Differentiated Mafic-Ultramafic Sills in the Archean Vermilion District

Total Page:16

File Type:pdf, Size:1020Kb

Differentiated Mafic-Ultramafic Sills in the Archean Vermilion District DIFFERENTIATED !-'1..1"\.FIC-ULTRAMAFIC SILLS IN THE ARCHEAN VERMILION DISTRICT, NORTHEASTERN .MINNESOTA A THESIS SUBMITTED TO THE FACULTY OF THE SCEOCL OF THE OF 1'1INNESOTl:. BY SCI·JULZ IN PARTIAL FULF'ILU--1EN'l1 OF TEE REQun;.EMEN'i.'S FOR THE DEGREE OF :MAS'rER OF SCIENCE FEBRUARY 1, 1974 i . ABSTRACT Detailed mapping of part of the Newton Lake Forma- tion north of Ely, Minnesota has shown the presence of numerous sill-like mafic-ultramafic intrusions in the Archean volcanic sequence. Three types of intrusions have been found: layered, differentiated mafic-ultra- mafic sills ranging from 400 to 1500 feet thick and at least 4 miles long; gabbroic sills of variable thickness and e x tent; and ultrarnafic lenses ranging from 75 to 300 feet thick and up to .3000 feet long. The layered sills were studied in detail. They have a wel1-developed internal stratigraphy which consists of a lower chilled-margin, peridotite, pyroxenite, bron- zite gabbro, and gabbro units and an upper chilled-margin. Petrographic studies indicate that the units formed by gravitational accumulation of mineral grains, The ::;tr at- igrap.hic succession reflects the general order of crystal- ization: 1) chromite, 2) chromite· + olivine, 3) clino- pyroxene + orthopyroxene, 4) clinopyroxene + orthopyroxene + plagioclase, 5) clinopyroxene + plagioclase. Microprobe analyses of cumulus pyroxenes has shown crypti c variations exist between units. Th e gabbroic sills are generally similar to the upper gabbroic parts of the layered sills. The ultramafic lense s consist of a central peridotite unit surround by a com- plex chilled-margin. Textural and structural features of ii the u1tramafic lenses suggest intrusion of an olivine bearing liquid, with flowage differentiation forming . the peridoti te unit and rapid chilling of a crystal free liquid forming the chilled-margin. Di£ferentiation trends of whole rock samples and calculated liquid compositions of the layered intrus- ions are generally in close agreement and show a gen- eral iron but ·minimal alkali enrichment with differ" entiation. Chemical analyses of chilled-:-ma.rgins are low in Al2o3 {lO wt%) and high in MgO (11 wt%) with a high Ca0/Al2o3 ratio {0.85). The calculated bulk composition is distinctly ultrabasic in nature (MgO= 17 wt%). Mixing calculations utilizing least square methods sugg.est that the magma Wi:lS partially di ff er- entiated at the time of intrusion. The bulk tion for the layered sills i.s very similar to high::-EgO basalts from the Archean of Western Australia, An i .nital magma temperature for the layered intrus-:- ions of between 1200°C and 1100°C is inferred from element partitioning between coexisting mineral phases. Textural relations ana phase equilibria suggest that crysta1lization of both sills and lenses probably did not take place under pressures greater than about l kb. ( 2. 7 h"1) and may have been even lower. Metamorphism of the lower gra.d.es of the greenschist facies has affected all rocks of the Newton Lake Forma- tion. The ultramafic rocks are serpentinized to varying degrees with olivine often the only altered phas e. ..L..L..L Serpentinization appears to have along microfractures which cut the peridotite. The mafic rocks typically have actinolite, sausseritized ioclase, chlorite, epidote, and rare sphene. Relict grains are common in both ultramafic and mafic units suggesting that metamorphic reactions were retarded perhaps by low H2o and co 2 availability and pressure, The layered sills and lenses of the Newton Lake Formation apparently formed penecontemporaneously with the surrounding basic volcanic rocks, The layered sills probably formed as high level synvolcanic intrusions,. some of which may have also acted as magma chambers for gabbroic liquids which formed sills and/or flows. The ultramafic lenses could be smaller injections of the same magma which formed the larger layered sills, iv TABLE OF CONTENTS Page ABSTRACT ...••.•..... , .•• . , , , . .. , , .. i TABLE OF CONTENTS .. , ... , ••••••• .. .. , ..... •.• iv LIST .OF ILLUSTRATIONS. • •.••.•.•. , . ' . , .. vi INTRODUCTION. • • . • • • . • • .•• . ' ... 1 Location ..••..•••. I • ' • • . .. .. "' .. ' . PE'J.'l.(OLOGY II ••••••• y ill ••• , •••••••••• ' , .. , .••.. , . 87 Formation of the Layered Sequence in the Differ- entiated Sills.,..... • ..••••••• ,. , .•••.•. 87 Peridotite.. ..••.••••••..•.••.•.•.•. .91 Pyroxenite.. • ., .•.•.•• ,,96 Bronzite Gabbro and Gabbro. ·, .• , •...•••. 100 Formation of the Chilled-Margins. • ••. .••• , . , 104 Chilled-Margins of the Ultramafic Lenses .••••. 109 PETROCHEMICAL ASPECTS OF Nm\1TON LAKE SILLS. • . .•. 110 Mineral for the Layered Sills •.•. , .. 110 ,... ..,., ... ... 110 Orthopyroxene..... ···•·i·••·•· ,113 li tlg i te ... , ... ... .. ... ••••. 116 Chromian • • • • !'. ' • , ••••••• ' • f , , • , 119 Amphibole ••. , .... .. ' ,. ' .. 120 Plagioclase ... ,. , . ... , .... , . .., •• 126 Major Element Geochemistry of the Layered SiJ.J.s ....... , ......................... ., ·. ·• ·• .130 v Cedar Lake Sill •••••. , ••.•••.•••• , .•. ,.,,,130 S i· 1 1ca.· , . , ......... ....... ! • ', . • , • , • , 137 Aluminum . ..... , " .•.. ,. ........ , ... , .•. , 13 7 Iron (Fe2o3 + FeO) .•. , .•.•.•.•.•••.•. 137 Magnesium .... , , •.•.•• , ,. •.•.•. #. •• • 138 Calcium ....... .,, .....•. , .•.... ,,., ... .,138 Sodium . , .... , ., , ... , .. f •• , ••••• , • ,. , • 13 9 Potassium . ... , ... , .. , , ..... , .. , .... !It • 13 9 Titanium . .... !' ••• , •••••• .,, ••••• , • , • , • • 13 9 Manganese ... f. !I,, .... , •••.• ••• 139 Phosphorus ..• , .. , .•••... , ..••.•.•••. ,140 Picketts Lake Sill Peridotite .•••..• ,., .•• 140 Differentiation Trends •.•• ,., .•.•.•. , .•••••• ,. ,141 Fe?t - MgO - Cao ..•• .•. •• 141 - FeOt - MgO Var1at1on ...•• , .•. ,., .•. ,142 Oxides Versus MgO ..•.... , .•...•.•••... ,.,.142 Successive Magmatic Liquid Compositions in a Di£ferentiated Layered Sill .. • .•....•.•. , ••. ,.,147 Bulk Compositions of the Layered Sills .•.•... ,.153 Comparison of the Bulk and Chilled--Margin Compo,... si tions w·i th other maf ic rock types .. , . , .•.•.•. 159 Order o .f Crystallization in the Layered Sills .. 167 Temoerature and Pressure of Formation of the I .. Sills based on Mineral Coi:Tlposi ti.on and Textural Relations ..•....•...••....•.•.•.•.•. , .17 5 Temperature . ..................... '! ..... t • , • , • 175 Orthopyrox ene-Clinopy roxene .•.•. ,., .• 175 Olivine-Chromia.n Sp inel . ...... ...•.• 176 Ca/Ca+ Mg Ratios in Pyroxenes ..•.•.• 178 Eval ua ti on . .. ,. , .. , .. 11 •• , • , 11 " • .. ••• , 178 Press t1r e ........ ., .......•. ,. ......... , ...... 18 0 METAMORPHISM OF THE NE\tJTON LAKE SILLS ............... 18 2 General Preservation of Textures ..•. , .....•.... 182 Ul tr amaf.ic Rocks ...........•................... 18 3 11-.af ic Rocks . •..... ....••...•.. a , . ........ ., ••••••• • 18 9 PETROGENESIS J._ND GEOLOGIC HIS'rORY FOR NEWTON LAKE S I LL S .. , , . .. " . , . • . , . , . ! • • • , 191 Classification .....••..•.... ,., ...•.•. ,.,. ,. , .• 191 Origin of the Newton Lake Sills and Lenses ••.•• 193 Summary of the Geologic History of the Newton Lake Form.a tion . .•.... , ...•. , . , . , .......•.•.• • 19 6 ECONOiciIC GEOLOGY ......•...•.••.• ••• , •....•...• , .. 198 SUMMARY AND CONCLUSIONS ......•. .... ! •• , • , ••••••••• , •• 200 ... ............. ,. .....•• it" •• ,.. 11 ?',.,.,.,.,.,. 205 vi LIST OF ILLUSTRATIONS Plates Page I Geologic Map of a Portion of the Newton Lake Formati.on. ,, .......... , ............... , ..... Pocket II NW-SE Structural Section of a Portion of the Newton Lake Formation ..••••••.•. ,. 1 ., ••• , ••• Pocket Tables 1. Rock-type Classification .....•.•...•...•••..... 17 2. Alteration products for layered sill minerals .. 25 3. Modal compositions for chilled-margin zone •..•• 30 4. Modal compositions for peridotite unit .•.••.. ,.41 5. Modal compositions for pyroxenite unit .... , ...• 50 6. Modal compositions for bronzite gabbro unit.,.,59 7, Modal compositions for gabbro unit ........•.•• ,67 8. Chemical composition and structural formulas for analyzed oli vines ....•. , ... , .•..... , •.... 111 9. Chemical composition and structural formulas for analyzed pyroxenes .....•...•.....•...•.•.• 115 10. Chemical composition and structural formulas for analyzed chromian spinels ... 11. Chemical composition and st:ructural formulas for analyzed-primary amphiboles ...... , ..•.•••. 125 12. Chemical analyses from the Newton Lake layered s i )".ls . ...... , ......................... 1 ·: •••• 13 3 13. Reca.lculated chemical analy ses ....... , .....•.• J. 34 . 14. C.I.P.W. norms for chemical a11a·:?:yses • .•...•.••...•..••.. , • _ •.••.•• , ....... , 13 5 15. BuJ_k analyses for relevant igneous rock types.165 Figures 1. Locationmap and geologic setting, .•.. , ..•. , ••• 2 2a. General geologic map for the weste rn portion of the Vermilion District., .. , ...•. , .........•• 5 2b. General geologic map of the central portion of the Vermilion District ... , .•.......•..... , .. 6 3. Major zones and units for a typical layered sill ....•. , .•...•...•.•. , .. , •.. 18 4. Stratigraphic columns for some of the Newton Lake s i 11 s . ! • • • • • • • • , • • , !t , 1 • , • • • , • • • • • 2 O 5. Rhythmic layering· in a bronzi te , • , • 23 6, Lamination in peridotite .......... , ... , .•• , ••. ,23 7, Ideal chilled-margin sequence, .•...•••••...•••. 28 8. Photomicrograph: Unit A, chilled-margin.,,., ••. 32 9. Photomicrograph: amygdule, Unit B, chilled,... mar·g i r.t . •••.••• r • ., • fJ .....
Recommended publications
  • List of New Mineral Names: with an Index of Authors
    415 A (fifth) list of new mineral names: with an index of authors. 1 By L. J. S~v.scs~, M.A., F.G.S. Assistant in the ~Iineral Department of the,Brltish Museum. [Communicated June 7, 1910.] Aglaurito. R. Handmann, 1907. Zeita. Min. Geol. Stuttgart, col. i, p. 78. Orthoc]ase-felspar with a fine blue reflection forming a constituent of quartz-porphyry (Aglauritporphyr) from Teplitz, Bohemia. Named from ~,Xavpo~ ---- ~Xa&, bright. Alaito. K. A. ~Yenadkevi~, 1909. BuU. Acad. Sci. Saint-P6tersbourg, ser. 6, col. iii, p. 185 (A~am~s). Hydrate~l vanadic oxide, V205. H~O, forming blood=red, mossy growths with silky lustre. Founi] with turanite (q. v.) in thct neighbourhood of the Alai Mountains, Russian Central Asia. Alamosite. C. Palaehe and H. E. Merwin, 1909. Amer. Journ. Sci., ser. 4, col. xxvii, p. 899; Zeits. Kryst. Min., col. xlvi, p. 518. Lead recta-silicate, PbSiOs, occurring as snow-white, radially fibrous masses. Crystals are monoclinic, though apparently not isom0rphous with wol]astonite. From Alamos, Sonora, Mexico. Prepared artificially by S. Hilpert and P. Weiller, Ber. Deutsch. Chem. Ges., 1909, col. xlii, p. 2969. Aloisiite. L. Colomba, 1908. Rend. B. Accad. Lincei, Roma, set. 5, col. xvii, sere. 2, p. 233. A hydrated sub-silicate of calcium, ferrous iron, magnesium, sodium, and hydrogen, (R pp, R',), SiO,, occurring in an amorphous condition, intimately mixed with oalcinm carbonate, in a palagonite-tuff at Fort Portal, Uganda. Named in honour of H.R.H. Prince Luigi Amedeo of Savoy, Duke of Abruzzi. Aloisius or Aloysius is a Latin form of Luigi or I~ewis.
    [Show full text]
  • Mineral Collecting Sites in North Carolina by W
    .'.' .., Mineral Collecting Sites in North Carolina By W. F. Wilson and B. J. McKenzie RUTILE GUMMITE IN GARNET RUBY CORUNDUM GOLD TORBERNITE GARNET IN MICA ANATASE RUTILE AJTUNITE AND TORBERNITE THULITE AND PYRITE MONAZITE EMERALD CUPRITE SMOKY QUARTZ ZIRCON TORBERNITE ~/ UBRAR'l USE ONLV ,~O NOT REMOVE. fROM LIBRARY N. C. GEOLOGICAL SUHVEY Information Circular 24 Mineral Collecting Sites in North Carolina By W. F. Wilson and B. J. McKenzie Raleigh 1978 Second Printing 1980. Additional copies of this publication may be obtained from: North CarOlina Department of Natural Resources and Community Development Geological Survey Section P. O. Box 27687 ~ Raleigh. N. C. 27611 1823 --~- GEOLOGICAL SURVEY SECTION The Geological Survey Section shall, by law"...make such exami­ nation, survey, and mapping of the geology, mineralogy, and topo­ graphy of the state, including their industrial and economic utilization as it may consider necessary." In carrying out its duties under this law, the section promotes the wise conservation and use of mineral resources by industry, commerce, agriculture, and other governmental agencies for the general welfare of the citizens of North Carolina. The Section conducts a number of basic and applied research projects in environmental resource planning, mineral resource explora­ tion, mineral statistics, and systematic geologic mapping. Services constitute a major portion ofthe Sections's activities and include identi­ fying rock and mineral samples submitted by the citizens of the state and providing consulting services and specially prepared reports to other agencies that require geological information. The Geological Survey Section publishes results of research in a series of Bulletins, Economic Papers, Information Circulars, Educa­ tional Series, Geologic Maps, and Special Publications.
    [Show full text]
  • The Original Lithologies and Their Metamorphism
    BASIC PLUTONIC INTRUSIONS OF THE RISÖR­ SÖNDELED AREA, SOUTH NORWAY: THE ORIGINAL LITHOLOGIES AND THEIR METAMORPHISM IAN C. STARMER Department of Geology, University of Nottingham, England Present address: Dept. of Geo/ogy, Queen Mary College, London, E. l STARMER, I. C.: Basic plutonic intrusions of the Risör-Sändeled area South Norway: The original Jithologies and their metamorphism Norsk Geologisk Tidsskri/1, Vol. 49, pp. 403-431. Oslo 1969. The emplacement of Pre-Cambrian basic intrusions is shown to have been a polyphase process and to have occurred Jargely between two major periods of metamorphism. The original igneous lithologies are discussed and a regional differentiation series is demonstrated, with changes in rock-type accompanied by some cryptic variation in the component minerals. Metamorphism after consolidation converted the intrusives to coronites and eaused partial amphibolitisation. Corona growths are described and attributed to essentially isochemical recrystal­ lisations in the solid-state, promoted by the diffusion of ions in inter­ granular fluids. The amphibolitisation of the bodies is briefly outlined, and it is concluded that the formation of amphibolite involved the intro­ duction of considerable amounts of extraneous water. The criterion for demoostrating the onset of amphibolitisation is thought to be the intemal replacement of pyroxene by homblende, contrasting with the replacement of plagioclase by various amphiboles during corona growth. Both amphibolites and coronites have been scapolitised, and this may have been an extended process which certainly continued after amphi­ bolitisation. Regional implications are considered and it is suggested that a !arge mass of differentiating magma may have underlain the whole region in Pre-Cambrian times.
    [Show full text]
  • Petrology of the Noritic and Gabbronoritic Rocks Below the J-M Reef in the Mountain View Area, Stillwater Complex, Montana
    Petrology of the Noritic and Gabbronoritic Rocks below the J-M Reef in the Mountain View Area, Stillwater Complex, Montana U.S. GEOLOGICAL SURVEY BULLETIN 1674-C Chapter C Petrology of the Noritic and Gabbronoritic Rocks below the J-M Reef in the Mountain View Area, Stillwater Complex, Montana By NORMAN J PAGE and BARRY C. MORING U.S. GEOLOGICAL SURVEY BULLETIN 1674 CONTRIBUTIONS ON ORE DEPOSITS IN THE EARLY MAGMATIC ENVIRONMENT DEPARTMENT OF THE INTERIOR MANUEL LUJAN, JR., Secretary U.S. GEOLOGICAL SURVEY Dallas L. Peck, Director Any use of trade, product, or firm names in this publication is for descriptive purposes only and does not imply endorsement by the U.S. Government UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1990 For sale by the Books and Open-File Reports Section, U.S. Geological Survey Federal Center, Box 25425 Denver, CO 80225 Library of Congress Cataloging-in-Publication Data Page, Norman, J Petrology of the noritic and gabbronoritic rocks below the J-M Reef in the Mountain View area, Stillwater Complex, Montana / by Norman J Page and Barry C. Moring. p. cm. (U.S. Geological Survey bulletin ; 1674-C) (Contributions on ore deposits in the early magmatic environment Includes bibliographical references. Supt. of Docs, no.: I 19.3: 1674-C 1. Petrology Beartooth Mountains Region (Mont, and Wyo.) 2. Geolo­ gy Beartooth Mountains Region (Mont, and Wyo.) I. Moring, Barry C. II. Title. III. Title: Stillwater Complex, Montana. IV. Series. V. Series: Contri­ butions on ore deposits in the early magmatic environment ; ch.
    [Show full text]
  • Wang Et Al., 2001
    American Mineralogist, Volume 86, pages 790–806, 2001 Characterization and comparison of structural and compositional features of planetary quadrilateral pyroxenes by Raman spectroscopy ALIAN WANG,* BRAD L. JOLLIFF, LARRY A. HASKIN, KARLA E. KUEBLER, AND KAREN M. VISKUPIC Department of Earth and Planetary Sciences and McDonnell Center for the Space Sciences, Washington University, St. Louis, Missouri 63130, U.S.A. ABSTRACT This study reports the use of Raman spectral features to characterize the structural and composi- tional characteristics of different types of pyroxene from rocks as might be carried out using a por- table field spectrometer or by planetary on-surface exploration. Samples studied include lunar rocks, martian meteorites, and terrestrial rocks. The major structural types of quadrilateral pyroxene can be identified using their Raman spectral pattern and peak positions. Values of Mg/(Mg + Fe + Ca) of pyroxene in the (Mg, Fe, Ca) quadrilateral can be determined within an accuracy of ±0.1. The preci- sion for Ca/(Mg + Fe + Ca) values derived from Raman data is about the same, except that correc- tions must be made for very low-Ca and very high-Ca samples. Pyroxenes from basalts can be distinguished from those in plutonic equivalents from the distribution of their Mg′ [Mg/(Mg + Fe)] and Wo values, and this can be readily done using point-counting Raman measurements on unpre- pared rock samples. The correlation of Raman peak positions and spectral pattern provides criteria to distinguish pyroxenes with high proportions of non-quadrilateral components from (Mg, Fe, Ca) quadrilateral pyroxenes. INTRODUCTION pyroxene group of minerals is amenable to such identification Laser Raman spectroscopy is well suited for characteriza- and characterization.
    [Show full text]
  • Monographs of the USGS Vol. XXXVI – Part I – Page 127 of 133 PLATE XXXVI
    PLATE XXXIV. PLATE XXXV. FIG. A. FIG. A. (Sp. No. 23746. Without analyzer, x 17.) (Sp. No. 26059. Without analyzer, x 18.) Contact product of a granite. This muscovite-biotite-gneiss (?) Photomicrograph showing an eruptive contact between granite is the result of contact action of a granite upon a graywacke. and metamorphosed sedimentary rock. As a result of this Complete recrystallization of the sedimentary rock has taken contact the elements of the granite have become partly place, with the production of a porphyritic schistose structure. automorphic. The center of the figure is occupied by a quartz The large porphyritic muscovite plates seen as white areas in phenocryst which is partly surrounded by the schistose the photomicrograph evidently represent the last products of metamorphic product. It contains, near the edge, grains of recrystallization, as they include all of the minerals which have feldspar and flakes of mica, and thus an imperfect poikilitic been previously formed. They are possibly to be looked upon zone is produced. The mineral constituents of the as the product of mineralizers, to whose action may also be metamorphosed sedimentary are arranged parallel to the referred the presence of tourmaline, which occurs in the contours of the phenocrysts. (Described, p. 198.) section. The irregular white areas represent quartz and FIG. B. feldspar. Dark greenish-brown biotite is included in the muscovite, and with iron oxides occupies the areas which in (Sp. No. 26059. With analyzer, x 18.) the figure are dark. (Described, p. 197.) The same section as the above, viewed between crossed FIG. B. nicols. (Described, p.
    [Show full text]
  • Review Komatiites: from Earth's Geological Settings to Planetary
    Running Head: Komatiites: geological settings to astrobiological contexts Review Komatiites: From Earth’s Geological Settings to Planetary and Astrobiological Contexts Delphine Nna-Mvondo1 and Jesus Martinez-Frias1 1 Planetary Geology Laboratory, Centro de Astrobiologia (CSIC/INTA), associated to NASA Astrobiology Institute, Ctra. De Ajalvir, km 4. 28850 Torrejon de Ardoz, Madrid, Spain. Correspondence: Laboratorio de Geología Planetaria, Centro de Astrobiología (CSIC/INTA), associated to NASA Astrobiology Institute, Instituto Nacional de Técnica Aeroespacial, Ctra. De Ajalvir, km 4. 28850 Torrejón de Ardoz, Madrid, Spain. Phone: +34 915206434 Fax: +34 915201074 E-mail: [email protected] 1 ABSTRACT Komatiites are fascinating volcanic rocks. They are among the most ancient lavas of the Earth following the 3.8 Ga pillow basalts at Isua and they represent some of the oldest ultramafic magmatic rocks preserved in the Earth’s crust at 3.5 Ga. This fact, linked to their particular features (high magnesium content, high melting temperatures, low dynamic viscosities, etc.), has attracted the community of geoscientists since their discovery in the early sixties, who have tried to determine their origin and understand their meaning in the context of terrestrial mantle evolution. In addition, it has been proposed that komatiites are not restricted to our planet, but they could be found in other extraterrestrial settings in our Solar System (particularly on Mars and Io). It is important to note that komatiites may be extremely significant in the study of the origins and evolution of Life on Earth. They not only preserve essential geochemical clues of the interaction between the pristine Earth rocks and atmosphere, but also may have been potential suitable sites for biological processes to develop.
    [Show full text]
  • Petrology of the Ultramafic and Gabbroic Rocks of the Brady Glacier Nickel-Copper Deposit, Fairweather Range, Southeastern Alaska
    Petrology of the Ultramafic and Gabbroic Rocks of the Brady Glacier Nickel-Copper Deposit, Fairweather Range, Southeastern Alaska By GLEN R. HIMMELBERG and ROBERT A. LONEY GEOLOGICAL SURVEY PROFESSIONAL PAPER 1195 LJNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1981 UNITED STATES DEPARTMENT OF THE INTERIOR JAMES G. WATT, Secretary GEOLOGICAL SURVEY Doyle G. Frederick, Acting Director Library of Congress Cataloging in Publication Data Himmelberg, Glen R. Petrology of the ultramafic and gabbroic rocks of the Brady Glacier nickel-copper deposit, Fairweather Range, southeastern Alaska (Geological Survey Professional Paper 1195) Bibliography: p. 24 Supt. of Docs. no.: I 19.16:1195 I. Rocks, Ultrabasic. 2. Gabbro-Alaska-Fairweather Range. 3. Ore-deposits-Alaska-Fairweather Range. 4. Petrology- Alaska-Fairweather Range. 1. Loney, Robert Ahlberg, 1922- joint author. 11. Title. 111. Series: United States Geological Survey Professional Paper 1195. QE462.U4H55 552l.1 80-607095 For sale by the Superintendent of Documents, U.S. Government Printing Office Washington, D.C. 20402 CON' Page Page Abstract .................................................................................................. Chemistry of cumulus minerals . 10 Introduction .......................................................................................... Olivine 10 Acknowledgments ................................................................................ Pyroxene .......................................................................................... 12
    [Show full text]
  • Lithogeochemistry of Ultramafic, Gabbroic and Tonalitic
    Current Research (2015) Newfoundland and Labrador Department of Natural Resources Geological Survey, Report 15-1, pages 191-213 LITHOGEOCHEMISTRY OF ULTRAMAFIC, GABBROIC AND TONALITIC ROCKS FROM THE NORTHEASTERN ARCHEAN ASHUANIPI COMPLEX, WESTERN LABRADOR: IMPLICATIONS FOR PETROGENESIS AND MINERAL POTENTIAL T.S. van Nostrand Regional Geology Section ABSTRACT The Ashuanipi Complex is a granulite-facies, sedimentary–plutonic subprovince of the Archean Superior Province, and is one of the largest high-grade gneiss terranes in Canada. In Labrador, the complex consists of older sequences of migmatitic paragneiss intercalated with pretectonic orthopyroxene-bearing tonalite to diorite, and subordinate gabbroic and ultramafic intrusions. These rocks predate the development of extensive metasedimentary diatexite, variably deformed granitoid intru- sions and late granite pegmatite. Previous geochemical studies in the eastern Ashuanipi Complex indicate that the tonalite to diorite intrusions have tonalite–trondhjemite–granodiorite (TTG) or adakite-like affinities. The similar field associations, presence of relict igneous textures and anhydrous assemblages of the pretectonic granitoid and ultramafic rocks suggest there may be a genetic(?) relationship between these units. Preliminary lithogeochemistry for gabbroic and ultramafic rocks do not indicate a direct petrogenetic link. However, some similarities in trace- and rare-earth element abundances and behaviour suggest derivation from similar, silicate melt- and fluid-metasomatised mantle sources that yielded both felsic and mafic to ultramafic suites. This source metasomatic event may be related to subduction processes, however, the extent of crustal recy- cling in these rocks requires further isotopic investigations. The presence of anomalous base metals, including Ni, Cr, Ti and local Au and PGE in some gossan zones locally developed in tonalite and ultramafic sills, and coincident elevated lake-sed- iment concentrations, indicate a potential for similar mineralizing systems.
    [Show full text]
  • Stable and Metastable Pyroxene Crystallization in Tayered Komatiite Lava Flows
    American Mineralogist, Yolume64, pages E56-864, 1979 Stable and metastable pyroxene crystallization in tayered komatiite lava flows Nrcnorns T. ARNDT Deportmentof Geological Sciences,University of Saskatchewan Saskatoon,Saskatchewan S7N 0W0 eNo Mrcnenl- E. FLEET Department of Geology, University of WesternOntario London, Ontario N6A 3K7 Abstract Pyroxenesin the rapidly-cooled upper portions of thich layered komatiite lava flows have significantly different compositions and structures from pyroxencs in the cumuliatelower por- tions of the same flows. Rocks in the flow tops contain composite pyroxene mcgacrystsmade up of needleswith coresof pigeonite and margins of subcalcic, aluminous augite. The pigeon- ite is more magnesian [Mgl(Mg + Fe) = 0.841than any previously reported in terrestrial rocks. In the cumulate zon€s,the pyroxenesare bronzite and augite. The pigeonite probably formed under conditions of strong undercooling developed during the solidifcation of the upper parts of the flows, whereasthe cumulus pyrox€nes formed un- der conditions approaching equilibrium in the more slowly-cooled ccntral parts of the flows. Introduction nald Township about 70 km west of Munro. It has In thick, layered komatiite lava flows, the composi- been discussedvery briefly by Arndt (1977x). tions and the types of pyroxenes in flow top zones Fred's Flow can be divided into four units: a brec- difer considerably from those in lower cumulate liay- ciated or spinifex-textured uppermost unit; a gab- ers of the same flows. Magnesian pigeonite and sub- broic unit; a cumulate unit; and a basal, olivine-de- calcic augite are present in the flow top zones, pleted marginal unit (Fig. la). The flowtop breccia is whereasbronzite coexistswith augite in the cumulate made up of fragments of porphyritic lava containing Layers.
    [Show full text]
  • INTRUSIVE IGNEOUS ROCKS, PART 3 (And Friends)
    GLY 4310C LAB 8 INTRUSIVE IGNEOUS ROCKS, PART 3 (and friends) Syenite, Phonolite, Ijolite, Carbonatite, Ultramafic Rocks and Lamprophyre These intrusive rocks correspond to fields 6, 6', 7, 7', 11, and 15 of figure 3-1 in Hyndman. The syenites are on the border between the QAP and the APF triangles. The remaining rocks are in the APF triangle. Phonolite is actually an extrusive or hypabyssal equivalent of nepheline syenite. The ultrmafic rocks and lamprophyre are very rich in mafic minerals. Consequently they cannot be plotted on the main part of the QAPF diagram, although technically they plot in field 16 (Figure 3-1, Hyndman) in a separate rectangle. More information on these rocks is available in Chapters 9, 14, 15, 16, and 17 in Moorhouse. SYENITE - Intrusive igneous, plutonic. The major mineral is feldspar, with greater than 65% alkali feldspar (K-spar or albite). The ferromagnesian minerals are usually # 20%. The K-spar is typically orthoclase, microcline or perthite. In dikes sanidine may be present. Any plagioclase present is generally subhedral and is often zoned (normal or oscillatory). Biotite is often present and is usually brown. Small amounts of feldspathoids, like nepheline and sodalite, may be present. If more than 5% of these minerals are present, the rock is called nepheline (or sodalite) syenite. Sphene, apatite, ilmenite, magnetite, zircon, and monzonite are accessories. In the IUGS classification, 0-5 Q, and P/(A+P) is 10-35. The name is for Syene (near Aswan), Egypt. Pliny the Elder named granite-like rocks from this area for the locality. ALKALI SYENITE - Intrusive igneous, plutonic.
    [Show full text]
  • The Stillwater Complex Chromitites: the Response of Chromite Crystal Chemistry to Magma Injection
    Geologica Acta, Vol.10, Nº 1, March 2012, 33-41 DOI: 10.1344/105.000001706 Available online at www.geologica-acta.com The Stillwater Complex chromitites: The response of chromite crystal chemistry to magma injection 1 2 2 3 1 D. LENAZ G. GARUTI F. ZACCARINI R.W. COOPER F. PRINCIVALLE 1 Department of Mathematics and Geosciences Via Weiss 8, 34127 Trieste, Italy. Lenaz E-mail: [email protected] 2 Department of Applied Geosciences and Geophysics Peter Tunner Strasse 5, 8700 Leoben, Austria 3 Department of Geology Lamar University, 77710 Beaumont TX, USA ABS TRACT Nineteen chromite crystals from the A, B, E, G, H, J and K chromitite layers of the Peridotite Zone of the Stillwater Complex (Montana, USA) have been studied by means of X-ray single crystal diffraction and microprobe analyses. The results show that samples from the basal A layer are quite different from the others showing very high oxygen positional parameter u (0.2633-0.2635) and Ti- contents (0.059-0.067apfu). Mg# values are within the range 0.21-0.23 while for the other chromites it is in the range 0.45-0.47. Moreover, for the other samples, according to the structural parameters, two groups have been identified. The first one comprises samples of layers B, E and G, the second includes H, J and K layer samples. It is supposed that high Fe2+ and Ti contents of A layer samples are due to the post-crystallization reaction with interstitial liquid. This fact allowed a very slow cooling rate as evidenced by the high u values.
    [Show full text]