have occurred Jargely between two major periods of metamorphism. The original igneous lithologies are discussed and a regional differentiation series is demonstrated, with changes in rock-type accompanied by some cryptic variation in the component minerals. Metamorphism after consolidation converted the intrusives to coronites and eaused partial amphibolitisation. Corona growths are described and attributed to essentially isochemical recrystal lisations in the solid-state, promoted by the diffusion of ions in inter granular fluids. The amphibolitisation of the bodies is briefly outlined, and it is concluded that the formation of amphibolite involved the intro duction of considerable amounts of extraneous water. The criterion for demoostrating the onset of amphibolitisation is thought to be the intemal replacement of pyroxene by homblende, contrasting with the replacement of plagioclase by various amphiboles during corona growth. Both amphibolites and coronites have been scapolitised, and this may have been an extended process which certainly continued after amphi bolitisation. Regional implications are considered and it is suggested that a !arge mass of differentiating magma may have underlain the whole region in Pre-Cambrian times. -
Platinum Group Minerals in Eastern Brazil GEOLOGY and OCCURRENCES in CHROMITITE and PLACERS
DOI: 10.1595/147106705X24391 Platinum Group Minerals in Eastern Brazil GEOLOGY AND OCCURRENCES IN CHROMITITE AND PLACERS By Nelson Angeli Department of Petrology and Metallogeny, University of São Paulo State (UNESP), 24-A Avenue, 1515, Rio Claro (SP), 13506-710, Brazil; E-mail: [email protected] Brazil does not have working platinum mines, nor even large reserves of the platinum metals, but there is platinum in Brazil. In this paper, four massifs (mafic/ultramafic complexes) in eastern Brazil, in the states of Minas Gerais and Ceará, where platinum is found will be described. Three of these massifs contain concentrations of platinum group minerals or platinum group elements, and gold, associated with the chromitite rock found there. In the fourth massif, in Minas Gerais State, the platinum group elements are found in alluvial deposits at the Bom Sucesso occurrence. This placer is currently being studied. The platinum group metals occur in specific Rh and Os occur together in minerals in various areas of the world: mainly South Africa, Russia, combinations. This particular PGM distribution Canada and the U.S.A. Geological occurrences of can also form noble metal alloys (7), and minerali- platinum group elements (PGEs) (and sometimes sation has been linked to crystallisation during gold (Au)) are usually associated with Ni-Co-Cu chromite precipitation of hydrothermal origin. sulfide deposits formed in layered igneous intru- In central Brazil there are massifs (Americano sions. The platinum group minerals (PGMs) are do Brasil and Barro Alto) that as yet are little stud- associated with the more mafic parts of the layered ied, and which are thought to contain small PGM magma deposit, and PGEs are found in chromite concentrations. -
Petrology of the Noritic and Gabbronoritic Rocks Below the J-M Reef in the Mountain View Area, Stillwater Complex, Montana
Petrology of the Noritic and Gabbronoritic Rocks below the J-M Reef in the Mountain View Area, Stillwater Complex, Montana U.S. GEOLOGICAL SURVEY BULLETIN 1674-C Chapter C Petrology of the Noritic and Gabbronoritic Rocks below the J-M Reef in the Mountain View Area, Stillwater Complex, Montana By NORMAN J PAGE and BARRY C. MORING U.S. GEOLOGICAL SURVEY BULLETIN 1674 CONTRIBUTIONS ON ORE DEPOSITS IN THE EARLY MAGMATIC ENVIRONMENT DEPARTMENT OF THE INTERIOR MANUEL LUJAN, JR., Secretary U.S. GEOLOGICAL SURVEY Dallas L. Peck, Director Any use of trade, product, or firm names in this publication is for descriptive purposes only and does not imply endorsement by the U.S. Government UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1990 For sale by the Books and Open-File Reports Section, U.S. Geological Survey Federal Center, Box 25425 Denver, CO 80225 Library of Congress Cataloging-in-Publication Data Page, Norman, J Petrology of the noritic and gabbronoritic rocks below the J-M Reef in the Mountain View area, Stillwater Complex, Montana / by Norman J Page and Barry C. Moring. p. cm. (U.S. Geological Survey bulletin ; 1674-C) (Contributions on ore deposits in the early magmatic environment Includes bibliographical references. Supt. of Docs, no.: I 19.3: 1674-C 1. Petrology Beartooth Mountains Region (Mont, and Wyo.) 2. Geolo gy Beartooth Mountains Region (Mont, and Wyo.) I. Moring, Barry C. II. Title. III. Title: Stillwater Complex, Montana. IV. Series. V. Series: Contri butions on ore deposits in the early magmatic environment ; ch. -
Wang Et Al., 2001
American Mineralogist, Volume 86, pages 790–806, 2001 Characterization and comparison of structural and compositional features of planetary quadrilateral pyroxenes by Raman spectroscopy ALIAN WANG,* BRAD L. JOLLIFF, LARRY A. HASKIN, KARLA E. KUEBLER, AND KAREN M. VISKUPIC Department of Earth and Planetary Sciences and McDonnell Center for the Space Sciences, Washington University, St. Louis, Missouri 63130, U.S.A. ABSTRACT This study reports the use of Raman spectral features to characterize the structural and composi- tional characteristics of different types of pyroxene from rocks as might be carried out using a por- table field spectrometer or by planetary on-surface exploration. Samples studied include lunar rocks, martian meteorites, and terrestrial rocks. The major structural types of quadrilateral pyroxene can be identified using their Raman spectral pattern and peak positions. Values of Mg/(Mg + Fe + Ca) of pyroxene in the (Mg, Fe, Ca) quadrilateral can be determined within an accuracy of ±0.1. The preci- sion for Ca/(Mg + Fe + Ca) values derived from Raman data is about the same, except that correc- tions must be made for very low-Ca and very high-Ca samples. Pyroxenes from basalts can be distinguished from those in plutonic equivalents from the distribution of their Mg′ [Mg/(Mg + Fe)] and Wo values, and this can be readily done using point-counting Raman measurements on unpre- pared rock samples. The correlation of Raman peak positions and spectral pattern provides criteria to distinguish pyroxenes with high proportions of non-quadrilateral components from (Mg, Fe, Ca) quadrilateral pyroxenes. INTRODUCTION pyroxene group of minerals is amenable to such identification Laser Raman spectroscopy is well suited for characteriza- and characterization. -
The Bushveld Igneous Complex
The Bushveld Igneous Complex THE GEOLOGY OF SOUTH AFRICA’S PLATINUM RESOURCES By C. A. Cousins, MSC. Johannesburg Consolidated Investment Company Limited A vast composite body of plutonic and volcanic rock in the central part of the Transvaal, the Bushveld igneous complex includes the platinum reef worked by Rustenburg Platinum Mines Limited and constituting the world’s greatest reserve of the platinum metals. This article describes the geological and economic aspects of this unusually interesting formation. In South Africa platinum occurs chiefly in square miles. Two of these areas lie at the the Merensky Reef, which itself forms part of eastern and western ends of the Bushveld and the Bushveld igneous complex, an irregular form wide curved belts, trending parallel to oval area of some 15,000 square miles occupy- the sedimentary rocks which they overlie, and ing a roughly central position in the province dipping inwards towards the centre of the of the Transvaal. A geological map of the Bushveld at similar angles. The western belt area, which provides the largest known has a flat sheet-like extension reaching the example of this interesting type of formation, western boundary of the Transvaal. The is shown on the facing page. third area extends northwards and cuts out- The complex rests upon a floor of sedi- side the sedimentary basin. Its exact relation- mentary rocks of the Transvaal System. This ship to the other outcrops within the basin floor is structurally in the form of an immense has not as yet been solved. oval basin, three hundred miles long and a As the eastern and western belts contain hundred miles broad.