Rock Magnetism and the Interpretation of Anisotropy
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CERI 7022/8022 Global Geophysics Spring 2016
FerrimagnetismI I Recall three types of magnetic properties of materials I Diamagnetism I Paramagnetism I Ferromagnetism I Anti-ferromagnetism I Parasitic ferromagnetism I Ferrimagnetism I Ferrimagnetism I Spinel structure is one of the common crystal structure of rock-forming minerals. I Tetrahedral and octahedral sites form two sublattices. 2+ 3+ I Fe in 1/8 of tetrahedral sites, Fe in 1/2 of octahedral sites. FerrimagnetismII I xmujpkc.xmu.edu.cn/jghx/source/chapter9.pdf Ferrimagnetism III I www.tf.uni-kiel.de/matwis/amat/def_en/kap_2/basics/b2_1_6.html I Anti-spinel structure of the most common iron oxides 3+ 3+ 2+ I Fe in 1/8 tetrahedral sites, (Fe , Fe ) in 1/2 of octahedral sites. FerrimagnetismIV I Indirect exchange involves antiparallel and unequal magnetization of the sublattices, a net spontaneous magnetization appears. This phenomenon is called ferrimagnetism. I Ferrimagnetic materials are called ferrites. I Ferrites exhibit magnetic hysteresis and retain remanent magnetization (i.e. behaves like ferromagnets.) I Above the Curie temperature, becomes paramagnetic. I Magnetite (Fe3O4), maghemite, pyrrhotite and goethite (' rust). Magnetic properties of rocksI I Matrix minerals are mainly silicates or carbonates, which are diamagnetic. I Secondary minerals (e.g., clays) have paramagnetic properties. I So, the bulk of constituent minerals have a magnetic susceptibility but not remanent magnetic properties. I Variable concentrations of ferrimagnetic and matrix minerals result in a wide range of susceptibilities in rocks. Magnetic properties of rocksII I I The weak and variable concentration of ferrimagnetic minerals plays a key role in determining the magnetic properties of the rock. Magnetic properties of rocks III I Important factors influencing rock magnetism: I The type of ferrimagnetic mineral. -
Magnetism, Magnetic Properties, Magnetochemistry
Magnetism, Magnetic Properties, Magnetochemistry 1 Magnetism All matter is electronic Positive/negative charges - bound by Coulombic forces Result of electric field E between charges, electric dipole Electric and magnetic fields = the electromagnetic interaction (Oersted, Maxwell) Electric field = electric +/ charges, electric dipole Magnetic field ??No source?? No magnetic charges, N-S No magnetic monopole Magnetic field = motion of electric charges (electric current, atomic motions) Magnetic dipole – magnetic moment = i A [A m2] 2 Electromagnetic Fields 3 Magnetism Magnetic field = motion of electric charges • Macro - electric current • Micro - spin + orbital momentum Ampère 1822 Poisson model Magnetic dipole – magnetic (dipole) moment [A m2] i A 4 Ampere model Magnetism Microscopic explanation of source of magnetism = Fundamental quantum magnets Unpaired electrons = spins (Bohr 1913) Atomic building blocks (protons, neutrons and electrons = fermions) possess an intrinsic magnetic moment Relativistic quantum theory (P. Dirac 1928) SPIN (quantum property ~ rotation of charged particles) Spin (½ for all fermions) gives rise to a magnetic moment 5 Atomic Motions of Electric Charges The origins for the magnetic moment of a free atom Motions of Electric Charges: 1) The spins of the electrons S. Unpaired spins give a paramagnetic contribution. Paired spins give a diamagnetic contribution. 2) The orbital angular momentum L of the electrons about the nucleus, degenerate orbitals, paramagnetic contribution. The change in the orbital moment -
Rock and Paleomagnetic Investigations Technical Detailed
NWM-USGS-GPP-06 RO Rock and Paleomagnetic Investigations Technical Detailed Procedure GPP-O NNWSI Project Quality Assurance Program U.S. Geological Survey Effective Date: pepared by: Joseph Rosenbaum Technical Reviewer: Richard Reynolds 'Branch Chief: Adel Zohdy NNWI Project Coordinator: W. Dudley Quality Assurance: P. L. Bussolini 8502210165 841130 PDR WASTE PDR Wm-II NWM-USGS-GPP- 06, RO NWM-USGS-GPP- o RO Page 2 of 13 Rock and Paleomagnetic Investigations 1.0 PURPOSE 1.1 This procedure provides a means of assuring the accuracy, validity, and applicability of the methods used to determine paleomagnetic and rock magnetic properties. 1.2 The procedure documents the USGS responsibilities for quality assurance training and enforcement, the processes and authority for procedure modification and revision, the requirements for procedure and personnel interfacing, and to whom the procedure applies. 1.3 The procedure describes the system components, the principles of the methods used, and the limits of their use. 1.4 The procedure describes the detailed methods to be used, where applicable, for system checkout and maintenance, calibration, operation and performance verification. 1.5 The procedure defines the requirements for data acceptance, documentation and control; and provides a means of data traceability. 1.6 The procedure provides a guide for USGS personnel and their contractors engaged to determining paleomagnetic and rock mag- netic properties and a means by which the Department of Energy (DOE) and the Nuclear Regulatory Commission (NRC) can evaluate these activities in meeting requirements for the NNWSI repository. 2.0 SCOPE OF COMPLIANCE 2.1 This procedure applies to all USGS personnel, and persons assigned by the USGS, who perform work on the procedure as described by the work activity given in Section 1.1, or use data from such activities, if the activities or data are deemed by the USGS Project Coordinator to potentially affect public health and safety as related to a nuclear waste repository. -
Magnetic Force Microscopy of Superparamagnetic Nanoparticles
Magnetic Force Microscopy of Superparamagnetic Nanoparticles for Biomedical Applications Dissertation Presented in Partial Fulfillment of the Requirements for the Degree Doctor of Philosophy in the Graduate School of The Ohio State University By Tanya M. Nocera, M.S. Graduate Program in Biomedical Engineering The Ohio State University 2013 Dissertation Committee: Gunjan Agarwal, PhD, Advisor Stephen Lee, PhD Jessica Winter, PhD Anil Pradhan, PhD Copyright by Tanya M. Nocera 2013 Abstract In recent years, both synthetic as well as naturally occurring superparamagnetic nanoparticles (SPNs) have become increasingly important in biomedicine. For instance, iron deposits in many pathological tissues are known to contain an accumulation of the superparamagnetic protein, ferritin. Additionally, man-made SPNs have found biomedical applications ranging from cell-tagging in vitro to contrast agents for in vivo diagnostic imaging. Despite the widespread use and occurrence of SPNs, detection and characterization of their magnetic properties, especially at the single-particle level and/or in biological samples, remains a challenge. Magnetic signals arising from SPNs can be complicated by factors such as spatial distribution, magnetic anisotropy, particle aggregation and magnetic dipolar interaction, thereby confounding their analysis. Techniques that can detect SPNs at the single particle level are therefore highly desirable. The goal of this thesis was to develop an analytical microscopy technique, namely magnetic force microscopy (MFM), to detect and spatially localize synthetic and natural SPNs for biomedical applications. We aimed to (1) increase ii MFM sensitivity to detect SPNs at the single-particle level and (2) quantify and spatially localize iron-ligated proteins (ferritin) in vitro and in biological samples using MFM. -
Two-Dimensional Field-Sensing Map and Magnetic Anisotropy Dispersion
PHYSICAL REVIEW B 83, 144416 (2011) Two-dimensional field-sensing map and magnetic anisotropy dispersion in magnetic tunnel junction arrays Wenzhe Zhang* and Gang Xiao† Department of Physics, Brown University, Providence, Rhode Island 02912, USA Matthew J. Carter Micro Magnetics, Inc., 617 Airport Road, Fall River, Massachusetts 02720, USA (Received 22 July 2010; revised manuscript received 24 January 2011; published 22 April 2011) Due to the inherent disorder in local structures, anisotropy dispersion exists in almost all systems that consist of multiple magnetic tunnel junctions (MTJs). Aided by micromagnetic simulations based on the Stoner-Wohlfarth (S-W) model, we used a two-dimensional field-sensing map to study the effect of anisotropy dispersion in MTJ arrays. First, we recorded the field sensitivity value of an MTJ array as a function of the easy- and hard-axis bias fields, and then extracted the anisotropy dispersion in the array by comparing the experimental sensitivity map to the simulated map. Through a mean-square-error-based image processing technique, we found the best match for our experimental data, and assigned a pair of dispersion numbers (anisotropy angle and anisotropy constant) to the array. By varying each of the parameters one at a time, we were able to discover the dependence of field sensitivity on magnetoresistance ratio, coercivity, and magnetic anisotropy dispersion. The effects from possible edge domains are also discussed to account for a correction term in our analysis of anisotropy angle distribution using the S-W model. We believe this model is a useful tool for monitoring the formation and evolution of anisotropy dispersion in MTJ systems, and can facilitate better design of MTJ-based devices. -
Design of a Curie Point Meter
BULLETIN 69 DESIGN OF A CURIE POINT METER A. Larochelle Price, 50 cents 1961 DESIGN OF A CURIE POINT METER 3,000-1960-1818 91594-2-1 11 026: General view of Curie point meter GEOLOGICAL SURVEY OF CANADA BULLETIN 69 DESIGN OF A CURIE POINT METER By A. Larochelle DEPARTMENT OF MINES AND TECHNICAL SURVEYS CANADA 91594-2-2 ROGER DUHAMEL. F.R.S.C. QUEEN'S PRINTER AND CONTROLLER OF STATIONERY OTTAWA, 1961 Price 50 cents Cat. No. M42-69 Preface Magnetic properties are rarely used to identify minerals because they are generally difficult to detect or to determine accurately. Ferromagnetic minerals are, however, an exception. Not only can a family of ferromagnetic minerals be identified from its magnetic properties, but individual members of the family can be recognized. The Curie point is one of the most reliable magnetic properties for identifying such minerals. The apparatus described in this bulletin was designed to permit the rapid, accurate measurement of the Curie point of the ferromagnetic minerals in rock specimens, and by this means to identify them. J. M. HARRISON, Director, Geological Survey of Canada OTTAWA, April 28, 1960 v CONTENTS PAGE Introduction 1 General description 1 The torsion balance 2 The recording system 6 The heating element ........ ..... 8 The electromagnet 9 Operation and calibration of the apparatus 12 Practical application . 15 Bibliography 18 Table I. Curie points of specimens of basic intrusive rocks . 16 Plate I. General view of Curie point meter Frontispiece Figure 1. Schematic view of the Curie point meter . 2 2. Longitudinal section of torsion balance 3 3. -
Rock Magnetism of Remagnetized Carbonate Rocks: Another Look
Downloaded from http://sp.lyellcollection.org/ at University of California Berkeley on July 30, 2013 Rock magnetism of remagnetized carbonate rocks: another look MIKE JACKSON* & NICHOLAS L. SWANSON-HYSELL Institute for Rock Magnetism, Winchell School of Earth Sciences, University of Minnesota, Minnesota, US *Corresponding author (e-mail: [email protected]) Abstract: Authigenic formation of fine-grained magnetite is responsible for widespread chemical remagnetization of many carbonate rocks. Authigenic magnetite grains, dominantly in the super- paramagnetic and stable single-domain size range, also give rise to distinctive rock-magnetic prop- erties, now commonly used as a ‘fingerprint’ of remagnetization. We re-examine the basis of this association in terms of magnetic mineralogy and particle-size distribution in remagnetized carbon- ates having these characteristic rock-magnetic properties, including ‘wasp-waisted’ hysteresis loops, high ratios of anhysteretic remanence to saturation remanence and frequency-dependent susceptibility. New measurements on samples from the Helderberg Group allow us to quantify the proportions of superparamagnetic, stable single-domain and larger grains, and to evaluate the mineralogical composition of the remanence carriers. The dominant magnetic phase is magnetite-like, with sufficient impurity to completely suppress the Verwey transition. Particle sizes are extremely fine: approximately 75% of the total magnetite content is superparamagnetic at room temperature and almost all of the rest is stable single-domain. Although it has been pro- posed that the single-domain magnetite in these remagnetized carbonates lacks shape anisotropy (and is therefore controlled by cubic magnetocrystalline anisotropy), we have found strong exper- imental evidence that cubic anisotropy is not an important underlying factor in the rock-magnetic signature of chemical remagnetization. -
Magnetic Properties of the Magnetite-Spinel Solid Solution: Curie Temperatures, Magnetic Susceptibilities, and Cation Ordering
American Mineralogist, Volume 81, pages 375-384, 1996 Magnetic properties of the magnetite-spinel solid solution: Curie temperatures, magnetic susceptibilities, and cation ordering RICHARD J. HARRISON ANDANDREW PurNIS * Department of Earth Sciences, University of Cambridge, Downing Street, Cambridge CB2 3EQ, U.K. ABSTRACT Curie temperatures (Td of the (Fe304)x(MgA1204)1-xsolid solution have been deter- mined from measurements of magnetic susceptibility (x) vs. temperature. The trend in Te vs. composition extrapolates to 0 K at x = 0.27. This behavior is rationalized in terms of the trend in cation distribution vs. composition suggested by Nell and Wood (1989), with Fe occurring predominantly on tetrahedral sites for x < 0.27. High-temperature x-T curves are nonreversible because of the processes of cation or- dering and exsolution, which occur in the temperature range 400-650 0c. The Curie tem- perature of single-phase material is shown to be sensitive to the state of nonconvergent cation order, with a difference in Te of more than 70°C being observed between a sample quenched from 1400 °C and the same sample after heating to 650°C. This interaction between magnetic and chemical ordering leads to thermal hysteresis behavior such that Te measured during heating experiments is approximately 10°Chigherthan that measured during cooling. The hysteresis is due to a reversible difference in the state of cation order during heating and cooling caused by a kinetic lag in the cation-ordering behavior. Samples with compositions in the range 0.55 < x < 0.7 undergo exsolution to a mixture of ferrimagnetic and paramagnetic phases after heating to 650°C. -
Tailored Magnetic Properties of Exchange-Spring and Ultra Hard Nanomagnets
Max-Planck-Institute für Intelligente Systeme Stuttgart Tailored Magnetic Properties of Exchange-Spring and Ultra Hard Nanomagnets Kwanghyo Son Dissertation An der Universität Stuttgart 2017 Tailored Magnetic Properties of Exchange-Spring and Ultra Hard Nanomagnets Von der Fakultät Mathematik und Physik der Universität Stuttgart zur Erlangung der Würde eines Doktors der Naturwissenschaften (Dr. rer. nat.) genehmigte Abhandlung Vorgelegt von Kwanghyo Son aus Seoul, SüdKorea Hauptberichter: Prof. Dr. Gisela Schütz Mitberichter: Prof. Dr. Sebastian Loth Tag der mündlichen Prüfung: 04. Oktober 2017 Max‐Planck‐Institut für Intelligente Systeme, Stuttgart 2017 II III Contents Contents ..................................................................................................................................... 1 Chapter 1 ................................................................................................................................... 1 General Introduction ......................................................................................................... 1 Structure of the thesis ....................................................................................................... 3 Chapter 2 ................................................................................................................................... 5 Basic of Magnetism .......................................................................................................... 5 2.1 The Origin of Magnetism ....................................................................................... -
Understanding the Origin of Magnetocrystalline Anisotropy in Pure and Fe/Si Substituted Smco5
Understanding the origin of magnetocrystalline anisotropy in pure and Fe/Si substituted SmCo5 *Rajiv K. Chouhan1,2,3, A. K. Pathak3, and D. Paudyal3 1CNR-NANO Istituto Nanoscienze, Centro S3, I-41125 Modena, Italy 2Harish-Chandra Research Institute, HBNI, Jhunsi, Allahabad 211019, India 3The Ames Laboratory, U.S. Department of Energy, Iowa State University, Ames, IA 50011–3020, USA We report magnetocrystalline anisotropy of pure and Fe/Si substituted SmCo5. The calculations were performed using the advanced density functional theory (DFT) including onsite electron-electron correlation and spin orbit coupling. Si substitution substantially reduces both uniaxial magnetic anisotropy and magnetic moment. Fe substitution with the selective site, on the other hand, enhances the magnetic moment with limited chemical stability. The magnetic hardness of SmCo5 is governed by Sm 4f localized orbital contributions, which get flatten and split with the substitution of Co (2c) with Si/Fe atoms, except the Fe substitution at 3g site. It is also confirmed that Si substitutions favor the thermodynamic stability on the contrary to diminishing the magnetic and anisotropic effect in SmCo5 at either site. INTRODUCTION Search for high-performance permanent magnets is always being a challenging task for modern technological applications as they are key driving components for propulsion motors, wind turbines and several other direct or indirect market consumer products. Curie temperature Tc, magnetic anisotropy, and saturation magnetization Ms, of the materials, are some basic fundamental properties used to classify the permanent magnets. At Curie temperature a material loses its ferromagnetic properties, hence higher the Tc, better is the magnets to be used under extreme conditions. -
8. Data Report: Paleomagnetic and Rock Magnetic Characterization of Rocks Recovered from Leg 173 Sites1
Beslier, M.-O., Whitmarsh, R.B., Wallace, P.J., and Girardeau, J. (Eds.) Proceedings of the Ocean Drilling Program, Scientific Results Volume 173 8. DATA REPORT: PALEOMAGNETIC AND ROCK MAGNETIC CHARACTERIZATION OF ROCKS RECOVERED FROM LEG 173 SITES1 Xixi Zhao,2 Brent D. Turrin,3 Mike Jackson,4 and Peter Solheid4 ABSTRACT We present detailed paleomagnetic and rock magnetic results of rock samples recovered during Leg 173. The Leg 173 cores display a multi- component magnetization nature. Variations in magnetic properties correlate with changes in lithology that result from differences in the 1Zhao, X., Turrin, B.D., Jackson, M., abundance and size of magnetic minerals. The combined investigation and Solheid, P., 2001. Data report: suggests that the magnetic properties of the “fresher” peridotite sam- Paleomagnetic and rock magnetic ples from Site 1070 are controlled mainly by titanomagnetite, with a characterization of rocks recovered from Leg 173 sites. In Beslier, M.-O., strong Verwey transition in the vicinity of 110 K, and with field- and Whitmarsh, R.B., Wallace, P.J., and frequency-dependent susceptibility curves that resemble those of tita- Girardeau, J. (Eds.), Proc. ODP, Sci. nomagnetites. These results are in excellent agreement with thermo- Results, 173, 1–34 [Online]. Available magnetic characteristics where titanomagnetites with Curie tempera- from World Wide Web: <http:// ture ~580°C were identified from the “fresher” peridotites. In contrast www-odp.tamu.edu/publications/ 173_SR/VOLUME/CHAPTERS/ to the magnetic properties observed from the “fresher” peridotites, the SR173_08.PDF>. [Cited YYYY-MM-DD] low-temperature curves for the “altered” peridotites did not show any 2Institute of Tectonics, University of Verwey transition. -
Superparamagnetism and Magnetic Properties of Ni Nanoparticles Embedded in Sio2
PHYSICAL REVIEW B 66, 104406 ͑2002͒ Superparamagnetism and magnetic properties of Ni nanoparticles embedded in SiO2 F. C. Fonseca, G. F. Goya, and R. F. Jardim* Instituto de Fı´sica, Universidade de Sa˜o Paulo, CP 66318, 05315-970, Sa˜o Paulo, SP, Brazil R. Muccillo Centro Multidisciplinar de Desenvolvimento de Materiais Ceraˆmicos CMDMC, CCTM-Instituto de Pesquisas Energe´ticas e Nucleares, CP 11049, 05422-970, Sa˜o Paulo, SP, Brazil N. L. V. Carren˜o, E. Longo, and E. R. Leite Centro Multidisciplinar de Desenvolvimento de Materiais Ceraˆmicos CMDMC, Departamento de Quı´mica, Universidade Federal de Sa˜o Carlos, CP 676, 13560-905, Sa˜o Carlos, SP, Brazil ͑Received 4 March 2002; published 6 September 2002͒ We have performed a detailed characterization of the magnetic properties of Ni nanoparticles embedded in a SiO2 amorphous matrix. A modified sol-gel method was employed which resulted in Ni particles with ϳ Ϸ average radius 3 nm, as inferred by TEM analysis. Above the blocking temperature TB 20 K for the most diluted sample, magnetization data show the expected scaling of the M/M S vs H/T curves for superparamag- netic particles. The hysteresis loops were found to be symmetric about zero field axis with no shift via Ͻ exchange bias, suggesting that Ni particles are free from an oxide layer. For T TB the magnetic behavior of these Ni nanoparticles is in excellent agreement with the predictions of randomly oriented and noninteracting magnetic particles, as suggested by the temperature dependence of the coercivity field that obeys the relation ϭ Ϫ 1/2 ϳ HC(T) HC0͓1 (T/TB) ͔ below TB with HC0 780 Oe.