The Bushveld Igneous Complex
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Beneficiation of Stillwater Complex Rock for the Production of Lunar Simulants
National Aeronautics and NASA/TM—2014–217502 Space Administration IS20 George C. Marshall Space Flight Center Huntsville, Alabama 35812 Beneficiation of Stillwater Complex Rock for the Production of Lunar Simulants D.L. Rickman Marshall Space Flight Center, Huntsville, Alabama C. Young Metallurgical and Materials Engineering, Montana Tech, Butte, Montana D. Stoeser USGS, Denver, Colorado J. Edmunson Jacobs ESSSA Group, Huntsville, Alabama March 2014 The NASA STI Program…in Profile Since its founding, NASA has been dedicated to the • CONFERENCE PUBLICATION. Collected advancement of aeronautics and space science. The papers from scientific and technical conferences, NASA Scientific and Technical Information (STI) symposia, seminars, or other meetings sponsored Program Office plays a key part in helping NASA or cosponsored by NASA. maintain this important role. • SPECIAL PUBLICATION. Scientific, technical, The NASA STI Program Office is operated by or historical information from NASA programs, Langley Research Center, the lead center for projects, and mission, often concerned with NASA’s scientific and technical information. The subjects having substantial public interest. NASA STI Program Office provides access to the NASA STI Database, the largest collection of • TECHNICAL TRANSLATION. aeronautical and space science STI in the world. English-language translations of foreign The Program Office is also NASA’s institutional scientific and technical material pertinent to mechanism for disseminating the results of its NASA’s mission. research and development activities. These results are published by NASA in the NASA STI Report Specialized services that complement the STI Series, which includes the following report types: Program Office’s diverse offerings include creating custom thesauri, building customized databases, • TECHNICAL PUBLICATION. -
Mineral Profile
Platinum September 2009 Definition, mineralogy and Pt Pd Rh Ir Ru Os Au nt Atomic 195.08 106.42 102.91 192.22 101.07 190.23 196.97 deposits weight opme vel Atomic Definition and characteristics 78 46 45 77 44 76 79 de number l Platinum (Pt) is one of a group of six chemical elements ra UK collectively referred to as the platinum-group elements Density ne 21.45 12.02 12.41 22.65 12.45 22.61 19.3 (gcm-3) mi (PGE). The other PGE are palladium (Pd), iridium (Ir), osmium e Melting bl (Os), rhodium (Rh) and ruthenium (Ru). Reference is also 1769 1554 1960 2443 2310 3050 1064 na point (ºC) ai commonly made to platinum-group metals and to platinum- Electrical st group minerals, both often abbreviated to PGM. In this su resistivity r document we use PGM to refer to platinum-group minerals. 9.85 9.93 4.33 4.71 6.8 8.12 2.15 f o (micro-ohm re cm at 0º C) nt Chemically the PGE are all very similar, but their physical Hardness Ce Minerals 4-4.5 4.75 5.5 6.5 6.5 7 2.5-3 properties vary considerably (Table 1). Platinum, iridium (Mohs) and osmium are the densest known metals, being significantly denser than gold. Platinum and palladium are Table 1 Selected properties of the six platinum-group highly resistant to heat and to corrosion, and are soft and elements (PGE) compared with gold (Au). ductile. Rhodium and iridium are more difficult to work, while ruthenium and osmium are hard, brittle and almost pentlandite, or in PGE-bearing accessory minerals (PGM). -
Timeline of Natural History
Timeline of natural history This timeline of natural history summarizes significant geological and Life timeline Ice Ages biological events from the formation of the 0 — Primates Quater nary Flowers ←Earliest apes Earth to the arrival of modern humans. P Birds h Mammals – Plants Dinosaurs Times are listed in millions of years, or Karo o a n ← Andean Tetrapoda megaanni (Ma). -50 0 — e Arthropods Molluscs r ←Cambrian explosion o ← Cryoge nian Ediacara biota – z ←Earliest animals o ←Earliest plants i Multicellular -1000 — c Contents life ←Sexual reproduction Dating of the Geologic record – P r The earliest Solar System -1500 — o t Precambrian Supereon – e r Eukaryotes Hadean Eon o -2000 — z o Archean Eon i Huron ian – c Eoarchean Era ←Oxygen crisis Paleoarchean Era -2500 — ←Atmospheric oxygen Mesoarchean Era – Photosynthesis Neoarchean Era Pong ola Proterozoic Eon -3000 — A r Paleoproterozoic Era c – h Siderian Period e a Rhyacian Period -3500 — n ←Earliest oxygen Orosirian Period Single-celled – life Statherian Period -4000 — ←Earliest life Mesoproterozoic Era H Calymmian Period a water – d e Ectasian Period a ←Earliest water Stenian Period -4500 — n ←Earth (−4540) (million years ago) Clickable Neoproterozoic Era ( Tonian Period Cryogenian Period Ediacaran Period Phanerozoic Eon Paleozoic Era Cambrian Period Ordovician Period Silurian Period Devonian Period Carboniferous Period Permian Period Mesozoic Era Triassic Period Jurassic Period Cretaceous Period Cenozoic Era Paleogene Period Neogene Period Quaternary Period Etymology of period names References See also External links Dating of the Geologic record The Geologic record is the strata (layers) of rock in the planet's crust and the science of geology is much concerned with the age and origin of all rocks to determine the history and formation of Earth and to understand the forces that have acted upon it. -
Predictability of Pothole Characteristics and Their Spatial Distribution At
79_Chitiyo:Template Journal 12/15/08 11:16 AM Page 733 Predictability of pothole characteristics J o and their spatial distribution at u Rustenburg Platinum Mine r n by G. Chitiyo*, J. Schweitzer*, S. de Waal*, P. Lambert*, and a P. Olgilvie* l P a p Synopsis thermo-chemical erosion of the cumulus floor by new influxes of superheated magma best explains the observed data. e Prediction of pothole characteristics is a challenging task, Partial to complete melting of the cumulate floor occurred in r confronting production geologists at the platinum mines of three phases. The first represents the emplacement of hot the Bushveld Complex. The frequency, distribution, size, magma. This magma, due to turbulent flow and high chemical shape, severity and relationship (FDS3R) of potholes has a and physical potential, aggressively attacks the existing floor huge impact on mine planning and scheduling, and (crystal mush on the magma/floor interface). Regional consequently cost. It is with this in mind that this study was erosion is manifested by large, often coalescing potholes. initiated. During the second phase, when the magma emplacement Quantitative analysis of potholes indicates that pothole process ceased and cooling in situ started, two distinct size (area covered) can be described by two partly periods of pothole formation ensued. The first is related to overlapping lognormal distributions. These are referred to as rapid cooling along the relatively steep part of the Newton Populations A (smaller) and B (larger). The range of Cooling Curve, when Population B potholes nucleated observed pothole sizes conforms to a simple double randomly and grew rapidly with concurrent convective exponential growth model based on Newton’s Cooling Curve. -
STRATIFORM and ALLUVIAL Plafl NUM MINERALIZATION in THE
LU3 The Canadian M iner alog is t Vol. 33,pp. 1023-lM5(1995) STRATIFORMAND ALLUVIALPLAfl NUM MINERALIZATION IN THENEW CALEDONIA OPHIOLITE COMPLEX THIERRY AUGE lNI PIERREMATIRZOT BRGM'Metallogeny and Geotynarnics", B.P. 6009, 45060 Orldans Cedex 2, France ABSTRA T An unusualtype offt mineralizationhas beenfound in the New Caledoniaophiolite complex, associatedwitl stratiform chromite-bearingrocks at the baseof the cumulateseries (close to the transition zone betweendunite and pyroxene-bearing rocks) and with cbromite-richpyroxenite dykes from the samezone. Two placer deposis, both enrichedin Fl also have been recognized one derived from the chromite-rich horizons and the other a cbromitiferous beach sand of unknown origin. Chromite-bearingrocks aremarked by a very strongenrichment in Pt relative to fhe other platinum-groupelements (PGE), $'ith a rrardmunconcentration of 11.5ppm (average3.9 ppm). The Pt enrichmenttakes the form of platinum-groupminerals (PGM) included in chromite crystals and is interpretedas being pdlrar'/. The following minerals have been identified: ft-Fe{u alloys (isoferroplatinum,tulame€nite, tetraferroplatinum and undeterminedphases), cooperite, laurite, bowieite, malanite, cuprorhodsite,unnamed PGE oxides, and base-metalsulfides with PGE in solid solution. The associatedplacers show a slightly different mineral association,with isoferroplatinum,tulameenite, and rare cooperite,sperrylite, Os-k-Ru alloys and PGE oxides. A more complex paragenesishas been identified in the beach san4 with isoferroplatinum,cooperite, laurite, erlichmanite, Os-Ir-Ru alloys, bowieite, ba$ite, hollingworthire, sperrylite, stibiopalladinite, and unnamed Rh sulfide, Pt-Ru-Rh alloy and PGE oxides. This type of mineralization, which differs markedly from the Os-Ru-h mineralization previously recognized in podiform cbromitite in New Caledonia, shows several analogies with Alaskan-type PGE mineralization.The host chromitite,with typical cumulustextwes, is markedby Ti and Feh emichmentdue to derivationfrom an evolved liquid. -
Exkursionen Excursions
EXKURSIONEN EXCURSIONS 174 MITT.ÖSTERR.MINER.GES. 161 (2015) A GEOLOGICAL EXCURSION TO THE MINING AREAS OF SOUTH AFRICA by Aberra Mogessie, Christoph Hauzenberger, Sara Raic, Philip Schantl, Lukas Belohlavek, Antonio Ciriello, Donia Daghighi, Bernhard Fercher, Katja Goetschl, Hugo Graber, Magdalena Mandl, Veronika Preissegger, Gerald Raab, Felix Rauschenbusch, Theresa Sattler, Simon Schorn, Katica Simic, Michael Wedenig & Sebastian Wiesmair Institute of Earth Sciences, University of Graz, Universitaetsplatz 2, A-8010 Graz Frank Melcher, Walter Prochaska, Heinrich Mali, Heinz Binder, Marco Dietmayer-Kräutler, Franz Christian Friedman, Maximilian Mathias Haas, Ferdinand Jakob Hampl, Gustav Erwin Hanke, Wolfgang Hasenburger, Heidi Maria Kaltenböck, Peter Onuk, Andrea Roswitha Pamsl, Karin Pongratz, Thomas Schifko, Sebastian Emanuel Schilli, Sonja Schwabl, Cornelia Tauchner, Daniela Wallner & Juliane Hentschke Chair of Geology and Economic Geology, Mining University of Leoben, Peter-Tunner-Strasse 5, A-8700 Leoben Christoph Gauert Department of Geology, University of the Free State, South Africa 1. Preface Almost a year ago Aberra Mogessie planned to organize a field excursion for the students of the Institute of Earth Sciences, University of Graz. The choices were Argentina, Ethiopia (where we had organized past excursions) and South Africa. Having discussed the matter with Christoph Hauzenberger concerning geology, logistics etc. we decided to organize a field excursion to the geologically interesting mining areas of South Africa. We contacted Christoph Gauert from the University of Free State, South Africa to help us with the local organization especially to get permission from the different mining companies to visit their mining sites. We had a chance to discuss with him personally during his visit to our institute at the University of Graz in May 2014 and make the first plan. -
ECONOMIC GEOLOGY RESEARCH INSTITUTE HUGH ALLSOPP LABORATORY University of the Witwatersrand Johannesburg
ECONOMIC GEOLOGY RESEARCH INSTITUTE HUGH ALLSOPP LABORATORY University of the Witwatersrand Johannesburg CHROMITITES OF THE BUSHVELD COMPLEX- PROCESS OF FORMATION AND PGE ENRICHMENT J.A. KINNAIRD, F.J. KRUGER, P.A.M. NEX and R.G. CAWTHORN INFORMATION CIRCULAR No. 369 UNIVERSITY OF THE WITWATERSRAND JOHANNESBURG CHROMITITES OF THE BUSHVELD COMPLEX – PROCESSES OF FORMATION AND PGE ENRICHMENT by J. A. KINNAIRD, F. J. KRUGER, P.A. M. NEX AND R.G. CAWTHORN (Department of Geology, School of Geosciences, University of the Witwatersrand, Private Bag 3, P.O. WITS 2050, Johannesburg, South Africa) ECONOMIC GEOLOGY RESEARCH INSTITUTE INFORMATION CIRCULAR No. 369 December, 2002 CHROMITITES OF THE BUSHVELD COMPLEX – PROCESSES OF FORMATION AND PGE ENRICHMENT ABSTRACT The mafic layered suite of the 2.05 Ga old Bushveld Complex hosts a number of substantial PGE-bearing chromitite layers, including the UG2, within the Critical Zone, together with thin chromitite stringers of the platinum-bearing Merensky Reef. Until 1982, only the Merensky Reef was mined for platinum although it has long been known that chromitites also host platinum group minerals. Three groups of chromitites occur: a Lower Group of up to seven major layers hosted in feldspathic pyroxenite; a Middle Group with four layers hosted by feldspathic pyroxenite or norite; and an Upper Group usually of two chromitite packages, hosted in pyroxenite, norite or anorthosite. There is a systematic chemical variation from bottom to top chromitite layers, in terms of Cr : Fe ratios and the abundance and proportion of PGE’s. Although all the chromitites are enriched in PGE’s relative to the host rocks, the Upper Group 2 layer (UG2) shows the highest concentration. -
Noritic Anorthosite Bodies in the Sierra Nevada Batholith
MINERALOGICAL SOCIETY OF AMERICA, SPECIAL PAPER 1, 1963 INTERNATIONALMINERALOGICAL ASSOCIATION,PAPERS, THIRD GENERAL MEETING NORITIC ANORTHOSITE BODIES IN THE SIERRA NEVADA BATHOLITH ALDEN A. LOOMISl Department of Geology, Stanford University, Stanford, California ABSTRACT A group of small noritic plutons were intruded prior to the immediately surrounding granitic rocks in a part of the composite Sierra Nevada batholith near Lake Tahoe. Iron was more strongly concentrated in the late fluids of individual bodies than during the intrusive sequence as a whole. Pyroxenes are more ferrous in rocks late in the sequence, although most of the iron is in late magnetite which replaces pyroxenes. Both Willow Lake type and normal cumulative layering are present. Cumulative layering is rare; Willi ow Lake layering is common and was formed early in individual bodies. Willow Lake layers require a compositional uniqueness providing high ionic mobility to explain observed relations. The Sierran norites differ from those in large stratiform plutons in that (1) the average bulk composition is neritic anorthosite in which typical rocks contain over 20% AbO" and (2) differentiation of both orthopyroxene and plagioclase produced a smooth progressive sequence of mineral compositions. A plot of modal An vs. En for all the rocks in the sequence from early Willow Lake-type layers to late no rite dikes defines a smooth non-linear trend from Anss-En76 to An,,-En54. TLe ratio An/ Ab decreased faster than En/Of until the assemblage Anso-En65 was reached and En/Of began to decrease more rapidly. Similar plots for large stratiform bodies show too much scatter to define single curves. -
Footprint of a Late Carboniferous Ice Sheet D.P
https://doi.org/10.1130/G46590.1 Manuscript received 3 June 2019 Revised manuscript received 31 July 2019 Manuscript accepted 7 August 2019 © 2019 The Authors. Gold Open Access: This paper is published under the terms of the CC-BY license. Published online 23 September 2019 Scratching the surface: Footprint of a late Carboniferous ice sheet D.P. Le Heron1, P. Dietrich2,3, M.E. Busfield4, C. Kettler1, S. Bermanschläger1 and B. Grasemann1 1 Department für Geodynamik und Sedimentologie, Althanstraße 14, Universität Wien, 1190 Vienna, Austria 2 Department of Geology, University of Johannesburg, Auckland Park Kingsway Campus, Johannesburg 2092, South Africa 3 Géosciences Rennes, UMR6118, Université de Rennes 1, 263 Avenue du Général Leclerc, Bâtiment 15, Campus de Beaulieu, 35042 Rennes Cedex, France 4 Department of Geography and Earth Sciences, Aberystwyth University, Llandinam Building, Aberystwyth SY23 3DB, UK ABSTRACT records deglaciation punctuated by short-term Field observations in conjunction with aerial images from an unmanned aerial vehicle stillstands and minor readvances (Dietrich and were used to create the first map of a glacial unconformity underlying the late Carboniferous Hofmann, 2019). Such basin-margin locali- Dwyka Group of South Africa. Crosscutting relationships reveal that the glacial unconformity ties record glacially striated pavements of two at Oorlogskloof, in which flutes, grooves, and striae were ploughed into unconsolidated sand, types: (1) hard-bedrock pavements, recording formed in a three-phased process charting a periodic shift in the locus of subglacial erosion. the direct abrasion of LPIA ice sheets onto The unconformity formed by a periodically decoupled ice sheet in a probable tidewater set- hard bedrock material (Du Toit, 1954; Visser ting. -
Geochemistry of the Mafic and Felsic Norite: Implications for the Crystallization History of the Sudbury Igneous Complex, Sudbury Ontario
Geochemistry of the Mafic and Felsic Norite: Implications for the Crystallization History of the Sudbury Igneous Complex, Sudbury Ontario G. R. Dessureau Mineral Exploration Research Centre, Department of Earth Sciences, Laurentian University, Sudbury, ON, P3E 6B5 e-mail: [email protected] Introduction Whistle Embayment Geology The 1.85 Ga Sudbury Igneous Complex The Whistle Embayment occurs along the (SIC) is a 60 x 30 km layered igneous body NE margin of the basin under the Main Mass of the occupying the floor of a crater in northern Ontario. SIC and extends into the footwall as an Offset dyke The SIC comprises, from base to top: a (Whistle/Parkin Offset). Pattison (1979) and discontinuous unit of sulfide-rich, inclusion-bearing Lightfoot et al. (1997) provide detailed descriptions norite (Contact Sublayer), mafic norite, felsic of the embayment environment at Whistle. The norite, gabbro transition zones, and granophyre embayment contains up to ~300m of inclusion-rich, (Main Mass). Concentric and radial Quartz Diorite sulfide-bearing Sublayer in a well-zoned funnel Offset Dykes extend into the footwall rocks. extending away from the base of the SIC. Poikilitic, The distributions of the Sublayer and hypersthene-rich Mafic Norite occurs in and along associated Ni-Cu-PGE ores are controlled by the the flanks of the embayment as discontinuous morphology of the footwall: the Sublayer and lenses between the Sublayer and the Felsic Norite. contact ores are thickest within km-sized radial The Felsic Norite in the Whistle area ranges from depressions in the footwall referred to as ~450m thick adjacent to the embayment to >600m embayments (e.g., Whistle Embayment) and thick directly over the embayment. -
An Hypothesis for the Origin of Kimberlite 51
Mineral. Soc. Amer. Spec. Pap. 3,51-62 (1970). AN HYPOTHESIS FOR THE ORIGIN OF KIMBERLITE IAN D. MACGREGOR Department of Geology, University of California, Davis, California 95616 ABSTRACT Kimberlites are characteristically associated with a suite of mafic and ultramafic xenoliths whose mineralogy indicates an origin within the upper mantle. The phase chemistry of the xenoliths may be reconciled with known experimental data at high pressures, as suites of crystal cumulates, or residual phases, that have formed during the high-pressure fractional crystallization of a mafic magma. The geological association of kimberlites with specificsuites of xenoliths, and the com- parison with experimental data, give support to this cognate hypothesis previously proposed by a number of other authors. Models of the Earth's thermal history indicate that the upper mantle heated up for the first few billions of years after which time it has slowly cooled to its present state. It is postulated that the kimberlites are formed by the closed system fractional crystallization of mafic magmas which have formed by fractional fusion during the early heating of the upper mantle. During the cooling cycle in the last few billions of years, the mafic liquids have cooled through fractional crystal- lization to the ambient mantle temperatures, and changed composition towards a kimberlite. Sequential primary phase assemblages are represented by harzburgite, garnet harzburgite, garnet lherzolite, hypersthene eclogite, eclogite, kyanite eclogite to an olivine-diopside-perovskite rock. Parallel changes in the liquid composition are through picrite, tholeiite, alkali basalt, a diopside-ilmenite composition to kimberlite. INTRODUCTION logical and geophysical characteristics common to the gen- Although kimberlites occupy only a very small propor- eral description included in the following section. -
The Centenary of the Discovery of Platinum in the Bushveld Complex (10Th November, 1906)
CAWTHORN, R.G. The centenary of the discovery of platinum in the Bushveld Complex (10th November, 1906). International Platinum Conference ‘Platinum Surges Ahead’, The Southern African Institute of Mining and Metallurgy, 2006. The centenary of the discovery of platinum in the Bushveld Complex (10th November, 1906) R.G. CAWTHORN School of Geosciences, University of the Witwatersrand, South Africa The earliest authenticated scientific report of the occurrence of platinum in rocks from the Bushveld Complex appears to be by William Bettel on 10th November 1906. Thereafter, prospecting of the chromite-rich rocks for platinum proved frustrating. I suggest that the resurgence of interest shown by Dr Hans Merensky in 1924 resulted from his realization that newly-panned platinum had a different grain size from that in the chromite layers and indicated a different source rock, which he located and it became known as the Merensky Reef. Merensky’s discoveries in Johannesburg). He found it contained ‘silver, gold, The story of Dr. Hans Merensky’s discoveries of the platinum and iridium (with osmium)’. Hence, the presence platinum-rich pipes and the Merensky Reef itself in 1924 of the platinum-group elements (PGE) in South Africa in have been well documented (Cawthorn, 1999; Scoon and minor amounts was well-established by the end of the Mitchell, 2004, and references therein), but the events that nineteenth century. preceded it have not been summarized. In the probable centenary year of the first report of platinum in the In situ platinum Bushveld it is appropriate to review the events between In his article Bettel reported that he had ‘recently’ (i.e.